CN103013499B - Light emitting composition and preparation method thereof and application - Google Patents
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- CN103013499B CN103013499B CN201110279405.XA CN201110279405A CN103013499B CN 103013499 B CN103013499 B CN 103013499B CN 201110279405 A CN201110279405 A CN 201110279405A CN 103013499 B CN103013499 B CN 103013499B
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Abstract
The invention discloses a kind of light emitting composition and preparation method thereof and application.This light emitting composition, wax material, oxalate ester and fluorescent agent.The per-cent that described wax material accounts for described light emitting composition gross weight is 15% ~ 98.69%, preferably 25% ~ 85%; The per-cent that described fluorescent agent accounts for described light emitting composition gross weight is 0.01% ~ 5%, preferably 0.1% ~ 1%.The per-cent that described oxalate ester accounts for described light emitting composition gross weight is 1% ~ 60%, preferably 5% ~ 35%.Light emitting composition provided by the invention, selects cerul oxalate ester system, overcomes the shortcoming of current light pen, is the good replacer of existing chemoluminescence pen, has important using value.
Description
Technical field
The present invention relates to a kind of light emitting composition and preparation method thereof and application.
Background technology
Oxalate ester chemical luminous system all the time, all affects the using method to it with the water sensitivity of its height.The chemical luminous composite developing the impact of a kind of high resistance ambient moisture is industry needs always.Chemiluminescent writing implement is on sale on the market, and relevant patented technology also has sees openly, no matter but be had commercially available product or patent openly to have certain limitation.They are normally based upon on the basis of liquid luminous agent, or with oxygenant mixed luminescence after write on paper, or liquid luminous agent is write bestow oxygenant again after on paper thus obtain paper luminescence.Front kind of scheme light pen can only once use.Then a kind of scheme is easy to infiltrate the inside of paper due to liquid luminous agent, thus make the luminous agent of suction paper inside be difficult to effective catalytic oxidation agent, simultaneously because the reason shut out the light of paper fiber thus make illumination effect very poor, the lettering feature of the luminous agent of flowing is very poor on the other hand, the intention of expression painter that often can not be intact, easily pollutes drawing paper or hand simultaneously.
Summary of the invention
The object of this invention is to provide a kind of light emitting composition and preparation method thereof and application.
The light emitting composition being combined luminescence with superoxide provided by the invention, comprises wax material, oxalate ester and fluorescent agent.
Above-mentioned light emitting composition also can only be made up of said components.
Described wax material is selected from least one in paraffin, polyethylene wax, Microcrystalline Wax, river wax, carnauba wax, white soft wax, silicon wax, wax-like pentaerythritol ester compounds and wax-like stearate compounds, at least one in preferred paraffin, silicon wax and ethylene waxes; The softening temperature of described wax material is 40 DEG C ~ 115 DEG C; Described wax-like pentaerythritol ester compounds is selected from least one in pentaerythritol tetrastearate and pentaerythritol tetrabenzoate, preferred pentaerythritol tetrastearate, described wax-like stearate compounds is selected from least one in stearic acid octadecyl and two Lauryl Alcohol stearates, preferred stearic acid octadecyl; Described paraffin can be 52#, 54,56,58,60 and 65# full refining or SEMI-REFINED PARAFFIN WAX at least one; The per-cent that described wax material accounts for described light emitting composition gross weight is 15% ~ 98.69%, preferably 25% ~ 85%, specifically can be 15-85%, 15-79.9%, 15-60%, 15-30%, 30-98.69%, 30-85%, 30-79.9%, 30-60%, 60-98.69%, 60-85%, 60-79.9%, 79.9-98.69% or 79.9-85%;
Described fluorescent agent is selected from 9, 10 pairs of phenylacetylene base anthracenes, 2-ethyl-9, 10 pairs of phenylacetylene base anthracenes, 9, 10 pairs of phenylanthracenes, 2-chloro-9, 10 biconjugate methyl ether base phenylanthracenes, 1-chloro-9, 10-tolane base anthracene 1, 8-bis-chloro-9, 10-tolane base anthracene, 1, 6, 7, 12-tetra-couples of tert-butyl group Ben Yang Ji perylene-N, two 18 carboxamides of N ', 1, 6, 7, 12-tetra-couples of tert-butyl group Ben Yang Ji perylene-N, two 8 carboxamides of N ', 1, 6, 7, 12-tetra-phenoxy group-N-N`-two (2, 6-diisopropyl phenyl)-3, 4, 9, 10-perylene two carbonyl acid amides and 2, at least one in 9 dimethylquinacridone.The per-cent that described fluorescent agent accounts for described light emitting composition gross weight is 0.01% ~ 5%, preferably 0.1% ~ 1%, specifically can be 0.01-2,0.01-0.11,0.11-5,0.11-2 or 2-5%.
Described oxalate ester is often referred to the oxalic acid di-esters compound of the phenyl replaced by halogen or nitro, and in most cases phenyl also can be esterified.As two (2 can be selected from, 4,5-tri-chloro-6-carbonyl pentyloxy phenyl) barkite (be called for short CPPO), two (2,4,5-tri-chloro-6-carbonyl isopentyloxy phenyl) barkite, two (2,4,5-tri-chloro-6-carbonyl butoxy phenyl) barkite, two (2,4,6-trichlorophenyl) barkite, two (five chlorophenyl) barkite and two (2,4, dinitrophenyl) at least one in barkite.The per-cent that described oxalate ester accounts for described light emitting composition gross weight is 1% ~ 60%, preferably 5% ~ 35%, specifically can be 1-18%, 1-35%, 1-5%, 18-60%, 18-35%, 5-18% or 5-60%.
In order to regulate the hardness of wax crayon and improve lettering feature, change the self color of wax crayon, to be in harmonious proportion out the color being applicable to writing, described light emitting composition also comprises at least one in liquid hardness regulator, solid hardness regulator, dyestuff and pigment.
Wherein, described liquid hardness regulator is selected from least one in Witco 70, white oil, phthalate compound, citric acid ester type compound, benzoate compounds, carbonates, dipropylene glycol dibenzoate, diethylene glycol dibenzoate, propylene glycol dibenzoate, ethylene glycol bisthioglycolate benzoic ether, isomery eicosanol pivalate, silicone oil compound, at least one in preferred paraffinic oils, phthalate compound and benzoates;
Wherein, described phthalate compound is selected from least one in dimethyl phthalate and dibutyl phthalate, preferred dibutyl phthalate; Described citric acid ester type compound is selected from least one in triethyl citrate, tributyl citrate and Tributyl O-acetylcitrate, at least one in optimization citric acid tri-n-butyl and Tributyl O-acetylcitrate; Described benzoate compounds is selected from least one in n-octyl benzoate, C12-15 benzoic ether and phenylformic acid Bian ester, preferred C12-15 benzoic ether; Described carbonats compound is selected from least one in carbonic acid monooctyl ester, carbonic acid tridecane ester and butyl carbonate, preferred carbonic acid tridecane ester; Described silicone oil compound is selected from least one in methyl-silicone oil, ethyl silicon oil, phenyl silicone oil, Methyl Hydrogen Polysiloxane Fluid, methyl phenyl silicone oil, methylchlorophenyl silicone oil, MethylethoxylsiliconFluid Fluid, methyl trifluoro propyl silicone oil, methyl vinyl silicon oil, ethyl containing hydrogen silicone oil, at least one in preferred phenyl silicone oil, methyl trifluoro propyl silicone oil and MethylethoxylsiliconFluid Fluid; The per-cent that described liquid hardness regulator accounts for described light emitting composition gross weight is 0%-35%, preferred 1%-15%, specifically can be 0.1-35%, 0.1-19.9%, 0.1-5%, 0.1-0.2%, 0.2-35%, 0.2-19.9%, 0.2-5%, 5-35%, 5-19.9% or 19.9-35%, the per-cent of described liquid hardness regulator is not 0;
Described solid hardness regulator can be metal oxide or their organic acid salt, at least one in preferred Magnesium Stearate, aluminum stearate, calcium stearate, magnesium oxide and aluminum oxide, silicon oxide; The per-cent that described solid hardness regulator accounts for described light emitting composition gross weight is 0%-30%, and preferred 1%-10%, specifically can be 4.89-30%, and the per-cent of described solid hardness regulator is not 0;
Described dyestuff is selected from least one in oily molten class dyestuff, at least one in preferred solvent blue 67, solvent blue 104 and solvent blue 19 4; The per-cent that described dyestuff accounts for described light emitting composition gross weight is not more than 0.1%.
Described pigment is selected from least one in Pigment blue 56, pigment Blue 15 and Prussian blue, preferred pigments indigo plant 15.The per-cent that described pigment accounts for described light emitting composition gross weight is not more than 0.1%.
The method of the above-mentioned light emitting composition of preparation provided by the invention, comprises the steps:, by aforementioned each component melts mixing cooling, to obtain described light emitting composition.
The light emitting composition that the invention described above provides, preparing the application in light-emitting writing writing tools, also belongs to protection scope of the present invention.
The using method of the light emitting composition that the invention described above provides, comprises the steps: that light emitting composition is under catalyzer existent condition, contacts in organic solvent with superoxide;
Described superoxide is selected from least one in hydrogen peroxide, tertbutanol peroxide, carbamide peroxide, Sodium peroxoborate and benzoyl peroxide, preferred hydrogen peroxide;
Described organic solvent is selected from least one in dimethyl phthalate, triethyl citrate and the trimethyl carbinol; The mass percentage concentration of described superoxide in described organic solvent is 0.1-5%;
Described catalyzer is selected from least one in sodium salicylate, Whitfield's ointment four butylamine and lithium salicylate, preferred Whitfield's ointment four butylamine.
In addition, the test kit be made up of aforementioned light emitting composition, superoxide, organic solvent and catalyzer, also belongs to protection scope of the present invention;
Described superoxide is selected from least one in hydrogen peroxide, tertbutanol peroxide, carbamide peroxide, Sodium peroxoborate and benzoyl peroxide, preferred hydrogen peroxide;
Described organic solvent is selected from least one in dimethyl phthalate, triethyl citrate and the trimethyl carbinol; The mass percentage concentration of described superoxide in described organic solvent is 0.1-5%;
Described catalyzer is selected from least one in sodium salicylate, Whitfield's ointment four butylamine and lithium salicylate, preferred Whitfield's ointment four butylamine.
Light emitting composition provided by the invention, selects cerul oxalate ester system, overcomes the shortcoming of current light pen, is the good replacer of existing chemoluminescence pen, has important using value.
Embodiment
Below in conjunction with specific embodiment, the present invention is further elaborated, but the present invention is not limited to following examples.Described method is ordinary method if no special instructions.Described material all can obtain from open commercial sources if no special instructions.Described concentration is mass percentage concentration if no special instructions.
Embodiment 1
Melting 60 grams of Fushun petrochemical industry produce the Kunlun board 58# paraffin wax fully refined at 80 degrees celsius, add 35g two (2,4,5-tri-chloro-6-carbonyl pentyloxy phenyl) barkite and 5g fluorescent agent 2-ethyl-9,10 pairs of phenylacetylene base anthracenes, import wax crayon mould after stirring and dissolving, after cooling, obtain the wax crayon of green-yellow appearance.
In 100ml dimethyl phthalate (hereinafter referred to as DMP), add 10mg sodium salicylate, and the aqueous hydrogen peroxide solution of 2.5ml85%, be stirred to whole dissolving, obtain superoxol.
After painting on plain copying paper with above-mentioned green wax crayon, above-mentioned superoxol is applied to the drawing position on paper, obtains Green Chemistry luminescence immediately.
Be heated to add 35 grams two (2 in 80 degree of dibutyl phthalates with nitrogen purging to 60g, 4,5-tri-chloro-6-carbonyl pentyloxy phenyl) barkite and 5g fluorescent agent 2-ethyl-9,10 pairs of phenylacetylene base anthracenes mix continuously, cool completely until dissolve, obtain conventional barkite luminescent solution.Paint at above-mentioned identical paper with it, result drawing track permeates out a slice immediately, and penetrates paper and fall into oblivion to back side of paper.Not only can not accurately show drawing, also can pollute desktop or hand.After smearing above-mentioned oxidation solution, paper also obtains green emitting, just fluorescent lifetime than wax crayon paint shorten 2 little time.
Embodiment 2:
At the polyethylene wax PE890 that 125 degrees Celsius of lower meltings, 85 grams of Clariants are produced, add 5g two (2,4,5-tri-chloro-6-carbonyl butoxy phenyl) barkite, 5g liquid hardness regulator Witco 70,4.89g solid hardness regulator aluminum stearate, 0.109g fluorescent agent 2-chloro-9,10 biconjugate methyl ether base phenylanthracenes and 0.001g oil-soluble dyes solvent blue 67, be stirred to whole dissolving, import wax crayon mould, after cooling, obtain the wax crayon of blue colored appearance.
In 100ml dimethyl phthalate, add the aqueous hydrogen peroxide solution of 10mg sodium salicylate and 2.5ml85%, be stirred to whole dissolving, obtain superoxol.
Paint on plain copying paper with above-mentioned blue look wax crayon, the easily release of wax crayon lubrication can be felt, above-mentioned superoxol is applied to the drawing position on paper, obtains blue colour chemistry immediately luminous.
Embodiment 3:
At 100 degrees Celsius of lower meltings, 20 grams of shell-M225 Microcrystalline Waxes, 20 grams of pentaerythritol tetrastearates, 20 grams of stearic acid octadecyl, 19.9 grams of these 4 kinds of wax materials of silicon wax and 0.1g liquid hardness regulator isomery eicosanol pivalate, 18g oxalate ester CPPO, 2g fluorescent agents 1,8-bis-chloro-9,10-tolane base anthracene is stirred to whole dissolving, take out after paper being immersed this melts, cool, obtain light emitting composition provided by the invention.
Be rolled into web-like, loaded glass test tube.In test tube, add appropriate tertbutanol peroxide, submergence paper roll, obtain yellow chemoluminescence immediately.
Embodiment 4:
100 degrees Celsius of lower meltings, 30 grams of U.S. produce the white soft wax of MicroWax170A, 35g liquid hardness regulator C12-15 benzoic ether, 4.99g oxalate ester CPPO, 0.01g fluorescent agent 1,6,7,12-tetra-couples of tert-butyl group Ben Yang Ji perylene-N, two 18 carboxamides of N ' and 30g solid hardness regulator calcium stearate are stirred to and all mix, and melts are poured into 100mm*20mm*1mm mono-flat-shaped mould, cool, cooling, obtains red bar thing provided by the invention, loads glass beaker for subsequent use.
In 100ml triethyl citrate, add 10mg Whitfield's ointment four butylamine, and the aqueous hydrogen peroxide solution of 2.5ml85%, be stirred to whole dissolving, obtain superoxol.
In beaker, add appropriate above-mentioned superoxol, this embodiment gained red bar thing of submergence, obtains red chemoluminescence immediately.
Embodiment 5:
At palm wax (CAS-Number8015-86-9), 1g oxalate ester CPPO, 0.2g liquid hardness regulator phenyl silicone oil and 0.11g fluorescent agent 2 that 100 degrees Celsius of lower meltings, 98.69 grams of Brazilian ROGUIMO originate in, 9 dimethylquinacridone are stirred to and all mix, melts is poured into 100mm*20mm*1mm mono-flat-shaped mould, cool, take out cooled orange bar, be light emitting composition provided by the invention, load 500ml glass beaker for subsequent use.
Another configuration conventional luminescent solution in contrast: get 98.69g dibutyl phthalate, 1g oxalate ester CPPO, 0.1g2,9 dimethylquinacridone are stirred to whole dissolving at 130 degrees Celsius, cool, and pour 500ml beaker into, obtain conventional luminescent solution.
In 1000mlDMP, add the aqueous hydrogen peroxide solution of 100mg Whitfield's ointment four butylamine and 25ml85%, be stirred to whole dissolving, obtain superoxol for subsequent use, be placed on humidity 60%, the indoor of 25 degrees Celsius, lucifuge stores 30 days.
Prepare gained light emitting composition and preceding method in this embodiment to prepare in the conventional luminescent solution sample of gained and add the appropriate above-mentioned superoxol of 500ml respectively, prepare by this embodiment the tangerine colour chemistry that orange bar prepared by gained carnauba wax obtains becoming clear immediately luminous, and conventional luminescent solution illustrate only faint luminescence.
Embodiment 6:
At 100 degrees Celsius of lower melting 15g river waxes, 60g oxalate ester CPPO, 5g fluorescent agent 1-chloro-9,10-tolane base anthracene, 9.9g liquid hardness regulator diethylene glycol dibenzoate, 10g liquid hardness regulator carbonic acid tridecane ester and 0.1g Pigment blue 56 are stirred to evenly, melts is poured into the 100mm elongated tubular mould of 5mm diameter, cool, take out cooled green wax club, be light emitting composition provided by the invention.
In 100ml dimethyl phthalate, add the carbamide peroxide of 200mg lithium salicylate and 5g, be stirred to evenly.Green for this embodiment gained wax club is dropped into aforementioned containing in the solution of carbamide peroxide and lithium salicylate, and this green wax club sends yellow-green colour radiance, for up to 96 hours, and 12 hours that are longer than general liquid chemiluminescent system far away.
Claims (11)
1. be combined a luminous light emitting composition with superoxide, comprise wax material, oxalate ester and fluorescent agent;
Described wax material is selected from least one in paraffin, polyethylene wax, Microcrystalline Wax, river wax, carnauba wax, white soft wax, silicon wax, wax-like pentaerythritol ester compounds and wax-like stearate compounds; Described wax-like pentaerythritol ester compounds is selected from pentaerythritol tetrastearate, and described wax-like stearate compounds is selected from stearic acid octadecyl;
Described fluorescent agent is selected from 9,10 pairs of phenylacetylene base anthracenes, 2-ethyl-9,10 pairs of phenylacetylene base anthracenes, 9,10 pairs of phenylanthracenes, 2-chloro-9,10 biconjugate methyl ether base phenylanthracene, chloro-9, the 10-tolane base anthracenes 1 of 1-, chloro-9, the 10-tolane base anthracenes of 8-bis-, 1,6,7,12-, tetra-couples of tertiary butyl phenylate base perylene-N, two 18 carboxamides of N ', 1,6,7,12-, tetra-couples of tertiary butyl phenylate base perylene-N, two 8 carboxamides of N ', 1,6, two (2, the 6-diisopropyl phenyl)-3 of 7,12-tetra-phenoxy group-N-N`-, 4, at least one in 9,10-perylene two carbonyl acid amides and 2,9 dimethylquinacridone;
Described oxalate ester is selected from two (2,4,5-tri-chloro-6-carbonyl pentyloxy phenyl) barkite, two (2,4,5-tri-chloro-6-carbonyl isopentyloxy phenyl) at least one in barkite and two (2,4,5-tri-chloro-6-carbonyl butoxy phenyl) barkite;
The per-cent that described wax material accounts for described light emitting composition gross weight is 60-98.69%;
The per-cent that described oxalate ester accounts for described light emitting composition gross weight is 1-35%;
The per-cent that described fluorescent agent accounts for described light emitting composition gross weight is 0.01% ~ 5%;
Prepare the method for described light emitting composition, comprise the steps:, by each component melts mixing cooling of the described light emitting composition of preparation, to obtain described light emitting composition.
2. light emitting composition according to claim 1, is characterized in that: described light emitting composition is made up of described wax material, described oxalate ester and described fluorescent agent.
3. light emitting composition according to claim 1 and 2, is characterized in that: described wax material is selected from least one in paraffin, silicon wax and polyethylene wax.
4. light emitting composition according to claim 1 and 2, is characterized in that:
The per-cent that described oxalate ester accounts for described light emitting composition gross weight is 5% ~ 35%;
The per-cent that described fluorescent agent accounts for described light emitting composition gross weight is 0.1% ~ 1%.
5. light emitting composition according to claim 1, is characterized in that: described solid luminescence composition also comprises at least one in liquid hardness regulator, solid hardness regulator, dyestuff and pigment;
Wherein, described liquid hardness regulator is selected from least one in Witco 70, white oil, phthalate compound, citric acid ester type compound, benzoate compounds, carbonates, dipropylene glycol dibenzoate, diethylene glycol dibenzoate, propylene glycol dibenzoate, ethylene glycol bisthioglycolate benzoic ether, isomery eicosanol pivalate, silicone oil compound;
Wherein, described phthalate compound is selected from least one in dimethyl phthalate and dibutyl phthalate; Described citric acid ester type compound is selected from least one in triethyl citrate, tributyl citrate and Tributyl O-acetylcitrate; Described benzoate compounds is selected from least one in n-octyl benzoate, C12-15 alcohol benzoic ether and peruscabin; Described carbonats compound is selected from least one in carbonic acid monooctyl ester, carbonic acid tridecane ester and butyl carbonate; Described silicone oil compound is selected from least one in methyl-silicone oil, ethyl silicon oil, phenyl silicone oil, Methyl Hydrogen Polysiloxane Fluid, methyl phenyl silicone oil, methylchlorophenyl silicone oil, MethylethoxylsiliconFluid Fluid, methyl trifluoro propyl silicone oil, methyl vinyl silicon oil, ethyl containing hydrogen silicone oil;
The per-cent that described liquid hardness regulator accounts for described light emitting composition gross weight is 0%-35%, and the per-cent of described liquid hardness regulator is not 0;
Described solid hardness regulator is selected from least one in Magnesium Stearate, aluminum stearate, calcium stearate, magnesium oxide and aluminum oxide;
The per-cent that described solid hardness regulator accounts for described light emitting composition gross weight is 0%-30%, and the per-cent of described solid hardness regulator is not 0;
Described dyestuff is oil-soluble colourant;
The per-cent that described dyestuff accounts for described light emitting composition gross weight is not more than 0.1%;
Described pigment be selected from Pigment blue 56, pigment Blue 15 and Prussian blue at least one;
The per-cent that described pigment accounts for described light emitting composition gross weight is not more than 0.1%;
Described superoxide is selected from least one in hydrogen peroxide, tertbutanol peroxide, carbamide peroxide, Sodium peroxoborate and benzoyl peroxide.
6. light emitting composition according to claim 5, is characterized in that:
Described liquid hardness regulator is selected from least one in paraffin oil, phthalate compound and benzoates;
Wherein, described phthalate compound is selected from dibutyl phthalate; Described benzoate compounds is selected from C12-15 benzoic ether;
The per-cent that described liquid hardness regulator accounts for described light emitting composition gross weight is 1%-15%;
The per-cent that described solid hardness regulator accounts for described light emitting composition gross weight is 1%-10%;
Described dyestuff is at least one in solvent blue 67, solvent blue 104 and solvent blue 19 4;
Described pigment is selected from pigment Blue 15;
Described superoxide is selected from hydrogen peroxide.
7. the arbitrary described light emitting composition of claim 1-6 is preparing the application in light-emitting writing writing tools.
8. the using method of the arbitrary described light emitting composition of claim 1-6, comprises the steps: arbitrary for claim 1-6 described light emitting composition under catalyzer existent condition, contacts with superoxide in organic solvent;
Described superoxide is selected from least one in hydrogen peroxide, tertbutanol peroxide, carbamide peroxide, Sodium peroxoborate and benzoyl peroxide;
Described organic solvent is selected from least one in dimethyl phthalate, triethyl citrate and the trimethyl carbinol; The mass percentage concentration of described superoxide in described organic solvent is 0.1-5%;
Described catalyzer is selected from least one in sodium salicylate, Whitfield's ointment four butylamine and lithium salicylate.
9. using method according to claim 8, is characterized in that:
Described superoxide is selected from hydrogen peroxide;
Described catalyzer is selected from Whitfield's ointment four butylamine.
10. the test kit be made up of the arbitrary described light emitting composition of claim 1-6, superoxide, organic solvent and catalyzer;
Described superoxide is selected from least one in hydrogen peroxide, tertbutanol peroxide, carbamide peroxide, Sodium peroxoborate and benzoyl peroxide;
Described organic solvent is selected from least one in dimethyl phthalate, triethyl citrate and the trimethyl carbinol; The mass percentage concentration of described superoxide in described organic solvent is 0.1-5%;
Described catalyzer is selected from least one in sodium salicylate, Whitfield's ointment four butylamine and lithium salicylate.
11. test kits according to claim 10, is characterized in that: described superoxide is hydrogen peroxide; Described catalyzer is Whitfield's ointment four butylamine.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE4216497C2 (en) * | 1992-05-19 | 2000-09-28 | Schwan Stabilo Schwanhaeusser | Marker pen |
| DE9215344U1 (en) * | 1992-11-11 | 1994-03-24 | Faber Castell A W | Solid mine |
| US5597517A (en) * | 1996-04-30 | 1997-01-28 | Jame Fine Chemicals, Inc. | Two-component chemiluminescent composition |
| US6207077B1 (en) * | 2000-02-18 | 2001-03-27 | Orion 21 A.D. Pty Ltd | Luminescent gel coats and moldable resins |
| CN1120207C (en) * | 1999-12-30 | 2003-09-03 | 大连路明科技集团有限公司 | Luminous plastic masterbatch and its production |
| EP1146098A1 (en) * | 2000-04-14 | 2001-10-17 | Sicpa Holding S.A. | Solid marking composition as writing means, a writing instrument, an optically variable marking layer and use of a plurality of optically variable pigments |
| JP4327568B2 (en) * | 2003-11-20 | 2009-09-09 | 株式会社サクラクレパス | Phosphorescent solid drawing material |
| CN100422284C (en) * | 2004-03-25 | 2008-10-01 | 金朝阳 | Chemiluminescent composition |
| WO2006029100A1 (en) * | 2004-09-02 | 2006-03-16 | The University Of Georgia Research Foundation, Inc. | Phosphorescent/fluorescent compositions and methods |
| MXPA05010971A (en) * | 2004-10-13 | 2006-04-20 | Oreal | Dye composition comprising a pigment and at least one specific electrophilic monomer. |
| CN100526418C (en) * | 2005-05-26 | 2009-08-12 | 中国科学院长春光学精密机械与物理研究所 | Fluorescent powder film coating material for plasma display device and its preparation method |
| US7758268B2 (en) * | 2005-12-20 | 2010-07-20 | Xerox Corporation | Hand held photochromic marking implement |
| CN101191051A (en) * | 2006-11-23 | 2008-06-04 | 天津天龙化学发光管有限公司 | Pasty chemical luminous composite with relative high viscosity |
| CN101070469A (en) * | 2007-06-08 | 2007-11-14 | 金朝阳 | Novel use of carbonats compound |
| US20090045360A1 (en) * | 2007-08-13 | 2009-02-19 | Xerox Corporation | Quantum dot-based luminescent marking material |
| EP2318475A1 (en) * | 2008-07-23 | 2011-05-11 | Cyalume Technologies, Inc | Pressure activatable chemiluminescent system useful for covert intrusion detection |
| CN101735806B (en) * | 2009-12-25 | 2013-03-27 | 彩虹集团公司 | Method for preparing light-cumulating luminescent size |
| CN102133977B (en) * | 2010-12-31 | 2012-05-23 | 深圳市华熙生物科技有限公司 | Food and beverage outer package printed with luminescent patterns |
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