Summary of the invention
An object of the present invention is to provide a kind of color make-up color compositions containing nature strength thing namely containing a kind of color make-up color compositions containing Flos Carthami nature strength thing, should be pure natural, safe, bright in luster containing contained Flos Carthami natural pigment of color make-up color compositions of Flos Carthami nature strength thing, should be better containing the color make-up color compositions colour stability of Flos Carthami nature strength thing, color divergence is even, and there is certain antioxidant effect, be applicable to the color make-up pigment such as lipstick.
Two of object of the present invention is to provide the preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami nature strength thing.
Technical scheme of the present invention
Containing a color make-up color compositions for Flos Carthami nature strength thing, comprise water phase components and oil phase component:
Water-soluble liquid nonionic emulsifier, colorant powder, Flos Carthami natural pigment and distilled water that wherein said water phase components is greater than 7 by HLB value mix, calculate in mass ratio, i.e. the HLB value water-soluble liquid nonionic emulsifier that is greater than 7: colorant powder: Flos Carthami natural pigment: distilled water is 1:2:2-10:5:
The water-soluble liquid nonionic emulsifier that wherein said HLB value is greater than 7 is the liquid non-ionic emulsifier being applicable to prepare O/W emulsion, is preferably TWEEN80 etc.;
Described Flos Carthami natural pigment is prepared by the following method:
Flos Carthami is dried after pulverizing, joining mass percent concentration is in the ethanol water of 50%, control Flos Carthami and mass percent concentration be 50% ethanol water by weight volume ratio calculate, i.e. Flos Carthami: obtain mixed liquor after the ratio of mass percent concentration to be 50% ethanol water be 1g:4-20ml mixes;
By the mixed liquor of gained under the ultrasound condition of power 150W, frequency 40kHz, and control temperature is 25 DEG C, and the time is that 15-30min carries out supersound extraction, then uses 0.45 μm of filtering with microporous membrane;
The filtrate obtained after filtration being controlled vacuum is carry out rotary evaporation in vacuo under the condition of 0.094-0.096MPa, obtains Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution control temperature of gained is-55 DEG C and carries out lyophilization, obtain Flos Carthami natural pigment;
Described colorant powder is the mixture that superfine titanic oxide, corn starch or superfine titanic oxide and corn starch form, and the particle diameter of described colorant powder is 50-500nm;
Oil soluble liquid nonionic emulsifier, antiseptic and liquid fat that wherein said oil phase component is less than 7 by HLB value mix;
Wherein HLB value is less than the oil soluble liquid nonionic emulsifier of 7 is the liquid non-ionic emulsifier being applicable to prepare W/O emulsion, and be preferably SPAN80 etc., its consumption is 2 times that HLB value is greater than the quality of the water-soluble liquid nonionic emulsifier of 7;
The consumption of liquid fat is 20 times of distilled water consumption;
The consumption of antiseptic is the 0.1-0.3% of the color make-up color compositions gross mass containing Flos Carthami nature strength thing;
Described liquid fat is one in isopropyl palmitate, Jojoba oil, iso-octyl palmitate, isopropyl myristate, Trivent OCG, tricaprin, white oil, dimethicone, synthesis squalane or two or more;
Described antiseptic is one or more in methyl hydroxybenzoate, ethyl hydroxybenzoate, propyl hydroxybenzoate, butyl hydroxybenzoate.
The preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami nature strength thing, comprises the following steps:
(1), the extraction of Flos Carthami natural pigment
Flos Carthami is dried after pulverizing, joining mass percent is in the ethanol water of 50%, by Flos Carthami and mass percent be 50% ethanol water by weight volume ratio calculate, i.e. Flos Carthami: mass percent be 50% ethanol water be obtain mixed liquor after the ratio of 1g:4-20ml mixes;
By the mixed liquor of above-mentioned gained at power 150W, under the ultrasound condition of frequency 40kHz, and control temperature is 25 DEG C, time is that 15-30min carries out supersound extraction, then 0.45 μm of filtering with microporous membrane is used, the filtrate obtained after filtration being controlled vacuum is carry out rotary evaporation in vacuo under the condition of 0.094-0.096MPa, obtains Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution control temperature of gained is-55 DEG C and carries out lyophilization, obtain Flos Carthami natural pigment;
(2), the preparation of water phase components
Water phase components is obtained after water-soluble liquid nonionic emulsifier distilled water, Flos Carthami natural pigment, colorant powder and HLB value being greater than 7 mixes;
(3), the preparation of oil phase component
Oil phase component is obtained after HLB value being less than the mixing of the oil soluble liquid nonionic emulsifier of 7, antiseptic and liquid fat;
(4), biphase emulsifying mixing
By the water phase components of step (2) gained under the condition stirred, oil phase component poured in water phase components, homogenizing or stirring 5-8min, after making water phase components and oil phase component mix homogeneously, obtain the color make-up color compositions containing Flos Carthami nature strength thing.
Beneficial effect of the present invention
A kind of color make-up color compositions containing Flos Carthami nature strength thing of the present invention, due to the Flos Carthami natural pigment adopted, is natural, therefore harmless.
Further, a kind of color make-up color compositions containing Flos Carthami nature strength thing of the present invention, because Flos Carthami natural pigment is attached on colorant powder, thus improve Flos Carthami natural pigment containing the heat stability in the color make-up color compositions of Flos Carthami nature strength thing, make its covering power higher and not easily decolour.
Further, the preparation method of a kind of color make-up color compositions containing Flos Carthami nature strength thing of the present invention, owing to adopting the method for W/O emulsifying to make the color make-up color compositions containing Flos Carthami nature strength thing of gained be uniformly dispersed, and preparation technology is simple, is suitable for suitability for industrialized production.
Detailed description of the invention
Below by specific embodiment, the present invention is set forth further, but do not limit the present invention.
embodiment 1
Containing a color make-up color compositions for Flos Carthami nature strength thing, comprise water phase components and oil phase component:
Water-soluble liquid nonionic emulsifier, colorant powder, Flos Carthami natural pigment and distilled water that wherein said water phase components is greater than 7 by HLB value mix, calculate in mass ratio, i.e. the HLB value water-soluble liquid nonionic emulsifier that is greater than 7: colorant powder: Flos Carthami natural pigment: distilled water is 1:2:2:5:
The water-soluble liquid nonionic emulsifier that wherein said HLB value is greater than 7 is TWEEN80;
Described Flos Carthami natural pigment is prepared by the following method:
5g Flos Carthami is dried after pulverizing, the mass percent concentration joining 20ml is in the ethanol water of 50%, control the ethanol water volume ratio by weight that Flos Carthami and mass percent concentration are 50%, i.e. Flos Carthami: mass percent concentration be 50% ethanol water be obtain mixed liquor after the ratio of 1g:4ml mixes;
By the mixed liquor of above-mentioned gained under the ultrasound condition of power 150W, frequency 40kHz, and control temperature is 25 DEG C, and the time is that 20min carries out supersound extraction, then uses 0.45 μm of filtering with microporous membrane;
The filtrate obtained after filtration being controlled vacuum is carry out rotary evaporation in vacuo under the condition of 0.094-0.096MPa, obtains Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution control temperature of gained is-55 DEG C and carries out lyophilization, obtain 0.46g Flos Carthami natural pigment;
The superfine titanic oxide of described colorant powder to be particle diameter be 50-500nm;
Oil soluble liquid nonionic emulsifier, antiseptic and liquid fat that wherein said oil phase component is less than 7 by HLB value are obtained by mixing;
Wherein HLB value is less than the oil soluble liquid nonionic emulsifier of 7 is SPAN-80, and its consumption is 2 times that HLB value is greater than the quality of the water-soluble liquid nonionic emulsifier TWEEN80 of 7;
The consumption of liquid fat is 20 times of distilled water consumption;
The consumption of antiseptic is 0.145% of the color make-up color compositions gross mass containing Flos Carthami nature strength thing;
Described liquid fat is isopropyl palmitate, dimethicone calculates by volume, i.e. isopropyl palmitate: dimethicone is the mixture of 1:1 composition;
Described antiseptic is methyl hydroxybenzoate.
The preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami nature strength thing, comprises the following steps:
(1), get 1mL distilled water, add 0.4g Flos Carthami natural pigment, 0.4g superfine titanic oxide, the TWEEN-80 of 0.2g, obtains water phase components after mix homogeneously;
(2), get 10mL dimethicone, 10mL isopropyl palmitate, 0.4gSPAN-80 and 0.03g methyl hydroxybenzoate, after mix homogeneously, obtain oil phase component;
(3), by the water phase components of step (1) gained stir condition under, oil phase component is poured in water phase components, homogenizing or stirring 5min, after making water phase components and oil phase component mix homogeneously, obtain the color make-up color compositions containing Flos Carthami nature strength thing of 20.63g.
The color make-up color compositions containing Flos Carthami nature strength thing of above-mentioned gained, heat 2h through more than 80 DEG C, color is without significant change.
embodiment 2
Containing a color make-up color compositions for Flos Carthami nature strength thing, comprise water phase components and oil phase component:
Water-soluble liquid nonionic emulsifier, colorant powder, Flos Carthami natural pigment and distilled water that wherein said water phase components is greater than 7 by HLB value mix, calculate in mass ratio, i.e. the HLB value water-soluble liquid nonionic emulsifier that is greater than 7: colorant powder: Flos Carthami natural pigment: distilled water is 1:2:2:5:
The water-soluble liquid nonionic emulsifier that wherein said HLB value is greater than 7 is TWEEN80;
Described Flos Carthami natural pigment is prepared by the following method:
The Flos Carthami of 5g is dried after pulverizing, the mass percent concentration joining 50ml is in the ethanol water of 50%, control Flos Carthami and mass percent concentration be 50% ethanol water by weight volume ratio calculate, i.e. Flos Carthami: mass percent concentration be 50% ethanol water be obtain mixed liquor after 1g:10ml mixes;
By the mixed liquor of gained under the ultrasound condition of power 150W, frequency 40kHz, and control temperature is 25 DEG C, and the time is that 15-30min carries out supersound extraction and then uses 0.45 μm of filtering with microporous membrane;
The filtrate obtained after filtration being controlled vacuum is carry out rotary evaporation in vacuo under the condition of 0.094-0.096MPa, obtains Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution control temperature of gained is-55 DEG C and carries out lyophilization, obtain the Flos Carthami natural pigment of 0.53g;
The superfine titanic oxide of described colorant powder to be particle diameter be 50-500nm and particle diameter are that the corn starch of 50-500nm calculates in mass ratio, i.e. superfine titanic oxide: corn starch is the mixture of the ratio composition of 1:1;
Oil soluble liquid nonionic emulsifier, antiseptic and liquid fat that wherein said oil phase component is less than 7 by HLB value mix;
Wherein HLB value is less than the oil soluble liquid nonionic emulsifier of 7 is SPAN-80, and its consumption is 2 times that HLB value is greater than the quality of the water-soluble liquid nonionic emulsifier TWEEN80 of 7;
The consumption of liquid fat is 20 times of distilled water consumption;
The consumption of antiseptic is 0.145% of the color make-up color compositions gross mass containing Flos Carthami nature strength thing;
Described liquid fat is that isopropyl palmitate and dimethicone calculate by volume, i.e. isopropyl palmitate: dimethicone is the mixture of 1:1 composition;
Described antiseptic is methyl hydroxybenzoate.
The preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami nature strength thing, comprises the following steps:
(1), get 1mL distilled water, add 0.4g Flos Carthami natural pigment, 0.2g superfine titanic oxide, 0.2g corn starch, the TWEEN-80 of 0.2g, obtains water phase components after mix homogeneously;
(2), get 10mL dimethicone, 10mL isopropyl palmitate, 0.4g SPAN-80 and 0.03g methyl hydroxybenzoate, after mix homogeneously, obtain oil phase component;
(3), by the water phase components of step (1) gained stir condition under, oil phase component is poured in water phase components, homogenizing or stirring 8min, after making water phase components and oil phase component mix homogeneously, obtain the color make-up color compositions containing Flos Carthami nature strength thing of 20.63g.
The color make-up color compositions containing Flos Carthami nature strength thing of above-mentioned gained, heat 2h through more than 80 DEG C, color is without significant change.
embodiment 3
Containing a color make-up color compositions for Flos Carthami nature strength thing, comprise water phase components and oil phase component:
Water-soluble liquid nonionic emulsifier, colorant powder, Flos Carthami natural pigment and distilled water that wherein said water phase components is greater than 7 by HLB value mix, calculate in mass ratio, i.e. the HLB value water-soluble liquid nonionic emulsifier that is greater than 7: colorant powder: Flos Carthami natural pigment: distilled water is 1:2:5:5;
The water-soluble liquid nonionic emulsifier that wherein said HLB value is greater than 7 is TWEEN80;
Described Flos Carthami natural pigment is prepared by the following method:
The Flos Carthami of 10g is dried after pulverizing, the mass percent concentration adding 200ml is in the ethanol water of 50%, control the ethanol water volume ratio by weight that Flos Carthami and mass percent concentration are 50%, i.e. Flos Carthami: mass percent concentration be 50% ethanol water be obtain mixed liquor after the ratio of 1g:20ml mixes;
By the mixed liquor of gained under the ultrasound condition of power 150W, frequency 40kHz, and control temperature is 25 DEG C, and the time is that 20min carries out supersound extraction, then uses 0.45 μm of filtering with microporous membrane;
The filtrate obtained after filtration being controlled vacuum is carry out rotary evaporation in vacuo under the condition of 0.094-0.096MPa, obtains Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution control temperature of gained is-55 DEG C and carries out lyophilization, obtain the Flos Carthami natural pigment of 1.46g;
The superfine titanic oxide of described colorant powder to be particle diameter be 50-500nm;
Oil soluble liquid nonionic emulsifier, antiseptic and liquid fat that wherein said oil phase component is less than 7 by HLB value are obtained by mixing;
Wherein HLB value is less than the oil soluble liquid nonionic emulsifier of 7 is SPAN-80, and its consumption is 2 times that HLB value is greater than the water-soluble liquid nonionic emulsifier TWEEN80 of 7;
The consumption of liquid fat is 20 times of distilled water consumption;
The consumption of antiseptic is 0.141% of the color make-up color compositions gross mass containing Flos Carthami nature strength thing;
Described liquid fat is that isopropyl palmitate and dimethicone calculate by volume, i.e. isopropyl palmitate: dimethicone is the mixture of 1:1 composition;
Described antiseptic is methyl hydroxybenzoate.
The preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami nature strength thing, comprises the following steps:
(1), get 1mL distilled water, add 1.0g Flos Carthami natural pigment, 0.4g superfine titanic oxide, the TWEEN-80 of 0.2g, obtains water phase components after mix homogeneously;
(2), get 10mL dimethicone, 10mL isopropyl palmitate, 0.4g SPAN-80 and 0.03g methyl hydroxybenzoate, after mix homogeneously, obtain oil phase component;
(3), by the water phase components of step (1) gained stir condition under, oil phase component is poured in water phase components, homogenizing or stirring 8min, after making water phase components and oil phase component mix homogeneously, obtain the color make-up color compositions containing Flos Carthami nature strength thing of 21.23g.
The color make-up color compositions containing Flos Carthami nature strength thing of above-mentioned gained, heat 2h through more than 80 DEG C, color is without significant change.
Above said content be only the present invention conceive under basic explanation, and according to any equivalent transformation that technical scheme of the present invention is done, all should protection scope of the present invention be belonged to.