CN105385343A - Anti-dazzle glass coating liquid formula - Google Patents
Anti-dazzle glass coating liquid formula Download PDFInfo
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- CN105385343A CN105385343A CN201510845760.7A CN201510845760A CN105385343A CN 105385343 A CN105385343 A CN 105385343A CN 201510845760 A CN201510845760 A CN 201510845760A CN 105385343 A CN105385343 A CN 105385343A
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- coating liquid
- glass coating
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- USAHQSDPXPFEJY-UHFFFAOYSA-N CC=CC=CC(S(O[Si](C)(C)C=C)O[Si](C)(c1ccccc1)OC)=C Chemical compound CC=CC=CC(S(O[Si](C)(C)C=C)O[Si](C)(c1ccccc1)OC)=C USAHQSDPXPFEJY-UHFFFAOYSA-N 0.000 description 1
- WPWAAYMTZQYISW-UHFFFAOYSA-N CN(C=C)ON(C)C=C Chemical compound CN(C=C)ON(C)C=C WPWAAYMTZQYISW-UHFFFAOYSA-N 0.000 description 1
- BASDFMMFNXATJQ-UHFFFAOYSA-N CNON(C)C=C Chemical compound CNON(C)C=C BASDFMMFNXATJQ-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Oc1ccccc1 Chemical compound Oc1ccccc1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- PARWUHTVGZSQPD-UHFFFAOYSA-N [SiH3]c1ccccc1 Chemical compound [SiH3]c1ccccc1 PARWUHTVGZSQPD-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to an anti-dazzle glass coating liquid formula, prepared from 1-10 percent of nanoscale silicon dioxide particle, 40-50 percent of organic silicon resin solution, 0.1-2 percent of surface binder, 0.1-1 percent of silane coupling agent, 0.1-0.5 percent of catalyst and the balance of organic solvent. Compared with the prior art, the anti-dazzle glass coating liquid formula has the advantages that anti-dazzle glass coating liquid can achieve the following properties: the hardness can reach pencil hardness of 6-8H; the abrasive resistance is good, and the number of abrasion-resisting times can reach 1000; a haze value can reach 12 plus/minus 2, the glossiness can reach 60-80, and the light transmittance can reach 90-93 percent; under an environment with the relative humidity of 90 percent and a high temperature of 90 DEG C, the liquid can be maintained for 168 hours, and the adhesive force is 5B. The anti-dazzle glass coating liquid formula is reasonable in design and can be popularized on a large scale.
Description
Technical field
The present invention relates to glare proof glass technical field, particularly relate to a kind of anti-dazzle coating liquid formula.
Background technology
Anti-dazzle AG glass: reduce the interference that environment is reflective, improves the visible angle of display frame, reduces screen reflecting, strengthen the visual effect of people to picture, numeral, make image more clear true to nature, allow you enjoy better visual effect, anti-dazzle, not dazzling, anti-eye strain.Anti-dazzle AG glass has purposes very widely, for the glass surface of handset touch panel, panel computer touch-screen and large-sized touch display screen.At present, the effect of anti-dazzle can be realized by two kinds of approach: one is corroded glass surface, makes glass surface produce particulate state, is uneven, form diffuse-reflectance to light; Another kind does a kind of film coating at glass surface, forms rugged coating, forms diffuse-reflectance to light.Rear kind is the coating that anti-dazzle coating liquid is formed.The formula of anti-dazzle coating liquid has a variety of, and different ingredients has different performances, all not identical in hardness, wear resistance, glossiness and transparence.At present, it is good not that anti-dazzle coating liquid general on market has usually with the cementability of glass, and its wear resistance does not reach the problems such as industry service requirements.
Summary of the invention
To the present situation of above-mentioned prior art, technical problem to be solved by this invention is to provide a kind of and is base material by silicone resin and all good glare proof glass coating liquid formula of hardness, wear resistance, glossiness and transparence.
The present invention solves the problems of the technologies described above adopted technical scheme: a kind of glare proof glass coating liquid formula, comprise the nanosized silica particles of 1-10%, the silicone resin solution of 40-50%, the surface treating adhesive of 0.1-2%, 0.1-1% silane coupling agent, the catalyzer of 0.1-0.5%, all the other are organic solvent.
Further, described silicone resin solution can be methylsiloxane resin and phenyl silicone resin.
Further, described methylsiloxane resin chemical structural formula such as formula shown in (A),
Further, described phenyl silicone resin chemical structural formula such as formula shown in (B),
Further, described surface treating adhesive chemical structural formula is such as formula C) shown in,
Further, described catalyst chemical structural formula such as formula shown in (D),
Further, described silane coupling agent is KH550 or KH560 or KH570.
Further, described organic solvent can be saturation type aliphatic hydrocarbon, annular aliphatic hydrocarbon, aromatic hydrocarbons, halogenated alkane and halogenated aromatic hydrocarbon.
Compared with prior art, the invention has the advantages that: a kind of glare proof glass coating liquid of the present invention, utilize the cementability of silicone resin itself and the feature good with the matching of silicon-dioxide composition in glass, improve cementability and the wear resistance of Anti Glare Coatings and glass-based version, following performance can be reached: hardness can reach pencil hardness 6-8H; Wear resistance is good, can reach abrasion resistance: 1000 times; Haze value can reach 12 ± 2, and glossiness can reach 60-80, and transmittance can reach 90-93%; Under the hot environment of relative humidity 90% and 90 degree, maintain 168 hours, sticking power is 5B, and the present invention is reasonable in design, can large-scale promotion.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, the present invention is further elaborated.
A kind of glare proof glass coating liquid formula, comprise the nanosized silica particles of 1-10%, particle diameter is the silicone resin solution of 10-100nm, 40-50%, the surface treating adhesive of 0.1-2%, 0.1-1% silane coupling agent, the catalyzer of 0.1-0.5%, all the other are organic solvent, and described silicone resin solution can be methylsiloxane resin and phenyl silicone resin, described methylsiloxane resin chemical structural formula is such as formula shown in (A)
Described phenyl silicone resin chemical structural formula such as formula shown in (B),
Described surface treating adhesive chemical structural formula such as formula shown in (C),
Described catalyst chemical structural formula such as formula shown in (D),
Described silane coupling agent is KH550 or KH560 or KH570, and described organic solvent can be saturation type aliphatic hydrocarbon, such as Skellysolve A, hexane, normal heptane, octane-iso and dodecane; Annular aliphatic hydrocarbon, such as pentamethylene and hexanaphthene; Aromatic hydrocarbons, such as benzene,toluene,xylene and sym-trimethylbenzene; Halogenated alkane, such as trichloroethane; Halogenated aromatic hydrocarbon, such as bromobenzene and chlorobenzene.
Case study on implementation 1:
SiO 2 powder (surface is through hydrophobicity process) with 15%, the organosilicon based resin of 30%, the catalyzer of 5%, the hydrogeneous organic silicone oil of 5%, the surface bonding agent of 0.1%, the silane coupling agent KH560 of 0.2%, all the other are that toluene makes coating liquid as solvent interpolation.After being sprayed on and glass also solidifies, the thickness of coating is 1.5 microns, and glossiness is 80 (BYK photometers), and transmittance is 92% (400nm-800nm wave band).Good with glass surface cementability, with the soft cloth friction of 0.5kg pressure, after 1000 times, coating is without obvious damage.The pencil tested for hardness of coating can reach 8H.
Case study on implementation 2:
SiO 2 powder (surface is through hydrophobicity process) with 20%, the organosilicon methyl resin (condensed type) of 40%, the catalyzer of 0.5%, the surface bonding agent of 0.1%, the Silane coupling agent KH550 of 0.1%, all the other are that normal heptane makes coating liquid as solvent interpolation.Through being sprayed on after on glass, the thickness of coating is 1.5 microns, and glossiness is 90-100 (BYK photometer), and transmittance is 91% (400nm-800nm wave band).Good with glass surface cementability, with the soft cloth friction of 0.5kg pressure, after 1000 times, coating is without obvious damage.The pencil tested for hardness of coating can reach 7H.
This coating liquid using method;
After solution mixes, apply, coating can adopt the techniques such as rotary coating, spraying, blade coating and dip-coating, glass after coating is put into baking oven, setting storing temperature is at 150 DEG C-200 DEG C, and baking 0.5-2 hour, solidifies rear film forming, thickness is 1-10 micron, and the film after baking is vaporific at glass surface.
Compared with prior art, the invention has the advantages that: a kind of glare proof glass coating liquid of the present invention, can reach following performance: hardness can reach pencil hardness 6-8H; Wear resistance is good, can reach abrasion resistance: 1000 times; Haze value can reach 12 ± 2, and glossiness can reach 60-80, and transmittance can reach 90-93%; Under the hot environment of relative humidity 90% and 90 degree, maintain 168 hours, sticking power is 5B, and the present invention is reasonable in design, can large-scale promotion.
Claims (8)
1. a glare proof glass coating liquid formula, is characterized in that, comprise the nanosized silica particles of 1-10%, the silicone resin solution of 40-50%, the surface treating adhesive of 0.1-2%, 0.1-1% silane coupling agent, the catalyzer of 0.1-0.5%, all the other are organic solvent.
2. a kind of glare proof glass coating liquid formula according to claim 1, it is characterized in that, described silicone resin solution can be methylsiloxane resin and phenyl silicone resin.
3. a kind of glare proof glass coating liquid formula according to claim 2, is characterized in that, described methylsiloxane resin chemical structural formula such as formula shown in (A),
。
4. a kind of glare proof glass coating liquid formula according to claim 2, is characterized in that, described phenyl silicone resin chemical structural formula such as formula shown in (B),
。
5. a kind of glare proof glass coating liquid formula according to claim 1, is characterized in that, described surface treating adhesive chemical structural formula such as formula shown in (C),
。
6. a kind of glare proof glass coating liquid formula according to claim 1, is characterized in that, described catalyst chemical structural formula such as formula shown in (D),
。
7. a kind of glare proof glass coating liquid formula according to claim 1, it is characterized in that, described silane coupling agent is KH550 or KH560 or KH570.
8. a kind of glare proof glass coating liquid formula according to claim 1, it is characterized in that, described organic solvent can be saturation type aliphatic hydrocarbon, annular aliphatic hydrocarbon, aromatic hydrocarbons, halogenated alkane and halogenated aromatic hydrocarbon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510845760.7A CN105385343A (en) | 2015-11-30 | 2015-11-30 | Anti-dazzle glass coating liquid formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510845760.7A CN105385343A (en) | 2015-11-30 | 2015-11-30 | Anti-dazzle glass coating liquid formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105385343A true CN105385343A (en) | 2016-03-09 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510845760.7A Pending CN105385343A (en) | 2015-11-30 | 2015-11-30 | Anti-dazzle glass coating liquid formula |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105385343A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115093791A (en) * | 2022-07-22 | 2022-09-23 | 深圳市中仁能源科技有限公司 | Blue-blocking anti-glare coating liquid for display screen and preparation method thereof |
| CN115216222A (en) * | 2022-09-06 | 2022-10-21 | 深圳市中仁能源科技有限公司 | Anti-glare coating material for enhancing scratch resistance of display screen and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1969023A (en) * | 2004-06-11 | 2007-05-23 | 东丽株式会社 | Siloxane coating material, optical articles and process for the production of siloxane coating materials |
| JP2008197320A (en) * | 2007-02-13 | 2008-08-28 | Nippon Paint Co Ltd | Antiglare coating composition, antiglare film, and method for manufacturing the same |
| CN101600664A (en) * | 2006-12-20 | 2009-12-09 | 陶氏康宁公司 | Organosilicon resin composition with multiple layers of cured applies or laminated glass baseplate |
| CN102239222A (en) * | 2008-10-10 | 2011-11-09 | 3M创新有限公司 | Silica coating for enhanced hydrophilicity |
| JP2013134358A (en) * | 2011-12-26 | 2013-07-08 | Dainippon Printing Co Ltd | Composition for antidazzle layer, preparation method of composition for antidazzle layer, and manufacturing method of antidazzle film |
| CN104755570A (en) * | 2012-10-30 | 2015-07-01 | 乐金华奥斯有限公司 | Anti-reflective coating composition including siloxane compound, and anti-reflective film adjusting surface energy by using same |
-
2015
- 2015-11-30 CN CN201510845760.7A patent/CN105385343A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1969023A (en) * | 2004-06-11 | 2007-05-23 | 东丽株式会社 | Siloxane coating material, optical articles and process for the production of siloxane coating materials |
| CN101600664A (en) * | 2006-12-20 | 2009-12-09 | 陶氏康宁公司 | Organosilicon resin composition with multiple layers of cured applies or laminated glass baseplate |
| JP2008197320A (en) * | 2007-02-13 | 2008-08-28 | Nippon Paint Co Ltd | Antiglare coating composition, antiglare film, and method for manufacturing the same |
| CN102239222A (en) * | 2008-10-10 | 2011-11-09 | 3M创新有限公司 | Silica coating for enhanced hydrophilicity |
| JP2013134358A (en) * | 2011-12-26 | 2013-07-08 | Dainippon Printing Co Ltd | Composition for antidazzle layer, preparation method of composition for antidazzle layer, and manufacturing method of antidazzle film |
| CN104755570A (en) * | 2012-10-30 | 2015-07-01 | 乐金华奥斯有限公司 | Anti-reflective coating composition including siloxane compound, and anti-reflective film adjusting surface energy by using same |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115093791A (en) * | 2022-07-22 | 2022-09-23 | 深圳市中仁能源科技有限公司 | Blue-blocking anti-glare coating liquid for display screen and preparation method thereof |
| CN115216222A (en) * | 2022-09-06 | 2022-10-21 | 深圳市中仁能源科技有限公司 | Anti-glare coating material for enhancing scratch resistance of display screen and preparation method thereof |
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Address after: 315000 Zhejiang, Zhenhai District, Ningbo mayor Shao Lu, Kowloon lake, No. 165 Applicant after: NINGBO RUISHIDA NEW MATERIALS CO., LTD. Address before: 315000 Zhejiang, Zhenhai District, Ningbo mayor Shao Lu, Kowloon lake, No. 165 Applicant before: NINGBO RUISHIDA NEW MATERIAL CO., LTD. |
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Application publication date: 20160309 |