CN101959535A - Aromatic agent composition for openable storage space - Google Patents
Aromatic agent composition for openable storage space Download PDFInfo
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- CN101959535A CN101959535A CN2009801066520A CN200980106652A CN101959535A CN 101959535 A CN101959535 A CN 101959535A CN 2009801066520 A CN2009801066520 A CN 2009801066520A CN 200980106652 A CN200980106652 A CN 200980106652A CN 101959535 A CN101959535 A CN 101959535A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
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Abstract
Disclosed is an aromatic agent composition for an openable storage space that can retain aroma having a homogeneous and constant intensity within a closed storage space and, even when the storage space is opened and closed, can fill the storage space with aroma having a homogeneous and constant intensity. The aromatic agent composition contains 15 to 90% by weight of a glycol ether having a boiling point of 120 to 185 DEG C under ordinary pressure as a solvent.
Description
Technical field
Perfume composition that the accommodation space that the present invention relates to open and close is used and manufacture method thereof.More specifically, relate to perfume composition and the manufacture method thereof that is arranged in the accommodation space that can open and close, in accommodation space, can keeps even fragrance with certain intensity.In addition, the present invention relates in the accommodation space that can open and close, make the fragrance emissions method of uniform fragrance emissions with certain intensity.The invention still further relates to and to adjust uniform method in the fragrance emissions in the accommodation space that can open and close with certain intensity.
Background technology
For the discomfort that the foul smell of eliminating the accommodation space and the interior space produces, build comfortable space, be extensive use of aromatic.
Generally speaking, the interior space is with respect to contained perfume bloom speed in the aromatic, and its spatial volume is big, so for the employed aromatic of the interior space, in order to improve the sporadic of spice, require spice is distributed constantly.
On the other hand, for accommodation spaces such as drawer and shoe chest, with respect to the speed of distributing of contained spice in the aromatic, its spatial volume is little, and only opens and closes when collecting article is come in and gone out, and is generally the environment of closing, and is different with the interior space in this.Therefore, in accommodation space, if improve the sporadic of spice, make spice continue to distribute, then the perfume bloom amount in the accommodation space just increases, and the fragrance that smells when opening accommodation space is just too strong.In addition, employed aromatic also uses for the collecting article in the accommodation space is composed fragrant purpose in accommodation space, so the perfume bloom amount increase meeting in the accommodation space is excessively composed perfume (or spice) to collecting article, thereby can not moderately compose perfume (or spice).And in the accommodation space of closing, the perfume bloom raising can cause the inhomogeneities that is produced aroma strength by the shut-in time length of accommodation space, also causes aromatic shortening service time.Therefore, for for the aromatic that uses in the accommodation space that can open and close, the such perfume bloom of employed aromatic and distribute persistence in the interior space, strong request can make fragrance in accommodation space with certain intensity and keep equably.
Nowadays, various types of aromatic obtain exploitation and commercialization, but present present situation is, even in the accommodation space of closing, can evenly and with certain intensity keeping fragrance to carry out the switching of accommodation space, also can make the aromatic of the fragrance that is full of even and certain intensity in the accommodation space, so far not exploitation still.
Patent documentation 1: TOHKEMY 2003-102822 communique
Summary of the invention
The perfume composition that the object of the present invention is to provide a kind of accommodation space that can open and close to use, this perfume composition can evenly and with certain intensity keep fragrance in the accommodation space of closing, even carry out the switching of accommodation space, in accommodation space, also can be full of the fragrance of even and certain intensity.In addition, the present invention also aims to provide a kind of fragrance emissions method that in the accommodation space that can open and close, makes uniform fragrance emissions with certain intensity.In addition, the present invention also aims to provide a kind of and will adjust uniform method with certain intensity in the fragrance emissions in the accommodation space that can open and close.
The present inventor furthers investigate in order to solve above-mentioned problem, found that, by use boiling point under the normal pressure with the cooperation ratio of 15～90 weight % is that 120～185 ℃ glycol ethers is as the solvent of perfume composition, can in the accommodation space of closing, evenly and with certain intensity keep fragrance, even open and close accommodation space, also can in accommodation space, be full of the fragrance of even and certain intensity.The present invention further studies repeatedly and finishes with regard to being based on such opinion.
That is,, provide the invention of following institute prompt mode based on above-mentioned opinion.
1. 1 kinds of perfume compositions that the accommodation space that can open and close is used is characterized in that, contain boiling point under spice and 15～90 weight % normal pressures and be 120～185 ℃ glycol ethers.
An item 2. as 1 a described perfume composition, wherein, the cooperation ratio of above-mentioned glycol ethers is 25～55 weight %.
An item 3. as 1 a described perfume composition, wherein, the vapour pressure of above-mentioned glycol ethers in the time of 20 ℃ is 0.05～1kPa.
An item 4. as 1 a described perfume composition, wherein, above-mentioned glycol ethers is a propylene glycol one hydrocarbyl ether.
An item 5. as 1 a described perfume composition, wherein, above-mentioned glycol ethers is a propylene glycol one positive propyl ether.
An item 6. as 1 a described perfume composition, wherein, the cooperation ratio of above-mentioned spice is 10～85 weight %.
An item 7. as 1 a described perfume composition, wherein, the boiling point of spice under normal pressure is 50～360 ℃.
An item 8. as 1 a described perfume composition, wherein, above-mentioned spice is at least one spice that is selected from d-limonene, caryophyllene, cis-3-hexenol, citronellol, phenethanol, diphenyl ether, dl-rose oxide, hexanal, jasminolene, ethyl n-butyrate., methyl phenyl carbinyl acetate, o-tert-butyl cyclohexyl-acetic acid ester, methyln-hexyl ketone and the δ-damascenone.
An item 9. as 1 a described perfume composition, wherein, the cooperation ratio of above-mentioned spice is 45～75 weight %, the cooperation ratio of above-mentioned glycol ethers is 25～55 weight %.
An item 10. as 1 a described perfume composition, this perfume composition are liquid.
An item 11. as 1 a described perfume composition, it is arranged in drawer or the shoe chest and uses.
An item 12. as 1 a described perfume composition, it is arranged in the medicated clothing accommodation space and uses.
The manufacture method of the perfume composition that 13. 1 kinds accommodation spaces that can open and close are used is characterized in that, so that boiling point is that the cooperation ratio of 120～185 ℃ glycol ethers is mode potpourri and this glycol ethers of 15～90 weight % under the normal pressure.
Fragrance emissions method in 14. 1 kinds accommodation spaces that can open and close is characterized in that, makes in the accommodation space that can open and close that to contain boiling point under spice and 15～90 weight % normal pressures be that the perfume composition of 120～185 ℃ glycol ethers distributes.
The method of adjustment of the fragrance emissions in 15. 1 kinds accommodation spaces that can open and close is characterized in that, so that boiling point is that the cooperation ratio of 120～185 ℃ glycol ethers is mode potpourri and this glycol ethers of 15～90 weight % under the normal pressure.
16. contain that boiling point is the use of compositions in the manufacturing of the perfume composition that the accommodation space that can open and close is used of 120～185 ℃ glycol ethers under spice and 15～90 weight % normal pressures.
Boiling point is the use in 120～185 ℃ the adjustment of the perfume bloom of glycol ethers in the accommodation space that can open and close under the normal pressure of 15～90 weight % of 17. every perfume composition total amounts.
The effect of invention
If according to the present invention,, can make it to possess desired emission characteristics in the accommodation space that can open and close for the spice that is contained.
That is, perfume composition of the present invention can be in the accommodation space of closing evenly and with certain intensity keeps fragrance, even and open and close accommodation space repeatedly, also can in accommodation space, be full of the fragrance of even and certain intensity.Thereby, by perfume composition of the present invention is arranged in the accommodation spaces such as drawer and shoe chest, can make to be full of desirable fragrance in these accommodation spaces, it is fragrant to apply desirable tax to the collecting article of inside.
Description of drawings
After Fig. 1 is illustrated in the perfume composition that makes embodiment 1 and 2 in the drawer and distributes, measure the result that the concentration of spice and solvent obtains.Among the figure, PnP refers to a propylene glycol one positive propyl ether.In addition, the result of the perfume composition of expression embodiment 1 in epimere figure, the result of the perfume composition of expression embodiment 2 in hypomere figure.
After Fig. 2 is illustrated in perfume composition that the interior space makes embodiment 2 and distributes, measure the result that spice and solvent strength obtain.Among the figure, PnP refers to a propylene glycol one positive propyl ether.
The specific embodiment
1. perfume composition
Perfume composition of the present invention is an employed perfume composition in the accommodation space that can open and close, and it is characterized in that, contains boiling point under spice and 15～90 weight % normal pressures and be 120～185 ℃ glycol ethers.Below, be described in detail the specific embodiment of perfume composition of the present invention.
As at the spice that perfume composition of the present invention comprised, can be natural perfume material, any one spice from the isolating single product spice of natural perfume material, synthetic single product spice and their compound perfume, can use existing known spice.In addition, as natural perfume material, illustration tuberose oil, musk tincture, castoreum tincture, the civet aromatin tincture, Ambra Grisea, Oleum menthae, perilla oil, petitgrain bigarade oil, Oleum Pini, Oleum Rosae Rugosae, oil of rosemary, Oleum Camphora, Lignum cinnamomi camphorae oil, sage oil, sandalwood oil, Oleum menthae, aspic oil, Oleum Anisi Stellati, lavandin oil, Oleum lavandula angustifolia, Fructus Citri Limoniae oil, Indian oil of verbena, white lemon oil, orange blossom oil, oak moss oil, ocotea oil, patchouli oil, Oleum thymi vulgaris, Herba Lysimachiae foenum-graeci bean tincture, Oleum Terebinthinae, vanilla bean tincture, oil of basil, Semen Myristicae oil, citronella oil, Oleum Caryophylli, rosewood oil, Cananga odorata oil, Cardamom oil, Oleum Cinnamomi, cedarwood oil, orange peel oil, mandarin oil, mandarin oil, Oleum Anisi Stellati, laurel oil, Fructus Coriandri oil, elemi oil, eucalyptus oil, fennel oil, galbanum oil, geranium oil, arhat pitch, juniper oil, Jasmin oil, vetiver oil, bergamot oil, Cananga odorata oil, oil of grapefruit, the Fructus Citri grandis wet goods.
In perfume composition of the present invention, these spice can be used alone, and also can the two or more perfumery of combination in any use in addition.
In these spice, can the preferred normal pressure of illustration under boiling point be 50～360 ℃, be preferably 70～340 ℃, 90～310 ℃ spice more preferably.In addition, when compound perfume, so-called here boiling point refers to the boiling point of compound perfume self, and the single product spice of each in the compound perfume not necessarily must satisfy above-mentioned boiling spread.Prove effective more significantly by using these spice, can make the even and effect of the present invention certain intensity of the fragrance that is discharged in the accommodation space of closing.
In the present invention, as spice, preferred illustration d-limonene, caryophyllene, cis-3-hexenol, citronellol, phenethanol, diphenyl ether, dl-rose oxide, hexanal, jasminolene, ethyl n-butyrate., methyl phenyl carbinyl acetate, o-tert-butyl cyclohexyl-acetic acid ester, methyln-hexyl ketone and δ-damascenone.If use these spice, then in perfume composition of the present invention, just can possess desired emission characteristics in the accommodation space more effectively.
Cooperate ratio about the spice in the perfume composition of the present invention, according to employed spice kind, the fragrance effect expected etc. and different, therefore stipulate with cannot treat different things as the same, but as an example, can enumerate the gross weight with respect to this perfume composition, the spice total amount is 10～85 weight %, be preferably 25～85 weight %, the ratio of 45～75 weight % more preferably.
Perfume composition of the present invention except above-mentioned spice, contains boiling point under the normal pressure and is 120～185 ℃ glycol ethers.As glycol ethers, boiling point is 130～170 ℃, 140～160 ℃ glycol ethers more preferably under the preferred normal pressure.By using such glycol ethers as solvent, for the spice that is contained, can make it possess desired emission characteristics in accommodation space more effectively with cooperation ratio described later.
As the glycol ethers of boiling point in above-mentioned scope, particularly, can illustration monoethylene glycol monomethyl ether, monoethylene glycol one hydrocarbyl ether such as monoethylene glycol one ether, monoethylene glycol one diisopropyl ether, monoethylene glycol one n-butyl ether, monoethylene glycol one diisobutyl ether, monoethylene glycol one allyl ether; Monoethylene glycol dialkyl ethers such as monoethylene glycol dimethyl ether; Diglycol dialkyl ethers such as diglycol MEE, diglycol diethyl ether; One propylene glycol, one hydrocarbyl ethers such as one propylene glycol monomethyl ether, a propylene glycol monoethyl ether, a propylene glycol one propyl ether, a propylene glycol one n-butyl ether; Dipropylene glycol dialkyl ethers such as dipropylene glycol dimethyl ether; One propylene glycol such as monoethylene glycols such as monoethylene glycol monomethyl ether acetas one hydrocarbyl ether acetas, a propylene glycol monomethyl ether acetas, one hydrocarbyl ether acetas etc.Wherein, from making the viewpoint that the fragrance that is discharged in the accommodation space of closing is even and effect of the present invention certain intensity is proved effective more significantly, can enumerate a preferred propylene glycol one hydrocarbyl ether and a propylene glycol one hydrocarbyl ether acetas; Be more preferably a propylene glycol one alkyl (carbon number 2 or 3) ether and a propylene glycol one alkyl (carbon number 1 or 2) ether acetic acid ester; A preferred especially propylene glycol one n-propyl ether.
The glycol ethers that is cooperated in perfume composition of the present invention except boiling point satisfies above-mentioned scope, wishes that also the vapour pressure in the time of 20 ℃ satisfies 0.05～1kPa, preferably satisfies 0.08～0.8kPa, more preferably satisfies 0.1～0.6kPa.If use the glycol ethers satisfy such vapour pressure, the even and effect of the present invention certain intensity of the fragrance that is discharged in the accommodation space of closing is proved effective more significantly.
In perfume composition of the present invention, the glycol ethers of boiling point in above-mentioned scope can be used alone, in addition also can the two or more uses of combination in any.
In perfume composition of the present invention, the cooperation ratio of the glycol ethers of boiling point in above-mentioned scope can be 15～90 weight %, by satisfying such cooperation ratio, then for the spice that is contained, just can possess the emission characteristics that in accommodation space, requires.In perfume composition of the present invention,, can enumerate preferred 15～75 weight %, more preferably 25～55 weight % as the cooperation ratio of the glycol ethers of boiling point in above-mentioned scope.
Perfume composition of the present invention except above-mentioned spice and glycol ethers, is a limit not hinder effect of the present invention, can cooperate other composition.As other composition that can in perfume composition of the present invention, cooperate, for example, can enumerate surfactant, antiseptic, antioxidant, solvent, deodorizer, bacteria remover, UV absorbent, pH adjusts agent, insecticidal constituent, insect protected composition, avoids to keep away and become to grade composition.
As the surfactant that can in perfume composition of the present invention, cooperate, particularly, can enumerate nonionic surfactants such as polyoxyethylene sclerosis Semen Ricini oil, polyoxyethylene sclerosis Semen Ricini oil ether, polyoxyethylene alkyl ether, polyoxyethylene lauryl ether, polyoxyethylene oleoyl ether, polyoxyethylene fatty acid ester, polyoxyethylene glycerol ether fatty acid ester, alkyl alkanolamide, alkyl polyglucoside, sorbitan fatty acid esters, fatty acid glyceride, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene polyoxypropylene glycol; Anionic surfactants such as alkyl sulfate, polyoxyethylene alkyl ether sulfate salt, sulfosuccinate, N-acyl amino hydrochlorate, carboxylate, sulfonic acid, phosphate ester; Cationic surfactants such as alkylammonium salt; Amphoteric surfactant such as alkyl amido betaine, alkyl dimethyl amine oxide etc.
As the antiseptic that can in perfume composition of the present invention, cooperate, particularly, can enumerate sorbic acid, methyl parahydroxybenzoate, 1,2-benzisothiazole-3-ketone, 2-n-octyl-isothiazoline-3-ketone etc.
As the antioxidant that can in perfume composition of the present invention, cooperate, particularly, can enumerate dibenzylatiooluene (BHT), Butylated hydroxyanisole (BHA), Ascorbate, isoflavone, alpha-tocopherol etc.
As the solvent that can in perfume composition of the present invention, cooperate, particularly, can enumerate isoparaffin, ethanol, propanol, butanols, ethylene glycol, propylene glycol, dipropylene glycol of water, 3-methoxyl group-3-methyl isophthalic acid-butanols, nowed forming etc.
As the deodorizer that can in perfume composition of the present invention, cooperate, particularly, can enumerate dichlorisocyanurate; The extract of plants such as rice, pine, Chinese juniper, bamboo, Fructus Kaki, tea; Desalination type betaine compound; The modification organic acid compound; Alkanolamine; Stabilizing chlorine dioxide; Aldehyde compound; The glycol ethers chemical compound; Phytocide class spice; Lower aliphatic aldehydes spice etc.
As the bacteria remover that can in perfume composition of the present invention, cooperate, particularly, can enumerate isopropyl cresol, p-Hydroxybenzoate, PCMX, IPBC, gluconic acid chlorhexidine, hydrochloric acid chlorhexidine, benzethonium chloride, cetylpyridinium chloride, chlorine dioxide, dichlorisocyanurate, terpene hydrocarbons spice, terpene alcohols spice, phenols spice, aromatic series alcohols spice, aldehydes spice etc.
As the UV absorbent that can cooperate in perfume composition of the present invention, particularly, (2-(3 can to enumerate benzotriazole, 5-two tertiary pentyls-2-hydroxy phenyl)-the 2H-benzotriazole), benzophenone (2,2,4, the 4-tetrahydroxybenzophenone) etc.
Adjust agent as the pH that can in perfume composition of the present invention, cooperate, particularly, can enumerate alkanolamines such as monoethanolamine, diisopropanolamine (DIPA), diethanolamine, triethanolamine; The alkali metal salt of citric acid such as trisodium citrate, potassium citrate; Calcium salts such as ethylene diaminetetraacetic acid, sodium hydroxide, alkali type amino acid (arginine), calcium carbonate etc.
As the insecticidal constituent that can in perfume composition of the present invention, cooperate, particularly, can enumerate Chinese juniper another name for, arhat pitch, allyl isothiocyanate salt, propylene glycol monomethyl ether, ethanol, propanol, 1,8-cineole etc.
As the insect protected composition that can in perfume composition of the present invention, cooperate, particularly, can enumerate pyrethroid coumpound, naphthalene compounds, paracide compounds, Camphora etc.
As the taboo composition that can in perfume composition of the present invention, cooperate, particularly, can enumerate N, N-diethyl-m-toluamide, dimethyl phthalate, dibutyl phthalate, right-terpane-3,8-glycol, 2-ethyl-1,3-hexanediol, third fly drive, paracide, succinic acid di-n-butyl, carane-3,4-glycol, 1-methyl-propyl-2-(2-ethoxy)-1-piperidine carboxylic acid ester, isothiocyanic acid allyl ester etc.Can also enumerate plant extracts such as terpene hydrocarbons spice, terpene alcohols spice, phenols spice, aromatic series alcohols spice, aldehydes spice, ketone fragrance, mustard, pepper root and pyroligneous acid etc.
Shape about perfume composition of the present invention is not particularly limited, and both can be liquid state, also can be gel.Be preferably liquid state.
Perfume composition of the present invention prepares by the quantitative above-mentioned spice of hybrid regulatory and above-mentioned glycol ethers and other gradation composition as required.
Perfume composition of the present invention uses as the aromatic that is arranged in the accommodation space that can open and close.In the present invention, the accommodation space that what is called can open and close is the accommodation space that collecting article can be taken out or takes in by opening and closing, particularly, and can the illustration drawer, shoe chest, suitcase, glove compartment, cabinet etc.In above-mentioned accommodation space, shoe chest and drawer, particularly drawer are preferably as the object accommodation space of perfume composition of the present invention.Accommodation space as using perfume composition of the present invention is not particularly limited about its volume, can enumerate common 0.5～150L, preferred 1～100L, more preferably 10～80L.For volumetrical like this accommodation space, the effect of fragrance can be brought into play evenly and be kept with certain intensity to perfume composition of the present invention more effectively.
In addition, because perfume composition of the present invention can be given fragrance to the collecting article in the accommodation space, so, by being arranged in the medicated clothing accommodation space, can give comfortable fragrance to the medicated clothing of being taken in.If in view of such effect of the present invention, as an example that is fit to of the accommodation space that uses perfume composition of the present invention, can illustration medicated clothing accommodation space.
Perfume composition of the present invention is accommodated in spice and can uses in the container that distribute the outside.About the structure of such container, can suitably set according to the shape of the perfume composition that uses.For example, when perfume composition of the present invention is liquid state, can illustration (i) possess the container that distributes member that sucts that the perfume composition that is used for being accommodated in container sucts and make it to distribute, and (ii) use and liquid perfume composition is spilt and make known permeability film that the perfume composition that distributes passes through container the peristome sealing.The latter's container particularly, even impacted when accommodation space opens and closes, liquid can not spill outside container yet, therefore is suitable for taking in of perfume composition of the present invention.In addition, when perfume composition of the present invention is liquid state, can also be accommodated in the container with the state that contains in the base materials such as natural resinoid such as being immersed in paper, paper pulp, synthetic fibers, synthetic resin, cellulose, by being accommodated in the container with such state, liquid spills in the time of can preventing the accommodation space switching.
II. the fragrance emissions method in the accommodation space that can open and close
As mentioned above, in the accommodation space that can open and close, above-mentioned perfume composition can be evenly and is scentetd with certain intensity.Therefore, the present invention also provides the fragrance emissions method in a kind of accommodation space that can open and close, it is characterized in that, in the accommodation space that can open and close, make that to contain boiling point under spice and 15～90 weight % normal pressures be that the perfume composition of 120～185 ℃ glycol ethers distributes.
In this spreading method, about using method of the composition of perfume composition, the accommodation space that can open and close, perfume composition etc., as the record on above-mentioned " I. perfume composition " hurdle.
III. the method for adjustment of the fragrance emissions in the accommodation space that can open and close
In addition, as mentioned above, by so that under the normal pressure boiling point be that 120～185 ℃ glycol ethers is mode potpourri and this glycol ethers of 15～90 weight %, can adjust dispensation of fragrance, making in the accommodation space of closing can be evenly and scentetd with certain intensity.Therefore, the present invention also provides the method for adjustment of the fragrance emissions in a kind of accommodation space that can open and close, and it is characterized in that, so that boiling point is that the cooperation ratio of 120～185 ℃ glycol ethers is mode potpourri and this glycol ethers of 15～90 weight % under the normal pressure.
In this method of adjustment, about the kind of employed spice kind, employed glycol ethers, their cooperation ratio etc., as the record on above-mentioned " I. perfume composition " hurdle.
Embodiment
Below, enumerate embodiment and wait explanation the present invention, but the present invention is not subjected to the qualification of these embodiment.
Test example 1Perfume bloom The Characteristic Study in the drawer
The perfume composition of forming shown in the preparation table 1, the perfume bloom characteristic in the research drawer.
[table 1]
The commodity that # one propylene glycol one positive propyl ether uses Dow Chemical Japan Ltd. to produce.The boiling point of one propylene glycol, one positive propyl ether under normal pressure is 150 ℃, and the vapour pressure in the time of 20 ℃ is 0.205kPa.
Particularly, at the volumetrical container of the 40ml (area of opening portion: about 1cm
2) the middle perfume composition that adds composition shown in the 20g table 1.Then, insert to suct in the container that has added perfume composition and distribute member, this sucts and distributes member and have and be used to suct the portion that sucts of the perfume composition in the container and be configured in the outer portion that distributes that is used to make the perfume composition that sucts to distribute of container outside container.Wherein, distribute member, use the member that constitutes by paper pulp or man-made fibre material as sucting.The container that the perfume composition for preparing like this can be distributed be arranged on drawer (wooden, in 50 * 40 * 8.5cm), drawer is closed fully, make perfume composition in drawer, begin to distribute.After perfume composition begins to distribute 20 minutes, beginning is after 4 days and after beginning 7, opens drawer, judges the fragrance that is smelt according to following benchmark by 6 participants.Wherein, in the test,, drawer is kept closing state, do not carry out the switching of drawer except perfume composition begins to distribute after 20 minutes, beginning is after 4 days and beginning after 7 days.
＜metewand 〉
1 minute: smell faint fragrance
2 minutes: smell weak a little fragrance
3 minutes: smell just right fragrance
4 minutes: smell strong slightly fragrance
5 minutes: smell strong fragrance
Re-using gas chromatograph has measured and has begun to distribute preceding, beginning after 4 days and begin to remain in after 7 days concentration of perfume in the perfume composition in the container.
Represent that in table 2 in addition, Fig. 1 represents to measure the result that the concentration of perfume in the perfume composition obtains about the evaluation result of the fragrance that is smelt.Wherein, in Fig. 1, as the representative example of the measurement result of the concentration of relevant spice of perfume composition and solvent, expression embodiment 1 result relevant with 2 perfume composition.Can confirm according to this result, the perfume composition of embodiment 1～9 when beginning to distribute the 7th day to the beginning back, the fragrance that is smelt is kept evenly.In addition, also can be clear and definite according to the measurement result of the concentration of spice in the perfume composition and solvent, the concentration of spice and solvent is almost constant, even open and close drawer repeatedly, also can be full of the fragrance of even and certain intensity in the drawer.
[table 2]
The result of determination of #1 fragrance is represented the meansigma methods of 6 participants' result of determination
The difference of #2 fragrance result of determination represents that the result of determination that the result of determination value after 20 minutes deducted after 7 days is worth resulting value
Reference test example 1The perfume bloom The Characteristic Study of the interior space
Similarly the perfume composition of forming shown in the table 1 is added in the container with above-mentioned test example 1, make it be in the state that can distribute, it is rested on indoor, make the beginning of distributing of perfume composition.Perfume composition begin to distribute preceding, the beginning 4 days after and begin 7 after, the container former state that has added perfume composition is moved to and will remain on 22 ℃ in the storehouse, approach the storehouse (volume: 1000L) of the stainless steel of calm tasteless state, after leaving standstill 20 minutes, to judge the fragrance that smells with above-mentioned test example 1 same method.Adopt again to measure and begin to distribute preceding, beginning after 4 days and begin the spice in the perfume composition and the concentration of solvent after 7 days with the same method of above-mentioned test example 1.
Expression is for the evaluation result of the fragrance that is smelt in table 3, and in addition, Fig. 2 represents to measure the result that the concentration of spice in the perfume composition and solvent obtains.Wherein, in table 3, as the representative example of the result of determination of the fragrance that is smelt, the result that expression embodiment 3,5,6 is relevant with 9 perfume composition.For embodiment 1,2,4 and 7～8, omit the result of determination of the fragrance smelt, but can confirm the tendency same with embodiment 3,5,6 and 9.In addition, in Fig. 2, as the representative example of the measurement result of the concentration of relevant spice of perfume composition and solvent, the result of the perfume composition of expression embodiment 2.For embodiment 1 and 3～9, omit the measurement result of the concentration of relevant spice of perfume composition and solvent, but can confirm tendency similarly to Example 2.
As can be known from these results, if the perfume composition of embodiment 1～9 is arranged on the interior space, then the fragrance that is smelt will become inhomogeneous along with the time, and the concentration of spice and solvent also has the tendency along with time fluctuation.
[table 3]
The result of determination of #1 fragrance is represented the meansigma methods of 6 participants' result of determination
The difference of #2 fragrance result of determination represents that the result of determination that the result of determination value before begin to distribute deducted after 7 days is worth resulting value
From above result as can be known, the perfume composition of embodiment 1～9 than the use in the common interior space, is more suitable for the use in the accommodation space that drawer etc. is closed.
Reference test example 2Perfume bloom The Characteristic Study when using other solvent
Using boiling point under the normal pressure is solvent beyond 120～185 ℃ the glycol ethers or a propylene glycol one hydrocarbyl ether of 10 weight %, preparation perfume composition, the perfume bloom characteristic of research in drawer.Particularly, the perfume composition of forming shown in the preparation table 4 adopts with the same method of above-mentioned test example 1 it is arranged in the drawer, makes and distributes beginning.After perfume composition begins to distribute 20 minutes, beginning is after 4 days and after beginning 7, opens drawer, adopt with the same method of above-mentioned test example 1 and judge the fragrance that is smelt.
[table 4]
Unit: weight %
#1ISOPAR MB is the commodity that Exxon Mobil Corporation produces, and is that boiling point under the expression normal pressure vapour pressure when being 225～254 ℃, 20 ℃ is the isoparaffin class hydrocarbon of 0.01kPa.
#2Dowanol DPM is the commodity that Dow Chemical Japan Ltd. produces, and is dipropylene glycol one ether of boiling point under the expression normal pressure vapour pressure position 0.037kPa when being 190 ℃, 20 ℃.
#3SOLFIT is the commodity that Kuraray Co., Ltd. produces, and is that boiling point under the expression normal pressure is 3-methoxyl group-3-methyl isophthalic acid-butanols of 174 ℃.
The commodity that #4 one propylene glycol one positive propyl ether uses Dow Chemical Japan Ltd. to produce.Boiling point under one propylene glycol, the one positive propyl ether normal pressure is 150 ℃, and the vapour pressure in the time of 20 ℃ is 0.205kPa.
This result is, confirms after beginning to distribute 20 minutes and beginning after 7 days, and the aroma strength that smells obviously changes, and confirms that the fragrance that is smelt becomes inhomogeneous along with the time.
From above result as can be known, by make boiling point under the normal pressure be the concentration of 120～185 ℃ glycol ethers be 15～90 weight %, in particular for 20～70 weight %, (10～85 weight %, particularly 30～80 weight %) mix with spice, fragrance evenly and with certain intensity is kept, and when using other solvent, in accommodation spaces such as drawer, can not and keep fragrance equably, can not create the comfortable space that is full of good fragrance along with the time variation.
Claims (17)
1. perfume composition that the accommodation space that can open and close is used is characterized in that:
Contain boiling point under spice and 15～90 weight % normal pressures and be 120～185 ℃ glycol ethers.
2. perfume composition as claimed in claim 1 is characterized in that:
The cooperation ratio of described glycol ethers is 25～55 weight %.
3. perfume composition as claimed in claim 1 is characterized in that:
The vapour pressure of described glycol ethers in the time of 20 ℃ is 0.05～1kPa.
4. perfume composition as claimed in claim 1 is characterized in that:
Described glycol ethers is a propylene glycol one hydrocarbyl ether.
5. perfume composition as claimed in claim 1 is characterized in that:
Described glycol ethers is a propylene glycol one positive propyl ether.
6. perfume composition as claimed in claim 1 is characterized in that:
The cooperation ratio of described spice is 10～85 weight %.
7. perfume composition as claimed in claim 1 is characterized in that:
The boiling point of described spice under normal pressure is 50～360 ℃.
8. perfume composition as claimed in claim 1 is characterized in that:
Described spice is at least one spice that is selected from d-limonene, caryophyllene, cis-3-hexenol, citronellol, phenethanol, diphenyl ether, dl-rose oxide, hexanal, jasminolene, ethyl n-butyrate., methyl phenyl carbinyl acetate, o-tert-butyl cyclohexyl-acetic acid ester, methyln-hexyl ketone and the δ-damascenone.
9. perfume composition as claimed in claim 1 is characterized in that:
The cooperation ratio of described spice is 45～75 weight %, and the cooperation ratio of described glycol ethers is 25～55 weight %.
10. perfume composition as claimed in claim 1 is characterized in that:
This perfume composition is liquid.
11. perfume composition as claimed in claim 1 is characterized in that:
Be arranged in drawer or the shoe chest and use.
12. perfume composition as claimed in claim 1 is characterized in that:
Be arranged in the medicated clothing accommodation space and use.
13. the manufacture method of the perfume composition that the accommodation space that can open and close is used is characterized in that: so that boiling point is that the cooperation ratio of 120～185 ℃ glycol ethers is mode potpourri and this glycol ethers of 15～90 weight % under the normal pressure.
14. the fragrance emissions method in the accommodation space that can open and close is characterized in that:
Make in the accommodation space that can open and close that to contain boiling point under spice and 15～90 weight % normal pressures be that the perfume composition of 120～185 ℃ glycol ethers distributes.
15. the method for adjustment of the fragrance emissions in the accommodation space that can open and close is characterized in that: so that boiling point is that the cooperation ratio of 120～185 ℃ glycol ethers is mode potpourri and this glycol ethers of 15～90 weight % under the normal pressure.
Boiling point is the use of compositions in the manufacturing of the perfume composition that the accommodation space that can open and close is used of 120～185 ℃ glycol ethers under spice and 15～90 weight % normal pressures 16. contain.
17. boiling point is the use in 120～185 ℃ the adjustment of the perfume bloom of glycol ethers in the accommodation space that can open and close under the normal pressure of 15～90 weight % of every perfume composition total amount.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008046938 | 2008-02-27 | ||
| JP2008-046938 | 2008-02-27 | ||
| PCT/JP2009/053767 WO2009107813A1 (en) | 2008-02-27 | 2009-02-27 | Aromatic agent composition for openable storage space |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101959535A true CN101959535A (en) | 2011-01-26 |
Family
ID=41016197
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009801066520A Pending CN101959535A (en) | 2008-02-27 | 2009-02-27 | Aromatic agent composition for openable storage space |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2272541A4 (en) |
| JP (1) | JP5867998B2 (en) |
| CN (1) | CN101959535A (en) |
| WO (1) | WO2009107813A1 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102845416A (en) * | 2011-07-01 | 2013-01-02 | 大日本除虫菊株式会社 | Aromatic insect-preventing vermifuge |
| CN103060092A (en) * | 2012-12-25 | 2013-04-24 | 林翔云 | Essence composition capable of eliminating formaldehyde hazards and preparation method thereof |
| CN106039365A (en) * | 2016-06-11 | 2016-10-26 | 南京晶云化工有限公司 | Deodorant and preparation method thereof |
| CN107569709A (en) * | 2017-09-22 | 2018-01-12 | 宁波芬畅凝科香精香料有限公司 | Air freshener limonene glue and preparation method thereof |
| CN107708652A (en) * | 2015-06-12 | 2018-02-16 | 宝洁公司 | Perfume composition and application thereof |
| CN108348629A (en) * | 2015-11-17 | 2018-07-31 | 奇华顿股份有限公司 | Spice composition and air freshener device |
| CN109464690A (en) * | 2017-09-07 | 2019-03-15 | 湖南省开元博物馆 | A kind of face powder or solid perfume of composition and its preparation with fragrance |
| CN110584185A (en) * | 2019-09-12 | 2019-12-20 | 深圳雾芯科技有限公司 | Flavor composition and electronic cigarette liquid containing same |
| CN113750279A (en) * | 2020-06-02 | 2021-12-07 | 苏州工业园区艾舍尔环境技术有限公司 | Oily concentrated air deodorant and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9205165B2 (en) | 2012-10-22 | 2015-12-08 | S.C. Johnson & Son, Inc. | Volatile material dispensing system having an adjustable diffusion apparatus |
| JP7001344B2 (en) | 2016-12-28 | 2022-01-19 | 小林製薬株式会社 | Fragrance composition |
| CN112439091A (en) * | 2020-12-11 | 2021-03-05 | 大理白族自治州中医医院 | Fragrant slice and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1067585A (en) * | 1991-06-13 | 1993-01-06 | 莎拉李/迪有限公司 | Air freshener composition |
| CN1286123A (en) * | 1999-08-26 | 2001-03-07 | 国际香料和香精公司 | Monophasic waer surfactant-free non-toxic air refreshing agent composition and core type air refreshing device using same |
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| EP0194017B1 (en) * | 1985-01-31 | 1989-08-30 | BUSH BOAKE ALLEN Limited | Liquid air fresheners |
| JPH03275066A (en) * | 1990-03-23 | 1991-12-05 | Mitsutoshi Kashiwazaki | Apparatus for diffusing volatile medicine |
| JP4224175B2 (en) * | 1999-08-11 | 2009-02-12 | 長谷川香料株式会社 | Transparent gel fragrance / deodorant composition |
| JP2001333970A (en) * | 2000-05-29 | 2001-12-04 | Ranpanto Kk | Filling type multipurpose aromatic implement |
| JP4959889B2 (en) | 2001-09-28 | 2012-06-27 | 小林製薬株式会社 | Aromatic deodorant composition |
| JP2004344558A (en) * | 2003-05-26 | 2004-12-09 | Matsushita Electric Works Ltd | Method for improving quality of air in closed space |
| JP2006282549A (en) * | 2005-03-31 | 2006-10-19 | Kobayashi Pharmaceut Co Ltd | Aroma liquid composition |
| US7449441B2 (en) * | 2005-05-18 | 2008-11-11 | Toilex, Llc | Liquid composition for reducing toilet odor |
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2009
- 2009-02-27 WO PCT/JP2009/053767 patent/WO2009107813A1/en active Application Filing
- 2009-02-27 JP JP2010500788A patent/JP5867998B2/en active Active
- 2009-02-27 CN CN2009801066520A patent/CN101959535A/en active Pending
- 2009-02-27 EP EP09713864A patent/EP2272541A4/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1067585A (en) * | 1991-06-13 | 1993-01-06 | 莎拉李/迪有限公司 | Air freshener composition |
| CN1286123A (en) * | 1999-08-26 | 2001-03-07 | 国际香料和香精公司 | Monophasic waer surfactant-free non-toxic air refreshing agent composition and core type air refreshing device using same |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102845416A (en) * | 2011-07-01 | 2013-01-02 | 大日本除虫菊株式会社 | Aromatic insect-preventing vermifuge |
| CN102845416B (en) * | 2011-07-01 | 2016-08-03 | 大日本除虫菊株式会社 | Armaticity insecting driving insect agent |
| CN103060092A (en) * | 2012-12-25 | 2013-04-24 | 林翔云 | Essence composition capable of eliminating formaldehyde hazards and preparation method thereof |
| CN103060092B (en) * | 2012-12-25 | 2014-04-30 | 林翔云 | Essence composition capable of eliminating formaldehyde hazards and preparation method thereof |
| CN107708652A (en) * | 2015-06-12 | 2018-02-16 | 宝洁公司 | Perfume composition and application thereof |
| CN107708652B (en) * | 2015-06-12 | 2021-09-21 | 宝洁公司 | Fragrance compositions and uses thereof |
| CN108348629A (en) * | 2015-11-17 | 2018-07-31 | 奇华顿股份有限公司 | Spice composition and air freshener device |
| CN106039365A (en) * | 2016-06-11 | 2016-10-26 | 南京晶云化工有限公司 | Deodorant and preparation method thereof |
| CN109464690A (en) * | 2017-09-07 | 2019-03-15 | 湖南省开元博物馆 | A kind of face powder or solid perfume of composition and its preparation with fragrance |
| CN109464690B (en) * | 2017-09-07 | 2021-06-15 | 湖南省开元博物馆 | Composition with fragrant smell and incense powder or solid incense prepared from composition |
| CN107569709A (en) * | 2017-09-22 | 2018-01-12 | 宁波芬畅凝科香精香料有限公司 | Air freshener limonene glue and preparation method thereof |
| CN110584185A (en) * | 2019-09-12 | 2019-12-20 | 深圳雾芯科技有限公司 | Flavor composition and electronic cigarette liquid containing same |
| WO2021046918A1 (en) * | 2019-09-12 | 2021-03-18 | 深圳雾芯科技有限公司 | Flavor composition and electronic cigarette liquid containing same |
| CN113750279A (en) * | 2020-06-02 | 2021-12-07 | 苏州工业园区艾舍尔环境技术有限公司 | Oily concentrated air deodorant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2272541A1 (en) | 2011-01-12 |
| WO2009107813A1 (en) | 2009-09-03 |
| JP5867998B2 (en) | 2016-02-24 |
| JPWO2009107813A1 (en) | 2011-07-07 |
| EP2272541A4 (en) | 2011-06-15 |
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Application publication date: 20110126 |