CN106087631A - A kind of sintering brick permeable to water and preparation method thereof - Google Patents

A kind of sintering brick permeable to water and preparation method thereof Download PDF

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Publication number
CN106087631A
CN106087631A CN201610380111.9A CN201610380111A CN106087631A CN 106087631 A CN106087631 A CN 106087631A CN 201610380111 A CN201610380111 A CN 201610380111A CN 106087631 A CN106087631 A CN 106087631A
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surface layer
blank
water
pug
temperature
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CN106087631B (en
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樊传刚
常治铁
张飞
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Sichuan Green Island Environmental Engineering Co., Ltd.
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樊传刚
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    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/04Pavings made of prefabricated single units made of bricks
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • C04B38/0675Vegetable refuse; Cellulosic materials, e.g. wood chips, cork, peat, paper
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • C04B38/068Carbonaceous materials, e.g. coal, carbon, graphite, hydrocarbons
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/22Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
    • E01C11/224Surface drainage of streets
    • E01C11/225Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

Open a kind of sintering brick permeable to water of the present invention and preparation method thereof, belongs to sintering ceramic technology field.This water-permeable brick forms and proportioning is: in surface layer, composition and the percentage by weight of structure pug are: structure fine aggregate: 45~65%;Plasticity high-temperature agglomerant: 20~30%;Water: 15~25%;In surface layer, composition and the percentage by weight of pore-forming pug are: pore former aggregate: 20 50%;Plasticity increases hole binding agent 45 80%;Biomass fuel internal combustion catalyst: 0 5%;Composition and the percentage by weight of secondary surface layer blank be: coarse-texture aggregate: 70~75%;Plasticity high-temperature agglomerant: 10~15%;Pore forming agent coarse aggregate: 0~5%;Water: 10~15%.First surface layer and secondary surface layer blank are prepared, the structure pug containing ordered distribution and pore-forming pug in surface layer blank, then carry out single shaft extrusion forming, be dried and burn till this water-permeable brick prepared.Water-permeable brick of the present invention has high permeability rate, high intensity and high abrasion and durability, is a kind of to have the preferably ecological and paving material of environmental protection function.

Description

A kind of sintering brick permeable to water and preparation method thereof
Technical field:
The invention belongs to sinter ceramic technology field, particularly to a kind of sintering brick permeable to water and preparation method thereof, this sintering Water-permeable brick is particularly well-suited to need to leak rapidly the square of rainwater, road two is close to and the paving of the public place drainage system such as stadium Face, and it is applicable to the permeable supporting layer of artificial swamp.
Background technology:
At present, when building the public places such as station, square, sports ground, road, it is necessary to rapid in view of to rainwater The row's of letting out problem, thus below square, road two is close to and is all designed with drainage system, such as gutter etc..On these gutter covers It is typically all and lays the Concrete brick with bakie, or every one section of longer distance on closely knit Concrete brick paving Just build upper block floor drain, be used for draining hydrops.Owing to some rubbish all can be accumulated in road, square at ordinary times, add when heavy rain is near, companion With strong wind by many deadwoods, lose leaf and blow off to road, square, these residual branches are lost leaf by rainwater, rubbish rushes to drainage outlet also It is frequently occluded scupper, causes low-lying place hydrops serious, it is impossible to the row of letting out.Additionally scupper before blocking existing a large amount of rubbish, Residual leaves etc. enter gutter from scupper, and in the course of time, can result in blockage gutter, has seriously undermined the draining merit of drainage system Energy.
Summary of the invention:
The present invention is directed to the above-mentioned technical problem that existing drainage system exists, it is provided that a kind of high permeability rate, anti-blocking, durable With wear-resisting sintering brick permeable to water and preparation method thereof.
Sintering brick permeable to water provided by the present invention is made up of two-layer pervious bed, and surface layer is that 2~10mm thickness of anti-blocking are permeable Layer is constituted, and secondary surface layer is the pervious bed composition of big flux, high intensity;The permeable aperture of surface layer is 0.05~about 0.2mm;Secondary face The permeable aperture of layer is 0.5~2mm;Surface layer and time surface layer by following match ratio, are processed into the surface layer granule of densification respectively respectively With secondary surface layer blank, then cloth, extrusion forming and make the sintering brick permeable to water of the present invention after burning till the most in a mold.As this The special case of invention, surface material can also be separately formed and be fired into water-permeable brick or plate.
The present invention provides the composition of sintering brick permeable to water and proportioning specific as follows:
(1) in surface layer graininess blank, composition and the mass percent of structure pug are:
Structure fine aggregate: 45~65%;Plasticity high-temperature agglomerant: 20~30%;Water: 15~25%.
(2) in surface layer graininess blank, composition and the mass percent of pore-forming pug are:
Pore former aggregate: 20-50%;Plasticity increases hole binding agent 45-80%;Combustion catalyst in biomass fuel: 0- 5%.
Described structure fine aggregate is the thick slag of flyash, slag, water-granulated slag, granulated copper slag, nickel slag, calcined kaolin, coal Spoil, quartz, calcined bauxite, ripe clay, gangue, scrap glass, waste old ceramics powder, discarded sintering wall brick and discarded sa are resistance to Any one in firebrick or the wantonly broken powder granule obtained of two kinds of things mixed above warp, the particle diameter of described powder granule is less than 0.2mm and all processing through high-temperature stableization, i.e. cools down or discards high temperature sintering material through broken from high-temperature fusant or sintered body Obtain.
Described plasticity high-temperature agglomerant is loam, Kaolin, clayey raw material, bentonite, kieselguhr, montmorillonite, clay Any one in raw material or the mixture of wantonly more than two kinds, clayey raw material includes iron tailings mud, dig up mine and quarry in stripping Digging dregs from soil, Geotechnical Engineering dregs, subway and tunnel drill, the grain graininess of described plasticity high-temperature agglomerant is less than 200 mesh.
Described pore former aggregate be powder of straw, powdered rice hulls, leaf powder, wood flour, charcoal powder, coal dust, coke blacking, molding powder and Any one in shredded paper bits or the broken powder granule obtained of mixture warp of wantonly more than two kinds, the particle diameter of described powder granule is little In 0.2mm;Coal dust is preferably brown coal and mud coal.
Described plasticity increases hole binding agent and is city water treatment sludge, cattle manure, makes compost appointing in methane slag, dredged mud, mud A kind of or the mixture of wantonly more than two kinds, described plasticity increases in the solid content of hole binding agent containing a large amount of organic principles;Mud contains Water rate is higher, reaches 50~90%.
Described biomass fuel internal combustion catalyst be nickeliferous or in the compound of ferrum, dolomite and limestone any one or The mixture of wantonly more than two kinds is through the broken granule obtained, and described grain graininess is not more than 10 microns.
(3) composition and the mass percent of secondary surface layer blank is:
Coarse-texture aggregate: 70~75%;Plasticity high-temperature agglomerant: 10~15%;Pore forming agent coarse aggregate: 0~5%;Water: 10 ~15%.
Coarse-texture aggregate in described surface layer blank is the thick slag of flyash, blast furnace slag, ageing slag, steam coal Slag, granulated copper slag, nickel slag, cullet slag, discarded clay brick, waste ceramic brick, discarded domestic ceramics, discarded sa are fire-resistant Any one in brick, Kaolin, gangue, quartz, calcined bauxite and ripe clay or the mixing of wantonly more than two kinds, preferably flyash Any one in thick slag, blast furnace slag and Boiler Cinder Surveying or the mixing of wantonly more than two kinds, the acidity of described coarse-texture aggregate Coefficient is not less than 0.9, and granularity is 1~6mm, and preferred size is 2~5mm.
Plasticity high-temperature agglomerant in described surface layer blank is loam, Kaolin, clayey raw material, bentonite, diatom A kind of or the mixing of wantonly more than two kinds in soil, montmorillonite, gangue, clayey raw material includes iron tailings mud, dig up mine and quarry Stripping soil, Geotechnical Engineering dregs, subway and tunnel drill dig dregs, grain graininess be less than 200 mesh.
Pore forming agent coarse aggregate in described surface layer blank is in straw, rice husk, leaves, wood flour, Linesless charcoal, coal, coke The mixture of any one or wantonly more than two kinds through the broken granule obtained, grain graininess 0.5~1.5mm.
The preparation method of sintering brick permeable to water provided by the present invention specifically comprises the following steps that
(1) surface layer graininess blank is prepared:
After structure pug component in surface layer graininess blank being mixed, pugging obtains A pug;By the one-tenth in pore-forming pug Hole agent aggregate is prewetted, and then pugging after pore-forming pug component mixing in surface layer graininess blank is obtained B pug;After pugging The A pug with close or equal plasticity index becomes 1~5mm thick A mud cake and B mud cake with the pressure rolling respectively of B pug, then by A, B Mud cake makes the double pug component thickness mud cake of AB, then pug component thickness mud double to described AB according to ABA lamellar composite stacked system Cake carries out pressure rolling, forms the overall mud cake of thickness 2~4mm, described overall mud cake is finally divided into the little mud fourth of 2~4mm, from And complete the pelletize of surface layer graininess blank, then it is dried and sloughs unnecessary moisture, it is thus achieved that surface layer graininess blank.
Surface layer graininess blank has A, B pug composition and each thickness equal, between A, B pug composition being etc. Every distribution, surface layer graininess blank shape is cylindrical, spherical or square column type.The outermost of described surface layer graininess blank is all the time There are structure pug layer, i.e. A pug layer.
For improving the wearability of surface layer, water penetration and anti-blocking performance, above-mentioned pugging process optimum is vacuum pugging, A, B Mud cake be superimposed pressure rolling become the overall mud cake of 2~4mm after segmentation granulation process only apply shear action, in granulation structure Maintain the constant microcell composition of A, B pug of overall mud cake.Additionally it is in the permeable voidage to surface layer, wearability, anti-blocking The consideration that the performance synthesis such as performance, freeze-thaw resistance optimizes, the pelletize mud cake that A, B mud cake is superimposed as is not limited merely to ABA Three layers of combination, other combinations such as other forms such as ABABA, ABAABAABA combination, the technical scope also emphasized in the present invention In, the common trait of combinations thereof is that the outermost of granule has structure pug layer, i.e. A pug layer all the time.
(2) preparation time surface layer blank:
First the coarse-texture aggregate in secondary surface layer blank is prewetted, then the plasticity high-temperature agglomerant in secondary surface layer blank is added Enter stirring, after coarse-texture aggregate surface is by one layer of plasticity high-temperature agglomerant of tight, then by the increasing hole in secondary surface layer blank Agent coarse aggregate adds, and time surface layer blank, the water content≤15wt% of described surface layer blank are made in stirring.
(3) molding, be dried and burn till:
(A) molding: pave after first secondary surface layer blank being added mould, then surface layer graininess blank is added time surface layer face On material and pave, carrying out single shaft extrusion forming the most on a hydraulic press, briquetting pressure is 5~30MPa, becomes adobe after the demoulding.
(B) it is dried: described adobe is dried in baking oven or dry kiln, is dried maximum temperature and is less than 200 DEG C, make base In body, moisture content is less than 5wt%.
(C) burn till: dried adobe is burnt till in kiln, wherein 200~500 DEG C of temperature ranges, heat up Speed 0.5 DEG C~1 DEG C/min;500~900 DEG C of temperature ranges, programming rate 0.5 DEG C~1.5 DEG C/min, at 900 DEG C~ The temperature range of high firing temperature, programming rate 1 DEG C~2 DEG C/min, maximum sintering temperature is 1050~1250 DEG C, in hyperpyrexia Becoming temperature 5~10h, then cool down, the speed that cools is not more than 5 DEG C/min, is cooled to room temperature and prepares described burning Knot water-permeable brick, the permeability rate 0.2~1cm/S of described sintering brick permeable to water, comprcssive strength is more than 30MPa, and rupture strength is more than 4MPa, Permeability rate life-time service does not reduces, and water-permeable brick can be used for urban pavement laying and the porous filtering supporting layer for artificial swamp.
Sintering brick permeable to water that the present invention proposes or plate and production method thereof, compare with prior art and have the advantage that
(1) high permeability rate.Surface layer permeable hole ordered distribution, tortuous is little, even aperture distribution, hair in filtration channel Pore amount is few, and water-permeable passage smooth surface, permeable resistance are little, makes the sintering brick permeable to water of the present invention or plate have high permeability rate, with Time surface layer also there is the anti-blocking function of grating type mesh structure.
(2) high intensity.The passage forming process of surface layer and time surface layer height permeability rate need not use existing sintering brick permeable to water In specific granule grating and by reduce sintering temperature means improve permeability rate, therefore the technical program can by increase Briquetting pressure and properly increase sintering temperature with improve water-permeable brick intensity, the water-permeable brick obtained or plate have than same material its His water-permeable brick or the much higher resistance to compression of plate and rupture strength.
(3) high abrasion and durability.The structure of surface layer blank forms pug and pore-forming pug after sequential combination is distributed Carrying out pelletize, the pug before pelletize have passed through extruding pugging process, and the particle packing in pug is fine and close, has in made granule Having position and the position of pore-forming component designing constant constituent, this granule is through high-pressure molding, and surface pressurized is maximum, makes Burn till rear pore former to burn the loose structure surface layer stayed there is high wearability and blockage resisting performance simultaneously, add that porous is made pottery Pore in porcelain structure is less, therefore has higher wearability, durability and permeable than existing sintering brick permeable to water or plate Service life.
(4) primary raw material of the present invention is the various solid waste through pyroprocess, and need not followed by continued powder Galling broken, approach is found in the low cost optimum utilization forming industrial solid castoff for high-temperature fusant after therefore cooling down, and makes simultaneously The cubical contraction that burns till of water-permeable brick or plate reduces, and the product qualified rate of sintered products improves.
(5) mud and biomass straw are as the pore former of the orderly pervious bed of high intensity, dispensing adds have make raw The catalyst component that the combustion process such as biomass fuel cracks, decomposes, oxidation are accelerated or the plasticity iron tailings mud containing catalyst component, The forming process of water-permeable passage in high temperature base substrate is made to promote the structural strength of porous ceramic bodies without negative effect.
(6) simultaneously, above-mentioned sintering brick permeable to water surface layer be by pelletize after surface layer granule form through high-pressure molding, surface layer Initial particle size is relatively big, and the matsurface making acquisition product surface be a kind of unartificial process has good skidproof effect.
(7) utilizing sintering brick permeable to water of the present invention or the high water-permeability of plate and high respiratory, sintering brick permeable to water has become as The ecological functional paving material with environmental protection mode of tool.If without soil or having soil (when having soil, native permeable with sintering organic media Between brick spread one layer of semi permeability non-woven fabrics) cultivation grass blanket plant above this sintering brick permeable to water, owing to this layer of water-permeable brick can remain good Good the earth water circulatory function, i.e. can be impregnated with rainwater rapidly during the rainy day in the earth, and during fine day, can be by the water of the earth Supply plant to use on part " suction ", maintain the ecological environment of a kind of organic circulation, both had a piece of glossy and green meadow, and gathered around again There is a piece of straightway drainage system, it is also possible to prevent fault sag, the core material of above-mentioned artificial swamp can be become.
Detailed description of the invention:
Embodiment 1: a kind of sintering brick permeable to water, at Boiler Cinder Surveying, the thick slag of flyash, iron tailings mud, powdered rice hulls, municipal water The dirty mud as a raw material of reason, is processed by formula as below.
One, formula
(1) surface layer structure pug formula (by weight percentage):
The thick slag of flyash 50%, iron tailings mud (moisture content 40%) 50% (being equivalent to dry iron tailings mud 30%, water 20%), In iron tailings mud, grain graininess is less than 200 mesh.
(2) surface layer pore-forming pug formula:
Powdered rice hulls 20%, granularity is less than 0.2mm, city water treatment sludge (moisture content 80%) 77.5%, agstone 2.5%, granularity is less than 10 μm.
(3) secondary surface layer blank formulation:
Boiler Cinder Surveying 70%, particle size range 2~5mm, iron tailings mud (moisture content 40%) 25% (is equivalent to dry iron tailings mud 15%, water 10%, in tailings mud, grain graininess is less than 200 mesh), powdered rice hulls 5%, granularity is less than 1.5mm.
Two, blank preparation process
(1) in surface layer blank prepared by structure pug:
By the thick slag of flyash needed for surface layer structure pug and iron tailings mud after premixing, feeding vacuum deairing machine enters Row pugging, becomes structure mud cake A thick for 1mm by the structure pug pressure rolling after pugging.
(2) in surface layer blank prepared by pore-forming pug:
Powdered rice hulls needed for pore-forming pug in surface layer blank and city water treatment sludge are carried out premixing, then by it Feeding vacuum deairing machine carries out pugging, then will obtain the pore-forming mud cake B that pore-forming pug pressure rolling becomes thick for 1mm after pugging.
(3) prepared by surface layer blank granule:
By the pore-forming mud cake B of structure mud cake A, being superimposed according to ABA, form surface layer mud cake, feeding plastic mud material is made Grain machine carries out pelletize, made grain graininess about 2.5mm, then sloughs the moisture in granule to being less than at 120 DEG C of insulation 5h 5%.
(4) prepared by secondary surface layer blank:
Iron tailings mud in secondary surface layer dispensing and Boiler Cinder Surveying the most quickly being stirred, tailings mud is wrapped in pot uniformly After stove cinder surface forms one layer of thin layer, then the powdered rice hulls increasing hole is admixed at a slow speed, after stirring 5 minutes, obtain time surface layer base Material.
Three, molding and burning till:
Secondary surface layer blank is uniformly fed in the mould of single shaft hydraulic press, and blank surface layer in mould is struck off, so After feed surface layer particulate material, wherein surface layer sotck thinkness 1cm in mould again, secondary surface thickness 9cm, the pressure using 10MPa will In mould, blank is pressed into the adobe that 8cm is thick, adobe is dried in dry kiln, is dried maximum temperature 180 DEG C, makes in base substrate Moisture content is less than 5wt%.Then dry complete adobe being put into tunnel cave to burn till, maximum sintering temperature is 1200 DEG C, Wherein 200~500 DEG C of temperature ranges, 0.5 DEG C/min of programming rate;500~900 DEG C of temperature ranges, programming rate 1 DEG C/ Min, at 900 DEG C~the temperature range of 1200 DEG C, 1.5 DEG C/min of programming rate, is incubated 10h maximum sintering temperature 1200 DEG C, Then cooling down, the speed that cools is not more than 5 DEG C/min, is cooled to room temperature and obtains comprcssive strength 35MPa, permeability rate The water-permeable brick of 0.5cm/s, wherein the aperture diameter of surface layer is less than 0.1mm, will not block after life-time service.
Embodiment 2: a kind of sintering brick permeable to water, with coarse granule blast furnace slag, fine grained blast furnace slag, ground work Journey dregs, powder of straw, silt mud as a raw material, processed by formula as below.
One, formula
(1) surface layer structure pug formula (by weight percentage):
Fine grained blast furnace slag 60%, granularity is less than 0.2mm, and (granularity of dregs is less than Geotechnical Engineering dregs 25% 200 mesh), water 15%.
(2) surface layer pore-forming pug formula:
Powder of straw 25%, granularity is less than 0.2mm;
Mud (moisture content 80%) 70%;
Dolomite dust 5%, granularity is less than 10 μm.
(3) secondary surface layer blank formulation:
Coarse granule blast furnace slag 75%, particle size range 2~5mm;
Geotechnical Engineering dregs 10%, the granularity of dregs is less than 200 mesh;
Powder of straw 5%, granularity is less than 1mm;
Water 10%.
Two, blank preparation process
(1) in surface layer blank prepared by structure pug:
Weigh the fine grained blast furnace slag needed for surface layer structure pug dispensing, Geotechnical Engineering dregs and water, through pre- After mixing, feeding vacuum deairing machine carries out pugging, and the structure pug pressure rolling after pugging becomes structure mud cake A thick for 2mm.
(2) in surface layer blank prepared by pore-forming pug:
Powder of straw needed for pore-forming pug dispensing in surface layer blank and mud are carried out premixing, is then fed true Empty pug mill carries out pugging, then will obtain the pore-forming mud cake B that pore-forming pug pressure rolling becomes thick for 2mm after pugging.
(3) prepared by surface layer blank granule:
By structure mud cake A and pore-forming mud cake B, it is superimposed according to ABA, forms surface layer mud cake, then become through pressure rolling The mud cake that 3mm is thick, feeding plastic mud material comminutor carries out pelletize, made grain graininess about 3mm, is then incubated 5h at 120 DEG C Slough the moisture in granule to less than 5%.
(4) prepared by secondary surface layer blank:
Weigh Geotechnical Engineering dregs, coarse granule blast furnace slag and the appropriate water in time surface layer dispensing, first carry out fast Speed stirring mixing, Geotechnical Engineering dregs is wrapped in coarse granule blast furnace slag surface uniformly and forms one layer of thin layer, the most again The powder of straw increasing hole is admixed at a slow speed, after stirring 2 minutes, it is thus achieved that secondary surface layer blank.
Three, molding and burning till:
Secondary surface layer blank is uniformly fed in the mould of single shaft hydraulic press, and in mould surface layer blank is struck off, Feed surface layer particulate material, wherein surface layer blank thickness 0.8cm in mould, secondary surface layer sotck thinkness 9.2cm the most again, use 20MPa Pressure blank in mould is pressed into the thick adobe of 7cm, adobe is dried in dry kiln, is dried maximum temperature 150 DEG C, Moisture content in base substrate is made to be less than 5wt%.Then dry complete adobe being put into tunnel cave to burn till, maximum sintering temperature is 1150 DEG C, wherein 200~500 DEG C of temperature ranges, 0.75 DEG C/min of programming rate;500~900 DEG C of temperature ranges, heat up 1 DEG C/min of speed, 900 DEG C~the temperature range of 1150 DEG C, 1.5 DEG C/min of programming rate, maximum sintering temperature 1150 DEG C Insulation 10h, then cools down, and the speed that cools is not more than 5 DEG C/min, is cooled to room temperature and obtains comprcssive strength 45MPa, thoroughly The water-permeable brick of water rate 0.7cm/s, wherein the aperture diameter of surface layer is less than 0.1mm, will not block after life-time service.
Embodiment 3: a kind of sintering brick permeable to water, smelts copper ashes, fine grained smelting copper ashes, dredged mud, coal dust, earth with coarse granule Soil, wood flour are raw material, process by formula as below.
One, formula
(1) surface layer structure pug formula (by weight percentage):
Fine grained copper smelting slag 50%, granularity is less than 0.2mm;
Loam 30%, granularity is less than 200 mesh;
Water 20%.
(2) surface layer pore-forming pug formula:
Coal dust 40%, granularity is less than 0.2mm;
Dredged mud (moisture content 70%) 60%.
(3) secondary surface layer blank formulation:
Coarse granule copper smelting slag 75%, particle size range 2~5mm;
Loam 12.5%, granularity is less than 200 mesh;
Wood flour 2.5%, particle size range 0.5~1.5mm;
Water 10%.
Two, blank preparation process
(1) in surface layer blank prepared by structure pug:
By fine grained copper smelting slag, loam and the water needed for surface layer structure pug dispensing after premixing, feed vacuum Pug mill carries out pugging, and the structure pug pressure rolling after pugging becomes structure mud cake A thick for 3mm.
(2) in surface layer blank prepared by pore-forming pug:
Coal dust needed for pore-forming pug dispensing in surface layer blank and dredged mud are carried out premixing, is then fed vacuum Pug mill carries out pugging, then the pore-forming pug pressure rolling obtained after pugging becomes pore-forming mud cake B thick for 3mm.
(3) prepared by surface layer blank granule:
By the pore-forming pug mud cake B of structure pug mud cake A, it is superimposed according to ABA, forms 3mm thickness through pressure rolling Surface layer mud cake, feeding plastic mud material comminutor carries out pelletize, made grain graininess about 3mm, then sloughs at 120 DEG C of insulation 5h Moisture in granule is to less than 5%.
(4) prepared by secondary surface layer blank:
Coarse granule copper smelting slag, loam and water in secondary surface layer dispensing is the most quickly stirred, when argillization loam is uniform The coarse granule copper smelting slag surface that is wrapped in formed after one layer of thin layer, then the wood flour increasing hole is admixed at a slow speed, stirs 5 minutes After, it is thus achieved that secondary surface layer blank.
Three, molding and burning till:
Secondary surface layer blank is uniformly fed in the mould of single shaft hydraulic press, and blank surface layer in mould is struck off, so After feed surface layer particulate material, wherein surface layer sotck thinkness 1cm in mould again, secondary surface layer sotck thinkness 9cm, use the pressure of 30MPa Blank in mould is pressed into the adobe that 8cm is thick by power, adobe is dried in dry kiln, is dried maximum temperature 150 DEG C, makes base In body, moisture content is less than 5wt%.Then dry complete adobe being put into tunnel cave to burn till, maximum sintering temperature is 1200 DEG C, wherein 200~500 DEG C of temperature ranges, 0.5 DEG C/min of programming rate;At 500~900 DEG C of temperature ranges, programming rate 1 DEG C/min, 900 DEG C~the temperature range of 1150 DEG C, 1.5 DEG C/min of programming rate, in maximum sintering temperature 1200 DEG C insulation 10h, then cools down, and the speed that cools is not more than 5 DEG C/min, is cooled to room temperature and obtains comprcssive strength 55MPa, permeability rate The water-permeable brick of 0.3cm/s, wherein the aperture diameter of surface layer is less than 0.1mm, will not block after life-time service.
Embodiment 4: a kind of sintering brick permeable to water, with the thick slag of flyash, waste and old clay brick coarse granule, cattle manure, carbon dust, kaolinite Soil, leaf powder, brown iron oxide are raw material, form by formula as below sintering.
One, formula
(1) surface layer structure pug formula (by weight percentage):
The thick slag of flyash 45%, granularity is less than 0.2mm;
Kaolin 30%, granularity is less than 200 mesh;
Water 25%.
(2) surface layer pore-forming pug formula:
Carbon dust 50%, granularity is less than 0.2mm;
Cattle manure (moisture content 60%) 45%;
Brown iron oxide 5%, granularity is less than 10 μm.
(3) secondary surface layer blank formulation:
Waste and old clay brick coarse granule 70%, particle size range 2~5mm;
Kaolin 15%, granularity is less than 200 mesh;
Leaf powder 5%, granularity is less than 1.5mm;
Water 10%.
Two, blank preparation process
(1) in surface layer blank prepared by structure pug:
By the thick slag of flyash, Kaolin and the water needed for surface layer structure pug after premixing, feed vacuum deairing machine Carry out pugging, the structure pug pressure rolling after pugging is become structure pug A mud cake thick for 2mm.
(2) in surface layer blank prepared by pore-forming pug:
Carbon dust needed for pore-forming pug in surface layer blank and cattle manure are carried out premixing, is then fed vacuum pugging Machine carries out pugging, obtains the B mud cake that pore-forming pug pressure rolling becomes thick for 2mm after pugging.
(3) prepared by surface layer blank granule:
By the pore-forming pug B mud cake of structure pug A mud cake, it is superimposed according to ABABA, forms 3mm through pressure rolling thick Surface layer mud cake, feeding plastic mud material comminutor carries out pelletize, made grain graininess about 3mm, then de-at 120 DEG C of insulation 5h Moisture in degranulation is to less than 5%.
(4) prepared by secondary surface layer blank:
Waste and old clay brick coarse granule in secondary surface layer dispensing, Kaolin, water the most quickly being stirred, argillization Kaolin is equal Even after coarse granule copper smelting slag surface is wrapped to form one layer of thin layer, then the leaf powder increasing hole is admixed at a slow speed, stir 5 points Zhong Hou, it is thus achieved that secondary surface layer blank.
Three, molding and burning till:
Secondary surface layer blank is uniformly fed in the mould of single shaft hydraulic press, and blank surface layer in mould is struck off, so After feed surface layer particulate material, wherein surface layer sotck thinkness 1cm in mould again, secondary surface layer sotck thinkness 9cm, use the pressure of 30MPa Blank in mould is pressed into the adobe that 8cm is thick by power, adobe is dried in dry kiln, is dried maximum temperature 120 DEG C, makes base In body, moisture content is less than 5wt%.Then dry complete adobe being put into tunnel cave to burn till, maximum sintering temperature is 1200 DEG C, wherein 200~500 DEG C of temperature ranges, 0.5 DEG C/min of programming rate;At 500~900 DEG C of temperature ranges, programming rate 1 DEG C/min, at 900 DEG C~the temperature range of 1150 DEG C, 1 DEG C/min of programming rate, it is incubated 10h maximum sintering temperature 1200 DEG C, Then cooling down, the speed that cools is not more than 5 DEG C/min, is cooled to room temperature and obtains comprcssive strength 60MPa, permeability rate The water-permeable brick of 0.1cm/s, wherein the aperture diameter of surface layer is less than 0.1mm, will not block after life-time service.
Embodiment 5: a kind of sintering brick permeable to water, with cullet powder, coarse granule blast furnace slag, methane slag, waste or used plastics Powder, bentonite are raw material, form by formula as below sintering.
One, formula
(1) surface layer structure pug formula (by weight percentage):
Cullet powder 65%, granularity is less than 0.2mm;
Bentonite 20%, granularity is less than 200 mesh;
Water 15%.
(2) surface layer pore-forming pug formula:
Thin waste or used plastics powder 30%, granularity is less than 0.2mm;
Make compost methane slag (moisture content 80%) 70%;
(3) secondary surface layer blank formulation
Coarse granule blast furnace slag 70%, particle size range 2~5mm;
Bentonite 15%;
Water 15%.
Two, blank preparation process
(1) in surface layer blank prepared by aggregate pug:
By cullet powder, bentonite and the water needed for surface layer structure pug after premixing, feeding vacuum deairing machine enters Row pugging, becomes A mud cake thick for 2mm by the structure pug pressure rolling after pugging.
(2) in surface layer blank prepared by pore-forming pug:
Molding powder thin needed for pore-forming pug in surface layer blank and methane slag of making compost are carried out premixing, is then fed Vacuum deairing machine carries out pugging, obtains the B mud cake that pore-forming pug pressure rolling becomes thick for 2mm after pugging.
(3) prepared by surface layer blank granule:
By the pore-forming pug B mud cake of structure pug A mud cake, it is superimposed according to ABA, forms 3mm thickness through pressure rolling Surface layer mud cake, feeding plastic mud material comminutor carries out pelletize, made grain graininess about 3mm, then sloughs at 120 DEG C of insulation 5h Moisture in granule is to less than 5%.
(4) prepared by secondary surface layer blank:
Coarse granule blast furnace slag in secondary surface layer dispensing, bentonite, water are the most quickly stirred, argillization bentonite It is wrapped in coarse granule blast furnace slag surface uniformly and forms one layer of thin layer, then the molding powder increasing hole is admixed at a slow speed, stir After mixing 2 minutes, it is thus achieved that secondary surface layer blank.
Three, molding and burning till:
Secondary surface layer blank is uniformly fed in the mould of single shaft hydraulic press, and blank surface layer in mould is struck off, so After feeding surface layer particulate material, wherein surface layer sotck thinkness 1cm in mould, secondary surface layer sotck thinkness 9cm, use 30MPa pressure Blank in mould is pressed into the adobe that 8cm is thick by power, adobe is dried in dry kiln, is dried maximum temperature 190 DEG C, makes base In body, moisture content is less than 5wt%.Then dry complete adobe being put into tunnel cave to burn till, maximum sintering temperature is 1100 DEG C, wherein 200~500 DEG C of temperature ranges, 0.75 DEG C/min of programming rate;At 500~900 DEG C of temperature ranges, programming rate 1 DEG C/min, 900 DEG C~the temperature range of 1150 DEG C, 1.5 DEG C/min of programming rate, in maximum sintering temperature 1100 DEG C insulation 5h, then cools down, and the speed that cools is not more than 5 DEG C/min, is cooled to room temperature and obtains comprcssive strength 30MPa, permeability rate The water-permeable brick of 0.5cm/s, wherein the aperture diameter of surface layer is less than 0.1mm, will not block after life-time service.

Claims (2)

1. a sintering brick permeable to water, it is characterised in that composition and the proportioning of this sintering brick permeable to water are specific as follows:
(1) in surface layer graininess blank, composition and the percentage by weight of structure pug are:
Structure fine aggregate: 45~65%;Plasticity high-temperature agglomerant: 20~30%;Water: 15~25%;
(2) in surface layer graininess blank, composition and the percentage by weight of pore-forming pug are:
Pore former aggregate: 20-50%;Plasticity increases hole binding agent 45-80%;Combustion catalyst in biomass fuel: 0-5%;
Described structure fine aggregate be the thick slag of flyash, slag, water-granulated slag, granulated copper slag, nickel slag, calcined kaolin, gangue, Quartz, calcined bauxite, ripe clay, gangue, scrap glass, waste old ceramics powder, discarded sintering wall brick and discarded sa refractory brick In any one or wantonly two kinds of things mixed above be less than 0.2mm through the broken powder granule obtained, the particle diameter of described powder granule And all process through high-temperature stableization, i.e. cool down or discard high temperature sintering material from high-temperature fusant or sintered body and obtain through broken;
Described plasticity high-temperature agglomerant is that loam, Kaolin, clayey raw material, bentonite, kieselguhr, montmorillonite, clayey are former Any one in material or the mixture of wantonly more than two kinds, described clayey raw material includes iron tailings mud, dig up mine and quarry in stripping Digging dregs from soil, Geotechnical Engineering dregs, subway and tunnel drill, the fineness of the particles of described plasticity high-temperature agglomerant is less than 200 mesh;
Described pore former aggregate is powder of straw, powdered rice hulls, leaf powder, wood flour, charcoal powder, coal dust, coke blacking, molding powder and shredded paper Any one in bits or the broken powder granule obtained of mixture warp of wantonly more than two kinds, the particle diameter of described powder granule is less than 0.2mm;
Described plasticity increase hole binding agent be city water treatment sludge, cattle manure, make compost in methane slag, dredged mud, mud any one Or the mixture of wantonly more than two kinds;
Described biomass fuel internal combustion catalyst is nickeliferous or any one in the compound of ferrum, dolomite and limestone or wantonly two Planting the above mixture granule through broken acquisition, described grain graininess is not more than 10 microns;
(3) composition and the mass percent of secondary surface layer blank is:
Coarse-texture aggregate: 70~75%;Plasticity high-temperature agglomerant: 10~15%;Pore forming agent coarse aggregate: 0~5%;Water: 10~ 15%;
Coarse-texture aggregate in described surface layer blank be the thick slag of flyash, blast furnace slag, ageing slag, Boiler Cinder Surveying, Granulated copper slag, nickel slag, cullet slag, discarded clay brick, waste ceramic brick, discarded domestic ceramics, discarded sa refractory brick, height Any one in ridge soil, gangue, quartz, calcined bauxite and ripe clay or the mixing of wantonly more than two kinds, described coarse-texture aggregate Acidity coefficient is not less than 0.9, and granularity is 1~6mm, and preferred size is 2~5mm;
Plasticity high-temperature agglomerant in described surface layer blank is loam, Kaolin, clayey raw material, bentonite, kieselguhr, illiteracy A kind of or the mixing of wantonly more than two kinds in de-soil, gangue, clayey raw material includes iron tailings mud, dig up mine and quarry in stripping Soil, Geotechnical Engineering dregs, subway and tunnel drill dig dregs, and fineness of the particles is less than 200 mesh;
Pore forming agent coarse aggregate in described surface layer blank is appointing in straw, rice husk, leaves, wood flour, Linesless charcoal, coal, coke A kind of or wantonly more than two kinds mixture warps crush the granule obtained, grain graininess 0.5~1.5mm.
2. the preparation method of sintering brick permeable to water described in claim 1, it is characterised in that the method specifically comprises the following steps that
(1) surface layer graininess blank is prepared:
After structure pug component in surface layer graininess blank being mixed, pugging obtains A pug;By the pore former in pore-forming pug Aggregate is prewetted, and then pugging after pore-forming pug component mixing in surface layer graininess blank is obtained B pug;By having after pugging The A pug of close or equal plasticity index becomes 1~5mm thick A mud cake and B mud cake with the pressure rolling respectively of B pug, then by A, B mud cake Making the double pug component thickness mud cake of AB according to ABA lamellar composite stacked system, then pug component thickness mud cakes double to described AB enter Row pressure rolling, forms the overall mud cake of thickness 2~4mm, described overall mud cake is finally divided into the little mud fourth of 2~4mm, thus complete Become the pelletize of surface layer graininess blank, be then dried and slough unnecessary moisture, it is thus achieved that surface layer graininess blank;
(2) preparation time surface layer blank:
First the coarse-texture aggregate in secondary surface layer blank is prewetted, then the plasticity high-temperature agglomerant in secondary surface layer blank is added and stir Mix, after coarse-texture aggregate surface is by one layer of plasticity high-temperature agglomerant of tight, then by thick for the pore forming agent in secondary surface layer blank Aggregate adds, and time surface layer blank, the water content≤15wt% of described surface layer blank are made in stirring;
(3) molding, be dried and burn till:
(A) molding: pave after first secondary surface layer blank being added mould, then surface layer graininess blank is added on time surface layer fabric And pave, carrying out single shaft extrusion forming the most on a hydraulic press, briquetting pressure is 5~30MPa, becomes adobe after the demoulding;
(B) it is dried: described adobe is dried in baking oven or dry kiln, is dried maximum temperature and is less than 200 DEG C, make in base substrate Moisture content is less than 5wt%;
(C) burn till: dried adobe is burnt till in kiln, wherein at 200~500 DEG C of temperature ranges, programming rate 0.5 DEG C~1 DEG C/min;500~900 DEG C of temperature ranges, programming rate 0.5 DEG C~1.5 DEG C/min, 900 DEG C~hyperpyrexia Becoming the temperature range of temperature, programming rate 1 DEG C~2 DEG C/min, maximum sintering temperature is 1050~1250 DEG C, burns till temperature the highest Degree insulation 5~10h, then cools down, and the speed that cools is not more than 5 DEG C/min, and being cooled to room temperature, to prepare described sintering saturating Water brick, the permeability rate 0.2~1cm/S of described sintering brick permeable to water, comprcssive strength is more than 30MPa, and rupture strength is more than 4MPa.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101519616A (en) * 2009-03-27 2009-09-02 同济大学 Biomass fuel as well as preparation and application thereof
CN201620327U (en) * 2010-02-08 2010-11-03 马鞍山市国林建材有限公司 Anti-block pervious concrete road surface brick
CN104276800A (en) * 2014-09-10 2015-01-14 李勇 Preparation method of water filter brick
WO2016037316A1 (en) * 2014-09-09 2016-03-17 南京工业大学 Preparation method of sic porous ceramic material and porous ceramic material manufactured by using same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101519616A (en) * 2009-03-27 2009-09-02 同济大学 Biomass fuel as well as preparation and application thereof
CN201620327U (en) * 2010-02-08 2010-11-03 马鞍山市国林建材有限公司 Anti-block pervious concrete road surface brick
WO2016037316A1 (en) * 2014-09-09 2016-03-17 南京工业大学 Preparation method of sic porous ceramic material and porous ceramic material manufactured by using same
CN104276800A (en) * 2014-09-10 2015-01-14 李勇 Preparation method of water filter brick

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CN110342905A (en) * 2019-06-26 2019-10-18 商洛学院 High-performance water permeable brick and preparation method thereof
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CN110894168A (en) * 2019-11-22 2020-03-20 河海大学 Water permeable system for treating micro-polluted water, composite water permeable brick and preparation method thereof
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CN113636829A (en) * 2021-08-12 2021-11-12 河北工程大学 Method for preparing high-strength sintered water permeable brick by using vanadium-titanium-iron tailings and reservoir sediment
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