CN106417324A - Efficient composite germicide for industrial circulating cooling water system - Google Patents
Efficient composite germicide for industrial circulating cooling water system Download PDFInfo
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- CN106417324A CN106417324A CN201610649606.7A CN201610649606A CN106417324A CN 106417324 A CN106417324 A CN 106417324A CN 201610649606 A CN201610649606 A CN 201610649606A CN 106417324 A CN106417324 A CN 106417324A
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- cooling water
- water system
- circulating cooling
- industrial circulating
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
- A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an efficient composite germicide for an industrial circulating cooling water system. The efficient composite germicide comprises, by weight, 8-10 parts of isothiazolinone derivatives, 6-8 parts of bronopol and 6-8 parts of acrylic acid-2-methyl-acrylamido propane sulfonic acid polymer. By the aid of the isothiazolinone derivatives, the bronopol and the acrylic acid-2-methyl-acrylamido propane sulfonic acid polymer, the efficient composite germicide for the industrial circulating cooling water system can effectively adapt to different water quality, is non-corrosive in industrial application and is good in solubility when added into liquid. The efficient composite germicide has special effects on heterotrophic bacteria, adding concentration is 50-80ppm, heterotrophic bacteria killing percentage is higher than or equal to 99%, sulfate reducing bacteria killing percentage is higher than or equal to 99%, and iron bacteria killing percentage is higher than or equal to 99%.
Description
Technical field
The present invention relates to antibacterial technical field, specially one kind are for the sterilization of industrial circulating cooling water system high efficiency composition
Agent.
Background technology
Industrial circulating cooling water system is using water as cooling medium, and a kind of cooling water system recycling, mainly
It is made up of cooling device, water pump and pipeline, cold water flows through the production equipment needing cooling（Often claim heat transmission equipment, such as heat exchanger, cold
Condenser, reactor）Afterwards, temperature rises, if discharged at once, cold water is only used once（Claim once-through cooling water system）, make intensification cold
Then water temperature returns fall to current supercooling equipment, and available pumped back production equipment reuses, and the consumption of cold water substantially reduces, Chang Kejie
About more than 95%, cooling water accounts for the 70% about of industrial water consumption, and therefore, recirculating cooling water system has played a large amount of water for industrial use of saving
Effect.
Antibacterial usually can be used in present industrial circulating cooling water system, antibacterial is also known as biocide, sterilizing
Algae agent or microbicide etc., typically refer to efficiently control or kill microbial bacterial in water system, funguses and
The chemicals of algae.But it is not applied for different water quality more present antibacterial, have certain when industrially applying
Corrosivity, when putting in liquid, dissolubility is poor, and compounds and the effect of creating antagonism because each component is unsuitable, with it
Its antibacterial compatibility is also poor, leads to effect to reduce or the phenomenon of forfeiture happens occasionally, the effect of impact sterilization.
Content of the invention
It is an object of the invention to provide a kind of be used for industrial circulating cooling water system high efficiency composition antibacterial, on solving
State proposition in background technology more and be not applied for different water quality, when industrially applying, there are certain corrosivity, put into
During in liquid, dissolubility is poor, and compounds and the effect of creating antagonism because each component is unsuitable, joins with other antibacterial
5 property are also poor, lead to effect to reduce or the phenomenon of forfeiture happens occasionally, the problem of the effect of impact sterilization.
For achieving the above object, the present invention provides following technical scheme：A kind of efficient for industrial circulating cooling water system
Compound disinfectant, including the raw material of following parts by weight proportioning：Isothiazolinone derivatives 8-10 part, smell nitre alcohol 6-8 part and third
Olefin(e) acid -2- methyl -2- acrylamido propane sulfonic acid polymer 6-8 part.
Preferably, including the raw material of following parts by weight proportioning：10 parts of isothiazolinone derivatives, smell 8 parts of nitre alcohol and third
8 parts of olefin(e) acid -2- methyl -2- acrylamido propane sulfonic acid polymer.
Preferably, including the raw material of following parts by weight proportioning：8 parts of isothiazolinone derivatives, smell 6 parts of nitre alcohol and propylene
6 parts of acid -2- methyl -2- acrylamido propane sulfonic acid polymer.
Preferably, including the raw material of following parts by weight proportioning：9 parts of isothiazolinone derivatives, smell 7 parts of nitre alcohol and propylene
7 parts of acid -2- methyl -2- acrylamido propane sulfonic acid polymer.
The invention solves the problems that another technical problem be provide one kind kill for industrial circulating cooling water system high efficiency composition
Microbial inoculum, comprises the following steps：Successively in order by isothiazolinone derivatives 8-10 part, smell nitre alcohol 6-8 part and acrylic acid -2- first
Base -2- acrylamido propane sulfonic acid polymer 6-8 part is put in reactor, stirs 2-3 hour, directly under the conditions of 110 DEG C
To solution clear, then pass through 500 mesh filter screens and filter, finished product.
Preferably, described isothiazolinone derivatives are mainly by CMIT（CIT）With
MIT（MIT）Press（4-6.5）:（6-3.5）Composition, isothiazolinone derivatives are thin by disconnecting
The key of bacterium and algae protein matter and act the effect of killing livestock, after it is contacted with microorganism, can promptly irreversibly suppress its growth,
Thus leading to the death of microbial cell, therefore to common bacteria, funguses, algae etc., there is very strong suppression and killing action, energy
Miscible with chlorine and most of anions and canons and nonionic surfactant, when isothiazolinone derivatives are in ratio of the present invention
During dosage 8-10 part, isothiazolone has remarkable result to biological sludge stripping.
Preferably, described acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer is mainly used as open type industry
The antiscaling dispersion of recirculating cooling water system, rejection of oil flied effluent system and metallurgical system circulating water treatment, prevents iron sesquioxide
Stickydeposit, can be with organic phosphonate and zinc salt compound use.
The invention has the beneficial effects as follows：This is used for industrial circulating cooling water system high efficiency composition antibacterial, by by different thiophene
Oxazoline ketone derivatives, smell nitre alcohol and acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer and be combined collaborative, Ke Yineng
It is applied to different water quality well, non-corrosiveness when industrially applying, when putting in liquid, dissolubility is good, and due to
Compatibility between each group is divided is good, is not in the effect creating antagonism because unsuitable compounding, simultaneously with other antibacterial
Compatibility is also preferably it is ensured that the normal performance of effect and sterilizing ability.This high efficiency composition antibacterial has specially good effect to heterotrophic bacteria, adds
Concentration is 50-80ppm, kills heterotrophic bacteria percentage rate >=99%；Kill sulfate reducting bacteria percentage rate >=99%；Kill iron bacteria percentage rate >=
99%, field germicidal efficacy detects：Heterotrophic bacteria≤2*102Individual/ml；Sulfate reducting bacteria≤25/ml；Iron bacteria≤10/
ml.
Specific embodiment
Below by the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, shows
So, described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on the reality in the present invention
Apply example, the every other embodiment that those of ordinary skill in the art are obtained under the premise of not making creative work, all belong to
In the scope of protection of the invention.
Embodiment one：
One kind is used for industrial circulating cooling water system high efficiency composition antibacterial, including the raw material of following parts by weight proportioning：Different thiophene
8 parts of oxazoline ketone derivatives（100 kilograms every part, similarly hereinafter）, smell 8 parts of nitre alcohol and acrylic acid -2- methyl -2- acrylamido propane sulphur
8 parts of acid polymer.
One kind is used for industrial circulating cooling water system high efficiency composition antibacterial, comprises the following steps：Successively in order will be different
Thiazolinone derivant（Mainly by CMIT（CIT）With 2- methyl -4- isothiazoline -3-
Ketone（MIT）By 5:5 compositions）8 parts, smell 8 parts of nitre alcohol and 8 parts of acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer is put
Enter in reactor, under the conditions of 110 DEG C, stir 2-3 hour, until solution clear, then pass through 500 mesh filter screens and filter,
Finished product.
Embodiment two：
One kind is used for industrial circulating cooling water system high efficiency composition antibacterial, including the raw material of following parts by weight proportioning：Different thiophene
Oxazoline ketone derivatives（CMIT（CIT）And MIT（MIT）Press
6:4 compositions）10 parts, smell 8 parts of nitre alcohol and 8 parts of acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer.
One kind is used for industrial circulating cooling water system high efficiency composition antibacterial, comprises the following steps：Successively in order will be different
10 parts of thiazolinone derivant, smell 8 parts of nitre alcohol and 8 parts of acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer is put into
To in reactor, under the conditions of 110 DEG C, stir 2-3 hour, until solution clear, then pass through 500 mesh filter screens and filter, system
Obtain finished product.
Embodiment three：
One kind is used for industrial circulating cooling water system high efficiency composition antibacterial, including the raw material of following parts by weight proportioning：Different thiophene
Oxazoline ketone derivatives（CMIT（CIT）And MIT（MIT）Press
4:6 compositions）8 parts, smell 6 parts of nitre alcohol and 6 parts of acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer.
One kind is used for industrial circulating cooling water system high efficiency composition antibacterial, comprises the following steps：Successively in order will be different
8 parts of thiazolinone derivant, smell 6 parts of nitre alcohol and 6 parts of acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer is put into
To in reactor, under the conditions of 110 DEG C, stir 2-3 hour, until solution clear, then pass through 500 mesh filter screens and filter, system
Obtain finished product.
Example IV：
One kind is used for industrial circulating cooling water system high efficiency composition antibacterial, including the raw material of following parts by weight proportioning：Different thiophene
Oxazoline ketone derivatives（CMIT（CIT）And MIT（MIT）Press
6.5:3.5 composition）9 parts, smell 7 parts of nitre alcohol and 7 parts of acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer.
One kind is used for industrial circulating cooling water system high efficiency composition antibacterial, comprises the following steps：Successively in order will be different
9 parts of thiazolinone derivant, smell 7 parts of nitre alcohol and 7 parts of acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer is put into
To in reactor, under the conditions of 110 DEG C, stir 2-3 hour, until solution clear, then pass through 500 mesh filter screens and filter, system
Obtain finished product.
Experimental example：Following table be antibacterial comparative test result in order to verify the effect of the present invention, under identical dosage, will
The high efficiency composition antibacterial of embodiment two to four preparation and existing antibacterial carry out the contrast test of bactericidal effect, and its result is such as
Shown in following table.
Criterion：Compared to existing antibacterial product, using the high efficiency composition antibacterial of inventive formulation preparation, its
Sterilizing ability is more preferable.
The invention has the beneficial effects as follows：This is used for industrial circulating cooling water system high efficiency composition antibacterial, different by arranging
Thiazolinone derivant, smell nitre alcohol and acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer, can well
It is applied to different water quality, non-corrosiveness when industrially applying, when putting in liquid, dissolubility is good, and due to each component
Between compatibility good, be not in the effect creating antagonism because unsuitable compounding, simultaneously with other antibacterial compatibilities
Also preferably it is ensured that the normal performance of effect and sterilizing ability.This high efficiency composition antibacterial has specially good effect to heterotrophic bacteria, adds concentration and is
50-80ppm, kills heterotrophic bacteria percentage rate >=99%；Kill sulfate reducting bacteria percentage rate >=99%；Kill iron bacteria percentage rate >=99%, existing
Field bactericidal effect：Heterotrophic bacteria percentage rate≤200/ml；Sulfate reducting bacteria≤25/ml；Iron bacteria≤10/ml.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, permissible
Understand and can carry out multiple changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (7)
1. one kind is joined it is characterised in that including following parts by weight for industrial circulating cooling water system high efficiency composition antibacterial
The raw material of ratio：Isothiazolinone derivatives 8-10 part, smell nitre alcohol 6-8 part and acrylic acid -2- methyl -2- acrylamido propane sulphur
Acid polymer 6-8 part.
2. according to claim 1 a kind of for industrial circulating cooling water system high efficiency composition antibacterial it is characterised in that
Raw material including following parts by weight proportioning：10 parts of isothiazolinone derivatives, smell 8 parts of nitre alcohol and acrylic acid -2- methyl -2- third
8 parts of acrylamide base propane sulfonic acid polymer.
3. according to claim 1 a kind of for industrial circulating cooling water system high efficiency composition antibacterial it is characterised in that
Raw material including following parts by weight proportioning：8 parts of isothiazolinone derivatives, smell 6 parts of nitre alcohol and acrylic acid -2- methyl -2- third
6 parts of acrylamide base propane sulfonic acid polymer.
4. according to claim 1 a kind of for industrial circulating cooling water system high efficiency composition antibacterial it is characterised in that
Raw material including following parts by weight proportioning：9 parts of isothiazolinone derivatives, smell 7 parts of nitre alcohol and acrylic acid -2- methyl -2- third
7 parts of acrylamide base propane sulfonic acid polymer.
5. a kind of prepare described in claim 1 be used for industrial circulating cooling water system high efficiency composition antibacterial method, its feature
It is that the method comprises the following steps：Successively in order by isothiazolinone derivatives 8-10 part, smell nitre alcohol 6-8 part and propylene
Acid -2- methyl -2- acrylamido propane sulfonic acid polymer 6-8 part is put in reactor, stirs 2-3 under the conditions of 110 DEG C
Hour, until solution clear, then pass through 500 mesh filter screens and filter, finished product.
6. according to claim 1 a kind of for industrial circulating cooling water system high efficiency composition antibacterial it is characterised in that
Described isothiazolinone derivatives are mainly by CMIT（CIT）With 2- methyl -4- isothiazole
Quinoline -3- ketone（MIT）Composition, isothiazolinone derivatives are to act, by disconnecting the key of antibacterial and algae protein matter, the effect of killing livestock
, after it is contacted with microorganism, promptly can irreversibly suppress its growth, thus leading to the death of microbial cell, thus right
Common bacteria, funguses, algae etc. have very strong suppression and killing action, can be with chlorine and most of anions and canons and nonionic
Surfactant is miscible, and isothiazolinone derivatives, in 8-10 part, have remarkable result to biological sludge stripping.
7. according to claim 1 a kind of for industrial circulating cooling water system high efficiency composition antibacterial it is characterised in that
Described acrylic acid -2- methyl -2- acrylamido propane sulfonic acid polymer be mainly used as open type industrial circulating cooling water system,
Rejection of oil flied effluent system and the antiscaling dispersion of metallurgical system circulating water treatment, prevent iron sesquioxide Stickydeposit, can with have
Organic phosphonates and zinc salt compound use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610649606.7A CN106417324A (en) | 2016-08-10 | 2016-08-10 | Efficient composite germicide for industrial circulating cooling water system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610649606.7A CN106417324A (en) | 2016-08-10 | 2016-08-10 | Efficient composite germicide for industrial circulating cooling water system |
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| CN106417324A true CN106417324A (en) | 2017-02-22 |
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| CN201610649606.7A Pending CN106417324A (en) | 2016-08-10 | 2016-08-10 | Efficient composite germicide for industrial circulating cooling water system |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928196A (en) * | 1973-12-05 | 1975-12-23 | Calgon Corp | Inhibition of scale deposition |
| US4732905A (en) * | 1987-03-13 | 1988-03-22 | Betz Laboratories, Inc. | Biocidal compositions and use thereof containing a synergistic mixture of 2-bromo-2-nitropropane-1,3-diol and a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one |
| JP2003238318A (en) * | 2002-02-18 | 2003-08-27 | Takeda Chem Ind Ltd | Industrial microbicidal composition |
| CN103304045A (en) * | 2013-07-03 | 2013-09-18 | 成都万潮表面技术有限公司 | Scale and corrosion inhibitor and preparation method thereof |
-
2016
- 2016-08-10 CN CN201610649606.7A patent/CN106417324A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3928196A (en) * | 1973-12-05 | 1975-12-23 | Calgon Corp | Inhibition of scale deposition |
| US4732905A (en) * | 1987-03-13 | 1988-03-22 | Betz Laboratories, Inc. | Biocidal compositions and use thereof containing a synergistic mixture of 2-bromo-2-nitropropane-1,3-diol and a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one |
| JP2003238318A (en) * | 2002-02-18 | 2003-08-27 | Takeda Chem Ind Ltd | Industrial microbicidal composition |
| CN103304045A (en) * | 2013-07-03 | 2013-09-18 | 成都万潮表面技术有限公司 | Scale and corrosion inhibitor and preparation method thereof |
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Application publication date: 20170222 |