CN101880824A - Q345q-series super-thick bridge steel plate and production method thereof - Google Patents

Q345q-series super-thick bridge steel plate and production method thereof Download PDF

Info

Publication number
CN101880824A
CN101880824A CN2010102083053A CN201010208305A CN101880824A CN 101880824 A CN101880824 A CN 101880824A CN 2010102083053 A CN2010102083053 A CN 2010102083053A CN 201010208305 A CN201010208305 A CN 201010208305A CN 101880824 A CN101880824 A CN 101880824A
Authority
CN
China
Prior art keywords
steel plate
thick
rolling
bridge
production method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2010102083053A
Other languages
Chinese (zh)
Other versions
CN101880824B (en
Inventor
朱书成
许少普
崔冠军
赵迪
高照海
杨东
李红阳
于飒
庞百鸣
张少辉
袁永旗
雷文慧
唐郑磊
黄文震
李治强
徐昭
彭卡丽
徐番
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanyang Hanye Special Steel Co Ltd
Original Assignee
Nanyang Hanye Special Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanyang Hanye Special Steel Co Ltd filed Critical Nanyang Hanye Special Steel Co Ltd
Priority to CN2010102083053A priority Critical patent/CN101880824B/en
Publication of CN101880824A publication Critical patent/CN101880824A/en
Application granted granted Critical
Publication of CN101880824B publication Critical patent/CN101880824B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

The invention discloses a Q345q-series super-thick guaranteed performance and flaw detection bridge steel plate comprising the following chemical components in percentage by mass: 0.08-0.16 percent of C, 0.20-0.50 percent of Si, 1.15-1.60 percent of Mn, not more than 0.020 percent of P, not more than 0.010 percent of S, not more than 0.12 percent of microalloyed element (V+Nb+Ti+Ni), 0.010-0.050 percent of AlS and the balance of Fe and residual elements; and carbon equivalent is not more than 0.43. The invention also discloses a production method of the steel plate, comprising the steps of rolling, cooling, straightening, cooling in pile and thermal treatment. In the rolling, the cooling and the straightening, the 130 mm super-thick Q345qD(E) steel plate is successfully developed in the production line of a converter, die casting, mill rolling and normalization thermal treatment through carrying out reasonable composition design, die casting, TMCP (Thermal Mechanical Control Process) rolling and thermal treatment; the secondary flaw detection qualification rate reaches 90 percent, the performance initial test qualification rate reaches 100 percent, and the Z-direction performance of the entity of the steel plate can reach Z15 level. The development of the super-thick steel plate satisfies the higher requirements on bridge industry.

Description

Q345q special thick bridge steel plate of series and production method thereof
Technical field
The present invention relates to steel, be specifically related to a kind of Q345q special thick bridge steel plate of series and production method thereof.
Background technology
Along with developing rapidly of Chinese national economy, the development of Bridge Steel is also thick towards the spy, extra wide, high-performance direction develop.Bridge structure is widely used in the main body of various Longspan Bridges with steel, requirement can exempt to bear bigger quiet, moving load, long active time is arranged, therefore the Bridge Steel industry has proposed higher requirement to steel plate obdurability, welding property, yield tensile ratio, anti-lamellar tearing ability, high strength, good low-temperature flexibility through and the demand of the Bridge Steel of good welds performance constantly increase.The domestic fertile steel mill of bridge plate more than the thickness 100m is also few at present, but can't produce about reasons such as the special thick bridge steel plate of Q345q series (comprising: Q345qC steel, Q345qD steel and Q345qE steel) of thickness more than 100111m are big with its production difficulty, the tooling requirement is special.
Summary of the invention
At the problems referred to above, the inventor has obtained the Q345q series special thick bridge steel plate of a kind of thickness more than 100m, thereby has finished the present invention through groping.
Therefore, the object of the present invention is to provide the Q345q series special thick bridge steel plate of a kind of thickness more than 100mm.Another object of the present invention is to provide the production method of this this steel plate.
For reaching above-mentioned first purpose, the technical scheme that the present invention takes be the special thick bridge steel plate of this Q345q series comprise following chemical components in mass percent (unit, wt%): C:0.08~0.16, Si:0.20~0.50, Mn:1.15~1.60, P :≤0.020, S :≤0.010, micro alloying element (V+Nb+Ti+Ni) :≤0.12, AlS:0.010~0.050, other is Fe and relict element;
Carbon equivalent [Ceq=C+Mn/5+ (Cr+Mo+V)/5+ (Ni+Cu)/15] :≤0.43.
More than the function analysis of each chemical ingredients as follows:
C: be most basic strengthening element in the steel, improve intensity, but C influences the welding property of steel and influences toughness.Take all factors into consideration, the content of carbon is hanging down of control as far as possible.
Si: be the solution strengthening element, favourable to the intensity that improves steel plate.
Mn: be the solution strengthening element, all favourable to intensity and the toughness that improves steel plate.
P: unfavorable to welding, and have certain cold shortness, and in this steel grade, belong to harmful element, that should control is low as far as possible.
S: easily form the MnS type impurity, have certain red brittleness, belong to harmful element in this steel grade, that should control is low as far as possible.
V, Nb, Ti: in steel, can combine, form fine carbide or carbonitride, can play crystal grain thinning and dispersion-strengthened action, thereby reach the net effect of the obdurability of effective raising steel with C, N.
Ni: an amount of adding can effectively improve the low-temperature impact toughness of steel plate.
Al: can play the crystal grain thinning strengthening effect.
The thickness of the thick bridge steel plate of described spy is more than 100mm.
For achieving the above object, the production method that the present invention takes comprises: converter smelting, LF refining, vacuum refinement, cast, heating, control are cold, slow cooling, thermal treatment; It is characterized in that the fs start rolling temperature is controlled between 1000~1200 ℃, it is rolling to adopt high temperature low speed to depress greatly, and reduction in pass is not less than 40mm; When temperature is not less than 1000 ℃, stop rolling the steel that dries in the air, the steel thickness that dries in the air is 2-3 times of finished product thickness; When the rolled piece temperature was 860~920 ℃, the beginning subordinate phase was rolling, and reduction in pass is not less than 30mm, and last three percentage pass reductions 〉=15% increases progressively by the road; Finishing temperature is controlled at 800~860 ℃; The rolling back that finishes adopts the ACC control cold, and final cooling temperature is controlled between 650~750 ℃, is sent to the straightener aligning then.
The bridge structure steel is had relatively high expectations to intensity and welding property, makes the use of carbon equivalent be restricted, and for the thick bridge plate of spy, the composition design is more prudent and crucial.Maximum ga(u)ge in the GB/T714-2008 GB only is 100mm, expect the special thick bridge plate of 130mm, should rationally select micro alloying element for use, utilize the compound adding of best proportioning of Nb, V, Ti, give full play to precipitation strength and refined crystalline strengthening double effects, do not reducing under the flexible prerequisite, guaranteeing that every performance index of bridge plate reach the requirement of GB 50-100mm.
For obtaining internal soundness preferably, guarantee the requirement of detecting a flaw, the smelting of Clean Steel is the basis, mainly guarantee from two aspects, the one, total rank of non-metallic inclusion in the molten steel (A, B, C, D four big classes) is controlled in 4.0, the 2nd, the content of five big harmful elements in the strict molten steel, concrete measure is: desulfurization taked for two steps walked, and taked molten iron pre-desulfurization technology to guarantee the content into stove molten iron S on the one hand; Make white slag in the reinforcement of LF refining furnace on the other hand and carry out the secondary desulfurization.Deoxidation taked for two steps walked equally, and the deoxidation operation is strengthened in strict on the one hand control converter terminal C% content (preventing peroxidation), reinforcement pushing off the slag tapping, improves the molten steel purity; Make full use of the LF refining furnace on the other hand, adopt high temperature, high basicity, the abundant deoxidation of high quantity of slag suboxide iron slagging process; Moreover need prolongation dwell time under the VD vacuum condition fully outgases.In strict accordance with the Clean Steel production process route, guarantee that S, P, N, H, O five big harmful elements are controlled in the 160ppm.Adopt suitable burning steel temperature, burning the steel time is 13min/cm+60min, guarantee that micro alloying element melts at the fully solid of austenitic area, rough rolling step takes high temperature low speed to depress technology greatly, two-stage takes>and the steel thickness that dries in the air of 2.5H is rolling, ACC adopts suitable roller speed and the cooling rate of 5~15 ℃/S, to guarantee the effect of controlled rolling crystal grain thinning.
Be further uniform formation, eliminate banded structure, crystal grain thinning improves the steel plate comprehensive mechanical property, adopts normalizing heat treatment technique to rolling the back steel plate, and normalizing temperature is chosen in Ar3+ (30-50 ℃) interval, adopts the soaking time of 2.2min/mm+30min.In order to guarantee obdurability and welding property requirement, the composition design is taked the low-carbon high-manganese scheme, the steel grade [P] of keeping under strict control simultaneously, [S], [N], [H], [O] five big harmful element content.
By carry out reasonable component design, die casting cast, TMCP is rolling and thermal treatment, successfully developed special thick Q345qD (E) steel plate of 130mm at converter-die casting cast-rolling-normalizing heat-treatment production line, the secondary flaw detection qualification rate reaches 90%, performance initial test qualification rate reaches 100%, and its ballistic work in kind can reach the E level, Z reaches the Z15 level to performance.The exploitation of the thick bridge plate of this spy has been satisfied bridge industry high requirement.
Description of drawings
Below in conjunction with accompanying drawing, the present invention is further elaborated.
Fig. 1 is a process flow sheet of the present invention.
Fig. 2 is the metallographic structure figure of TMCP of the present invention after rolling.
Fig. 3 is the metallographic structure figure after the thermal treatment of the present invention.
Embodiment
The special thick bridge steel plate of Q345qD of the present invention comprises following chemical components in mass percent: C%:0.08~0.16, Si%:0.20~0.45, Mn%:1.15~1.60, P% :≤0.020, S :≤0.010, micro alloying element (V+Nb+Ti+Ni) % :≤0.12, AlS%:0.010~0.050, other is Fe and relict element; Carbon equivalent [Ceq=C+Mn/5+ (Cr+Mo+V)/5+ (Ni+Cu)/15] :≤0.43.
The production method that the present invention takes, comprise rolling, cooling, aligning, cooling in heap, thermal treatment,, it is characterized in that the fs start rolling temperature is controlled between 1000~1200 ℃ at described rolling, cooling, aligning, it is rolling to adopt high temperature low speed to depress greatly, and reduction in pass is not less than 40mm; When temperature is not less than 1000 ℃, stop rolling the steel that dries in the air, the steel thickness that dries in the air is 2-3 times of finished product thickness; When the rolled piece temperature was 860~920 ℃, the beginning subordinate phase was rolling, and reduction in pass is not less than 30mm, and last three percentage pass reductions 〉=15% increases progressively by the road; Finishing temperature is controlled at 800~860 ℃; The rolling back that finishes adopts the ACC control cold, and final cooling temperature is controlled between 650~750 ℃, is sent to the straightener aligning then.
In described converter smelting, tapping carbon 〉=0.06%, tapping P≤0.012%, S≤0.012%; Point blows number of times and must not avoid slag under the tapping process greater than 2 times.
In described LF refining, take the big quantity of slag to carry out slag making, guarantee that the white slag hold-time is controlled at more than the 15min.
In described vacuum refinement, the dwell time under≤67Pa is controlled by 〉=10min.
Pine in described adding, the holding temperature of dead soaking pit is controlled at 1200 ℃~1300 ℃.
In described control is cold, return red temperature<740 ℃, cooling rate is controlled at 5~15 ℃/s.
In described slow cooling, go into burial pit temperature 〉=300 ℃; Cooling in heap time 〉=24 hour.
In described thermal treatment, holding temperature: 910 ± 30 ℃; Heat-up time: 1.5-2.5min/mm; The type of cooling: air cooling or air-cooled.
In the described cooling in heap, the temperature before the steel plate stacking slow cooling should be higher than 300 ℃, the content of hydrogen, steel plate initial temperature and steel plate thickness in the stacking slow cooling basis of time steel plate and decide.
Embodiment 1
, slow cooling cold by converter smelting, LF refining, vacuum refinement, cast, heating, control, thermal treatment process obtain to be described in table 2 below the Q345qD Finished Steel of chemical ingredients, and wherein each processing parameter and mechanical property are seen as following table 4,5,6.
The chemical ingredients of table 1 embodiment 1 steel
??C(%) ??Si(%) ??Mn(%) ??P(%) ??S(%) ??Ni+V+Nb+Ti(%) ??AlS(%) ??N(%)
??0.12 ??0.30 ??1.50 ??0.013 ??0.002 ??0.09-0.10 ??0.030 ??0.004
Embodiment 2
, slow cooling cold by converter smelting, LF refining, vacuum refinement, cast, heating, control, thermal treatment process obtain to be described in table 2 below the Q345qD Finished Steel of chemical ingredients, and wherein each processing parameter and mechanical property are seen as following table 4,5,6.
The chemical ingredients of table 2 embodiment 2 steel
??C(%) ??Si(%) ??Mn(%) ??P(%) ??S(%) ??Ni+V+Nb+Ti(%) ??AlS(%) ??N(%)
??0.11 ??0.28 ??1.50 ??0.011 ??0.001 ??0.09 ??0.020 ??≤0.006
Embodiment 3
, slow cooling cold by converter smelting, LF refining, vacuum refinement, cast, heating, control, thermal treatment process obtain to be described in table 2 below the Q345qD Finished Steel of chemical ingredients, and wherein each processing parameter and mechanical property are seen as following table 4,5,6.
The chemical ingredients of table 3 embodiment 3 steel
??C(%) ??Si(%) ??Mn(%) ??P(%) ??S(%) ??Ni+V+Nb+Ti(%) ??AlS(%) ??N(%)
??0.13 ??0.35 ??1.45 ??0.012 ??0.002 ??0.10 ??0.032 ??≤0.008
Operational path of the present invention
Molten iron KR desulfurization-converter smelting-LF is concise-VD vacuum outgas-die casting cast-steel ingot demoulding slow cooling-heating-dephosphorization-mill milling-ACC cooling-aligning-steel plate cooling in heap-surface inspection-finishing-normalizing thermal treatment-flaw detection-Performance Detection one warehouse-in.
1.1 steel-making part
1.1.1 composition design
The bridge structure steel is had relatively high expectations to intensity and welding property, makes the use of carbon equivalent be restricted, and for the thick bridge plate of spy, the composition design is more prudent and crucial.Maximum ga(u)ge in the GB/T714-2008 GB only is 100mm, expect the special thick bridge plate of 130mm, should rationally select micro alloying element for use, utilize the compound adding of best proportioning of Nb, V, Ti, Ni, give full play to precipitation strength and refined crystalline strengthening double effects, do not reducing under the flexible prerequisite, guaranteeing that every performance index of bridge plate reach the requirement of GB 50-100mm.In order to guarantee obdurability and welding property requirement, the composition design is taked the low-carbon high-manganese scheme, the steel grade [P] of keeping under strict control simultaneously, [S], [N], [H], [O] five big harmful element content.
1.1.2 compression ratio design
Owing to require to protect flaw detection, strict to performance index simultaneously, in conjunction with practical experience in the past, this compression ratio at least 〉=4, in conjunction with the steel ingot characteristics, select the 33t ingot shape more reasonable, the thick 820mm of this steel ingot microcephaly, the thick 960mm of major part, mean thickness 890mm, average compression ratio 6.85 reaches design requirements fully.
1.1.3 molten steel cleanliness factor
For obtaining internal soundness preferably, guarantee secondary flaw detection requirement, the smelting of Clean Steel is the basis, mainly guarantee from two aspects, the one, total rank of non-metallic inclusion in the molten steel (A, B, C, D four big classes) is controlled in 4.0, the 2nd, the content of five big harmful elements in the strict molten steel, concrete measure is: desulfurization taked for two steps walked, and taked molten iron pre-desulfurization technology to guarantee into stove molten iron S content≤0.005% on the one hand; Make white slag in the reinforcement of LF refining furnace on the other hand and carry out the secondary desulfurization.Deoxidation taked for two steps walked equally, and the deoxidation operation is strengthened in strict on the one hand control converter terminal C% content (preventing peroxidation), reinforcement pushing off the slag tapping, improves the molten steel purity; Make full use of the LF refining furnace on the other hand, adopt high temperature, high basicity, the abundant deoxidation of high quantity of slag suboxide iron slagging process; Moreover need prolongation dwell time under the VD vacuum condition fully outgases.In strict accordance with the Clean Steel production process route, guarantee that S, P, N, H, O five big harmful elements are controlled in the 160ppm.
1.1.4TMCP it is rolling
Adopt suitable burning steel temperature, burning the steel time is 13min/cm+60min, guarantee that micro alloying element melts at the fully solid of austenitic area, rough rolling step takes high temperature low speed to depress technology greatly, two-stage takes>and the steel thickness that dries in the air of 2.5H is rolling, ACC adopts suitable roller speed and the cooling rate of 5~15 ℃/S, to guarantee the effect of controlled rolling crystal grain thinning.
1.1.5 thermal treatment
Be further uniform formation, eliminate banded structure, crystal grain thinning improves the steel plate comprehensive mechanical property, adopts normalizing heat treatment technique to rolling the back steel plate, and normalizing temperature is chosen in Ar3+ (30-50 ℃) interval, adopts the soaking time of 2.2min/mm+30min.
2.2 ingot shape is selected
Conventional ingot casting has 24T, 26T, 32T, 33T, 43T and 48T, and the water cooled mo(u)ld ingot has 50T and 60T, selects the conventional die casting ingot shape of comparatively suitable 33T.
2.3 heating
Different heating cycles influences austenite original grain degree, and austenite original grain degree influences the grain size behind the recrystallize.Contain the higher Nb of content in Q345qD (E) steel, the carboritride that this type of steel temperature reaches niobium more than 900 ℃ just begins to decompose solid solution, make austenite crystal begin to grow up, more even to 1150 ℃ of grain growths, crystal grain was further grown up when temperature was brought up to 1200 ℃, and promptly so-called secondary recrystallization takes place.Therefore, for the steel after rolling have evenly tiny crystal grain, Heating temperature generally is advisable with about 1150 ℃.If be heated to 1050 ℃, austenite grain size inequality then makes and rolls the back steel and easily produce mixed crystal, if be heated to 1200 ℃ or higher, then crystal grain is excessively grown up, and makes to roll back steel crystal grain and be difficult to refinement, therefore, Heating temperature is set at 1100~1200 ℃, and soaking time is 13cm/min+60min.
2.4 controlled rolling and controlled cooling
Adopt (austenite recrystallization district, the austenite non-recrystallization district) controlled rolling of II stage.In fs rolling, mainly be static recrystallize, this stage makes the critical draft (simultaneously total deformation greater than 50%) of percentage pass reduction greater than static recrystallize as far as possible, and this specification steel plate is rolled with steel ingot in addition, for improving subsurface defect, adopt high temperature low speed to depress technology greatly.For avoiding rolling in part austenite recrystallization district, the two-stage start rolling temperature should be less than 950 ℃, give bigger accumulative total draft (total deformation 60%~80%) simultaneously, a suitable temperature thickness for the treatment of is promptly arranged, austenite fully is out of shape, form many deformation bands, increase deformed nucleus, reach the purpose of refinement ferrite and pearlitic grain.By above-mentioned distortion distribution principle, rolling back its intensity of steel improves, and brittle transition temperature reduces, low-temperature flexibility be improved significantly.
Be the austenite structure before the abundant refinement phase transformation, stop or postpone carbide and in process of cooling, separate out too early, its disperse in ferrite is separated out, improve intensity, reduce the size of pearlite colony simultaneously, the refine pearlite sheet interlayer spacing, improve the comprehensive mechanical property that steel comprise plasticity, toughness etc., after controlled rolling is finished, according to finished product thickness, rationally control ACC technology is carried out controlled chilling, guarantees that steel plate returns red temperature and is lower than Ar1.
Execution technology is as follows: the fs start rolling temperature is controlled between 1000~1200 ℃, and it is rolling to adopt high temperature low speed to depress greatly, and reduction in pass is not less than 40mm; When temperature is not less than 1000 ℃, stop rolling the steel that dries in the air, the steel thickness that dries in the air is 2-3 times of finished product thickness; When the rolled piece temperature was 860~920 ℃, the beginning subordinate phase was rolling, and reduction in pass is not less than 30mm, and last three percentage pass reductions 〉=15% increases progressively by the road; Finishing temperature is controlled at 800~860 ℃; The rolling back that finishes adopts the ACC control cold, and final cooling temperature is controlled between 650~750 ℃, is sent to the straightener aligning then.
2.5 cooling in heap technology
Adopt high temperature cooling in heap technology can effectively avoid to reduce the content of hydrogen in the steel plate simultaneously greatly, improve the steel plate inspection defective because of cooling off the unrelieved stress that produces fast.Temperature before the steel plate stacking slow cooling should be higher than 300 ℃, the content of hydrogen, steel plate initial temperature and steel plate thickness etc. in the stacking slow cooling basis of time steel plate and decide.
2.6 thermal treatment process
Execution technology is holding temperature: holding temperature: 910 ± 30 ℃; Heat-up time: 1.5-2.5min/mm; The type of cooling: air cooling or air-cooled.
Trial result is analyzed
3.1 Composition Control analysis
For guaranteeing good welding property, should control carbon equivalent Ceq about 0.38, carbon is as one of strengthening element, and limit control in adopting in composition design internal control scope in the time of the proof strength performance, does not cause deterioration to welding property; Mn is one of crystal grain thinning element, in order to improve intensity, reduces the steel brittle transition temperature, improves low-temperature impact toughness, but that Mn content is difficult for is too high, otherwise unfavorable to toughness and welding property, so Mn content is controlled at about 1.5%.The Nb element has significant crystal grain thinning effect, and the over-all properties of improving steel is apparent in view, but Nb content makes easily in the strand process of cooling and produce surface crack when high, preferably helps controlling the surface quality of continuously cast bloom with V, the compound adding of Ti alloy.So control of Nb, V, Ti.P, S content are controlled in the lower scope.In a word, whole Composition Control is stable, satisfies the design requirements of Q345qD (E) composition.
3.2 mechanical mechanics property analysis
This produces 20 crowdes of the thick Q345Qd of 130mm (E) altogether as a trial, because Q345qD (E) has adopted Ni+V+Nb+Ti combined microalloying composition system, in the operation of rolling with micro-alloying technology and the effective combination of TMCP technology, give full play to the refined crystalline strengthening effect of microalloy element, improved steel plate obdurability index effectively, wherein: yield strength is controlled at 315~350MPa, has on average reached 335MPa, than the rich 40MPa of standard; Tensile strength is controlled at 490~515MPa, has on average reached 500MPa, than the rich 30MPa of standard; Elongation is controlled at 29%-32%, on average reaches 28%, than standard affluence 8%;-20 ℃ of impact of collision power controls have on average reached 178J built in 144~256J, and performance index have satisfied Q345Qd (E) development requires, and table 4 is Q345qD (E) performance level in kind.Simultaneously in order further to understand the in kind real performance level of this time experiment, to the steel plate of this time experiment carried out thickness Z to stretch ,-40 ℃ of indexs such as impact detect, detected result sees Table 5.The result shows, the special thick Q345qD bridge plate of this exploitation has reached the level of E level, Z15.
Table 4 the present invention test-manufactures the thick bridge structure of 130mm rigidity energy
Figure BSA00000155009100101
Table 5 the present invention test-manufactures the thick bridge structure of 130mm steel additional properties level detection
Figure BSA00000155009100102
3.3 mirco structure analysis
Fig. 2 is the thickness of slab 1/4 place high power metallographic structure figure of the rolling back of TMCP steel plate, and display organization is ferrite and perlite as a result, 1.5 grades of banded structures, grain fineness number 6-7 level.Fig. 3 shows that for the thickness of slab 1/4 place high power metallographic structure figure of steel plate after the thermal treatment, result banded structure disappears, 9 grades of grain fineness numbers.Show according to data; continuous reduction along with the Bridge Steel carbon content; standard weave is also developed to acicular ferrite and bainite and full bainite direction by ferrite and perlite; this low-carbon micro steel-alloy can obtain a series of tissues usually when cooling off continuously: polygonal ferrite, quasi-polygonal ferrite, acicular ferrite, granular bainite, ferrite bainite and M/A tissue etc.; the carbon content of this test is substantially more than 0.10%, and what obtain after TMCP is rolling is conventional ferrite and pearlitic structure.

Claims (12)

1. the thick Q345q Series Bridge of spy steel plate is characterized in that described steel plate comprises following chemical components in mass percent: C:0.08~0.16, Si:0.20~0.50, Mn:1.15~1.60, P :≤0.020, S :≤0.010, micro alloying element (V+Nb+Ti+Ni) :≤0.12, AlS:0.010~0.050, other is Fe and relict element; Carbon equivalent :≤0.43.
2. the special thick bridge steel plate of Q345q series as claimed in claim 1, the thickness that it is characterized in that the special thick bridge steel plate of described Q345q series is more than 100mm.
3. the production method of the thick Q345q Series Bridge of spy as claimed in claim 1 or 2 steel plate steel plate comprises that converter smelting, LF refining, vacuum refinement, cast, heating, control are cold, slow cooling, thermal treatment.
4. the production method of the thick Q345q Series Bridge of spy as claimed in claim 3 steel plate steel plate, in described converter smelting, tapping carbon 〉=0.06%, tapping P≤0.012%, S≤0.012%; Point blows number of times and must not avoid slag under the tapping process greater than 2 times.
5. the production method of the thick Q345q Series Bridge of spy as claimed in claim 3 steel plate steel plate is characterized in that taking the big quantity of slag to carry out slag making in described LF refining, guarantees that the white slag hold-time is controlled at more than the 15min.
6. the production method of the thick Q345q Series Bridge of spy as claimed in claim 3 steel plate steel plate is characterized in that in described vacuum refinement, and the dwell time under≤67Pa is controlled by 〉=10min.
7. the production method of the thick Q345q Series Bridge of spy as claimed in claim 3 steel plate steel plate is characterized in that pining in described adding, and the holding temperature of dead soaking pit is controlled at 1200 ℃~1300 ℃.
8. the production method of the thick Q345q Series Bridge of spy as claimed in claim 3 steel plate steel plate is characterized in that the fs start rolling temperature is controlled between 1000~1200 ℃, and it is rolling to adopt high temperature low speed to depress greatly, and reduction in pass is not less than 40mm; When temperature is not less than 1000 ℃, stop rolling the steel that dries in the air, the steel thickness that dries in the air is 2-3 times of finished product thickness.
9. the production method of the thick Q345q Series Bridge of spy as claimed in claim 3 steel plate steel plate, it is characterized in that when the rolled piece temperature is 860~920 ℃ the beginning subordinate phase is rolling, reduction in pass is not less than 30mm, last three percentage pass reductions 〉=15% increases progressively by the road; Finishing temperature is controlled at 800~860 ℃; The rolling back that finishes adopts the ACC control cold.
10. the production method of the thick Q345q Series Bridge of spy as claimed in claim 3 steel plate steel plate is characterized in that in described control is cold, returns red temperature<740 ℃, and cooling rate is controlled at 5~15 ℃/s.
11. the production method of the thick Q345q Series Bridge of spy as claimed in claim 3 steel plate steel plate is characterized in that in described slow cooling, goes into burial pit temperature 〉=300 ℃; Cooling in heap time 〉=24 hour.
12. the production method of the special thick bridge steel plate of Q345q series as claimed in claim 3 is characterized in that in described thermal treatment holding temperature: 910 ± 30 ℃; Heat-up time: 1.5-2.5min/mm; The type of cooling: air cooling or air-cooled.
CN2010102083053A 2010-06-14 2010-06-14 Q345q-series super-thick bridge steel plate and production method thereof Active CN101880824B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010102083053A CN101880824B (en) 2010-06-14 2010-06-14 Q345q-series super-thick bridge steel plate and production method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010102083053A CN101880824B (en) 2010-06-14 2010-06-14 Q345q-series super-thick bridge steel plate and production method thereof

Publications (2)

Publication Number Publication Date
CN101880824A true CN101880824A (en) 2010-11-10
CN101880824B CN101880824B (en) 2012-05-23

Family

ID=43052964

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010102083053A Active CN101880824B (en) 2010-06-14 2010-06-14 Q345q-series super-thick bridge steel plate and production method thereof

Country Status (1)

Country Link
CN (1) CN101880824B (en)

Cited By (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002630A (en) * 2010-11-29 2011-04-06 南阳汉冶特钢有限公司 Q345R-Z35 super-thick steel plate resisting HIC (hydrogen induced crack) pressure vessel and production method thereof
CN102021478A (en) * 2010-12-27 2011-04-20 马鞍山钢铁股份有限公司 High-toughness high-weather-resistance bridge steel and plate coil rolling method thereof
CN102041447A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Q345C steel plate and production method thereof
CN102041438A (en) * 2010-12-22 2011-05-04 南阳汉冶特钢有限公司 Low-alloy high-strength structural-steel extra-thick board Q460C and production method thereof
CN102041435A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Hot rolling steel plate made of weldable fine grain structural steel S355ML and production method thereof
CN102041437A (en) * 2010-12-22 2011-05-04 南阳汉冶特钢有限公司 160mm-thick Q345E-Z35 steel plate for high-rise buildings and production method thereof
CN102041433A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 X70 steel plate for low-cost pipe fittings and production method thereof
CN102041441A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Low-alloy medium-thickness steel plate Q345D-Z35 and production process thereof
CN102041436A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Steel plate for low-alloy high-strength structured steel Q460C and production method thereof
CN102041434A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Steel plate for low-alloy high-strength structured steel Q460E-Z35 and production method thereof
CN102041432A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Q420GJD-Z35 steel plate with thickness of less than or equal to 60 millimeters for high-rise building and production method thereof
CN102051525A (en) * 2010-12-07 2011-05-11 秦皇岛首秦金属材料有限公司 Method for producing steel plate used for Q420qE bridge at low cost
CN102051522A (en) * 2010-12-21 2011-05-11 南阳汉冶特钢有限公司 Steel plate made of bainite structure high-strength toughness structural steel Q550D(E) and production method thereof
CN102061426A (en) * 2010-12-21 2011-05-18 南阳汉冶特钢有限公司 400-420mm large-thickness low-alloy high-strength constructional steel and production method thereof
CN102061424A (en) * 2010-12-21 2011-05-18 南阳汉冶特钢有限公司 Super-thick Q390GJC-Z35 steel plate for high-rise buildings and production method thereof
CN102080185A (en) * 2010-12-21 2011-06-01 南阳汉冶特钢有限公司 High-tensile quenched and tempered steel plate for large-thickness structures and production method thereof
CN102080182A (en) * 2010-12-27 2011-06-01 南阳汉冶特钢有限公司 High-strength steel plate Q460GJE-Z35 for extra-thick high-rise building structure and production method thereof
CN102080186A (en) * 2010-12-22 2011-06-01 南阳汉冶特钢有限公司 Crack-free steel Q245R medium-thickness plate for pressure container and production method
CN102080184A (en) * 2010-12-21 2011-06-01 南阳汉冶特钢有限公司 75-mm Z15 series steel plate prepared by rolling 250-mm casting blank and production method of 75-mm Z15 series steel plate
CN102080183A (en) * 2010-12-29 2011-06-01 南阳汉冶特钢有限公司 Q345GJ series structural steel plates for ultra-thick building and production method thereof
CN102091727A (en) * 2010-12-21 2011-06-15 南阳汉冶特钢有限公司 Method for improving internal quality of medium plate
CN102151696A (en) * 2010-12-28 2011-08-17 西部钛业有限责任公司 Temperature control rolling method for Q345 steel plate
CN102337456A (en) * 2011-09-30 2012-02-01 内蒙古包钢钢联股份有限公司 Thick bridge steel plate and rolling method thereof
CN102345063A (en) * 2011-07-08 2012-02-08 南阳汉冶特钢有限公司 Structural steel plate Q345Qdz35 steel for extra-thick bridge and production method thereof
CN102345049A (en) * 2011-06-28 2012-02-08 南阳汉冶特钢有限公司 Low alloy Q345C-Z35 thick plate and production method thereof
CN102367538A (en) * 2011-12-21 2012-03-07 南阳汉冶特钢有限公司 Super-thick low alloy high strength Q345C steel plate and production method thereof
CN102560243A (en) * 2011-12-02 2012-07-11 内蒙古包钢钢联股份有限公司 Rolling method for Q345 steel plate with thickness of 50-100mm
CN102605241A (en) * 2011-12-30 2012-07-25 内蒙古包钢钢联股份有限公司 Normalizing type 16MnDR low temperature pressure vessel steel plate and manufacturing method thereof
CN103045939A (en) * 2012-12-27 2013-04-17 安阳钢铁股份有限公司 Resource-saving Q345 low-alloy series steel plate and production method thereof
CN103157671A (en) * 2013-03-16 2013-06-19 南阳汉冶特钢有限公司 Method of improving steel plate quality
CN104018060A (en) * 2014-05-23 2014-09-03 内蒙古包钢钢联股份有限公司 Guaranteed crack detection and guaranteed performance Q345B steel plate with thickness of 150mm and production method thereof
CN104164621A (en) * 2014-07-25 2014-11-26 武汉钢铁(集团)公司 Extremely thick bridge anchor steel-plate with low compression ratio and production method
CN104471098A (en) * 2012-12-04 2015-03-25 “奥穆特宁斯克冶金厂”封闭式股份公司 Low-alloy, high-strength structural steel
CN105063472A (en) * 2015-08-07 2015-11-18 舞阳钢铁有限责任公司 Low-cost 345 Mpa level low-alloy steel sheet and production method thereof
CN105256218A (en) * 2015-11-10 2016-01-20 湖南华菱湘潭钢铁有限公司 Production method of ultra-thick low-alloy steel plate
CN105969964A (en) * 2016-06-27 2016-09-28 舞阳钢铁有限责任公司 Production method for high-toughness ultra-thick steel plate at position half of plate thickness
WO2017181632A1 (en) * 2016-04-19 2017-10-26 江阴兴澄特种钢铁有限公司 Low compression ratio, high-performance, and super-thick steel plate produced using continuous billet casting, and manufacturing method thereof
CN107326162A (en) * 2017-06-08 2017-11-07 舞阳钢铁有限责任公司 A kind of production method of normalized steel
CN107557690A (en) * 2016-06-30 2018-01-09 鞍钢股份有限公司 The super-thick steel plate and its manufacture method of a kind of low temperature resistant and anti-lamellar tearing
CN108165703A (en) * 2017-11-24 2018-06-15 南阳汉冶特钢有限公司 It is a kind of to improve the production technology without Dehydroepiandrosterone derivative billet rolling slab flaw detection quality
CN108660381A (en) * 2018-08-10 2018-10-16 武汉钢铁集团鄂城钢铁有限责任公司 A kind of low-cost manufacture method for protecting Q345B grades of steel plates of flaw detection
CN109663816A (en) * 2018-11-19 2019-04-23 包头钢铁(集团)有限责任公司 A method of improving the thickness and precision of bridge steel plate steel plate
CN110586649A (en) * 2019-09-18 2019-12-20 舞阳钢铁有限责任公司 Production method of ultra-thick corrosion-resistant support rib plate
CN111254350A (en) * 2020-01-21 2020-06-09 宝钢湛江钢铁有限公司 Thin single-rolled steel plate for low-yield-ratio high-toughness bridge and manufacturing method thereof
CN111621716A (en) * 2020-05-14 2020-09-04 河北普阳钢铁有限公司 Nb-containing low alloy steel rolling process
CN112126847A (en) * 2020-07-31 2020-12-25 天津钢铁集团有限公司 Large-thickness Q420FTE high-strength steel plate for wind tower structure and production method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114540580A (en) * 2022-03-11 2022-05-27 新疆八一钢铁股份有限公司 Production method of low-cost Q345Q series bridge steel plate

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1970811A (en) * 2005-11-25 2007-05-30 鞍钢股份有限公司 High-strength cold-roll-forming structural steel and method for producing same
CN101323929A (en) * 2007-06-14 2008-12-17 舞阳钢铁有限责任公司 High strength steel plate for big thickness tall building structure and production method thereof
CN101705423A (en) * 2009-11-25 2010-05-12 首钢总公司 Low-cost steel plate for building structure and manufacturing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1970811A (en) * 2005-11-25 2007-05-30 鞍钢股份有限公司 High-strength cold-roll-forming structural steel and method for producing same
CN101323929A (en) * 2007-06-14 2008-12-17 舞阳钢铁有限责任公司 High strength steel plate for big thickness tall building structure and production method thereof
CN101705423A (en) * 2009-11-25 2010-05-12 首钢总公司 Low-cost steel plate for building structure and manufacturing method thereof

Cited By (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002630A (en) * 2010-11-29 2011-04-06 南阳汉冶特钢有限公司 Q345R-Z35 super-thick steel plate resisting HIC (hydrogen induced crack) pressure vessel and production method thereof
CN102051525A (en) * 2010-12-07 2011-05-11 秦皇岛首秦金属材料有限公司 Method for producing steel plate used for Q420qE bridge at low cost
CN102061426B (en) * 2010-12-21 2012-10-03 南阳汉冶特钢有限公司 400-420mm large-thickness low-alloy high-strength constructional steel and production method thereof
CN102080184A (en) * 2010-12-21 2011-06-01 南阳汉冶特钢有限公司 75-mm Z15 series steel plate prepared by rolling 250-mm casting blank and production method of 75-mm Z15 series steel plate
CN102041435A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Hot rolling steel plate made of weldable fine grain structural steel S355ML and production method thereof
CN102091727B (en) * 2010-12-21 2012-12-05 南阳汉冶特钢有限公司 Method for improving internal quality of medium plate
CN102041433A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 X70 steel plate for low-cost pipe fittings and production method thereof
CN102041441A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Low-alloy medium-thickness steel plate Q345D-Z35 and production process thereof
CN102041436A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Steel plate for low-alloy high-strength structured steel Q460C and production method thereof
CN102041434A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Steel plate for low-alloy high-strength structured steel Q460E-Z35 and production method thereof
CN102041432A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Q420GJD-Z35 steel plate with thickness of less than or equal to 60 millimeters for high-rise building and production method thereof
CN102041447A (en) * 2010-12-21 2011-05-04 南阳汉冶特钢有限公司 Q345C steel plate and production method thereof
CN102051522A (en) * 2010-12-21 2011-05-11 南阳汉冶特钢有限公司 Steel plate made of bainite structure high-strength toughness structural steel Q550D(E) and production method thereof
CN102061426A (en) * 2010-12-21 2011-05-18 南阳汉冶特钢有限公司 400-420mm large-thickness low-alloy high-strength constructional steel and production method thereof
CN102061424A (en) * 2010-12-21 2011-05-18 南阳汉冶特钢有限公司 Super-thick Q390GJC-Z35 steel plate for high-rise buildings and production method thereof
CN102080185A (en) * 2010-12-21 2011-06-01 南阳汉冶特钢有限公司 High-tensile quenched and tempered steel plate for large-thickness structures and production method thereof
CN102061424B (en) * 2010-12-21 2012-10-03 南阳汉冶特钢有限公司 Super-thick Q390GJC-Z35 steel plate for high-rise buildings and production method thereof
CN102091727A (en) * 2010-12-21 2011-06-15 南阳汉冶特钢有限公司 Method for improving internal quality of medium plate
CN102041438A (en) * 2010-12-22 2011-05-04 南阳汉冶特钢有限公司 Low-alloy high-strength structural-steel extra-thick board Q460C and production method thereof
CN102041437A (en) * 2010-12-22 2011-05-04 南阳汉冶特钢有限公司 160mm-thick Q345E-Z35 steel plate for high-rise buildings and production method thereof
CN102080186A (en) * 2010-12-22 2011-06-01 南阳汉冶特钢有限公司 Crack-free steel Q245R medium-thickness plate for pressure container and production method
CN102041438B (en) * 2010-12-22 2012-10-03 南阳汉冶特钢有限公司 Low-alloy high-strength structural-steel extra-thick board Q460C and production method thereof
CN102041437B (en) * 2010-12-22 2013-06-12 南阳汉冶特钢有限公司 160mm-thick Q345E-Z35 steel plate for high-rise buildings and production method thereof
CN102021478A (en) * 2010-12-27 2011-04-20 马鞍山钢铁股份有限公司 High-toughness high-weather-resistance bridge steel and plate coil rolling method thereof
CN102080182A (en) * 2010-12-27 2011-06-01 南阳汉冶特钢有限公司 High-strength steel plate Q460GJE-Z35 for extra-thick high-rise building structure and production method thereof
CN102151696A (en) * 2010-12-28 2011-08-17 西部钛业有限责任公司 Temperature control rolling method for Q345 steel plate
CN102080183A (en) * 2010-12-29 2011-06-01 南阳汉冶特钢有限公司 Q345GJ series structural steel plates for ultra-thick building and production method thereof
CN102345049A (en) * 2011-06-28 2012-02-08 南阳汉冶特钢有限公司 Low alloy Q345C-Z35 thick plate and production method thereof
CN102345063A (en) * 2011-07-08 2012-02-08 南阳汉冶特钢有限公司 Structural steel plate Q345Qdz35 steel for extra-thick bridge and production method thereof
CN102337456A (en) * 2011-09-30 2012-02-01 内蒙古包钢钢联股份有限公司 Thick bridge steel plate and rolling method thereof
CN102560243A (en) * 2011-12-02 2012-07-11 内蒙古包钢钢联股份有限公司 Rolling method for Q345 steel plate with thickness of 50-100mm
CN102367538A (en) * 2011-12-21 2012-03-07 南阳汉冶特钢有限公司 Super-thick low alloy high strength Q345C steel plate and production method thereof
CN102605241A (en) * 2011-12-30 2012-07-25 内蒙古包钢钢联股份有限公司 Normalizing type 16MnDR low temperature pressure vessel steel plate and manufacturing method thereof
CN104471098A (en) * 2012-12-04 2015-03-25 “奥穆特宁斯克冶金厂”封闭式股份公司 Low-alloy, high-strength structural steel
CN104471098B (en) * 2012-12-04 2017-11-07 Ao奥穆特宁斯克冶金厂 Low-alloy high-tensile structural steel
CN103045939A (en) * 2012-12-27 2013-04-17 安阳钢铁股份有限公司 Resource-saving Q345 low-alloy series steel plate and production method thereof
CN103157671A (en) * 2013-03-16 2013-06-19 南阳汉冶特钢有限公司 Method of improving steel plate quality
CN104018060A (en) * 2014-05-23 2014-09-03 内蒙古包钢钢联股份有限公司 Guaranteed crack detection and guaranteed performance Q345B steel plate with thickness of 150mm and production method thereof
CN104164621A (en) * 2014-07-25 2014-11-26 武汉钢铁(集团)公司 Extremely thick bridge anchor steel-plate with low compression ratio and production method
CN104164621B (en) * 2014-07-25 2016-05-04 武汉钢铁(集团)公司 A kind of spy's thick bridge anchor pading plate and production method thereof of low compression ratio
CN105063472A (en) * 2015-08-07 2015-11-18 舞阳钢铁有限责任公司 Low-cost 345 Mpa level low-alloy steel sheet and production method thereof
CN105256218A (en) * 2015-11-10 2016-01-20 湖南华菱湘潭钢铁有限公司 Production method of ultra-thick low-alloy steel plate
WO2017181632A1 (en) * 2016-04-19 2017-10-26 江阴兴澄特种钢铁有限公司 Low compression ratio, high-performance, and super-thick steel plate produced using continuous billet casting, and manufacturing method thereof
CN105969964A (en) * 2016-06-27 2016-09-28 舞阳钢铁有限责任公司 Production method for high-toughness ultra-thick steel plate at position half of plate thickness
CN107557690B (en) * 2016-06-30 2019-03-26 鞍钢股份有限公司 The super-thick steel plate and its manufacturing method of a kind of low temperature resistant and anti-lamellar tearing
CN107557690A (en) * 2016-06-30 2018-01-09 鞍钢股份有限公司 The super-thick steel plate and its manufacture method of a kind of low temperature resistant and anti-lamellar tearing
CN107326162A (en) * 2017-06-08 2017-11-07 舞阳钢铁有限责任公司 A kind of production method of normalized steel
CN108165703A (en) * 2017-11-24 2018-06-15 南阳汉冶特钢有限公司 It is a kind of to improve the production technology without Dehydroepiandrosterone derivative billet rolling slab flaw detection quality
CN108165703B (en) * 2017-11-24 2019-11-22 南阳汉冶特钢有限公司 A kind of production technology improved without Dehydroepiandrosterone derivative billet rolling slab flaw detection quality
CN108660381A (en) * 2018-08-10 2018-10-16 武汉钢铁集团鄂城钢铁有限责任公司 A kind of low-cost manufacture method for protecting Q345B grades of steel plates of flaw detection
CN108660381B (en) * 2018-08-10 2019-11-05 武汉钢铁集团鄂城钢铁有限责任公司 A kind of low-cost manufacture method for protecting Q345B grades of steel plates of flaw detection
CN109663816A (en) * 2018-11-19 2019-04-23 包头钢铁(集团)有限责任公司 A method of improving the thickness and precision of bridge steel plate steel plate
CN110586649A (en) * 2019-09-18 2019-12-20 舞阳钢铁有限责任公司 Production method of ultra-thick corrosion-resistant support rib plate
CN111254350A (en) * 2020-01-21 2020-06-09 宝钢湛江钢铁有限公司 Thin single-rolled steel plate for low-yield-ratio high-toughness bridge and manufacturing method thereof
CN111621716A (en) * 2020-05-14 2020-09-04 河北普阳钢铁有限公司 Nb-containing low alloy steel rolling process
CN111621716B (en) * 2020-05-14 2021-10-01 河北普阳钢铁有限公司 Nb-containing low alloy steel rolling process
CN112126847A (en) * 2020-07-31 2020-12-25 天津钢铁集团有限公司 Large-thickness Q420FTE high-strength steel plate for wind tower structure and production method thereof

Also Published As

Publication number Publication date
CN101880824B (en) 2012-05-23

Similar Documents

Publication Publication Date Title
CN101880824B (en) Q345q-series super-thick bridge steel plate and production method thereof
CN105839003B (en) A kind of 180~200mm thickness EH36 steel plates of normalizing state delivery and preparation method thereof
CN106756543B (en) A kind of TMCP states low cost Large Heat Input Welding high strength ship plate steel and its manufacturing method
CN101008066B (en) Hot rolling martensite steel plate with tensile strength higher than 1000Mpa and its production method
CN105463324B (en) A kind of thick-specification high-tenacity pipe line steel and its manufacture method
CN101985722B (en) Pipeline steel plate with low yield ratio, fine grains and high strength and production method thereof
CN106498278B (en) A kind of cut deal of high-strength high-elongation ratio low-density and preparation method thereof
CN108546885B (en) A kind of the L555M pipe line steel and its manufacturing method of excellent in low temperature toughness
CN108914006B (en) Ultrahigh-strength quenched and tempered steel plate with excellent performance in thickness direction and manufacturing method thereof
CN102041437B (en) 160mm-thick Q345E-Z35 steel plate for high-rise buildings and production method thereof
CN103014554A (en) Low-yield-ratio high-tenacity steel plate and manufacture method thereof
CN104328356A (en) Manufacturing method of thin-specification high-strength-structure steel plate with steckel mill
CN102051522A (en) Steel plate made of bainite structure high-strength toughness structural steel Q550D(E) and production method thereof
CN108950388A (en) A kind of the L485M pipe line steel and its manufacturing method of excellent in low temperature toughness
CN106498296A (en) A kind of manufacture method of yield strength 1100MPa level high-strength steel
CN112553532A (en) High-toughness reduced ship plate marine steel and preparation method thereof
CN104372257A (en) Low-alloy high-strength middle-thickness plate capable of utilizing self-tempering waste heat to improve toughness and preparation method of low-alloy high-strength middle-thickness plate
CN102080184A (en) 75-mm Z15 series steel plate prepared by rolling 250-mm casting blank and production method of 75-mm Z15 series steel plate
CN101270436B (en) Hot-rolled polyphase steel plate and method for manufacturing same
CN109207854A (en) The Marine Engineering Steel and its manufacturing method of ultra-wide size high-tensile high-ductility performance
CN105838996A (en) 800MPa-grade high-strength and weather-proof steel plate and production method thereof
CN102345063A (en) Structural steel plate Q345Qdz35 steel for extra-thick bridge and production method thereof
CN102925799A (en) Production method of ultrahigh-strength steel plate
CN102400041A (en) Extra-thick, low-alloy and high-strength Q390D-Z35 steel plate and production method thereof
CN102191430A (en) Easy welding steel plate with yield strength of 550MPa and high toughness and manufacturing method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant