CN103834347B - Viscose glue, adopt adhesive plaster, the manufacture method of adhesive plaster and application prepared by viscose glue - Google Patents
Viscose glue, adopt adhesive plaster, the manufacture method of adhesive plaster and application prepared by viscose glue Download PDFInfo
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- CN103834347B CN103834347B CN201210472605.1A CN201210472605A CN103834347B CN 103834347 B CN103834347 B CN 103834347B CN 201210472605 A CN201210472605 A CN 201210472605A CN 103834347 B CN103834347 B CN 103834347B
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Abstract
The present invention relates to one and realize seamless bonding, the viscose glue that can repeatedly use and the adhesive plaster adopting this viscose glue to prepare. Silica gel that the main component of this viscose glue includes and viscosifier, the weight of this silica gel accounts for the 40%-60% of this viscose glue overall weight, and the weight of these viscosifier accounts for the 40%-60% of this viscose glue overall weight. This viscose glue has higher active group, can be filled with in the gap on adhesion surface during use, is got rid of by the air in gap, makes colloid adhere to attaching thing surface. Attaching owing to the viscose glue of the present invention relies primarily on the adhesion strength of adsorption-type, therefore it can tear very easily, and will not remain unnecessary colloid in attaching on thing. This viscose glue is utilized to be fabricated to the adhesive plaster of incidentally certain pattern, it is possible to extensive use is such as fishing without hook, hangs all kinds of households, advertisement, the print products such as patch, electronic product pad pasting, has the very big scope of application and market prospect.
Description
[technical field]
The present invention relates to a kind of adhesives, realize particularly to one seamless bonding, the viscose glue that can repeatedly use and the adhesive plaster adopting this viscose glue to prepare.
[background technology]
It is solid that traditional object fixed form mainly includes nail, gluing, absorption. Fixing of relatively solid object, is generally adopted the mode that nail is solid, and its shortcoming is: can stay nail trace, and follow closely trace and cannot repair, also fixed body can be caused damage, also increase fixing difficulty simultaneously, if when rigid condition can be met, generally do not select this fixed form. Relatively lighter object is fixed, is generally adopted gluing or absorption fixed form.
If employing suction type, it is necessary to use electrostatic material, owing to electrostatic material is the new material of development in recent years, the not concrete feature of environmental protection of this new material itself, simultaneously because the viscosity that material behavior makes product is very poor, causes product easily come off and deform.
If employing adhesive means, it is accomplished by adopting and has sticking glue, and adopt existing viscose glue that sticker is attached to basal plane (body of wall, panel, glass etc.) upper after, sticker cannot be taken off again, if tearing sticker or being replaced by new sticker, will sticker being damaged, residual fraction viscose glue on basal plane, causes basal plane very untidy simultaneously. Therefore, adopt the sticker that existing viscose glue is made to be used only once, but also viscose glue can be remained in putting up on basal plane, very impracticable. The more important thing is, existing viscose glue all comprises the volatility additive that some are poisonous, unsuitable life-time service, also human body can be damaged, use very dangerous. In addition, for rough basal plane, gluing mode can only be adopted, will result in above-described defect, for rough surface, just adopt the mode of absorption, but the defect that product easily comes off and deforms can be caused, therefore, face many use environment, unified fixed form cannot be used, significantly limit wideling popularize of viscose glue.
Facing the stickup articles for use that existing viscose glue and viscose glue make and be pasted with residual, it is impossible to reuse, use technical barrier that is dangerous and that use narrow scope, people can make up the defect of prior art by seamless, repeatable, safe viscose glue in the urgent need to a kind of.
[summary of the invention]
For overcoming existing paste adhesive to have residual, it is impossible to reuse, use unsafe technical barrier, the present invention provides a kind of seamless, repeatable, safe viscose glue and the adhesive plaster adopting this viscose glue to prepare.
This invention address that the scheme of technical problem is to provide the manufacture method of a kind of adhesive plaster, including: step S1, it is provided that raw material,
The ratio that various raw materials account for this viscose glue overall weight is as follows:
Account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more; Step S2, carries out mixing, makes phase counterdiffusion or infiltration between each material after being mixed by above-mentioned material; Melting temperature selects to carry out under normal temperature condition, and mixing time is 0.5-2 hour; And step S3, the mixture after mixing being rolled on adhesive layer by calender, makes viscose glue absorption patch, the rolling temperature of this step is maintained in the scope of 120 DEG C-170 DEG C.
Preferably, the manufacture method of adhesive plaster farther includes, step S4, molding printing layer, at the pattern that the preparation of adhesive layer surface needs, forms printing layer; Step S5, prepares adhesive plaster, attaches a protective layer, at upper attaching one release layer of adhesive-layer on printing layer.
Preferably, this printing layer is adopt air brushing mode directly form printing layer on adhesive layer surface or adopt the printing layer prepared in advance paste or be adsorbed on adhesive layer surface.
The present invention further provides a kind of viscose glue, the composition of this viscose glue is as follows: account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more.
The present invention also provides for a kind of adhesive plaster, including protective layer, prints layer, adhesive layer; adhesive-layer and release layer, this five-layer structure is followed successively by protective layer according to mutual stickup order, prints layer, adhesive layer; adhesive-layer and release layer, this adhesive-layer is made by having sticking viscose glue, and the composition of this viscose glue is as follows:
Account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more.
Preferably; this adhesive-layer rolls on this adhesive layer; the material of this adhesive layer is any one of PET, PVC, PP, PE; this printing layer material is any one of PET, PVC, PP, PE or synthetic paper; this protective layer material is any one of PET, PVC, PP or PE, and this release layer material is any one of PE, PVC, PET or release paper.
A kind of electronic product decorating film of the present invention, for being attached to electronic product, this decorating film includes a peel ply, one seamless adhesive-layer, one adhesive layer, one printing layer and a protective layer, this peel ply, seamless adhesive-layer, adhesive layer, the shape and size of printing layer and protective layer are all mated with the shape and size of electronic product wall-attached surface, this peel ply, seamless adhesive-layer, adhesive layer, printing layer and protective layer be closely stacking laminating successively, this seamless adhesive-layer is made by having sticking viscose glue, the composition of this viscose glue is as follows: account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more.
A kind of household articles decorative paste of the present invention, for family product, this decorative paste includes a peel ply, one seamless adhesive-layer, one adhesive layer, one printing layer and a protective layer, this peel ply, seamless adhesive-layer, adhesive layer, the shape and size of printing layer and protective layer are all mated with the shape and size of household articles wall-attached surface, this peel ply, seamless adhesive-layer, adhesive layer, printing layer and protective layer be closely stacking laminating successively, this seamless adhesive-layer is made by having sticking viscose glue, the composition of this viscose glue is as follows: account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more.
Compared with prior art, the viscose glue of the present invention adopts silica gel or resin material and a certain proportion of viscosifier to carry out being mixed the colloid of solid-state, the colloid of this material has higher active group, the gap on adhesion surface can be filled with during use, air in gap is got rid of, makes colloid adhere to attaching thing surface.Attach owing to the viscose glue of the present invention relies primarily on the adhesion strength of adsorption-type, therefore it can tear very easily, and unnecessary colloid will not be remained in attaching on thing, in addition this viscose glue bonding plane active group has very big mobility, if there is booty on surface, can again use again after only need to cleaning, not affect the performance of its surface active groups, it may be achieved repeatedly reuse. The present invention also provides for the manufacture method of this viscose glue, the silica gel material mixture of solid-state is directly rolled on adhesive layer by this manufacture method, and manufacturing process is very simple, and compares liquid-state silicon gel coating technique, the adhesion strength of silica gel can well be maintained, not by the impact of other extraneous factors. This viscose glue is utilized to be fabricated to the adhesive plaster of incidentally certain pattern, it is possible to extensive use is such as fishing without hook, hangs all kinds of households, advertisement, the print products such as patch, electronic product pad pasting, has the very big scope of application and market prospect. The more important thing is, utilize the adhesive plaster that the viscose glue of the present invention makes for smooth wall-attached surface, the content of its viscosifier can be controlled so that it is attach mainly by absorption affinity. For the wall-attached surface that surface ratio is rougher, the content of its viscosifier can be controlled so that it is there is bigger adhesion strength, tightly be attached on attaching thing with coordinating of absorption affinity by adhesion strength. Therefore, the whether smooth bonding articles for use that this viscose glue can be used to make of apparent condition no matter attaching thing attach.
[accompanying drawing explanation]
Fig. 1 is the structural representation that adhesive plaster of the present invention is used as electronic product decorating film.
Fig. 2 is the structural representation that adhesive plaster of the present invention is used as household articles decorative paste.
[detailed description of the invention]
In order to make the purpose of the present invention, technical scheme and advantage are clearly understood, below in conjunction with accompanying drawing and embodiment, the present invention are further elaborated. Should be appreciated that specific embodiment described herein is only in order to explain the present invention, is not intended to limit the present invention.
The main component of the viscose glue of the present invention includes: the silica gel (accounting for the ratio of this viscose glue overall weight) of 40%-60%, the viscosifier (accounting for the ratio of this viscose glue overall weight) of 40%-60%, in this silica gel, active group ratio is 0.1%��10%. This silica gel can be liquid, solid or liquid crystal, one or more of the organic siliconresin that it can be silicone oil, silicone rubber, synthetic resin or organosilicon and resin is mixed into by a certain percentage. These viscosifier are the silane containing alkoxyl, silicon hydrogen-based and reactive organic group or siloxane oligomer, or, Colophonium, modified rosin, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more.
The present invention further provides a kind of manufacture method adopting above-mentioned viscose glue to prepare adhesive plaster, concretely comprise the following steps:
Step one, it is provided that raw material, the proportioning of various raw materials following (the following stated content is the ratio accounting for this raw material overall weight):
Solid silicone rubber (40%-60%),
Viscosifier (40%-60%),
Vulcanizing agent (1-5%),
Serpentis glue (0.1%-1%);
Or,
Solid state synthetic resin (40%-60%),
Viscosifier (40%-60%),
Vulcanizing agent (1-5%),
Serpentis glue (0.1%-1%);
Or,
Solid organosilicon resin (40%-60%),
Viscosifier (40%-60%),
Vulcanizing agent (1-5%),
Serpentis glue (0.1%-1%).
Above-mentioned solid silicone rubber, solid state synthetic resin and solid organosilicon resin can also be liquid or liquid crystal state, and the optimum selection of the present invention is solid feed.
Step 2, mixing. Put into after above-mentioned material being mixed under room temperature mill carries out mixing so that phase counterdiffusion or infiltration between each material. Melting temperature selects to carry out under normal temperature condition, and mixing time is 0.5-2 hour, and optimum efficiency is mixing 1 hour.
Step 3, calendering. Solid mixt after mixing is rolled on adhesive layer by calender, makes certain thickness viscose glue absorption patch. This adhesive layer can be PET (polyethyleneterephthalate, polyethylene terephthalate), PVC (Polyvinylchlorid, polrvinyl chloride), PP (Polypropylene, polypropylene), PE (Polyethylene, polyethylene) etc. there is the material of identical characteristics, in this example, preferred PET is as adhesive layer. The rolling temperature of this step is maintained in the scope of (120 DEG C-170 DEG C).
Step 4, rinses. Viscose glue absorption patch layer of surface after calendering is adhesive-layer adsorption plane, and another surface is the smooth surface without absorption affinity of adhesive layer, is rinsed on two sides with water, keeps the dustless, bright and clean of two sides.
Viscose glue in order to realize the present invention attaches occasion in difference and all has good viscosity, and the present invention provides specific examples below:
Embodiment one, attaching thing is smooth wall-attached surface.
There is provided raw material, the proportioning of various raw materials following (the following stated content is the ratio accounting for this raw material overall weight):
Solid silicone rubber (40%-50%),
Viscosifier (50%-60%),
Vulcanizing agent (1-5%),
Serpentis glue (0.1%-1%);
Or,
Solid state synthetic resin (40%-50%),
Viscosifier (50%-60%),
Vulcanizing agent (1-5%),
Serpentis glue (0.1%-1%);
Or,
Solid organosilicon resin (40%-50%),
Viscosifier (50%-60%),
Vulcanizing agent (1-5%),
Serpentis glue (0.1%-1%).
Put into after above-mentioned material being mixed under room temperature mill carries out mixing so that phase counterdiffusion or infiltration between each material. Melting temperature selects to carry out under normal temperature condition, and mixing time is 0.5-2 hour, and optimum efficiency is mixing 1 hour.
Solid mixt after mixing is rolled on adhesive layer by calender, makes certain thickness viscose glue absorption patch. The rolling temperature of this step is maintained in the scope of (120 DEG C-170 DEG C).
Viscose glue absorption patch layer of surface after calendering is adhesive-layer adsorption plane, and another surface is the smooth surface without absorption affinity of adhesive layer, is rinsed on two sides with water, keeps the dustless, bright and clean of two sides.
Embodiment two, attaching thing is coarse wall-attached surface.
There is provided raw material, the proportioning of various raw materials following (the following stated content is the ratio accounting for this raw material overall weight):
Solid silicone rubber (50%-60%),
Viscosifier (40%-50%),
Vulcanizing agent (1-5%),
Serpentis glue (0.1%-1%);
Or,
Solid state synthetic resin (50%-60%),
Viscosifier (40%-50%),
Vulcanizing agent (1-5%),
Serpentis glue (0.1%-1%);
Or,
Solid organosilicon resin (50%-60%),
Viscosifier (40%-50%),
Vulcanizing agent (1-5%),
Serpentis glue (0.1%-1%).
Put into after above-mentioned material being mixed under room temperature mill carries out mixing so that phase counterdiffusion or infiltration between each material. Melting temperature selects to carry out under normal temperature condition, and mixing time is 0.5-2 hour, and optimum efficiency is mixing 1 hour.
Solid mixt after mixing is rolled on adhesive layer by calender, makes certain thickness viscose glue absorption patch. The rolling temperature of this step is maintained in the scope of (120 DEG C-170 DEG C).
Viscose glue absorption patch layer of surface after calendering is adhesive-layer adsorption plane, and another surface is the smooth surface without absorption affinity of adhesive layer, is rinsed on two sides with water, keeps the dustless, bright and clean of two sides.
Promote the use of in order to the viscose glue of above-mentioned making absorption patch is put in family life, also need the viscose glue adopting above-mentioned manufacture method to make absorption patch is done following process, make adhesive plaster.
Step 5: molding printing layer. In order to make product can provide a pattern with aesthetic to user in the process used, or realize certain instruction, mark effect, at the pattern that the adhesive layer surface preparation that above-mentioned steps is made needs, form printing layer. This printing layer can adopt the usual ways such as air brushing directly to form printing layer on adhesive layer surface. The printing layer prepared in advance can also be adopted to paste or be adsorbed on adhesive layer surface, this printing layer material directly attaching form can be art paper, PET (polyethyleneterephthalate, polyethylene terephthalate), PVC (Polyvinylchlorid, polrvinyl chloride), PP (Polypropylene, polypropylene), PE (Polyethylene, polyethylene), book paper or synthetic paper.
Step 6: prepare adhesive plaster. At adhesive-layer, adhesive layer, after printing layer three layers is combined, adhesive layer is between adhesive-layer and printing layer, and the side surface exposure of printing layer is in outside, and the side surface exposure of adhesive-layer is in outside. Exposed surface at printing layer attaches a protective layer, is used for protecting printing layer and is not scratched in use and wear and tear, and this protective layer can be made up of similar materials such as PET, PVC, PP, PE, and the present invention selects PET as preferred material. Meanwhile; a side surface at adhesive-layer attaches a release layer; release layer is used for protecting this alignment layers; tear this release layer in use; adhesive-layer is pressed on docile thing surface; get rid of adhesive-layer and by the air between wall-attached surface, utilize the stickiness of atmospheric pressure and/or viscose glue to be attached to and docile thing does not fall off. This release layer can be the similar materials such as art paper, PE, PVC, PET, release paper, and the present invention selects PET as preferred material.
Step 7: cut. The adhesive plaster of the five-layer structure (being followed successively by protective layer, print layer, adhesive layer, adhesive-layer, release layer) made above-mentioned size as required cuts manually or automatically. Making the adhesive plaster that different size needs, the more commonly used has: fishing without hook adhesive plaster, to coupling adhesive plaster, mobile phone protection adhesive plaster, notebook computer adhesive plaster, variable color coloured picture adhesive plaster, some conventional household articles adhesive plasters etc.
Refer to Fig. 1; the adhesive plaster utilizing the present invention is fabricated to the decorating film of electronic product; this electronic product decorating film 100 includes a peel ply 101, a seamless adhesive-layer 102, an adhesive layer 103; one printing layer 104 and a protective layer 105; peel ply 101, seamless adhesive-layer 102, adhesive layer 103; printing layer 104 is identical with protective layer 105 shape, and the laminating that is layering successively.
This seamless adhesive-layer 102 is above-mentioned adhesive-layer, and it is that the solid-state viscose glue with certain viscosity is formed, and this seamless adhesive-layer 102 is laminated structure, and thickness can adjust within the scope of 0.02mm-10mm.
Adhesive layer 103 is that one layer of PET material is made, and adhesive layer 103 is laminated structure, and thickness can adjust within the scope of 0.01mm-5mm. Solid-state viscose glue described in seamless adhesive-layer 102 is attached directly on adhesive layer 103 by prolonging compression technology.
Printing layer 104 material can be PET, PVC, PP, PE, book paper or synthetic paper, and printing material can carry out noctilucence simultaneously, toning, and base material color and luster is chosen, and wire printing material etc. processes. This layer can print various pattern. Printing layer 104 fits tightly on adhesive layer 103, and this layer thickness can adjust within the scope of 0.01mm-5mm.
Protective layer 105 material is PET. This layer is transparent sheet-like structure, and thickness is 0.02mm-10mm. Protective layer 105 fits tightly in printing layer 104. This layer had both protected printing layer 104, also can protect electronic product surface, it is prevented that electronic product surface is scratched.
Peel ply 101 material can be art paper, PE, PVC, PET, release paper etc. This layer is laminated structure, and thickness is within the scope of 0.01mm-5mm. Peel ply 101 fits in seamless adhesive-layer 102, is used for protecting seamless adhesive-layer 102 so that it is being not adhered to dust and dirt, in use, peel ply 101 will be stripped.
Shape and the protective layer size of above-mentioned peel ply 101, seamless adhesive-layer 102, adhesive layer 103, printing layer 104 and protective layer 105 all match with the shape and size of electronic product 110 wall-attached surface.
In sum, when using this decorating film 100, can directly this decorating film 100 be pasted onto on electronic product 110 as long as its peel ply 101 is torn off by we. Owing to these decorating film 100 shape and size are mated with the geomery of electronic product 110, therefore, the surface of electronic product 110 is just covered by decorating film 100.
This electronic product decorating film 100 is generally used on mobile phone, notebook computer or panel computer; its surface is protected; prevent from being scratched damage electronic product 110; pass through to print various beautiful pattern on printing layer 104 electronic product 110 is beautified simultaneously, meet the visual enjoyment of consumer.
Referring to Fig. 2, utilize the adhesive plaster of the present invention to be fabricated to the decorative paste 300 of household articles, this decorative paste 300 includes a peel ply 301, a seamless adhesive-layer 302, an adhesive layer 303, printing layer 304 and a protective layer 305. Peel ply 301, adhesive-layer 302, thin layer 303, printing layer 304 is identical with protective layer 305 shape, and close bed stacking adds laminating successively.
This seamless adhesive-layer 302 is above-mentioned adhesive-layer, and it is that the solid-state viscose glue with certain viscosity is formed, and this seamless adhesive-layer 302 is laminated structure, and thickness can adjust within the scope of 0.02mm-10mm.
Adhesive layer 303 is that one layer of PET material is made, and adhesive layer 303 is laminated structure, and thickness can adjust within the scope of 0.01mm-5mm. Solid-state viscose glue described in seamless adhesive-layer 302 is attached directly on adhesive layer 303 by prolonging compression technology.
Printing layer 304 material can be PET, PVC, PP, PE, book paper or synthetic paper, on selected printing layer 304 material, we can adopt the arbitrarily printing board type such as letterpress, lithographic printing, intaglio printing and porous printing to produce required pattern, printing material can carry out noctilucence simultaneously, toning, base material color and luster is chosen, and wire printing material etc. processes. In this layer printing after pattern, printing layer 304 fits tightly on adhesive layer 303, and its thickness can adjust within the scope of 0.01mm-5mm.
Protective layer 305 material is PET. This layer is transparent sheet-like structure, and thickness is within the scope of 0.02mm-10mm. Protective layer 305 fits tightly in printing layer 304. This layer is used for protecting printing layer 304.
Peel ply 301 material can be art paper, PE, PVC, PET, release paper etc.This layer is laminated structure, and thickness is within the scope of 0.02mm-10mm. Peel ply 301 fits in seamless adhesive-layer 302, is used for protecting seamless adhesive-layer 302 so that it is being not adhered to dust and dirt, in use, peel ply 301 will be stripped.
Shape and the protective layer size of above-mentioned peel ply 301, seamless adhesive-layer 302, adhesive layer 303, printing layer 304 and protective layer 305 all match with the shape and size of household articles wall-attached surface.
In sum, when putting up this decorative paste 300, if we its peel ply 301 is torn off can directly this decorative paste 300 is pasted onto on door, on wall, on glass or on other smooth and rougher surfaces.
Compared with prior art, the viscose glue of the present invention adopts silica gel or resin material and a certain proportion of viscosifier to carry out being mixed the colloid of solid-state, the colloid of this material has higher active group, the gap on adhesion surface can be filled with during use, air in gap is got rid of, makes colloid adhere to attaching thing surface. Attach owing to the viscose glue of the present invention relies primarily on the adhesion strength of adsorption-type, therefore it can tear very easily, and unnecessary colloid will not be remained in attaching on thing, in addition this viscose glue bonding plane active group has very big mobility, if there is booty on surface, can again use again after only need to cleaning, not affect the performance of its surface active groups, it may be achieved repeatedly reuse. The present invention also provides for the manufacture method of this viscose glue, the silica gel material mixture of solid-state is directly rolled on adhesive layer by this manufacture method, and manufacturing process is very simple, and compares liquid-state silicon gel coating technique, the adhesion strength of silica gel can well be maintained, not by the impact of other extraneous factors. This viscose glue is utilized to be fabricated to the adhesive plaster of incidentally certain pattern, it is possible to extensive use is such as fishing without hook, hangs all kinds of households, advertisement, the print products such as patch, electronic product pad pasting, has the very big scope of application and market prospect. The more important thing is, utilize the adhesive plaster that the viscose glue of the present invention makes for smooth wall-attached surface, the content of its viscosifier can be controlled so that it is attach mainly by absorption affinity. For the wall-attached surface that surface ratio is rougher, the content of its viscosifier can be controlled so that it is there is bigger adhesion strength, tightly be attached on attaching thing with coordinating of absorption affinity by adhesion strength. Therefore, the whether smooth bonding articles for use that this viscose glue can be used to make of apparent condition no matter attaching thing attach.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all any amendments made within the principle of the present invention, equivalent replacement and improvement etc. all should comprise within protection scope of the present invention.
Claims (8)
1. the manufacture method of an adhesive plaster, it is characterised in that: including:
Step S1, it is provided that raw material,
The ratio that various raw materials account for this viscose glue overall weight is as follows:
Account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more;
Step S2, carries out mixing, makes phase counterdiffusion or infiltration between each material after being mixed by above-mentioned material; Melting temperature selects to carry out under normal temperature condition, and mixing time is 0.5-2 hour; And
Step S3, is rolled the mixture after mixing on adhesive layer by calender, makes viscose glue absorption patch, and the rolling temperature of this step is maintained in the scope of 120 DEG C-170 DEG C.
2. the manufacture method of adhesive plaster as claimed in claim 1, it is characterised in that: farther include,
Step S4, molding printing layer, at the pattern that the preparation of adhesive layer surface needs, form printing layer;
Step S5, prepares adhesive plaster, attaches a protective layer, at upper attaching one release layer of adhesive-layer on printing layer.
3. the manufacture method of adhesive plaster as claimed in claim 2, it is characterised in that: this printing layer is adopt air brushing mode directly form printing layer on adhesive layer surface or adopt the printing layer prepared in advance paste or be adsorbed on adhesive layer surface.
4. a viscose glue, it is characterised in that: adopting the viscose glue that manufacture method as described in the appended claim 1 prepares, the composition of this viscose glue is as follows:
Account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more.
5. an adhesive plaster; it is characterized in that: include protective layer; printing layer, adhesive layer, adhesive-layer and release layer; this five-layer structure is followed successively by protective layer according to mutual stickup order; printing layer, adhesive layer, adhesive-layer and release layer; this adhesive-layer is made by having sticking viscose glue, and the composition of this viscose glue is as follows:
Account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more.
6. adhesive plaster as claimed in claim 5; it is characterized in that: this adhesive-layer rolls on this adhesive layer; the material of this adhesive layer is any one of PET, PVC, PP, PE; this printing layer material is any one of PET, PVC, PP, PE or synthetic paper; this protective layer material is any one of PET, PVC, PP or PE, and this release layer material is any one of PE, PVC, PET or release paper.
7. an electronic product decorating film; for being attached to electronic product; it is characterized in that: this decorating film includes a peel ply, a seamless adhesive-layer, an adhesive layer, printing layer and a protective layer; the shape and size of this peel ply, seamless adhesive-layer, adhesive layer, printing layer and protective layer are all mated with the shape and size of electronic product wall-attached surface; this peel ply, seamless adhesive-layer, adhesive layer, printing layer and protective layer be closely stacking laminating successively; this seamless adhesive-layer is made by having sticking viscose glue, and the composition of this viscose glue is as follows:
Account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more.
8. a household articles decorative paste; for family product; it is characterized in that: this decorative paste includes a peel ply, a seamless adhesive-layer, an adhesive layer, printing layer and a protective layer; the shape and size of this peel ply, seamless adhesive-layer, adhesive layer, printing layer and protective layer are all mated with the shape and size of household articles wall-attached surface; this peel ply, seamless adhesive-layer, adhesive layer, printing layer and protective layer be closely stacking laminating successively; this seamless adhesive-layer is made by having sticking viscose glue, and the composition of this viscose glue is as follows:
Account for the solid silicone rubber of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Or,
Account for the solid state synthetic resin of this viscose glue overall weight 40%-60%,
Account for the viscosifier of this viscose glue overall weight 40%-60%,
Account for the vulcanizing agent of this viscose glue overall weight 1-5%,
Account for the Serpentis glue of this viscose glue overall weight 0.1%-1%;
Any one;
These viscosifier are the silane containing reactive organic group or siloxane oligomer, or, Colophonium, or, terpene resin, terpene phenolic resin, or, copal, Lac, or, coumarone, indene resin one or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210472605.1A CN103834347B (en) | 2012-11-20 | 2012-11-20 | Viscose glue, adopt adhesive plaster, the manufacture method of adhesive plaster and application prepared by viscose glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210472605.1A CN103834347B (en) | 2012-11-20 | 2012-11-20 | Viscose glue, adopt adhesive plaster, the manufacture method of adhesive plaster and application prepared by viscose glue |
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| CN103834347A CN103834347A (en) | 2014-06-04 |
| CN103834347B true CN103834347B (en) | 2016-06-08 |
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Families Citing this family (7)
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|---|---|---|---|---|
| CN104616591B (en) * | 2015-01-10 | 2019-01-01 | 东莞市想联实业投资有限公司 | A kind of antifalsification label and preparation method thereof |
| CN104992620A (en) * | 2015-07-28 | 2015-10-21 | 大族激光科技产业集团股份有限公司 | Self-adhesive label |
| CN105479868A (en) * | 2015-12-26 | 2016-04-13 | 曾程琴 | Machining method of traceless self-adhesive glue |
| CN107189747A (en) * | 2017-07-14 | 2017-09-22 | 芜湖市三山区绿色食品产业协会 | Adhesive for paper food package film and preparation method thereof |
| CN107353860A (en) * | 2017-07-14 | 2017-11-17 | 芜湖市三山区绿色食品产业协会 | For paper food package film and preparation method thereof |
| CN107699149A (en) * | 2017-10-18 | 2018-02-16 | 冯新 | A kind of traffic mark sticker |
| CN113201306A (en) * | 2021-05-11 | 2021-08-03 | 江苏申阳交通装备有限公司 | Silicone rubber traceless repairing organic silicon adhesive and preparation method thereof |
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|---|---|---|---|---|
| CN101417579A (en) * | 2008-12-03 | 2009-04-29 | 中国乐凯胶片集团公司 | Decorating film |
| CN101932329A (en) * | 2008-01-31 | 2010-12-29 | 久光制药株式会社 | Adhesive patch |
| CN201857363U (en) * | 2010-09-03 | 2011-06-08 | 翟晓智 | Environmentally-friendly home decoration paster |
| CN102516895A (en) * | 2011-11-29 | 2012-06-27 | 常熟市富邦胶带有限责任公司 | Method for making self-adhesive insulating tape |
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|---|---|---|---|---|
| JP2865342B2 (en) * | 1989-12-28 | 1999-03-08 | 東洋化学株式会社 | Pressure-sensitive adhesive tape and wound surface protection material |
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|---|---|---|---|---|
| CN101932329A (en) * | 2008-01-31 | 2010-12-29 | 久光制药株式会社 | Adhesive patch |
| CN101417579A (en) * | 2008-12-03 | 2009-04-29 | 中国乐凯胶片集团公司 | Decorating film |
| CN201857363U (en) * | 2010-09-03 | 2011-06-08 | 翟晓智 | Environmentally-friendly home decoration paster |
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