CN105936729A - Outdoor high weatherability ABS plastic-wood composite board for buildings - Google Patents

Outdoor high weatherability ABS plastic-wood composite board for buildings Download PDF

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Publication number
CN105936729A
CN105936729A CN201610398808.9A CN201610398808A CN105936729A CN 105936729 A CN105936729 A CN 105936729A CN 201610398808 A CN201610398808 A CN 201610398808A CN 105936729 A CN105936729 A CN 105936729A
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China
Prior art keywords
parts
abs
outdoor high
composite board
weatherability
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Pending
Application number
CN201610398808.9A
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Chinese (zh)
Inventor
叶伟然
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Huzhou Zhongchen Construction Co Ltd
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Huzhou Zhongchen Construction Co Ltd
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Priority to CN201610398808.9A priority Critical patent/CN105936729A/en
Publication of CN105936729A publication Critical patent/CN105936729A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention discloses an outdoor high weatherability ABS plastic-wood composite board for buildings. The composite board is made of the following components by weight: 60-70 parts of ABS, 60-79 parts of rice straw powder, 10-15 parts of epoxy resin, 10-15 parts of EVA, 2-8 parts of triallylisocyanurate, 2-6 parts of aluminum sulfate, 3-7 parts of borax, 4-8 parts of kaolin, 2-6 parts of phthalic acid dimethyl anhydride, 3-7 parts of aluminum nitride, 2-6 parts of benzoic acid, and 3-5 parts of dibasic lead phosphate. The outdoor high weatherability ABS plastic-wood composite board provided by the invention has good toughness, rigidity and elasticity, and can stand the test of various harsh climates outdoors.

Description

A kind of outdoor high-weatherability ABS for building moulds wood composite board
Technical field
The invention belongs to building material technical field, be specifically related to a kind of outdoor high-weatherability ABS Mould wood composite board.
Background technology
Wood plastic composite is the novel environment friendly building materials the most just occurred, is the most also just Starting.Raw material used by wood-plastic products can use waste or used plastics and discarded timber, agricultural Fructus Citri tangerinae bar etc. Plant fiber makees base material, without any additional harmful components.And recyclable again with, claim Environmental protection truly, energy-conservation, the novel products of resource regeneration must be gone up.
" plastic-wood material ", is also " wood plastic composite ", as the term suggests can be regarded as mainly with Plastics are raw material, are mixed into new wood by adding the useless Plant fiber such as wood powder, rice husk, straw Material, then through the plastic processings such as extruding, mold pressing, injection moulding, the sheet material produced Or section bar.It is mainly used in the industries such as building materials, furniture, logistics packaging.By plastics and wooden powder By a certain percentage through the sheet material of hot extrusion molding after mixing, referred to as extrude wood-plastic composite panel.
The Waterproof corrosion of plastics and two kinds of characteristics of texture of timber are had concurrently so that it becomes owing to moulding wood For a kind of function admirable the most durable outdoor building materials (floor, fence, bench, gardens or Water bank view etc.);Also replace the Wood member that harbour, harbour etc. use, it may also be used for replace Making various packing materials, pallet, warehouse pallet etc. for timber too numerous to enumerate, purposes is extremely wide.
Plastic wood sheet, combines Plant fiber and the plurality of advantages of plastics macromolecular material, can be big Amount substitutes timber, can effectively alleviate the contradiction that China's Forest Resources is poor, wood supply is in short supply, It is the low-carbon (LC) of a kind of great development prospect, green, renewable ecological plastic-wood material capable of circulation. Along with people's raising to environmental resource attention degree, reclaim with waste and old material and resource comprehensive profit The trend of development of world economy has been become by the circular-type economy developmental pattern for core.Open energetically Send out resource circulation utilization technology, will the national economic development and environment sustainable development be produced far-reaching Impact.And utilize waste or used plastics and wood fiber to produce Wood Plastics Composite Product and adapt to this just The one good project required.
Owing to domestic market is still at the initial stage, plastic-wood products market at home does not also have large area Promote.Chinese market is compared with North America market, and the growth of wood plastic composite and manufactured goods also has Sizable space, it is contemplated that domestic Wood plastic composite market yield in recent years will be more than million Ton, the output value is more than 1,000,000,000 yuan, and forms novel wood-plastic composite article system.
Plastic-wood products will become following trend trend place, for consumers, moulds wooden Product belong to energy saving and environment friendly product, not only can well control the discharge of nuisance, additionally it is possible to Accomplish that the waterproof and dampproof of ground waits effect.
Moulding wood composite board is a kind of environment-friendly materials, recyclable reuses, and cheaper starting materials is rich Richness, it has good benefit at minimizing environmental pollution, aspect of promoting economic development, except having Outside the advantages such as modern design, wide ranges and nearly xyloid outward appearance, also has good mechanical performance With features such as excellent decay resistances.But mould wood composite board there is also some shortcomings it Place, such as life-time service, the most outdoor use, irradiates through sunlight for a long time and easily fades, weather-proof Property is poor;Service life is short, needs moulding the outer one layer of preservative oil of brush of plank every year, and maintenance cost is high.
The most how overcoming the deficiencies in the prior art is that current building material technical field needs solution badly Problem certainly.
Summary of the invention
To achieve these goals, the invention provides a kind of outdoor high-weatherability ABS for building Mould wood composite board.
It is an object of the invention to be achieved through the following technical solutions:
A kind of outdoor high-weatherability ABS for building moulds wood composite board, and it is by following weight portion The component mix and blend of number is made: ABS 60-70 part, rice straw powder 60-79 part, epoxy Resin 10-15 part, EVA 10-15 part, triallyl isocyanate 2-8 part, aluminum sulfate 2-6 Part, Borax 3-7 part, Kaolin 4-8 part, phthalic acid diformazan acid anhydride 2-6 part, aluminium nitride 3-7 part, benzoic acid 2-6 part, dibasic lead phosphite 3-5 part.
One of preferred version: it is to be prepared by the component of following parts by weight: ABS 60 parts, 60 parts of rice straw powder, epoxy resin 10 parts, EVA 10 parts, triallyl isocyanate 2 Part, 2 parts of aluminum sulfate, Borax 3 parts, Kaolin 4 parts, phthalic acid diformazan acid anhydride 2 parts, Aluminium nitride 3 parts, 2 parts of benzoic acid, dibasic lead phosphite 3 parts.
The two of preferred version: it is to be prepared by the component of following parts by weight: ABS 70 parts, 79 parts of rice straw powder, epoxy resin 15 parts, EVA 15 parts, triallyl isocyanate 8 Part, 6 parts of aluminum sulfate, Borax 7 parts, Kaolin 8 parts, phthalic acid diformazan acid anhydride 6 parts, Aluminium nitride 7 parts, 6 parts of benzoic acid, dibasic lead phosphite 5 parts.
The three of preferred version: it is to be prepared by the component of following parts by weight: ABS 62 parts, 63 parts of rice straw powder, epoxy resin 12 parts, EVA 12 parts, triallyl isocyanate 3 Part, 3 parts of aluminum sulfate, Borax 4 parts, Kaolin 5 parts, phthalic acid diformazan acid anhydride 3 parts, Aluminium nitride 4 parts, 3 parts of benzoic acid, dibasic lead phosphite 4 parts.
The four of preferred version: it is to be prepared by the component of following parts by weight: ABS 68 parts, 75 parts of rice straw powder, epoxy resin 14 parts, EVA 14 parts, triallyl isocyanate 7 Part, 5 parts of aluminum sulfate, Borax 6 parts, Kaolin 7 parts, phthalic acid diformazan acid anhydride 5 parts, Aluminium nitride 6 parts, 5 parts of benzoic acid, dibasic lead phosphite 4 parts.
Its preparation method is: carries out mixing treatment by weighing above-mentioned each component by proportioning, obtains Mixed material;Then gained uses extruder by mixed material extrusion molding, i.e. obtains finished product. The method have the advantages that
The outdoor high-weatherability ABS that the present invention provides mould wood composite board have good toughness, Rigidity and elasticity, sheet material can resist the test of outdoor various harsh weather.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, Although the present invention being described in detail with reference to previous embodiment, for the technology of this area For personnel, the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention Within the scope of.
Embodiment 1
A kind of outdoor high-weatherability ABS for building moulds wood composite board, and it is by following weight portion The component mix and blend of number is made:
ABS 60 parts, 60 parts of rice straw powder, epoxy resin 10 parts, EVA 10 parts, three Allyl iso cyanurate 2 parts, 2 parts of aluminum sulfate, Borax 3 parts, Kaolin 4 parts, adjacent benzene two Formic acid diformazan acid anhydride 2 parts, aluminium nitride 3 parts, 2 parts of benzoic acid, dibasic lead phosphite 3 parts. Its preparation method is: carries out mixing treatment by weighing above-mentioned each component by proportioning, is mixed Material;Then gained uses extruder by mixed material extrusion molding, i.e. obtains finished product.
Embodiment 2
A kind of outdoor high-weatherability ABS for building moulds wood composite board, and it is by following weight portion The component mix and blend of number is made:
ABS 70 parts, 79 parts of rice straw powder, epoxy resin 15 parts, EVA 15 parts, three Allyl iso cyanurate 8 parts, 6 parts of aluminum sulfate, Borax 7 parts, Kaolin 8 parts, adjacent benzene two Formic acid diformazan acid anhydride 6 parts, aluminium nitride 7 parts, 6 parts of benzoic acid, dibasic lead phosphite 5 parts. Its preparation method is: carries out mixing treatment by weighing above-mentioned each component by proportioning, is mixed Material;Then gained uses extruder by mixed material extrusion molding, i.e. obtains finished product.
Embodiment 3
A kind of outdoor high-weatherability ABS for building moulds wood composite board, and it is by following weight portion The component mix and blend of number is made:
ABS 62 parts, 63 parts of rice straw powder, epoxy resin 12 parts, EVA 12 parts, three Allyl iso cyanurate 3 parts, 3 parts of aluminum sulfate, Borax 4 parts, Kaolin 5 parts, adjacent benzene two Formic acid diformazan acid anhydride 3 parts, aluminium nitride 4 parts, 3 parts of benzoic acid, dibasic lead phosphite 4 parts. Its preparation method is: carries out mixing treatment by weighing above-mentioned each component by proportioning, is mixed Material;Then gained uses extruder by mixed material extrusion molding, i.e. obtains finished product.
Embodiment 4
A kind of outdoor high-weatherability ABS for building moulds wood composite board, and it is by following weight portion The component mix and blend of number is made:
ABS 68 parts, 75 parts of rice straw powder, epoxy resin 14 parts, EVA 14 parts, three Allyl iso cyanurate 7 parts, 5 parts of aluminum sulfate, Borax 6 parts, Kaolin 7 parts, adjacent benzene two Formic acid diformazan acid anhydride 5 parts, aluminium nitride 6 parts, 5 parts of benzoic acid, dibasic lead phosphite 4 parts. Its preparation method is: carries out mixing treatment by weighing above-mentioned each component by proportioning, is mixed Material;Then gained uses extruder by mixed material extrusion molding, i.e. obtains finished product.

Claims (5)

1. an outdoor high-weatherability ABS for building moulds wood composite board, it is characterised in that it To be prepared by the component of following parts by weight: ABS 60-70 part, rice straw powder 60-79 part, Epoxy resin 10-15 part, EVA 10-15 part, triallyl isocyanate 2-8 part, sulphuric acid Aluminum 2-6 part, Borax 3-7 part, Kaolin 4-8 part, phthalic acid diformazan acid anhydride 2-6 part, Aluminium nitride 3-7 part, benzoic acid 2-6 part, dibasic lead phosphite 3-5 part.
It is multiple that one the most according to claim 1 outdoor high-weatherability ABS for building moulds wood Plywood material, it is characterised in that it is to be prepared by the component of following parts by weight: ABS 60 parts, 60 parts of rice straw powder, epoxy resin 10 parts, EVA 10 parts, triallyl isocyanate 2 Part, 2 parts of aluminum sulfate, Borax 3 parts, Kaolin 4 parts, phthalic acid diformazan acid anhydride 2 parts, Aluminium nitride 3 parts, 2 parts of benzoic acid, dibasic lead phosphite 3 parts.
It is multiple that one the most according to claim 1 outdoor high-weatherability ABS for building moulds wood Plywood material, it is characterised in that it is to be prepared by the component of following parts by weight: ABS 70 parts, 79 parts of rice straw powder, epoxy resin 15 parts, EVA 15 parts, triallyl isocyanate 8 Part, 6 parts of aluminum sulfate, Borax 7 parts, Kaolin 8 parts, phthalic acid diformazan acid anhydride 6 parts, Aluminium nitride 7 parts, 6 parts of benzoic acid, dibasic lead phosphite 5 parts.
It is multiple that one the most according to claim 1 outdoor high-weatherability ABS for building moulds wood Plywood material, it is characterised in that it is to be prepared by the component of following parts by weight: ABS 62 parts, 63 parts of rice straw powder, epoxy resin 12 parts, EVA 12 parts, triallyl isocyanate 3 Part, 3 parts of aluminum sulfate, Borax 4 parts, Kaolin 5 parts, phthalic acid diformazan acid anhydride 3 parts, Aluminium nitride 4 parts, 3 parts of benzoic acid, dibasic lead phosphite 4 parts.
It is multiple that one the most according to claim 1 outdoor high-weatherability ABS for building moulds wood Plywood material, it is characterised in that it is to be prepared by the component of following parts by weight: ABS 68 parts, 75 parts of rice straw powder, epoxy resin 14 parts, EVA 14 parts, triallyl isocyanate 7 Part, 5 parts of aluminum sulfate, Borax 6 parts, Kaolin 7 parts, phthalic acid diformazan acid anhydride 5 parts, Aluminium nitride 6 parts, 5 parts of benzoic acid, dibasic lead phosphite 4 parts.
CN201610398808.9A 2016-06-06 2016-06-06 Outdoor high weatherability ABS plastic-wood composite board for buildings Pending CN105936729A (en)

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CN201610398808.9A CN105936729A (en) 2016-06-06 2016-06-06 Outdoor high weatherability ABS plastic-wood composite board for buildings

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106700584A (en) * 2016-11-22 2017-05-24 湖北硅金凝节能减排科技有限公司 Aerogel density board and preparation method thereof
CN106752002A (en) * 2016-12-21 2017-05-31 凤台县双利生物科技有限公司 Enhanced waterproof flame-retardant type biomass board of a kind of composite antibacterial film and preparation method thereof
CN116003996A (en) * 2023-02-20 2023-04-25 达柏博(苏州)新材料有限公司 Nylon film and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1482166A (en) * 2002-12-23 2004-03-17 北京欧尼克环保技术有限公司 Wood plastic composite material and method for producing the same, method for producing panel and sheet made of wood plastic composite
CN1621440A (en) * 2004-10-21 2005-06-01 俞立群 Plastic lignified board and its making method
CN1740234A (en) * 2005-09-16 2006-03-01 浙江诚信包装材料有限公司 Making process of compound wood-plastic material product
CN101294001A (en) * 2007-04-25 2008-10-29 中山市森朗环保装饰建材有限公司 Method for producing wood-plastic composite material
CN102863809A (en) * 2011-07-07 2013-01-09 深圳市格林美高新技术股份有限公司 Plastic wood material and preparation method thereof
CN103772894A (en) * 2014-02-28 2014-05-07 李胜刚 Plastic-wood composite material and manufacturing method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1482166A (en) * 2002-12-23 2004-03-17 北京欧尼克环保技术有限公司 Wood plastic composite material and method for producing the same, method for producing panel and sheet made of wood plastic composite
CN1621440A (en) * 2004-10-21 2005-06-01 俞立群 Plastic lignified board and its making method
CN1740234A (en) * 2005-09-16 2006-03-01 浙江诚信包装材料有限公司 Making process of compound wood-plastic material product
CN101294001A (en) * 2007-04-25 2008-10-29 中山市森朗环保装饰建材有限公司 Method for producing wood-plastic composite material
CN102863809A (en) * 2011-07-07 2013-01-09 深圳市格林美高新技术股份有限公司 Plastic wood material and preparation method thereof
CN103772894A (en) * 2014-02-28 2014-05-07 李胜刚 Plastic-wood composite material and manufacturing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106700584A (en) * 2016-11-22 2017-05-24 湖北硅金凝节能减排科技有限公司 Aerogel density board and preparation method thereof
CN106752002A (en) * 2016-12-21 2017-05-31 凤台县双利生物科技有限公司 Enhanced waterproof flame-retardant type biomass board of a kind of composite antibacterial film and preparation method thereof
CN116003996A (en) * 2023-02-20 2023-04-25 达柏博(苏州)新材料有限公司 Nylon film and preparation method thereof

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Application publication date: 20160914