CN105237145B - A kind of humic acid plants growing nutrient high-performance solid fertilizer and preparation method thereof - Google Patents
A kind of humic acid plants growing nutrient high-performance solid fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN105237145B CN105237145B CN201510553347.3A CN201510553347A CN105237145B CN 105237145 B CN105237145 B CN 105237145B CN 201510553347 A CN201510553347 A CN 201510553347A CN 105237145 B CN105237145 B CN 105237145B
- Authority
- CN
- China
- Prior art keywords
- humic acid
- chinaberry
- aqueous solution
- parts
- solid fertilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses a kind of humic acid plants growing nutrient high-performance solid fertilizer, it includes that component is, humic acid sodium salt, urea, Diammonium phosphate (DAP), potassium sulfate, micronutrient element metal ion chelation agent, ammonium hydrogen carbonate, nonionic surface active agent, the mix preparation that chinaberry preparation or chinaberry and sea-buckthorn are mixed by any ratio, functional form auxiliary agent.The invention also discloses a kind of preparation method of solid fertilizer, the method for particularly having used intelligent pH controller and peristaltic pump to be combined control pH.
Description
Technical field
The present invention relates to fertilizer preparation fields, particularly, are related to a kind of dynamical vegetable solid fertilizer and its preparation side
Method, more specifically it relates to which a kind of high-efficiency multi-function containing metal ion chelation agent, nonionic surface active agent and Chinese medicine is solid
Body fertilizer and the preparation method based on intelligent pH control system.
Background technique
At present due to the fertilizer of the plants such as crops, vegetables, fruit tree be mainly based upon the mixed fertilizer of chemical fertilizer, multielement micro-fertilizer,
Solid special fertilizer.Such fertilizer is unfavorable for by the way that various microelements and macroelement are made through mechanical equipment stirring and processing
The operation in field, and easily cause and burn.Simultaneously as long-term a large amount of application chemical fertilizer, soil overall target is caused to decline,
Basicity raising, soil hardening, soil fertility weaken, and cause crop quality to decline, all kinds of fruit mouthfeels are bad；Harmful substance is in the soil
Retain (especially with greenhouse be very), the health of human body is directly affected after being absorbed by crops.Progress and people with modern science
Long term production, negative effect of the chemical fertilizer in terms of crop fertilization oneself confirmed by a variety of subjects.
In recent years, take much count of the production and application of humic acid solid fertilizer both at home and abroad.Humic acid solid fertilizer is from effect
With functionally, auxotype and functional form two major classes can be divided into.Auxotype humic acid solid fertilizer is by a large amount of, middle amount and micronutrient member
One of element or more than one elements are formulated, and main function is required for targeted offer and supplement plant growth
Nutrition；Functional form humic acid solid fertilizer is to be combined together the functional form of some additives and inorganic nutritive element supplement,
To have the function that a kind of to be mutually improved and promote.
One of natural type humic acid solid fertilizer function of dominant type humic acid fertilizer.Containing by different natural in such solid fertilizer
Substance is such as: seaweed, stalk, turf, the fermentation material or metabolin extracted in weathered coal deposit, such as amino acid, humic acid, sea
The substances such as alginic acid.These substances to crop have significant physiological regulatory action, such as stimulate plant growth, promote crop metabolism,
Improve crop itself anti-adversity etc..
Currently, the manufacturer of solid fertilizer containing humic acid is more, although formula is not quite similar, has and significantly increase income effect
Fruit.But there is also many technical problems for existing humic acid solid fertilizer:
1, the fertilizer product of solid containing humic acid in recent years, promoted in the market, there are its constituents to solve only crop
Nutrition problem, it is therefore prevented that the generation of nutritional deficiency disease, but lack the regulating power to plant growth, it is unable to the length of Effective Regulation crop
Gesture, the effect of increasing income are not significant enough.
2, there are also some humic acid solid fertilizers, although overcoming disadvantages mentioned above, it, which lacks, makees the chelating of metal ion
With so that the absorption rate of microelement is not high；Simultaneously as lacking drought resistance agent, falling for crop dry season growth not can solve
Flower, shedding problem.
3, the auxiliary exhibition of generally existing fertilizer is poor with penetrating power in solid fertilizer use, it is short in crop root part infiltrating time and
The problem of being unevenly distributed, reducing fertilization effect, cause fertilizer damage.Selection is seeped in domestic some humic acid solid fertilizers manufacturer
Saturating wetting agent has carried out the experiment that studies for a long period of time, but does not have big breakthrough on solving this key technical problem.Some solid fertilizers
The infiltration wetting agent selected in formula has JFC (alcohol ethoxylates), AES (fatty alcohol polyoxy hexene ether sulfuric ester
Sodium salt), citric acid or sodium citrate etc., some takes addition dodecyl benzene sulfonic acid (neutral soap), quality in solid fertilizer
The method of preferable wetting agent, penetration-assisting agent, reduces the surface tension of solution, increases the contact area with root.Though these methods
It plays a role, but effect is unobvious, affects the effect of fertilizer efficiency.
Summary of the invention
The first purpose of this invention is to provide a kind of humic acid plants growing nutrient high-performance solid fertilizer.
Second object of the present invention is to provide a kind of preparation method of humic acid plants growing nutrient high-performance solid fertilizer.
The first purpose of this invention is implemented by following technical solution, a kind of humic acid plants growing nutrient high-performance solid
Fertilizer comprising the component of following mass parts: 20~30 parts of humic acid sodium salt, 2~40 parts of urea, 4~40 parts of Diammonium phosphate (DAP), sulfuric acid
5~40 parts of potassium, 1~6 part of micronutrient element, 4~6 parts of ammonium hydrogen carbonate, 1~5 part of nonionic surface active agent, chinaberry water
Be mixed by any ratio 0.5~5 part of mixed aqueous solution, 0.01~1 part of functional form auxiliary agent of solution or chinaberry and sea-buckthorn.
The primary raw material of the humic acid sodium salt is the humic acid sodium salt containing fulvic acid 60%~90%, especially a kind of use
Peat rich in various plants humus extracts the humic acid sodium salt of fulvic acid containing high activity 70%~90% through chemical method.
The effect of the potassium sulfate predominantly promotes bearing fruit for plant.
The micronutrient element metal ion chelation agent is grouped part by following weight and is made: micronutrient element 1~6
Part, 0.1~0.5 part of the acid solution of pH=1,4~6 parts of ammonium hydrogen carbonate, ammonium hydrogen carbonate used herein is matched greatly with solid fertilizer
Ammonium hydrogen carbonate ingredient described in side exists side by side, and ammonium hydrogen carbonate described in the big formula of solid fertilizer is grown as humic acid plants to be sought
Support one of the constituent of macronutrient of high-performance solid fertilizer, ammonium hydrogen carbonate in micronutrient element metal ion chelation agent
Exist as the chelating body for generating micronutrient element metal ion chelation agent, enhancing plant is reinforced planting to the utilization rate of fertilizer
The disease resistance of object.
The micronutrient element is copper sulphate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, two
Any two or more in selenium oxide and borax presses the mixture of any ratio, and effect predominantly promotes plant growth.
The nonionic surface active agent is disodium edta, the compound of alkyl phenol polyoxyethylene ether, first
Any one in base phenylpropyl triazole or disecoctylmaleate sodium sulfonate.Its main function is to destroy plant root table
The vegetable wax in face improves plant to the utilization rate of fertilizer so that nutriment is more preferably absorbed by plants faster；Secondly, be pair
Plant root is destroyed biowax and is repaired.
The functional form auxiliary agent be mepiquat chloride, paclobutrazol, cycocel, sodium-para-nitrophenolate or α-methyl α-naphthyl acetate in any one or
More than one press the mixture of any ratio.Its main function is the growth for promoting plant, adjusts the growth of plant and inhibits harmful
The growth of plant.
Second object of the present invention is implemented by following technical solution, a kind of humic acid plants growing nutrient high-performance solid fertilizer
Preparation method comprising following steps: (1) prepare fulvic acid content 70% -90% humic acid sodium salt；(2) original is weighed
Material；(3) sodium humate saline solution is prepared；(4) humic acid sodium salt macronutrient aqueous solution is prepared；(5) micro battalion is prepared
Support metal element ion chelating agent；(6) chinaberry aqueous solution or chinaberry and sea-buckthorn mixed aqueous solution are prepared；(7) it is made rotten to plant
Acid plant growth nutrient efficient solid fertilizer.Wherein:
(1) prepare 70% -90% humic acid sodium salt of fulvic acid content: the peat that will be enriched in phytodet ritus is dried
Dry and crushing, partial size are 60~80 mesh, and with 30% dust technology acidified degradation, it is 1: 0.3 that coal acid, which compares, in the process；Reaction, acidification
Peat after degradation is added in reaction kettle water, and coal-water ratio example is 1: 4, particularly, is mutually tied by intelligent pH controller with peristaltic pump
Closing and adjusting the pH value of reaction solution is 10 ± 0.01, destroys in production process and retains fulvic acid to greatest extent while generating colloid
Activity, while activate process it is also higher to the accuracy requirement of the pH value of solution, if being reacted with general control method
Initial stage can influence production efficiency because neutralizer is added due to inadequate pH value rises too slow, and when close to the breakdown point of colloid
The excessive of neutralizer can be caused to be added because of reaction delay again, so that pH value is risen too many and overshoot is occurred, cause the activation of humic acid
Degree is bad.The use of intelligent pH controller and peristaltic pump is compared to traditional titration device because peristaltic pump is by variable-frequency motor
Driving so can perfectly be matched with the linear sense signal of pH controller during use, titration early period can be complete
Speed work improves production efficiency, and is linearly adjusted rate of titration automatically according to the signal of intelligent pH controller in the titration later period
Section avoids the generation of overshoot.Liquid precipitate is reacted after titration process, supernatants after precipitation centrifuge finally dries and fulvic acid is made
The humic acid sodium salt of content 70% -90%；
(2) it weighs raw material: weighing each raw material component by the formula of humic acid plants growing nutrient high-performance solid fertilizer, i.e., it is rotten to plant
20~30 parts of sour sodium, 2~40 parts of urea, 4~40 parts of Diammonium phosphate (DAP), 0~40 part of potassium sulfate, micronutrient element metal ion chela
1~6 part of mixture, 4~6 parts of ammonium hydrogen carbonate, 10~20 parts of nonionic surface active agent, 0.01~l parts of functional form auxiliary agent；China tree
Be mixed by any ratio 0.5~5 part of mix preparation of sub- preparation or chinaberry and sea-buckthorn；
(3) it prepares sodium humate saline solution: the weighed humic acid sodium salt being added to the water and is warming up to 60~70 DEG C,
Stirring is prepared the humic acid that mass concentration is 5~20% and urinates oxime aqueous solution to its dissolution；
(4) it prepares micronutrient element metal ion chelation agent: weighing 0.1~5 part of micronutrient element and ammonium hydrogen carbonate 4
~6 parts, the water that weighed micronutrient element pours into 1 part of addition in container is stirred, so that microelement all dissolves, is formed
Metal ion complex；
(5) load weighted Diammonium phosphate (DAP) and potassium sulfate, stirring 1~2 is added in humic acid sodium salt urine oxime aqueous solution
Hour dissolution, is made humic acid sodium salt macronutrient aqueous solution；
(6) chinaberry aqueous solution or chinaberry and sea-buckthorn mixed aqueous solution are prepared: weighing chinaberry or chinaberry and sea-buckthorn
Object is mixed by any ratio, after the weighed chinaberry or the chinaberry and the sea-buckthorn are crushed, the water logging at 100 DEG C
Bubble 10~50 minutes, is prepared chinaberry aqueous solution or chinaberry and sea-buckthorn mixed aqueous solution, it is water-soluble then to weigh chinaberry
Liquid or chinaberry and 0.5~5 part of sea-buckthorn mixed aqueous solution it is spare；
(7) humic acid plants growing nutrient high-performance solid fertilizer is made: by metal ion complex made from step (4), step
Suddenly humic acid sodium salt macronutrient aqueous solution made from (5) and the weighed chinaberry aqueous solution of step (6) or chinaberry and
Sea-buckthorn aqueous solution all mixes, and the weighed nonionic surfactant is added, is warming up to 60 DEG C~80 DEG C dissolutions, then adds
Add the weighed functional form auxiliary agent, be cooled to 50 DEG C of holding constant temperature to solution, humic acid is made by the method for vacuum distillation
Plant growth nutrient efficient solid fertilizer.
The primary raw material of the humic acid sodium salt be it is a kind of with rich in humus peat pass through based on intelligent pH controller with it is compacted
The humic acid sodium salt for the fulvic acid containing high activity 70%~90% that the chemical method of dynamic pump technology is extracted.
The micronutrient element is copper sulphate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, two
Any a variety of mixtures by any ratio in selenium oxide and borax.
The nonionic surfactant is disodium edta, the compound of alkyl phenol polyoxyethylene ether, methyl
Any one in phenylpropyl triazole or disecoctylmaleate sodium sulfonate.
The functional form auxiliary agent is mepiquat chloride, paclobutrazol, cycocel, sodium-para-nitrophenolate or α-methyl α-naphthyl acetate, any in DA -6
One or more press the mixture of any ratio.
It is an advantage of the current invention that humic acid used in (1) present invention, is to be with the peat rich in various plants humus
Raw material, such as the peat of Inner Mongol Tumote Left Banner, particularly, through being characteristic based on pH intelligent controller and peristaltic pump technology
Chemical method extracts the humic acid sodium salt containing fulvic acid 70%~90%.Due to fulvic acid content and work in this kind of humic acid sodium salt
Property be higher than the humic acid sodium salt that produce with other raw materials (such as weathered coal), and molecular weight is small, high to crop activity, with this kind corruption plant
Acid sodium-salt is that the humic acid plants growing nutrient solid fertilizer of main material production has more efficient, nontoxic, noresidue, wide spectrum etc.
The advantages that feature, applicable crops range is wide, wide using concentration range.It is widely used in cereal crops, industrial crops, vegetables, melon
Fruit, fruit tree, oil crops and flowers etc..
(2) present invention takes the method that nonionic surface active agent is added in solid fertilizer, breaks crop root part
Cutin wax layer reduces the surface tension of fertilizer solution, increases the contact area with crop root part, makes solution in crop root part
Upper extension generates uniform and stable liquid film, enhances the adhesive ability and penetrating power of solution, and crop root part is helped to absorb, and shows
It writes and increases and extend solution in the wetting time of most of crop root parts.Fertilizer damage can be effectively prevented, improve farming
Absorption efficiency 20% or more of the object to available nutrient.
(3) present invention takes a kind of addition Chinese medicine chinaberry, sand in humic acid plants growing nutrient high-performance solid fertilizer
Method of the spine as crop root part renovation agent solves and nonionic surface active agent solid fertilizer is added due to using, cause
The problem of crop root part cutin wax layer is broken, and plant growth is affected, repairs crop root part in time.
(4) present invention removes the heavy metal substance in humic acid by the method for a series of physics and chemistry, solves
Traditional humic acid solid fertilizer is because content of beary metal is excessively high, the case where causing soil heavy metal pollution.
(5) present invention, which takes, a kind of adds metal ion chelation agent in humic acid plants growing nutrient high-performance solid fertilizer
Method, enhancing crop absorb the ability of nutrient, so that the ion of micronutrient element is formed chelate, improve the absorption of microelement
Utilization rate, convenient for the absorption and utilization of plant.
The present invention is compared with the advantages of the prior art
Innovative slave peat extracts fulvic acid to this project at home.Particularly, in the Purification of fulvic acid
A kind of new technique for preparing fulvic acid from peat based on intelligent pH control technology is proposed for the characteristics of river silt, due to
The fulvic acid that the difference of raw material and the method for preparation produces this project has good activity, and activity is compared with patent
It is greatly improved used in foliar fertilizer from the humic acid that lignite purifies in CN102167635.It is wanted based on this kind of humic acid sodium salt
The humic acid plants growing nutrient solid fertilizer of raw material production has the characteristics that more efficient, nontoxic, noresidue, wide spectrum, is suitable for
The advantages that object range is wide, wide using concentration range.
Compared to foliar fertilizer in patent CN102167635, the solid fertilizer of this patent, which can rush, to be applied, because passing through plant
Root absorption can significantly improve crops to the absorptivity of fertilizer.This patent production fertilizer containing humic acid water-soluble because
Its humic acid excellent activity can improve the existence that soil environment is allowed to bacterium in more adapted soil, improve the utilization of fertilizer
Rate, while it is residual significantly to reduce agriculture, the final agricultural product that obtain substantially increase production.
Specific embodiment
Embodiment 1
Humic acid plants growing nutrient high-performance solid fertilizer for cucumber comprising the component of following mass parts: with Inner Mongol
The peat rich in various plants humus of ancient Tumote Left Banner, which is passed through, to be applied with intelligent pH control technology and peristaltic pump as core
20 parts of humic acid sodium salt of chemical method extraction fulvic acid containing high activity 70%~90%, 15 parts of urea, 10 parts of Diammonium phosphate (DAP), sulphur
30 parts of sour potassium, (its Meso- and micro-nutrients is sub- by copper sulphate, magnesium sulfate, sulfuric acid for 1 part of micronutrient element metal ion chelation agent
Iron, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, selenium dioxide and borax 1:1:1:1:1:1:1:1:1 ratio in mass ratio mix
Composition), 4 parts of ammonium hydrogen carbonate, 5 parts of nonionic surface active agent, 1 part of (wherein chinaberry of mix preparation of chinaberry and sea-buckthorn
Mixed with sea-buckthorn in 1:1 ratio), 0.4 part of functional aid (α-naphthaleneacidsodium).
The humic acid plants growing nutrient high-performance solid fertilizer of cucumber is prepared as follows:
(1) it weighs raw material: weighing each raw material component by above-mentioned formula；
(2) it prepares sodium humate saline solution: weighed humic acid sodium salt being added to the water and is warming up to 60 DEG C, stirring 4 is small
When dissolve, be prepared mass concentration be 5% sodium humate saline solution；
(3) it prepares humic acid sodium salt macronutrient aqueous solution: being added in sodium humate saline solution load weighted
Urea and Diammonium phosphate (DAP) stir 2 hours and dissolve, humic acid sodium salt macronutrient aqueous solution is made；
(4) it prepares micronutrient element metal ion chelation agent: being 3% with weighed ammonium hydrogen carbonate configuration quality concentration
Ammonium bicarbonate aqueous solution；By weighed copper sulphate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, dioxy
Change selenium and borax is mixed and stirred in the sulfuric acid solution for pouring into PH=1, so that microelement all dissolves, trace metal ion is made
Acid solution；By the ammonium bicarbonate aqueous solution prepared gradually pour into trace metal ion acid solution stirring formed metal from
Then as PH=3, remaining ammonium bicarbonate aqueous solution is added in sub- complex compound, micronutrient element metal ion-chelant is made
Agent；
(5) chinaberry and sea-buckthorn mixed aqueous solution are prepared: after weighed chinaberry and sea-buckthorn are crushed, being lauched at 100 DEG C
It impregnates 50 minutes, chinaberry and sea-buckthorn mixed aqueous solution is prepared；
(6) humic acid plants growing nutrient high-efficiency foliage fertilizer is made: by a large amount of nutrition of humic acid sodium salt made from step (3)
Element aqueous solution, chinaberry and sea-buckthorn made from micronutrient element metal ion chelation agent made from step (4) and step (5)
Aqueous solution all mixes, and weighed nonionic surfactant is added, is warming up to 60 DEG C~80 DEG C dissolutions, and then addition weighs
Functional form auxiliary agent, be cooled to 50 DEG C of holding constant temperature to solution, the humic acid for cucumber be made by the method for vacuum distillation
Plant growth nutrient efficient solid fertilizer.
This contains humic acid solid fertilizer there are two types of application method, and one kind being used as base fertilizer for 60Kg/ mus, and another kind is 1OKg/
Mu pours with water and is used as top dressing.For the humic acid plants growing nutrient high-performance solid fertilizer of cucumber, plant absorption can be promoted, inhaled
Rate of producing effects improves.It can promote rhizome portion prosperity, rapidly, leaf color is dark green for growth, and blade face is plump, and toughness enhancing, increase bears fruit, improves
Quality.Crop yield rate reaches 25% or more.
Humic acid solid fertilizer and humic acid foliar fertilizer comparative test: test executable unit is that Huhehaote vegetables technology pushes away
Wide station, variety of crops are " saliva spring No. two " cucumber, are experimental field many years planting vegetable lands used, and soil property is sandy loam, soil fertilizer
Fertile, land fertility difference is small.0.8 ten thousand kilograms or so of sheep dung is applied in greenhouse per acre, and 60Kg/ mus of humic acid solid fertilizers make base fertilizer,
Cucumber top dressing 14 times during the growth process, wherein secondary is humic acid solid fertilizer, 10 kgs/acre every time, remaining is di(2-ethylhexyl)phosphate
Ammonium, each 15-20 pounds/acre.
Test result and analysis: specific processing is as follows: in seedling stage two leaves wholeheartedly when rush apply humic acid solid fertilizer for the first time
Top dressing, humic acid solid fertilizer top dressing is applied in second of punching after being colonized slow seedling, and fruiting period applies Diammonium phosphate (DAP) top dressing, 10 days left sides with water punching
It is right primary, until having harvested.Entire test sets two controls, and CK I is sprayed containing humic acid foliar fertilizer, and II Routine control of CK, which is not done, to be located
Reason, management routinely manage.
Humic acid solid fertilizer has apparent facilitation, the plant growth phenological period of test process to trial crops kind
It is obvious to do sth. in advance, it is shown in Table 1
1 plant growth phenological period of table application form
Cucumber growth can do sth. in advance 4-6 days, and plant growing way is better than check plot when uprooting plants after their edible portions have been harvested.
Humic acid solid fertilizer also has apparent influence to the botanical characteristics of experiment crop varieties, and concrete outcome is shown in Table 2
2 crop plants characteristic survey table of table (unit: centimetre)
Trial crops after top dressing, begin to obvious greening, growth potential enhancing for three days in seedling stage.Cucumber shows as morning of blooming,
It is early to tie melon, sugar-preserved gourd growth is fast, and picking is primary every three days for control, can pick within treated every 2.5 days, then the too big market of long melon
After processing, barbed sugar-preserved gourd thorn becomes apparent from, it appears melon is fresher for bad sale, especially cucumber.
Humic acid fertilizer has a significant effect to the yield of trial crops, is shown in Table 3
3 crop yield application form of table (unit: kilogram)
4 table of table, 3 test data the results of analysis of variance
From the aspect of 3 yield of table, 480.7 kilograms of average cell production of cucumber processing, 8907.4 kilograms of per mu yield is converted into,
It is the 121.85% of I yield of CK, is the 125.92% of II yield of CK, treatment region is that amount of increase in production is highest.From test result point
Analysis, II yield difference of CK I and CK is unobvious, and treated crop yield is horizontal significant, and amount of increase in production is in 21.85%-
25.92%.The effect that the crop for imposing solid humic acid fertilizer increases economic benefit than check plot becomes apparent from, in addition, top dressing
The crop product commodity of humic acid fertilizer is more preferable, and per kilogram, which can be sold more, sells 0.1-0.3 member, and can increase a part of benefit, because
This its amplitude for increasing economic benefit is in 20%-30%.
Embodiment 2
Humic acid plants growing nutrient high-efficiency foliage fertilizer for potato comprising the component of following mass parts: within
The peat rich in various plants humus of Mongolian Tumote Left Banner, which is passed through, to be applied with intelligent pH control technology and peristaltic pump as core
Chemical method extract 30 parts of humic acid sodium salt of fulvic acid containing high activity 70%~90%, 30 parts of urea, 6 parts of Diammonium phosphate (DAP),
10 parts of potassium sulfate, (its Meso- and micro-nutrients is by copper sulphate, magnesium sulfate, sulfuric acid for 5 parts of micronutrient element metal ion chelation agent
Ferrous iron, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid and borax are 1:1:5:5:1:1:1:1 ratio mixing composition in mass ratio), carbon
6 parts of sour hydrogen ammonium, 5 parts of nonionic surface active agent, 5 parts of the mix preparation of chinaberry and sea-buckthorn (wherein press by chinaberry and sea-buckthorn
Mass ratio is the mixing of 3:7 ratio), 1 part of functional form auxiliary agent (being in mass ratio 1:4 mixing by mepiquat chloride and paclobutrazol).
Humic acid plants growing nutrient high-performance solid fertilizer for potato is prepared as follows:
(1) it weighs raw material: weighing each raw material component by above-mentioned formula；
(2) it prepares sodium humate saline solution: weighed humic acid sodium salt being added to the water and is warming up to 60 DEG C, stirring 4 is small
When dissolve, be prepared mass concentration be 10% sodium humate saline solution；
(3) it prepares humic acid sodium salt macronutrient aqueous solution: being added in sodium humate saline solution load weighted
Urea and Diammonium phosphate (DAP) stir 2 hours and dissolve, humic acid sodium salt macronutrient aqueous solution is made；
(4) it prepares micronutrient element metal ion chelation agent: being 3% with weighed ammonium hydrogen carbonate configuration quality concentration
Ammonium bicarbonate aqueous solution；By weighed copper sulphate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid and borax
It mixes and is stirred in the hydrochloric acid solution for pouring into PH=1, so that microelement all dissolves, trace metal ion acid solution is made；
The ammonium bicarbonate aqueous solution prepared is gradually poured into stirring in trace metal ion acid solution and forms metal ion complex,
Then, as PH=3, remaining ammonium bicarbonate aqueous solution is added, micronutrient element metal ion chelation agent is made；
(5) chinaberry and sea-buckthorn mixed aqueous solution are prepared: after weighed chinaberry and sea-buckthorn are crushed, being lauched at 100 DEG C
It impregnates 50 minutes, chinaberry and sea-buckthorn mixed aqueous solution is prepared；
(6) humic acid plants growing nutrient high-performance solid fertilizer is made: by a large amount of nutrition of humic acid sodium salt made from step (3)
Element aqueous solution, chinaberry and sea-buckthorn made from micronutrient element metal ion chelation agent made from step (4) and step (5)
Aqueous solution all mixes, and weighed nonionic surface active agent is added, is warming up to 95 DEG C of dissolutions, then adds weighed function
Type auxiliary agent is cooled to 50 DEG C of holding constant temperature to solution, the humic acid plants for potato is made by the method for vacuum distillation
Growing nutrient high-performance solid fertilizer.
For the humic acid plants growing nutrient high-performance solid fertilizer of potato, plant absorption can be promoted, absorption efficiency mentions
It is high.Setting percentage can be increased, fruit is uniform greatly, and quality is good.Crop yield rate reaches 30% or more.
Humic acid solid fertilizer and humic acid foliar fertilizer comparative test: test executable unit is Heilongjiang Province's clay fertilizer station, agriculture
Crop varieties are " jute gives " potato, and experimental field soil types is black earth, and the soil texture is viscous earth, the content of organic matter
29.236g/kg, full nitrogen 1.419g/kg, alkali-hydrolyzable nitrogen 138.7mg/kg, available phosphorus 38.8mg/kg, available potassium 151.5mg/kg,
PH6.9, preceding crop: corn.Specific processing is as follows: (mu applies Diammonium phosphate (DAP) 55Kg+ potassium sulfate 25Kg+ urea to conventional fertilizer application
25Kg)+and humic acid solid fertilizer 30Kg is used per acre, make base fertilizer use, after the neat seedling of potato and 2 corruption are applied in the punching of rhizome expanding stage
Phytic acid solid fertilizer, each 1OKg.Entire test sets a check plot, and management, which is routinely managed+used per acre, contains humic acid foliar fertilizer
It sprays twice, after the neat seedling of potato and rhizome expanding stage sprays 2 times containing humic acid foliar fertilizer.
Humic acid solid fertilizer has apparent facilitation, the plant growth phenological period of test process to trial crops kind
It is obvious to do sth. in advance, illustrate that solid fertilizer containing humic acid has the effect of potato to promote growing process.It is shown in Table 5
5 plant growth phenological period of table application form unit: the moon, day
Found out by potato biological character application form: treatment region is 3.6cm higher than check plot plant height in plant height, in block
Compare treatment region on stem counterpoise than check plot weight 16g, shows that solid fertilizer containing humic acid has potato and increase plant height, increase
The effect of stem tuber weight.It is shown in Table 6
6 potato biological character application form unit of table: cm, m2, g, %
| Processing | Plant height | Density | Stem tuber counterpoise |
| Treatment region | 52.7 | 5.5 | 199 |
| Check plot | 49.1 | 5.5 | 183 |
Compare treatment region in yield than check plot mu volume increase 222.9kg, volume increase 10.2%, i.e. potato application is planted containing rotten
Sour solid fertilizer obvious effect of increasing production.It is shown in Table 7
7 yield result list position of table: Kg/ plants, Kg, %
Solid fertilizer containing humic acid has the effect of potato to promote growing process relative to humic acid foliar fertilizer is contained:
It potato prematurity 3 days, early goes public 3 days, the increase yield significantly on potato, volume increase 20.4%.
Claims (5)
1. a kind of humic acid plants growing nutrient high-performance solid fertilizer, which is characterized in that it includes the component of following mass parts: rotten
20~30 parts of phytic acid sodium salt, 2~40 parts of urea, 4~40 parts of Diammonium phosphate (DAP), 5~40 parts of potassium sulfate, micronutrient element 1~6
Part, 4~6 parts of ammonium hydrogen carbonate, 1~5 part of nonionic surface active agent, chinaberry aqueous solution or chinaberry and sea-buckthorn press any ratio
0.5~5 part of mixed mixed aqueous solution, 0.01~1 part of functional form auxiliary agent；
Preparation method includes the following steps:
(1) the humic acid sodium salt of fulvic acid content 70%-90% is prepared；(2) raw material is weighed；(3) oxime water is urinated with preparing humic acid
Solution；(4) micronutrient element metal ion chelation agent is prepared；(5) humic acid sodium salt macronutrient aqueous solution is prepared；
(6) chinaberry aqueous solution or chinaberry and sea-buckthorn mixed aqueous solution are prepared；(7) humic acid plants growing nutrient high-performance solid is made
Fertilizer；
Wherein:
(1) prepare fulvic acid content 70%-90% humic acid sodium salt: will be enriched in phytodet ritus peat carry out drying with
It crushes, partial size is 60~80 mesh, and with 30% dust technology acidified degradation, it is 1: 0.3 that coal acid, which compares, in the process；Reaction, acidified degradation
Peat afterwards is added in reaction kettle water, and coal-water ratio example is 1: 4, and the pH value for controlling reaction solution is 10 ± 0.01, destroys production process
The activity for retaining fulvic acid while middle generation colloid to greatest extent, to reaction liquid precipitate, supernatants after precipitation is centrifuged, finally
Dry the humic acid sodium salt that fulvic acid content 70%-90% is made；
The pH of control reaction solution is that realization is used in combination by intelligent pH controller and peristaltic pump；
(2) it weighs raw material: weighing each raw material component, i.e. sodium humate by the formula of humic acid plants growing nutrient high-performance solid fertilizer
20~30 parts of salt, 2~40 parts of urea, 4~40 parts of Diammonium phosphate (DAP), 5~40 parts of potassium sulfate, 1~6 part of micronutrient element, carbonic acid
4~6 parts of hydrogen ammonium, 1~5 part of nonionic surface active agent, 0.01~1 part of functional form auxiliary agent；Chinaberry aqueous solution or chinaberry
0.5~5 part of the mixed aqueous solution being mixed by any ratio with sea-buckthorn；
(3) oxime aqueous solution is urinated with preparing humic acid: the weighed humic acid sodium salt and urea being added to the water and are warming up to 60~70
DEG C, stirring is prepared the humic acid that mass concentration is 5~20% and urinates oxime aqueous solution to its dissolution；
(4) it prepares micronutrient element metal ion chelation agent: weighing 1~6 part and 4~6 parts of ammonium hydrogen carbonate of micronutrient element,
Weighed micronutrient element is poured into 0.1~0.5 part of acid solution stirring of the water and pH=1 of 1 part of addition in container, so that
Microelement all dissolves, and forms micronutrient element metal ion chelation agent；
(5) load weighted Diammonium phosphate (DAP) and potassium sulfate is added in humic acid sodium salt urine oxime aqueous solution, stirs 1~2 hour
Humic acid sodium salt macronutrient aqueous solution is made in dissolution；
(6) chinaberry aqueous solution or chinaberry and sea-buckthorn mixed aqueous solution are prepared: weighing chinaberry or chinaberry and sea-buckthorn by appointing
Meaning is lauched immersion 10 at 100 DEG C after crushing the weighed chinaberry or the chinaberry and the sea-buckthorn than mixture
~50 minutes, chinaberry aqueous solution or chinaberry and sea-buckthorn mixed aqueous solution is prepared, then weigh chinaberry aqueous solution or
Chinaberry and 0.5~5 part of sea-buckthorn mixed aqueous solution it is spare；
(7) humic acid plants growing nutrient high-performance solid fertilizer is made: by micronutrient element metal ion chela made from step (4)
Mixture, humic acid sodium salt macronutrient aqueous solution and the weighed chinaberry aqueous solution of step (6) made from step (5), or
Chinaberry and sea-buckthorn aqueous solution all mix, and the weighed nonionic surface active agent is added, is warming up to 60 DEG C~80 DEG C
Dissolution, then adds the weighed functional form auxiliary agent, is cooled to 50 DEG C of holding constant temperature to solution, passes through the method for vacuum distillation
Humic acid plants growing nutrient high-performance solid fertilizer is made.
2. a kind of humic acid plants growing nutrient high-performance solid fertilizer according to claim 1, which is characterized in that described micro
Nutrient metal ion chelation agent is grouped part by following weight and is made: 1~6 part of micronutrient element, the acid solution of pH=1
0.1~0.5 part, 4~6 parts of ammonium hydrogen carbonate.
3. a kind of humic acid plants growing nutrient high-performance solid fertilizer according to claim 2, which is characterized in that described micro
Nutrient is in copper sulphate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, selenium dioxide and borax
Any one or more mixture in any proportion.
4. a kind of humic acid plants growing nutrient high-performance solid fertilizer according to claim 1, which is characterized in that it is described it is non-from
Subtype surfactant is disodium edta, the compound of alkyl phenol polyoxyethylene ether, methyl phenylpropyl triazole, suitable fourth
Any one in enedioic acid di-sec-octyl sodium sulfonate.
5. a kind of humic acid plants growing nutrient high-performance solid fertilizer according to claim 1, which is characterized in that the function
Type auxiliary agent is any one or more than one by any in mepiquat chloride, paclobutrazol, cycocel, compound sodium nitrophenolate or α-naphthaleneacidsodium
The mixture of ratio.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510553347.3A CN105237145B (en) | 2015-09-01 | 2015-09-01 | A kind of humic acid plants growing nutrient high-performance solid fertilizer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510553347.3A CN105237145B (en) | 2015-09-01 | 2015-09-01 | A kind of humic acid plants growing nutrient high-performance solid fertilizer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105237145A CN105237145A (en) | 2016-01-13 |
| CN105237145B true CN105237145B (en) | 2019-03-19 |
Family
ID=55035022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510553347.3A Active CN105237145B (en) | 2015-09-01 | 2015-09-01 | A kind of humic acid plants growing nutrient high-performance solid fertilizer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105237145B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106045688A (en) * | 2016-06-01 | 2016-10-26 | 卞佳林 | Preparation method of humic acid compound fertilizer |
| CN106748110A (en) * | 2016-12-15 | 2017-05-31 | 岑溪市安安农业科技发展有限公司 | The preparation method of humic acid potassium |
| CN108911916A (en) * | 2018-08-01 | 2018-11-30 | 芜湖三月禾园艺设计有限公司 | A kind of flowers cladding humic acid biology base manure and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060632A (en) * | 2010-11-19 | 2011-05-18 | 孟献堡 | Method for preparing multielement organic fertilizer by spontaneous fermentation of active humic acid |
| CN102167635A (en) * | 2010-12-31 | 2011-08-31 | 莫日根 | Nutritious and high efficient foliar fertilizer for growth of humic acid plant and preparation method thereof |
| CN102503682A (en) * | 2011-10-28 | 2012-06-20 | 马鞍山科邦生态肥有限公司 | Crop organic fertilizer and preparation method thereof |
| CN102701855A (en) * | 2012-06-13 | 2012-10-03 | 方宁 | Fertilizer produced by using coal special for improving humic acid salt licks |
| CN103497220A (en) * | 2013-10-21 | 2014-01-08 | 张京三 | Production technology of sodium humate |
| CN103588977A (en) * | 2013-11-08 | 2014-02-19 | 云南联合药业有限责任公司 | Method for extracting and preparing peat fulvic acid and drug application |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6884756B2 (en) * | 2001-09-14 | 2005-04-26 | The Andersons Agriservices, Inc. | Water-dispersible pellets |
-
2015
- 2015-09-01 CN CN201510553347.3A patent/CN105237145B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060632A (en) * | 2010-11-19 | 2011-05-18 | 孟献堡 | Method for preparing multielement organic fertilizer by spontaneous fermentation of active humic acid |
| CN102167635A (en) * | 2010-12-31 | 2011-08-31 | 莫日根 | Nutritious and high efficient foliar fertilizer for growth of humic acid plant and preparation method thereof |
| CN102503682A (en) * | 2011-10-28 | 2012-06-20 | 马鞍山科邦生态肥有限公司 | Crop organic fertilizer and preparation method thereof |
| CN102701855A (en) * | 2012-06-13 | 2012-10-03 | 方宁 | Fertilizer produced by using coal special for improving humic acid salt licks |
| CN103497220A (en) * | 2013-10-21 | 2014-01-08 | 张京三 | Production technology of sodium humate |
| CN103588977A (en) * | 2013-11-08 | 2014-02-19 | 云南联合药业有限责任公司 | Method for extracting and preparing peat fulvic acid and drug application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105237145A (en) | 2016-01-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102167635B (en) | Nutritious and high efficient foliar fertilizer for growth of humic acid plant and preparation method thereof | |
| Akpan-Idiok et al. | The use of human urine as an organic fertilizer in the production of okra (Abelmoschus esculentus) in South Eastern Nigeria | |
| CN102391052B (en) | Kiwi fruit special fertilizer | |
| CN102863277A (en) | Production method of dual-acid chelating organic-inorganic composite fertilizer | |
| CN105210606A (en) | The implantation methods of one grow wheat | |
| CN104909872A (en) | Fertilizer used for pawpaw plantation | |
| CN102511350A (en) | Apple rich in organic selenium and production method thereof | |
| CN104591823B (en) | The method that one planting fruit-trees applies trace-element fertilizer | |
| CN110436980A (en) | A kind of Queensland nut special complex fertilizer and its set meal fertilizer and fertilizing method | |
| CN104276884A (en) | Rosa chinensis planting fertilizer prepared by oil residue fermentation and preparation method thereof | |
| CN105237145B (en) | A kind of humic acid plants growing nutrient high-performance solid fertilizer and preparation method thereof | |
| Small et al. | The fate of compost-derived phosphorus in urban gardens | |
| CN103833440A (en) | Walnut tree composite nutrition top dressing and preparation method thereof | |
| CN102771298A (en) | High-selenium wheat and production method thereof | |
| CN102511349A (en) | Jujube rich in organic selenium and production method thereof | |
| CN105924250A (en) | Nitrogen phosphorus and potassium compound fertilizer with high pH value and preparing method of nitrogen phosphorus and potassium compound fertilizer | |
| CN107827583A (en) | A kind of special humic acid Water soluble fertilizer of beans and preparation method thereof and application method | |
| CN104098408B (en) | A kind of cultural method of leaf vegetables | |
| CN106538111A (en) | A kind of prevention and controls of Bulbus Allii continuous cropping disease | |
| CN109354543A (en) | A kind of water-soluble nano charcoal base manure and its preparation method and application | |
| CN107827650A (en) | One kind of special fertilizer for peanut and preparation method thereof | |
| CN103787770A (en) | Zinc-rich nutrient for rice, preparation method thereof and method for producing zinc-rich rice with nutrient | |
| CN102630424B (en) | Fertilizing method for inhibiting continuous cropping diseases of Chinese cabbage in north cool areas | |
| Ottman | Alfalfa Nutrient Reguirements, Defisiency Symptoms, and Fertilizer Application | |
| CN105461447A (en) | Special fertilizer for increasing rose flower fragrance and application of special fertilizer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210118 Address after: No.372, shanqiandian village, shanqiandian Town, Laiyang City, Yantai City, Shandong Province, 265210 Patentee after: Tang Chunyu Address before: 010021 room 901, No.37, zone 4, Qingcheng lane, Xincheng District, Hohhot City, Inner Mongolia Autonomous Region Patentee before: Mo Rigen |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230420 Address after: No. 18 Haihe Road, Laiyang City, Yantai City, Shandong Province, 265200 Patentee after: Shandong Di nanny Agricultural Technology Co.,Ltd. Address before: No.372, shanqiandian village, shanqiandian Town, Laiyang City, Yantai City, Shandong Province, 265210 Patentee before: Tang Chunyu |
|
| TR01 | Transfer of patent right |