CN105153956A - Stretching adhesive tape - Google Patents
Stretching adhesive tape Download PDFInfo
- Publication number
- CN105153956A CN105153956A CN201510575086.5A CN201510575086A CN105153956A CN 105153956 A CN105153956 A CN 105153956A CN 201510575086 A CN201510575086 A CN 201510575086A CN 105153956 A CN105153956 A CN 105153956A
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- layer
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- aging agent
- rubber
- tackiness agent
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- Adhesive Tapes (AREA)
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Abstract
The invention relates to a stretching adhesive tape sequentially comprising an isolation layer, an adhesive layer A, an adhesive layer B, an adhesive layer C from top to bottom, wherein the release force of the isolation layer is 5-100g; the adhesive layer A comprises the following components in percentage by weight: 30-50% of synthetic rubber elastomers and 30-50% of tackifying resin; the adhesive layer B comprises the following components in percentage by weight: 30-50% of SIS rubber, 30-50% of butyl rubber, 1-3% of an accelerant, 1-4% of a coupling agent, 1-3% of an anti-aging agent and 1-10% of lithopone; and the adhesive layer C comprises the following components in percentage by weight: 30-50% of synthetic rubber elastomers and 30-50% of tackifying resin. The stretching adhesive tape has extremely good cohesive strength and stretchability and also has portability and temperature resistance; and when being stripped after being adhered to an adhered object, the stretching adhesive tape can be wholly stripped by only stretching one end of the adhesive tape, and the phenomena of adhesive residues on the surface of the adhered object and stripping difficulty are avoided.
Description
Technical field
The present invention relates to a kind of stretch tape.
Background technology
Adhesive tape is made up of base material and binding agent two portions, by bonding, two or more disjunct object is linked together, it scribbles one deck tackiness agent on the surface, tackiness agent is the earliest from animal and plant, at 19th-century, rubber is the major ingredient of tackiness agent, and the modern times are the various polymkeric substance of widespread use then.Tackiness agent can cling thing, is that this bond can stick together molecule firmly due to the molecule of itself and the intermolecular formation bond for attachment.Although adhesive tape is convenient to two object bondings, made troubles also can to during current used adhesive tape us, namely when tearing adhesive tape off, adhesive tape cannot be peeled off completely, can leave cull on affixed object surface and there is the phenomenon being difficult to peel off.
Summary of the invention
The object of this invention is to provide a kind of stretch tape, it has fabulous cohesive strength and stretchiness, has high movable and temperature tolerance simultaneously, and when peeling off, affixed object surface can not be left cull and there is the difficult phenomenon peeled off.
To achieve these goals, the technical solution adopted in the present invention is as follows: a kind of stretch tape, comprise sealing coat, tackiness agent A layer, tackiness agent B layer and tackiness agent C layer from top to bottom successively, the off-type force of wherein said sealing coat is 5 ~ 100g, and described tackiness agent A layer comprises the synthetic rubber elastomerics of 30 ~ 50% and the tackifying resin of 30 ~ 50% according to weight percent; Described tackiness agent B layer according to weight percent comprise 30 ~ 50% SIS rubber, 30 ~ 50% isoprene-isobutylene rubber, 1 ~ 3% promotor, the coupling agent of 1 ~ 4%, the anti-aging agent of 1 ~ 3% and 1 ~ 10% zinc sulfide white; Described tackiness agent C layer comprises the synthetic rubber elastomerics of 30 ~ 50% and the tackifying resin of 30 ~ 50% according to weight percent.
Further, the off-type force of described sealing coat is 10 ~ 30g.
Further, described sealing coat is two-sided separate-type paper or release film.
Further, described sealing coat is polyethylene release film or polyethylene terephthalate release film.
Further, described synthetic rubber elastomerics according to weight percent comprise the styrene-butadiene rubber(SBR) of 3 ~ 8%, the SIS rubber of 30 ~ 40% and 2 ~ 5% SBS rubber; Described tackifying resin is at least one in terpene phenolic resin, C5 petroleum resin, C5/C9 petroleum resin, synthesis C5/C9 petroleum resin, esterase.
Further, described tackiness agent A layer also comprises the anti-aging agent of 1 ~ 5% and the Rubber Softener of 3 ~ 8% according to weight percent, and described anti-aging agent comprises the first anti-aging agent and the second anti-aging agent, and described first anti-aging agent is dibutylcarbamate; Described second anti-aging agent is 2,6 ditertiary butyl p cresol; The weight ratio of described first anti-aging agent and the second anti-aging agent is 1 ~ 5:1; Described Rubber Softener is at least one in white oil, liquid polyisobutene, liquid nitrile rubber.
Further, described tackiness agent C layer also comprises the anti-aging agent of 1 ~ 5% and the Rubber Softener of 3 ~ 8% according to weight percent, and described anti-aging agent comprises the first anti-aging agent and the second anti-aging agent, and described first anti-aging agent is dibutylcarbamate; Described second anti-aging agent is 2,6 ditertiary butyl p cresol; The weight ratio of described first anti-aging agent and the second anti-aging agent is 1 ~ 5:1; Described Rubber Softener is at least one in white oil, liquid polyisobutene, liquid nitrile rubber.
Further, described promotor is zinc dibutyl dithiocarbamate; Described coupling agent is silane coupling agent; Described anti-aging agent is one or both in dibutylcarbamate, 2,6 ditertiary butyl p cresol; Described zinc sulfide white is the mixture of zinc sulphide and barium sulfate.
Further, described stretch tape total thickness is 30 ~ 1500um.
Further, the thickness of described tackiness agent A layer is 5 ~ 500um, and the thickness of described tackiness agent B layer is 20 ~ 500um, and the thickness of described tackiness agent C layer is 5 ~ 500um.
By such scheme, the present invention at least has the following advantages: stretch tape of the present invention has fabulous cohesive strength and stretchiness, there is high movable and temperature tolerance simultaneously, fit when peeling off again after affixed object, only need stretch along one end of adhesive tape, this stretch tape just can be stripped down by complete, and affixed object surface can not be left cull and there is the difficult phenomenon peeled off.
Above-mentioned explanation is only the general introduction of technical solution of the present invention, in order to better understand technique means of the present invention, and can be implemented according to the content of specification sheets, coordinates accompanying drawing to be described in detail as follows below with preferred embodiment of the present invention.
Accompanying drawing explanation
Fig. 1 is the structural representation of stretch tape in one embodiment of the invention.
Embodiment
Below in conjunction with drawings and Examples, the specific embodiment of the present invention is described in further detail.Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Refer to Fig. 1, stretch tape of the present invention comprises sealing coat 1, tackiness agent A layer 2, tackiness agent B layer 3 and tackiness agent C layer 4 from top to bottom successively, described stretch tape total thickness is 30 ~ 1500um, the thickness of wherein said tackiness agent A layer 2 is 5 ~ 500um, the thickness of described tackiness agent B layer 3 is 20 ~ 500um, and the thickness of described tackiness agent C layer 4 is 5 ~ 500um.Preferably, the thickness of described tackiness agent A layer 2 is 30 ~ 100um, and the thickness of described tackiness agent B layer 3 is 30 ~ 200um, and the thickness of described tackiness agent C layer 4 is 30 ~ 1500um.Because this stretch tape has certain thickness, make this stretch tape have the buffering effect of foam adhesive tape, can be used for frame laminating and sealing.The off-type force of described sealing coat 1 is 5 ~ 100g, and the off-type force of described sealing coat 1 is preferred 10-30g.Described sealing coat 1 is two-sided separate-type paper or release film, and described sealing coat 1 is polyethylene release film or polyethylene terephthalate release film.
Described tackiness agent A layer 2 comprises the synthetic rubber elastomerics of 30 ~ 50% and the tackifying resin of 30 ~ 50% according to weight percent.Synthetic rubber elastomerics in described tackiness agent A layer 2 according to weight percent comprise the styrene-butadiene rubber(SBR) of 3 ~ 8%, the SIS rubber of 30 ~ 40% and 2 ~ 5% SBS rubber; Tackifying resin in described tackiness agent A layer 2 is at least one in terpene phenolic resin, C5 petroleum resin, C5/C9 petroleum resin, synthesis C5/C9 petroleum resin, esterase.Described tackiness agent A layer 2 also comprises the anti-aging agent of 1 ~ 5% and the Rubber Softener of 3 ~ 8% according to weight percent, and described anti-aging agent comprises the first anti-aging agent and the second anti-aging agent; Described first anti-aging agent is dibutylcarbamate; Described second anti-aging agent is 2,6 ditertiary butyl p cresol, and the weight ratio of described first anti-aging agent and the second anti-aging agent is 1 ~ 5:1; Described Rubber Softener is at least one in white oil, liquid polyisobutene, liquid nitrile rubber.The preferred liquid nitrile rubber of this Rubber Softener, it is in certain ratio, can good softened rubber elastomerics and do not affect the force of cohesion of glue.
Described tackiness agent B layer 3 according to weight percent comprise 30 ~ 50% SIS rubber, 30 ~ 50% isoprene-isobutylene rubber, 1 ~ 3% promotor, the coupling agent of 1 ~ 4%, the anti-aging agent of 1 ~ 3% and 1 ~ 10% zinc sulfide white, wherein, the cohesive strength that SIS rubber can provide base membrane layer enough and tensile strength, paracril has good chemical stability and light stability while providing cohesive strength and tensile strength, and there is good resistance to air loss and watertightness, can also heat-resisting, resistance to ozone, ageing-resistant, chemical-resistant resistance, and there is shock-absorbing and electrical insulating property.Described promotor is zinc dibutyl dithiocarbamate; Described coupling agent is silane coupling agent; Described anti-aging agent is one or both in dibutylcarbamate, 2,6 ditertiary butyl p cresol; Described zinc sulfide white is the mixture of zinc sulphide and barium sulfate, its white crystalline powder, strong covering power, uses as tackiness agent filler usually, can increase adhesive tape shielding and can be effectively cost-saving, to the temperature tolerance of adhesive tape and with face glue be combined with certain promoter action.
Described tackiness agent C layer 4 comprises the content of the synthetic rubber elastomerics of 30 ~ 50% and the tackifying resin of 30 ~ 50% according to weight percent.Synthetic rubber elastomerics in described tackiness agent C layer 4 according to weight percent comprise the styrene-butadiene rubber(SBR) of 3 ~ 8%, the SIS rubber of 30 ~ 40% and 2 ~ 5% SBS rubber; Tackifying resin in described tackiness agent C layer 4 is at least one in terpene phenolic resin, C5 petroleum resin, C5/C9 petroleum resin, synthesis C5/C9 petroleum resin, esterase.Described tackiness agent C layer 4 also comprises the anti-aging agent of 1 ~ 5% and the Rubber Softener of 3 ~ 8% according to weight percent, and described anti-aging agent comprises the first anti-aging agent and the second anti-aging agent; Described first anti-aging agent is dibutylcarbamate; Described second anti-aging agent is 2,6 ditertiary butyl p cresol, and the weight ratio of described first anti-aging agent and the second anti-aging agent is 1 ~ 5:1; Described Rubber Softener is at least one in white oil, liquid polyisobutene, liquid nitrile rubber.The preferred liquid nitrile rubber of this Rubber Softener, it is in certain ratio, can good softened rubber elastomerics and do not affect the force of cohesion of glue.
Above-mentioned tackiness agent A layer 2 can be identical with tackiness agent C layer 4, also can be different, and described tackiness agent A layer 2, tackiness agent B layer 3 and tackiness agent C layer 4 can be made into solvent-borne type glue, and coating method can be directly to be scraped or shifts gluing, also can be made into hot-melting type, extrusion coated.
Below by embodiment, above-mentioned stretch tape is specifically described.
Embodiment one:
Stretch tape comprises sealing coat 1, tackiness agent A layer 2, tackiness agent B layer 3 and tackiness agent C layer 4 from top to bottom successively, wherein the off-type force of sealing coat 1 is 10g, the thickness of tackiness agent A layer 2 is 30um, and the thickness of tackiness agent B layer 3 is 30um, and the thickness of tackiness agent C layer 4 is 30um.Tackiness agent A layer 2 according to weight percent comprise 40% synthetic rubber elastomerics, the terpene phenolic resin of 50% and the anti-aging agent of 5% and 5% liquid nitrile rubber, wherein synthetic rubber elastomerics according to weight percent comprise the styrene-butadiene rubber(SBR) of 8%, the SIS rubber of 30% and 2% SBS rubber, anti-aging agent is dibutylcarbamate and the 2,6 ditertiary butyl p cresol of 1:1; Tackiness agent B layer 3 according to weight percent comprise 50% SIS rubber, 40% isoprene-isobutylene rubber, 3% zinc dibutyl dithiocarbamate, the silane coupling agent of 1%, the dibutylcarbamate of 1% and 5% zinc sulfide white, wherein zinc sulfide white is the mixture of zinc sulphide and barium sulfate; Described tackiness agent C layer 4 is identical with tackiness agent A layer 2.
Embodiment two:
Stretch tape comprises sealing coat 1, tackiness agent A layer 2, tackiness agent B layer 3 and tackiness agent C layer 4 from top to bottom successively, wherein the off-type force of sealing coat 1 is 30g, the thickness of tackiness agent A layer 2 is 100um, and the thickness of tackiness agent B layer 3 is 200um, and the thickness of tackiness agent C layer 4 is 1500um.Tackiness agent A layer 2 according to weight percent comprise 50% synthetic rubber elastomerics, the tackifying resin of 40% and the anti-aging agent of 2% and 8% liquid polyisobutene and liquid nitrile rubber, wherein synthetic rubber elastomerics according to weight percent comprise the styrene-butadiene rubber(SBR) of 5%, the SIS rubber of 40% and 5% SBS rubber, tackifying resin is the mixture of C5 petroleum resin and C5/C9 petroleum resin, anti-aging agent is dibutylcarbamate and the 2,6 ditertiary butyl p cresol of 1:5; Tackiness agent B layer 3 according to weight percent comprise 39% SIS rubber, 50% isoprene-isobutylene rubber, 1% zinc dibutyl dithiocarbamate, the silane coupling agent of 4%, 3% 2,6-ditertbutylparacresol and 3% zinc sulfide white, wherein zinc sulfide white is the mixture of zinc sulphide and barium sulfate; Described tackiness agent C layer 4 is identical with tackiness agent A layer 2.
Embodiment three:
Stretch tape comprises sealing coat 1, tackiness agent A layer 2, tackiness agent B layer 3 and tackiness agent C layer 4 from top to bottom successively, wherein the off-type force of sealing coat 1 is 20g, the thickness of tackiness agent A layer 2 is 60um, and the thickness of tackiness agent B layer 3 is 100um, and the thickness of tackiness agent C layer 4 is 900um.Tackiness agent A layer 2 according to weight percent comprise 48% synthetic rubber elastomerics, the esterase of 48% and the anti-aging agent of 1% and 3% liquid nitrile rubber, wherein synthetic rubber elastomerics according to weight percent comprise the styrene-butadiene rubber(SBR) of 5%, the SIS rubber of 38% and 5% SBS rubber, anti-aging agent is dibutylcarbamate and the 2,6 ditertiary butyl p cresol of 1:3; Tackiness agent B layer 3 according to weight percent comprise 39% SIS rubber, the isoprene-isobutylene rubber of 50%, 1% 2,6-ditertbutylparacresol, the silane coupling agent of 4%, the dibutylcarbamate of 3% and 3% zinc sulfide white, wherein zinc sulfide white is the mixture of zinc sulphide and barium sulfate; Tackiness agent B layer 2 according to weight percent comprise 40% synthetic rubber elastomerics, the tackifying resin of 50% and the anti-aging agent of 5% and 5% liquid nitrile rubber, wherein synthetic rubber elastomerics according to weight percent comprise the styrene-butadiene rubber(SBR) of 8%, the SIS rubber of 40% and 2% SBS rubber, tackifying resin is the mixture of terpene phenolic resin, C5 petroleum resin and esterase, anti-aging agent is dibutylcarbamate and the 2,6 ditertiary butyl p cresol of 1:2.
According to PSTC-107 testing method, the stretch tape in above-mentioned above-described embodiment one to embodiment three is made into hook, when normal temperature is fitted, during area 25MM*25MM, hangs heavy 5kg and can be greater than 30 days; After laminating affixed object after dismounting, do not leave any cull, pollute affixed object.Can stretch along adhesive tape one end during the dismounting of stretching glue, stretch tape will be inharmonious gradually, until come off from affixed object.
In sum, stretch tape of the present invention has fabulous cohesive strength and stretchiness, there is high movable and temperature tolerance simultaneously, fit when peeling off again after affixed object, only need stretch along one end of stretch tape, this stretch tape just can be stripped down by complete, and affixed object surface can not be left cull and there is the difficult phenomenon peeled off, can be applicable in multiple industry, as electron trade needs often to dismantle to some, recycles and need the laminating of salvage material, the conventional cell box as notebook, some wiring board, bezel seal etc. of electronic apparatus; As in family expenses industry, be used for hanging and weigh, laminating wallpaper, photo frame etc., require certain heavy burden ability, simultaneously when needing to readjust or remove original design, can not be formed two sides affixed object and polluting, only need along adhesive tape one end stretch release, this stretch tape will be removed completely, can not remain in affixed object surface.In addition, because above-mentioned stretch tape has certain thickness, so it has again the buffering effect of foam adhesive tape.
The above is only the preferred embodiment of the present invention; be not limited to the present invention; should be understood that; for those skilled in the art; under the prerequisite not departing from the technology of the present invention principle; can also make some improvement and modification, these improve and modification also should be considered as protection scope of the present invention.
Claims (10)
1. a stretch tape, it is characterized in that: comprise sealing coat, tackiness agent A layer, tackiness agent B layer and tackiness agent C layer from top to bottom successively, the off-type force of wherein said sealing coat is 5 ~ 100g, and described tackiness agent A layer comprises the synthetic rubber elastomerics of 30 ~ 50% and the tackifying resin of 30 ~ 50% according to weight percent; Described tackiness agent B layer according to weight percent comprise 30 ~ 50% SIS rubber, 30 ~ 50% isoprene-isobutylene rubber, 1 ~ 3% promotor, the coupling agent of 1 ~ 4%, the anti-aging agent of 1 ~ 3% and 1 ~ 10% zinc sulfide white; Described tackiness agent C layer comprises the synthetic rubber elastomerics of 30 ~ 50% and the tackifying resin of 30 ~ 50% according to weight percent.
2. stretch tape according to claim 1, is characterized in that: the off-type force of described sealing coat is 10 ~ 30g.
3. stretch tape according to claim 1 and 2, is characterized in that: described sealing coat is two-sided separate-type paper or release film.
4. stretch tape according to claim 3, is characterized in that: described sealing coat is polyethylene release film or polyethylene terephthalate release film.
5. stretch tape according to claim 1, is characterized in that: described synthetic rubber elastomerics according to weight percent comprise the styrene-butadiene rubber(SBR) of 3 ~ 8%, the SIS rubber of 30 ~ 40% and 2 ~ 5% SBS rubber; Described tackifying resin is at least one in terpene phenolic resin, C5 petroleum resin, C5/C9 petroleum resin, synthesis C5/C9 petroleum resin, esterase.
6. stretch tape according to claim 1 or 5, it is characterized in that: described tackiness agent A layer also comprises the anti-aging agent of 1 ~ 5% and the Rubber Softener of 3 ~ 8% according to weight percent, described anti-aging agent comprises the first anti-aging agent and the second anti-aging agent, and described first anti-aging agent is dibutylcarbamate; Described second anti-aging agent is 2,6 ditertiary butyl p cresol; The weight ratio of described first anti-aging agent and the second anti-aging agent is 1 ~ 5:1; Described Rubber Softener is at least one in white oil, liquid polyisobutene, liquid nitrile rubber.
7. stretch tape according to claim 1 or 5, it is characterized in that: described tackiness agent C layer also comprises the anti-aging agent of 1 ~ 5% and the Rubber Softener of 3 ~ 8% according to weight percent, described anti-aging agent comprises the first anti-aging agent and the second anti-aging agent, and described first anti-aging agent is dibutylcarbamate; Described second anti-aging agent is 2,6 ditertiary butyl p cresol; The weight ratio of described first anti-aging agent and the second anti-aging agent is 1 ~ 5:1; Described Rubber Softener is at least one in white oil, liquid polyisobutene, liquid nitrile rubber.
8. stretch tape according to claim 1, is characterized in that: described promotor is zinc dibutyl dithiocarbamate; Described coupling agent is silane coupling agent; Described anti-aging agent is one or both in dibutylcarbamate, 2,6 ditertiary butyl p cresol; Described zinc sulfide white is the mixture of zinc sulphide and barium sulfate.
9. stretch tape according to claim 1, is characterized in that: described stretch tape total thickness is 30 ~ 1500um.
10. the stretch tape according to claim 1 or 9, is characterized in that: the thickness of described tackiness agent A layer is 5 ~ 500um, and the thickness of described tackiness agent B layer is 20 ~ 500um, and the thickness of described tackiness agent C layer is 5 ~ 500um.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510575086.5A CN105153956A (en) | 2015-09-10 | 2015-09-10 | Stretching adhesive tape |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510575086.5A CN105153956A (en) | 2015-09-10 | 2015-09-10 | Stretching adhesive tape |
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| CN105153956A true CN105153956A (en) | 2015-12-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510575086.5A Pending CN105153956A (en) | 2015-09-10 | 2015-09-10 | Stretching adhesive tape |
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| CN (1) | CN105153956A (en) |
Cited By (5)
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| CN106675433A (en) * | 2017-01-12 | 2017-05-17 | 深圳市美信电子有限公司 | Anti-explosive easy-to-disassemble safe adhesive tape and manufacturing method thereof |
| US20180198099A1 (en) * | 2017-01-12 | 2018-07-12 | Shenzhen Meixin Electronics Co., Ltd. | Anti-explosive easy-to-dissemble safe adhesive tape and manufacturing method thereof |
| CN109825210A (en) * | 2018-12-29 | 2019-05-31 | 苏州高泰电子技术股份有限公司 | Dismantling separation gel band, structure and its preparation process of integral electronic product |
| CN110183987A (en) * | 2019-05-17 | 2019-08-30 | 新纶科技（常州）有限公司 | A kind of easy-to-draw glue of rubber series and preparation method thereof |
| CN114007858A (en) * | 2020-02-17 | 2022-02-01 | 米岛毛毡产业株式会社 | Laminate, method for producing intermediate sheet, and method for producing composite material |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106675433A (en) * | 2017-01-12 | 2017-05-17 | 深圳市美信电子有限公司 | Anti-explosive easy-to-disassemble safe adhesive tape and manufacturing method thereof |
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| CN109825210A (en) * | 2018-12-29 | 2019-05-31 | 苏州高泰电子技术股份有限公司 | Dismantling separation gel band, structure and its preparation process of integral electronic product |
| WO2020134859A1 (en) * | 2018-12-29 | 2020-07-02 | 苏州高泰电子技术股份有限公司 | Disassembly and separation adhesive tape for integrated electronic products, structure thereof and preparation process therefor |
| CN110183987A (en) * | 2019-05-17 | 2019-08-30 | 新纶科技（常州）有限公司 | A kind of easy-to-draw glue of rubber series and preparation method thereof |
| CN114007858A (en) * | 2020-02-17 | 2022-02-01 | 米岛毛毡产业株式会社 | Laminate, method for producing intermediate sheet, and method for producing composite material |
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Application publication date: 20151216 |