CN103154182B - The auxiliary dispersion liquid of petroleum drilling - Google Patents
The auxiliary dispersion liquid of petroleum drilling Download PDFInfo
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- CN103154182B CN103154182B CN201180048958.2A CN201180048958A CN103154182B CN 103154182 B CN103154182 B CN 103154182B CN 201180048958 A CN201180048958 A CN 201180048958A CN 103154182 B CN103154182 B CN 103154182B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/588—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/504—Compositions based on water or polar solvents
- C09K8/506—Compositions based on water or polar solvents containing organic compounds
- C09K8/508—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/5086—Compositions based on water or polar solvents containing organic compounds macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/06—Clay-free compositions
- C09K8/12—Clay-free compositions containing synthetic organic macromolecular compounds or their precursors
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/504—Compositions based on water or polar solvents
- C09K8/506—Compositions based on water or polar solvents containing organic compounds
- C09K8/508—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/512—Compositions based on water or polar solvents containing organic compounds macromolecular compounds containing cross-linking agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C09K8/70—Compositions for forming crevices or fractures characterised by their form or by the form of their components, e.g. foams
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
- C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/885—Compositions based on water or polar solvents containing organic compounds macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/08—Fiber-containing well treatment fluids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/18—Bridging agents, i.e. particles for temporarily filling the pores of a formation; Graded salts
Abstract
A kind of by the micro-solid shape polyglycolic acid resin dispersion auxiliary dispersion liquid of petroleum drilling in an aqueous medium, described micro-solid shape polyglycolic acid resin is 70 by weight-average molecular weight, more than 000 500, the polyglycolic acid resin of less than 000 is formed, its weight conservation rate in the water of 80 DEG C is, is be after less than 80%, 168 hours be less than 45% after more than 85%, 72 hours after 12 hours.Above-mentioned petroleum drilling assists the micro-solid shape polyglycolic acid resin with containing in dispersion liquid, in the drilling operation that Oil Generation output expands again, play mobility control the effect of material, the recovery of the liquid permeability after its suppression for the operation initial stage liquid permeability of the oil well surrounding formations required and the end of job has desirable decomposability.
Description
Technical field
The auxiliary dispersion liquid of drilling well that can use well in the operation that to the present invention relates in the mine pit probing of the hydrocarbon that to reclaim with oil and gas at lower temperature (40 ~ 80 DEG C) be representative or amplify in production fluid recovery amount.
Background technology
In order to reclaim from underground the hydrocarbon compound (being hereinafter called typically " oil ") being representative with oil and gas, and excavate the mine pit (being hereinafter often called typically " oil well ") of oil well, gas well etc.While make muddy water flow back and forth in shaft, while carry out the operation of drilling well with rig, and add afterwards and carry out following operation: break up fluid (fracturing fluid) is injected into Zhong Shi stratum, stratum and produces be full of cracks, thus the operation of expanding production amount (pressure break).Originally, stratum (formation) liquid permeability of oil well periphery was high, this from promote oil from stratum by, to flow into the viewpoint of oil well be good, but in drilling operation and pressure break, from the viewpoint of operating efficiency, have and want suppression fluid to the situation of transparent liquid in stratum suddenly.This, for such as, prevents the operation water such as muddy water from passing through and overflowing to be necessary from existing oil well wall.The suppression of liquid permeability mainly by be mixed in the inorganic particulate of sandstone, calcium carbonate etc. in operation water etc. or guar gum (guar) isogel shape organism etc. temporarily stifled material (agent) realize, the recovery of suppressed liquid permeability, by the dissolving of the inorganics temporary plugging agents such as acid or by using gel organic substance decomposing agent (gel breaker) to realize.These materials are generally collectively referred to as mobility and control material (fluid loss (control) additives) or diverting agent (diverting agent).On the other hand, propose some in recent years polyglycolic acid, poly(lactic acid) etc. to be had water-disintegrable aliphatic polyester and control as mobility the scheme (patent documentation 1 ~ 4 etc.) that material (and/or gel decomposition agent) uses separately or together with the dissolution aids such as alkaline source.These aliphatic polyesters are at least passing through and can obtain water-disintegrable faster at the temperature of more than 80 DEG C used (pressurization) water vapour and obtain, thus the recovery of the liquid permeability having made suppressed difficult especially during mobility is controlled more successfully realizes.Particularly, control material as the mobility also under the low temperature of 40 ~ 80 DEG C with gratifying hydrolysis rate, propose the polyglycolic acid resin that molecular weight is the oligopolymer scope such as 200 ~ 4000 (patent documentations 1) or 200 ~ 600 (patent documentations 2 and 4) in a large number.
Prior art document
Patent documentation
Patent documentation 1: United States Patent (USP) the 4th, 715, No. 967 specification sheetss
Patent documentation 2: United States Patent (USP) the 4th, 986, No. 353 specification sheetss
Patent documentation 3: United States Patent (USP) the 7th, 265, No. 079 specification sheets
Patent documentation 4: United States Patent (USP) the 7th, 066, No. 260 specification sheetss
Summary of the invention
The problem that invention will solve
In view of the situation of above-mentioned prior art, main purpose of the present invention is to provide the auxiliary dispersion liquid of petroleum drilling controlling material containing mobility that have more versatility than ever, that be more suitable for using at low temperatures.
Solve the means of problem
Petroleum drilling of the present invention is assisted and is completed to achieve these goals with dispersion liquid, it is characterized in that, micro-solid shape polyglycolic acid resin is made to disperse to form in an aqueous medium, described micro-solid shape polyglycolic acid resin is 70 by weight-average molecular weight, more than 000 500, the polyglycolic acid resin of less than 000 is formed, and its weight conservation rate in the water of 80 DEG C is: be after less than 80%, 168 hours be less than 45% after more than 85%, 72 hours after 12 hours.
According to the understanding of the present inventor etc., the aforesaid polyglycolic acid resin with oligopolymer Range molecular weight, even if be adapted at using compared with in the mine pit probing carried out in short-term and frac job, but control material as the mobility used in the operation between more extensive, longer-term, too short between liquid permeability inhibition period.The present inventor etc. are under above-mentioned cognition and then study; found that; use the polyglycolic acid resin of more macromolecule to extend between mobility inhibition period and between the decubation of the liquid permeability using undersized micro-solid (particulate or staple fibre) to regulate suppressed; ideal like this, be based on the recognition and complete the invention described above.The mobility formed by the polyglycolic acid resin with molecular weight such in the present invention controls material, and compared with controlling material with the mobility formed by other aliphatic polyester proposed in the past, advantage is summarized as follows.
(I) the first, compared with the existing polyglycolic acid resin with the molecular weight of oligopolymer scope, at least at the low-temperature region of 40 ~ 80 DEG C, can obtain between fully long liquid permeability inhibition period.
(II) compared with other aliphatic polyester such as poly(lactic acid), at least when micro-solid shape, even if also there is the water-disintegrable of appropriateness in the neutral water of low temperature, between the decubation of the liquid permeability that can shorten suppressed.In addition, although polycaprolactone (PCL) can not keep micro-solid shape and consolidated block in decomposition, but polyglycolic acid resin weight can occur when keeping its micro-solid shape reduces (thereupon, size reduce), so the recovery easily carrying out liquid permeability controls.
(III) in general, aliphatic polyester is comminuted and bad.In order to form particulate to shorten between liquid permeability decubation, general preferred powder fragility is good, but the polyglycolic acid resin of such molecular weight ranges used in the present invention demonstrates better more comminuted than other aliphatic polyesters such as poly(lactic acid) at least under cryogenic, the particulate of desired size can be obtained with higher yield.
The characteristic of above-mentioned (I) ~ (III) is all the contrasts by aftermentioned embodiment and comparative example, confirms through test.In addition, polyglycolic acid resin has higher crystallization degree than other aliphatic polyester, by during fabrication with manufacture after thermal history can also improve further comminuted.
Embodiment
Below the present invention is specifically described according to its preferred implementation.
(polyglycolic acid resin)
The polyglycolic acid resin used in the present invention, except only containing glycolic acid units (-OCH as repeating unit
2-CO-) glycolic acid homopolymer (i.e. polyglycolic acid) beyond, also comprise the ethanol copolymer of the hydroxycarboxylic acid unit containing other monomer (comonomer) unit, preferably lactic acid etc. with the ratio of less than 10 % by weight.By using the multipolymer comprising other monomeric unit, to a certain degree can regulate the hydrolysis rate, crystallinity etc. of polyglycolic acid resin, but be greater than 10 % by weight and containing sometimes, the excellent specific property of the above-mentioned polyglycolic acid (resin) used in the present invention can be destroyed, so not preferred.
As polyglycolic acid resin, use weight-average molecular weight is the polyglycolic acid resin of 70,000 ~ 500,000.If weight-average molecular weight is lower than 70,000, then water-disintegrable excessive, be difficult to obtain between the desirable liquid permeability inhibition period required for mine pit probing and frac job.If weight-average molecular weight is greater than 500,000 on the other hand, then comminuted variation, molding processibility becomes not enough, is difficult to the advantage obtaining polymer quantification.
In order to obtain the polyglycolic acid resin of this macromolecule, compared with the polymerization of oxyacetic acid, more preferably following methods is taked: make the dimer of oxyacetic acid and glycollide at a small amount of catalyzer (such as, the cationic catalysts such as organic carboxyl acid tin, tin halides, antimony halides) existence under and under there is not in fact the condition of solvent (i.e. bulk polymerization conditions), be heated to the temperature of about 120 ~ 250 DEG C, make its ring-opening polymerization.Therefore, when forming multipolymer, preferably use such as comonomer, more than a kind in the lactides being representative with the dimer of lactic acid and rac-Lactide, lactone (such as, caprolactone, beta-propiolactone, beta-butyrolactone).
It should be noted that, the fusing point (Tm) of polyglycolic acid resin is generally more than 200 DEG C.Such as, the fusing point of polyglycolic acid is about 220 DEG C, and second-order transition temperature is about 38 DEG C, and crystallized temperature is about 90 DEG C.But the fusing point of these polyglycolic acid resins can change to some extent according to kind of the comonomer of the molecular weight of polyglycolic acid resin, use etc.
Normally formed separately by polyglycolic acid resin as the micro-solid of mobility control materials'use in the present invention, but for controlling its decomposability, comminuted etc. object, other aliphatic polyester (such as, for obtaining homopolymer or the multipolymer of the comonomer of above-mentioned ethanol copolymer) can also be coordinated or comprise the monomer of aliphatic polyester of oxyacetic acid (or glycollide).But its use level, in order to not destroy the excellent properties of above-mentioned polyglycolic acid resin, be limited in and being less than 30 % by weight, preferably be less than 20 % by weight, be more preferably less than 10 % by weight.
In addition, in polyglycolic acid resin, in the limit without prejudice to object of the present invention (particularly decomposability and comminuted), the various additives such as thermo-stabilizer, photostabilizer, mineral filler, softening agent, damp proof compound, water-resisting agent, hydrophobizing agent, lubricant can be added as required.
Petroleum drilling of the present invention assist with dispersion liquid with the micro-solid shape demonstrating the weight conservation rate in 80 DEG C of water of above-mentioned appropriateness contain above-mentioned obtain like that polyglycolic acid resin (with, according to circumstances comprise the composition of other any composition).Micro-solid comprises: comprise by hot cut method, the solid cutting the pellet of the uniform shapes that the various method such as rope method, under water cutting method makes after the sheet stock after polyglycolic acid resin (composition) polymerization or melting (with mixing), the micro-solid that it is the appropriate size of weight conservation rate in the above-mentioned water of display, the length of such as length direction is 1 ~ 10mm, aspect ratio is less than 5; And then also comprise a solid and then carry out forming process etc. and the particulate, staple fibre, diaphragm etc. that obtain.
To the conversion of particulate, preference as, use under the cooling being directly mixed into liquid nitrogen or dry ice and can carry out carefully finely driving gram mill (pin mill), hammer mill, vane-type grinding machine (blade mill) etc. high speed rotating grinding or airflow milling, a sand mill.In addition, after polyglycolic acid resin manufactures, if carry out the thermal treatment of long period, then can pulverize under the condition not being special low temperature or the remarkable condition relaxed of cooling.By like this, major diameter (L)/minor axis (D) can be made to be generally less than 1.9, to accumulate 50 % by weight median size (D
50) (assay method later describe) be that the particulate of 1 ~ 1000 μm performs well in the present invention.
In addition, preferably use as micro-solid, by the melts of polyglycolic acid resin (composition) is extruded by path nozzle, the fiber cutting obtained or first stretch as required is cut off again, thus the ratio of the length obtained (L) and minor axis (footpath, cross section) (D) be 10 ~ 2000, minor axis (D) is the staple fibre of 5 ~ 95 μm.
In addition, as micro-solid, also can be the micro-solid being melt extruded the shaping sheet that obtains or the fine shearing of film by above-mentioned polyglycolic acid resin (composition), also preferred usable floor area 0.01 ~ 10cm
2, thickness 1 ~ 500 μm diaphragm.
And then, the present invention in use, except above-mentioned micro-solid shape polyglycolic acid resin (composition) can being used alone separately, by different shape and/or different more than the two kinds micro-solid shape polyglycolic acid resins of size being used with arbitrary ratio combine, weight conservation rate and/or mobility inhibition in water can also be controlled.
Usually, particulate is applicable to a large amount of production, and the situation that the necessity of some polyglycolic acid resin reduced comminuted or the homogenization of mobility inhibition is higher for attention decomposability preferably uses staple fibre.Contain the micro-solid of particulate or the staple fibre so obtained; in order to obtain between the desirable liquid permeability decubation primarily of the decomposability domination of the value of minor axis (D) and polyglycolic acid resin, the weight conservation rate (assay method is as aftermentioned) be adjusted to according to the present invention in the water of 80 DEG C is: be after less than 80%, 168 hours be less than 45% after more than 85%, 72 hours after 12 hours.The weight conservation rate that weight conservation rate in the water of above-mentioned 80 DEG C is equivalent in the water of 40 DEG C is: be after less than 80%, 3000 hours be less than 45% after more than 85%, 1200 hours after 72 hours.
Petroleum drilling of the present invention is assisted substantially can by obtaining the above-mentioned micro-solid shape polyglycolic acid resin dispersion obtained like that in an aqueous medium with dispersion liquid.Aqueous medium refers to the liquid medium of the moisture at least containing more than 10%.Different according to using method, also putting into after in mine pit, having a mind to import the aqueous medium that moisture forms this composition, can be formed then and there.In moisture free situation, the hydrolysis of polyglycolic acid resin can not fully be carried out, and this poor efficiency recovered with liquid permeability is associated.
As the composition beyond water, from the viewpoint of dispersiveness, the polyethers such as ethers and polyoxyethylene glycol etc. such as the ketone such as sturated aliphatic hydrocarbon, acetone, ether such as the polyvalent alcohol such as fatty alcohol and Polyglycerine, hexane, heptane, octane such as methyl alcohol, ethanol, ethylene glycol can be used.
(other mobility controls material)
The micro-solid shape polyglycolic acid resin used in the present invention is that it can play separately the function of mobility suppression material and play the mobility control material with the function of the mobility restorer of self-decomposition in an aqueous medium.But, according to the character on the stratum of the oil well periphery of manipulating object, and control material by other mobility and also often have.
Control material as other mobility this, the various mobility in the past used can be used to control materials.As its example, there are anti-avalanche agent, alkali metal halide or alkaline earth metal halide (such as, the CaBr such as the inorganic hole such as sandstone, calcium carbonate wall mud wall strengthening material, KCl
2, CaCl
2) inorganic substance such as reconditioning dose of geometric ratio grade; The organic colloid agent (polymer class) such as guar gum or organic hole wall mud wall strengthening material and mineral colloid agent (clay class), dispersion dispergator, tensio-active agent, leakage preventing agent, defoamer, anticorrosive agent etc., they contain with corresponding concentration according to the stratum of respective function and manipulating object in the auxiliary dispersion liquid of petroleum drilling.
Embodiment
The present invention is further illustrated below according to embodiment and comparative example.Comprise following example, the characteristic value recorded in this specification sheets with the value measured by following method for benchmark.
< weight-average molecular weight (Mw) >
The weight-average molecular weight (Mw) of raw material and micro-solid shape polyglycolic acid (PGA) and poly(lactic acid) (PLA) is by dissolving in the hexafluoroisopropanol (HFIP) of sodium trifluoroacetate with the concentration of 5mM by the sample dissolution of each 10mg, pass through membrane filtration after forming 10mL, obtain liquor sample.This liquor sample 10 μ l is injected in gel permeation chromatography (GPC) device, with following condition determining molecular weight.It should be noted that, be injected within liquor sample upon dissolution 30 minutes in GPC device.
< GPC condition determination >
Device: Shimazu LC-9A,
Post: Showa electrician (strain) HFIP-806M2 root (being connected in series)+front pillar processed: HFIP-LG1 root
Column temperature: 40 DEG C,
Elutriant: with the concentration of 5mM dissolve sodium trifluoroacetate HFIP solution,
Flow velocity: 1mL/ minute,
Detector: differential refraction rate meter
Molecular weight calibration: the molecular mass standard curve data that utilization uses the polymethylmethacrylate (POLYMER LABORATORIES Ltd. system) of 5 kinds of different standard molecular weights of molecular weight and produces.
< median size >
Use laser diffraction formula particle size distribution device ((strain) Shimadzu Seisakusho Ltd. system " SALD-3000S "), size distribution is obtained to the particle dispersion in the water be dispersed in by PGA or PLA grain sample containing tensio-active agent (サ Application ノ プ コ society system " SN デ ィ ス パ ー サ Application ト 7347-c diluent "), according to this size distribution, obtain particle diameter when (from Large stone side too) accumulating weight from small particle size side reaches 50% as median size (D
50).
< particles modulate method (breaking method) and pulverizing yield >
Breaking method (1): solid state polymer sample is about 20kg and is immersed in liquid nitrogen after cooling, what use can carry out cooled with liquid nitrogen when pulverizing to drive gram mill (wild industry (strain) system of Omaki " micronizing drives a gram mill: コ Application ト ラ プ レ ッ Network ス シ リ ー ズ "), while cool in liquid nitrogen, while to pulverize temperature 7.5 DEG C, the condition of speed of rotation 187m/ second pulverizes 2 minutes, then the sieve of perforate 106 μm (150 order) is used to sieve, reclaim the lower particulate of sieve, ratio according to its weight and the sample weight before pulverizing obtains pulverizing yield (%).
Breaking method (2): a solid state polymer sample is about 40g and puts in hammer mill (KINEMATIC AG system " POLYMIX PX-MFC90D ") together with the dry ice of its 2 times of weight, after pulverizing 1 minute with rotating speed 6000 revs/min, sieve with the sieve of perforate 840 μm, reclaim the lower particulate of sieve, according to the ratio of the sample weight before its weight and pulverizing, obtain and pulverize yield (%).
< staple fibre modulator approach >
Be melting under the condition of 240 ~ 250 DEG C at resin temperature by polyglycolic acid (PGA), discharge from 24 hole nozzles (aperture: 0.3mm) with the speed of every hole 0.51g/ minute, cool in the air of about 5 DEG C, with thread solidification, obtain undrawn yarn.Next, undrawn yarn is stretched to 2.7 times at the temperature of 60 DEG C, then at 100 DEG C, carries out thermal treatment in 3 minutes, obtain the drawn yarn of about 16 μm, footpath, cross section (fiber number 1.7 DENIER).And then this drawn yarn is cut into length is about 5mm, obtain PGA staple fibre.
< weight conservation rate >
By micro-solid shaped polymer sample 1g (and, the additional composition according to circumstances sometimes added) be dispersed in Glass Containers (day physics and chemistry Xiao Zi Co., Ltd. screw socket bottle SV-50) 50mL water (or aqueous solution), in the thermostatic bath of 80 DEG C (or 40 DEG C), preserve the specified time.Next, the content liquid of Glass Containers is poured on filter paper, by himself gravity filtration, the solids component remained on filter paper is at room temperature placed 1 day, then dry in the nitrogen environment of 80 DEG C.Measure the weight of dried solid polymer composition, according to its ratio with the polymer sample weight installed in Glass Containers, obtain the weight conservation rate (%) every the specified time.It should be noted that, when using calcium carbonate as additional composition, the calcium carbonate remained on the filter paper water of the amount being enough to be dissolved is washed removing, in addition, when using sandstone as additional composition, amount of polymers on filter paper is obtained by deducting this additional quantity.
(embodiment 1)
Major diameter is about 3mm, polyglycolic acid (PGA) ((strain) Network レ Ha system, weight-average molecular weight (Mw)=17.3 ten thousand) that cylinder that footpath, cross section is about 3mm is granular pulverized by breaking method 1, the screen underflow as perforate 106 μm obtains PGA particulate (A).Dispersion liquid in 3 Glass Containerss obtained in 50mL ion exchanged water by making this PGA particulate (A) 1g be dispersed in Glass Containers is kept 12 hours, 72 hours and 168 hours respectively in the thermostatic bath of 80 DEG C, by aforesaid method, weight conservation rate is obtained to remaining solids component.
By above-mentioned summary situation and pulverize the results are shown in aftermentioned table 1 of the measurement result of yield and weight conservation rate and following embodiment and comparative example.
(embodiment 2)
Use the dispersion liquid obtained in the NaCl aqueous solution 50mL by the PGA obtained in embodiment 1 particulate (A) 1g being dispersed in the concentration 0.35M be contained in phial, in addition, the weight conservation rate every the specified time is obtained in mode similarly to Example 1.
(embodiment 3)
Use the dispersion liquid obtained in the NaCl aqueous solution 50mL by the PGA obtained in embodiment 1 particulate (A) 1g being dispersed in the concentration 1.92M be contained in phial, in addition, the weight conservation rate every the specified time is obtained in mode similarly to Example 1.
(embodiment 4)
Use the dispersion liquid obtained in the KCl aqueous solution 50mL by the PGA obtained in embodiment 1 particulate (A) 1g being dispersed in the concentration 1.92M be contained in phial, in addition, the weight conservation rate every the specified time is obtained in mode similarly to Example 1.
(embodiment 5)
Use the CaCl by the PGA obtained in embodiment 1 particulate (A) 1g being dispersed in the concentration 1.92M be contained in phial
2the dispersion liquid obtained in aqueous solution 50mL, in addition, obtains the weight conservation rate every the specified time in mode similarly to Example 1.
(embodiment 6)
Use the CaCO by the PGA obtained in embodiment 1 particulate (A) 1g being dispersed in the concentration 1.92M be contained in phial
3the dispersion liquid obtained in aqueous solution 50mL, in addition, obtains the weight conservation rate every the specified time in mode similarly to Example 1.
(embodiment 7)
Use by the PGA obtained in embodiment 1 particulate (A) 1g and 0.3g sandstone (particle diameter is about 0.15 ~ 2.39mm) being dispersed in the dispersion liquid obtained in the ion exchanged water 50mL that is contained in phial, in addition, the weight conservation rate every the specified time is obtained in mode similarly to Example 1.
(embodiment 8)
Major diameter is about 3mm, the granular polyglycolic acid of cylinder (PGA) ((strain) Network レ Ha system, weight-average molecular weight (Mw)=250,000) that footpath, cross section is about 3mm pulverized by breaking method 1, the screen underflow as perforate 106 μm obtains PGA particulate (B).Except using this PGA particulate (B) to replace except PGA particulate (A), obtain dispersion liquid in mode similarly to Example 1, in mode similarly to Example 1, weight conservation rate every the specified time is obtained to it.
(embodiment 9)
Major diameter is about 3mm, polyglycolic acid (PGA) ((strain) Network レ Ha system, weight-average molecular weight (Mw)=8.5 ten thousand) that cylinder that footpath, cross section is about 3mm is granular pulverized by breaking method 2, the screen underflow as perforate 840 μm obtains PGA particulate (C).Except using this PGA particulate (C) to replace except PGA particulate (A), obtain dispersion liquid in mode similarly to Example 1, in mode similarly to Example 1, weight conservation rate every the specified time is obtained to it.
(embodiment 10)
Aforesaid staple fibre modulator approach is used to the particulate state PGA used in embodiment 1 and obtains PGA staple fibre (D).Except using this PGA staple fibre (D) to replace except PGA particulate (A), obtain dispersion liquid in mode similarly to Example 1, in mode similarly to Example 1, weight conservation rate every the specified time is obtained to it.
(comparative example 1)
70% aqueous solution (デ ュ ポン society preparing industrial grade) of oxyacetic acid is stirred at ambient pressure while heat, lasts 24 hours from room temperature to 220 DEG C.During this period, the distillation of generated water is removed, while carry out condensation reaction.Next, last 1 hour from normal pressure and slowly reduce pressure 2kPa, then 220 DEG C of heating 3 hours, carry out condensation reaction, obtain the oligopolymer of molecular weight 2.8 ten thousand thus.
Pulverized by the oligopolymer breaking method 1 obtained, the screen underflow as perforate 106 μm obtains PGA (oligopolymer) particulate.Except using this PGA (oligopolymer) particulate to replace except PGA particulate (A), to obtain dispersion liquid in mode similarly to Example 1, the weight conservation rate every the specified time is obtained similarly to Example 1 to it.
(comparative example 2)
Forming process become the granular crystalline polylactic acid (Nature Works society system " 7000D ") that major diameter is about 3mm, footpath, cross section is about 3mm to be pulverized by breaking method 1, the screen underflow as perforate 106 μm obtains PLA particulate (A).Except using this PLA particulate (A) to replace except PGA particulate (A), obtain dispersion liquid in mode similarly to Example 1, the weight conservation rate every the specified time is obtained similarly to Example 1 to it.
(comparative example 3)
Pulverized by the granular crystalline polylactic acid breaking method 2 used in comparative example 2, the screen underflow as perforate 840 μm obtains PLA particulate (B).Except using this PLA particulate (B) to replace except PGA particulate (A), obtain dispersion liquid in mode similarly to Example 1, the weight conservation rate every the specified time is obtained similarly to Example 1 to it.
(comparative example 4 ~ 9)
Replace except the PGA particulate (A) of use in embodiment 2 ~ 7 except using the PLA particulate (B) obtained in comparative example 3, obtain dispersion liquid respectively in the same manner as embodiment 2 ~ 7.In the mode same with embodiment 2 ~ 7, weight conservation rate every the specified time is obtained to these dispersion liquids.
The summary situation of above-described embodiment and comparative example and the measurement result pulverizing yield and weight conservation rate (80 DEG C and in some examples also at 40 DEG C) are shown in following table 1 in the lump.
Table 1
Industry utilizability
From the result of above-mentioned table 1, in the auxiliary dispersion liquid of petroleum drilling of the present invention, the micro-solid shape polyglycolic acid resin of the macromolecule of materials'use is controlled as mobility, in drilling operation and frac job, liquid permeability needed for the operation initial stage suppresses 12 hours weight conservation rates in necessary 80 DEG C of water high, and necessary 72 hours of the recovery of liquid permeability suppressed after the end of job and 168 hours weight conservation rates fully low, there is desirable flow control, in addition, the necessary comminuted height more obvious than poly(lactic acid) of micronize, described micronize is carried out to be suitable as mobility control material.
Claims (13)
1. the auxiliary dispersion liquid of petroleum drilling, makes micro-solid shape polyglycolic acid resin disperse to form in an aqueous medium,
Also material is controlled containing following material as the mobility added in described dispersion liquid:
More than a kind inorganic substance in sandstone, calcium carbonate, KCl and mineral colloid agent, or organic colloid agent, dispersion dispergator, tensio-active agent, defoamer and anticorrosive agent in more than a kind organic substance,
Described micro-solid shape polyglycolic acid resin is 70 by weight-average molecular weight, more than 000 500, the polyglycolic acid resin of less than 000 is formed, and its weight conservation rate in the water of 80 DEG C is: be after less than 80%, 168 hours be less than 45% after more than 85%, 72 hours after 12 hours.
2. the auxiliary dispersion liquid of petroleum drilling as claimed in claim 1, polyglycolic acid resin is the homopolymer of oxyacetic acid.
3. the auxiliary dispersion liquid of petroleum drilling as claimed in claim 1 or 2, also contains than reconditioning inorganic substance.
4. the auxiliary dispersion liquid of petroleum drilling as claimed in claim 3, contains alkali metal halide or alkaline earth metal halide than reconditioning inorganic substance.
5. the auxiliary dispersion liquid of petroleum drilling as claimed in claim 1 or 2, the weight conservation rate of micro-solid shape polyglycolic acid resin in the water of 40 DEG C is: be after less than 80%, 3000 hours be less than 45% after more than 85%, 1200 hours after 72 hours.
6. the auxiliary dispersion liquid of petroleum drilling as claimed in claim 1 or 2, micro-solid shape polyglycolic acid resin is that the length of length direction is 1 ~ 10mm and aspect ratio is more than 1 and is less than a solid of 5.
7. the auxiliary dispersion liquid of petroleum drilling as claimed in claim 1 or 2, micro-solid shape polyglycolic acid resin to be accumulation 50 % by weight median size D50 be 1 ~ 1000 μm microgranular.
8. the auxiliary dispersion liquid of petroleum drilling as claimed in claim 1 or 2, micro-solid shape polyglycolic acid resin is the staple fibre shape of major diameter 1 ~ 10mm, minor axis 5 ~ 95 μm.
9. the auxiliary dispersion liquid of petroleum drilling as claimed in claim 1 or 2, micro-solid shape polyglycolic acid resin is area 0.01 ~ 10cm
2, thickness 1 ~ 500 μm diaphragm.
10. the auxiliary dispersion liquid of petroleum drilling as claimed in claim 6, micro-solid shape polyglycolic acid resin is combined by shape and/or different two or more of size.
The auxiliary dispersion liquid of 11. petroleum drilling as claimed in claim 7, micro-solid shape polyglycolic acid resin is combined by shape and/or different two or more of size.
The auxiliary dispersion liquid of 12. petroleum drilling as claimed in claim 8, micro-solid shape polyglycolic acid resin is combined by shape and/or different two or more of size.
The auxiliary dispersion liquid of 13. petroleum drilling as claimed in claim 9, micro-solid shape polyglycolic acid resin is combined by shape and/or different two or more of size.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010231954 | 2010-10-14 | ||
| JP231954/2010 | 2010-10-14 | ||
| PCT/JP2011/073646 WO2012050187A1 (en) | 2010-10-14 | 2011-10-14 | Oil drilling auxiliary dispersion |
Publications (2)
| Publication Number | Publication Date |
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| CN103154182A CN103154182A (en) | 2013-06-12 |
| CN103154182B true CN103154182B (en) | 2015-09-30 |
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| CN201180048958.2A Active CN103154182B (en) | 2010-10-14 | 2011-10-14 | The auxiliary dispersion liquid of petroleum drilling |
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| US (2) | US20130252854A1 (en) |
| JP (1) | JPWO2012050187A1 (en) |
| CN (1) | CN103154182B (en) |
| WO (1) | WO2012050187A1 (en) |
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| JPWO2013161754A1 (en) * | 2012-04-27 | 2015-12-24 | 株式会社クレハ | Polyglycolic acid resin short fiber for well treatment fluid |
| WO2013161755A1 (en) * | 2012-04-27 | 2013-10-31 | 株式会社クレハ | Short polyglycolic-acid-resin fibers and well-treatment fluid |
| US20140073539A1 (en) * | 2012-09-07 | 2014-03-13 | Mitsui Chemicals, Inc. | Aqueous dispersion and additives for fracturing work |
| JP6183039B2 (en) | 2012-12-12 | 2017-08-23 | 東洋製罐株式会社 | Dispersion liquid for excavation and mining method using the same |
| CN104854215B (en) * | 2012-12-12 | 2018-03-13 | 东洋制罐集团控股株式会社 | Excavation dispersion liquid and the method using dispersion liquid digging subterranean resource |
| JP6221475B2 (en) * | 2012-12-12 | 2017-11-01 | 東洋製罐株式会社 | Dispersion liquid for excavation and excavation method using the same |
| CA2898412C (en) * | 2013-01-18 | 2016-09-06 | Kureha Corporation | Well treatment fluid material and well treatment fluid comprising the same |
| CN105164229B (en) * | 2013-06-03 | 2017-06-16 | 株式会社吴羽 | Mine pit treatment fluid decomposability fiber, its manufacture method and mine pit processing method |
| WO2015068688A1 (en) * | 2013-11-05 | 2015-05-14 | 株式会社カネカ | Method of manufacturing hydrocarbon fluid from hydrocarbon fluid-rich shale |
| FR3013055B1 (en) * | 2013-11-14 | 2020-05-15 | Arkema France | FLUID COMPOSITION FOR STIMULATION IN THE OIL AND GAS PRODUCTION FIELD |
| WO2015072317A1 (en) * | 2013-11-15 | 2015-05-21 | 株式会社クレハ | Temporary sealing agent for use in well boring |
| JP6451061B2 (en) * | 2014-03-11 | 2019-01-16 | 東洋製罐グループホールディングス株式会社 | Submerged resin molding |
| WO2015182622A1 (en) * | 2014-05-26 | 2015-12-03 | 東洋製罐グループホールディングス株式会社 | Method for decomposing ester resin |
| WO2016051777A1 (en) | 2014-09-30 | 2016-04-07 | 株式会社日本触媒 | Method for liquefaction of water-absorbing resin in water-containing state and method for contraction of same |
| JP6451250B2 (en) * | 2014-11-19 | 2019-01-16 | 東洋製罐グループホールディングス株式会社 | Hydrolytic fracturing method added to the fluid used for underground mining method and hydraulic fracturing using hydraulic fracturing method |
| US11104840B2 (en) | 2015-02-12 | 2021-08-31 | Toyo Seikan Group Holdings, Ltd. | Method of extracting underground resources by using hydrolysable particles |
| JP6834117B2 (en) * | 2015-02-12 | 2021-02-24 | 東洋製罐グループホールディングス株式会社 | Hydrolytic particles |
| CN104694113B (en) * | 2015-02-13 | 2017-12-01 | 中国石油天然气股份有限公司 | A kind of method and its fibre-bearing fracturing fluid for improving fracturing fluid prop-carrying capacity |
| JP2016186055A (en) * | 2015-03-27 | 2016-10-27 | 株式会社クレハ | Polyglycolic acid composition and temporary filling material |
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- 2011-10-14 JP JP2012538725A patent/JPWO2012050187A1/en not_active Withdrawn
- 2011-10-14 WO PCT/JP2011/073646 patent/WO2012050187A1/en active Application Filing
- 2011-10-14 CN CN201180048958.2A patent/CN103154182B/en active Active
- 2011-10-14 US US13/878,606 patent/US20130252854A1/en not_active Abandoned
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| CN1708569A (en) * | 2002-10-28 | 2005-12-14 | 索菲泰克公司 | Self-destructing filter cake |
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| CN103154182A (en) | 2013-06-12 |
| US20150072903A1 (en) | 2015-03-12 |
| US20130252854A1 (en) | 2013-09-26 |
| JPWO2012050187A1 (en) | 2014-02-24 |
| WO2012050187A1 (en) | 2012-04-19 |
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