CN103305003A - Formula of modified polyphenylene sulfide plastic - Google Patents
Formula of modified polyphenylene sulfide plastic Download PDFInfo
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- CN103305003A CN103305003A CN2013102904631A CN201310290463A CN103305003A CN 103305003 A CN103305003 A CN 103305003A CN 2013102904631 A CN2013102904631 A CN 2013102904631A CN 201310290463 A CN201310290463 A CN 201310290463A CN 103305003 A CN103305003 A CN 103305003A
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Abstract
The invention discloses a formula of modified polyphenylene sulfide plastic. The formula includes polyphenylene sulfide plastic and additives, wherein the additives include a flexibilizer, a filling agent, a compatilizer, an anti-impact modifier, and a coupling agent, wherein the flexibilizer is polyvinyl butyral, the filling agent is glass fiber, the compatilizer is m-isopropenyl-2,2-dimethyl benzenesulfonyl isocyanate, the anti-impact modifier is styrene-butadiene copolymer, and the coupling agent is aminopropyltriethoxysilane. The prepared modified polyphenylene sulfide plastic has the characteristics of being high in mechanical and physical properties, good in flexibility, large in anti-impact strength, good in compatibility and the like, the production rate of the modified polyphenylene sulfide plastic can be increased, and the production cost can be lowered.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of modified polyphenyl thioether plastics.
Background technology
Polyphenylene sulfide plastic electrical insulating property (especially high-frequency insulation) is good, the tint permanence water tolerance, and rigidity is fine, and chemical stability is good.Good flame retardant resistance is arranged, for not firing plastics.But intensity own is general, and matter is crisp, easily produces stress embrittlement, the organic solvents such as not anti-benzene, gasoline.Shock strength is low simultaneously, and is mobile general, easily decomposes.
Summary of the invention
The object of the present invention is to provide that a kind of mechanical and physical performance is high, good toughness, resistance to impact shock is large, consistency good, improve the prescription of the modified polyphenyl thioether plastics of throughput rate.
Technical scheme of the present invention is, a kind of prescription of modified polyphenyl thioether plastics, comprise polyphenylene sulfide plastic and additive, described additive comprises toughner, weighting agent, compatilizer, anti-impact modifier and coupling agent, described toughner is polyvinyl butyral acetal, described weighting agent is glass fibre, described compatilizer is meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester, described anti-impact modifier is styrene-butadiene-copolymer, and described coupling agent is aminopropyl triethoxysilane.
In a preferred embodiment of the present invention, each composition weight percent of the prescription of described modified polyphenyl thioether plastics is that polyphenylene sulfide plastic accounts for 75.6%-82.1%, polyvinyl butyral acetal accounts for 2.9%-3.8%, glass fibre accounts for 7.4%-9.8%, meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 1.8%-2.7%, and styrene-butadiene-copolymer accounts for 3.4%-4.6%, and aminopropyl triethoxysilane accounts for 2.4%-3.5%.
In a preferred embodiment of the present invention, each composition weight percent of the prescription of described modified polyphenyl thioether plastics is that polyphenylene sulfide plastic accounts for 76.5%, polyvinyl butyral acetal accounts for 3.7%, glass fibre accounts for 9.6%, meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 2.5%, and styrene-butadiene-copolymer accounts for 4.4%, and aminopropyl triethoxysilane accounts for 3.3%.
Of the present invention is a kind of prescription of modified polyphenyl thioether plastics, makes the characteristics such as the modified polyphenyl thioether plastics machinery physicals that makes is high, good toughness, resistance to impact shock is large, consistency is good, can improve the throughput rate of product simultaneously, reduces production costs.
Embodiment
The below is described in detail preferred embodiment of the present invention, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that protection scope of the present invention is made more explicit defining.
Of the present invention is a kind of prescription of modified polyphenyl thioether plastics, comprise polyphenylene sulfide plastic and additive, described additive comprises toughner, weighting agent, compatilizer, anti-impact modifier and coupling agent, described toughner is polyvinyl butyral acetal, described weighting agent is glass fibre, described compatilizer is meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester, described anti-impact modifier is styrene-butadiene-copolymer, and described coupling agent is aminopropyl triethoxysilane.
Further, each composition weight percent of the prescription of described modified polyphenyl thioether plastics is that polyphenylene sulfide plastic accounts for 75.6%-82.1%, polyvinyl butyral acetal accounts for 2.9%-3.8%, glass fibre accounts for 7.4%-9.8%, meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 1.8%-2.7%, and styrene-butadiene-copolymer accounts for 3.4%-4.6%, and aminopropyl triethoxysilane accounts for 2.4%-3.5%.
Further, each composition weight percent of the prescription of described modified polyphenyl thioether plastics is that polyphenylene sulfide plastic accounts for 76.5%, polyvinyl butyral acetal accounts for 3.7%, glass fibre accounts for 9.6%, meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 2.5%, and styrene-butadiene-copolymer accounts for 4.4%, and aminopropyl triethoxysilane accounts for 3.3%.
Further, each composition weight percent of the prescription of described modified polyphenyl thioether plastics is that polyphenylene sulfide plastic accounts for 81.1%, polyvinyl butyral acetal accounts for 3.1%, glass fibre accounts for 7.6%, meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 2.1%, and styrene-butadiene-copolymer accounts for 3.5%, and aminopropyl triethoxysilane accounts for 2.6%.
Of the present invention is a kind of prescription of modified polyphenyl thioether plastics, makes the characteristics such as the modified polyphenyl thioether plastics machinery physicals that makes is high, good toughness, resistance to impact shock is large, consistency is good, can improve the throughput rate of product simultaneously, reduces production costs.
The above only is the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the prescription of modified polyphenyl thioether plastics, it is characterized in that: comprise polyphenylene sulfide plastic and additive, described additive comprises toughner, weighting agent, compatilizer, anti-impact modifier and coupling agent, described toughner is polyvinyl butyral acetal, described weighting agent is glass fibre, described compatilizer is meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester, described anti-impact modifier is styrene-butadiene-copolymer, and described coupling agent is aminopropyl triethoxysilane.
2. the prescription of modified polyphenyl thioether plastics according to claim 1, it is characterized in that: each composition weight percent of the prescription of described modified polyphenyl thioether plastics is that polyphenylene sulfide plastic accounts for 75.6%-82.1%, polyvinyl butyral acetal accounts for 2.9%-3.8%, glass fibre accounts for 7.4%-9.8%, meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 1.8%-2.7%, and styrene-butadiene-copolymer accounts for 3.4%-4.6%, and aminopropyl triethoxysilane accounts for 2.4%-3.5%.
3. the prescription of modified polyphenyl thioether plastics according to claim 2, it is characterized in that: each composition weight percent of the prescription of described modified polyphenyl thioether plastics is that polyphenylene sulfide plastic accounts for 76.5%, polyvinyl butyral acetal accounts for 3.7%, glass fibre accounts for 9.6%, meta-pseudoallyl-2,2-dimethyl benzoyl isocyanic ester accounts for 2.5%, and styrene-butadiene-copolymer accounts for 4.4%, and aminopropyl triethoxysilane accounts for 3.3%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102904631A CN103305003A (en) | 2013-07-11 | 2013-07-11 | Formula of modified polyphenylene sulfide plastic |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102904631A CN103305003A (en) | 2013-07-11 | 2013-07-11 | Formula of modified polyphenylene sulfide plastic |
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| CN103305003A true CN103305003A (en) | 2013-09-18 |
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| CN2013102904631A Pending CN103305003A (en) | 2013-07-11 | 2013-07-11 | Formula of modified polyphenylene sulfide plastic |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571191A (en) * | 2013-11-08 | 2014-02-12 | 苏州市双赢包装材料有限公司 | Formula of modified polyphenylene sulfide resin |
| CN104045828A (en) * | 2014-07-10 | 2014-09-17 | 苏州新区华士达工程塑胶有限公司 | Polyphenylene sulfide production method |
| CN104231589A (en) * | 2014-10-11 | 2014-12-24 | 江苏宏达拉链制造有限公司 | High-intensity resin zipper |
| CN104974525A (en) * | 2015-07-22 | 2015-10-14 | 广州高八二塑料有限公司 | Polyvinyl-alcohol-fiber-reinforced polyphenyl thioether composite material and preparation method thereof |
| WO2016182212A1 (en) * | 2015-05-14 | 2016-11-17 | 이니츠 주식회사 | Polyarylene sulfide composition having excellent adhesiveness with metal |
| WO2016182215A1 (en) * | 2015-05-14 | 2016-11-17 | 이니츠 주식회사 | Polyarylene sulfide composition with excellent adhesion to metal |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5625002A (en) * | 1988-06-02 | 1997-04-29 | Toray Industries, Inc. | Polyphenylene sulfide composition and shaped articles made therefrom |
| CN101559644A (en) * | 2009-05-15 | 2009-10-21 | 德阳科吉高新材料有限责任公司 | Manufacturing method for high strength polyphenylene sulfide tube |
| CN101619168A (en) * | 2009-08-12 | 2010-01-06 | 深圳市华力兴工程塑料有限公司 | Modified polyphenylene sulfide resin and preparation method thereof |
| CN102408716A (en) * | 2010-06-11 | 2012-04-11 | 提克纳有限责任公司 | Blow molded articles and process for making same |
-
2013
- 2013-07-11 CN CN2013102904631A patent/CN103305003A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5625002A (en) * | 1988-06-02 | 1997-04-29 | Toray Industries, Inc. | Polyphenylene sulfide composition and shaped articles made therefrom |
| CN101559644A (en) * | 2009-05-15 | 2009-10-21 | 德阳科吉高新材料有限责任公司 | Manufacturing method for high strength polyphenylene sulfide tube |
| CN101619168A (en) * | 2009-08-12 | 2010-01-06 | 深圳市华力兴工程塑料有限公司 | Modified polyphenylene sulfide resin and preparation method thereof |
| CN102408716A (en) * | 2010-06-11 | 2012-04-11 | 提克纳有限责任公司 | Blow molded articles and process for making same |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571191A (en) * | 2013-11-08 | 2014-02-12 | 苏州市双赢包装材料有限公司 | Formula of modified polyphenylene sulfide resin |
| CN104045828A (en) * | 2014-07-10 | 2014-09-17 | 苏州新区华士达工程塑胶有限公司 | Polyphenylene sulfide production method |
| CN104231589A (en) * | 2014-10-11 | 2014-12-24 | 江苏宏达拉链制造有限公司 | High-intensity resin zipper |
| WO2016182212A1 (en) * | 2015-05-14 | 2016-11-17 | 이니츠 주식회사 | Polyarylene sulfide composition having excellent adhesiveness with metal |
| WO2016182215A1 (en) * | 2015-05-14 | 2016-11-17 | 이니츠 주식회사 | Polyarylene sulfide composition with excellent adhesion to metal |
| KR20160134050A (en) * | 2015-05-14 | 2016-11-23 | 이니츠 주식회사 | Polyarylene sulfide composition having improved adhesion to metal |
| CN107207856A (en) * | 2015-05-14 | 2017-09-26 | 英驰株式会社 | Polyarylene sulfide composition with excellent metal adhesive |
| CN107207856B (en) * | 2015-05-14 | 2020-10-20 | Sk化学公司 | Polyarylene sulfide composition having excellent metal adhesion |
| KR102289864B1 (en) * | 2015-05-14 | 2021-08-13 | 에스케이케미칼 주식회사 | Polyarylene sulfide composition having improved adhesion to metal |
| CN104974525A (en) * | 2015-07-22 | 2015-10-14 | 广州高八二塑料有限公司 | Polyvinyl-alcohol-fiber-reinforced polyphenyl thioether composite material and preparation method thereof |
| CN104974525B (en) * | 2015-07-22 | 2017-07-04 | 广州高八二塑料有限公司 | Vinal enhancing polyphenyl thioether composite material and preparation method thereof |
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Application publication date: 20130918 |