CN105746569A - Insecticide composition containing dinotefuran and cyromazine - Google Patents
Insecticide composition containing dinotefuran and cyromazine Download PDFInfo
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- CN105746569A CN105746569A CN201610199865.4A CN201610199865A CN105746569A CN 105746569 A CN105746569 A CN 105746569A CN 201610199865 A CN201610199865 A CN 201610199865A CN 105746569 A CN105746569 A CN 105746569A
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- cyromazine
- mti
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- pesticidal preparations
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of farm chemical application and particularly relates to an insecticide composition containing dinotefuran and cyromazine.The insecticide composition is formed by conducting two-element compounding with dinotefuran and cyromazine as effective constituents, wherein the mass ratio of dinotefuran to cyromazine is 1: 50-50: 1.The composition has an obvious synergistic effect, the prevention and controlling effect is obviously superior to that achieved when only single type of insecticide is used, meanwhile, the using amount of insecticide is lowered, prevention and controlling cost is lowered, pest resistance to insecticide is delayed, and environmental pollution is reduced.
Description
Technical field
The invention belongs to pesticides application technical field, relate to a kind of composition pesticide, specifically one is containing MTI-446
Pesticidal combination with cyromazine.
Background technology
MTI-446 (dinotefuran) is the nicotinic insecticide of Mitsui company research and development.It is with existing nicotinoids
The chemical constitution of insecticide is far from each other, and its tetrahydrofuran base instead of former chloro-pyridine base, chloro-thiazole base,
Without halogen.Meanwhile, also different with nicotine at aspect of performance, so, current people are referred to as " furans cigarette
Alkali ".This medicament have tag, absorption height strong, quick-acting in stomach toxicity and root, lasting period long 3-4 week (theoretical lasting effect 43 days),
The features such as insecticidal spectrum is wide, and sucking insect is had excellent preventive effect, and i.e. show that the highest desinsection is lived at the lowest dosage
Property.It is mainly used in the aphid in the various crop such as preventing and treating wheat, paddy rice, cotton, vegetables, fruit tree, tobacco leaf, leafhopper, plant hopper, Ji
Horse, aleyrodid and resistant strain thereof, have height to coleoptera, Diptera and Lepidoptera, Diptera, beetle mesh and total wing mesh insect simultaneously
Effect, and the sanitary insect pests such as blattaria, termite, housefly are had efficiently.
Cyromazine is a kind of insect growth regulator, IGR class low toxic pesticide, has the strongest selectivity, mainly to Diptera
Insect is active.Its mechanism of action is to make Dipteran larvae and pupa morphologically be distorted, and adult eclosion is not complete or is subject to
Suppression.This medical instrument has tags and stomach poison function, and has strong Uptake and translocation, and the lasting period is longer, but speed of action is slower.Cyromazine
People, animal are had no side effect, environmentally safe.Cyromazine have with AVM, poison cicada with poison, Cupric sulfate mixture produces compounding killing
Worm agent.Cyromazine is applicable to multiple gourd, fruit and vegetable, mainly " flies " insect is had good insecticidal action.Gourd, fruit and vegetable at present
Production is mainly used in prevent and treat: U.S.'s state liriomyza bryoniae of various melon and fruit classes, solanaceous vegetables, beans and multiple leaf vegetables, South America spot
Multiple Liriomyza, leek and green onion, the root maggots etc. of garlic such as latent fly, M. sojae, green onion spot Liriomyza, liriomyza trifolii.
Being carried out by the pesticide active ingredient of the different mechanisms of action compounding is to develop pesticide new product at present and prevent and treat resistance disease
A kind of effectively quick way of insect pest.After different pesticide active ingredients carry out compounding, three kinds of type of action can be shown: be added
Effect, synergistic effect and antagonism.Generally, after only just learning that different pesticide active ingredient is compounding by substantial amounts of test
Type of action.The Recompounded pesticide of screening tool synergistic effect, it is possible to significantly improve prevention effect, reduce Pesticide use amount, reduce
Cost accounting, it is also possible to expanding prevention is composed, and delays the generation of pest and disease damage resistance, is the important means of current integrated pest prevention and control
One of.
Inventor is tested and field control effectiveness test by a large amount of indoor biometricses, filters out the desinsection group of MTI-446 and cyromazine
Compound, said composition has synergistic effect within the specific limits, and the composition of the present invention is to the Lepidoptera on crops, half wing
Mesh, homoptera pest are respectively provided with preferable preventive effect.Up to now, the Insecticidal combinations as active ingredient with MTI-446 and cyromazine
Thing, at home and abroad there is not yet relevant report.
Summary of the invention
It is an object of the invention to big for common insecticides dosage, cost accounting is high, insecticidal spectrum is narrow, resistance produce fast
Outstanding problem, it is provided that a kind of containing MTI-446 with the Pesticidal combination of cyromazine, said composition tool improves prevention effect, expands and kill
Worm spectrum, delaying drug resistance occur, reduce pesticide dosage and the advantage reducing cost.
The technical scheme is that
A kind of containing MTI-446 with the Pesticidal combination of cyromazine, this Pesticidal combination be with MTI-446 and cyromazine be effective
Composition, MTI-446 and cyromazine mass ratio are 1:50-50:1.
As preferably, the described mass ratio containing MTI-446 and the Pesticidal combination of cyromazine, MTI-446 and cyromazine is
1:10。
The invention also discloses a kind of pesticidal preparations comprising described Pesticidal combination, wherein MTI-446 and the matter of cyromazine
Amount accounts for the 1-80% of pesticidal preparations gross mass, and remaining is the auxiliary element allowing in agricultural chemicals to use.
As preferably, described auxiliary element is by solvent, cosolvent, emulsifying agent, wetting agent, dispersant, thickener, antifreeze
One or more compositions in agent, carrier and disintegrant.
As preferably, described solvent is esters or sulfone class, and described esters is sec-butyl acetate and ethyl acetate；Sulfone class is two
Methyl sulfoxide.
As preferably, described cosolvent is ketone or higher alcohol, and described ketone is cyclohexanone and N-pyrrolidones；Higher alcohol
For n-butanol.
As preferably, described emulsifying agent, wetting agent, dispersant are nonionic surfactant or anion surface active
Agent, described nonionic surfactant is castor oil polyoxyethylene ether, NPE, styryl phenyl polyoxy second
Alkene polyethenoxy ether, aliphatic alcohol polyethenoxy polyoxypropylene graft copolymer, tristyrylphenyl APEO and 12
Alkyl benzene calcium sulfonate castor oil polyoxyethylene ether；Anion surfactant is calcium dodecyl benzene sulfonate, sodium lignin sulfonate
Lauryl sodium sulfate, thermally coupled distillation columns and aliphatic alcohol polyoxyvinethene phosphate ammonium salt.
As preferably, described thickener is xanthans, Arabic gum, Magnesiumaluminumsilicate and polyvinyl alcohol.
As preferably, described antifreezing agent is polyalcohol, and described polyalcohol is ethylene glycol, glycerine and propane diols.
As preferably, described carrier is white carbon, kaolin or diatomite.
As preferably, described disintegrant is ammonium sulfate, sodium chloride or ammonium sulfate.
Described insecticides can use method well known in the art to be prepared as being suitable for the formulations of pesticide of agricultural use.
As preferably, the formulations of pesticide that can prepare are aqueous emulsion, microemulsion, suspending agent, wettable powder or water dispersible granules.
Described Pesticidal combination is respectively provided with preferable preventive effect to the Lepidoptera on crops, Semiptera, homoptera pest.
Compared with prior art, the invention has the beneficial effects as follows:
1. the Pesticidal combination of the present invention is after two kinds of active ingredients are compounding, has obvious synergistic effect, improves anti-
Control effect.
2. no interactions resistance between two kinds of active ingredients of the Pesticidal combination of the present invention, thus use and can delay after compounding
The generation of resistance and development.
3. the Pesticidal combination of the present invention can reduce the usage amount of agricultural chemicals, reduces cost accounting, reduces environmental pollution, thus
Alleviate the pressure to environment.
Detailed description of the invention
Present invention specific examples below is described in detail its beneficial effect.
One, indoor virulence test measures
1. experiment material: test medicine uses 95% MTI-446 and the former medicine of 95% cyromazine；Examination worm beet armyworm is in reality
Testing the population that indoor employing man-made feeds are raised continuously, examination worm is 4-5 instar larvae；Prodenia litura is to use manually in laboratory
The population that feed is raised continuously, examination worm is 3 instar larvaes；Striped rice borer is to use rice seedling to raise continuously in laboratory, and examination worm was 3 ages
Larva.
2. test method: adopted leaf butterfly spray-on process, each single dose arranges 5 different concentration, often processes and set 3 with Mixed Pharmacy
Secondary repetition, makees blank with clear water.
3. operating procedure: beet armyworm uses drop method, and the pronotary at 5 instar larvaes drips 1 μ L liquid, feeds cleaning
Man-made feeds, the 48h investigation examination worm death rate after process.
Prodenia litura, striped rice borer use leaching leaf butterfly feeding method, take cleaning cabbage and break into leaf butterfly, dry in the air after soaking 10s in medicine
Dry, to put in plate, access prodenia litura or striped rice borer 3 instar larvae, every ware puts 3 pieces of leaf butterflies, selects indoor feeding, health
, the prodenia litura that age is consistent or striped rice borer 3 instar larvae be inoculated on leaf butterfly, every leaf butterfly inoculates 20, then will process
Culture dish put into 12h/12h lighting box and cultivate, 48h checks dead borer population, the calculating death rate.Often process and set 3 repetitions, with clearly
Water makees blank.
4. computational methods: analyzed test data with DPS statistical analysis software, calculate the LC50 of each medicament, come
Evaluate the insecticidal activity of each medicament.And the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) × 100.
Percentage composition+B medicament the toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent.
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] × 100.
According to the NY/T1154.13-2008 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as increasing
Effect effect；Co-toxicity coefficient (CTC)≤80 shows as antagonism；< 120 show as summation action to 80 < co-toxicity coefficient (CTC).
5. result of the test (referring to table 1-3)
Table 1 MTI-446 and the cyromazine indoor joint toxicity measuring to beet armyworm
As shown in Table 1, the present invention containing MTI-446 and cyromazine pesticide composition, when MTI-446 and the mass ratio of cyromazine
In the range of 1:50-50:1, co-toxicity coefficient is all higher than 120, and this Pesticidal combination shows as synergistic effect to beet armyworm；Especially
When the mass ratio of MTI-446 and cyromazine is 1:10, and synergistic effect is the most obvious.
Table 2 MTI-446 and the cyromazine indoor joint toxicity measuring to prodenia litura
As shown in Table 2, the present invention containing MTI-446 and cyromazine pesticide composition, when MTI-446 and the mass ratio of cyromazine
In the range of 1:50-50:1, co-toxicity coefficient is all higher than 120, i.e. the biologically active of prodenia litura is all showed by this Pesticidal combination
For synergistic effect；Being especially 1:10 when the mass ratio of MTI-446 and cyromazine, synergistic effect is the most obvious.
Table 3 MTI-446 and the cyromazine indoor joint toxicity measuring to striped rice borer
As shown in Table 3, the present invention containing MTI-446 and cyromazine pesticide composition, when MTI-446 and the mass ratio of cyromazine
In the range of 1:50-50:1, co-toxicity coefficient is all higher than 120, i.e. said composition all shows as synergy to the biologically active of striped rice borer
Effect；Being especially 1:10 when the mass ratio of MTI-446 and cyromazine, synergistic effect is the most obvious.
Two, embodiment prepared by agricultural chemicals
Embodiment 1: 1% MTI-446 cyromazine aqueous emulsion
Embodiment 2: 10% MTI-446 cyromazine aqueous emulsion
Embodiment 3: 15% MTI-446 cyromazine aqueous emulsion
Described in above-described embodiment 1-3, the preparation method of aqueous emulsion is: by active ingredient MTI-446 and cyromazine solvent,
After cosolvent fully dissolves, input emulsifying agent, dispersant, wetting agent form oil phase after being sufficiently stirred for；Antifreezing agent is added to the water
Dissolve, form aqueous phase；Aqueous phase is slowly added in oil phase, use high-speed shearing machine shear, aqueous emulsion.
Embodiment 4: 5% MTI-446 cyromazine microemulsion
Embodiment 5: 8% MTI-446 cyromazine microemulsion
Embodiment 6: 15% MTI-446 cyromazine microemulsion
Described in above-described embodiment 4-6, the preparation method of microemulsion is: by active component MTI-446 and cyromazine solvent,
After cosolvent fully dissolves, put into emulsifying agent, after being sufficiently stirred for, form oil phase；Antifreezing agent is added to the water and obtains aqueous phase；By water
Be slowly added to mutually in oil phase, use high-speed shearing machine shear, transparent microemulsion.
Embodiment 7: 20% MTI-446 cyromazine suspending agent
Embodiment 8: 30% MTI-446 cyromazine suspending agent
Embodiment 9: 50% MTI-446 cyromazine suspending agent
Described in above-described embodiment 7-9, the preparation method of suspending agent is: active component MTI-446 and cyromazine are used gas
After stream pulverizer is pulverized, put in stirred tank, put into dispersant, wetting agent, antifreezing agent and water, after being sufficiently stirred for, by thing simultaneously
Material suction sand mill is fully ground, after having ground, in suction high-speed shearing machine, after adding thickener, carries out at a high speed
Shear, after having sheared, i.e. prepare suspending agent.
Embodiment 10: 50% MTI-446 cyromazine wettable powder
Embodiment 11: 60% MTI-446 cyromazine wettable powder
Embodiment 12: 80% MTI-446 cyromazine wettable powder
Described in above-described embodiment 10-12, the preparation method of wettable powder is: by formula rate, by active ingredient and system
Agent auxiliary element mixes, and pulverizes through airslide disintegrating mill, remixes uniformly, i.e. prepares wettable powder.
Embodiment 13: 25% MTI-446 cyromazine water dispersible granules
Embodiment 14: 50% MTI-446 cyromazine water dispersible granules
Embodiment 15: 70% MTI-446 cyromazine water dispersible granules
Described in above-described embodiment 13-15, the preparation method of water dispersible granules is: by formula rate, by active ingredient and system
After agent auxiliary element mixes, pulverize through airslide disintegrating mill, again mix, then, add a certain amount of water and this is mixed
Compound is mediated, extruder grain, and drying is sieved, and i.e. obtains water dispersible granules.
Three, field control effectiveness test
Embodiment 16: the complex preparation of MTI-446 and the cyromazine prevention effect to beet armyworm
As can be seen from the above table, 50% MTI-446 MTI-446 wettable powder uses 25g a.i./ha, 50% furan worm
After amine MTI-446 water dispersible granules uses 25g a.i./ha medicine, 30d is superior to each single dose (comparison) to the preventive effect of beet armyworm
It is used alone, during pilot survey, does not finds that this compound drug produces poisoning to paddy rice simultaneously.
Embodiment 17: the complex preparation of MTI-446 and the cyromazine prevention effect to rice-stem borer
As can be seen from the above table, 10% MTI-446 cyromazine aqueous emulsion uses 25g a.i./ha, 25% MTI-446 to go out
After fly aqueous amine dispersible granule uses 25g a.i./ha medicine, 30d is superior to each single dose (comparison) individually to the preventive effect of rice-stem borer
Use, during pilot survey, do not find that this compound drug produces poisoning to paddy rice simultaneously.
In sum, the Pesticidal combination containing MTI-446 and cyromazine of the present invention has synergistic function, with existing
Unitary agent compare, pest control effect significantly improves, and to crop safety, and highly promoting in agricultural production should
With.
The foregoing is only presently preferred embodiments of the present invention, be not limited to the substantial technological content of the present invention
Scope, the substantial technological content of the present invention is broadly to be defined in the right of application, any skill that other people complete
Art or method, if with claims hereof scope defined in identical, or the replacement of a kind of equivalence, all
It is considered to be covered by among this right.
Claims (7)
1. one kind contains MTI-446 and the Pesticidal combination of cyromazine, it is characterised in that: described Pesticidal combination be with MTI-446 and
Cyromazine be the mass ratio of active ingredient, MTI-446 and cyromazine be 1:50-50:1.
Pesticidal combination the most according to claim 1, it is characterised in that: described MTI-446 and cyromazine mass ratio be
1:10。
3. the pesticidal preparations comprising Pesticidal combination described in claim 1 or 2, it is characterised in that: in described pesticidal preparations
The quality of active ingredient MTI-446 and cyromazine accounts for the 1-80% of pesticidal preparations gross mass, and remaining is for allowing the auxiliary of use in agricultural chemicals
Co-ingredients.
Pesticidal preparations the most according to claim 3, it is characterised in that: described agricultural chemicals allow the auxiliary element used by molten
One or more compositions in agent, cosolvent, emulsifying agent, wetting agent, dispersant, thickener, antifreezing agent, carrier and disintegrant；
Described solvent is esters or sulfone class, and described cosolvent is ketone or higher alcohol, described emulsifying agent, wetting agent, dispersant be non-from
Sub-surface activating agent or anion surfactant, described thickener is xanthans, Arabic gum, Magnesiumaluminumsilicate and polyethylene
Alcohol, described antifreezing agent is polyalcohol, and described carrier is white carbon, kaolin or diatomite, and described disintegrant is ammonium sulfate, chlorination
Sodium or ammonium sulfate.
Pesticidal preparations the most according to claim 4, it is characterised in that: described esters is sec-butyl acetate and ethyl acetate；Sulfone
Class is dimethyl sulfoxide (DMSO)；Described ketone is cyclohexanone and N-pyrrolidones；Higher alcohol is n-butanol；Described non-ionic surface active
Agent is castor oil polyoxyethylene ether, NPE, styryl phenyl polyoxyethylene poly-oxygen propylene aether, poly alkyl alcohol
Oxygen ethene polyoxypropylene graft copolymer, tristyrylphenyl APEO and calcium dodecyl benzene sulfonate castor oil polyoxy
Vinethene；Anion surfactant be calcium dodecyl benzene sulfonate, sodium lignin sulfonate lauryl sodium sulfate, nonyl phenol gather
Oxygen vinethene phosphate and aliphatic alcohol polyoxyvinethene phosphate ammonium salt；Described polyalcohol is ethylene glycol, glycerine and propane diols.
Pesticidal preparations the most according to claim 3, it is characterised in that: the formulation of described pesticidal preparations be aqueous emulsion, microemulsion,
Suspending agent, wettable powder or water dispersible granules.
7. according to the arbitrary described pesticidal preparations of claim 3-6 in the application preventing and treating agriculturally insect.
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| CN201610199865.4A CN105746569A (en) | 2016-03-31 | 2016-03-31 | Insecticide composition containing dinotefuran and cyromazine |
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| CN201610199865.4A CN105746569A (en) | 2016-03-31 | 2016-03-31 | Insecticide composition containing dinotefuran and cyromazine |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104920372A (en) * | 2015-05-08 | 2015-09-23 | 天峨县平昌生态农业有限公司 | Acaricidal composition comprising pyriminostrobin and chlorofluorocarbon cyantraniliprole |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1220991A (en) * | 1993-10-26 | 1999-06-30 | 三井化学株式会社 | Tetrahydro-3-furanyl methylamine |
| EP2225940B1 (en) * | 2009-03-05 | 2014-03-12 | GAT Microencapsulation GmbH | Oil dispersions of nAChR binding neonicotinoids |
| CN104186530A (en) * | 2014-08-21 | 2014-12-10 | 青岛蓝图文化传播有限公司市南分公司 | Highly-efficient pesticide containing cyromazine, sufluoxime, dinotefuran and fipronil |
| CN104770388A (en) * | 2015-03-31 | 2015-07-15 | 阮积恩 | Insecticide composition containing CFC cyantraniliprole and thiacloprid |
-
2016
- 2016-03-31 CN CN201610199865.4A patent/CN105746569A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1220991A (en) * | 1993-10-26 | 1999-06-30 | 三井化学株式会社 | Tetrahydro-3-furanyl methylamine |
| EP2225940B1 (en) * | 2009-03-05 | 2014-03-12 | GAT Microencapsulation GmbH | Oil dispersions of nAChR binding neonicotinoids |
| CN104186530A (en) * | 2014-08-21 | 2014-12-10 | 青岛蓝图文化传播有限公司市南分公司 | Highly-efficient pesticide containing cyromazine, sufluoxime, dinotefuran and fipronil |
| CN104770388A (en) * | 2015-03-31 | 2015-07-15 | 阮积恩 | Insecticide composition containing CFC cyantraniliprole and thiacloprid |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104920372A (en) * | 2015-05-08 | 2015-09-23 | 天峨县平昌生态农业有限公司 | Acaricidal composition comprising pyriminostrobin and chlorofluorocarbon cyantraniliprole |
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