CN102533000A - Ultraviolet light curing ink and preparation method thereof - Google Patents
Ultraviolet light curing ink and preparation method thereof Download PDFInfo
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- CN102533000A CN102533000A CN2011104467851A CN201110446785A CN102533000A CN 102533000 A CN102533000 A CN 102533000A CN 2011104467851 A CN2011104467851 A CN 2011104467851A CN 201110446785 A CN201110446785 A CN 201110446785A CN 102533000 A CN102533000 A CN 102533000A
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Abstract
The embodiment of the invention provides ultraviolet light curing ink and a preparation method of the ultraviolet light curing ink, wherein the ultraviolet light curing ink comprises the following ingredients: methacrylic acid isobornyl thiocyanoacetate, 2-hydroxy acrylic resin, 1-hydroxy cyclohexyl phenylacetone, essence microcapsules, pigments and alkyd resin. The ultraviolet light curing ink provided by the embodiment of the invention is favorable for improving the ink toughness, and further, the product quality is improved.
Description
Technical field
The present invention relates to printing technology, be specifically related to a kind of UV curable ink and preparation method thereof.
Background technology
At present; In screen printing process; Ink film thickness behind the film-forming is compared the black bed thickness reality of other mode of printing, and the ink film thickness of general single printing is 20～40 μ m, for guaranteeing that printing ink is in the lip-deep good adhesion of the article of undertaking the printing of; The printing ink total thickness of the surperficial double exposure of article of undertaking the printing of should not surpass 100 μ m, and promptly printing ink is on the article of undertaking the printing of general maximum overprintable 3 times.
Test is found; For the need double exposure more than 3 times to embody the article of undertaking the printing of of its unique printing effect; If use existing printing ink to print, then at ink printing on the article surface of undertaking the printing of and after solidifying, extruding or bending this when undertaking the printing of article; More significantly ftractureing and coming off appears in ink film surface usually, influences quality product.
Summary of the invention
The embodiment of the invention provides a kind of UV curable ink and preparation method thereof, in the hope of the toughness of raising printing ink, and then promotes quality product.
For solving the problems of the technologies described above, the embodiment of the invention provides following technical scheme:
The embodiment of the invention provides a kind of UV curable ink on the one hand, and component can comprise:
Isobornyl methacrylate, 2-Hydroxylated acrylic resin, 1-hydroxy-cyclohexyl phenyl-acetone, essence microcapsule, pigment and Synolac.
Optional, the weight specific gravity range of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 50 parts to 70 parts,
Said isobornyl methacrylate account for 5 parts to 15 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts to 5 parts,
Said pigment account for 10 parts to 20 parts,
Said Synolac account for 10 parts to 20 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
Optional, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 70 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 4 parts,
Said isobornyl methacrylate account for 6 parts,
Said pigment account for 10 parts,
Said Synolac account for 10 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
Optional, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 60 parts,
Said isobornyl methacrylate account for 15 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts,
Said pigment account for 13 parts,
Said Synolac accounts for 10 parts.
Said essence microcapsule accounts for 0.5 part～5 parts.
Optional, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 55 parts,
Said isobornyl methacrylate account for 10 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts,
Said pigment account for 18 parts,
Said Synolac account for 15 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
Optional, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 55 parts,
Said isobornyl methacrylate account for 8 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 5 parts,
Said pigment account for 15 parts,
Said Synolac account for 17 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
Optional, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 50 parts,
Said isobornyl methacrylate account for 5 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 5 parts,
Said pigment account for 20 parts,
Said Synolac account for 20 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
Optional, the weight proportion of said isobornyl methacrylate accounts for 8 parts.
The embodiment of the invention provides a kind of preparation method of UV curable ink on the other hand, can comprise:
Taking by weighing 2-Hydroxylated acrylic resin, isobornyl methacrylate, pigment, essence microcapsule, Synolac and 1-hydroxy-cyclohexyl phenyl-acetone is contained in the container;
The 2-Hydroxylated acrylic resin, isobornyl methacrylate, 1-hydroxy-cyclohexyl phenyl-acetone, essence microcapsule, pigment and the Synolac that are contained in the said container are carried out uniform mixing to obtain UV curable ink.
Optional, the weight specific gravity range of each component of UV curable ink that takes by weighing for example can be:
The 2-Hydroxylated acrylic resin account for 50 parts to 70 parts,
Isobornyl methacrylate account for 5 parts to 15 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts to 5 parts,
Pigment account for 10 parts to 20 parts,
Synolac account for 10 parts to 20 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
Therefore; Embodiment of the invention scheme can guarantee the good adhesion of double exposure ink film in the flexible while of greatly improving cured film because employing has the toughness modified monomer of good flexible isobornyl methacrylate as printing ink; Thereby help overcoming the ink film cracking that has general printing ink now and in double exposure more than 3 times, cause, the defective that comes off because of snappiness is not good; Particularly for the plastic flexible package product, effect is very obvious, has promoted quality product.And, add essence microcapsule in the UV curable ink and make UV curable ink can give out fragrance, can improve user's comfort of the product of having used this UV curable ink, more environmental protection.
Description of drawings
In order to be illustrated more clearly in the embodiment of the invention or technical scheme of the prior art; To do to introduce simply to the accompanying drawing of required use in embodiment or the description of the Prior Art below; Obviously, the accompanying drawing in describing below only is some embodiments of the present invention, for those of ordinary skills; Under the prerequisite of not paying creative work property, can also obtain other accompanying drawing according to these accompanying drawings.
Fig. 1 is the schematic flow sheet that the embodiment of the invention provides a kind of preparation method of UV curable ink.
Embodiment
The embodiment of the invention provides a kind of UV curable ink and preparation method thereof, in the hope of the toughness of bigger raising printing ink, and then promotes quality product.
In order to make those skilled in the art person understand the present invention program better; To combine the accompanying drawing in the embodiment of the invention below; Technical scheme in the embodiment of the invention is carried out clear, intactly description; Obviously, described embodiment only is the embodiment of the present invention's part, rather than whole embodiment.Based on the embodiment among the present invention, those of ordinary skills are not making the every other embodiment that is obtained under the creative work prerequisite, all should belong to the scope of the present invention's protection.
Below be elaborated respectively through specific embodiment.
The embodiment of the invention provides a kind of UV curable ink, and its component can comprise:
Isobornyl methacrylate, 2-Hydroxylated acrylic resin, 1-hydroxy-cyclohexyl phenyl-acetone, essence microcapsule, pigment and Synolac.
Wherein, the weight specific gravity range of each component of UV curable ink for example can be:
The 2-Hydroxylated acrylic resin account for 50 parts to 70 parts (for example 50 parts, 52 parts, 55 parts, 56 parts, 58 parts or 60 parts, 62 parts, 65 parts, 67 parts, 70 parts or other umbers),
Isobornyl methacrylate account for 5 parts to 15 parts (for example 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts or other umbers),
1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts to 5 parts (for example 2 parts, 3 parts, 3.5 parts, 4 parts, 5 parts or other umbers),
Pigment (can select the pigment of different colours and attribute for use as required) account for 10 parts to 20 parts (for example 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts or other umbers),
Synolac account for 10 parts to 20 parts (for example 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts or other umbers),
Essence microcapsule accounts for 0.5 part～5 parts (for example 0.5 part, 1 part, 2 parts, 3 parts, 5 parts or other umbers).
Wherein, the particle diameter of essence microcapsule for example can be 0.1～30 micron, perhaps is made as other size as required.
For instance, under a kind of application scenarios, the weight proportion of each component of UV curable ink for example can for: 2-Hydroxylated acrylic resin account for 70 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 4 parts,
Isobornyl methacrylate account for 6 parts,
Pigment account for 10 parts,
Synolac account for 10 parts,
Essence microcapsule accounts for 0.5 part to 5 parts (for example 0.5 part, 1 part, 2 parts, 3 parts, 5 parts or other umber).
Under another kind of application scenarios, the weight proportion of each component of UV curable ink for example can be:
The 2-Hydroxylated acrylic resin account for 60 parts,
Isobornyl methacrylate account for 15 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts,
Pigment account for 13 parts,
Synolac account for 10 parts,
Essence microcapsule accounts for 0.5 part to 5 parts (for example 0.5 part, 1 part, 2 parts, 3 parts, 5 parts or other umber).
Under another kind of application scenarios, the weight proportion of each component of UV curable ink for example can be:
The 2-Hydroxylated acrylic resin account for 55 parts,
Isobornyl methacrylate account for 10 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts,
Pigment account for 18 parts,
Synolac account for 15 parts,
Essence microcapsule accounts for 0.5 part to 5 parts (for example 0.5 part, 1 part, 2 parts, 3 parts, 5 parts or other umber).
Under another kind of application scenarios, the weight proportion of each component of UV curable ink for example can be:
The 2-Hydroxylated acrylic resin account for 55 parts,
Isobornyl methacrylate account for 8 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 5 parts,
Pigment account for 15 parts,
Synolac account for 17 parts,
Essence microcapsule accounts for 0.5 part to 5 parts (for example 0.5 part, 1 part, 2 parts, 3 parts, 5 parts or other umber).
Under another kind of application scenarios, the weight proportion of each component of UV curable ink for example can be:
The 2-Hydroxylated acrylic resin account for 50 parts,
Isobornyl methacrylate account for 5 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 5 parts,
Pigment account for 20 parts,
Synolac account for 20 parts,
Essence microcapsule accounts for 0.5 part to 5 parts (for example 0.5 part, 1 part, 2 parts, 3 parts, 5 parts or other umber).
Under another kind of application scenarios, the weight proportion of each component of UV curable ink for example can be:
The weight proportion of isobornyl methacrylate accounts for 8 parts (test finds that when the weight proportion of isobornyl methacrylate accounted for 8 parts, the snappiness effect of UV curable ink was very good relatively);
The weight proportion of 2-Hydroxylated acrylic resin, 1-hydroxy-cyclohexyl phenyl-acetone, essence microcapsule, pigment and Synolac and account for 92.5 parts～97 parts.Certainly the weight specific gravity range of these several components can satisfy: the 2-Hydroxylated acrylic resin accounts for 50 parts to 70 parts, 1-hydroxy-cyclohexyl phenyl-acetone and accounts for 2 parts to 5 parts, pigment and account for 10 parts to 20 parts, Synolac and account for 10 parts to 20 parts, essence microcapsule and account for 0.5 part to 5 parts.
Certainly, those skilled in the art are according to the needs of practical application, also can adjust the weight proportion of each component of UV curable ink, be not limited to above-mentioned for example, enumerate no longer one by one here.
In the embodiment of the invention, select the toughness modified monomer of isobornyl methacrylate for use as UV curable ink.Add isobornyl methacrylate, can the hardness and the flexility of UV curable ink is unified capitally for one, make polymkeric substance have outstanding high photosensitiveness, clarity, scuff resistance, resistance to medium and weathering resistance.Simultaneously, isobornyl methacrylate also can be used as reactive thinner, in the uv curing ink system, can reduce the viscosity of printing ink effectively, improves the leveling characteristics of printing ink.
Wherein, vinyl resin (for example can be the 2-Hydroxylated acrylic resin) is as the photopolymerization prepolymer of UV curable ink; 1-hydroxy-cyclohexyl phenyl-acetone is then as ultraviolet light polymerization light trigger (being light trigger); Synolac is as dispersion agent.
The embodiment of the invention also provides a kind of preparation method of UV curable ink.
Referring to Fig. 1, a kind of preparation method of UV curable ink can comprise:
101, taking by weighing 2-Hydroxylated acrylic resin, isobornyl methacrylate, 1-hydroxy-cyclohexyl phenyl-acetone, essence microcapsule, pigment and Synolac is contained in the container;
The weight specific gravity range of each component that wherein, takes by weighing for example can be:
The 2-Hydroxylated acrylic resin account for 50 parts to 70 parts (for example 50 parts, 52 parts, 55 parts, 56 parts, 58 parts or 60 parts, 62 parts, 65 parts, 67 parts, 70 parts or other umbers),
Isobornyl methacrylate account for 5 parts to 15 parts (for example 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts or other umbers),
1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts to 5 parts (for example 2 parts, 3 parts, 3.5 parts, 4 parts, 5 parts or other umbers),
Pigment (can select the pigment of different colours and attribute for use as required) account for 10 parts to 20 parts (for example 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts or other umbers),
Synolac account for 10 parts to 20 parts (for example 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts or other umbers),
Essence microcapsule accounts for 0.5 part～5 parts (for example 0.5 part, 1 part, 2 parts, 3 parts, 5 parts or other umbers).
Wherein, the particle diameter of essence microcapsule for example can be 0.1～30 micron, perhaps is made as other size as required.
For instance, under a kind of application scenarios, the weight proportion of each component of UV curable ink that takes by weighing for example can be: the 2-Hydroxylated acrylic resin account for 70 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 4 parts,
Isobornyl methacrylate account for 6 parts,
Pigment account for 10 parts,
Synolac account for 10 parts,
Essence microcapsule accounts for 0.5 part to 5 parts.
Under another kind of application scenarios, the weight proportion of each component of UV curable ink that takes by weighing for example can be: the 2-Hydroxylated acrylic resin account for 60 parts,
Isobornyl methacrylate account for 15 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts,
Pigment account for 13 parts,
Synolac account for 10 parts,
Essence microcapsule accounts for 0.5 part to 5 parts.
Under another kind of application scenarios, the weight proportion of each component of UV curable ink that takes by weighing for example can be: the 2-Hydroxylated acrylic resin account for 55 parts,
Isobornyl methacrylate account for 10 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts,
Pigment account for 18 parts,
Synolac account for 15 parts,
Essence microcapsule accounts for 0.5 part to 5 parts.
Under another kind of application scenarios, the weight proportion of each component of UV curable ink that takes by weighing for example can be: the 2-Hydroxylated acrylic resin account for 55 parts,
Isobornyl methacrylate account for 8 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 5 parts,
Pigment account for 15 parts,
Synolac account for 17 parts,
Essence microcapsule accounts for 0.5 part to 5 parts.
Under another kind of application scenarios, the weight proportion of each component of UV curable ink that takes by weighing for example can be: the 2-Hydroxylated acrylic resin account for 50 parts,
Isobornyl methacrylate account for 5 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 5 parts,
Pigment account for 20 parts,
Synolac account for 20 parts,
Essence microcapsule accounts for 0.5 part to 5 parts.
Under another kind of application scenarios, the weight proportion of each component of UV curable ink that takes by weighing for example can be: the weight proportion of isobornyl methacrylate accounts for 8 parts; The weight proportion of 2-Hydroxylated acrylic resin, 1-hydroxy-cyclohexyl phenyl-acetone, essence microcapsule, pigment and Synolac and account for 92.5 parts～97 parts.Certainly, the weight specific gravity range of these several components can satisfy: the 2-Hydroxylated acrylic resin accounts for 50 parts to 70 parts, 1-hydroxy-cyclohexyl phenyl-acetone and accounts for 2 parts to 5 parts, pigment and account for 10 parts to 20 parts, Synolac and account for 10 parts to 20 parts, essence microcapsule and account for 0.5 part to 5 parts.
Certainly, those skilled in the art are according to the needs of practical application, also can adjust the weight proportion of each component of UV curable ink, be not limited to above-mentioned for example, enumerate no longer one by one here.
2-Hydroxylated acrylic resin, isobornyl methacrylate, 1-hydroxy-cyclohexyl phenyl-acetone, essence microcapsule, pigment and the Synolac that 102, will be contained in the container carry out uniform mixing to obtain UV curable ink.
In the practical implementation process, for example can other each component that does not comprise essence microcapsule that take by weighing be contained in the container (for example selecting stainless steel vessel for use), then utilize stirrer for example mixing under 2000 rev/mins the rotating speed.Certainly, if the granularity of the 2-Hydroxylated acrylic resin, isobornyl methacrylate, 1-hydroxy-cyclohexyl phenyl-acetone, pigment and the Synolac that take by weighing is bigger, then can be earlier its grinding enough be carried out uniform mixing with essence microcapsule after carefully more together.Behind other each the component uniform mixing that does not comprise essence microcapsule; Again to wherein adding essence microcapsule and uniform mixing to obtain UV curable ink; For guaranteeing that essence microcapsule is not destroyed, add essence microcapsule and can select slower mixing stirring velocity to carry out uniform mixing afterwards.
Further, can and under room temperature (as 15～25 ℃), preserve the UV curable ink cooling back sealing that obtains behind grinding and the uniform mixing.
The UV curable ink that the embodiment of the invention provides can be applicable to plane and curved face product printing.
For example when being applied to the polyethylene plastic hose surface printing, its use step can be following:
Earlier flame or corona treatment are carried out in the polyethylene plastic hose surface; Then ultraviolet curing varnish is uniformly coated on this polyethylene plastic hose surface and solidifies (ultraviolet light polymerization radiation of equipment capable of using solidifies, for example the ultraviolet light polymerization baking oven) through glazing device; The UV curable ink that again embodiment of the invention is provided is coated on this polyethylene plastic hose surface through screen process press; At last, the drying through passing through UV-light low temperature fast setting.
Test is found; Have the toughness modified monomer of good flexible isobornyl methacrylate owing to adopt as printing ink; Can guarantee the good adhesion of double exposure ink film in the flexible while of greatly improving cured film, thereby help overcoming the ink film cracking that has general printing ink now and in double exposure more than 3 times, cause, the defective that comes off because of snappiness is not good; Particularly for the plastic flexible package product, effect is very obvious.
For instance, the plastic hose that prints is carried out 180 ° of bendings, can see obviously that the ink film of stack printing place is repeatedly compared the repeatedly ink film of double exposure gained of the general printing ink of use, its toughness is improved greatly, can not occur cracking, obscission basically.
Because essence is wrapped in the microcapsule, so volatilization process is slow, lasting fragrance.Touch print surface with have gentle hands behind the ink solidification, promptly can smell fragrance.Essence microcapsule in the UV curable ink provided by the invention can have lemon, orange, coconut, strawberry, grape, apple, sweet osmanthus, santal, cherry or rose or the like fragrance.As required; Can select the UV curable ink consistent that the packing of product is printed, realize that promptly the fragrance that the human consumer is distributed according to the packing of product comes the fragrance of sense of reality product and instructs the purpose of choosing the product of oneself admiring with this with the fragrance of wrapped product.
In the above-described embodiments, possibly emphasize particularly on different fields, not have the part that details among certain embodiment the description of each embodiment, can be referring to the associated description of other embodiment.
To sum up; Embodiment of the invention scheme can guarantee the good adhesion of double exposure ink film in the flexible while of greatly improving cured film because employing has the toughness modified monomer of good flexible isobornyl methacrylate as printing ink; Thereby help overcoming the ink film cracking that has general printing ink now and in double exposure more than 3 times, cause, the defective that comes off because of snappiness is not good; Particularly for the plastic flexible package product, effect is very obvious, has promoted quality product.And, add essence microcapsule in the UV curable ink and make UV curable ink can give out fragrance, can improve user's comfort of the product of having used this UV curable ink, more environmental protection.
Simultaneously, the embodiment of the invention combines microcapsulary and the quick low-temperature curing technology of UV-light, when can be implemented in the snappiness requirement when satisfying the UV curable ink double exposure, makes the printing ink that is printed on outside the wrapped product volatilize persistent fragrance.Suppose that the fragrance of printing-ink and the fragrance of wrapped product are consistent, be able to embody thereby can satisfy the fragrance that on the basis of the good barrier property that guarantees built-in product, makes product simultaneously, so overcome the deficiency that existing perfumed product exists on packing.
More than a kind of UV curable ink that the embodiment of the invention provided and preparation method thereof has been carried out detailed introduction; Used concrete example among this paper principle of the present invention and embodiment are set forth, the explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof; Simultaneously, for one of ordinary skill in the art, according to thought of the present invention, the part that on embodiment and range of application, all can change, to sum up, this description should not be construed as limitation of the present invention.
Claims (10)
1. UV curable ink is characterized in that component comprises:
Isobornyl methacrylate, 2-Hydroxylated acrylic resin, 1-hydroxy-cyclohexyl phenyl-acetone, Synolac, pigment and essence microcapsule.
2. UV curable ink according to claim 1 is characterized in that, the weight specific gravity range of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 50 to 70 parts,
Said isobornyl methacrylate account for 5 parts to 15 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts to 5 parts,
Said pigment account for 10 parts to 20 parts,
Said Synolac account for 10 parts to 20 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
3. UV curable ink according to claim 2 is characterized in that, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 70 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 4 parts,
Said isobornyl methacrylate account for 6 parts,
Said pigment account for 10 parts,
Said Synolac account for 10 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
4. UV curable ink according to claim 2 is characterized in that, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 60 parts,
Said isobornyl methacrylate account for 15 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts,
Said pigment account for 13 parts,
Said Synolac account for 10 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
5. UV curable ink according to claim 2 is characterized in that, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 55 parts,
Said isobornyl methacrylate account for 10 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts,
Said pigment account for 18 parts,
Said Synolac account for 15 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
6. UV curable ink according to claim 2 is characterized in that, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 55 parts,
Said isobornyl methacrylate account for 8 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 5 parts,
Said pigment account for 15 parts,
Said Synolac account for 17 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
7. UV curable ink according to claim 2 is characterized in that, the weight proportion of said each component of UV curable ink is:
Said 2-Hydroxylated acrylic resin account for 50 parts,
Said isobornyl methacrylate account for 5 parts,
Said 1-hydroxy-cyclohexyl phenyl-acetone account for 5 parts,
Said pigment account for 20 parts,
Said Synolac account for 20 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
8. UV curable ink according to claim 2 is characterized in that,
The weight proportion of said isobornyl methacrylate accounts for 8 parts.
9. the preparation method of a UV curable ink is characterized in that, comprising:
Taking by weighing 2-Hydroxylated acrylic resin, isobornyl methacrylate, pigment, essence microcapsule, Synolac and 1-hydroxy-cyclohexyl phenyl-acetone is contained in the container;
The 2-Hydroxylated acrylic resin, isobornyl methacrylate, 1-hydroxy-cyclohexyl phenyl-acetone, pigment, essence microcapsule and the Synolac that are contained in the said container are carried out uniform mixing to obtain UV curable ink.
10. preparation method according to claim 9 is characterized in that,
The weight specific gravity range of each component of UV curable ink that takes by weighing for example can be:
The 2-Hydroxylated acrylic resin account for 50 parts to 70 parts,
Isobornyl methacrylate account for 5 parts to 15 parts,
1-hydroxy-cyclohexyl phenyl-acetone account for 2 parts to 5 parts,
Pigment account for 10 parts to 20 parts,
Synolac account for 10 parts to 20 parts,
Said essence microcapsule accounts for 0.5 part～5 parts.
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| CN103666071A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Light-curable printing ink used for silk screen printing and preparation method thereof |
| CN103666033A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Novel UV (ultraviolet) curing silk-screen printing pearly-luster ink and preparation method thereof |
| CN105087163A (en) * | 2015-08-28 | 2015-11-25 | 上海应用技术学院 | Cocoanut flavoring essence for oily printing ink and preparation method therefor |
| CN105132170A (en) * | 2015-08-28 | 2015-12-09 | 上海应用技术学院 | Lemon essence for water-based ink and preparation method of lemon essence |
| CN105132171A (en) * | 2015-08-28 | 2015-12-09 | 上海应用技术学院 | Cucumber essence used for water-based ink and preparation method of cucumber essence |
| CN105132169A (en) * | 2015-08-28 | 2015-12-09 | 上海应用技术学院 | Green apple essence used for water-based ink and preparation method of green apple essence |
| CN109263323A (en) * | 2018-10-09 | 2019-01-25 | 东莞特式印刷制品有限公司 | Fruit prints fragrance technique |
| CN110436762A (en) * | 2019-08-13 | 2019-11-12 | 咖法科技(上海)有限公司 | A kind of marble paper glass production method that can generate smell |
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| CN103666033A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Novel UV (ultraviolet) curing silk-screen printing pearly-luster ink and preparation method thereof |
| CN103666033B (en) * | 2013-11-23 | 2016-05-04 | 铜陵方正塑业科技有限公司 | A kind of novel UV solidifies serigraphy pearl ink and preparation method thereof |
| CN103666071A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Light-curable printing ink used for silk screen printing and preparation method thereof |
| CN105087163A (en) * | 2015-08-28 | 2015-11-25 | 上海应用技术学院 | Cocoanut flavoring essence for oily printing ink and preparation method therefor |
| CN105132170A (en) * | 2015-08-28 | 2015-12-09 | 上海应用技术学院 | Lemon essence for water-based ink and preparation method of lemon essence |
| CN105132171A (en) * | 2015-08-28 | 2015-12-09 | 上海应用技术学院 | Cucumber essence used for water-based ink and preparation method of cucumber essence |
| CN105132169A (en) * | 2015-08-28 | 2015-12-09 | 上海应用技术学院 | Green apple essence used for water-based ink and preparation method of green apple essence |
| CN109263323A (en) * | 2018-10-09 | 2019-01-25 | 东莞特式印刷制品有限公司 | Fruit prints fragrance technique |
| CN110436762A (en) * | 2019-08-13 | 2019-11-12 | 咖法科技(上海)有限公司 | A kind of marble paper glass production method that can generate smell |
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