CN105367227B - A kind of preparation method of Carbon balance organic liquid fertilizer - Google Patents
A kind of preparation method of Carbon balance organic liquid fertilizer Download PDFInfo
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- CN105367227B CN105367227B CN201510777279.9A CN201510777279A CN105367227B CN 105367227 B CN105367227 B CN 105367227B CN 201510777279 A CN201510777279 A CN 201510777279A CN 105367227 B CN105367227 B CN 105367227B
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Abstract
The invention discloses a kind of preparation methods of Carbon balance organic liquid fertilizer, it is using organic waste as raw material, acid is added and carries out resolution reaction, resolution reaction carries out in the closed reactor of microwave irradiation, the time of resolution reaction is 3~20min, the acid of resolution reaction is nitric acid, sulfuric acid, the mixing of one or more of perchloric acid or hydrogen peroxide, the mass ratio of organic waste and acid is (10~1): 1, microwave frequency is 300MHz~300GHz, nano-synergistic agent is added after resolution reaction, the nano-synergistic agent is nano diatomite, nano-bentonite, the mixing of one or more of nano silica.The present invention obtains by the collective effect of acid resolution and micro-wave digestion and is easy to be absorbed by crops the small molecular organic compounds utilized, can supply crop carbon, balances carbon content in crop.
Description
Technical field
The present invention relates to technical field of fertilizers, and in particular to a kind of to meet crop carbon by raw material preparation of organic waste
The method for balancing the organic liquid fertilizer needed.
Background technique
Agricultural is one of pillar of the national economic development, and chemical fertilizer is the material base of agricultural sustainable development, increases in grain production
Guarantee.As construction land gradually extends, in arable land in the case where relative shortage, being increase soil fertility by fertilising is to hold
The continuous important guarantee using soil and developing agricultural.It has been reported that China's utilization rate of nitrogen fertilizer is only 20~50%, phosphate fertilizer at present
It is 30~35% for 15~25%, potash fertilizer.Low do not weigh of utilization rate of fertilizer causes the huge wasting of resources, while but also soil matter
Amount decline, and polluted surface water, underground water and atmospheric environment, the quality of life and living environment for making the mankind are by serious prestige
The side of body.The quality for improving crops, will not only pay attention to the use of a great number of elements such as nitrogen, phosphorus, potassium fertilizer, more pay attention to the supply of carbon in
The use of microelement, beneficial element fertilizer.
In the case where agricultural, trade waste are largely dropped, preparing production fertilizer using these wastes is that can hold
The important channel of supervention exhibition.Currently, the technology using alcohol waste liquid production active humic acid is had already appeared, mainly by heavy
It drops, aoxidize, adding the techniques such as various beneficial elements and obtain fertilizer.Also there is the liquid using high concentrated organic wastewater production high activity
Fertilizer, waste water are mainly alcohol waste water, gourmet powder waste water, yeast wastewater, paper waste or rubbish waste liquid, pass through Stirring and ammonia
Water, which reacts to obtain, is conducive to the fulvic acid that crop is absorbed and utilized.Also have and utilize the organic matter in nitric acid and hydrogen peroxide oxidation waste water
So that organic molecular chemistry key is broken to obtain organic matter.
The method that available organic matter is made in the above Decomposition Wastewater is chemical-agent technique, merely uses chemical reagent
Method if reaction not enough the organic matter that generates be larger molecular organics, if overreact organic matter may be by excessive oxygen
Turn to carbon dioxide.
To sum up, research and develop it is a kind of using organic waste preparation crop can the organic liquid fertilizer that utilizes of efficient absorption, promote
Being absorbed and utilized for carbon, balances carbon content in crop, it is ensured that the new technology that crop health generates is very necessary.
Summary of the invention
It is an object of the invention to overcome the defect of the above-mentioned prior art, a kind of preparation of Carbon balance organic liquid fertilizer is provided
Method, this method is using organic waste as raw material, by the collective effect of acid resolution and micro-wave digestion, obtains and is easy to be inhaled by crop
The small molecular organic compounds utilized are received, crop carbon can be supplied, balance carbon content in crop.
Carbon balance organic liquid fertilizer of the present invention refers to that organic carbonaceous small molecular weight percentage accounts for 5-85%, the carbon
Balancing organic liquid fertilizer can be by obtaining the polymer substance containing organic carbon by processing, and wherein organic carbonaceous small molecule is
Refer to molecular weight 800 hereinafter, may include the ingredients such as alkanes, fats, carbohydrate, acids；The macromolecule mixture of organic carbon can
Think alcohol waste water, yeast wastewater, amino acid wastewater etc.；Processing mode can be sour resolution, micro-wave digestion, microbiological treatment alkali
Solution, photodissociation, enzymatic hydrolysis etc..Carbon balance organic liquid fertilizer can be diluted or be concentrated in use, to reach fertilizer product institute
The function of needing.
The present invention to achieve the goals above, prepares Carbon balance organic liquid fertilizer with the following method: a kind of Carbon balance has
The preparation method of machine Liquid Fertilizer comprising following steps: using organic waste as raw material, acid is added and carries out resolution reaction, clears up
Reaction carries out in the closed reactor of microwave irradiation.
Preferably, the time for clearing up reaction is 3~20min, and the acid for clearing up reaction is nitric acid, sulfuric acid, perchloric acid or double
The mass ratio of the mixing of one or more of oxygen water, organic waste and acid solution is (10~1): 1, the concentration of acid solution
It is 2mol/L with pH meter, microwave frequency is 300MHz~300GHz.
Preferably, 1~2h first is impregnated with digestion solution before resolution reaction.
Preferably, between ammonia water conditioning system PH to 6~8 after resolution reaction.
Preferably, nano-synergistic agent is added after resolution reaction.
Preferably, the nano-synergistic agent is one of nano diatomite, nano-bentonite, nano silica or two
Kind or more mixing.
Preferably, the dosage of the nano-synergistic agent is the 0.1~20% of organic waste amount of substance.
Further, the present invention is to overcome technological deficiency described in background technology, provides a kind of Carbon balance organic liquid
Fertilizer, which is characterized in that be prepared using Carbon balance organic liquid fertilizer of the present invention as raw material.
Compared with prior art, the beneficial effects of the present invention are:
1, the present invention is using organic waste as raw material, by its recycling, clears up the collective effect with micro-wave digestion by acid,
The small molecular organic compounds such as acetic acid, propionic acid, amino acid, glucose, xylose are obtained, can be handy by crop efficient absorption, be
Crop supplements carbon, balances crop carbon content.
2, the present invention combines acid resolution and micro-wave digestion, and first impregnates before resolution, guarantees that raw material is not by excessive decomposition
Carbon dioxide, and can be decomposed by the small molecular organic compounds of crop efficient absorption.
3, the present invention also introduces nano-synergistic agent, since the surface area of nano-synergistic agent is big, surface-active atom is more, insatiable hunger
The atom of sum has very big combination energy, can promote the absorption of nitrogen, phosphorus, potassium, improves the utilization rate of fertilizer, reduces fertilizer loss
Pollution to environment.
4, present invention introduces nano-synergistic agent be easy by plant root hair or tip of a root partial adsorbates, can supplement micro in silicon
Element improves anti-shade and the lodging resistance of crop, promotes photosynthetic generation, and with carbon collective effect in farming
Object further improves absorption and utilization of the crop to carbon again, crops quality is improved while increasing production and improying productivity.
Specific embodiment
The present invention is described in further detail below by specific embodiment, so that the clear present invention is claimed
Technical solution.
Embodiment 1
It takes the waste water 100L of Alcohol Production factory to be put into micro-wave diminishing pot, 47L is added, hydrogen ion concentration is the nitre of 2mol/L
Sour digestion solution impregnates waste water 1.5h, then opens microwave irradiation and is cleared up, and microwave frequency 110GHZ clears up response duration
Between be 15min.Ammonium hydroxide is added after resolution reaction and adjusts pH value to 7, and nano diatomite 10kg is added.
Above-mentioned acid hydrolysis solution selects the product of Shenzhen Ding Qing Chemical Co., Ltd., and microwave dissolver is Italy
The ETHOS A type of Milestone company production clears up instrument.
Embodiment 2
It takes the waste water 100L of Alcohol Production factory to be put into micro-wave diminishing pot, 47L is added, hydrogen ion concentration is 2mol/L nitric acid
Digestion solution impregnates 2h, then opens microwave irradiation and is cleared up, microwave frequency 300GHZ, and resolution duration of the reaction is
20min.Ammonium hydroxide is added after resolution reaction and adjusts pH value to 8, and nano diatomite 20kg is added.
Above-mentioned acid hydrolysis solution selects the product of Shenzhen Ding Qing Chemical Co., Ltd., and microwave dissolver is Italy
The ETHOS A type of Milestone company production clears up instrument.
Embodiment 3
It takes the waste water 100L of Alcohol Production factory to be put into micro-wave diminishing pot, 47L is added, hydrogen ion concentration is 2mol/L nitric acid
Digestion solution impregnates 1h, then opens microwave irradiation and is cleared up, microwave frequency 300MHZ, and resolution duration of the reaction is
3min.Ammonium hydroxide is added after resolution reaction and adjusts pH value to 6, and nano-bentonite 1kg is added.
Above-mentioned acid hydrolysis solution selects the product of Shenzhen Ding Qing Chemical Co., Ltd., and microwave dissolver is Italy
The ETHOS A type of Milestone company production clears up instrument.
Comparative example 1
It takes the waste water 100L of Alcohol Production factory to be put into reactor tank, 47L is added, hydrogen ion concentration is the resolution of 2mol/L nitric acid
Liquid impregnates 1h, and then heating duration of the reaction is 30min.Ammonium hydroxide is added after resolution reaction and adjusts pH value to 6, and is added and is received
Rice bentonite 1kg.
The product of embodiment 1-3 and the product of comparative example 1 are applied in capsicum field in conditions such as identical environment,
In 100kg/ mus of chilli seedling root application.Production is surveyed after being simultaneously stopped harvesting.
Table 1: result of implementation
| Fertilizer | Test process | Yield of hot pepper/kg/ mus |
| Embodiment 1 | 100kg/ mus of root application | 1953.26 |
| Embodiment 2 | 100kg/ mus of root application | 1979.32 |
| Embodiment 3 | 100kg/ mus of root application | 1927.38 |
| Comparative example 1 | 100kg/ mus of root application | 1620.46 |
| Blank | Common organic fertilizer | 1500.80 |
According to the disclosure and teachings of the above specification, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula is changed and is modified.Therefore, the invention is not limited to the specific embodiments disclosed and described above, to of the invention
Some modifications and changes should also be as falling into the scope of the claims of the present invention.In addition, although being used in this specification
Some specific terms, these terms are merely for convenience of description, does not limit the present invention in any way.
Claims (2)
1. a kind of preparation method of Carbon balance organic liquid fertilizer, it is characterised in that the following steps are included: being original with organic waste
1~2h of acid soak is added in material, then carries out resolution reaction, uses between ammonia water conditioning system pH to 6~8 after resolution reaction, then plus
Enter nano-synergistic agent；The resolution reaction carries out in the closed reactor of microwave irradiation, and the time is 3~20min, resolution reaction
Acid be the mixing of one or more of nitric acid, sulfuric acid, perchloric acid or hydrogen peroxide；The matter of the organic waste and acid
Amount is than being (10~1): 1, for acid concentration with pH meter for 2mol/L, microwave frequency is 300MHz~300GHz；The nanometer increases
Effect agent is the mixing of one or more of nano diatomite, nano-bentonite, nano silica, the nano-synergistic agent
Dosage be organic waste amount of substance 0.1~20%.
2. a kind of organic carbon fertilizer, which is characterized in that be with the preparation method system of Carbon balance organic liquid fertilizer described in claim 1
For what is obtained.
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| CN201510777279.9A CN105367227B (en) | 2014-11-15 | 2015-11-13 | A kind of preparation method of Carbon balance organic liquid fertilizer |
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| CN201410653468 | 2014-11-15 | ||
| CN2014106534680 | 2014-11-15 | ||
| CN201510777279.9A CN105367227B (en) | 2014-11-15 | 2015-11-13 | A kind of preparation method of Carbon balance organic liquid fertilizer |
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| CN105367227A CN105367227A (en) | 2016-03-02 |
| CN105367227B true CN105367227B (en) | 2018-12-18 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112225623A (en) * | 2020-11-26 | 2021-01-15 | 宁夏大学 | Nano modified water-soluble fertilizer and preparation method and application thereof |
| CN113943195A (en) * | 2021-10-08 | 2022-01-18 | 吉林化工学院 | Method for preparing organic carbon nutrient by using alcohol processing waste liquid |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1281835A (en) * | 2000-09-06 | 2001-01-31 | 南京农业大学 | Method for decomposing stalks and straws of crops and fertilizer made of them |
| CN1480430A (en) * | 2002-09-04 | 2004-03-10 | 莫志鸿 | Liquid fertilizer made from waste fluid of molasses and alcohol as well as its preparing method |
| CN101605739A (en) * | 2006-11-03 | 2009-12-16 | 种子生物科学私人有限公司 | The production of functionally effective organic molecules in the brown coal cracking |
| CN102503683A (en) * | 2011-10-28 | 2012-06-20 | 马鞍山科邦生态肥有限公司 | Efficient biological organic fertilizer and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040111161A (en) * | 2003-06-19 | 2004-12-31 | 간사이 페인트 가부시키가이샤 | Process for purifying waste water containing organic substances |
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- 2015-11-13 CN CN201510777279.9A patent/CN105367227B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1281835A (en) * | 2000-09-06 | 2001-01-31 | 南京农业大学 | Method for decomposing stalks and straws of crops and fertilizer made of them |
| CN1480430A (en) * | 2002-09-04 | 2004-03-10 | 莫志鸿 | Liquid fertilizer made from waste fluid of molasses and alcohol as well as its preparing method |
| CN101605739A (en) * | 2006-11-03 | 2009-12-16 | 种子生物科学私人有限公司 | The production of functionally effective organic molecules in the brown coal cracking |
| CN102503683A (en) * | 2011-10-28 | 2012-06-20 | 马鞍山科邦生态肥有限公司 | Efficient biological organic fertilizer and preparation method thereof |
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Effective date of registration: 20191115 Address after: 31st and 30th Floors, United Headquarters Building, 63 Xuefu Road, Nanshan High-tech Park, Shenzhen, Guangdong 518000 Co-patentee after: Guigang Batian Ecology Co.,Ltd. Patentee after: Batian Ecological Engineering Co., Ltd., Shenzhen Address before: 518057 Guangdong province Shenzhen city Nanshan District high tech park two Hing Road No. 10 Patentee before: Batian Ecological Engineering Co., Ltd., Shenzhen |
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