CN103289473A - Dye-sublimation ink and preparation method thereof - Google Patents
Dye-sublimation ink and preparation method thereof Download PDFInfo
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- CN103289473A CN103289473A CN2013102709766A CN201310270976A CN103289473A CN 103289473 A CN103289473 A CN 103289473A CN 2013102709766 A CN2013102709766 A CN 2013102709766A CN 201310270976 A CN201310270976 A CN 201310270976A CN 103289473 A CN103289473 A CN 103289473A
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- 238000000859 sublimation Methods 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 230000008022 sublimation Effects 0.000 claims abstract description 57
- 239000006185 dispersion Substances 0.000 claims abstract description 32
- 239000003960 organic solvent Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 54
- 239000000975 dye Substances 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- 239000013543 active substance Substances 0.000 claims description 18
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 18
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 229920001732 Lignosulfonate Polymers 0.000 claims description 12
- 230000033444 hydroxylation Effects 0.000 claims description 12
- 238000005805 hydroxylation reaction Methods 0.000 claims description 12
- 235000019357 lignosulphonate Nutrition 0.000 claims description 12
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 6
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 6
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 claims description 6
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 239000001045 blue dye Substances 0.000 claims description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- -1 polyoxyethylene Polymers 0.000 claims description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims description 6
- 239000001044 red dye Substances 0.000 claims description 6
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 6
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000001043 yellow dye Substances 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 5
- 238000005374 membrane filtration Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 14
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000003755 preservative agent Substances 0.000 abstract 2
- 230000002335 preservative effect Effects 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 238000000227 grinding Methods 0.000 abstract 1
- 238000007641 inkjet printing Methods 0.000 abstract 1
- 238000007639 printing Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 206010037660 Pyrexia Diseases 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses dye-sublimation ink and a preparation method thereof. The dye-sublimation ink is adapted to and matched with sixth-generation Epson digital printer nozzle, and is low in cost. The dye-sublimation ink consists of the following components in percentage by mass: 10-40 percent of sublimation dye, 0.5-10 percent of a dispersing agent, 20-40 percent of an organic solvent, 30-60 percent of water, 0.5-2 percent of a surfactant and 0.05-0.2 percent of a preservative. The method for preparing the dye-sublimation ink comprises the following steps of: mixing and grinding the sublimation dye and the dispersing agent, thus obtaining a dispersion solution; adding the organic solvent, deionized water, the surfactant and the preservative into the dispersion solution, and stirring to obtain the dye-sublimation ink. Compared with the prior art, the dye-sublimation ink has high smoothness and stability, is well matched with and adapted to a sixth-generation Epson digital printer and can be used for large-format ink-jet printing of the printer with the sixth-generation Epson nozzle.
Description
Technical field
The present invention relates to a kind of printing ink ink and preparation method thereof, particularly a kind of ink for ink-jet print for Epson the 6th algebraic code printing press shower nozzle and preparation method thereof.
Background technology
Epson the 6th algebraic code printing press (six a generations machine) shower nozzle is single 360 spray orifices, 10 rows have 360 * 10=3600 spray orifice, monochromatic passage, and full accuracy can reach 2880dpi, can realize the printing of ten looks, be all can reach impeccable effect at color gamut or on precision.It is by the control piezoquartz, and ink dot is realized controllability, reaches the minimum 3.5pl ink droplet of ink drop size, the perfect adaptation of realization speed and precision, and whether shower nozzle stops up automatic measuring ability in addition in addition, has effectively guaranteed the perfection of the picture that prints.Its requirement to ink for ink-jet print is also higher on the other hand; on the market much originally on five generations machines print performance preferably ink for ink-jet print be applied on Epson six generations machine; broken string or plug phenomenon appear printing through regular meeting; cause print performance relatively poor; the ink for ink-jet print of prior art is not good to adaptability and the matching of Epson six generations machine; the high-performance of six a generations machine be can not give full play to, very big inconvenience and loss brought to the user.And six generations a machine-specific ink for ink-jet print price higher.
Summary of the invention
The purpose of this invention is to provide a kind of heat sublimation ink and preparation method thereof, the technical problem that solve is to adapt to and coupling Epson the 6th algebraic code printing press shower nozzle, and cost is low.
The present invention is by the following technical solutions: a kind of heat sublimation ink, formed by following mass percent component: sublimation dye 10～40%, dispersion agent 0.5～10%, organic solvent 20～40%, water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%;
The dispersed blue dye that cyan is formed in described sublimation dye employing is numbered more than one in 14,28,56,60,72,73,77,334,336 and 359; Or the dispersive red dye that is used for the composition magenta ink is numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or the disperse yellow dye that is used for the composition yellow ink is numbered 51,54,60,64,65,82,98,119,160 and 211 more than one;
Described dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin that have hydrophilic radical; Described hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen; Described lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10; Described sulfonated lignin are sodium lignosulfonate;
Described organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--in the butyl ether more than one of methyl ether, glycol ether--methyl ether and glycol ether--;
Described tensio-active agent adopts any one or two kinds of among nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and the Surfynol465.
Sublimation dye of the present invention is 15～35%, and organic solvent is 26～38%, and water is 30～50%.
Water of the present invention is 35.4～43.4%.
Dispersion agent of the present invention adopts the lignosulfonic acid sodium salt.
Sanitas of the present invention adopts Proxel GXL.
Sublimation dye of the present invention, dispersion agent, organic solvent, tensio-active agent and sanitas industrial pure material, water are deionized water.
A kind of preparation method of heat sublimation ink may further comprise the steps:
One, under the room temperature, by mass percentage, after sublimation dye 10～40% and dispersion agent 0.5～10% mixing, use the zirconium pearl of diameter 0.25-0.35mm, the volume ratio of sublimation dye and dispersion agent sum and zirconium pearl is 1:6, rotating speed 2200～2800r/min, grind and disperse 24h, obtain dispersion liquid;
The dispersed blue dye that cyan is formed in described sublimation dye employing is numbered more than one in 14,28,56,60,72,73,77,334,336 and 359; Or the dispersive red dye that is used for the composition magenta ink is numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or the disperse yellow dye that is used for the composition yellow ink is numbered 51,54,60,64,65,82,98,119,160 and 211 more than one;
Described dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin that have hydrophilic radical; Described hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen; Described lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10; Described sulfonated lignin are sodium lignosulfonate.
Two, in dispersion liquid, add organic solvent 20～40%, deionized water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%, rotating speed 2200～2800r/min behind the stirring 60min, uses the 0.22u membrane filtration, obtains heat sublimation ink;
Described organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--in the butyl ether more than one of methyl ether, glycol ether--methyl ether and glycol ether--;
Described tensio-active agent adopts any one or two kinds of combinations among nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and the Surfynol465.
Described sanitas adopts Proxel GXL;
Described sublimation dye, dispersion agent, organic solvent, tensio-active agent, sanitas industrial pure material.
Method sublimation dye of the present invention is 15～35%, and organic solvent is 26～38%, and deionized water is 30～50%.
Method deionized water of the present invention is 35.4～43.4%.
Method powder of the present invention adopts the lignosulfonic acid sodium salt.
The present invention compared with prior art, heat sublimation ink has good fluency and stability, and Epson the 6th algebraic code printing press is had good matching and adaptability, the large-format ink-jet that can be used for Epson six generations machine is printed.
Embodiment
Be described in further detail below in conjunction with the present invention of embodiment.
Heat sublimation ink of the present invention is made up of following mass percent component: sublimation dye 10～40%, dispersion agent 0.5～10%, organic solvent 20～40%, water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%.
Be preferably: sublimation dye 15～35%, organic solvent 26～38%, water 30～50%.
More preferably: water 35.4～43.4%.
Sublimation dye adopts the dyestuff of prior art: the dispersed blue dye that is used for the composition cyan is numbered more than one of 14,28,56,60,72,73,77,334,336 and 359; Or the dispersive red dye that is used for the composition magenta ink is numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or the disperse yellow dye that is used for the composition yellow ink is numbered 51,54,60,64,65,82,98,119,160 and 211 more than one.
Dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin that have hydrophilic radical.The hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen, and the lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10, and sulfonated lignin are sodium lignosulfonate.Be preferably the lignosulfonic acid sodium salt.
Organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--in the butyl ether more than one of methyl ether, glycol ether--methyl ether and glycol ether--.
Tensio-active agent adopts any one or two kinds of combination among nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and the Surfynol465.
Sanitas adopts Proxel GXL.
Sublimation dye, dispersion agent, organic solvent, tensio-active agent and sanitas industrial pure material, water are deionized water.
Heat sublimation ink of the present invention, viscosity are 3～7mPa.s, and surface tension is 20～45mN/m, dissolved oxygen content DO value≤2PPM.Viscosity is 3～5mPa.s preferably, and good surface tension is 20～40mN/m.
The preparation method of heat sublimation ink of the present invention may further comprise the steps:
One, under the room temperature (20 ℃), by mass percentage, after sublimation dye 10～40% and dispersion agent 0.5～10% mixing, in sand mill, use the zirconium pearl of diameter 0.25-0.35mm, the volume ratio of sublimation dye and dispersion agent sum and zirconium pearl is 1:6, rotating speed 2200～2800r/min grinds and disperses 24h, obtains dispersion liquid.
Two, dispersion liquid is put into reactor, add organic solvent 20～40%, deionized water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%, rotating speed 600～800r/min behind the stirring 60min, uses the 0.22u membrane filtration, obtains heat sublimation ink.
Be preferably: sublimation dye 15～35%, organic solvent 26～38%, deionized water 30～50%.
More preferably: deionized water 35.4～43.4%.
Sublimation dye adopts the dyestuff of prior art: the dispersed blue dye that is used for the composition cyan is numbered more than one of 14,28,56,60,72,73,77,334,336 and 359; Or the dispersive red dye that is used for the composition magenta ink is numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or the disperse yellow dye that is used for the composition yellow ink is numbered 51,54,60,64,65,82,98,119,160 and 211 more than one.
Dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin that have hydrophilic radical.The hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen, and the lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10, and sulfonated lignin are sodium lignosulfonate.Be preferably the lignosulfonic acid sodium salt.
Organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--in the butyl ether more than one of methyl ether, glycol ether--methyl ether and glycol ether--.
Tensio-active agent adopts any one or two kinds of combinations among nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and the Surfynol465.
Sanitas adopts Proxel GXL.
Sublimation dye, dispersion agent, organic solvent, tensio-active agent, sanitas industrial pure material.
Component and the processing parameter of embodiment 1-3 see Table 1.
The heat sublimation ink of the embodiment 1-3 that the inventive method prepares, viscosity test is set to 30 ℃ ﹠amp with the digital viscometer of DV-II+Pro type; 60rpm; Surface tension is tested with the full-automatic surface tension instrument of BZY-1, platinum plate method; Dissolved oxygen content DO value adopts the test of Hana HI9146 dissolved oxygen meter, and test result sees Table 2.
Comparative Examples 1 adopts the blue fever transfer printing ink (martial prowess C) of the general icepro of Chinese Zhuhai martial prowess trade Co., Ltd, presses the identical method tested viscosity of embodiment 1-3, surface tension, dissolved oxygen content DO value, and test result sees Table 2.
Comparative Examples 2, adopting the country of origin is Italy, retailer is the yellow heat sublimation ink (ten thousand exquisite Y) of the exquisite chemical industry of Kai Angwan (Shanghai) Co., Ltd., presses the identical method tested viscosity of embodiment 1-3, surface tension, dissolved oxygen content DO value, and test result sees Table 2.
As can be seen from Table 2, the viscosity of embodiment 1-3 is less than Comparative Examples 1-2, surface tension is less than Comparative Examples 1-2, the DO value is less, viscosity and surface tension be low guarantees that ink has good flowability and to the adaptability of shower nozzle, the less bubble that reduces to greatest extent in the ink of DO value influences the ink fluency in print procedure.
The heat sublimation ink of the embodiment 1-3 that the inventive method prepares and the ink of Comparative Examples 1-2 are got 1000ml respectively, print having Epson six generations machine EPSON7710 ink-jet printer, to detect the printing fluency of ink.Print media is heat-transferring printing paper, and ink printed fluency test result sees Table 3.
The assessment method of ink fluency test is:
A level: print 1000ml continuously, print the smooth broken string that do not have;
B level: print 1000ml continuously, print procedure interrupt line＜3 lattice;
C level: print 1000ml continuously, print procedure interrupt line 〉=3 lattice test printing fluencies.
According to test result, illustrate that the heat sublimation ink that the inventive method prepares has good matching and adaptability, have good fluency in Epson six generations machine printing.
Component and the processing parameter of table 1 embodiment 1-3
The heat sublimation ink of table 2 embodiment 1-3 and Comparative Examples 1-2 tested viscosity, surface tension, dissolved oxygen content DO value
The heat sublimation ink of table 3 embodiment 1-3 and Comparative Examples 1-2 ink printed fluency test result
| Embodiment and Comparative Examples | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative Examples 1 | Comparative Examples 2 |
| The fluency test | A | A | A | C | C |
Claims (10)
1. heat sublimation ink, it is characterized in that: described heat sublimation ink is made up of following mass percent component: sublimation dye 10～40%, dispersion agent 0.5～10%, organic solvent 20～40%, water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%;
The dispersed blue dye that cyan is formed in described sublimation dye employing is numbered more than one in 14,28,56,60,72,73,77,334,336 and 359; Or the dispersive red dye that is used for the composition magenta ink is numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or the disperse yellow dye that is used for the composition yellow ink is numbered 51,54,60,64,65,82,98,119,160 and 211 more than one;
Described dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin that have hydrophilic radical; Described hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen; Described lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10; Described sulfonated lignin are sodium lignosulfonate;
Described organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--in the butyl ether more than one of methyl ether, glycol ether--methyl ether and glycol ether--;
Described tensio-active agent adopts any one or two kinds of among nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and the Surfynol465.
2. heat sublimation ink according to claim 1, it is characterized in that: described sublimation dye is 15～35%, and organic solvent is 26～38%, and water is 30～50%.
3. heat sublimation ink according to claim 1, it is characterized in that: described water is 35.4～43.4%.
4. heat sublimation ink according to claim 1 is characterized in that: described dispersion agent employing lignosulfonic acid sodium salt.
5. heat sublimation ink according to claim 1 is characterized in that: described sanitas employing ProxelGXL.
6. according to each described heat sublimation ink in the claim 1 to 5, it is characterized in that: described sublimation dye, dispersion agent, organic solvent, tensio-active agent and sanitas industrial pure material, water are deionized water.
7. the preparation method of a heat sublimation ink may further comprise the steps:
One, under the room temperature, by mass percentage, after sublimation dye 10～40% and dispersion agent 0.5～10% mixing, use the zirconium pearl of diameter 0.25-0.35mm, the volume ratio of sublimation dye and dispersion agent sum and zirconium pearl is 1:6, rotating speed 2200～2800r/min, grind and disperse 24h, obtain dispersion liquid;
The dispersed blue dye that cyan is formed in described sublimation dye employing is numbered more than one in 14,28,56,60,72,73,77,334,336 and 359; Or the dispersive red dye that is used for the composition magenta ink is numbered 4,22,55,59,60,146,152,191 and 302 more than one; Or the disperse yellow dye that is used for the composition yellow ink is numbered 51,54,60,64,65,82,98,119,160 and 211 more than one;
Described dispersion agent adopts xylogen, hydroxylation xylogen, lignosulfonic acid sodium salt or the sulfonated lignin that have hydrophilic radical; Described hydroxylation xylogen is phenolic group xylogen, hydroxyl xylogen or carboxyl xylogen; Described lignosulfonic acid sodium salt is NP-6, NP-10, TX-4 or TX-10; Described sulfonated lignin are sodium lignosulfonate.
Two, in dispersion liquid, add organic solvent 20～40%, deionized water 30～60%, tensio-active agent 0.5～2%, sanitas 0.05～0.2%, rotating speed 2200～2800r/min behind the stirring 60min, uses the 0.22u membrane filtration, obtains heat sublimation ink;
Described organic solvent is ethylene glycol, polyoxyethylene glycol, glycol ether, butyleneglycol, triglycol, propylene glycol, polypropylene glycol, glycerine, ethylene glycol--in the butyl ether more than one of methyl ether, glycol ether--methyl ether and glycol ether--;
Described tensio-active agent adopts any one or two kinds of combinations among nonionogenic tenside, anion surfactant, zwitterionics APEO, AEO, Surfynol604 and the Surfynol465.
Described sanitas adopts Proxel GXL;
Described sublimation dye, dispersion agent, organic solvent, tensio-active agent, sanitas industrial pure material.
8. the preparation method of heat sublimation ink according to claim 7, it is characterized in that: described sublimation dye is 15～35%, and organic solvent is 26～38%, and deionized water is 30～50%.
9. the preparation method of heat sublimation ink according to claim 8, it is characterized in that: described deionized water is 35.4～43.4%.
10. the preparation method of heat sublimation ink according to claim 7 is characterized in that: described dispersion agent employing lignosulfonic acid sodium salt.
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| CN103450740A (en) * | 2013-09-29 | 2013-12-18 | 山东德创喷墨科技有限公司 | Sublimation ink-jetting ink used for industrial nozzle and manufacturing method thereof |
| CN105348919A (en) * | 2015-12-22 | 2016-02-24 | 中国科学院福建物质结构研究所 | Thermal transfer printing inkjet ink composition and preparation method thereof |
| CN105542568A (en) * | 2016-03-08 | 2016-05-04 | 珠海保税区天然宝杰数码科技材料有限公司 | Thermal sublimation ink for low-gram-weight transfer paper and printing method of thermal sublimation ink |
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| CN106497238A (en) * | 2016-11-28 | 2017-03-15 | 南通纳威数码材料科技有限公司 | A kind of superfine disperse dye yellow mill base and preparation method thereof |
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| CN106590178A (en) * | 2016-11-28 | 2017-04-26 | 南通纳威数码材料科技有限公司 | Ultrafine disperse dye red color paste and preparation method of same |
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| CN107083113A (en) * | 2017-05-24 | 2017-08-22 | 安徽正洁高新材料股份有限公司 | A kind of high stability heat sublimation ink based on dispersed blue dye and preparation method thereof |
| CN107201681A (en) * | 2017-05-24 | 2017-09-26 | 安徽正洁高新材料股份有限公司 | A kind of heat sublimation ink based on disperse yellow dye and preparation method thereof |
| CN108504190A (en) * | 2018-03-13 | 2018-09-07 | 深圳市墨库图文技术有限公司 | A kind of coating heat-transferring printing paper ink and preparation method thereof |
| EP3597818A1 (en) * | 2018-07-19 | 2020-01-22 | Artech GmbH design + production in plastic | Ink composition for direct sublimation printing |
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| CN109487578A (en) * | 2018-12-04 | 2019-03-19 | 深圳市墨库图文技术有限公司 | Thief zone heat sublimation ink and preparation method thereof |
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