CN102057925B - Insecticidal composition containing thiacloprid amide and biogenic insecticide - Google Patents
Insecticidal composition containing thiacloprid amide and biogenic insecticide Download PDFInfo
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Abstract
The invention discloses an insecticidal composition containing thiacloprid amide and a biogenic insecticide. The biogenic insecticide is selected from avermectin, emamectin benzoate, spinosad or spinetoram, and the ratio by weight of the thiacloprid amide to the biogenic insecticide is 1:40-40:1. The composition can be prepared into a dosage form which is agriculturally acceptable, such as water dispersible granules, wettable powder, a suspending agent, a dispersible oil suspending agent, a microcapsule suspending agent, missible oil or a micro emulsifier. The insecticidal composition has reasonable ingredients, great insecticide effect and low chemical cost. The activity and the insecticidal effect of the insecticidal composition are not just the simple sum of the activity and the insecticidal effect of all ingredients. Compared with the traditional single preparation, the insecticidal composition not only has remarkable insecticidal effect, but also has remarkable synergistic function, mitigates resistance generation, has small preparation residual quantity and high safety, does not pollute crops and meets the safety requirements of agricultural pesticide preparations. The insecticidal composition disclosed by the invention has better control effects on rice stem borers, vegetable plutella xylostella, beet armyworms, cotton bollworms and apple olethreutid.
Description
Technical field
The present invention relates to a kind of insecticides, be particularly related to the thiophene insect amide as the first active component, be selected from the biogenic substances insecticide of Avermectin, emamectin-benzoate, multiple killing teichomycin or ethyl pleocidin as the Pesticidal combination of the second active component, belong to technical field of compounded pesticide.
Background technology
The thiophene insect amide, test code number JS9117, chemical name is that (5-amino-1 for 3-bromo-N-{4-chloro-2-methyl-6-[2-, 3,4-thiadiazoles)] phenyl }-1-(3-chloropyridine-2-yl)-1H-pyrazoles-5-formamide, be the Novel ortho Heterocyclic formanilide compound that the Jiangsu pesticide research is developed, high-efficiency broad spectrum, harmful insect is had good control efficiency, and this compound can have efficiently with the insecticide in the fields such as preparation agricultural, gardening, low toxicity, eco-friendly advantage.Result of the test shows the specific activity other products of target pest high, and can cause some lepidopterous insects mating process disorderly, studies have shown that it can reduce the spawning rate of multiple noctuidae pests, because the biological property of the good and resistance of rainwater washing against of its lasting effect, these characteristics such as are actually permeability, conductivity, chemical stability, high insecticidal activity and cause that insect stops to take food immediately at the comprehensive embodiment that acts on.Therefore determined that it has longer and more stable and to the protective effect of crop than the present overwhelming majority at other insecticide of usefulness.But it exists quick-acting general, the defective that the single dose use cost is high.
Avermectin, english common name Abamectin, chemical molecular formula C
48H
72O
14(B1a) C
47H
70O
14(B1b) being a kind of macrolide disaccharide compounds, belonging to the biogenic insecticidal/acaricidal agent, is the natural products that separates from edaphon, insects and mites is had tag and stomach poison function and faint fumigation action is arranged, without systemic action.It has very strong osmosis to blade, can kill subepidermal insect, and the longevity of residure is long, not ovicidal.What its mechanism of action was different from general insecticide is that it disturbs neurophysiology movable, stimulate and discharge the r-aminobutyric acid, and the r-aminobutyric acid has inhibitory action to arthropodan nerve conduction, if paralysis symptom namely occurs after the mite class becomes mite and insect and larva and medicament contacts, inertia does not take food, and is dead after 2-4 days.Because not causing that insect dewaters rapidly, so its lethal effect is slower.But though predatism and parasite are had direct killing effect, because plant surface is residual few, therefore little to the damage of beneficial insect.In actual application, because the long-term Avermectin single dose of using causes pest resistance to rise year by year, the risk of use cost increase etc.
Emamectin-benzoate, English common name: Emamectin Benzoate.Chemical name: 4'-table-methylamino-4'-deoxidation abamectin benzoate.Be a kind of efficient, wide spectrum, long good insecticidal/acaricidal agent of the longevity of residure, its mechanism of action hinders pest movements nerve information transmission and makes the health paralysis dead.The mode of action without interior absorption energy, is used crop epidermal tissue but can effectively infiltrate, thereby is had the longer longevity of residure crop take stomach toxicity as main action of contace poison.Control Lepidoptera, mite class, coleoptera and homoptera pest are had high activity, and easily degraded noresidue is free from environmental pollution in soil and water, in the routine dose scope to useful insect and natural enemy, people, animal safety, can with most of combined use of pesticides.In actual application, because the long-term emamectin-benzoate single dose of using causes pest resistance to rise year by year, the risk of use cost increase etc.
Multiple killing teichomycin, English common name: Spinosad.Multiple killing teichomycin is a kind of a kind of macrolides Nuisanceless high-efficient biological source insecticide that extracts in thorn sugared many born of the same parents bacterium (Saccharopolyspora spinosa) zymotic fluid.Produce parent strain soil actinomycetes thorniness saccharopolyspora strain (the Saccharopolyspora Spinosa Metrz ﹠amp of pleocidin; Yao) initial separation is from one of the Caribbean discarded wine brewing field.Practical product is the mixture of SpinosynA and SpinosynB, so be called Spinosad.The mode of action of pleocidin is novel, can sustained activation target insect acetylcholine nicotine receptor, but its binding site is different from nicotine and Imidacloprid.Pleocidin also can affect the GABA acceptor, but mechanism of action is unclear.It can make insect benumb rapidly, paralyse, cause at last death, its desinsection speed can compare favourably with chemical pesticide, safe, and with present common insecticide be the biological insecticides of low toxicity, efficient, low-residual without cross resistance, existing efficient insecticidal properties has again the characteristic of beneficial insect and mammalian safe is arranged, and the most suitable pollution-free vegetable, Production of fruit are used.Multiple killing teichomycin is the insecticide of a kind of low toxicity, efficient, wide spectrum, insect had tag fast and stomach poison function, blade there is stronger osmosis, can kill subepidermal insect, the longevity of residure is longer, and some insects are had certain ovicidal action, without systemic action, can effectively preventing Lepidoptera, diptera and thrips insect, can prevent and treat well also that some takes food the pest species of blade in a large number in coleoptera and the orthoptera, relatively poor to the control efficiency of sucking pest and mite class.Safer to predatory natural enemy insect, unique because of insecticidal action mechanism, not yet find at present to have mutual drug-fast report with other insecticides, to plant safety without poisoning, insecticidal effect be subjected to rain affect less.The multiple killing teichomycin of selling in the market is 2.5% suspending agent and 48% suspending agent, and multiple killing teichomycin in use exists the use cost height, the risk that resistance increases gradually, the defective that the lasting period is general.
Ethyl pleocidin, English common name: Spinetoram, CA registration number: 187166-40-1,187166-15-0.Ethyl pleocidin produces from actinomycetes thorn saccharopolyspora strains (Saccharopolyspora Spinosa) fermentation, it is the derived product of pleocidin (Spinasad), the mixture that its former the effective elements of the medicine is ethyl pleocidin-J and ethyl pleocidin-L (ratio is 3:1), act on the nervous system of insect, diamond-back moth, beet armyworm, Liriomyza, thrips, prodenia litura, lima bean pod borer are had good control efficiency.The ethyl pleocidin of selling in the market is 60 grams per liter suspending agents, ethyl pleocidin in use exists the use cost height, the risk that resistance increases, the defective that lasting period is general, and rationally use with from the insecticide of the different mechanisms of action, for fully effectively promoting ethyl pleocidin, prolong its service life and have important function.
At present, the pesticidal preparations take the thiophene insect amide as effective ingredient is take 20% thiophene insect amide suspending agent as main, and in actual use, lasting effect is long, but quick-acting is general, and use cost is high; The biogenic substances good disinsection effect, quick-acting is fast, but the lasting period is general, use year by year, resistance development is very fast, and the inventor is unexpected to be found the use that is mixed of thiophene insect amide and biogenic substances, have significant synergistic effect, can reduce use cost, slow down the effect of the generation of pest resistance.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, significantly synergy, good disinsection effect, drug cost is low, the thiophene insect amide that is difficult for developing immunity to drugs and the Pesticidal combination of biogenic substances insecticide.
Another object of the present invention is to provide the Pesticidal combination preparation formulation that contains thiophene insect amide and biogenic substances insecticide.
A further object of the present invention is to provide the application of the Pesticidal combination of thiophene insect amide and biogenic substances insecticide.
In order to overcome the defective of existing unitary agent, technical scheme of the present invention is to solve like this:
Contain the Pesticidal combination of thiophene insect amide and biogenic substances insecticide, comprising:
A) the first active component thiophene insect amide;
B) the second active component biogenic substances insecticide is selected from a kind of in Avermectin, emamectin-benzoate, multiple killing teichomycin or the ethyl pleocidin;
The weight ratio of the first active component and the second active component is (1:40)～(40:1), is preferably (1:20)～(20:1), most preferably is (1:10)～(10:1).
The cumulant of the first active component and the second active component (content sum) is 1%～80% of described composition total weight, be preferably 5%～50%, the size of active component cumulant is also closely related with formulation, is no more than 50% as the active component cumulant of suspending agent.
But the preparation formulation that the Pesticidal combination of thiophene insect amide of the present invention and biogenic substances insecticide can be prepared according to the known method of those skilled in the art of the present technique is water dispersible granules, wetting powder, suspending agent dispersed oil suspending agent, microcapsule suspending agent, missible oil or microemulsion.
For water dispersible granules, those skilled in the art are familiar with the corresponding auxiliary agent of use and finish the present invention very much.Dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate; Wetting agent is selected from alkyl sulfate, alkylsulfonate, naphthalene sulfonate; Disintegrant is selected from ammonium sulfate, urea, sucrose, glucose; Binding agent is selected from diatomite, corn starch, PVA, PEG, carboxymethyl (ethyl) cellulose family; Filler is selected from diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite, potter's clay.
To wetting powder, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate; Wetting agent is selected from alkyl sulfate, alkylsulfonate, naphthalene sulfonate; Filler is selected from ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white carbon, precipitated calcium carbonate, talcum powder, attapulgite, potter's clay.
To suspending agent, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, TERSPERSE 2425(U.S. Huntsman Corporation product, alkyl naphthalene sulfonic acid salt); The sorbitan monostearate APEO), agricultural newborn 1601#(common name sorbitan monostearate), Tween-60 #(common name alkyl phenol formaldehyde resin polyoxyethylene ether), agricultural newborn 2201#, this dish-60#(common name emulsifier is selected from Nongru-700 #(common name:::: phenethyl phenol polyoxyethylene poly-oxygen propylene aether), TERSPERSE 4894(U.S. Huntsman Corporation produces); Wetting agent is selected from alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500; Thickener is selected from xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate; Preservative is selected from formaldehyde, benzoic acid, Sodium Benzoate; Defoamer is selected from silicone based defoamer; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts such as sodium chloride.
But to the dispersed oil suspending agent, spendable auxiliary agent has: dispersant is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate (dispersing agent NNO), TERSPERSE 2425; Emulsifier is selected from the BY(castor oil polyoxyethylene ether) serial emulsifier (BY-110, BY-125, BY-140) Nongru-700 #, agricultural newborn 2201#, this dish-60#, Tween-60 #, agricultural newborn 1601#, TERSPERSE 4894; Wetting agent is selected from alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500; Thickener is selected from white carbon, polyvinyl alcohol, bentonite, aluminium-magnesium silicate; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea, inorganic salts such as sodium chloride; Stabilizing agent is selected from epoxidized soybean oil, epoxychloropropane, triphenyl phosphate; Dispersion medium is selected from soybean oil, rapeseed oil, corn oil, methyl oleate, diesel oil, machine oil, mineral oil.
Octyl phenol polyoxy ethene (10) ether), agricultural newborn 1601#, agricultural newborn 600#, agricultural newborn 400# the sorbitan monostearate APEO), the TX-10(common name for missible oil, spendable auxiliary agent has: emulsifier is selected from calcium dodecyl benzene sulfonate (agricultural newborn 500#), Nongru-700 #, agricultural newborn 2201#, this dish-60#, emulsifier T-60(common name::; Solvent is selected from dimethylbenzene, solvent naphtha (S-150, S-180, S-200), toluene, biodiesel, methylated vegetable oil; Cosolvent is selected from ethyl acetate, methyl alcohol, dimethyl formamide, 1-METHYLPYRROLIDONE, dimethyl sulfoxide (DMSO), cyclohexanone, acetone; Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane, aceticanhydride.
To microemulsion, spendable auxiliary agent has: emulsifier is selected from calcium dodecyl benzene sulfonate (agricultural newborn 500#), Nongru-700 #, agricultural newborn 2201#, this dish-60#, Tween-60 #, TX-10, agricultural newborn 1601#, agricultural newborn 600#, agricultural newborn 400#; Assistant for emulsifying agent is selected from methyl alcohol, isopropyl alcohol, n-butanol, ethanol; Solvent is selected from cyclohexanone, 1-METHYLPYRROLIDONE, dimethylbenzene, toluene, solvent naphtha (trade mark: S-150, S-180, S-200); Stabilizing agent is selected from triphenyl phosphite, epoxychloropropane.
For microcapsule suspending agent, spendable auxiliary agent and filler have solvent, emulsifier, encystation monomer, wetting dispersing agent, antifreezing agent, thickener and water.Solvent is selected from toluene, dimethylbenzene, dimethyl formamide, cyclohexanone, acetone, dimethyl sulfoxide (DMSO), 1-METHYLPYRROLIDONE; Emulsifier is selected from Nongru-700 #, agricultural newborn 2201#, this dish-60#, Tween-60 #, TX-10, agricultural newborn 1601#; Described encystation monomer is selected from PPG (specification is 6305(GB12008.2-89)), polyalcohol modified MDI(product specification is PMM-20, the NCO(isocyanuric acid that dissociates) content is 27.0-28.0%, Suan Fen＜=0.1%, viscosity 150
+50mPas/25 ℃); Wetting dispersing agent is selected from alkyl phenol formaldehyde resin polyoxyethylene ether sodium sulphate (SOPA), alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate; Antifreezing agent is selected from ethylene glycol, propane diols, glycerine; Thickener is selected from xanthans, polyvinyl alcohol, bentonite; Preservative is selected from formaldehyde, benzoic acid, Sodium Benzoate.Described water is deionized water.Preparation process be with the first active component and the second active component with dissolution with solvents after, add encystation monomer and emulsifier and mix as oil phase, take deionized water as water.Oil phase is added aqueous phase, at the high-speed shearing machine down cut, make the particle diameter to 1 of emulsion ~ 3 microns, then by control temperature and mixing speed, micro-capsule is solidified, the system particle diameter for the treatment of suits the requirements stops the encystation reaction when big or small, then dispersant, thickener, preservative, antifreezing agent is added, and stirs.
Component of the present invention is reasonable, good disinsection effect, and drug cost is low, and its active and insecticidal effect is not the simple superposition of each composition activity, but significant synergistic effect is arranged, and can slow down the generation of resistance, and is good to crop safety, meets the security requirement of pesticidal preparations.The present invention has preferably control efficiency to insects such as the snout moth's larva of rice, vegetables diamond-back moth, beet armyworm, cotton cotton bollworm, apple olethreutids.
Embodiment
In order to prevent and treat rice leaf roller, diamond-back moth and the beet armyworm in the agricultural production, the inventor has carried out composite synergy research with compositions such as thiophene insect amide and Avermectin, emamectin-benzoate, multiple killing teichomycin or ethyl pleocidins.It is tested object that rice leaf roller, diamond-back moth and beet armyworm are adopted respectively in test, and concrete grammar is:
1) test method is with reference to " the agricultural industry criteria NY/T of the People's Republic of China (PRC) ".At first single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients, thiophene insect amide, multiple killing teichomycin, ethyl pleocidin are 1 ug/g, 2 ug/g, 4 ug/g, 8 ug/g, 16 ug/g, Avermectin, emamectin-benzoate are 0.5 ug/g, 1 ug/g, 2 ug/g, 4 ug/g, 8 ug/g, and the mixture concentration gradient is 0.5 ug/g, 1 ug/g, 2 ug/g, 4 ug/g, 8 ug/g; The examination worm is the rice leaf roller of picking up from the field, diamond-back moth, beet armyworm worm pupa, use rice seedlings in the greenhouse, the Chinese cabbage leaf raised for 3 generations, select uniformity four age nymph, be pressed into and put paddy rice, the culture dish of Chinese cabbage seedling (processing with the cotton ball moisturizing) diameter 12cm, every ware connects and anaesthetizes 30 of nymphs, every processing connects 4 culture dishes, spray under 50PSI pressure with the potter spray tower, ware of each spray, every ware spraying liquid 3ml after insect revives, puts into the 12H/12H illumination box with the culture dish of processing and cultivates, check dead borer population in 72 hours, calculate lethality.Blank spray equivalent clear water.Carry out statistical analysis with DPS data processor software, calculate the LC of each medicament
50Value is estimated reagent agent to the activity of examination worm with this.
The co-toxicity coefficient of mixture (CTC value) calculates by following formula:
ATI---mixture actual measurement toxicity index;
S---standard insecticide LC
50, unit is every liter (mg/L) of milligram;
The LC of M---mixture
50, unit is every liter (mg/L) of milligram;
TTI=TI
A×P
A+?TI
B×P
B
In the formula:
The theoretical toxicity index of TTI---mixture;
TI
A---A medicament toxicity index;
P
A---the percentage composition of A medicament in mixture, unit are percentage (%);
TI
B---B medicament toxicity index;
P
B---the percentage composition of B medicament in mixture, unit are percentage (%);
CTC---co-toxicity coefficient;
ATI---mixture actual measurement toxicity index;
The theoretical toxicity index of TTI---mixture;
2) three kinds of tested object measurement results see Table respectively 1-3.
As can be seen from Table 1, thiophene insect amide and Avermectin, emamectin-benzoate, multiple killing teichomycin or ethyl pleocidin are composite, proportioning is between (40:1)～(1:40) time, rice leaf roller is had very high synergistic effect, and each Mixed Pharmacy co-toxicity coefficient substantially all reaches more than 200.
As can be seen from Table 2, thiophene insect amide and Avermectin, emamectin-benzoate, multiple killing teichomycin, ethyl pleocidin are composite, proportioning has very high synergistic effect to diamond-back moth between (40:1)～(1:40) time, and each Mixed Pharmacy co-toxicity coefficient substantially all reaches more than 200.
As can be seen from Table 3, thiophene insect amide and Avermectin, emamectin-benzoate, multiple killing teichomycin, ethyl pleocidin are composite, proportioning has very high synergistic effect to beet armyworm between (40:1)～(1:40) time, and each Mixed Pharmacy co-toxicity coefficient substantially all reaches more than 200.
The invention will be further described below in conjunction with embodiment.
Example of formulations 1
Take by weighing 10% thiophene insect amide, 2% Avermectin, 3%TERSPERSE 4894,1%TERSPERSE 2500,2% dispersing agent NNO, 0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent (trade name: s-29 Nanjing "four news" (new ideas applied chemistry product company produces), deionized water adds to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with the thiophene insect amide Avermectin suspending agent that makes 12% behind the sand mill sand milling.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 12%, form new embodiment.
This prescription is used for the control rice-stem borer, and the mu consumption is 20g, and water 50kg dilutes spraying, and 7 days preventive effect is 92.4% behind the medicine, and 14 days preventive effect is 94.5% behind the medicine.4% abamectin emulsifiable concentrate is pressed a mu consumption 15g by mu consumption 50g and 20% thiophene insect amide suspending agent, the use that uses the same method, and 7 days preventive effect is respectively 82.62% and 78.81% behind the medicine, and 14 days preventive effect is respectively 78.53% and 82.85% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the abamectin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 2
Take by weighing 20% thiophene insect amide, 2% emamectin-benzoate, 4%TERSPERSE 4894,1.5%TERSPERSE 2500,1%TERSPERSE 2425,0.2% aluminium-magnesium silicate, 5% ethylene glycol, 0.5% formaldehyde, 0.5% silicone defoaming agent s-29, deionized water and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 22% thiophene insect amide emamectin benzoate suspending agent behind the sand mill sand milling.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 22%, form new embodiment.
This prescription is used for control paddy rice rice leaf roller, and the mu consumption is 10g, and water 50kg dilutes spraying, and 7 days preventive effect is 90.2% behind the medicine, and 14 days preventive effect is 92.6% behind the medicine.8% emamectin-benzoate missible oil is pressed a mu consumption 15g by mu consumption 30g and 20% thiophene insect amide suspending agent, the use that uses the same method, and 7 days preventive effect is respectively 83.4% and 81.2% behind the medicine, and 14 days preventive effect is respectively 78.4% and 84.6% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the emamectin-benzoate compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 3
Take by weighing 20% thiophene insect amide, 10% multiple killing teichomycin, 3%TERSPERSE 4894,1.5%TERSPERSE 2500,1%TERSPERSE 2425,0.2% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent s-29, deionized water and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with making 30% thiophene insect amide multiple killing teichomycin suspending agent behind the sand mill sand milling.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 30%, form new embodiment.
This prescription is used for control paddy rice rice leaf roller, and the mu consumption is 8g, and water 50kg dilutes spraying, and 7 days preventive effect is 94.3% behind the medicine, and 14 days preventive effect is 95.6% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 80g by mu consumption 15g and 2.5% multiple killing teichomycin suspending agent, the use that uses the same method, and 7 days preventive effect is respectively 83.6% and 82.4% behind the medicine, and 14 days preventive effect is respectively 85.7 % and 78.2% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the multiple killing teichomycin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 4
Take by weighing 15% thiophene insect amide, 5% ethyl pleocidin, 1% dispersing agent NNO, 3% Nongru-700 #, 2% agricultural newborn 1601#, 2%TERSPERSE 2500,0.3% xanthans, 5% propane diols, 0.5% benzoic acid, 0.5% silicone defoaming agent s-29, deionized water and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, with the thiophene insect amide ethyl pleocidin suspending agent that makes 20% behind the sand mill sand milling.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 20%, form new embodiment.
This prescription is used for control paddy rice rice leaf roller, and the mu consumption is 10g, and water 50kg dilutes spraying, and 7 days preventive effect is 90.1% behind the medicine, and 14 days preventive effect is 93.7% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 30g by mu consumption 15g and 6% ethyl pleocidin suspending agent, the use that uses the same method, and 7 days preventive effect is respectively 83.6% and 81.4% behind the medicine, and 14 days preventive effect is respectively 76.2 % and 77.8% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the ethyl pleocidin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 5
Take by weighing 20% thiophene insect amide, 1% Avermectin, 5% calcium lignosulfonate, 3% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1% lauryl sodium sulfate, 3% white carbon, kaolin and fill up the weight portion to 100%.Above-mentioned raw materials is prepared into 21% thiophene insect amide Avermectin wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 21%, form new embodiment.
This prescription is used for preventing and treating sweet basket diamond-back moth, and the mu consumption is 15g, and water 50kg dilutes spraying, and 3 days preventive effect is 89.5% behind the medicine, and 7 days preventive effect is 86.6% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 40g by mu consumption 20g and 2% abamectin emulsifiable concentrate, the use that uses the same method, and 3 days preventive effect is respectively 84.7% and 76.6% behind the medicine, and 7 days preventive effect is respectively 83.6% and 70.5% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the abamectin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 6
Take by weighing 40% thiophene insect amide, 1% emamectin-benzoate, 4% calcium lignosulfonate, 5% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1.5% lauryl sodium sulfate, 3% white carbon, fine particle calcium carbonate and fill up the weight portion to 100%.Above-mentioned raw materials is prepared into 41% thiophene insect amide emamectin-benzoate wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 41%, form new embodiment.
This prescription is used for preventing and treating sweet basket diamond-back moth, and the mu consumption is 7g, and water 50kg dilutes spraying, and 3 days preventive effect is 86.2% behind the medicine, and 7 days preventive effect is 87.6% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 8g by mu consumption 20g and 5% emamectin-benzoate water dispersible granules, the use that uses the same method, and 3 days preventive effect is respectively 81.2% and 79.1% behind the medicine, and 7 days preventive effect is respectively 80.7 % and 73.5% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the emamectin-benzoate compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 7
Take by weighing 5% thiophene insect amide, 10% multiple killing teichomycin, 6% calcium lignosulfonate, 4% alkylnaphthalene sulfonate formaldehyde condensation products (dispersing agent NNO), 1.5% lauryl sodium sulfate, 3% white carbon, fine particle calcium carbonate and fill up the weight portion to 100%.Above-mentioned raw materials is prepared into 15% thiophene insect amide multiple killing teichomycin wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 15%, form new embodiment.
This prescription is used for preventing and treating sweet basket diamond-back moth, and the mu consumption is 12g, and water 50kg dilutes spraying, and 3 days preventive effect is 88.2% behind the medicine, and 7 days preventive effect is 87.6% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 40g by mu consumption 20g and 5% multiple killing teichomycin missible oil, the use that uses the same method, and 3 days preventive effect is respectively 80.2% and 82.1% behind the medicine, and 7 days preventive effect is respectively 82.5 % and 72.6% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the multiple killing teichomycin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 8
Claim 3% thiophene insect amide, 30% ethyl pleocidin, 4% calcium lignosulfonate, 4% TERSPERSE 2425,2% lauryl sodium sulfate, 5% white carbon, kaolin to fill up the weight portion to 100%.Above-mentioned raw materials is prepared into 33% thiophene insect amide ethyl pleocidin wetting powder through mixing, ultra micro air-flow crushing, hybrid technique step.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 33%, form new embodiment.
This prescription is used for preventing and treating sweet basket diamond-back moth, and the mu consumption is 10g, and water 50kg dilutes spraying, and 3 days preventive effect is 90.2% behind the medicine, and 7 days preventive effect is 85.8% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 50g by mu consumption 20g and 6% ethyl pleocidin suspending agent, the use that uses the same method, and 3 days preventive effect is respectively 82.7% and 84.2% behind the medicine, and 7 days preventive effect is 81.2% and 80.3% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the ethyl pleocidin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 9
Take by weighing 2% thiophene insect amide, 80% Avermectin, 3% TERSPERSE 2700(polycarboxylate, U.S. Huntsman Corporation produces), 2% Nekal BX (nekal), 1%K-12(lauryl sodium sulfate), 3% corn starch, 5% ammonium sulfate, kaolin add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is namely mixed, ultra micro air-flow crushing, mixing, granulation step are produced 82% thiophene insect amide Avermectin water dispersible granules.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 82%, form new embodiment.
This prescription is used for control cauliflower beet armyworm, and the mu consumption is 3g, and water 50kg dilutes spraying, and 3 days preventive effect is 89.6% behind the medicine, and 7 days preventive effect is 87.7% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 100g by mu consumption 15g and 2.5% abamectin emulsifiable concentrate, the use that uses the same method, and 3 days preventive effect is respectively 81.8% and 83.2% behind the medicine, and 7 days preventive effect is respectively 82.5% and 75.4% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the abamectin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 10
Take by weighing 25% thiophene insect amide, 5% emamectin-benzoate, 5% TERSPERSE 2700,2% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX, 1%K-12,10% glucose, 10% ammonium sulfate, 1% carboxymethyl cellulose, diatomite and add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is namely mixed, ultra micro air-flow crushing, mixing, granulation step are produced 30% thiophene insect amide emamectin-benzoate water dispersible granules.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 30%, form new embodiment.
This prescription is used for control cauliflower beet armyworm, and the mu consumption is 5g, and water 50kg dilutes spraying, and 3 days preventive effect is 90.5% behind the medicine, and 7 days preventive effect is 89.5% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 40g by mu consumption 15g and 1% emamectin-benzoate missible oil, use uses the same method, 3 days preventive effect is respectively 82.6% and 84.8% behind the medicine, 7 days preventive effect is respectively 83.5 % and 79.7% behind the medicine, synergistic effect is obvious after thiophene insect amide and the emamectin-benzoate compounded combination, preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 11
Take by weighing 2% thiophene insect amide, 40% multiple killing teichomycin, 3% TERSPERSE 2700(polycarboxylate, U.S. Huntsman Corporation produces), 3% sodium lignin sulfonate, 1% Nekal BX, 1%K-12,1%PVA(molecular weight 2000), 10% ammonium sulfate, kaolin adds to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is namely mixed, ultra micro air-flow crushing, mixing, granulation step are produced 42% thiophene insect amide multiple killing teichomycin water dispersible granules.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 42%, form new embodiment.
This prescription is used for control cauliflower beet armyworm, and the mu consumption is 5g, and water 50kg dilutes spraying, and 3 days preventive effect is 89.5% behind the medicine, and 7 days preventive effect is 87.3% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 40g by mu consumption 15g and 5% multiple killing teichomycin missible oil, use uses the same method, 3 days preventive effect is respectively 81.5% and 83.7% behind the medicine, 7 days preventive effect is respectively 82.6 % and 76.8% behind the medicine, synergistic effect is obvious after thiophene insect amide and the multiple killing teichomycin compounded combination, preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 12
Take by weighing 30% thiophene insect amide, 20% ethyl pleocidin, 4% TERSPERSE 2700,2% dispersing agent NNO (alkylnaphthalene sulfonate formaldehyde condensation products), 2% Nekal BX, 2%K-12,10% diatomite, 8% urea, kaolin and add to 100% weight portion.The method of the frequent regulation of above-mentioned raw materials water intaking dispersible granule is namely mixed, ultra micro air-flow crushing, mixing, granulation step are produced 50% thiophene insect amide ethyl pleocidin water dispersible granules.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 50%, form new embodiment.
This prescription is used for control cauliflower beet armyworm, and the mu consumption is 5g, and water 50kg dilutes spraying, and 3 days preventive effect is 92.5% behind the medicine, and 7 days preventive effect is 90.3% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 30g by mu consumption 15g and 6% ethyl pleocidin suspending agent, use uses the same method, 3 days preventive effect is respectively 81.7% and 84.6% behind the medicine, 7 days preventive effect is respectively 82.5 % and 81.8% behind the medicine, synergistic effect is obvious after thiophene insect amide and the ethyl pleocidin compounded combination, preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 13
Take by weighing 5% thiophene insect amide, 2% Avermectin, 4% agricultural newborn 500#, 2% agricultural newborn 600#, 3% agricultural newborn 2201#, 3% triphenyl phosphite, 10% dimethyl formamide, solvent naphtha S-180 add to 100% weight portion.Above-mentioned raw materials makes 7% thiophene insect amide abamectin emulsifiable concentrate after mix, stirring and dissolving is complete.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 7%, form new embodiment.
This prescription is used for control cotton cotton bollworm, and the mu consumption is 50g, and water 50kg dilutes spraying, and 3 days preventive effect is 86.2% behind the medicine, and 14 days preventive effect is 84.7% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 100g by mu consumption 20g and 2% abamectin emulsifiable concentrate, the use that uses the same method, and 3 days preventive effect is respectively 81.3% and 77.5% behind the medicine, and 14 days preventive effect is respectively 83.8 % and 68.2% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the abamectin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 14
Take by weighing 8% thiophene insect amide, 2% emamectin-benzoate, 5% agricultural newborn 500#, 2% agricultural newborn 400#, 3% Nongru-700 #, 1% epoxychloropropane, 15% ethyl acetate, dimethylbenzene add to 100% weight portion.Above-mentioned raw materials makes 20% thiophene insect amide emamectin-benzoate missible oil after mix, stirring and dissolving is complete.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 10%, form new embodiment.
This prescription is used for control cotton cotton bollworm, and the mu consumption is 30g, and water 50kg dilutes spraying, and 3 days preventive effect is 89.8% behind the medicine, and 10 days preventive effect is 86.3% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 60g by mu consumption 20g and 3% emamectin-benzoate missible oil, the use that uses the same method, and 3 days preventive effect is respectively 81.3% and 76.2% behind the medicine, and 10 days preventive effect is respectively 80.5% and 67.6% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the emamectin-benzoate compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 15
Take by weighing 6% thiophene insect amide, 4% multiple killing teichomycin, 5% agricultural newborn 500#, 3% agricultural newborn 400#, 3% agricultural newborn 600#, 1% epoxychloropropane, 15% cyclohexanone, dimethylbenzene add to 100% weight portion.Above-mentioned raw materials makes 10% thiophene insect amide multiple killing teichomycin missible oil after mix, stirring and dissolving is complete.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 10%, form new embodiment.
This prescription is used for control cotton cotton bollworm, and the mu consumption is 35g, and water 50kg dilutes spraying, and 3 days preventive effect is 87.6% behind the medicine, and 10 days preventive effect is 85.5% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 60g by mu consumption 20g and 5% multiple killing teichomycin missible oil, the use that uses the same method, and 3 days preventive effect is respectively 82.1% and 76.2% behind the medicine, and 10 days preventive effect is respectively 81.3% and 67.8% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the multiple killing teichomycin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 16
Take by weighing 4% thiophene insect amide, 8% ethyl pleocidin, 5% agricultural newborn 500#, 3% TX-10,4% agricultural newborn 1601#, 1% epoxychloropropane, 10% acetone, dimethylbenzene add to 100% weight portion.Above-mentioned raw materials makes 12% thiophene insect amide ethyl pleocidin missible oil after mix, stirring and dissolving is complete.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 12%, form new embodiment.
This prescription is used for control cotton cotton bollworm, and the mu consumption is 20g, and water 50kg dilutes spraying, and 3 days preventive effect is 88.7% behind the medicine, and 7 days preventive effect is 87.7% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 50g by mu consumption 20g and 5% ethyl pleocidin missible oil, the use that uses the same method, and 3 days preventive effect is respectively 82.5% and 83.6% behind the medicine, and 7 days preventive effect is respectively 81.5% and 78.9% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the ethyl pleocidin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 17
Take by weighing 4% thiophene insect amide, 1% Avermectin, 4%TX-10,5% Nongru-700 #, 6% agricultural newborn 500#, 4% agricultural newborn 1601#, 15% cyclohexanone, 5%N-methyl pyrrolidone, 5% n-butanol, 1% epoxychloropropane, through dissolve complete and mix, deionized water adds to 100% weight portion, makes 5% thiophene insect amide avermectin micro-emulsion after the stirring.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 5%, form new embodiment.
This prescription is used for control paddy rice rice leaf roller, and the mu consumption is 50g, and water 50kg dilutes spraying, and 3 days preventive effect is 90.2% behind the medicine, and 14 days preventive effect is 92.6% behind the medicine.1% abamectin emulsifiable concentrate is pressed a mu consumption 15g by mu consumption 100g and 20% thiophene insect amide suspending agent, the use that uses the same method, and 3 days preventive effect is respectively 83.4% and 81.2% behind the medicine, and 14 days preventive effect is respectively 79.4% and 83.6% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the abamectin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 18
Take by weighing 5% thiophene insect amide, 1% emamectin-benzoate, 4% Nongru-700 #, 3% agricultural newborn 500#, 6% agricultural newborn 600#, 5% dimethylbenzene, 15% cyclohexanone, 5% methyl alcohol, 1% epoxychloropropane is through dissolve complete and mix, deionized water adds to 100% weight portion, makes 6% thiophene insect amide emamectin benzoate microemulsion after the stirring.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 6%, form new embodiment.
This prescription is used for preventing and treating sweet basket diamond-back moth, and the mu consumption is 20g, and water 50kg dilutes spraying, and 3 days preventive effect is 89.5% behind the medicine, and 7 days preventive effect is 86.6% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 20g by mu consumption 20g and 2% emamectin-benzoate missible oil, the use that uses the same method, and 3 days preventive effect is respectively 83.7% and 77.6% behind the medicine, and 7 days preventive effect is respectively 80.6% and 71.3% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the emamectin-benzoate compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 19
Take by weighing 10% thiophene insect amide, 5% multiple killing teichomycin, 5% Nongru-700 #, 3% agricultural newborn 500#, 6% agricultural newborn 600#, 5% 1-METHYLPYRROLIDONE, 20% cyclohexanone, 5% ethanol, 1% epoxychloropropane, through dissolve complete and mix, deionized water adds to 100% weight portion, makes 15% thiophene insect amide multiple killing teichomycin microemulsion after the stirring.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 15%, form new embodiment.
This prescription is used for control cauliflower beet armyworm, and the mu consumption is 20g, and water 50kg dilutes spraying, and 3 days preventive effect is 91.5% behind the medicine, and 7 days preventive effect is 88.3% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 40g by mu consumption 15g and 5% multiple killing teichomycin missible oil, use uses the same method, 3 days preventive effect is respectively 82.3% and 84.4% behind the medicine, 7 days preventive effect is respectively 83.6 % and 79.8% behind the medicine, synergistic effect is obvious after thiophene insect amide and the multiple killing teichomycin compounded combination, preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 20
Take by weighing 6% thiophene insect amide, 4% ethyl pleocidin, 5% Nongru-700 #, 3% agricultural newborn 500#, 6% agricultural newborn 600#, 5% dimethylbenzene, 20% cyclohexanone, 5% ethanol, through dissolve complete and mix, deionized water adds to 100% weight portion, makes 10% thiophene insect amide ethyl pleocidin microemulsion after the stirring.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 10%, form new embodiment.
This prescription is used for control apple olethreutid, dilutes 2500 times of sprayings, and 3 days preventive effect is 91.7% behind the medicine, and 14 days preventive effect is 88.5% behind the medicine.20% thiophene insect amide suspending agent by diluting 1500 times, is got the use that uses the same method of same amount by dilution 4000 times and 6% ethyl pleocidin missible oil, and 3 days preventive effect is respectively 83.7% and 81.8% behind the medicine, and 14 days preventive effect is respectively 81.6% and 74.6% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the ethyl pleocidin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 21
Take by weighing 15% thiophene insect amide, 2% Avermectin, 2%TERSPERSE 2425,4% this dish-60#, 3% Tween-60 #, 4% agricultural newborn 2201#, 3% Nongru-700 #, 1%TERSPERSE 2500,0.5% white carbon, 5% propane diols, 1% epoxychloropropane, methyl oleate and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 17% thiophene insect amide Avermectin dispersed oil suspending agent behind the sand mill sand milling.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 17%, form new embodiment.
This prescription is used for preventing and treating sweet basket diamond-back moth, and the mu consumption is 15g, and water 50kg dilutes spraying, and 3 days preventive effect is 88.5% behind the medicine, and 7 days preventive effect is 87.4% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 30g by mu consumption 20g and 2% abamectin emulsifiable concentrate, the use that uses the same method, and 3 days preventive effect is respectively 83.7% and 75.6% behind the medicine, and 7 days preventive effect is respectively 82.6% and 69.5% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the abamectin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 22
Take by weighing 20% thiophene insect amide, 2% emamectin-benzoate, 2% dispersing agent NNO, 3% agricultural newborn 2201#, 10% BY-110,1%TERSPERSE 2500,1% aluminium-magnesium silicate, 3% glycerine, 15% epoxidized soybean oil, soybean oil and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 22% thiophene insect amide emamectin-benzoate dispersed oil suspending agent behind the sand mill sand milling.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 22%, form new embodiment.
This prescription is used for control paddy rice rice leaf roller, and the mu consumption is 8g, and water 50kg dilutes spraying, and 3 days preventive effect is 91.2% behind the medicine, and 14 days preventive effect is 90.6% behind the medicine.1% emamectin-benzoate missible oil is pressed a mu consumption 15g by mu consumption 30g and 20% thiophene insect amide suspending agent, the use that uses the same method, and 3 days preventive effect is respectively 83.4% and 81.2% behind the medicine, and 14 days preventive effect is respectively 76.4% and 84.6% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the emamectin-benzoate compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 23
Take by weighing 10% thiophene insect amide, 8% multiple killing teichomycin, 1.5%TERSPERSE 2425,3% this dish-60#, 3% Tween-60 #, 8% BY-110,1%TERSPERSE 2500,0.5% white carbon, 5% propane diols, 20% epoxidized soybean oil, methyl oleate and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 18% thiophene insect amide multiple killing teichomycin dispersed oil suspending agent behind the sand mill sand milling.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 18%, form new embodiment.
This prescription is used for control paddy rice rice leaf roller, and the mu consumption is 15g, and water 50kg dilutes spraying, and 3 days preventive effect is 92.1% behind the medicine, and 14 days preventive effect is 91.7% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 40g by mu consumption 15g and 5% multiple killing teichomycin missible oil, the use that uses the same method, and 3 days preventive effect is respectively 82.6% and 84.4% behind the medicine, and 14 days preventive effect is respectively 84.2 % and 75.8% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the multiple killing teichomycin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 24
Take by weighing 10% thiophene insect amide, 4% ethyl pleocidin, 1% dispersing agent NNO, 5% BY-125,3% this dish-60#, 3% Tween-60 #, 4% agricultural newborn 1601#, 1% phenethyl phenol polyethenoxy base ether phosphate, 0.5% bentonite, 5% glycerine, 3% triphenyl phosphate, rapeseed oil and add to 100% weight portion.Above-mentioned raw materials is through mixing, and high speed shear is disperseed 30min, but with making 14% thiophene insect amide ethyl pleocidin dispersed oil suspending agent behind the sand mill sand milling.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 14%, form new embodiment.
This prescription is used for control cauliflower beet armyworm, and the mu consumption is 20g, and water 50kg dilutes spraying, and 3 days preventive effect is 92.5% behind the medicine, and 7 days preventive effect is 89.3% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 40g by mu consumption 15g and 5% ethyl pleocidin missible oil, use uses the same method, 3 days preventive effect is respectively 82.3% and 84.4% behind the medicine, 7 days preventive effect is respectively 83.6 % and 80.8% behind the medicine, synergistic effect is obvious after thiophene insect amide and the ethyl pleocidin compounded combination, preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 25
Take by weighing 7% thiophene insect amide, 3% Avermectin, solvent toluene 10%, cyclohexanone 8%, encystation monomer PMM-20 3%, emulsifier TX-10 4%, emulsifier 2,201 2%, dispersant alkylphenol-polyethenoxy base ether phosphate 4%, the yellow first glue 0.3% of thickener, antifreeze glycol 4%, 0.5% benzoic acid, deionized water supply 100%.With two kinds of active components of thiophene insect amide and Avermectin with solvent toluene, cyclohexanone heating for dissolving after, add encystation monomer and emulsifier and mix as oil phase, take excess water as water.Under 8000 rev/mins of speed of high-speed shearing machine, oil phase is joined the aqueous phase shearing obtained emulsion in 10-15 minute, the sampling and measuring emulsion particle diameter, average grain diameter gets final product at 3 microns.Then emulsion is transferred in the reactor with thermometer and agitator, heating-up temperature to 45 ℃, 500 rev/mins of mixing speeds make the encystation monomer that interface polymerization reaction slowly occur on the emulsion particulate, form gradually microcellular structure capsule skin on microparticle surfaces.After 3-3.5 hour, the sampling and measuring particle diameter is measured average grain diameter about 5 microns until the system reaction, and the encystation stage of reaction finishes.Then temperature is warmed up to 65 ℃, the system reaction changes capsule skin cure stage over to by the encystation stage of reaction, and the cure stage time is 1-1.5 hour.After capsule skin cure stage finished, system temperature returned to room temperature, then wetting dispersing agent, thickener, antifreezing agent, preservative was added, and stirred under 800 rev/mins speed and namely obtained 10% thiophene insect amide avermectin microcapsule suspending agent in 30 minutes.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 10%, form new embodiment.
This prescription is used for the control rice-stem borer, and the mu consumption is 20g, and water 50kg dilutes spraying, and 7 days preventive effect is 89.7% behind the medicine, and 14 days preventive effect is 88.7% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 50g by mu consumption 20g and 5% abamectin emulsifiable concentrate, the use that uses the same method, and 7 days preventive effect is respectively 83.5% and 82.6% behind the medicine, and 14 days preventive effect is respectively 82.5% and 75.9% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the abamectin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
Example of formulations 26
Take by weighing 5% thiophene insect amide, 5% multiple killing teichomycin, solvent xylene 10%, 5% cyclohexanone, encystation monomer PPG 6,305 4%, emulsifier Nongru-700 # 3%, emulsifier 2,201 2%, dispersant phenethyl phenol polyethenoxy base ether phosphate 4%, alkyl phenol formaldehyde resin polyoxyethylene ether sodium sulphate (SOPA) 2%, the yellow first glue 0.3% of thickener, antifreezing agent propane diols 4%, 0.5% Sodium Benzoate, deionized water supply 100%.The preparation method of preparation and embodiment 25 are similar.
The part by weight of thiophene insect amide and biogenic substances insecticide can change between 1:40～40:1 in the present embodiment, and both total weight items still are 10%, form new embodiment.
This prescription is used for control cotton cotton bollworm, and the mu consumption is 30g, and water 50kg dilutes spraying, and 3 days preventive effect is 86.2% behind the medicine, and 14 days preventive effect is 84.7% behind the medicine.20% thiophene insect amide suspending agent is pressed a mu consumption 100g by mu consumption 20g and 2.5% multiple killing teichomycin suspending agent, the use that uses the same method, and 3 days preventive effect is respectively 80.3% and 77.5% behind the medicine, and 14 days preventive effect is respectively 79.8 % and 70.2% behind the medicine.Synergistic effect is obvious after thiophene insect amide and the abamectin compounded combination, and preventive effect obviously is better than single dose, and effective ingredient consumption obviously reduces, to crop safety.
From above-mentioned a large amount of embodiment as seen, the thiophene insect amide be selected from Avermectin, emamectin-benzoate, biogenic substances insecticide composition one of in multiple killing teichomycin or the ethyl pleocidin is composite, can be made into water dispersible granules, wetting powder, suspending agent, but dispersed oil suspending agent, microcapsule suspending agent, missible oil or micro-emulsion form, to the snout moth's larva of rice, the vegetables diamond-back moth, beet armyworm, the cotton cotton bollworm, the apple olethreutid has significant control efficiency, dosage is few, the control efficiency advantages of higher, drug cost and dosage have been saved, and good to crop safety, therefore have wide practical use in the production.
Composition of the present invention is to adopt two kinds of active component compound schemes, its activity and insecticidal effect are not the simple superposition of each composition activity, compare with existing unitary agent, except having significant insecticidal effect, and significant synergistic effect is arranged, slow down the generation of resistance, the preparation less residue, pollution-free to crop, safety is good, meets the security requirement of pesticidal preparations.
Claims (7)
1. a Pesticidal combination that contains thiophene insect amide and biogenic substances insecticide is characterized in that active component is comprised of thiophene insect amide and ethyl pleocidin, and the weight ratio of thiophene insect amide and ethyl pleocidin is 1:40～40:1.
2. the described Pesticidal combination that contains thiophene insect amide and biogenic substances insecticide according to claim 1, it is characterized in that: the weight ratio of thiophene insect amide and ethyl pleocidin is 1:20～20:1.
3. the described Pesticidal combination that contains thiophene insect amide and biogenic substances insecticide according to claim 2, it is characterized in that: the weight ratio of thiophene insect amide and ethyl pleocidin is 1:10～10:1.
4. the described Pesticidal combination that contains thiophene insect amide and biogenic substances insecticide according to claim 1 is characterized in that the cumulant of thiophene insect amide and ethyl pleocidin is 1%～80% of described composition total weight.
5. the described Pesticidal combination that contains thiophene insect amide and biogenic substances insecticide according to claim 4 is characterized in that the cumulant of thiophene insect amide and ethyl pleocidin is 5%～50% of described composition total weight.
6. the described Pesticidal combination that contains thiophene insect amide and biogenic substances insecticide according to claim 1, but it is characterized in that described composition is water dispersible granules, wetting powder, suspending agent dispersed oil suspending agent, microcapsule suspending agent, missible oil or microemulsion.
7. the purposes of the described Pesticidal combination that contains thiophene insect amide and biogenic substances insecticide of claim 1 in the control snout moth's larva of rice, vegetables diamond-back moth, beet armyworm, cotton cotton bollworm, apple olethreutid insect.
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