Invention content
The present invention provides a kind of complex herbicidal composition containing furans sulphur humulone, with synergistic effect, for prevention
Resistant weed has excellent activity.
The technical scheme is that:
A kind of complex herbicidal composition containing furans sulphur humulone, including active components A and B, the active components A are furan
It mutters sulphur humulone, active constituent B is selected from least one of mesotrione, benzobicylon.
Active components A is 1 with active constituent B weight proportions:0.01-100;It is preferred that 1:0.05-10;It is preferred that 1:1-10;It is excellent
Select 1:1-5.
The content of effective constituents A and B in complex herbicidal composition is usually 1-98wt%, and preferably 5-90wt% is more excellent
Select 10-75wt%.
The complex herbicidal composition further includes auxiliary agent, and the auxiliary agent can be carrier, surfactant etc..
Term " carrier " herein indicates a kind of organic or inorganic, natural or synthetic substance.They contribute to activity
The application of ingredient, the carrier are usually inert and must be agriculturally acceptable, and especially processed plant is received.
Carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer;Or liquid
Body, such as water, alcohols, ketone, petroleum distillate, aromatic hydrocarbons or wax hydrocarbon, chlorohydrocarbon, liquefied gas.
Surfactant may include emulsifier, dispersant or wetting agent, it can be ionic or nonionic.It can carry
And example be the salt of polyacrylic acid, lignosulfonates, phenolsulfonic acid or naphthalene sulfonic acids salt, ethylene oxide and aliphatic alcohol or
Polymer, sulfosuccinic acid with aliphatic acid or with aliphatic amine and fortified phenol (especially alkylphenol or aryl phenol)
Phosphate, the alkyl of salt, taurine derivatives (especially taurine alkane fat) and the phenol of alcohol phosphate or multi-hydroxy ethyl
Sulfonate, alkylaryl sulfonates, alkyl sulfate, lauryl ether sulfate, aliphatic alcohol sulfate and sulphation 16-,
17-and octadecanol and sulphated fatty alcohol glycol ether, in addition there are the condensations of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde
Object, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol or nonyl phenol, alkyl phenyl polyglycol ether, three fourths
Base phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, alcohol and fatty alcohol/ethylene oxide contracting
Close object, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorb
Alcohol ester, lignin sulfite waste liquor and protein, albuminate, polysaccharide (such as methylcellulose), Hydrophobic Modified Starch,
Polyvinyl alcohol, polycarboxylate, poly-alkoxyl compound, polyvinylamine, polyvinylpyrrolidone and its copolymer.At least need one kind
Surfactant exists, to be conducive to active constituent dispersion in water and be conducive to enable them to correctly be applied to plant.
Above-mentioned composition also contains various other components, such as protecting colloid, adhesive, thickener, thixotropic agent, infiltration
Agent, stabilizer, chelating agent, dyestuff, colorant and polymer.
The composition of the present invention can used before through dilution or directly by user.It, which is prepared, to be added by common
Work method prepare, i.e., after active material being mixed with liquid flux or solid carrier, add surfactant such as dispersant, surely
Determine one or more of agent, wetting agent, adhesive, antifoaming agent etc..
The specific preparation of the Herbicidal combinations is wettable powder, dispersible oil-suspending agent, suspending agent, suspension emulsion, breast
Oil, water dispersible granules (dry suspending agent), aqueous emulsion, microemulsion.
Active compound, safener, solvent, emulsifier in above-mentioned formula are added in mother liquor modulation kettle, homogeneous oil phase is made, will go
In the uniformly mixed injection product modulation kettle such as ionized water, antifreeze, through high-speed stirred, it is uniformly mixed that the present composition is made is saturating
Bright or translucent microemulsion product.
In brief, composition of the invention can be added with conventional use of solid in the formula of the prior art and liquid
Agent mixes.
The composition of the present invention can be applied to by the method for spraying on pending plant leaf blade, that is, be applied to weeds,
Especially invaded and harassed on the surface of influence on the harmful weed infestation of plant growth or easily.
When the Herbicidal combinations of the application present invention, unexpected synergistic effect is obtained, and activity of weeding ratio makes
It is individually active more notable with the expected summation of the activity of single herbicide, and single herbicide.Synergistic effect shows as applying
Measure reductions, broader weeds distribution spectrum, herbicide effect faster, it is more longlasting, these characteristics are required in Weeds distribution practice process
It wants.For described characteristic, these new compositions are significantly superior to existing herbicide.
The undesirable plant is grassy weed, broad leaved weed and sedge weed.Such as Stellaria, Nasturtium officinale
Category, Agrostis, knotgrass, Avena, setaria, Europe sinapsis alba category, Lolium, Solanum, Brome, amur foxtail category, mother
Chrysanthemum, Tong fiber crops category, chrysanthemum harvest spp, Xanthium, Amaranthus, Chenopodium, Ipomoea, crowndaisy chrysanthemum category, Bedstraw, Viola and Veronica
Belong to.Specifically, such as flat bar rattan grass, needle spikesedge herb, Japan's Fischer grass, Herba Cyperi Glomerati, cyperus iria, difformed galingale herb, barnyard grass, lady's-grass, Cowhells
Grass, moleplant seed, green bristlegrass, annual bluegrass, needle spikesedge herb, firefly Lin, Monochoria vaginalis, mexicana, water starwort, dragon's tongue, cyperus iria L. rhizoma scirpi, open country are kind
Aunt, bog pondweed, clearvers, shepherd's purse, field thistle, Siberian cocklebur, the rhizome of nutgrass flatsedge, acalypha copperleaf, lamb's-quarters, thorn amaranth and branch amaranth, hold back blue dish, grass of meadow rue,
Angustifolia arrowhead herb etc..
The active ingredient of the present invention can also be administered in combination with one or more other herbicides to control wider scope
Undesirable vegetation.When being used in combination with other herbicides, active ingredient can be removed with other herbicide formulations or with other
Careless agent is sequentially applied.
Compared with prior art, beneficial effects of the present invention are:
(1) present invention selects mesotrione, benzobicylon and furans sulphur humulone mixture, for preventing and kill off field resistance weeds
With fine activity, harm of the resistant weed to field crops is effectively reduced, improves crop yield, promotes quality.
(2) benzobicylon broad weed-killing spectrum, action period length, speed are fast;Weeding is to broad-leaved class and portion after mesotrione bud
Divide grassy weed all effective, expand herbicide controlling spectrum, improves preventive effect.The two is mixed with furans sulphur humulone help to reduce it is each at
The dosage divided, the generation and development for reducing poisoning, reducing residual activity, delaying herbicide resistance.
Specific implementation mode
The following example not limits the present invention, and is used only to illustrate how the present invention realizes.For certain miscellaneous
Grass, these embodiments show especially significant validity.
A embodiments
1) dispersible oil-suspending agent
When active constituent B is mesotrione
Formula composition is:+ 5% dispersant phenethyl phenol polyoxyethylene ether of 3.6%+6% mesotrione of furans sulphur humulone
+ 8% emulsifier castor oil polyoxyethylene ether+2% of+5% emulsifier polyoxyethylene carboxylate of phosphate triethanolamine salt thickens
Agent organobentonite+methyl oleate is supplied.
2) dispersible oil-suspending agent
When active constituent B is benzobicylon
Formula composition is:+ 5% dispersant phenethyl phenol polyoxyethylene of 3.6%+15% benzobicylon of furans sulphur humulone
+ 8% emulsifier castor oil polyoxyethylene ether+2% of+5% emulsifier polyoxyethylene carboxylate of ether phosphate triethanolamine salt increases
Thick dose of organobentonite+methyl oleate is supplied.
3) suspending agent
When active constituent B is mesotrione
Formula composition is:+ 5% dispersant sodium lignin sulfonate+2% of 18%+30% mesotrione of furans sulphur humulone soaks
+ 5% antifreezing agent glycerine of+0.3% thickener xanthans of agent pull open powder+excess water is supplied.
Process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Process:All materials are put into mixing kettle, colloid mill is crossed after being stirred, enter sand mill three-level later
It is sanded, it is finished product finally to be sheared in cutter uniformly.
4) suspending agent
When active constituent B is benzobicylon
Formula composition is:+ 5% dispersant sodium lignin sulfonate+2% of 7.2%+30% benzobicylon of furans sulphur humulone moistens
+ 5% antifreezing agent glycerine of+0.3% thickener xanthans of humectant pull open powder+excess water is supplied.
Process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Process:All materials are put into mixing kettle, colloid mill is crossed after being stirred, enter sand mill three-level later
It is sanded, it is finished product finally to be sheared in cutter uniformly.
5) water dispersible granules
When active constituent B is mesotrione
Formula composition is:+ 5% wetting agent of 18%+10% dispersant naphthalenesulfonate of furans sulphur+30% mesotrione of humulone
+ 1% disintegrant polyvinyl alcohol of pull open powder+filler diatomite is supplied.
Process equipment:Airslide disintegrating mill, coulter type mixer, basket comminutor, drying box, screening machine etc..
Process:Above-mentioned material was uniformly mixed air-flow crushing, is added and mediates, dry after granulation, final sizing obtains
To finished product.
6) water dispersible granules
When active constituent B is benzobicylon
Formula composition is:+ 10% dispersant naphthalenesulfonate+5% of 10.8%+45% benzobicylon of furans sulphur humulone moistens
+ 1% disintegrant polyvinyl alcohol of humectant pull open powder+filler diatomite is supplied.
Process equipment:Airslide disintegrating mill, coulter type mixer, basket comminutor, drying box, screening machine etc..
Process:Above-mentioned material was uniformly mixed air-flow crushing, is added and mediates, dry after granulation, final sizing obtains
To finished product.
The B tests of pesticide effectiveness
The active determination test of mesotrione, benzobicylon and furans sulphur humulone mixture antagonism weeds is reported.
1 experimental condition
1.1 for trying target
Barnyard grass (Echinochloa crusgalli), picks up from Ningxia corn field.Angustifolia arrowhead herb (Sagittaria
Trifolia), bulb picks up from Liaoning Province Yingkou rice terrace.
Above-mentioned weeds use pot-culture method culture.With 180*140mm plastic nutrition bowls, it is placed in enamel tray, it is built-in from agriculture
The topsoil (at 4/5) for backing through and air-drying sieving is adopted in field, and soil moisture initial stage controls 20%, and it is uniform to select full seed
Weed seed is impregnated 6 hours, the vernalization in 28 DEG C of biochemical cultivation cases (dark), the ruderal species that will have just showed money or valuables one carries unintentionally with 25 DEG C of warm water
Son is uniformly placed in soil surface, then earthing 0.7cm.Chemicals treatment is placed on culture in controllable heliogreenhouse, is periodically warding off
A certain amount of water is added in porcelain dish, keeps ground moistening.
1.2 condition of culture
It is carried out in controllable heliogreenhouse, 18~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.
Soil types is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus
38.5mg/kg, available potassium 82.1mg/kg.
1.3 instrument and equipment
3WP-2000 type walking spray towers, Nanjing Agricultural Machinery Inst., Ministry of Agriculture.GA110 type a ten thousandth electronics day
Flat (Germany);ZDR2000 intelligent datas recorder (Hangzhou Ze great Instrument Ltd.);SPX type Intelligent biochemistry incubators (Ningbo
Jiangnan instrument plant).
2. experimental design
2.1 reagent
2.1.1 test medicine
95% mesotrione (Mesotrione) active compound (Shengbang Luye Chemical Co., Ltd., Shandong's offer);
95% benzobicylon (benzobicylon) active compound (Japanese SDS Biological Science Co., Ltd provides);
95% furans sulphur humulone (tefuryltrione) active compound (offer of Qingdao Nong Guan pesticides Co., Ltd).
Since these types of medicament is dissolved in acetone, two kinds of active compounds are all made of acetone as solvent, with 0.1% breast of content
Agent T-80 aqueous solutions dilute, current existing dilution.
2.2 test process
2.2.1 dosage is arranged
It, should be from two kinds of medicaments when determining mesotrione, benzobicylon and furans sulphur humulone each group distribution ratio or content
Action character and its measurements such as virulence, it is also contemplated that the main of the formula uses purpose.Mesotrione is cauline leaf process agent, is made
Fast with speed, benzobicylon also has cauline leaf active.Furans sulphur humulone is to awns cyperus iria category and resistance to sulfonylurea herbicide
Weeds are very effective, can inhibit the synthesis of pigment indispensable in plant growth, expand herbicide controlling spectrum, the two is mixed to be helped to reduce
The dosage of each ingredient reduces the pollution to environment.This research on the basis of prerun early period, if mesotrione, benzobicylon,
Furans sulphur humulone is applied alone and mixes dosage and is shown in Table 1,2 respectively, designs 15 groups altogether respectively.To be free of medicament, contain same solvent and breast
The water of agent is as blank control
2.2.2 experiment repeats
Often processing is repeated 4 times, and often handles 3 basins every time, and per basin, sowing seed or 20, bulb, often handle totally 60 plants.
2.3 processing mode
2.3.1 processing time and number
Experiment shares medicine 1 time.It waits for 1 heart stage of 2 leaf of weeds, thinning, keep 15 plants of weeds in per basin, often processing retains 45 plants,
Culture to 41 heart stage of 4 leaf of barnyard grass, angustifolia arrowhead herb leaf periods are then proceeded to be handled.
2.3.2 instrument and administrated method are used
Cultured examination material is uniformly placed in area 0.5m2Platform on, with 3WP-2000 type walking spray tower stems
Foliar spray mist, spouting liquid is based on 30 kilograms/hectare.Atomisation pressure 0.3MPa.After whole liquid medicine jets are complete, air valve is closed, after 30 seconds,
Spraying pyller is opened, nutritive cube is taken out.Then air valve is opened, clear water 50mL is sprayed, cleans sparge pipe.
3 test methods
Using pot-culture method.Weeds culture is shown in 1.1, reference《Farm-chemical indoor determination test rule herbicide》It carries out.With
Prescription method is shown in 2.3.2, using cauline leaf process method.
4 data surveys and statistical analysis
4.1 investigation method
Using absolute number investigation method, the survival whole strain seedling of weeds is cut off along soil surface with blade, is weighed with assay balance
Weeds fresh weight.It is based on zero by fresh weight for dead weeds.
4.2 control times and number
It investigates within 20 days after processing, investigates 1 time altogether.
4.3 data statistic analysis
With Gowing methods calculate it is each processing hybrid combining theoretical fresh weight inhibition rate (E0=X+Y-X*Y/100), then with
Actual measurement inhibiting rate (E) compares, the mixed synergy type to weeds of both evaluations, makees for synergy when E-E0 values are more than 10%
With, less than -10% be antagonism, be addition between -10%~10%.And it is special according to practical preventive effect and herbicide
The factors such as the balance of point, formula determine optimum proportioning.
X is mesotrione or fresh weight inhibition rate when benzobicylon dosage is P in formula;Y is that furans sulphur humulone dosage is Q
When fresh weight inhibition rate.
Statistical result is shown in Table 1.
5 interpretations of result and discussion
5.1 evaluating drug
Synergy type:Test result shows (table 1), mixed with the furans sulphur humulone each combined treatment pair of mesotrione 2
Value >=0 inhibiting rate E-E0 of kind weeds, shows certain increase drug effect trend.
The dosage form that the ratio range and content of selection preparation will be processed with due regard to, if being processed into dispersible oil-suspending agent,
The total content of preparation is unsuitable excessively high, and otherwise viscosity is too big, it is difficult to process, be typically chosen relatively small ratio range.If two medicines
Wettable powder, water-dispersible granules or aqueous suspension agent are processed into agent, and ratio range can be broader.
The mixed synergy effect (Gowing methods) to weeds of 1 mesotrione of table, furans sulphur humulone
Drug evaluation:Mesotrione is shown in Table 1 with furans sulphur humulone to barnyard grass, angustifolia arrowhead herb herbicidal effect measurement result.Five fluorine
There is cross resistance to the resistance barnyard grass for picking up from Ningxia in sulphur grass amine, pyrazosulfuron;Penoxsuam is wild to picking up from Liaoning resistance
Arrowhead no interactions resistance, and pyrazosulfuron has cross resistance to it.Mesotrione and furans sulphur humulone are with 60+36,60+54,60+
72,90+36,90+54,90+72,120+36 mixture composition show synergistic effect to barnyard grass, and E-E0 values correspond to respectively
29.7、21.0、17.8、25.1、17.8、15.1、11.6;To angustifolia arrowhead herb, all combinations all show as synergistic effect.Wherein 90
+ 36 mixture is best to barnyard grass, the effect of angustifolia arrowhead herb, and E-E0 values are respectively 25.1 and 30.0.In addition, in the case of high dose,
Since mesotrione single component preventive effect is higher, uses at this time, often show as addition, this is also mesotrione and furans
Sulphur humulone with 60+36,120+72 mixture combine, although the two ratio is identical, E-E0 values difference the reason of.Therefore,
The considerations such as the balance from cost, preventive effect, herbicide controlling spectrum and formula, mesotrione is with furans sulphur humulone in 1-5:1 range and near
It is mixed more suitable.
The mixed synergy effect (Gowing methods) to weeds of 2 benzobicylon of table, furans sulphur humulone
Drug evaluation:From table 2 it can be seen that furans sulphur humulone is slightly above barnyard grass to the preventive effect of angustifolia arrowhead herb.Nicosulfuron pair
There is cross resistance in the resistance barnyard grass for picking up from Ningxia and the resistance angustifolia arrowhead herb for picking up from Liaoning Yingkou.It is comprehensive to 2 in 9 proportionings
The whole preventive effect of kind weeds, benzobicylon+furans sulphur humulone dosage, which is 600+150 and all of above combination preventive effect, can meet
To the preventive effect of two kinds of weeds.To barnyard grass, low dosage combination shows as synergistic effect, and high dose combination shows as addition;It is right
Angustifolia arrowhead herb, all combinations show as addition.As can be seen that the ratio range of the two is wider, when furans sulphur humulone dosage is low
When, the high dosage of benzobicylon makes up, conversely, when benzobicylon dosage is low, the high dosage of furans sulphur humulone makes up.In addition,
In the case of high dose, since benzobicylon single component preventive effect is higher, uses at this time, often show as addition, this
It is that benzobicylon and furans sulphur humulone are combined with 600+150,1200+300 mixture, although the two ratio is identical, E-E0
The reason of being worth difference.Therefore, from the considerations such as the balance of cost, preventive effect, herbicide controlling spectrum and formula, benzobicylon and furans
Sulphur humulone is in 5-10:1 range and mixed more suitable nearby.
C, field demonstration
Paddy field weed is prevented and kill off using herbicidal composition made from embodiment to test.
Exemplary promote is carried out in Liaoning, Jilin, 3, the Heilungkiang testing site of rice belt 15 to test.Different demonstration area water
Rice varieties refer to table 3.
The different demonstration area rice varieties situations of table 3
Demonstration area |
Rice varieties |
Liaoning Yingkou |
Distant round-grained rice 436 |
Jilin songyuan |
Lucky round-grained rice 83 |
Heilungkiang Suihua |
Imperial round-grained rice 10 |
Application method:After rice transplanting slow seedling, the weeds 1-2 leaf phases, to convert fertilizer and spread fertilizer over the fields, specific test medicine and dosage are shown in Table 4,
50 square metres of plot area, often processing are repeated 4 times.45 days investigation preventive effects are shown in Table 4 after dispenser, and rice safety implementations are shown in Table
5。
4 field demonstration effect situation of table
5 field demonstration rice safety implementations of table
Note:Weed community type in each demonstration pilot project:Yingkou:Barnyard grass+angustifolia arrowhead herb+Monochoria korsakowii;Songyuan City:Barnyard grass+angustifolia arrowhead herb;It pacifies
Change:Barnyard grass+angustifolia arrowhead herb.
By a large number of experiments and exploration, it is an unexpected discovery of the invention that A is mixed with active constituent B, it is anti-for transplanted rice field
Except resistance barnyard grass, angustifolia arrowhead herb, there is surprising, unexpected synergistic effect, dosage can be reduced, and pacify to rice
Entirely, the pollution to environment is reduced, and rationally compounding reduces agricultural cost, there is good application prospect.
D, field demonstration
Utilize herbicidal composition Weed Control in Maize made from embodiment.
Exemplary promote is carried out in Shandong, Hebei, 3, the Henan testing site of Maize Region 15 to test.Different demonstration area rice
Kind refers to table 6.
The different demonstration area corn variety situations of table 6
Demonstration area |
Corn variety |
Qingdao |
Step on sea 605 |
Baoding |
First jade 335 |
District, Xinyang Area, Henan Province |
Zheng Dan 958 |
Application method:Corn 3-5 leaves, weeds 4-6 leaf phases are watered 30 kgs/acre, and hand sprayer, uniform cauline leaf is sprayed,
Specific test medicine and dosage are shown in Table 7, and 50 square metres of plot area, often processing is repeated 4 times.45 days investigation preventive effects after dispenser
7 are shown in Table, corn safety implementations are shown in Table 8.
7 field demonstration effect situation of table
8 field demonstration corn safety implementations of table
Note:Weed community type in each demonstration pilot project:Qingdao:Barnyard grass+lady's-grass+open country millet+Amaranthus retroflexus+lamb's-quarters;Songyuan City:Barnyard grass+horse
Tang+open country broom corn millet+piemarker+black nightshade;Suihua:Barnyard grass+Amaranthus retroflexus+piemarker+black nightshade+lamb's-quarters.
By a large number of experiments and exploration, it is an unexpected discovery of the invention that A is mixed with active constituent B, prevented and kill off for corn field anti-
Property barnyard grass and broad leaved weed, there is surprising, unexpected synergistic effect, can reduce dosage, and to corn safety,
The pollution to environment is reduced, and rationally compounding reduces agricultural cost, there is good application prospect.