CN103911135A - Oil displacement agent - Google Patents
Oil displacement agent Download PDFInfo
- Publication number
- CN103911135A CN103911135A CN201210594101.7A CN201210594101A CN103911135A CN 103911135 A CN103911135 A CN 103911135A CN 201210594101 A CN201210594101 A CN 201210594101A CN 103911135 A CN103911135 A CN 103911135A
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- CN
- China
- Prior art keywords
- agent
- oil
- total mass
- oil displacement
- accounting
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A provided oil displacement agent is prepared by compounding the following compositions: a) petroleum sulfonates accounting for 30%-70% of the total mass; b) a surfactant auxiliary agent accounting for 20%-30% of the total mass; c) a surfactant synergist accounting for 5%-15% of the total mass; and d) a surfactant solubilizer accounting for 3%-10% of the total mass. The beneficial effects comprise that the oil displacement agent is not added with alkalis, the production process does not pollute environment, the usage amount is 0.4%-0.6%, and the oil displacement agent is small in usage amount and low in cost.
Description
Technical field
The present invention relates to the chemical assistant field in tertiary oil recovery, especially relate to a kind of oil-displacing agent.
Background technology
The rational exploitation and utilization of petroleum-based energy has caused people's very big attention.Because first and second of routine total tar productivity of recovering the oil is not very high, generally only can reach 20%~40%, be up to 50%, also have 50%~80% crude oil to fail extraction.Therefore the in the situation that of being becoming tight in energy day, improving tar productivity has become the key subjects of oil production research, and tertiary oil recovery is a kind of method that especially effectively improves tar productivity.
At present, tertiary oil recovery research obtains people's generally attention with tensio-active agent and microbe oil production, surfactivity is driven and is demonstrated obvious superiority, wherein the main additive of oil driving liquid used is tensio-active agent, generally in using tensio-active agent, a certain amount of alkali or polymkeric substance are added therein, adding of alkali or polymkeric substance can make oil water interfacial tension lower, but, because alkali or polymkeric substance are adsorbed in a large number in stratum, stop up duct, stratum, destroyed stratal configuration, further exploitation has been brought to great difficulty.
Summary of the invention
The object of this invention is to provide a kind of oil-displacing agent that overcomes prior art problem.
Technical scheme of the present invention is: a kind of oil-displacing agent, is composited by following component:
A) sulfonated petro-leum, accounts for the 30%-70% of total mass;
B) surfactant adjuvant, accounts for the 20%-30% of total mass;
C) tensio-active agent synergistic agent 5%-15%;
D) surface active agent solubilization agent 3%-10%.
Further, described surfactant adjuvant is fatty alcohol-polyoxyethylene ether.
Further, described tensio-active agent synergistic agent is polyacrylamide.
Further, described surface active agent solubilization agent is ethanol.
Advantage and positively effect that the present invention has are: oil-displacing agent of the present invention does not need to add bases, environmentally safe in production process, and its consumption is 0.4%-0.6%, and usage quantity is little, and cost is low.
Embodiment
Embodiment mono-:
The preparation of oil-displacing agent: adding in reactor is to have sulfonate 40%, fatty alcohol-polyoxyethylene ether 20%, polyacrylamide 10%, ethanol 6%, be left for water, rising temperature of reaction kettle to 50 DEG C, keeps temperature of reaction, uninterrupted stirring, churning time 1 hour, obtains oil-displacing agent.
The gross weight of oil-displacing agent is 0.6%, and profit system is lonely six crude oil and mineralized water, and side-looking instrument is the TM-500 tensiometer of Biao Wei company, and probe temperature is 70 DEG C, and rotating speed is 5000 revs/min, and interfacial tension is minimum reaches 6 × 10
-5mNm
-1, within 7 minutes, can reach minimum.
Embodiment bis-:
The preparation of oil-displacing agent: adding in reactor is to have sulfonate 60%, fatty alcohol-polyoxyethylene ether 30%, polyacrylamide 5%, ethanol 3%, be left for water, rising temperature of reaction kettle to 70 DEG C, keeps temperature of reaction, uninterrupted stirring, churning time 3 hours, obtains oil-displacing agent.
The gross weight of oil-displacing agent is 0.4%, and profit system is lonely six crude oil and mineralized water, and side-looking instrument is the TM-500 tensiometer of Biao Wei company, and probe temperature is 70 DEG C, and rotating speed is 5000 revs/min, and interfacial tension is minimum reaches 6 × 10
-5mNm
-1, within 5 minutes, can reach minimum.
Embodiment tri-:
The preparation of oil-displacing agent: adding in reactor is to have sulfonate 70%, fatty alcohol-polyoxyethylene ether 20%, polyacrylamide 15%, ethanol 3%, be left for water, rising temperature of reaction kettle to 60 DEG C, keeps temperature of reaction, uninterrupted stirring, churning time 2 hours, obtains oil-displacing agent.
The gross weight of oil-displacing agent is 0.4%, and profit system is lonely six crude oil and mineralized water, and side-looking instrument is the TM-500 tensiometer of Biao Wei company, and probe temperature is 70 DEG C, and rotating speed is 5000 revs/min, and interfacial tension is minimum reaches 6 × 10
-5mNm
-1, within 9 minutes, can reach minimum.
Above one embodiment of the present of invention are had been described in detail, but described content is only preferred embodiment of the present invention, can not be considered to for limiting practical range of the present invention.All equalization variation and improvement etc. of doing according to the present patent application scope, within all should still belonging to patent covering scope of the present invention.
Claims (4)
1. an oil-displacing agent, is characterized in that: be composited by following component:
A) sulfonated petro-leum, accounts for the 30%-70% of total mass;
B) surfactant adjuvant, accounts for the 20%-30% of total mass;
C) tensio-active agent synergistic agent 5%-15%;
D) surface active agent solubilization agent 3%-10%.
2. a kind of oil-displacing agent according to claim 1, is characterized in that: described surfactant adjuvant is fatty alcohol-polyoxyethylene ether.
3. a kind of oil-displacing agent according to claim 1, is characterized in that: described tensio-active agent synergistic agent is polyacrylamide.
4. a kind of oil-displacing agent according to claim 1, is characterized in that: described surface active agent solubilization agent is ethanol.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210594101.7A CN103911135A (en) | 2012-12-31 | 2012-12-31 | Oil displacement agent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210594101.7A CN103911135A (en) | 2012-12-31 | 2012-12-31 | Oil displacement agent |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103911135A true CN103911135A (en) | 2014-07-09 |
Family
ID=51037149
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210594101.7A Pending CN103911135A (en) | 2012-12-31 | 2012-12-31 | Oil displacement agent |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103911135A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104962274A (en) * | 2015-06-17 | 2015-10-07 | 成都高普石油工程技术有限公司 | Composite surfactant for oil exploitation |
CN105001848A (en) * | 2015-06-17 | 2015-10-28 | 成都高普石油工程技术有限公司 | Preparing method for compound chemical flooding used for tertiary oil recovery |
CN111154471A (en) * | 2018-11-07 | 2020-05-15 | 中国石油天然气股份有限公司 | Composite oil displacement agent containing sodium chloride and preparation method thereof |
CN111154472A (en) * | 2018-11-07 | 2020-05-15 | 中国石油天然气股份有限公司 | Ternary composite oil displacement agent and preparation method thereof |
-
2012
- 2012-12-31 CN CN201210594101.7A patent/CN103911135A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104962274A (en) * | 2015-06-17 | 2015-10-07 | 成都高普石油工程技术有限公司 | Composite surfactant for oil exploitation |
CN105001848A (en) * | 2015-06-17 | 2015-10-28 | 成都高普石油工程技术有限公司 | Preparing method for compound chemical flooding used for tertiary oil recovery |
CN111154471A (en) * | 2018-11-07 | 2020-05-15 | 中国石油天然气股份有限公司 | Composite oil displacement agent containing sodium chloride and preparation method thereof |
CN111154472A (en) * | 2018-11-07 | 2020-05-15 | 中国石油天然气股份有限公司 | Ternary composite oil displacement agent and preparation method thereof |
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Legal Events
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C06 | Publication | ||
PB01 | Publication | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140709 |