CN103483993B - A kind of low-temperature curable powder coating - Google Patents

A kind of low-temperature curable powder coating Download PDF

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Publication number
CN103483993B
CN103483993B CN201310393362.7A CN201310393362A CN103483993B CN 103483993 B CN103483993 B CN 103483993B CN 201310393362 A CN201310393362 A CN 201310393362A CN 103483993 B CN103483993 B CN 103483993B
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powder coating
low
temperature curable
curable powder
carbon black
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CN201310393362.7A
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CN103483993A (en
Inventor
张洪滨
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Guangdong Pocket Powder Coatings Co.,Ltd.
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BENGBU HONGAN PRECISION MACHINERY Co Ltd
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Abstract

The invention discloses a kind of low-temperature curable powder coating, metaphenylene unsaturated polyester resin 50-60, E-12 epoxy resin 20-25 that it is made up of the raw material of following weight parts, white carbon black 0.1-0.5, lanthanum trioxide 3.5-4.5, activity charcoal powder 10-13, Diisopropyl azodicarboxylate 1-2, water glass 2-3, ferrous sulfate 2-3, resol 1-2, dimethyl silicone oil 0.1-1, compounded mix 10-20; Low-temperature curable powder coating provided by the invention, transparency is high, and solidification value is low, in spraying process, to object thermal pretreatment to 50-70 DEG C, keep 5-8 minute, carry out electrostatic spraying, then through the hot blast 20min of about 120 DEG C, naturally cooling and get final product, be applicable to the application of timber, any surface finish bubble-free, good film-forming property.

Description

A kind of low-temperature curable powder coating
Technical field
The present invention relates generally to a kind of coating, particularly relates to a kind of low-temperature curable powder coating.
Background technology
Its characteristic of powder coating has: 1, this product is not containing toxicity, containing solvent with containing the virose material that volatilizees, therefore without poisoning, without the problem of the public hazards such as discharge of fire, nothing " three wastes ", meet the requirement of national environmental protection method completely.2, utilization rate of raw materials is high, and the powder of the powder supplies business production of some famous brand names, it crosses the powder recoverable of spray, and the highest utilization ratio even can reach more than 99%.3, after coated article pre-treatment, one-off construction, without the need to primary coat, can obtain the film of adequate thickness, easily realize automated operation, production efficiency is high, can reduce costs.4, coating densification, sticking power, resistance to impact shock and toughness are all good, and corner coverage is high, have excellent resistance to corrosive chemicals energy and electrical insulation properties.5, powder coating storage, transportation safety and convenience.
Summary of the invention
The object of the invention is exactly to provide a kind of low-temperature curable powder coating.
The present invention is achieved by the following technical solutions:
A kind of low-temperature curable powder coating, is characterized in that what it was made up of the raw material of following weight parts:
Metaphenylene unsaturated polyester resin 50-60, E-12 epoxy resin 20-25, white carbon black 0.1-0.5, lanthanum trioxide 3.5-4.5, activity charcoal powder 10-13, Diisopropyl azodicarboxylate 1-2, water glass 2-3, ferrous sulfate 2-3, resol 1-2, dimethyl silicone oil 0.1-1, compounded mix 10-20;
Described compounded mix is made up of the raw material of following weight parts:
Gibbsite 30-40, attapulgite 20-30, silicon carbide 6-10, magnesium hydroxide 3-5, carboxymethyl cellulose 1-2, Jojoba oil 2-3;
By above-mentioned gibbsite, attapulgite, silicon carbide mixing, insulation calcining 2-4 hour at 600-800 DEG C, send in ball mill after discharging cooling and carry out ball milling mixing, add magnesium hydroxide and carboxymethyl cellulose again, continue ball milling 1-2 hour, add after Jojoba oil being heated to 25-30 DEG C, ball milling, cross 80-100 mesh sieve, obtain described compounded mix.
A preparation method for low-temperature curable powder coating, comprises the following steps:
By above-mentioned each raw material mixing except white carbon black, send into high-speed mixer, 800-1000 rev/min of dispersed with stirring 3-5 minute, send into forcing machine, melt extrude, be then placed in shredder, add white carbon black, speed lapping under 1000-1200r/min is the screen cloth of 80-100 μm after pore size, obtains described low-temperature curable powder coating.
Advantage of the present invention is:
Low-temperature curable powder coating provided by the invention, transparency is high, good dispersity, solidification value is low, in spraying process, to object thermal pretreatment to 50-70 DEG C, keep 5-8 minute, carry out electrostatic spraying, again through the hot blast 20min of about 120 DEG C, naturally cooling and get final product, is applicable to the application of timber and plastics, any surface finish bubble-free, good film-forming property.
Embodiment
Embodiment 1,
A kind of low-temperature curable powder coating, it is made up of the raw material of following weight parts (kilogram):
Metaphenylene unsaturated polyester resin 60, E-12 epoxy resin 25, white carbon black 0.5, lanthanum trioxide 4.5, activity charcoal powder 13, Diisopropyl azodicarboxylate 2, water glass 3, ferrous sulfate 3, resol 2, dimethyl silicone oil 0.1, compounded mix 10-20;
Described compounded mix is made up of the raw material of following weight parts:
Gibbsite 40, attapulgite 30, silicon carbide 10, magnesium hydroxide 5, carboxymethyl cellulose 1, Jojoba oil 3;
By above-mentioned gibbsite, attapulgite, silicon carbide mixing, calcining is incubated 4 hours at 800 DEG C, send in ball mill after discharging cooling and carry out ball milling mixing, add magnesium hydroxide and carboxymethyl cellulose again, continue ball milling 2 hours, add after Jojoba oil being heated to 30 DEG C, ball milling, cross 100 mesh sieves, obtain described compounded mix.
A preparation method for low-temperature curable powder coating, comprises the following steps:
By above-mentioned each raw material mixing except white carbon black, send into high-speed mixer, 1000 revs/min of dispersed with stirring 3-5 minute, send into forcing machine, melt extrude, be then placed in shredder, add white carbon black, speed lapping under 1200r/min is the screen cloth of 100 μm after pore size, obtains described low-temperature curable powder coating.
Performance test:
Solvent resistant: 240 hours, unchanged;
Salt-fog test (1000h): unchanged.

Claims (1)

1. a low-temperature curable powder coating, is characterized in that it is made up of the raw material of following weight parts:
Metaphenylene unsaturated polyester resin 50-60, E-12 epoxy resin 20-25, white carbon black 0.1-0.5, lanthanum trioxide 3.5-4.5, activity charcoal powder 10-13, Diisopropyl azodicarboxylate 1-2, water glass 2-3, ferrous sulfate 2-3, resol 1-2, dimethyl silicone oil 0.1-1, compounded mix 10-20;
Described compounded mix is made up of the raw material of following weight parts:
Gibbsite 30-40, attapulgite 20-30, silicon carbide 6-10, magnesium hydroxide 3-5, carboxymethyl cellulose 1-2, Jojoba oil 2-3;
By above-mentioned gibbsite, attapulgite, silicon carbide mixing, insulation calcining 2-4 hour at 600-800 DEG C, send in ball mill after discharging cooling and carry out ball milling mixing, add magnesium hydroxide and carboxymethyl cellulose again, continue ball milling 1-2 hour, add after Jojoba oil being heated to 25-30 DEG C, ball milling, cross 80-100 mesh sieve, obtain described compounded mix;
The preparation method of described low-temperature curable powder coating, comprises the following steps:
By above-mentioned each raw material mixing except white carbon black, send into high-speed mixer, 800-1000 rev/min of dispersed with stirring 3-5 minute, send into forcing machine, melt extrude, be then placed in shredder, add white carbon black, speed lapping under 1000-1200r/min is the screen cloth of 80-100 μm after pore size, obtains described low-temperature curable powder coating.
CN201310393362.7A 2013-09-03 2013-09-03 A kind of low-temperature curable powder coating Active CN103483993B (en)

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CN201310393362.7A CN103483993B (en) 2013-09-03 2013-09-03 A kind of low-temperature curable powder coating

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CN103483993B true CN103483993B (en) 2016-02-10

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Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104130604A (en) * 2014-08-08 2014-11-05 唐玉海 Multifunctional normal-temperature curable inorganic powdered paint
CN104845508A (en) * 2015-05-27 2015-08-19 湖州大周高分子材料有限公司 Powder coating
CN105062309A (en) * 2015-07-31 2015-11-18 安徽圣德建材科技有限公司 Weatherproof epoxy powdery paint
CN105062311A (en) * 2015-07-31 2015-11-18 安徽圣德建材科技有限公司 Water-resistant epoxy polyester powdery paint
CN105969125A (en) * 2016-03-29 2016-09-28 刘夏南 Rare earth furniture powder coating and preparation method thereof
CN107033751A (en) * 2016-12-07 2017-08-11 德阳力久云智知识产权运营有限公司 A kind of low temperature cured powder coating and preparation method thereof
CN109251631A (en) * 2018-09-10 2019-01-22 江苏叙然信息科技有限公司 A kind of high temperature resistant cleaning shaft and coating process
CN111701826A (en) * 2020-06-11 2020-09-25 北京傲威环亚家具有限公司 Low-temperature electrostatic powder spraying method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1834174A (en) * 2005-03-16 2006-09-20 嘉善维克托塑化有限公司 Electrostatic powdered paint esp. used for underground valve and prodn. technique
CN101016434A (en) * 2007-02-13 2007-08-15 湖南至诚涂料有限公司 Ultraviolet light ultra-low-temperature solidity powder coating
CN102559019A (en) * 2011-12-29 2012-07-11 文杰 Agate-imitating spray coating material
CN102993921A (en) * 2012-10-24 2013-03-27 宿迁市英杰装饰材料有限公司 Powder coating with low-temperature curing function

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007321113A (en) * 2006-06-05 2007-12-13 Sekisui Jushi Co Ltd Powder coating, coating film layer, coating method and coated article

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1834174A (en) * 2005-03-16 2006-09-20 嘉善维克托塑化有限公司 Electrostatic powdered paint esp. used for underground valve and prodn. technique
CN101016434A (en) * 2007-02-13 2007-08-15 湖南至诚涂料有限公司 Ultraviolet light ultra-low-temperature solidity powder coating
CN102559019A (en) * 2011-12-29 2012-07-11 文杰 Agate-imitating spray coating material
CN102993921A (en) * 2012-10-24 2013-03-27 宿迁市英杰装饰材料有限公司 Powder coating with low-temperature curing function

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Effective date of registration: 20190816

Address after: 510000 Guba West Village, Shawan Town, Panyu District, Guangzhou, Guangdong Province (K Workshop)

Patentee after: Guangdong Pocket Powder Coatings Co.,Ltd.

Address before: 233000 Anhui city of Bengbu province high tech District Road No. 168

Patentee before: BENGBU HONGAN PRECISION MACHINERY Co.,Ltd.

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: A low temperature curable powder coating

Effective date of registration: 20220629

Granted publication date: 20160210

Pledgee: Bank of China Limited Jiangmen Heshan sub branch

Pledgor: Guangdong Pocket Powder Coatings Co.,Ltd.

Registration number: Y2022980009338