CN104663922A - Gamma-linolenic acid and alpha-linolenic acid reinforced corn blend oil - Google Patents

Gamma-linolenic acid and alpha-linolenic acid reinforced corn blend oil Download PDF

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Publication number
CN104663922A
CN104663922A CN201510004313.9A CN201510004313A CN104663922A CN 104663922 A CN104663922 A CN 104663922A CN 201510004313 A CN201510004313 A CN 201510004313A CN 104663922 A CN104663922 A CN 104663922A
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China
Prior art keywords
oil
linolenic acid
alpha
gamma
ready
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CN201510004313.9A
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Inventor
王棣
阿纳斯
李伟
李曰强
李秋红
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SHANDONG XIWANG FOOD CO Ltd
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SHANDONG XIWANG FOOD CO Ltd
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Priority to CN201510004313.9A priority Critical patent/CN104663922A/en
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  • Edible Oils And Fats (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Fats And Perfumes (AREA)

Abstract

The invention discloses gamma-linolenic acid and alpha-linolenic acid reinforced corn blend oil. Corn germ is taken as a base material to be blended with linseed oil, borage oil and blackcurrant seed oil, and an antioxidant is added to prepare the gamma-linolenic acid and alpha-linolenic acid reinforced corn blend oil. The gamma-linolenic acid and alpha-linolenic acid reinforced corn blend oil disclosed by the invention has the effect of solving the problems that the corn oil is lack of C18:3, lack of alpha-linolenic acid and especially lack of gamma-linolenic acid; the oxidation resistance of the oil is stabilized, and good frying property of the oil is guaranteed.

Description

A kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid
Technical field
The present invention relates to ready-mixed oil technical field, particularly relate to a kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid.
Background technology
In January, 2012, explicitly point out in " food industry " 12 " development plan ", " 12 " period, carry forward vigorously with the production of the grain processing accessory substance corn wet goods that is raw material, promote the diversification of grease kind, promote the self-supporting level of edible vegetable oil.Deeply developing the oil resource beyond soybean, peanut, rapeseed, sunflower seeds, the large oil crops of cottonseed five, produce functional grease, ready-mixed oil, is prosperity edible oil market, the important means improving people ' s health level.Above-mentioned five large oil of illustrating plant in soybean oil and the main deficiency of peanut oil be: soybean cast of oil is comparatively dark, and have special beany flavor, heat endurance is poor, can produce more foam during heating.Peanut oil is relatively high containing saturated fatty acid, more than 20%, is not therefore very good to reduction cholesterol, the people that cholesterol is high, easily suffers from all unsuitable many edible peanut oils of people of enterogastritis.
Maize germ oil is oil obtained from maize germ, also known as corn oil, containing abundant natural B B-complex E, vitamin E is to human body cell division, the certain effect that delayed senility, all have obvious curative effect and prevention effect to cardiovascular and cerebrovascular disease, heart disease, thrombophlebitis, Reproductive Performance class obstacle, muscular atrophy, trophism encephalomalacia.Natural B B-complex E contained by maize germ oil, or a kind of natural.Maize germ oil has good frying and antioxidative stabilizer.Corn oil smoke point, up to more than 230 DEG C, is the light wood that smoke point value in vegetable oil is the highest.Corn oil contains abundant phytosterol, pure medical sterol is also many to be extracted inside corn or soybean, sterol have prevent coronary atherosclerosis, the medicine and health care such as katabolism that promotes cholesterol is worth, be important intermediate such as medicine such as class such as steroid such as synthesis of vitamin d 3 grade, can hair tonic, hair care and skin-nourishing agent be used as.In addition, maize germ oil is rich in the unrighted acid such as oleic acid C18:1, linoleic acid C18:2, also has the delicate fragrance of corn, non-greasy, in America and Europe fashionable decades.But in maize germ oil, C18:3 content of fatty acid is about 0.5%, and alpha-linolenic acid (ALA) particularly gamma-Linolenic acid (GLA), containing quantity not sufficient, makes its nutrition and health care beneficiaries be subject to the restriction of certain limit simultaneously.
The prehuman height morbidity of order is as high fat of blood, and diabetes, artery sclerosis, cancer, early ageing is waited for a long time all relevant with lacking of gamma-Linolenic acid, and the certain antiulcer of acid and gamma-linolenic and tissue repair effect are also just paid attention to.Although gamma-Linolenic acid can by the autologous generation of linoleic acid C18:2 metabolism in human homergy, but due to the feature at the elderly's age, because Ω in body 3 and Ω 6 fatty acid enzymatic activity start to decline, even if take in a large amount of linoleic acid C18:2, also often all normally cannot be converted into gamma-Linolenic acid, thus cause prostaglandin to lack, and then easily cause atherosclerotic, the hypotensive effect of auxiliary antilipemic is also not obvious, more easily other cardiovascular and cerebrovascular diseases concurrent.At present, the trend that becomes younger that cardiovascular and cerebrovascular disease occurs is also more and more obvious, meanwhile, patient also easily causes the gastro-intestinal tract problem such as digestive tract ulcer, hemorrhage even spasm in long-term drug administration process, and affects control and the Health restoration of disease conversely.In addition, there are easy oxidation, non-refractory, problem that smoke point is low containing C18:3 and the high vegetable oil of unrighted acid, make it apply and be subject to a definite limitation, rationally should determine the Fat acid content of its not resistance to oxidation component.
How to strengthen C18:3 content of fatty acid in maize germ oil, improve alpha-linolenic acid content especially gamma-linolenic acid content, its non-oxidizability of Simultaneous Stabilization and its good frying of protection, become the problem needing to solve.
Summary of the invention
Object of the present invention is exactly defect for above-mentioned existence and provides a kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid.Solve C18:3 content of fatty acid in corn oil not enough, especially gamma-linolenic acid content is not enough, the problem of its non-oxidizability of Simultaneous Stabilization and its good frying of protection.
A kind of corn oil ready-mixed oil technical scheme strengthening gamma-Linolenic acid and alpha-linolenic acid of the present invention is, adopts based on maize germ oil, and is in harmonious proportion with linseed oil, borage oil, 'Heijialun ' seed oil, adds antioxidant simultaneously and makes.
Every 100g ready-mixed oil contains following component:
Maize germ oil 66-97 g
Linseed oil 1-33 g
Borage oil 1-33g
'Heijialun ' seed oil 0-33g
TBHQ 0.001-0.017g
BHA 0.001-0.015g
Manner of packing nitrogen-filled seal is packed.
Further, every 100g ready-mixed oil contains following component:
Maize germ oil 68-94 g
Linseed oil 1-20 g
Borage oil 1-28g
'Heijialun ' seed oil 0-20g
TBHQ 0.001-0.017g
BHA 0.001-0.015g
Manner of packing nitrogen-filled seal is packed.
Preferably, every 100g ready-mixed oil contains following component:
Maize germ oil 86g
Linseed oil 4 g
Borage oil 6 g
'Heijialun ' seed oil 4g
TBHQ 0.015g
BHA 0.004g。
Mass fraction proportioning between each component is provided in the compositional range provided above, C18:3 content of fatty acid controls in 1%-10%, preferably control within 1%-8%, be conducive to preventing ready-mixed oil smoke point from reducing, better can stablize the non-oxidizability of ready-mixed oil and keep good frying performance, resistance in storage, be more applicable to Chinese and fry being accustomed to oil of cooking fried.
The mass percent of gamma-Linolenic acid in ready-mixed oil TFA is at 1%-7.5%.
The mass percent of alpha-linolenic acid in ready-mixed oil TFA is at 1%-7.5%.
Ready-mixed oil provided by the invention can strengthen gamma-Linolenic acid and alpha-linolenic acid two kinds of aliphatic acid simultaneously, adapts to the needs of different shortage feature crowd, the more balanced differentiation consumption demand meeting consumer.
Beneficial effect of the present invention is:
The unsaturated fatty acid content of linseed oil up to more than 60%, including abundant human body can not the essential fatty acid alpha-linolenic acid of self synthesis and linoleic acid.Alpha-linolenic acid changes EPA(eicosapentaenoic acid in human body) and DHA(DHA), there is reducing blood lipid, platelet aggregation-against, delay thrombotic curative effect, the metabolism conveying of cholesterol and excretion are played regulatory role.Have and increase intelligence, raising eyesight, adjustment antiallergy, antitumor, life-extending, antidepressant effect.There is hypotensive, develop immunitypty, raising memory health-care effect.But also simultaneously because its unsaturated fatty acid content is high, be therefore easy to oxidation, be unsuitable for high temperature frying and preserve for a long time, and its leukotrienes mostly is alpha-linolenic acid, lacks acid and gamma-linolenic, have impact on its result of use.
Borage oil is derived from American-European countries's traditional medicine food with the seed with crop Common Borage, γ-content of fatty acid in borage oil is up to more than 19%, gamma-Linolenic acid can be used as the intermediate of a lot of bulk drug and medicine, γ-aliphatic acid in vivo metabolism is eicosatrienoic acid (bishomo-γ-linolenic acid), the eicosanoid precursor substances such as arachidonic acid, there is prevention and cure of cardiovascular disease, prevent and treat diabetes, antitumor, anti-curing cancers, protection liver, anti-ageing, strengthen immunity, AntiHIV1 RT activity, anti-inflammation, suppress gastric ulcer and gastrorrhagia, the multiple physiological and pharmacological effects such as treatment skin disease.
Another kind is rich in the light wood 'Heijialun ' seed oil of gamma-Linolenic acid, is oil obtained from black currant seed.The another name currant of blackcurrant, in more plantations in the Northeast such as China Heilungkiang.In 'Heijialun ' seed oil, gamma-linolenic acid content is up to more than 10%, is rich in alpha-linolenic acid more than 14% simultaneously, and Ω 3 serial C18:3 content of fatty acid is high, and unsaturated fatty acid content, more up to about 90%, is applicable to the elderly and Patients with geriatric cardiovascular and cerebrovascular diseases use.Simultaneously because unrighted acid is too high, smoke point is on the low side, and non-oxidizability is slightly poor, not for shelf-stable, and it is not in full use to the benefit of health.
Maize germ oil is rich in the unrighted acid such as oleic acid, linoleic acid, and unsaturated fatty acid content is up to more than 80%.Natural B B-complex E and content of phytosterol higher, intrinsic good antioxidative stabilizer and frying property.So using maize germ oil as base oil; linseed oil, borage oil and 'Heijialun ' seed oil are in harmonious proportion into according to a certain percentage; then fully can solve and carry C18:3 content of fatty acid in strengthening maize germ oil; improve alpha-linolenic acid content particularly gamma-linolenic acid content, stablize the problem of its non-oxidizability and its good frying of protection.
So on the basis of maize germ oil, be in harmonious proportion a kind of be rich in gamma-Linolenic acid borage oil and 'Heijialun ' seed oil and be rich in the linseed oil of alpha-linolenic acid, the nutrition synergy of two kinds of aliphatic acid can be given full play to, look after the somagenic need of special population, expand beneficiaries' scope of maize germ oil.Aforementioned light wood, by rational allocation, using maize germ oil as base oil, is in harmonious proportion by the ready-mixed oil that the present invention determines, to be played stably the antioxygenic property of ready-mixed oil and its good frying effect of protection by natural B B-complex E abundant in maize germ oil; Alpha-linolenic acid and gamma-Linolenic acid, be all essential fatty acid, has nutrition synergy and health care synergy, increases the health-care effect that alpha-linolenic acid and gamma-Linolenic acid will promote corn oil and expand beneficiaries in corn oil.Ready-mixed oil of the present invention is rich in gamma-Linolenic acid simultaneously and alpha-linolenic acid two kinds of C18:3 nutritional labelings have played unique nutrition and health care effect, have been indivisible, and removing merely alpha-linolenic acid or removing merely gamma-Linolenic acid to affect nutrition and health care effect.
In addition, the present invention is also by adding antioxidant TBHQ and BHA, under the coordinating protection of vitamin E, can TBHQ and BHA addition be controlled respectively within 0.001-0.017% or 0.001-0.015% of ready-mixed oil quality, be conducive to the oxidation resistant effect of its collaborative performance; Take maize germ oil as base oil, rationally add borage oil and linseed oil, blackcurrant oil, be conducive to preventing smoke point from reducing, better can stablize the frying performance that the non-oxidizability of ready-mixed oil is good with maintenance, be more applicable to Chinese and fry being accustomed to oil of cooking fried.The present invention is further also good with nitrogen by carrying out filling with inert gas to this ready-mixed oil in Packaging Bottle, is more conducive to the long storage periods of ready-mixed oil.
In the present invention, the mediation of corn oil and linseed oil, borage oil or 'Heijialun ' seed oil, has synergy, shows that the anti-oxidation protection of natural VE is worked in coordination with and the nutrition comprised between the unrighted acid of gamma-Linolenic acid and alpha-linolenic acid etc. is worked in coordination with.
A kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid of the present invention, is rich in abundant natural B B-complex E, phytosterol, and non-oxidizability is stablized, and smoke point value is high, and frying property is good.Be rich in unrighted acid, enhance C18:3 content of fatty acid in maize germ oil, improve alpha-linolenic acid content especially gamma-linolenic acid content, give full play to gamma-Linolenic acid and alpha-linolenic acid and safeguard the collaborative nutrition and health care advantage in the function of the healthy and coordinating intestines and stomach of cardiovascular and cerebrovascular and raising memory etc., the more balanced differentiation consumption demand meeting consumer, expands beneficiaries' scope of maize germ oil.
detailed description of the invention:
In order to understand the present invention better, describe technical scheme of the present invention in detail with instantiation below.
Embodiment 1
Strengthen a corn oil ready-mixed oil for gamma-Linolenic acid and alpha-linolenic acid, contain following component by every 100g ready-mixed oil:
Maize germ oil 86g
Linseed oil 4 g
Borage oil 6 g
'Heijialun ' seed oil 4g
TBHQ 0.015g
BHA 0.004g
Manner of packing nitrogen-filled seal is packed.
Embodiment 2:
Strengthen a corn oil ready-mixed oil for gamma-Linolenic acid and alpha-linolenic acid, contain following component by every 100g ready-mixed oil:
Maize germ oil 80g
Linseed oil 2g
Borage oil 10 g
'Heijialun ' seed oil 8 g
TBHQ 0.008g
BHA 0.012g
Manner of packing nitrogen-filled seal is packed
Embodiment 3:
Strengthen a corn oil ready-mixed oil for gamma-Linolenic acid and alpha-linolenic acid, contain following component by every 100g ready-mixed oil:
Maize germ oil 68g
Linseed oil 2g
Borage oil 25 g
'Heijialun ' seed oil 5 g
TBHQ 0.016g
BHA 0.006g
Manner of packing nitrogen-filled seal is packed
The ready-mixed oil obtained by embodiment 1-3 carries out the detection of aliphatic acid according to GB/T17376-2008 and GB/T17377-2008, vitamin E and sterol detect by NY-T 1598-2008 and GB/T 25223-2010, the detection method of the national standard defined that the indexs such as color and luster, peroxide value, moisture, impurity are quoted by SB/T 10292-1998 detects, result, as table 1, all meets national regulation requirement.
Table 1

Claims (8)

1. strengthen a corn oil ready-mixed oil for gamma-Linolenic acid and alpha-linolenic acid, it is characterized in that, adopt based on maize germ oil, and be in harmonious proportion with linseed oil, borage oil, 'Heijialun ' seed oil, add antioxidant simultaneously and make.
2. a kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid according to claim 1, it is characterized in that, every 100g ready-mixed oil contains following component:
Maize germ oil 66-97 g
Linseed oil 1-33 g
Borage oil 1-33g
'Heijialun ' seed oil 0-33g
TBHQ 0.001-0.017g
BHA 0.001-0.015g
Manner of packing nitrogen-filled seal is packed.
3. a kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid according to claim 2, it is characterized in that, every 100g ready-mixed oil contains following component:
Maize germ oil 68-94 g
Linseed oil 1-20 g
Borage oil 1-28g
'Heijialun ' seed oil 0-20g
TBHQ 0.001-0.017g
BHA 0.001-0.015g
Manner of packing nitrogen-filled seal is packed.
4. a kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid according to claim 3, it is characterized in that, every 100g ready-mixed oil contains following component:
Maize germ oil 86g
Linseed oil 4 g
Borage oil 6 g
'Heijialun ' seed oil 4g
TBHQ 0.015g
BHA 0.004g。
5. a kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid according to claim 1, is characterized in that, the mass percent that C18:3 content of fatty acid accounts for TFA is 1%-10%.
6. a kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid according to claim 5, is characterized in that, the mass percent that C18:3 content of fatty acid accounts for TFA is 1%-8%.
7. a kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid according to claim 5, it is characterized in that, the mass percent of gamma-Linolenic acid in ready-mixed oil TFA is at 1%-7.5%.
8. a kind of corn oil ready-mixed oil strengthening gamma-Linolenic acid and alpha-linolenic acid according to claim 5, it is characterized in that, the mass percent of alpha-linolenic acid in ready-mixed oil TFA is at 1%-7.5%.
CN201510004313.9A 2015-01-06 2015-01-06 Gamma-linolenic acid and alpha-linolenic acid reinforced corn blend oil Pending CN104663922A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106879754A (en) * 2017-03-02 2017-06-23 黄海军 A kind of leukotrienes combined plant ready-mixed oil of nutrition and health care
CN107683908A (en) * 2017-09-08 2018-02-13 陶醒世 Alpha linolenic acid and nervonic acid fortification rapeseed oil and its preparation method and application
CN108741081A (en) * 2018-06-29 2018-11-06 许昌元化生物科技有限公司 One kind containing linolenic composite micro-powder and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1397181A (en) * 2002-02-28 2003-02-19 邵清福 Mixed plant oil containing linolenic acid
CN101466270A (en) * 2006-04-11 2009-06-24 马泰克生物科学公司 Food products comprising long chain polyunsaturated fatty acids and methods for preparing the same
CN102742672A (en) * 2012-07-02 2012-10-24 湖南金点油脂有限公司 Edible blend oil with efficacy of reducing blood fat and blood pressure
CN103859061A (en) * 2012-12-18 2014-06-18 山东西王食品有限公司 Plant blend oil with balanced n-3, n-6 and n-9 series fatty acids

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1397181A (en) * 2002-02-28 2003-02-19 邵清福 Mixed plant oil containing linolenic acid
CN101466270A (en) * 2006-04-11 2009-06-24 马泰克生物科学公司 Food products comprising long chain polyunsaturated fatty acids and methods for preparing the same
CN102742672A (en) * 2012-07-02 2012-10-24 湖南金点油脂有限公司 Edible blend oil with efficacy of reducing blood fat and blood pressure
CN103859061A (en) * 2012-12-18 2014-06-18 山东西王食品有限公司 Plant blend oil with balanced n-3, n-6 and n-9 series fatty acids

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106879754A (en) * 2017-03-02 2017-06-23 黄海军 A kind of leukotrienes combined plant ready-mixed oil of nutrition and health care
CN107683908A (en) * 2017-09-08 2018-02-13 陶醒世 Alpha linolenic acid and nervonic acid fortification rapeseed oil and its preparation method and application
CN108741081A (en) * 2018-06-29 2018-11-06 许昌元化生物科技有限公司 One kind containing linolenic composite micro-powder and preparation method thereof

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