CN102127347A - Fluorine-containing polymer coating for glass and product containing same - Google Patents
Fluorine-containing polymer coating for glass and product containing same Download PDFInfo
- Publication number
- CN102127347A CN102127347A CN2010100040053A CN201010004005A CN102127347A CN 102127347 A CN102127347 A CN 102127347A CN 2010100040053 A CN2010100040053 A CN 2010100040053A CN 201010004005 A CN201010004005 A CN 201010004005A CN 102127347 A CN102127347 A CN 102127347A
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- China
- Prior art keywords
- base composition
- particle size
- paint base
- colloidal silica
- goods
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011521 glass Substances 0.000 title claims abstract description 42
- 229920000642 polymer Polymers 0.000 title claims abstract description 17
- 239000011248 coating agent Substances 0.000 title abstract description 22
- 238000000576 coating method Methods 0.000 title abstract description 22
- 229910052731 fluorine Inorganic materials 0.000 title abstract description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title abstract 2
- 239000011737 fluorine Substances 0.000 title abstract 2
- 239000002245 particle Substances 0.000 claims abstract description 77
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000003973 paint Substances 0.000 claims abstract description 55
- 239000000203 mixture Substances 0.000 claims abstract description 52
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 18
- 239000010954 inorganic particle Substances 0.000 claims abstract description 3
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000008119 colloidal silica Substances 0.000 claims description 26
- 229920002313 fluoropolymer Polymers 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 22
- 239000004811 fluoropolymer Substances 0.000 claims description 18
- 239000011324 bead Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 7
- 229940075614 colloidal silicon dioxide Drugs 0.000 abstract 2
- 229940058401 polytetrafluoroethylene Drugs 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 description 15
- 239000000843 powder Substances 0.000 description 14
- 239000000377 silicon dioxide Substances 0.000 description 8
- -1 Perfluoro Chemical group 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 229920005548 perfluoropolymer Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 5
- 230000037452 priming Effects 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000007667 floating Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000005361 soda-lime glass Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000032900 absorption of visible light Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 150000001553 barium compounds Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001785 cerium compounds Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 150000002611 lead compounds Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HEBRGEBJCIKEKX-UHFFFAOYSA-M sodium;2-hexadecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HEBRGEBJCIKEKX-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
- B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
- B05D5/086—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers having an anchoring layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2203/00—Other substrates
- B05D2203/30—Other inorganic substrates, e.g. ceramics, silicon
- B05D2203/35—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/53—Base coat plus clear coat type
- B05D7/534—Base coat plus clear coat type the first layer being let to dry at least partially before applying the second layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
- C03C2217/478—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
Abstract
The invention relates to fluorine-containing polymer coating for glass and a product containing the same, and particularly discloses a base paint composition containing polytetrafluoro ethylene (PFA) polymer particles and colloidal silicon dioxide particles, which are dispersed in a vaporizable aqueous liquid medium. The weight ratio of the colloidal silicon dioxide particles to the PFA polymer particles is less than or equal to 0.6. The base paint composition contains a) less than 1 weight part of non-vaporizable organic compound having at least one C-H bond and b) inorganic particles of which the average particle size is larger than 1 micrometer. The invention also discloses a method for coating the base paint on glass and products.
Description
Technical field
The disclosure relates generally to fluorocarbon polymer coating.
Background technology
Because fluoropolymer can provide high thermostability, outstanding chemical resistant properties, good film toughness usually, to the UV of very wide scope and the low absorption of visible light, and low surface energy, it is widely known by the people as the important organic materials of a class in the industry,
Perfluoro and thermoplastic fluoropolymer, be called as fluoroplastics or thermoplastic fluoroelastomer plastics in the art, usually to nearly all chemical substance and solvent inertia, even also be like this under the temperature and pressure that raises, it only reacts with the basic metal that strong reducing property reagent for example melts.In addition, their high crystalline causes low relatively gas and moisture permeable, makes them can be used as fabulous barrier resins.They have caused well-known anti stick to be used with respect to the low surface energy and the frictional coefficient of other material.Specific refractory power that they are extremely low and optical clarity make them can be used for comprising the optical application of antireflecting coating.The monomeric fluoroplastics multipolymer that contains tetrafluoroethylene and perfluoro (propyl vinyl ether) is being collectively referred to as abbreviation PFA in the art.Term PFA has comprised the multipolymer of tetrafluoroethylene and perfluoro (propyl vinyl ether) (for example perfluoro (ethylene methacrylic ether)), and the multipolymer of tetrafluoroethylene and perfluoro (propyl vinyl ether) and one or more other perfluoro monomers (for example R 1216).
Fluoropolymer has been used to for example bulb of coated glass substrates, be used for when bulb break, preventing pulverizing and send forth, be used for the coating metal base material to obtain anti stick character (for example cooker, bakeware), also can in industrial application (chemical storage tanks, vapor pipe), be used for protection against corrosion.But their intrinsic anti stick characteristics can make difficulty takes place when attempting to be adhered to them on the base material.
Summary of the invention
On the one hand, the disclosure provides to contain and has been dispersed in the PFA polymer beads that can evaporate in the water-based liquid medium and the paint base composition of colloidal silica particle, wherein the weight ratio of the colloidal silica particle of paint base composition and PFA polymer beads is less than or equal to 0.6, and wherein paint base composition contains and is less than a weight: the organic compound that a) has the non-vaporising of at least one c h bond; And b) average particle size particle size is greater than 1 micron inorganic particle.
In certain embodiments, the weight ratio of colloidal silica particle and PFA polymer beads is more than or equal to 0.3.In certain embodiments, the average particle size particle size of colloidal silica particle is 4 to 45 nanometers (nm) or 4 to 20 nm.In certain embodiments, paint base composition is basically by PFA polymer beads, colloidal silica particle with can evaporate water-based liquid medium and form.In certain embodiments, paint base composition contains from the solids content of one of percentage to ten.In certain embodiments, can evaporate water-based liquid medium and not contain transpirable organic solvent.
On the other hand, the disclosure provides the goods that comprise the base material with glass surface, and this glass surface is equipped with prime coat on its at least a portion, wherein by paint base composition of the present disclosure to the dry prime coat that forms of small part.
In certain embodiments, goods also comprise the fluoropolymer layer that is coated on the prime coat.In certain embodiments, base material comprises bulb.In certain embodiments, base material comprises at least a in solar cell, mirror, window or the solar energy collector.
On the other hand, the disclosure provides a kind of such method, comprising: paint base composition of the present disclosure is contacted with the glass surface of base material, and can evaporate water-based liquid medium so that prime coat to be provided to small part evaporation.
In certain embodiments, method also is included in and is coated with fluoropolymer layer on the prime coat.
What have advantage is that paint base composition of the present disclosure has good adhesivity and the good light transmittance with glass, can provide suitable surface for further fluoropolymer supercoat (for example PFA layer).In addition, in typical embodiment, paint base composition has resistance for the variable color that is caused by thermooxidizing and/or light (for example weathering).
When using in this article:
Term " water-based " be meant the water that contains more than accidental amount (for example about at least 1,5,10 or even the water of about at least 20% weight, or more).
Term " inorganic " is meant anorganic compound; For the purpose of clear, when using in this article, it has clearly comprised all elements form of carbon.
Term " non-vaporising " is meant and can not evaporates.
Term " organically " is meant the compound of (the being C-H) key that has at least one carbon-hydrogen.
Term " perfluor plastics " is meant thermoplastic perfluoropolymer.
Term " (per) fluoropolymer " is meant the polymkeric substance that wherein all hydrogen atoms have been replaced by fluorine atom.
Term " transpirable " is meant under a normal atmosphere (0.1 MPa), can evaporate under 1 50 ℃ the temperature being lower than.
Claim postscript having considered detailed specification sheets and having enclosed will be understood that characteristics of the present disclosure and advantage.Below in conjunction with various illustrative embodiment of the present disclosure, these and other characteristics and advantage of the present disclosure are described.Top summary is not intended to describe each embodiment that is disclosed or each concrete enforcement of the present disclosure.Following figure and detailed description are more specifically for example understood illustrative embodiment.
Description of drawings
Fig. 1 is the side-view of exemplary article of the present disclosure.
Although the figure of pointing out has above been set forth several embodiment of the present disclosure, also considered other embodiment, as what propose under discussion. In all cases, the disclosure of disclosure proposition is illustrative and not restrictive. Should be appreciated that the professional of the art can design a large amount of other modifications and embodiment, they are within the scope and spirit of principle of the present disclosure. Figure may not draw in proportion.
Describe in detail
Paint base composition contains the PFA particle, usually is dispersed in and can evaporates in the water-based liquid medium with the latex form, although also can use other dispersion (for example can be metastable dispersion). Method for the manufacture of the PFA dispersion is well-known; For example at United States Patent (USP) 3,132, disclosed among 123 (Harris etc.), 4,029,868 (Carlson), 4,078,134 (Kuhls etc.) and 4,078,135 (Sulzbach etc.). Usually, the PFA fluoropolymer contains 92-99.5%, the more generally tetrafluoroethene of 96-99%, and 0.5-8%, the perfluor of 1-4% (propyl vinyl ether) more generally. Can trade name TEFLON PFA from E.I.du Pont de Nemoursand Co.of Wilmington, DE is commercially available water-based PFA dispersion, for example as TE-7224,857N-110,857N-210,858N-916 and 858N-917. Can use the combination of two kinds or above PFA particle.
In typical case, the PFA dispersion is stable in 1 to 11 pH scope, although also can use other pH value. In typical case, total the PFA content of paint base composition accounts for 0.1 to 40 percentage by weight of the gross weight of paint base composition, more be typically 2 to 25 percentage by weights, although also can use other amount.
Paint base composition can be chosen wantonly and contain one or more other (per) fluoropolymer particle. Example comprises polytetrafluoroethylgranule granule, polyhexafluoropropylene particle and hexafluoropropene-TFE copolymer (FEP) particle. The dispersion that other optional perfluoro polymer beads can be used as latex or other type provides; Obtain for example according to the known method preparation, or from commercial source.
If present, optional perfluoro polymer beads exists with following part by weight, i.e. PFA: the part by weight of optional perfluoro polymer beads is in 1: 4 to 4: 1 scope, in more typical 3: 7 to 7: 3 scope.
Silica dioxide granule has the average particle size particle size less than about 150nm usually, although if they can be suspended in the paint base composition, can use bigger average particle size particle size. Generally, the average particle size particle size of silica dioxide granule arrives in the scope of 45nm 4, is more typically in 4 in the scope of 20nm. Term used herein " silica dioxide granule " refers to not have the silica dioxide granule of any covalently bound organic surface group.
Generally, silica dioxide granule is provided in the colloidal dispersion system (for example colloidal sol), although this is optional. The colloidal silica particle of acidity or alkaline form can be obtained, any form can be used. The method of making colloidal silica particle comprises for example part neutralization of alkali-silicate solution. More generally, colloidal silica dispersions system is provided by commercial supplier, and for example from W.R.Grace of Columbia, MD provides with trade name LUDOX; Or as NALCO 1034A colloidal silica (NALCO 1034A), NALCO1129 colloidal silica (NALCO 1129), NALCO 2327 colloidal silicas (NALCO 2327), NALCO 2326 colloidal silicas (NALCO 2326), and NALCO 1140 colloidal silicas (NALCO 1140), they can be from NalcoChemical Company ofNaperville, and IL obtains.
The average particle size particle size of NALCO 1034A is 20nm, and the dioxide-containing silica in the water is about 34 percentage by weights, and pH is about 3.1. The average particle size particle size of NALCO 1129 is 20nm, the SiO in the solution of 40% isopropyl alcohol and 30% water2Content is about 30 percentage by weights. The average particle size particle size of NALCO 2327 is 20 nm, and the dioxide-containing silica in the water is about 40 percentage by weights, and pH is about 9.3, and ammonium is as stabilizing ion. The average particle size particle size of NALCO 2326 is 5nm, and the dioxide-containing silica in the water is about 14.5 percentage by weights, and pH is about 9.0, and ammonium is as stabilizing ion. The average particle size particle size of NALCO 1140 is 1 5nm, and the dioxide-containing silica in the water is about 40 percentage by weights, and pH is about 9.7, and sodium is as stabilizing ion.
Can evaporate water-based liquid medium and comprise water and one or more optional organic solvents, be generally volatile organic solvent, its amount can form single-phase so that can evaporate water-based liquid medium. The example of organic solvent comprises methyl alcohol, ethanol, isopropyl alcohol, acetone, 2-methyl cellosolve, glyme and oxolane. Generally, can evaporate waterborne liquid and be substantially free of mutually (for example contain be less than 1 percentage by weight) volatile organic solvent. Generally, the concentration of organic solvent accounts for 0 to 40 percentage by weight of the weight that can evaporate water-based liquid medium.
Paint base composition can have any such pH, is used as paint base composition for its expection, and described pH can give said composition with enough stability. Generally, pH arrives in about 11 the scope, although also can use other pH value about 9. Paint base composition can have any solids content, for example accounts for about 2 of paint base composition gross weight and arrives about 20 percentage by weights, although also can use other amount.
Randomly, can in paint base composition, add surfactant. Available surfactant comprises for example cetyl benzene sulfonic acid sodium salt of ionic surface active agent, and non-ionic surface active agent.
Generally, by PFA particle and the synthetic dispersion system of silica dioxide granule hybrid junctions are made paint base composition, although also can use other method. Generally, the pH of paint base composition be maintained at 9 or more than, but this can change according to the dispersion that uses.
Generally, paint base composition of the present disclosure is applied on the glass surface of base material, and at least part of drying to be to form prime coat, more generally bone dry basically. Term used herein " drying " refers to evaporate water-based liquid medium and removes as a whole, is not only water. Can paint base composition be placed on the glass surface by any suitable method for example dip-coating, spraying, brush, showering, blade coating, roller coating, bar type coating or trowelling. In case after being placed on the base material, with at least part of drying of paint base composition, with remove at least some, all evaporated water-based liquid medium basically generally. Can for example promote drying by air stream assisted evaporative, heating and/or decompression.
Then fluoropolymer is placed on the prime coat. This is presented among Fig. 1, and wherein exemplary article 100 contains the base material 110 with glass surface 11 5, and prime coat 120 places on the glass surface 11 5, and fluoropolymer layer 130 places on the prime coat 120.
Base material has the glass surface that is provided with paint base composition on it, all is glass although do not need all surface of base material. Paint base composition can be arranged on the part or whole glass surface of glass surface. In certain embodiments, paint base composition can spread on one or more other surperficial at least a portion except glass surface of base material. Term used herein " glass " refers to non-crystal transparent or translucent material, can formed after the cooling fast by the silica of fusing and optional other compound (for example soda and lime, lead compound, boron compound, barium compound, rare earth compound, iron compound and cerium compound). The glass of example comprises soda-lime glass and borosilicate glass.
Base material with example of glass surface comprises bulb, window, cooker (for example saucepan, saucepan), bakeware (for example roasting basin of PYREX), solar cell, solar thermal collector, windshield and mirror (for example Optical Solar Reflector). In certain embodiments, for example as the coating of bulb, apply the PFA layer at prime coat and can provide anti-comminuted. In the situation of bulb break, the PFA layer can be used for comprising glass fragment, and comprises mercury in the situation of fluorescent tube or compact fluorescent light bulb.
The (per) fluoropolymer layer comprises at least a (per) fluoropolymer.Generally, fluoropolymer layer is substantially free of the polymkeric substance that (for example contain be less than 1 weight percent) has c h bond, although this is optional.The (per) fluoropolymer layer can comprise other composition, for example weighting agent, photostabilizer, antioxidant, tensio-active agent and tinting material.The example of the (per) fluoropolymer that is fit to comprises FEP and PFA.Polymer layer for example can be used as that suspension is applied on the prime coat, perhaps directly is squeezed on the prime coat.
Under the vantage, paint base composition of the present disclosure, goods and method can solve the problem that existing P FA adhesion primer for example lacks high light transmission, improve the mechanical property of PFA coating, and improve the adhesion strength of perfluoro plastics and glass surface.
Purpose of the present disclosure and advantage will further specify by following non-limiting example, but concrete material and the amount thereof told about in these embodiments, and other condition and details, should not be interpreted as improper restriction of the present disclosure.
Embodiment
Except as otherwise noted, all umbers in the rest part of embodiment and specification sheets, percentage, ratio etc. all are by weight.
From Nalco Chemical Company of Naperville, IL obtains the nano SiO 2 particle dispersion system NALCO 1115 (solids of 15 weight percents, the colloidal silica of 4 nanometer average particle size particle size), NALCO 2326 (the silicon-dioxide of 14.5 weight percents, the colloidal silica of 5nm average particle size particle size) and NALCO 2327 (silicon-dioxide of 40 weight percents, 20nm average particle size particle size).
From 3M Dyneon of Oakdale, MN obtains DYNEON PFA 6900 N PFA dispersion systems (120 nm average particle size particle size, the solid of 50 weight percents).
From VWR International of West Chester, PA obtains the soda-lime glass slide glass, before use, by using Bros. from Fitzpatrick, Inc.of Chicago, the BAB-O powder sanitising agent of IL is cleaned gently, fully cleans with deionized water then and carries out pre-treatment.
Embodiment 1
NALCO 1115 silica dispersions system (1.0 grams (g), 4 nm average particle size particle size, 15 weight percent solids) is diluted with 9g water.In the dispersion system of dilution, add DYNEON PFA6900N dispersion system (1.0g).Blended dispersion system (paint base composition 1) is stable and transparent.
With the bulb (40 watts of osram lamps of General Electric Corporation) that is commercially available with water rinse and dry air.Except the neck area of bulb, apply (by dip-coating) above-described waterborne liquid priming paint to the surface.This provide PFA coating wherein not with the zone of glass attachment so that provide pulling-on piece (tab) for peeling off experiment.With the bulb after the coating in baking box 100 ℃ of dryings 1 hour.Use the manual powder coated system of Nordson SURECOAT (from Nordson Corp.ofWestlake then, OH), under 70 volts, 150kPa airflow, bulb is carried out the electrostatic powder coating with Dyneon PFA 6503B EPC powder (from the PFA powder of Dyneon LLC), up to not seeing exposed glass.Then with bulb in the air cycle baking box, 750 °F (400 ℃) baking 10 minutes.After from baking box, taking out, with bulb sample cool to room temperature.The bulb of the PFA coating that obtains is transparent, and PFA layer and not with the ratio of the interfacial phase between the neck area of priming paint, does not wherein observe and adheres to, and PFA layer and the interface that has a glass surface of priming paint are adhered to and shown outstanding adhesivity.
Embodiment 2
With the bulb (40 watts of osram lamps of General Electric Corporation) that is purchased with water rinse and dry air.According to aforementioned paint base composition 1 is applied on the bulb, just the whole surface of bulb is all applied.With the bulb that scribbles priming paint in baking box 1 00 ℃ of dryings 1 hour.Use the manual powder coated system of Nordson SURECOAT then, under 70 volts, 150kPa airflow, bulb is carried out the electrostatic powder coating with Dyneon PFA 6503B EPC powder (from the PFA powder of Dyneon LLC), up to not seeing exposed glass.Then with powder coated bulb in the air cycle baking box, 750 °F (400 ℃) baking 10 minutes.After from baking box, taking out, bulb is cooled off.The bulb that the bulb of the PFA coating that obtains and a last experiment obtain is about the same.The bulb of PFA coating is flung at ground from least 3 meters eminences.The bump back light finishes entirely and breaks, but all disruptive fragments are retained on the PFA layer of coating, and the PFA coating is kept perfectly.
Embodiment 3-7 and Comparative examples A-B
With two respectively is that the soda-lime glass microslide of 1 * 6 * 0.05 inch (2.54 * 1 5.2 * 0.127 cm) cleans with suds.Then with water rinse several times, dry air with glass bar.Except the top area of each glass bar one end, with the paint base composition coated glass bar of report in the table 1 above the glass bar of 2 inches (5cm).This is for providing its floating coat will be not and the zone of glass attachment, so that for peeling off experiment generation pulling-on piece.Use the manual powder coated system of NordsonSURECOAT then, under 70 volts, 150kPa airflow, glass bar is carried out the electrostatic powder coating with Dyneon PFA 6503B EPC powder (from the PFA powder of Dyneon LLC), up to not seeing exposed glass.Then with glass bar in the air cycle baking box, 750 °F (400 ℃) baking 10 minutes.After glass bar is taken out from baking box, with glass bar cooling, and with sharp blade in the scraping of the edge of each glass bar, to remove any coating that may be accumulated in the sample edge.Be equipped with the Instron tensile test device that floating roller is peeled off experimental installation by use, mainly according to test method ASTM D3167-03a (2004) " the floating roller of adhesive agent is peeled off resistance standard method of test (Standard Test Method for FloatingRoller Peel Resistance of Adhesives) ", with the pinblock speed of 6in/min (15cm/min) be stripped to the extension of 3.75 inches (9.5 cm) and specimen, thereby measure stripping strength.Use integral mean to calculate 1 to 3 inch interior stripping strength of (2.54 to 7.62cm) extension scope, and reported the mean value of three parts of parallel sampleses.Also measured pencil hardness and be reported in the table 1 (following).Use the percent transmittancy of UV-VIS spectrometer, measure to be reported in the table 2.
It is reference that patent that all are quoted in this article and publication draw with it in full at this.The example that all this paper provide, except as otherwise noted, it is nonrestrictive all being taken as.Those skilled in the art of the present technique can make various variant and change to the disclosure, and do not deviate from the scope of the present disclosure and spirit, should be appreciated that, the disclosure should not be subject to the illustrative embodiment that this paper proposes undeservedly.
Claims (24)
1. paint base composition, it contains and is dispersed in the PFA polymer beads and the colloidal silica particle that can evaporate in the water-based liquid medium, the weight ratio of colloidal silica particle that wherein said paint base composition has and PFA polymer beads is less than or equal to 0.6, and wherein said paint base composition contains and is less than a weight part: the organic compound that a) has the non-vaporising of at least one c h bond; And b) average particle size particle size is greater than 1 micron inorganic particle.
2. the paint base composition of claim 1, the weight ratio of wherein said colloidal silica particle and PFA polymer beads is more than or equal to 0.3.
3. the paint base composition of claim 1, the average particle size particle size of wherein said colloidal silica particle is 4 to 45 nanometers.
4. the paint base composition of claim 1, the average particle size particle size of wherein said colloidal silica particle is 4 to 20 nanometers.
5. the paint base composition of claim 1, wherein said paint base composition are mainly by PFA polymer beads, colloidal silica particle with can evaporate water-based liquid medium and form.
6. the paint base composition of claim 1, the solids content of wherein said paint base composition is that one of percentage is to 10.
7. the paint base composition of claim 1, the wherein said water-based liquid medium that evaporates does not contain transpirable organic solvent.
8. the goods that comprise the base material with glass surface, this glass surface is equipped with prime coat on its at least a portion, wherein prime coat forming to small part is dry by the paint base composition of claim 1.
9. the goods of claim 8, wherein the weight ratio of colloidal silica particle and PFA polymer beads is more than or equal to 0.3.
10. the goods of claim 8, wherein the average particle size particle size of colloidal silica particle is 4 to 45 nanometers.
11. the goods of claim 8, wherein the average particle size particle size of colloidal silica particle is 4 to 20 nanometers.
12. the goods of claim 8, wherein said paint base composition are mainly by PFA polymer beads, colloidal silica particle with can evaporate water-based liquid medium and form.
13. the goods of claim 8, the solids content of wherein said paint base composition are that one of percentage is to 10.
14. the goods of claim 8 also comprise the fluoropolymer layer that is coated on the described prime coat.
15. the goods of claim 8, wherein said base material comprises bulb.
16. the goods of claim 8, wherein said base material comprise at least a in solar cell, mirror, window or the solar energy collector.
17. make the method for goods, described method comprises: the paint base composition of claim 1 is contacted with the glass surface of base material, and can evaporate water-based liquid medium and proceed to small part and evaporate so that prime coat to be provided.
18. the method for claim 17 also is included on the described prime coat and is coated with fluoropolymer layer.
19. the method for claim 17, the weight ratio of wherein said colloidal silica particle and PFA polymer beads is more than or equal to 0.3.
20. the method for claim 17, the average particle size particle size of wherein said colloidal silica particle are 4 to 45 nanometers.
21. the method for claim 17, the average particle size particle size of wherein said colloidal silica particle are 4 to 20 nanometers.
22. the method for claim 17, wherein said paint base composition are mainly by PFA polymer beads, colloidal silica particle with can evaporate water-based liquid medium and form.
23. the method for claim 17, the solids content of wherein said paint base composition are that one of percentage is to 10.
24. the method for claim 17, wherein said base material comprise at least a in solar cell, mirror, window or the solar energy collector.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010100040053A CN102127347A (en) | 2010-01-14 | 2010-01-14 | Fluorine-containing polymer coating for glass and product containing same |
| PCT/US2011/020729 WO2011087997A1 (en) | 2010-01-14 | 2011-01-11 | Fluoropolymer coating for glass and articles including the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2010100040053A CN102127347A (en) | 2010-01-14 | 2010-01-14 | Fluorine-containing polymer coating for glass and product containing same |
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| CN102127347A true CN102127347A (en) | 2011-07-20 |
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| WO (1) | WO2011087997A1 (en) |
Cited By (1)
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|---|---|---|---|---|
| CN104781350A (en) * | 2012-11-14 | 2015-07-15 | 3M创新有限公司 | Fluoropolymer coatings suitable for films of photovoltaic modules |
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| US10400109B2 (en) | 2013-10-04 | 2019-09-03 | 3M Innovative Properties Company | Coatable composition, antistatic composition, antistatic articles, and methods of making the same |
| EP3710279A2 (en) | 2017-11-17 | 2020-09-23 | 3M Innovative Properties Company | Ink-receptive layers for durable labels |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3132123A (en) | 1960-11-25 | 1964-05-05 | Du Pont | Polymers of perfluoroalkoxy perfluorovinyl ethers |
| DE2523569C3 (en) | 1975-05-28 | 1980-08-07 | Hoechst Ag, 6000 Frankfurt | Process for the polymerization of tetrafluoroethylene by the suspension process |
| DE2617829C2 (en) | 1976-04-23 | 1982-06-03 | Hoechst Ag, 6000 Frankfurt | Process for the preparation of suspension polymers of tetrafluoroethylene |
| US4029868A (en) | 1976-03-10 | 1977-06-14 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene terpolymers |
| DE2906787A1 (en) * | 1979-02-22 | 1980-09-04 | Hoechst Ag | COATING AGENT BASED ON A COPOLYMER FROM TETRAFLUORETHYLENE AND A PERFLUOR (ALKYLVINYL) ETHER |
| DE3227043A1 (en) * | 1982-07-20 | 1984-01-26 | Hoechst Ag, 6230 Frankfurt | Primer containing polyarylene sulphide resin as coatings for fluorocarbon polymers |
| DE3366454D1 (en) * | 1982-07-20 | 1986-10-30 | Hoechst Ag | Primer for coatings containing fluorocarbon polymers with an amount of poly(arylene sulfide) resin, aromatic polyether sulfone resin or aromatic polyether ketone resin, and use thereof |
| US6207236B1 (en) * | 1996-06-19 | 2001-03-27 | Daikin Industries, Ltd. | Coating composition, coating film, and method for producing coating film |
| US6228932B1 (en) * | 1997-12-22 | 2001-05-08 | Dupont Mitsui Fluorochemicals | Fluororesin powder liquid dispersion capable of forming thick coatings |
| FR2869817B1 (en) * | 2004-05-04 | 2008-05-30 | Seb Sa | METHOD FOR MANUFACTURING AN ANTI-ADHESIVE COATING AND A CULINARY ARTICLE SO COATED |
| US20050267246A1 (en) * | 2004-05-28 | 2005-12-01 | Mckeen Laurence W | Abrasion resistant fluoropolymer compositions containing zeolite |
| US7531113B2 (en) * | 2004-05-28 | 2009-05-12 | E.I. Du Pont De Nemours And Company | Abrasion resistant fluoropolymer compositions containing micropulp |
| WO2007041227A2 (en) * | 2005-09-30 | 2007-04-12 | Dupont-Mitsui Fluorochemicals Company, Ltd. | A polymer composition with uniformly distributed nano-sized inorganic particles |
| JP2007266606A (en) * | 2006-03-28 | 2007-10-11 | Endicott Interconnect Technologies Inc | Fluoropolymer insulating composition for circuit board, and circuit board including same |
| JP5254042B2 (en) * | 2007-01-18 | 2013-08-07 | 三菱電機株式会社 | COATING COMPOSITION AND METHOD FOR PRODUCING THE SAME, HEAT EXCHANGER, AND AIR CONDITIONER |
-
2010
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104781350A (en) * | 2012-11-14 | 2015-07-15 | 3M创新有限公司 | Fluoropolymer coatings suitable for films of photovoltaic modules |
| CN104781350B (en) * | 2012-11-14 | 2017-09-05 | 3M创新有限公司 | Suitable for the fluorocarbon polymer coating of photovoltaic module film |
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| WO2011087997A1 (en) | 2011-07-21 |
| WO2011087997A8 (en) | 2012-02-23 |
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