CN105088267B - Electrolytic cell device for separation the anode chamber and the cathode chamber of electrolytic preparation Ozone Water - Google Patents
Electrolytic cell device for separation the anode chamber and the cathode chamber of electrolytic preparation Ozone Water Download PDFInfo
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- CN105088267B CN105088267B CN201510644018.XA CN201510644018A CN105088267B CN 105088267 B CN105088267 B CN 105088267B CN 201510644018 A CN201510644018 A CN 201510644018A CN 105088267 B CN105088267 B CN 105088267B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/13—Ozone
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
The invention discloses a kind of electrolytic cell device of separation the anode chamber and the cathode chamber for electrolytic preparation Ozone Water, including electrolytic cell, cathode electrode and anode electrode are provided with the electrolytic cell, the bottom of the cathode electrode and anode electrode and the bottom of electrolytic cell completely attach to, electrolytic cell is separated into mutually independent anode chamber and cathode chamber, being equipped with the anode chamber and cathode chamber isolation allows ion permeable, but isolates the proton exchange membrane that hydrogen passes through anode region.The structure design of the present invention is separated since anode chamber being isolated with cathode chamber, not connected so that the water of cathode chamber will not be mixed into anode chamber, therefore avoid the hydrogen produced in cathode chamber and be mixed into anode chamber and ozone O3Generation neutralization reaction, so as to reduce ozone O3Consumption, improve ozone O3Production efficiency and content.
Description
Technical field
The present invention relates to the research field of electrolytic cell device, more particularly to a kind of separation for electrolytic preparation Ozone Water is cloudy
The electrolytic cell device of anode chamber.
Background technology
The application of electrolysis water early in the seventies in last century NASA be used for manned spaceship give astronaut oxygen supply.Especially
It is after the eighties, and the applying of solid polymer electrolyte (SPE) technology prepares hydrogen in electrolysis water and oxygen is promoted.
Using general conductive material as electrode, electrochemical reaction generation oxygen and hydrogen can occur in anode and cathode surface respectively
Gas.Conductive diamond is proven to have splendid chemical property, using conductive diamond as anode, can be made into straight
Connect the ozone for being dissolved in water, abbreviation Ozone Water.
Chinese patent CN20061009226.7 and CN20118006557.9 prepare Ozone Water using diamond electrode, still
Anode region and cathodic region all do not separate, and anode chamber and cathode chamber are (as shown in Figure 1) communicated, are electrolysed the ozone produced afterwards
Again can be from the region mixing communicated so that the hydrogen in water dilutes ozone content again by ozone oxidation, so as to result in
Generator efficiency of ozone generation is low, ozone concentration is low.
The content of the invention
The shortcomings that it is a primary object of the present invention to overcome the prior art and deficiency, there is provided one kind is used for electrolytic preparation ozone
The electrolytic cell device of separation the anode chamber and the cathode chamber of water, for improving ozone O3Production efficiency and content.
In order to achieve the above object, the present invention uses following technical scheme：
A kind of electrolytic cell device of separation the anode chamber and the cathode chamber for electrolytic preparation Ozone Water, including electrolytic cell, the electrolysis
Cathode electrode and anode electrode are provided with groove, the bottom of the cathode electrode and anode electrode and the bottom of electrolytic cell connect completely
Touch, electrolytic cell be separated into mutually independent anode chamber and cathode chamber, be equipped with the anode chamber and cathode chamber isolation allow from
Son passes through, but isolates the proton exchange membrane that hydrogen passes through anode region.
As preference, the exhausting-gas hole for being used for discharging the hydrogen of generation is equipped with the cathode chamber.
As preference, the anode electrode and cathode electrode are equipped with the through hole for allowing water to pass through.
As preference, the through hole is circular hole, square hole, slot, taper hole, bar hole, polygonal hole or not
Regular shape hole.
As preference, the anode electrode and cathode electrode of one or more pairs of combination settings, shape are equipped with the electrolytic cell
Into two or more anode chambers and cathode chamber.
As preference, the anode electrode includes anode terminal, anode substrate and conductive film plating layer, the cathode electrode
Including cathode terminal, cathode substrate and conductive film plating layer, the conduction film plating layer is directly connected with cathode terminal and anode terminal.
As preference, the anode terminal and cathode terminal use elastic conduction intermediate plate, the elastic conduction intermediate plate is straight
Touch conducting film；Or the anode terminal and cathode terminal are connected by conductive adhesive thing with conducting film, the electricity is viscous
Thing is connect as conductive silver glue or conductive tin slurry.
As preference, the anode electrode is made of conductive material, the anode electrode is conductive diamond piece, or
Electroconductive diamond film using silicon chip as substrate；The cathode electrode is made of conductive material, and the cathode electrode is conductive Buddha's warrior attendant
Flag, either with the electroconductive diamond film or stainless steel substrates of silicon chip substrate.
As preference, the anode electrode and cathode electrode are equipped with the active material containing catalytic action.
As preference, the electrolytic cell device is using DC powered, exchange electric drive or pulse electric drive.
Compared with prior art, the present invention having the following advantages that and beneficial effect：
(1) structure design of the invention is separated since anode chamber being isolated with cathode chamber, not connected；So that cathode chamber
Water will not be mixed into anode chamber, thus avoid cathode chamber produce hydrogen will not be mixed into anode chamber and ozone O3Neutralize
Reaction, so that the ozone O of reduction3Consumption, improve ozone O3Production efficiency and content.
(2) due to being directly connected to the conducting film of coated electrode, the substrate material of the coated electrode of electrolytic cell in the present invention
Material can use nonconducting base material, such as：Glass, silicon chip, ceramics etc.；Conductive base material can also be used.
So greatly extended for Choice of substrate materials scope, and base material electric conductivity is not bad to coated electrode
Influence, so that designer can easily select the relatively good base material of those adhesion of coating film.Such as：Using silicon chip
Plate for substrate material and on it last layer electroconductive diamond film, the electrode metallizations strong adhesive force being fabricated to, it is not easy to demoulding, because
This electrode life is longer.
(3) cathode terminal, anode terminal are directly connected with conducting film in the present invention, so the series connection there is no base material
The influence of resistance, hence in so that the input voltage of electrolytic cell can reduce, the energy consumption of cell reaction reduces, and water temperature is also dropped
Low, the service life of electrode also extends many.
Brief description of the drawings
Fig. 1 is the unsegregated electrolytic cell device schematic diagram of cathode chamber and anode chamber in the prior art；
Fig. 2 is the separated electrolytic cell device structure diagram of cathode chamber of the present invention and anode chamber；
Fig. 3 is the multigroup cathode chamber of the present invention and the separated electrolytic cell device structure diagram in anode chamber；
Fig. 4 (a)-Fig. 4 (g) is the structure diagram of the various through holes of the present invention.
Drawing reference numeral explanation：1st, anode terminal；2nd, cathode terminal；3rd, anode electrode；4th, electroconductive diamond film；5th, cathode electricity
Pole；6th, anode chamber；7th, cathode chamber；8th, proton exchange membrane；9th, through hole；10th, anode compartment outlet；11st, cathode chamber outlet；12nd, entrance；
13rd, sealing material.
Embodiment
With reference to embodiment and attached drawing, the present invention is described in further detail, but embodiments of the present invention are unlimited
In this.
Embodiment 1
As shown in Fig. 2, the invention discloses a kind of electrolytic cell dress of separation the anode chamber and the cathode chamber for electrolytic preparation Ozone Water
Put, including electrolytic cell, cathode electrode 5 and anode electrode 3, cathode electrode and the anode electricity are vertically arranged with the electrolytic cell
The bottom of pole and the bottom of electrolytic cell completely attach to, and electrolytic cell is separated into mutually independent anode chamber 6 and cathode chamber 7, described
Being equipped with 7 isolation of anode chamber 6 and cathode chamber can be passed through with hydrogen ion, but isolate the proton exchange membrane 8 that hydrogen passes through anode region.This
Invention is separated since anode chamber 6 being isolated with cathode chamber 7, not connected；So that the water of cathode chamber will not be mixed into anode chamber, therefore
Anode chamber and ozone O will not be mixed into by avoiding the hydrogen produced in cathode chamber3Generation neutralization reaction, so that the ozone O of reduction3
Consumption, improve ozone O3Production efficiency and concentration.
The exhausting-gas hole for being used for discharging the hydrogen of generation is equipped with the present embodiment, in the cathode chamber, can smoothly by
Hydrogen is discharged out of cathode chamber, is conducive to the further progress of electrolysis.
Meanwhile the anode electrode is equipped with through hole 9, such as Fig. 4 (a)-Fig. 4 (g), the through hole is circular hole, square hole,
A variety of styles such as slot, taper hole, bar hole, polygonal hole or irregular shape hole etc., certainly, above-mentioned through hole is not stringent
Shape limitation, the shape of other forms is also applied for technical scheme.
In the present embodiment, water is flowed into from entrance 12, is flowed out from anode compartment outlet 10 and cathode chamber outlet 11, realizes electrolysis system
Standby Ozone Water.
In the present embodiment, the active material containing catalytic action on the anode electrode and cathode electrode, the electrolysis
Pool device samples DC powered.
As shown in figure 3, being equipped with the anode electrode and cathode electrode of multipair combination settings in the electrolytic cell, formed multipair
Anode chamber and cathode chamber, by this kind of form, can further increase the yield of ozone.
The present embodiment has made two structural model and has carried out experiment comparison, and experimental results reduction is as follows：
It can be seen that from above-mentioned experiment after applying the technical scheme of the present invention, the concentration of ozone has obtained significantly carrying
It is high.
Embodiment 2
In the present embodiment, in addition to following technical characteristics, other technical characteristics are same as Example 1：The anode electricity
Pole, which includes anode terminal 1, anode substrate and conductive film plating layer, the cathode electrode, includes cathode terminal 2, cathode substrate and conduction
Film plating layer, the conduction film plating layer are directly connected with cathode terminal and anode terminal.Electric current is from cathode terminal and anode tap subflow
It is electrolysed after going out directly through conductive film plating layer in electrolytic cell, the anode terminal and cathode terminal connect with conductive film plating layer
The part connect is arranged on outside electrolytic cell.
In the present embodiment, the anode terminal and cathode terminal use elastic conduction intermediate plate, in anode one end, the elasticity
Conductive clip just clamps anode terminal and conducting film, and electric current passes through anode terminal, not by substrate and directly and conducting film
Connection；In cathode one end, the elastic conduction intermediate plate equally just clamps cathode terminal and conducting film, and electric current passes through cathode terminal
Son, is not connected directly by substrate with conducting film, and under the collective effect of anode and cathode terminal, electricity is carried out to the water in electrolytic cell
Solution, obtains ozone, in the present embodiment, due to being directly connected to the conductive layer of coated electrode, the base of the coated electrode of electrolytic cell
Bottom material can use nonconducting base material, such as：Glass, silicon chip, ceramics etc.；Conductive substrate material can also be used
Material, so greatly extended for Choice of substrate materials scope, and base material electric conductivity is to the institute of coated electrode
With no harmful effect.
In the present embodiment, the elastic conduction intermediate plate uses phosphorus bronze sheet, and uses silicon chip for substrate material and plate on it
Last layer electroconductive diamond film 4, the electrode metallizations strong adhesive force being fabricated to, it is not easy to demoulding, therefore electrode life is longer, it is described
Elastic conduction intermediate plate is encapsulated with conducting film connecting portion sealing material 13, prevents from being corroded.Certainly, the elasticity in the present embodiment
Conductive clip is not limited to phosphorus bronze sheet one kind, other meet the conductive material of technical scheme in the protection model of the application
Within enclosing.
The present embodiment is compared by experiment, and experimental results reduction is as follows：
Note：The application is made of same process in experiment：Conductive silicon chip plates electroconductive diamond film.Operating current controls
1000mA (constant current test), the minimum operating voltage of two tentative modules therein have obvious difference：It is directly connected to mode
Design electrode voltage lower power consumption it is also low, when long-time cycle operation 3 is small after, its water temperature substantially reduces.
Comparison of experiment results shows：Although using the electrode monolithic anode working for being directly connected to coated electrode, test life
Also it is obvious longer than the work of two-way (equivalent to 2 anodes) cyclic switching.
As a kind of alternative of the present embodiment, the anode terminal and cathode terminal pass through electric sticky object and conducting film
Connection, electric current directly flow through conducting film from anode terminal (or cathode terminal), realize and are electrolysed, in the present embodiment, due to directly connecting
The conductive layer of coated electrode is connect, there is no the influence of the series resistance of base material, hence in so that the input voltage of electrolytic cell can
To reduce, the energy consumption of cell reaction reduces, and water temperature is also reduced, and the service life of electrode also extends many.
In the present embodiment, the electricity sticky object is electric elargol or conductive tin slurry, ensure that anode terminal (or) cathode terminal
The connection of son and conducting film, while ensure that good electric conductivity therebetween, certainly, except above-mentioned viscous in the present embodiment
Thing is connect, other sticky objects for meeting technical scheme are also within the protection domain of the application.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention and from above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (7)
- A kind of 1. electrolytic cell device of separation the anode chamber and the cathode chamber for electrolytic preparation Ozone Water, it is characterised in that including electrolytic cell, Cathode electrode and anode electrode, the bottom of the cathode electrode and anode electrode and the bottom of electrolytic cell are provided with the electrolytic cell End completely attaches to, and electrolytic cell is separated into mutually independent anode chamber and cathode chamber, is set at the anode chamber and cathode chamber isolation There is permission ion permeable, but isolate the proton exchange membrane that hydrogen passes through anode region；The anode electrode includes anode terminal, anode Substrate and conductive film plating layer, the cathode electrode include cathode terminal, cathode substrate and conductive film plating layer, the cathode electrode end Conductive film plating layer be directly connected with cathode terminal, the conductive film plating layer at the anode electrode end is connected with anode terminal；It is described The anode electrode and cathode electrode of one or more pairs of combination settings are equipped with electrolytic cell, forms two or more anode chambers and cathode Room；The anode terminal and cathode terminal use elastic conduction intermediate plate, and the elastic conduction intermediate plate directly contacts conductive plated film Layer；Or the anode terminal and cathode terminal are connected by conductive adhesive thing with conductive film plating layer, the electricity sticky object is to lead Electric elargol or conductive tin slurry.
- 2. the electrolytic cell device of separation the anode chamber and the cathode chamber according to claim 1 for electrolytic preparation Ozone Water, its feature It is, the exhausting-gas hole for being used for discharging the hydrogen of generation is equipped with the cathode chamber.
- 3. the electrolytic cell device of separation the anode chamber and the cathode chamber according to claim 1 for electrolytic preparation Ozone Water, its feature It is, the anode electrode and cathode electrode are equipped with the through hole for allowing water to pass through.
- 4. the electrolytic cell device of separation the anode chamber and the cathode chamber according to claim 3 for electrolytic preparation Ozone Water, its feature It is, the through hole is circular hole, square hole, slot, taper hole, polygonal hole or irregular shape hole.
- 5. the electrolytic cell device of separation the anode chamber and the cathode chamber according to claim 1 for electrolytic preparation Ozone Water, its feature It is, the anode electrode is made of conductive material, and the anode electrode is conductive diamond piece；The cathode electrode is by conduction Material forms, and the cathode electrode is conductive diamond piece.
- 6. the electrolytic cell device of separation the anode chamber and the cathode chamber according to claim 1 for electrolytic preparation Ozone Water, its feature It is, the anode electrode and cathode electrode are equipped with the active material containing catalytic action.
- 7. the electrolytic cell device of separation the anode chamber and the cathode chamber according to claim 1 for electrolytic preparation Ozone Water, its feature It is, the electrolytic cell device is using DC powered, exchange electric drive or pulse electric drive.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510644018.XA CN105088267B (en) | 2015-09-30 | 2015-09-30 | Electrolytic cell device for separation the anode chamber and the cathode chamber of electrolytic preparation Ozone Water |
| PCT/CN2016/073806 WO2017054392A1 (en) | 2015-09-30 | 2016-02-15 | Electrolytic cell apparatus with separated anode and cathode chambers for electrolytic preparation of ozone water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510644018.XA CN105088267B (en) | 2015-09-30 | 2015-09-30 | Electrolytic cell device for separation the anode chamber and the cathode chamber of electrolytic preparation Ozone Water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105088267A CN105088267A (en) | 2015-11-25 |
| CN105088267B true CN105088267B (en) | 2018-05-15 |
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| CN201510644018.XA Active CN105088267B (en) | 2015-09-30 | 2015-09-30 | Electrolytic cell device for separation the anode chamber and the cathode chamber of electrolytic preparation Ozone Water |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN105088267B (en) |
| WO (1) | WO2017054392A1 (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105112937A (en) * | 2015-09-30 | 2015-12-02 | 广州市德百顺电气科技有限公司 | Ozone water electrolysis device directly connected to coated electrode |
| CN105088267B (en) * | 2015-09-30 | 2018-05-15 | 钟建华 | Electrolytic cell device for separation the anode chamber and the cathode chamber of electrolytic preparation Ozone Water |
| CN106869273A (en) * | 2017-02-21 | 2017-06-20 | 中山市爱马仕洁具有限公司 | A kind of intelligent water toilet pan of use ozone water device |
| CN107177861B (en) * | 2017-05-12 | 2020-04-17 | 广州市德百顺电气科技有限公司 | Ozone generator nozzle |
| CN108611655B (en) * | 2018-03-18 | 2020-11-06 | 广州市德百顺电气科技有限公司 | Electrode unit and electrode composed of same |
| CN110499518B (en) * | 2018-05-18 | 2021-08-06 | 苏州庚泽新材料科技有限公司 | Electrolysis device |
| JP6937475B2 (en) * | 2018-07-13 | 2021-09-22 | パナソニックＩｐマネジメント株式会社 | Electrolytic liquid generator |
| KR20200007709A (en) * | 2018-07-13 | 2020-01-22 | 파나소닉 아이피 매니지먼트 가부시키가이샤 | Electrolytic liquid generating device |
| JP6937476B2 (en) * | 2018-07-13 | 2021-09-22 | パナソニックＩｐマネジメント株式会社 | Electrolytic liquid generator |
| CN109487293A (en) * | 2018-12-21 | 2019-03-19 | 广州市德百顺电气科技有限公司 | A kind of ozone tank house electrolytic arrangement |
| CN110123482A (en) * | 2019-05-27 | 2019-08-16 | 广州市德百顺电气科技有限公司 | A kind of Ozone Water Active MnO2 device |
| CN110846674A (en) * | 2019-10-16 | 2020-02-28 | 广州市德百顺电气科技有限公司 | Ozone electrolysis structure and electrolysis chamber |
| CN113388855A (en) * | 2020-03-11 | 2021-09-14 | 上海喜运环保科技有限公司 | Improved method and structure of ozone mouth wash instant generation device |
| CN112255288B (en) * | 2020-10-09 | 2022-08-12 | 泉州师范学院 | DSA anode electrochemical performance testing device |
| CN112267126B (en) * | 2020-10-23 | 2022-03-15 | 广州德百顺蓝钻科技有限公司 | Electrolysis chamber structure and have its electrolysis water disinfection spray bottle |
| CN113897622A (en) * | 2021-10-27 | 2022-01-07 | 广州德百顺蓝钻科技有限公司 | Electrolytic water assembly and device |
| CN218561639U (en) * | 2022-03-23 | 2023-03-03 | 江西欣远新材料科技有限公司 | Device for preparing disinfectant by electrolyzing diamond film |
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| CN2430450Y (en) * | 1999-12-23 | 2001-05-16 | 武汉大学 | Ozone water generator |
| JP4410155B2 (en) * | 2005-06-16 | 2010-02-03 | ペルメレック電極株式会社 | Electrolyzed water ejection device |
| JP5480542B2 (en) * | 2009-06-23 | 2014-04-23 | クロリンエンジニアズ株式会社 | Conductive diamond electrode and ozone generator using conductive diamond electrode |
| JP2011032507A (en) * | 2009-07-30 | 2011-02-17 | Sanyo Electric Co Ltd | Electrolytic electrode material, electrolytic electrode and method of producing the same |
| CN101634035B (en) * | 2009-09-03 | 2010-11-10 | 西安交通大学 | Electrochemical method and electrochemical device for synergistically generating ozone and hydrogen peroxide in neutral medium |
| DE202009015450U1 (en) * | 2009-11-16 | 2010-02-25 | Schulze, Dirk | Electrochemical ozone generator |
| US8980079B2 (en) * | 2010-12-03 | 2015-03-17 | Electrolytic Ozone, Inc. | Electrolytic cell for ozone production |
| US20130341204A1 (en) * | 2012-04-23 | 2013-12-26 | Ritedia Corporation | Carbon Electrode Devices for Use with Liquids and Associated Methods |
| US20140251795A1 (en) * | 2013-03-07 | 2014-09-11 | Cashido Corporation | Manufacturing method of cathode catalyst and ozone-generating device |
| CN205088310U (en) * | 2015-09-30 | 2016-03-16 | 钟建华 | A electrolytic bath device that is used for cloudy anode chamber of partition of electrolytic preparation ozone water |
| CN105088267B (en) * | 2015-09-30 | 2018-05-15 | 钟建华 | Electrolytic cell device for separation the anode chamber and the cathode chamber of electrolytic preparation Ozone Water |
| CN205241798U (en) * | 2015-09-30 | 2016-05-18 | 钟建华 | Electrolytic ozone water installation of lug connection coating film electrode |
| CN105112937A (en) * | 2015-09-30 | 2015-12-02 | 广州市德百顺电气科技有限公司 | Ozone water electrolysis device directly connected to coated electrode |
-
2015
- 2015-09-30 CN CN201510644018.XA patent/CN105088267B/en active Active
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2016
- 2016-02-15 WO PCT/CN2016/073806 patent/WO2017054392A1/en active Application Filing
Also Published As
| Publication number | Publication date |
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| CN105088267A (en) | 2015-11-25 |
| WO2017054392A1 (en) | 2017-04-06 |
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Effective date of registration: 20160226 Address after: 510000 Tianhe District, Guangdong, No. five road, No. 261, Applicant after: Zhong Jianhua Applicant after: Zhang Wenying Address before: No. 80 Guangzhou science and technology innovation base in E District 510663 Guangzhou Road, Guangdong province lanyue science 204-206 Applicant before: GUANGZHOU DEPOSON ELECTRIC TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20221103 Address after: Room 801, Building B4, No. 11, Kaiyuan Avenue, Huangpu District, Guangzhou, Guangdong 510663 Patentee after: Guangzhou debaishun Blue Diamond Technology Co.,Ltd. Address before: No. 261, Wushan Road, Tianhe District, Guangzhou, Guangdong 510000 Patentee before: Zhong Jianhua Patentee before: Zhang Wenying |