CN104673035B - Wall emulsion paint inside and outside a kind of high rigidity scrubbing resistance - Google Patents
Wall emulsion paint inside and outside a kind of high rigidity scrubbing resistance Download PDFInfo
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- CN104673035B CN104673035B CN201510104275.4A CN201510104275A CN104673035B CN 104673035 B CN104673035 B CN 104673035B CN 201510104275 A CN201510104275 A CN 201510104275A CN 104673035 B CN104673035 B CN 104673035B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
A kind of high rigidity scrubbing resistance inner-outer wall acrylic emulsion paint is provided, its composition includes the component of following parts by weight：Pure-acrylic emulsion 400 600, compound color stuffing 300 450, water 100 200, composite assistant 40 60, wherein, a kind of anti-cracking agent that can be with the resin component reaction in pure-acrylic emulsion is included in the composite assistant.The emulsion paint has wash-resistant property superior, environmental protection, hardness it is high thus adhesion strength it is superior the characteristics of.
Description
Technical field
The invention belongs to paint field, and in particular to a kind of inner-outer wall acrylic emulsion paint of modification.
Background technology
Emulsion paint is the class coating using macromolecule emulsion as film forming matter, also known as synthetic resin emulsion coating, and its is general
Using water as decentralized medium, with preparation technology it is simple, relatively environmental protection, colour retention is good the features such as, but existing emulsion paint
Also have paint film soft, anti-pollution characteristic is poor, adhesion strength is poor, the shortcomings of paint film is easily frayed.
CN102676012A discloses a kind of pure third exterior wall latex coating, it include pure-acrylic emulsion, dispersant, thickener,
Coalescents, levelling agent, titanium dioxide, coarse whiting, fine particle calcium carbonate, talcum powder, wollastonite in powder, preservative, defoamer, water, graining paste, the painting
Material has enhanced weatherability and longer service life, but its water resistance and scrub resistance are not enough, if simultaneously as interior
Wall coating is used, then the performance of resistance to multiple scrub water has to be strengthened.
CN103382334A discloses a kind of alkyd modified acrylic acid High weatherability emulsion, including according to mass fraction meter
The following raw material：It is 30-38 parts of water, 120-130 parts of acrylic emulsion, 10-15 parts of dryness modified alkyd resin, polyacrylic acid grafted
Polymer-modified PAA-L 0.2-0.5 parts, wetting agent306 0.5-1 parts, defoamer JY-822 0.1-0.2
Part, 1-1.5 parts of preservative DI702,0.1-0.2 parts of antioxidant CYANOX1790,10-20 parts of silicon powder, talcum powder 20-25
Part, the sour dibutylester 0.5- of 15-20 parts of titanium dioxide, 5-10 parts of hydroxyethyl cellulose, 5-7 parts of dibutyl tin laurate, maleic
0.8 part, 3-5 parts of propandiol butyl ether.The emulsion paint has improved weatherability, but the hardness of paint film and water-proof are waitd upon
Strengthen.
The content of the invention
The purpose of the present invention is to overcome the deficiencies in the prior art and propose a kind of pure third latex of high rigidity scrubbing resistance inner-outer wall
Paint, the emulsion paint has wash-resistant property superior, environmental protection, hardness it is high thus adhesion strength it is superior the characteristics of.
In order to achieve the above object, present invention firstly provides wall emulsion paint inside and outside a kind of high rigidity scrubbing resistance, it constitutes bag
Include the component of following parts by weight：
Wherein, a kind of anti-cracking agent that can be with the resin component reaction in pure-acrylic emulsion is included in the composite assistant.It is excellent
Selection of land, present inventor are it has been unexpectedly found that the anti-cracking agent is selected from C1~C8 alkylketene modified cellulose
When, the cracking resistance of the emulsion paint paint film can not only be improved, and its hardness and scrub resistance can be improved.
Preferably, the compound color stuffing is selected from rutile type titanium white, (average grain diameter is less than or equal to superfine alumina silicate
1.5 microns), it is wollastonite in powder, calcined kaolin, blanc fixe, two or more in sericite in powder.It is highly preferred that the application
It has been found that add it is proper amount of by rutile type titanium white, superfine alumina silicate, wollastonite in powder, calcining kaolinite on, precipitation
The compound color stuffing of barium sulfate, sericite in powder composition, not only uniformity of chromaticity is good for the emulsion paint, and abrasion resistance is brought up to
More than 800 times.
It is particularly preferred that the compound color stuffing contains rutile type titanium white 150-250 parts by weight, superfine alumina silicate
20-30 parts by weight, wollastonite in powder 20-30 parts by weight, calcined kaolin 35-45 parts by weight, blanc fixe 45-55 parts by weight and
Sericite in powder 35-45 parts by weight.
Ground is it is also particularly that, the compound color stuffing contains rutile type titanium white 180-200 parts by weight, superfine alumina silicate
25-26 parts by weight, wollastonite in powder 25-26 parts by weight, calcined kaolin 38-42 parts by weight, blanc fixe 49-51 parts by weight and
Sericite in powder 38-42 parts by weight.
Preferably, the composite assistant include anti-cracking agent, and comprising thickener, wetting agent, dispersant, levelling agent, into
One or more in film auxiliary agent, preservative, brightening agent, defoamer, anti-settling agent and anti-cracking agent.It is highly preferred that the auxiliary agent
Specifically comprise：Anti-cracking agent 2-8 parts by weight, thickener 3-4 parts by weight, wetting agent 2-4 parts by weight, dispersant 5-10 parts by weight,
Levelling agent 2-5 parts by weight, coalescents 20-40 parts by weight, preservative 0.5-2 parts by weight, brightening agent 0.1-1 parts by weight, ammoniacal liquor
0.5-2 parts by weight, defoamer 1-3 parts by weight and anti-settling agent 2-8 parts by weight.
The present invention additionally provides a kind of preparation method of wall emulsion paint inside and outside high rigidity scrubbing resistance, it is included above-mentioned each original
Material mixing, stirring, and the process ground.
Preferably, above-mentioned preparation method includes：
1) by part thickener, anti-cracking agent, wetting agent, dispersant, levelling agent, coalescents, preservative, brightening agent, ammonia
Water, defoamer and anti-settling agent are added in diluent water, mixing, are stirred；
2) to step 1) compound color stuffing is added in obtained mixture, stir；
3) to step 2) pure-acrylic emulsion is added in obtained mixture, stir；
4) to step 3) thickener of surplus is added in obtained mixture, stirring, grinding obtain the inner-outer wall latex
Paint.
It is highly preferred that above method step 1) in thickener be methyl cellulose ether, step 4) surplus thickening
Agent and step 1) described in thickener it is different, be specifically as follows ASE-60 and TT-935 combination.
Preferably, described defoamer uses mineral oil defoaming agent, plant oil defoamer, is specifically as follows B-943
Defoamer；Dispersant uses dispersant, the ammonium acrylate salt dispersant of hydrophobically modified co-poly carboxylic acid salt, is specifically as follows
SN5040,1124 dispersants；Wetting agent uses the wetting agent of ethoxylation class, is specifically as follows S-951 wetting agents；Thickener
Using cellulose family, acrylic compounds, hydrophobically modified association thickener etc., it is specifically as follows ASE-60 or TT-935 and its group
Close；Levelling agent uses the levelling agent of polyurethanes, is specifically as follows RM-2020；Coalescents can be using alkoxide and alcohol
Mixed system；Preservative uses isothiazolinone, is specifically as follows FF-02；Brightening agent can for double triazine amino-types and
Ultramarine etc.；Anti-settling agent can be conventional aqueous anti-settling thixotropic agent, be specifically as follows RX types.
Embodiment
The performance test of the application uses following standard：
GB/T 9755-2001《Exterior wall coating material of synthetic resin emulsion》；
GB/T 9756-2009《Resin latex dope》；
GB 18582-2008《Limits of harmful substances in indoor decorating and refurnishing materials interior wall coating》
The source of part material used in embodiment：
Embodiment 1
Wall emulsion paint inside and outside high rigidity scrubbing resistance is prepared by following steps：
1) by 0.3 part of thickener methyl cellulose ether, 5 parts of anti-cracking agent ethylene methacrylic ketone modified celluloses, 3 parts of wetting agents
S-951,2 parts of dispersant SN5040,6 parts of dispersants 1124,3 parts of levelling agent RM-2020,12 parts of coalescents Tcxanol and
20 parts of ethylene glycol, 1 part of preservative FF-02,0.4 part of brightening agent ultramarine, 1 part of ammoniacal liquor, 2 parts of defoamer B-943 and 5 parts of RX types
Anti-settling thixotropic agent is added in diluent water, mixing, is stirred；
2) to step 1) add compound color stuffing in obtained mixture, stir, wherein the compound color stuffing by
200 parts of rutile type titanium whites, 25 parts of superfine alumina silicates, 26 parts of wollastonites in powder, 40 parts of calcined kaolins, 50 parts of blanc fixes
With 40 parts of sericite in powder compositions；
3) to step 2) 520 parts of pure-acrylic emulsion AC261 are added in obtained mixture, stir；
4) to step 3) add 3 parts of thickener ASE-60 and 0.5 part of thickener TT-935 in obtained mixture, stirring,
Grinding, obtains the inside and outside wall emulsion paint.The performance test results of the emulsion are shown in Table 1.
Embodiment 2
Other conditions are same as Example 1, and difference is, the compound color stuffing is by 200 parts of rutile titanium dioxides
Powder, 51 parts of wollastonites in powder, 40 parts of calcined kaolins, 50 parts of blanc fixes and 40 parts of sericite in powder compositions.The performance of the emulsion
Test result is shown in Table 1.
Embodiment 3
Other conditions are same as Example 1, and difference is, the compound color stuffing is by 200 parts of rutile titanium dioxides
Powder, 25 parts of superfine alumina silicates, 26 parts of wollastonites in powder, 90 parts of blanc fixes and 40 parts of sericite in powder compositions.The performance of the emulsion
Test result is shown in Table 1.
Embodiment 4
Other conditions are same as Example 1, and difference is, the compound color stuffing is by 250 parts of rutile titanium dioxides
Powder, 25 parts of superfine alumina silicates, 26 parts of wollastonites in powder, 40 parts of calcined kaolins, 90 parts of blanc fixes and 40 parts of sericite in powder groups
Into.The performance test results of the emulsion are shown in Table 1.
Embodiment 5
Other conditions are same as Example 1, and difference is, the anticracking hardening agent is common lignocellulosic.Should
The performance test results of emulsion are shown in Table 1.
Embodiment 6
Other conditions are same as Example 1, and difference is that the anti-cracking agent is ethyl ketene modified cellulose.
Comparative example 1
Other conditions are same as Example 1, and difference is to be added without anti-cracking agent.The performance test results of the emulsion are shown in
Table 1.
Comparative example 2
Other conditions are same as Example 1, and difference is that adding 380 grams of rutile type titanium whites replaces its compound face
Filler.
The performance test results of the embodiment of table 1 and comparative example
Claims (8)
1. a kind of wall emulsion paint inside and outside high rigidity scrubbing resistance, its composition includes the component of following parts by weight：
Wherein, a kind of anti-cracking agent that can be with the resin component reaction in pure-acrylic emulsion is included in the composite assistant；It is described anti-
Split the alkylketene modified cellulose that agent is selected from C1~C8.
2. the emulsion paint described in claim 1, is less than wherein the compound color stuffing is selected from rutile type titanium white, average grain diameter
Equal to two or more in 1.5 microns of superfine alumina silicate, wollastonite in powder, calcined kaolin, blanc fixe, sericite in powder.
3. the emulsion paint described in claim 2, wherein the compound color stuffing is less than etc. by rutile type titanium white, average grain diameter
In 1.5 microns of superfine alumina silicate, wollastonite in powder, calcined kaolin, blanc fixe, sericite in powder composition.
4. the emulsion paint described in claim any one of 1-3, wherein the compound color stuffing contains rutile type titanium white 150-
It is 250 parts by weight, superfine alumina silicate 20-30 parts by weight, wollastonite in powder 20-30 parts by weight, calcined kaolin 35-45 parts by weight, heavy
Shallow lake barium sulfate 45-55 parts by weight and sericite in powder 35-45 parts by weight.
5. the emulsion paint described in claim any one of 1-3, wherein the compound color stuffing contains rutile type titanium white 180-
It is 200 parts by weight, superfine alumina silicate 25-26 parts by weight, wollastonite in powder 25-26 parts by weight, calcined kaolin 38-42 parts by weight, heavy
Shallow lake barium sulfate 49-51 parts by weight and sericite in powder 38-42 parts by weight.
6. the emulsion paint described in claim any one of 1-3, the composite assistant is specifically comprised：Anti-cracking agent 2-8 parts by weight,
Thickener 3-4 parts by weight, wetting agent 2-4 parts by weight, dispersant 5-10 parts by weight, levelling agent 2-5 parts by weight, coalescents 20-
40 parts by weight, preservative 0.5-2 parts by weight, brightening agent 0.1-1 parts by weight, ammoniacal liquor 0.5-2 parts by weight, defoamer 1-3 parts by weight
With anti-settling agent 2-8 parts by weight.
7. described in claim 6 inside and outside high rigidity scrubbing resistance wall emulsion paint preparation method, it comprises the following steps：
1) by part thickener, anti-cracking agent, wetting agent, dispersant, levelling agent, coalescents, preservative, brightening agent, ammoniacal liquor, disappear
Infusion and anti-settling agent are added in diluent water, mixing, are stirred；
2) to step 1) compound color stuffing is added in obtained mixture, stir；
3) to step 2) pure-acrylic emulsion is added in obtained mixture, stir；
4) to step 3) thickener of surplus is added in obtained mixture, stirring, grinding obtain the inside and outside wall emulsion paint.
8. the preparation method of emulsion paint described in claim 7, wherein step 1) in thickener be methyl cellulose ether, step 4)
The thickener and step 1 of the surplus) described in thickener it is different, specially ASE-60 and TT-935 combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510104275.4A CN104673035B (en) | 2015-03-11 | 2015-03-11 | Wall emulsion paint inside and outside a kind of high rigidity scrubbing resistance |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510104275.4A CN104673035B (en) | 2015-03-11 | 2015-03-11 | Wall emulsion paint inside and outside a kind of high rigidity scrubbing resistance |
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| Publication Number | Publication Date |
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| CN104673035A CN104673035A (en) | 2015-06-03 |
| CN104673035B true CN104673035B (en) | 2017-08-22 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752564A (en) * | 2016-11-25 | 2017-05-31 | 厦门富思特新材料科技有限公司 | A kind of non-through body technology texture coating surface layer special emulsion paint and preparation method thereof |
| CN107152170A (en) * | 2017-04-18 | 2017-09-12 | 山东电力建设第工程公司 | A kind of repairing technique of concrete |
| CN113736304A (en) * | 2021-10-13 | 2021-12-03 | 贵州柯维建材开发有限公司 | Paint formula for inner and outer wall construction and processing technology |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1414045A (en) * | 2002-10-25 | 2003-04-30 | 佛山市飞鸿涂料有限公司 | Super environmental protection latex paint with zero VOC |
| CN1566239A (en) * | 2003-07-04 | 2005-01-19 | 刘黎 | Environmental protection nano- latex paint for internal and external wall |
| CN1325587C (en) * | 2004-02-18 | 2007-07-11 | 方学平 | Surpergrade scrubbing-resistant interior wall paint and its prearation method |
| CN100357375C (en) * | 2004-12-16 | 2007-12-26 | 中国地质大学（武汉） | Anti-bacteria mildew-proof internal-wall emulsion paint and preparation method therefor |
| CN103642296B (en) * | 2013-12-23 | 2015-07-22 | 宜都宜龙特种水泥有限公司 | Novel radiation-proof putty powder |
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Inventor after: Shen Zhixian Inventor after: Deng Jianghua Inventor after: Gao Bo Inventor after: Hong Xincai Inventor before: Ma Qinghao |
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Effective date of registration: 20171121 Address after: 361000, No. 25 North Mountain Road, East Fu Street, Haicang District, Fujian, Xiamen Patentee after: Fujian wins reinforced material Co., Ltd. Address before: 101408 Beijing city Huairou District Huai Beizhen Hefangkou village 543 Mu lake company Patentee before: Ma Qinghao |
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