CN106092918A - A kind of miniature UV, visible light/Infrared Non-destructive Testing spectrogrph - Google Patents

A kind of miniature UV, visible light/Infrared Non-destructive Testing spectrogrph Download PDF

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Publication number
CN106092918A
CN106092918A CN201610387106.0A CN201610387106A CN106092918A CN 106092918 A CN106092918 A CN 106092918A CN 201610387106 A CN201610387106 A CN 201610387106A CN 106092918 A CN106092918 A CN 106092918A
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circuit
light
light source
visible
spectrogrph
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刘天军
董晓曦
洪阁
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/27Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N2021/1738Optionally different kinds of measurements; Method being valid for different kinds of measurement
    • G01N2021/1742Optionally different kinds of measurements; Method being valid for different kinds of measurement either absorption or reflection

Abstract

The invention discloses a kind of miniature UV, visible light/Infrared Non-destructive Testing spectrogrph, it includes light source, photoelectric sensor, Circuits System, shell and power supply.Light source includes pin, base, aluminium base, one chip microcomputer circuit, LED array, light conductor and light conducting cylinder;Photoelectric sensor is UV, visible light/infrasil photodiode;Circuits System includes the amplification of single chip machine controlling circuit, power amplifier, signal and filter circuit and data transmission circuit;Shell is with light source slot, outlet, communication socket and the cylinder of sealing coat;Power supply is DC source.Miniature UV, visible light/Infrared Non-destructive Testing the spectrogrph of the present invention may be used for measuring the UV, visible light/infrared transmission of one or more specific objective materials or reflection absorption spectrum, its machine volume is little, lightweight, with low cost, be suitable for Site Detection, it is easy to promote, spectral resolution is ideal, and anti-interference and the stability of system are preferable.

Description

A kind of miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph
Technical field
The invention belongs to optical instrument field, be specifically related to a kind of miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph and Purposes, particularly relates to by light source, photoelectric sensor, Circuits System, shell and electric power generating composition, a kind of or many for Non-Destructive Testing Plant the device of specific objective material ultraviolet-visible/infrared spectrum.
Background technology
Spectral detection be one by measuring the target substance transmission light in ultraviolet-visible light district and infrared light district or reflection The intensity of light carries out the emerging detection technique of qualitative or quantitative analysis.Spectrogrph based on this technical research can apply to Food and the field such as environment measuring, quantitative, the electromagnetic radiation analysis of chemical composition.Traditional spectrogrph by numerous optics, electricity with Mechanical system forms, and the structure of instrument is extremely complex, and integrated cost is higher, and global reliability is poor, working environment and daily dimension The condition protecting requirement is harsher, limits it and is widely applied.In order to meet testing agency and general population daily, real-time, The actual demand of (on-the-spot) spectral measurement online, we be badly in need of exploitation a kind of with low cost, volume is little, lightweight, it is simple to carry Micro spectrometer.
At present, the micro spectrometer of main flow is with U.S.'s marine optics, U.S.'s Agilent, Holland Ai Wantisi, Japan shore pine It is representative Deng the product of company, is mostly based on Cheney-Tener light path, flat filed concave grating light path or Michelson's interferometer, adopts Spectrum, data are received with charge-coupled image sensor (CCD) or cmos image sensor (CMOS) Shown to computer by built-in industrial control machine or USB/ Bluetooth transmission.Due to microelectromechanical systems (MEMS) technology with fine add The fast development of work technology, above-mentioned micro spectrometer can accomplish hand size, and its compact conformation is portable, easy to use, it is fast to measure Speed, price can drop to about ten thousand yuan, is therefore particularly suitable for on-the-spot the most quickly detection.
In recent years, along with the development of 3G/4G development of Mobile Internet technology, the shooting of CMOS camera circuit is carried with smart mobile phone Visible light, with mobile phone A PP analyze institute survey data, using mobile phone screen as show peripheral hardware mobile phone spectrogrph at micro spectral Instrument field shows bigger advantage.Mobile phone spectrogrph only need to design bare engine module, is fitted to each other with mobile phone and can realize spectrum Detection, therefore compares with specialty micro spectrometer and has more preferable portability;Owing to it is without special circuit and special showing Show peripheral hardware, therefore its cost the cheapest (about 3000 yuan can be down to);Pass through mobile Internet, it is possible to achieve count more efficiently Shared according to uploading, thus it is more prone to popularization and application.
Relative to traditional spectrogrph, above-mentioned micro spectrometer has very at aspects such as portability, cost and data transmission Big advantage.But, current micro spectrometer technology there is also a lot of weak points, mainly has:
First, spectral resolution is undesirable.In the optical path, the diverging light that polychromatic light light source sends, through plane transmission grating Light after diffraction is difficult in short distance inner focusing imaging, and therefore spectra overlapping is serious, and spectral resolution is undesirable.
Second, light path is complicated, anti-interference is poor.For realizing light splitting, whole micro spectral instrument system have employed the light of complexity Line structure.Partial optical element in light splitting optical path is such as: reflective micro-mirrors etc. are especially sensitive to ambient temperature, cause spectrometer system Stability and veracity change with ambient temperature, use complicated temperature control system that these elements are carried out temperature control, meeting The complexity of increase system, improves cost.Meanwhile, complex optical path systems for optical position of components requires higher, is once shaken Optical element is caused to misplace etc. physical factor impact, it may appear that bigger measurement error.For mobile phone spectrogrph, If its light channel structure and cellphone body itself are fixed into an entirety, then its complete machine cost is difficult to reduce;If by its light Learn structure and make dismountable module, then cannot avoid the measurement error caused due to each installation site deviation.
3rd, cost is of a relatively high.Owing to the cost of complex optical path and CCD system is of a relatively high, current micro spectral Instrument cost is still difficult to reach the degree that ordinary consumer accepts.As a example by food inspection, present society is for the day of food safety The raising day by day that benefit is paid close attention to and food quality is required by consumer so that before domestic detection spectrogrph is provided with great market Scape, but micro spectrometer is the most up to ten thousand at present, and the most thousands of costs limits its answering in domestic field of detection of food safety With.
The present invention provides a kind of miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph, and it uses LED array as light source Luminous component, controlled the sequence of light of different wave length LED in LED array by one chip microcomputer, based on transmission light or Reflection light, by photoelectric sensor collect signal, the control of whole spectrogrph, power supply, signal processing and data-transformation facility by Circuits System realizes.Miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph the volume of the present invention is little, lightweight, low cost, behaviour Make simple, be easy to carry, be suitable for Site Detection, the detection demand of professional and technical personnel and general population can be met simultaneously, There is wide market prospect and social value.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of miniature ultraviolet-visible/Infrared Non-destructive Testing Spectrogrph.
Second object of the present invention is to provide the purposes of a kind of miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph.
The purpose of the present invention is achieved through the following technical solutions:
The miniature ultraviolet-visible of the one/Infrared Non-destructive Testing spectrogrph of the present invention (includes reflective and transmission-type two kind Type), it is characterized in that including light source, photoelectric sensor, Circuits System, shell and power supply.
Described light source, is characterized in that including pin, base, aluminium base, one chip microcomputer circuit, LED array, light conductor And light conducting cylinder.Described pin, it is characterized in that including two-way power voltage supply pin, publicly pin, data transmission pin and with Walking clock pins, two-way power voltage supply pin powers to respectively one chip microcomputer circuit and LED array, and data transmission pin performs I2C communication between one chip microcomputer circuit and single chip machine controlling circuit.Described one chip microcomputer circuit, is characterized in that including One chip microcomputer, 0402 encapsulation Chip-R and electric capacity, for the control of LED array sequence of light.Described LED array, its Feature is to include one or more LED, and described LED can be Single wavelength LED or multi-wavelength LED lamp, and wavelength is at purple In outward-visible spectrum and infrared range of spectrum.
Described photoelectric sensor, is characterized in that ultraviolet-visible/infrasil photodiode, and its spectrum acquisition scope is relatively Width, can read the intensity of ultraviolet-visible/infrared light.
Described Circuits System, is characterized in that including that single chip machine controlling circuit, power amplifier, signal amplify and filter circuit And data transmission circuit.Wherein, the core parts of single chip machine controlling circuit are nRF51822 singlechip chips, it is characterized in that bag Include general purpose I/O Interface (GPIO), I2C communication interface, analog-digital converter (ADC), bluetooth module.Single chip machine controlling circuit leads to Cross GPIO controlling power amplifier is light source of short duration power supply of a length of 20s when carrying out, and controls the miniature of light source by I2C communication interface Single chip circuit and the sequence of light of LED array, by ADC read voltage signal, and be converted into absorbance or reflectance Data, carry out wireless data transmission by bluetooth module.The core parts of power amplifier are paster power amplification audions, mainly For light source power supply.Signal amplifies and filter circuit includes using the signal amplification circuit of integrated operational amplifier structure, low pass filtered Wave circuit and 50Hz trap circuit, the voltage signal recorded mainly for the treatment of photoelectric sensor.Wherein, signal amplification circuit pair The small-signal that photoelectric sensor records is amplified, and low-pass filter circuit filters the High-frequency Interference of doping in signal, and 50Hz falls into Wave circuit is for filtering the Hz noise in signal.Data transmission circuit uses USB communication or serial communication, can pass through data wire Upload surveyed data.
Described shell, is characterized in that with light source slot, outlet, communication socket and the cylinder of sealing coat.Light Source slot is for light source power supply, and outlet has duplex feeding positive pole and public negative pole, for ultraviolet-visible/infrared nothing Damaging detection spectrogrph to power, data transmission socket is for transmitting measured absorbance or reflectivity data, and sealing coat is mainly used Shield the external environment condition electromagnetic interference to Circuits System.
Described power supply is DC source, can be specifically lithium battery, silver oxide cell or alkaline manganese battery.
It is special that the miniature ultraviolet-visible of the one/Infrared Non-destructive Testing spectrogrph of the present invention may be used for measuring one or more Set the goal the ultraviolet-visible/infrared transmission of material or reflection absorption spectrum, and then is applied to chemical industry, water quality, food, geology, oil The fields such as paint, coating, metal, space flight, automobile and historical relic.
The miniature ultraviolet-visible of one of the present invention/Infrared Non-destructive Testing spectrogrph uses Micrometer-Nanometer Processing Technology, and light source is not with The polychromatic light light source of the LED array replacement conventional spectrometers of the LED composition of co-wavelength and complicated light splitting optical path, employing ultraviolet- Visible/infrasil photodiode replaces CCD photosensor arrays.Spectrogrph machine volume is little, lightweight, with low cost, It is suitable for Site Detection, it is simple to promote.The present invention, based on spectrum detection technique, utilizes the measured matter surface monochrome to different wave length The absorbance of light or the difference of reflectance judge the kind of material, and light source controls in LED array not by one chip microcomputer The LED of co-wavelength is the most luminous, and when measuring, photoelectric sensor reading is specific wavelength monochromatic light exposure measured object table every time , there is not spectra overlapping phenomenon, therefore spectral resolution be ideal in face produced reflection light or transmission light.Simultaneously as do not have There is the light splitting optical path that design is complicated, therefore the anti-interference of system and stability are preferable.
Accompanying drawing explanation
Fig. 1 is the knot of the miniature ultraviolet-visible of the reflective multi-wavelength/Infrared Non-destructive Testing spectrogrph of the embodiment of the present invention 1 Structure schematic diagram.
Fig. 2 is the knot of the miniature ultraviolet-visible of the transmission-type multi-wavelength/Infrared Non-destructive Testing spectrogrph of the embodiment of the present invention 3 Structure schematic diagram.
Fig. 3 is the functional structure signal of the miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph of embodiment of the present invention 1-3 Figure.
Fig. 4 is the workflow diagram of the miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph of embodiment of the present invention 1-3.
Fig. 5 is that the structure of the light source of the miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph of embodiment of the present invention 1-3 is shown It is intended to.
Fig. 6 is the profile of the LED array of the miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph of embodiment of the present invention 1-3 Schematic diagram.
Fig. 7 is the light source socket signal of the miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph of embodiment of the present invention 1-3 Figure.
Fig. 8 is the miniature ultraviolet-visible of the reflective multi-wavelength/Infrared Non-destructive Testing spectrophotometer of the embodiment of the present invention 1 The reflection-absorption curve of omethoate.
Fig. 9 is the miniature ultraviolet-visible of the transmission-type multi-wavelength/Infrared Non-destructive Testing spectrophotometer of the embodiment of the present invention 3 Longevity all mineral spring edible natural water and the absorption curve of tap water.
Reference: 1 shell 2 detects mouth 3 light source 4 photoelectric sensor 5 signal and amplifies and filter circuit 6 single-chip microcomputer Control circuit 7 data transmission circuit 8 power amplifier 9 power supply
Detailed description of the invention
Below by embodiment, the invention will be further described, and its purpose is only that and is better understood from present disclosure Rather than limit the scope of the invention:
The miniature ultraviolet-visible of the reflective multi-wavelength of embodiment 1/Infrared Non-destructive Testing spectrogrph
Light source 3, photoelectric sensor 4, Circuits System and the electricity of a kind of miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph Source 9 is installed in shell 1 (see Fig. 1,3-4).Light source 3, irradiation central point and photoelectric sensor 4 are in the same plane, light The angle gone out between light light path, the detection path of photoelectric sensor 4 and the normal of irradiation central point in source 3 is equal, it is ensured that reflection Light enters photoelectric sensor 4 to greatest extent.
Light source 3 includes that pin, base, aluminium base, one chip microcomputer circuit, LED array, light conductor and light conducting cylinder are (see figure 5).Pin includes two-way power voltage supply pin, publicly pin, data transmission pin and synchronised clock pin, and two-way voltage supplies Fulgurite foot powers to respectively one chip microcomputer circuit and LED array, and data transmission pin performs one chip microcomputer circuit and monolithic I2C communication between machine control circuit 6.Pin is connected on the left side of base, is inserted in ultraviolet-visible/Infrared Non-destructive Testing In the special pedestal of spectrogrph, power voltage supply pin and data transfer tube foot are connected to one by solder joint by base and aluminium base Rise.One chip microcomputer circuit includes one chip microcomputer, 0402 encapsulation Chip-R and electric capacity, and they are all welded on aluminium base, Control for LED array sequence of light.LED array includes 49 multi-wavelength LED lamps (see Fig. 6), and wavelength is all at ultraviolet-visible In spectrum and infrared range of spectrum, 0402 encapsulation Chip-R and the LED array that its supply voltage is drawn by one chip microcomputer The bleeder circuit constituted regulates.One chip microcomputer system model is the STM8S003 single-chip microcomputer of UFQFPN20 encapsulation, and its size is only It is 3 × 3mm2, cost is relatively low.The end of light conductor is convex surface, has light-focusing function, and light sends and be radiated at detected through light conductor Thing surface.The inner surface of light conducting cylinder is minute surface, is used for fixing light conductor and aluminium base, also can play optically focused effect.
Photoelectric sensor 4 is ultraviolet-visible/infrasil photodiode, and its spectrum acquisition wider range can read purple The intensity of outward-visible/infrared light.
Circuits System includes the amplification of single chip machine controlling circuit 6, power amplifier 8, signal and filter circuit 5 and data transmission Circuit 7.Wherein, the core parts of single chip machine controlling circuit 6 are nRF51822 singlechip chips, including general purpose I/O Interface (GPIO), I2C communication interface, analog-digital converter (ADC), bluetooth communication module.Single chip machine controlling circuit 6 is controlled by GPIO Power amplifier 8 processed is light source 3 of short duration power supply of a length of 20s when carrying out, and is controlled the minitype single-chip of light source 3 by I2C communication interface Dynamo-electric road and the sequence of light of LED array, by ADC read voltage signal, and be converted into reflectivity data, pass through bluetooth Module carries out wireless data transmission.The core parts of power amplifier 8 are that paster power amplification audion, predominantly light source 3 are powered. Signal amplify and filter circuit 5 include use integrated operational amplifier build signal amplification circuit, low-pass filter circuit and 50Hz trap circuit, the voltage signal recorded mainly for the treatment of photoelectric sensor 4.Wherein, signal amplification circuit is to photoelectric transfer The small-signal that sensor 4 records is amplified, and low-pass filter circuit filters the High-frequency Interference of doping, 50Hz trap circuit in signal For filtering the Hz noise in signal.Data transmission circuit 7 uses USB communication, can upload surveyed data by data wire.
Shell 1 is the black cylinder (see Fig. 7) with light source slot, outlet, communication socket and sealing coat.Light source Slot is for powering to light source 3, and outlet has duplex feeding positive pole and public negative pole, for ultraviolet-visible/infrared nondestructive Detection spectrogrph is powered, and data transmission socket is for transmitting measured spectroscopic data, and sealing coat is mainly used to shield external rings The border electromagnetic interference to Circuits System.
Power supply 9 is lithium battery.
Tested substance is placed in the position of detection mouth 2, and the detection light that light source 3 sends irradiates in place in detecting the tested of mouth 2 On material surface, the light intensity after the reflection-absorption of measured matter surface is received by photoelectric sensor 4 and is converted into voltage signal. Voltage signal amplifies and after filter circuit 5 filtering interfering through signal, by the core parts of single chip machine controlling circuit 6 The ADC of nRF51822 singlechip chip reads and is converted to measured matter surface reflectivity information.Reflectivity information can be by single The bluetooth communication module of sheet machine control circuit 6 core parts nRF51822 singlechip chip is to mobile phone uploading detection data. Described light source 3 is controlled power supply by single chip machine controlling circuit 6 by power amplifier 8.Signal amplifies and filter circuit 5, single-chip microcomputer Control circuit 6, data transmission circuit 7, power amplifier 8 are all powered by power supply 9.
Embodiment 2 reflective dual wavelength miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph
Light source 3, photoelectric sensor 4, Circuits System and the electricity of a kind of miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph Source 9 is installed in shell 1 (see Fig. 3-4).Light source 3, irradiation central point and photoelectric sensor 4 are in the same plane, light source 3 Go out light light path, photoelectric sensor 4 detection path and irradiate central point normal between angle equal, it is ensured that reflection light Enter photoelectric sensor 4 to greatest extent.
Light source 3 includes that pin, base, aluminium base, one chip microcomputer circuit, LED array, light conductor and light conducting cylinder are (see figure 5).Pin includes two-way power voltage supply pin, publicly pin, data transmission pin and synchronised clock pin, and two-way voltage supplies Fulgurite foot powers to respectively one chip microcomputer circuit and LED array, and data transmission pin performs one chip microcomputer circuit and monolithic I2C communication between machine control circuit 6.Pin is connected on the left side of base, is inserted in ultraviolet-visible/Infrared Non-destructive Testing In the special pedestal of spectrogrph, power voltage supply pin and data transfer tube foot are connected to one by solder joint by base and aluminium base Rise.One chip microcomputer circuit includes one chip microcomputer, 0402 encapsulation Chip-R and electric capacity, and they are all welded on aluminium base, Control for LED array sequence of light.LED array includes 2 Single wavelength LED (see Fig. 6), and wavelength is all at ultraviolet-visible In spectrum and infrared range of spectrum, 0402 encapsulation Chip-R and the LED array that its supply voltage is drawn by one chip microcomputer The bleeder circuit constituted regulates.One chip microcomputer system model is the STM8S003 single-chip microcomputer of UFQFPN20 encapsulation, and its size is only It is 3 × 3mm2, cost is relatively low.The end of light conductor is convex surface, has light-focusing function, and light sends and be radiated at detected through light conductor Thing surface.The inner surface of light conducting cylinder is minute surface, is used for fixing light conductor and aluminium base, also can play optically focused effect.
Photoelectric sensor 4 is ultraviolet-visible/infrasil photodiode, and its spectrum acquisition wider range can read purple The intensity of outward-visible/infrared light.
Circuits System includes the amplification of single chip machine controlling circuit 6, power amplifier 8, signal and filter circuit 5 and data transmission Circuit 7.Wherein, the core parts of single chip machine controlling circuit 6 are nRF51822 singlechip chips, including general purpose I/O Interface (GPIO), I2C communication interface, analog-digital converter (ADC), bluetooth communication module.Single chip machine controlling circuit 6 is controlled by GPIO Power amplifier 8 processed is light source 3 of short duration power supply of a length of 20s when carrying out, and is controlled the minitype single-chip of light source 3 by I2C communication interface Dynamo-electric road and the sequence of light of LED array, by ADC read voltage signal, and be converted into reflectivity data, pass through bluetooth Module carries out wireless data transmission.The core parts of power amplifier 8 are that paster power amplification audion, predominantly light source 3 are powered. Signal amplify and filter circuit 5 include use integrated operational amplifier build signal amplification circuit, low-pass filter circuit and 50Hz trap circuit, the voltage signal recorded mainly for the treatment of photoelectric sensor 4.Wherein, signal amplification circuit is to photoelectric transfer The small-signal that sensor 4 records is amplified, and low-pass filter circuit filters the High-frequency Interference of doping, 50Hz trap circuit in signal For filtering the Hz noise in signal.Data transmission circuit 7 uses serial communication, can upload surveyed data by data wire.
Shell 1 is the black cylinder (see Fig. 7) with light source slot, outlet, communication socket and sealing coat.Light source Slot is for powering to light source 3, and outlet has duplex feeding positive pole and public negative pole, for ultraviolet-visible/infrared nondestructive Detection spectrogrph is powered, and data transmission socket is for transmitting measured spectroscopic data, and sealing coat is mainly used to shield external rings The border electromagnetic interference to Circuits System.
Power supply 9 is silver oxide cell.
Tested substance is placed in the position of detection mouth 2, and the detection light that light source 3 sends irradiates in place in detecting the tested of mouth 2 On material surface, the light intensity after the reflection-absorption of measured matter surface is received by photoelectric sensor 4 and is converted into voltage signal. Voltage signal amplifies and after filter circuit 5 filtering interfering through signal, by the core parts of single chip machine controlling circuit 6 The ADC of nRF51822 singlechip chip reads and is converted to measured matter surface reflectivity information.Reflectivity information can be by number According to transmission circuit 7 to panel computer uploading detection data.Described light source 3 is controlled by power amplifier 8 by single chip machine controlling circuit 6 System power supply.Signal amplifies and filter circuit 5, single chip machine controlling circuit 6, data transmission circuit 7, power amplifier 8 are all by power supply 9 It is powered.
The miniature ultraviolet-visible of embodiment 3 transmission-type multi-wavelength/Infrared Non-destructive Testing spectrogrph
Light source 3, photoelectric sensor 4, Circuits System and the electricity of a kind of miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph Source 9 is installed in shell 1 (see Fig. 2-4).Light source 3, irradiation central point and photoelectric sensor 4 are in the same plane, light source 3 Go out light light path, the detection path of photoelectric sensor 4 and irradiate central spot on same straight line, it is ensured that transmitted ray maximum limit The entrance photoelectric sensor 4 of degree.
Light source 3 includes that pin, base, aluminium base, one chip microcomputer circuit, LED array, light conductor and light conducting cylinder are (see figure 5).Pin includes two-way power voltage supply pin, publicly pin, data transmission pin and synchronised clock pin, and two-way voltage supplies Fulgurite foot powers to respectively one chip microcomputer circuit and LED array, and data transmission pin performs one chip microcomputer circuit and monolithic I2C communication between machine control circuit 6.Pin is connected on the left side of base, is inserted in ultraviolet-visible/Infrared Non-destructive Testing In the special pedestal of spectrogrph, power voltage supply pin and data transfer tube foot are connected to one by solder joint by base and aluminium base Rise.One chip microcomputer circuit includes one chip microcomputer, 0402 encapsulation Chip-R and electric capacity, and they are all welded on aluminium base, Control for LED array sequence of light.LED array includes 24 Single wavelength LED and 25 multi-wavelength LED lamps (see Fig. 6), Wavelength all in ultraviolet-visible spectrum and infrared range of spectrum, its supply voltage by one chip microcomputer draw 0402 encapsulation The bleeder circuit that Chip-R and LED array are constituted regulates.One chip microcomputer system model is UFQFPN20 encapsulation STM8S003 single-chip microcomputer, its size is only 3 × 3mm2, cost is relatively low.The end of light conductor is convex surface, has light-focusing function, light warp Light conductor sends and is radiated at detected material surface.The inner surface of light conducting cylinder is minute surface, is used for fixing light conductor and aluminium base, also Optically focused effect can be played.
Photoelectric sensor 4 is for ultraviolet-visible/infrasil photodiode, its spectrum acquisition wider range, can read The intensity of ultraviolet-visible/infrared light.
Circuits System includes the amplification of single chip machine controlling circuit 6, power amplifier 8, signal and filter circuit 5 and data transmission Circuit 7.Wherein, the core parts of single chip machine controlling circuit 6 are nRF51822 singlechip chips, including general purpose I/O Interface (GPIO), I2C communication interface, analog-digital converter (ADC), bluetooth communication module.Single chip machine controlling circuit 6 is controlled by GPIO Power amplifier 8 processed is light source 3 of short duration power supply of a length of 20s when carrying out, and is controlled the minitype single-chip of light source 3 by I2C communication interface Dynamo-electric road and the sequence of light of LED array, by ADC read voltage signal, and be converted into transmisivity data, pass through bluetooth Module carries out wireless data transmission.The core parts of power amplifier 8 are that paster power amplification audion, predominantly light source 3 are powered. Signal amplify and filter circuit 5 include use integrated operational amplifier build signal amplification circuit, low-pass filter circuit and 50Hz trap circuit, the voltage signal recorded mainly for the treatment of photoelectric sensor 4.Wherein, signal amplification circuit is to photoelectric transfer The small-signal that sensor 4 records is amplified, and low-pass filter circuit filters the High-frequency Interference of doping, 50Hz trap circuit in signal For filtering the Hz noise in signal.Data transmission circuit 7 uses USB communication, can upload surveyed data by data wire.
Shell 1 is the black cylinder (see Fig. 7) with light source slot, outlet, communication socket and sealing coat.Light source Slot is for powering to light source 3, and outlet has duplex feeding positive pole and public negative pole, for ultraviolet-visible/infrared nondestructive Detection spectrogrph is powered, and data transmission socket is for transmitting measured spectroscopic data, and sealing coat is mainly used to shield external rings The border electromagnetic interference to Circuits System.
Power supply 9 is alkaline manganese battery.
Tested substance is placed in the position of detection mouth 2, and the detection light that light source 3 sends irradiates in place in detecting the tested of mouth 2 On material surface, the light intensity after measured matter absorbs is received by photoelectric sensor 4 and is converted into voltage signal.Voltage signal Amplify and after filter circuit 5 filtering interfering through signal, by the core parts nRF51822 single-chip microcomputer of single chip machine controlling circuit 6 The ADC of chip reads and is converted to measured matter absorbance information.Absorbance information can be by data transmission circuit 7 on PC Pass detection data.Described light source 3 is controlled power supply by single chip machine controlling circuit 6 by power amplifier 8.Signal amplifies and filtered electrical Road 5, single chip machine controlling circuit 6, data transmission circuit 7, power amplifier 8 are all powered by power supply 9.
The mensuration of embodiment 4 pesticide residues
For pesticide omethoate, use the miniature ultraviolet-visible/Infrared Non-destructive Testing of reflective multi-wavelength of embodiment 1 The reflection-absorption curve (see Fig. 8) of spectrophotometer omethoate, as seen from the figure, 435nm and 765nm is the reflection of omethoate Characteristic absorption peak, omethoate is compared reflection-absorption rate and be there is significantly change with pure water.
The mensuration of embodiment 5 pesticide residues
For pesticide omethoate, use the reflective dual wavelength miniature ultraviolet-visible/Infrared Non-destructive Testing of embodiment 2 The reflection-absorption rate (being shown in Table 1) of spectrophotometer variable concentrations omethoate, as seen from table, omethoate compares reflection with pure water There is significantly change in absorbance.Use 435nm and 765nm dual-wavelength LEDs lamp light source detect, lowest detectable limit up to To a ten million/concentration rank.
The reflection-absorption rate of table 1 variable concentrations omethoate
The analysis of embodiment 6 liquid
For longevity all mineral spring edible natural water (Ba Mahuoquan food and drink company) and the liquid analysis of tap water, adopt With the absorption curve of the miniature ultraviolet-visible of the transmission-type multi-wavelength of embodiment 3/Infrared Non-destructive Testing spectrophotometer water (see figure 9), as seen from the figure, longevity all mineral spring edible natural water compares absorbance with tap water and there is significant change.

Claims (5)

1. miniature ultraviolet-visible/Infrared Non-destructive Testing spectrogrph (including reflective and transmission-type two types), its feature It is to include light source, photoelectric sensor, Circuits System, shell and power supply;Described light source, is characterized in that including pin, base, aluminum Substrate, one chip microcomputer circuit, LED array, light conductor and light conducting cylinder;Described photoelectric sensor, is characterized in that ultraviolet-can See/infrasil photodiode, its spectrum acquisition wider range, can read the intensity of ultraviolet-visible/infrared light;Described Circuits System, is characterized in that including the amplification of single chip machine controlling circuit, power amplifier, signal and filter circuit and data transmission electricity Road;Described shell, is characterized in that with light source slot, outlet, communication socket and the cylinder of sealing coat;Described electricity Source is DC source, can be specifically lithium battery, silver oxide cell or alkaline manganese battery.
The miniature ultraviolet-visible of one the most according to claim 1/Infrared Non-destructive Testing spectrogrph, is characterized in that described Pin, is characterized in that including two-way power voltage supply pin, publicly pin, data transmission pin and synchronised clock pin, two-way Power voltage supply pin powers to respectively one chip microcomputer circuit and LED array, and data transmission pin performs one chip microcomputer circuit And the I2C communication between single chip machine controlling circuit;Described one chip microcomputer circuit, it is characterized in that including one chip microcomputer, 0402 encapsulation Chip-R and electric capacity, for the control of LED array sequence of light;Described LED array, is characterized in that including one Individual or multiple LED, described LED can be Single wavelength LED or multi-wavelength LED lamp, wavelength at ultraviolet-visible spectrum and In infrared range of spectrum.
The miniature ultraviolet-visible of one the most according to claim 1/Infrared Non-destructive Testing spectrogrph, is characterized in that described The core parts of single chip machine controlling circuit are nRF51822 singlechip chips, connect including general purpose I/O Interface (GPIO), I2C communication Mouth, analog-digital converter (ADC), bluetooth module, it is that light source is carried out that single chip machine controlling circuit controls power amplifier by GPIO The of short duration power supply of Shi Changwei 20s, suitable by the one chip microcomputer circuit of I2C communication interface control light source and the luminescence of LED array Sequence, by ADC read voltage signal, and is converted into absorbance or reflectivity data, carries out wireless number by bluetooth module According to transmission;The core parts of described power amplifier are paster power amplification audions, predominantly light source power supply;Described signal Amplify and filter circuit includes signal amplification circuit, low-pass filter circuit and the 50Hz trap that employing integrated operational amplifier builds Circuit, the voltage signal recorded mainly for the treatment of photoelectric sensor, it is faint that photoelectric sensor is recorded by signal amplification circuit Signal is amplified, and low-pass filter circuit filters the High-frequency Interference of doping in signal, and 50Hz trap circuit is used for filtering in signal Hz noise;Data transmission circuit uses USB communication or serial communication, can upload surveyed data by data wire.
The miniature ultraviolet-visible of one the most according to claim 1/Infrared Non-destructive Testing spectrogrph, is characterized in that described Light source slot is for light source power supply, and described outlet has duplex feeding positive pole and public negative pole, for ultraviolet-can See/Infrared Non-destructive Testing spectrogrph powers, described data transmission socket is for transmitting measured absorbance or reflectance number According to, described sealing coat is mainly used to shield the external environment condition electromagnetic interference to Circuits System.
The miniature ultraviolet-visible of one the most according to claim 1/Infrared Non-destructive Testing spectrogrph is measuring one or more Ultraviolet-visible/the infrared transmission of specific objective material or the application of reflection absorption spectrum.
CN201610387106.0A 2016-06-01 2016-06-01 A kind of miniature UV, visible light/Infrared Non-destructive Testing spectrogrph Pending CN106092918A (en)

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Application publication date: 20161109