CN106129157A - The packaging adhesive film of a kind of solar module and application thereof - Google Patents

The packaging adhesive film of a kind of solar module and application thereof Download PDF

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Publication number
CN106129157A
CN106129157A CN201610808539.9A CN201610808539A CN106129157A CN 106129157 A CN106129157 A CN 106129157A CN 201610808539 A CN201610808539 A CN 201610808539A CN 106129157 A CN106129157 A CN 106129157A
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CN
China
Prior art keywords
adhesive film
solar module
packaging adhesive
spectrum
conversion particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610808539.9A
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Chinese (zh)
Inventor
娄朝刚
邵国键
李路
曹辉辉
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Southeast University
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Southeast University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Southeast University filed Critical Southeast University
Priority to CN201610808539.9A priority Critical patent/CN106129157A/en
Publication of CN106129157A publication Critical patent/CN106129157A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/055Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means where light is absorbed and re-emitted at a different wavelength by the optical element directly associated or integrated with the PV cell, e.g. by using luminescent material, fluorescent concentrators or up-conversion arrangements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses packaging adhesive film and the application thereof of a kind of solar module, this packaging adhesive film is made up of conversion particles under transparent organic glued membrane and spectrum, during under described spectrum, conversion particles is distributed in transparent organic glued membrane, under spectrum, the distribution density of conversion particles becomes larger from top to bottom.The advantage of this glued membrane is to become the high-energy photons in sunlight being easier to absorbed energy photons, forms a graded index gradient from top to bottom simultaneously, reduce surface reflection in solar module.The present invention can either make high-energy photons be used more effectively, and can reduce again surface reflection, improve the photoelectric transformation efficiency of solar module.

Description

The packaging adhesive film of a kind of solar module and application thereof
Technical field
The invention belongs to technical field of solar batteries, particularly to the packaging adhesive film of a kind of solar module.
Background technology
When solar irradiation is mapped to solar cell surface, a portion light is reflected by surface, and remainder is absorbed Or pass through.Owing to being limited by solaode material therefor, in solar spectrum, the portion of energy of high-energy photons cannot be by Effectively absorb and be used for generating electricity, cause conversion efficiency of solar cell the highest.
After solar battery sheet is packaged into assembly, owing to assembly adding glass plate and organic glued membrane, bring into Penetrating the increase of luminous reflectance, after causing encapsulation, the conversion efficiency of assembly is less than the efficiency encapsulating front cell piece.
Summary of the invention
It is an object of the invention to provide the packaging adhesive film of a kind of solar module, to improve the profit of high-energy photons With the surface reflection of rate and reduction assembly, improve the conversion efficiency of solar module so that turning of solar module Change efficiency higher than the conversion efficiency of cell piece before encapsulation.
For achieving the above object, the technical solution used in the present invention is:
A kind of packaging adhesive film of solar module, it is made up of conversion particles under transparent organic glued membrane and spectrum, During under described spectrum, conversion particles is distributed in transparent organic glued membrane.
Further, under described spectrum, the distribution density of conversion particles becomes larger from top to bottom.
Further, described organic packages glued membrane is transparent ethylene-vinyl acetate copolymer or organic transparent silica gel.
Further, under described spectrum, the material of conversion particles is the one in fluorescent RE powder, quantum dot, organic dyestuff Or it is multiple.
Described fluorescent RE powder be the yttrium aluminium garnet fluorescent powder containing rare-earth element cerium or containing rare-earth element cerium and its The yttrium aluminium garnet fluorescent powder of his rare earth element.
The packaging adhesive film that present invention also offers above-mentioned solar module is improving solar module Application in terms of conversion efficiency.
Further, in solar module, described packaging adhesive film is positioned at lower surface and the solaode of glass Between the upper surface of sheet.
Further, described packaging adhesive film is one or more layers.
Further, described multilamellar is to have the glued membrane of conversion particles distribution density under different spectrum.
Beneficial effect: the present invention is to solve that solar module efficiency declines problem, used for encapsulation of solar battery Transparent organic glued membrane in be mixed into conversion particles under spectrum, make a kind of new packaging adhesive film, and make its distribution density to Under increase successively.Not only increase the utilization rate of high-energy photons, be low-energy photon by high-octane photon conversion, conversion During photon numbers can increase, and under the spectrum of gradual change, the distribution density of conversion particles can form the refractive index of a gradual change Gradient, reduces the surface reflection of incident illumination, so that the conversion efficiency of solar module is improved.This solar energy The packaging adhesive film of battery component can realize the wavelength convert of high-energy photons, can reduce again the reflection of assembly surface, its Conversion efficiency is higher than the conversion efficiency of cell piece before encapsulation.
Accompanying drawing explanation
Fig. 1 is to have the packaging adhesive film of conversion particles distribution density under gradual change;
Fig. 2 is that multilamellar has the glued membrane of conversion particles distribution density under different spectrum;
In figure, 1 is transparent organic glued membrane, and 2 is conversion particles under spectrum.
Detailed description of the invention
Below in conjunction with the accompanying drawings the present invention is further described.
As illustrated in fig. 1 and 2 for the packaging adhesive film of a kind of solar module, it is by transparent organic glued membrane 1 and spectrum Lower conversion particles 2 forms, and during under spectrum, conversion particles 1 is distributed in transparent organic glued membrane 2, under spectrum, the distribution of conversion particles 1 is close Degree becomes larger from top to bottom.
Wherein, organic packages glued membrane is transparent ethylene-vinyl acetate copolymer or organic transparent silica gel.
One or more during the material of conversion particles is fluorescent RE powder, quantum dot, organic dyestuff under spectrum.
Fluorescent RE powder is the yttrium aluminium garnet fluorescent powder containing rare-earth element cerium or dilute with other containing rare-earth element cerium The yttrium aluminium garnet fluorescent powder of earth elements.
The packaging adhesive film of above-mentioned solar module can improve the conversion efficiency of solar module.
In solar module, described packaging adhesive film is positioned at the lower surface of glass and the upper surface of solar battery sheet Between.
Packaging adhesive film is that one or more layers has the glued membrane of conversion particles distribution density under different spectrum.
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment 1:
The packaging adhesive film of a kind of solar module, it is by conversion particles 2 groups under transparent organic glued membrane 1 and spectrum Becoming, during under spectrum, conversion particles 1 is distributed in transparent organic glued membrane 2, under spectrum, conversion particles 1 uses ethylene-vinyl acetate altogether Polymers, under spectrum, conversion particles 2 uses the yttrium aluminium garnet fluorescent powder of rare-earth element cerium.
Preparation method is: during preparing transparent ethylene-vinyl acetate copolymer, mixes containing rare-earth element cerium Yttrium aluminium garnet fluorescent powder, make the mixture of three kinds of different fluorescent material content.Fall successively according to the size of fluorescent material content Enter in container, form the mixture that a distribution of particles density from top to bottom is gradually increased, then through overcuring and moulding process Form glued membrane.
Embodiment 2:
The packaging adhesive film of a kind of solar module, it is by conversion particles 2 groups under transparent organic glued membrane 1 and spectrum Becoming, during under spectrum, conversion particles 1 is distributed in transparent organic glued membrane 2, under spectrum, conversion particles 1 uses organic silica gel, lower turn of spectrum Change granule 2 to use containing rare-earth element cerium and the yttrium aluminium garnet fluorescent powder of ytterbium.
Preparation method is: during preparation is transparent with machine silica gel, mixes containing rare-earth element cerium and the yttrium aluminum of ytterbium Garnet phosphor powder, makes the mixture of five kinds of different fluorescent material content.By every kind of mixture through overcuring and moulding process shape Become the glued membrane that fluorescent powder grain density is different.
Embodiment 3:
The packaging adhesive film of a kind of solar module, it is by conversion particles 2 groups under transparent organic glued membrane 1 and spectrum Becoming, during under spectrum, conversion particles 1 is distributed in transparent organic glued membrane 2, under spectrum, conversion particles 1 uses ethylene-vinyl acetate altogether Polymers, under spectrum, conversion particles 2 uses quantum dot.
Preparation method is: during preparing transparent ethylene-vinyl acetate copolymer, mixes quantum dot, makes three Plant the mixture of different quantum dot content.Pour into successively in container according to the size of quantum dot content, form one from top to bottom The mixture that is gradually increased of distribution of particles density, then form glued membrane through overcuring with moulding process.
Embodiment 4:
The packaging adhesive film of a kind of solar module, it is by conversion particles 2 groups under transparent organic glued membrane 1 and spectrum Becoming, during under spectrum, conversion particles 1 is distributed in transparent organic glued membrane 2, under spectrum, conversion particles 1 uses ethylene-vinyl acetate altogether Polymers, under spectrum, conversion particles 2 uses organic dyestuff.
Preparation method is: during preparing transparent ethylene-vinyl acetate copolymer, is mixed with organic dye, makes The mixture of three kinds of different quantum dot content.Every kind of mixture is formed organic dye content through overcuring from moulding process different Glued membrane.
The above is only the preferred embodiment of the present invention, it should be pointed out that: for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (9)

1. the packaging adhesive film of a solar module, it is characterised in that: this packaging adhesive film is by transparent organic glued membrane and light The lower conversion particles composition of spectrum, during under described spectrum, conversion particles is distributed in transparent organic glued membrane.
The packaging adhesive film of solar module the most according to claim 1, it is characterised in that: conversion particles under spectrum Distribution density become larger from top to bottom.
The packaging adhesive film of solar module the most according to claim 1, it is characterised in that: described organic packages glue Film is transparent ethylene-vinyl acetate copolymer or organic transparent silica gel.
The packaging adhesive film of solar module the most according to claim 1, it is characterised in that: change under described spectrum The material of granule is one or more in fluorescent RE powder, quantum dot, organic dyestuff.
The packaging adhesive film of solar module the most according to claim 1, it is characterised in that: described fluorescent RE powder For the yttrium aluminium garnet fluorescent powder containing rare-earth element cerium or containing rare-earth element cerium and the yttrium-aluminium-garnet of other rare earth elements Fluorescent material.
6. the packaging adhesive film of the arbitrary described solar module of claim 1-5 is improving turning of solar module Change the application in terms of efficiency.
Application the most according to claim 6, it is characterised in that: in solar module, described packaging adhesive film is positioned at Between lower surface and the upper surface of solar battery sheet of glass.
Application the most according to claim 7, it is characterised in that: described packaging adhesive film is one or more layers.
Application the most according to claim 8, it is characterised in that: described multilamellar is for having conversion particles distribution under different spectrum The glued membrane of density.
CN201610808539.9A 2016-09-07 2016-09-07 The packaging adhesive film of a kind of solar module and application thereof Pending CN106129157A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610808539.9A CN106129157A (en) 2016-09-07 2016-09-07 The packaging adhesive film of a kind of solar module and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610808539.9A CN106129157A (en) 2016-09-07 2016-09-07 The packaging adhesive film of a kind of solar module and application thereof

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CN106129157A true CN106129157A (en) 2016-11-16

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108389926A (en) * 2018-01-18 2018-08-10 合肥晶澳太阳能科技有限公司 A kind of packaging method of photovoltaic module
CN110416339A (en) * 2019-07-04 2019-11-05 东南大学 A kind of structure improving solar cell module transfer efficiency
CN110643298A (en) * 2019-10-10 2020-01-03 常州斯威克光伏新材料有限公司 Multilayer fluorescent packaging adhesive film
US20230402559A1 (en) * 2022-06-09 2023-12-14 Toyota Jidosha Kabushiki Kaisha Fluorescent light-guiding plate and method of manufacturing the same

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108389926A (en) * 2018-01-18 2018-08-10 合肥晶澳太阳能科技有限公司 A kind of packaging method of photovoltaic module
CN110416339A (en) * 2019-07-04 2019-11-05 东南大学 A kind of structure improving solar cell module transfer efficiency
CN110643298A (en) * 2019-10-10 2020-01-03 常州斯威克光伏新材料有限公司 Multilayer fluorescent packaging adhesive film
US20230402559A1 (en) * 2022-06-09 2023-12-14 Toyota Jidosha Kabushiki Kaisha Fluorescent light-guiding plate and method of manufacturing the same

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