CN101861136B - Wet forming compact composition containing volatile silicone oil and silicone resin - Google Patents
Wet forming compact composition containing volatile silicone oil and silicone resin Download PDFInfo
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- CN101861136B CN101861136B CN2008801165466A CN200880116546A CN101861136B CN 101861136 B CN101861136 B CN 101861136B CN 2008801165466 A CN2008801165466 A CN 2008801165466A CN 200880116546 A CN200880116546 A CN 200880116546A CN 101861136 B CN101861136 B CN 101861136B
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
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- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Disclosed herein is a cake-type, wet-molded compact cosmetic composition. More specifically, disclosed is a cake- type, wet-molded compact cosmetic composition which is prepared by wet molding using a mixed solvent of volatile silicone oil and silicone resin so as to have excellent durability and a soft touch feel.
Description
Technical field
The present invention relates to densification (compact) cosmetic composition a kind of pie (cake-type), wet moulding (wet-molded); Particularly carry out densification cosmetic compositions pie, wet moulding that wet moulding prepares, thereby make said composition have good durability and softish sense of touch through the mixed solvent that utilizes volatile silicone oils (volatile silicone oil) and organic siliconresin (silicone resin).
Background technology
The fine and close cosmetic product of conventional pie uses conventional methods preparation; This traditional method is included in the agitator mixes extender pigment (extender pigment), pigment and Chinese white, and on the surface of mixture spray adhesive (binder).Yet well-known is to utilize this mixed method to be difficult to realize uniform mixing.For overcoming such shortcoming, developed so-called re-injection method (back-injection method), this method is the method (wet molding method) of wet moulding.
In the early stage of development of wet moulding method, the re-injection method was used widely in nineteen nineties.Application about the re-injection method; Pie, the densification cosmetic compositions be through in the mixed solvent that the powder (powdercontent) of densification (in vinyl disc before the molding) is dispersed in isopropyl alcohol (IPA) and water with preparation pulpous state material (slurry-type content); Through the re-injection method said pulpous state material is seated in the vinyl disc again; Draw certain amount of solvent through suction machine (sucking machine), then said pulpous state cake is placed in the exsiccator to remove remaining solvent.This technology also once was widely used in preparing eye shadow cream (eye shadow) and kermes (blushers).In addition; Because make water and isopropyl alcohol as solvent; So the problem that said fine and close cosmetic product exists is; The hydrophilic of solvent makes it be difficult to hold a large amount of powder that is coated with polydimethylsiloxane (dimethylpolysiloxane) or alkyl silane (alkylsilane) with homodisperse form, so durability is low.
Recently, for the homodisperse of the powder guaranteeing to apply with make the powder that holds a large amount of coatings become possibility, in wet moulding, use emulsifying agent to substitute the mixed solvent of isopropyl alcohol and water, thereby improve the durability of fine and close cosmetics.Yet, used emulsifying agent owing to contain the fine and close cosmetics of the powder of a large amount of coatings, therefore, can reduce resistance when using this densification cosmetic product for a long time, thereby seem greasy and blackout sebum and perspiration.
Open No 1999-40922 of Korean Patent and 2003-50531, the open No H3-204806 of Japan Patent and the open No 2005-0142089 of United States Patent (USP) disclose the compositions of utilizing silicone oil and organic siliconresin preparation.The prescription of these compositionss is liquid type foundation cream (liquid-type foundation) or bottoming breast (makeup bases).Under the situation of said liquid type foundation cream, generally emulsifying agent must be used so that oil and water disperse equably.But as stated, because the use of emulsifying agent, said liquid type foundation cream has reduced the resistance to sebum and perspiration when long-time the use, thereby seems greasy and blackout.
Summary of the invention
Therefore, through research repeatedly, the present invention has developed a kind of densification cosmetic compositions with wet moulding of softish sense of touch and good durability; The result finds; The bottoming powder (makeup powder) that can will apply through the mixed solvent that uses silicone oil and organic siliconresin is evenly dispersed in the starch (slurrypowder), and need not use emulsifying agent, thereby has improved durability; Make this dispersion molding again; And the drying of materials that makes this molding to be removing said mixed solvent, thereby makes densification cosmetic compositions wet moulding, pie, thereby accomplished the present invention.
Therefore, the purpose of this invention is to provide a kind of densification cosmetic compositions with wet moulding of good durability and softish sense of touch.
For reaching above-mentioned target, the invention provides a kind of densification cosmetic compositions of wet moulding, this cosmetic composition contains the bottoming powder of coating, and this cosmetic composition uses the mixed solvent of volatile silicone oils and organic siliconresin and makes.
More particularly; Contain basis bottoming powder and organic siliconresin according to densification cosmetic compositions of the present invention; And the gross weight with before the said composition wet moulding is a benchmark; The volatile silicone oils through using 30-40 weight % and the mixed solvent of organic siliconresin with the bottoming powder of the coating of 60-70 weight % be dispersed in slurry mutually in, make this sizing material forming again, and the drying of materials that makes this molding is to remove used volatile silicone oils.
Through following detailed description, above-mentioned and other target of the present invention, feature and advantage to one skilled in the art, are conspicuous.
Densification cosmetic compositions according to said wet moulding of the present invention makes through the mixed solvent that uses volatile silicone oils and organic siliconresin; And need not use any emulsifying agent; Therefore, said cosmetic composition has excellent durability, shows softish sense of touch simultaneously.
The specific embodiment
Hereinafter, the present invention is with describing in further detail.
In the present invention, for the densification cosmetic compositions that makes wet moulding has good durability and softish sense of touch, the powder coated material (power coating substance) and the selection of solvent types are very important.
In the present invention, in order to prepare the densification cosmetic compositions of wet moulding, use the bottoming powder that is coated with coating substance with good resistance to water and oil resistivity with softish sense of touch and excellent durability.
General polydimethylsiloxane with resistance to water and oil resistivity and the alkyl silane of adopting is as coating substance, and still scope of the present invention is not limited thereto.Yet, in order to improve durability, the preferred powder that uses through wet-process coating (wet coating) preparation.In general, through selecting the amount of powder that will apply and the coating substance of wanting, in solvent, mix this powder and this coating substance, flush away perhaps evaporates this solvent and makes to have only said coating substance to be retained on the said powder, then to the powder heat treatment.
Simultaneously, the composition that is used for the bottoming powder of foundation cream product (makeup product) traditionally can comprise extender pigment, pigment and Chinese white.Especially, can use Talcum, Muscovitum, sericite, tripoli, nylon powder, silica flour, polymethyl methacrylate (PMMA), boron nitride powder and Barium Sulfate, but scope of the present invention is not limited in this.
According to said densification cosmetic compositions of the present invention, be benchmark with the gross weight of said compositions, the content of the bottoming powder of said coating is preferably 60-70 weight %.If the content of the bottoming powder of said coating is lower than 60 weight %, then this powder can flow out in forming process, thereby causes the problem of mouldability; And if be higher than 70 weight %, then the powder of this coating is difficult to homodisperse.In addition, said powder composition is the powder that is coated with silicones or alkyl silane, and this powder composition refers to the pie powder in the step before the molding, and this powdery components contains extender pigment, pigment, Chinese white and spice.
In the present invention, for the bottoming powder that makes said coating be evenly dispersed in slurry mutually in, use solvent through volatile silicone oils and organic siliconresin are obtained with weight ratio mixing in 97: 3 to 99: 1.
According to the densification cosmetic compositions of said wet moulding of the present invention, be benchmark with the gross weight of said compositions, the content of said solvent is preferably 30-40 weight %.If the content of said solvent is lower than 30 weight %; Then the bottoming powder of said coating can not uniform distribution, and if said content is higher than 40 weight %, the problem of mouldability then can appear; Even with said composition molding, also the crack can appear when drying.
To one skilled in the art, volatile silicone oils used in the present invention can easily be selected from commercially available product.The example that can be used for volatile silicone oils in the present invention includes but not limited to available from the dimethicone DC 200 (0.65cs) of Dow Corning Corporation (Dow Corning) with available from the cyclomethicone DC 345 of Dow Corning Corporation.
In the present invention, in order when improving durability, to keep pie, use trimethylsiloxy group silicate (trimethylsiiloxysilicate) as said organic siliconresin.To one skilled in the art, said trimethylsiloxy group silicate can easily be selected from commercially available product.The example that can be used for the present invention's trimethylsiloxy group silicate includes but not limited to KF-7312F, KF-7312J, KF-7312K, KF-9001, X-21-5249, KF-9002, X-21-5250 and KF-9021 available from Japanese Shinetsu.
Hereinafter, will describe the method for the wet moulding of mixture according to the present invention.
At first, put into general agitator to the mixed solvent of volatile silicone oils and organic siliconresin with the bottoming powder of coating and seal.Make about 5 minutes of the contents mixed of said agitator; A certain amount of mixture is loaded in the forming disk (molding dish); And carry out molding with the molding cloth that is applied to said forming disk (molding cloth), with absorption with remove the said solvent of about 30-60%.Then, the material of said molding was descended dry 2-12 hour, to remove remaining solvent fully in exsiccator at 60-150 ℃.
The compact composition of said wet moulding of the present invention can have conventional formulation, and said composition has good durability and softish sense of touch.For example, said composition can be processed the form of paired cake (twin cake), powder box (compact), muffin (powder compact) and the close powder of compression (pressed powder).Compositions with each these prescription can extraly contain the various suitable basis and the additive of needs in the prescription of said compositions, and concerning the staff of this area, the kind of these extra compositions and quantity can be selected easily.
Hereinafter, structure of the present invention and effect will combine embodiment and test case to make further detailed description.These examples are for better elaboration the present invention, and scope of invention is not limited in these examples.
Embodiment 1: the fine and close cosmetic combinations of wet moulding
According to compositions as shown in table 1 below, the densification cosmetic compositions of preparation wet moulding.
Table 1
| Component | Content (weight %) |
| 1, is coated with the mixture of powders of polydimethylsiloxane | 70 |
| 2, organic siliconresin (KF-9002) | 0.5 |
| 3, silicone oil (DC 200/0.65cs) | 29.5 |
The mixture of powders of raw material 1 through squalene and dimethicone are added to by Talcum, Muscovitum, sericite, tripoli, nylon powder, silica flour, polymethyl methacrylate (PMMA) as binding agent thereby, make in the powder formed of boron nitride powder and Barium Sulfate, this mixture of powders is coated with polydimethylsiloxane.
Method for preparing: raw material 2 and 3 is mixed under low temperature and low speed in agitator.The mixture of said raw material 2 and 3 is added in the powder of said raw material 1, and make this powder disperse five minutes with preparation slurry phase.A certain amount of said slurry is filled in the forming disk, and the molding cloth that reuse is applied to said forming disk carries out molding, thereby removes the solvent of about 40-50%.Then, the material of this molding was descended dry 6 hours, to remove remaining solvent fully in exsiccator at 60-70 ℃.
Embodiment 2: the densification cosmetic compositions of wet moulding
According to compositions as shown in table 2 below, use with embodiment 1 identical method to prepare the densification cosmetic compositions.
Table 2
| Component | Content (weight %) |
| 1, is coated with the mixture of powders of polydimethylsiloxane | 70 |
| 2, organic siliconresin (X-21-5250) | 0.5 |
| 3, silicone oil (DC 200/0.65cs) | 29.5 |
The mixture of powders of raw material 1 through squalene and dimethicone are added to by Talcum, Muscovitum, sericite, tripoli, nylon powder, silica flour, polymethyl methacrylate (PMMA) as binding agent thereby, make in the powder formed of boron nitride powder and Barium Sulfate, this mixture of powders is coated with polydimethylsiloxane.
Comparative Examples 1: the densification cosmetic compositions of general wet moulding
According to compositions as shown in table 3 below, use the densification cosmetic compositions for preparing Comparative Examples 1 with embodiment 1 identical method.
Table 3
| Component | Content (weight %) |
| 1, uncoated mixture of powders | 70 |
| 2, water-soluble thickening agent (Veegum HV) | 2.0 |
| 3, water | 28.0 |
The mixture of powders of raw material 1 through squalene and dimethicone are added to by Talcum, Muscovitum, sericite, tripoli, nylon powder, silica flour, polymethyl methacrylate (PMMA) as binding agent thereby, make in the powder formed of boron nitride powder and Barium Sulfate, this mixture of powders does not apply.
Comparative Examples 2: the densification cosmetic compositions of general wet moulding
According to compositions as shown in table 4 below, use the densification cosmetic compositions for preparing Comparative Examples 2 with embodiment 1 identical method.
Table 4
| Component | Content (weight %) |
| 1, is coated with the mixture of powders of polydimethylsiloxane | 70 |
| 2, water-soluble thickening agent (Veegum HV) | 2.0 |
| 3, emulsifying agent (AbilEM 90) | 1.0 |
| 3, water | 27.0 |
The powder film mixture of raw material 1 through squalene and dimethicone are added to by Talcum, Muscovitum, sericite, tripoli, nylon powder, silica flour, polymethyl methacrylate (PMMA) as binding agent thereby, make in the powder formed of boron nitride powder and Barium Sulfate, this mixture of powders is coated with polydimethylsiloxane.Use cetyl PEG/PPG-10/1 dimethicone (Abil EM 90) as emulsifying agent.
Test case 1: Evaluation of Durability
To embodiment 1 and 2 and Comparative Examples 1 and 2 in the resistance to water and the oil resistivity of compositions of preparation compare evaluation.And, use after these compositionss by the women consumer between 10 20-30 year, the flexibility of these compositionss is compared evaluation.Evaluation result is as shown in table 5 below.
Table 5
| Stability | Resistance to water | Oil resistivity | Flexibility | |
| Embodiment 1 | Stable | ◎(138°) | ○(54°) | ○ |
| Embodiment 2 | Stable | ◎(134°) | ○(45°) | ○ |
| Comparative Examples 1 | Stable | * (can't measure) | * (can't measure) | ○ |
| Comparative Examples 2 | Stable | △ | △ | △ |
The ※ evaluation criterion
◎: very good, zero: good, △: general, *: poor, and * *: very poor.
The ※ evaluation methodology
1) stability:, observe each compositions simultaneously and As time goes on whether can break, thereby estimate through each compact composition being stored under 37 ℃ the constant temperature.
2) resistance to water: estimate the unmixability with water through measuring contact angle.
3) oil resistivity: estimate the unmixability with sebum through measuring contact angle.
4) flexibility: test through the group of consumer after each said composition is executed the skin that is overlying on consumer and to assess.
Can find out that from the result of table 5 for resistance to water and the oil resistivity measured by the measurement of contact angle, embodiment 1 and 2 compositions obviously are superior to the compositions of Comparative Examples 1.And the compositions of the Comparative Examples 2 of the powder preparation that usefulness applies is owing to having used emulsifying agent, so its resistance to water and oil resistivity are inferior to the compositions of embodiment 1 and 2.
In the test of group of consumer; Can find out; When consumer directly directly executes the skin that is overlying on consumer with said composition, go out and the similar flexibility of compositions according to the Comparative Examples 1 of existing method preparation according to the compositions display of embodiments of the invention 1.Based on The above results, can find out that the compact composition according to embodiments of the invention 1 and 2 has good durability.
Claims (7)
1. the densification cosmetic compositions of a wet moulding; Said composition contains the bottoming powder of coating; And said composition is used the mixed solvent of volatile silicone oils and organic siliconresin and is made; Said volatile silicone oils and organic siliconresin are to mix in 97: 3 to 99: 1 with weight ratio, before wet moulding, comprise that the gross weight of the said compositions of said mixed solvent is a benchmark, and the content of the bottoming powder of said coating is 60-70 weight %; The content of said mixed solvent is 30-40 weight %, and the bottoming powder of said coating is coated with polydimethylsiloxane or alkyl silane.
2. compositions according to claim 1, wherein, the bottoming powder of said coating is to be selected from least a in the group of being made up of Talcum, Muscovitum, sericite, tripoli, nylon powder, silica flour, polymethyl methacrylate, boron nitride powder and Barium Sulfate.
3. compositions according to claim 1, wherein, said silicone oil is polydimethylsiloxane or cyclomethicone.
4. compositions according to claim 1, wherein, said organic siliconresin is a trimethylsiloxy group silicate.
5. according to any described compositions among the claim 1-4, wherein, said composition does not contain emulsifying agent.
6. according to any described compositions among the claim 1-4, wherein, said composition has the resistance to water and the oil resistivity of raising, and softish sense of touch is provided.
7. method for preparing the densification cosmetic compositions of wet moulding, this method may further comprise the steps:
1) the bottoming powder that is coated with polydimethylsiloxane or alkyl silane and the mixed solvent of volatile silicone oils and organic siliconresin are mixed in general agitator; Wherein, Said volatile silicone oils and organic siliconresin are to mix in 97: 3 to 99: 1 with weight ratio; Gross weight with the mixed solvent of the said bottoming powder that is coated with polydimethylsiloxane or alkyl silane and volatile silicone oils and organic siliconresin is a benchmark; The consumption of the bottoming powder of said coating is 60-70 weight %, and the consumption of said mixed solvent is 30-40 weight %, and the bottoming powder of said coating is coated with polydimethylsiloxane or alkyl silane; And
2) mixture is seated in the compression forming dish, the mixture forming that makes this filling with the molding cloth that is applied to said forming disk to be removing the said solvent of part, and makes the material of this molding dry down to remove remaining solvent at 60-150 ℃ in exsiccator.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020070119349A KR101135252B1 (en) | 2007-11-21 | 2007-11-21 | Wet forming compact composition containing volatile silicone oil and silicone resin |
| KR10-2007-0119349 | 2007-11-21 | ||
| PCT/KR2008/005299 WO2009066862A1 (en) | 2007-11-21 | 2008-09-08 | Wet forming compact composition containing volatile silicone oil and silicone resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101861136A CN101861136A (en) | 2010-10-13 |
| CN101861136B true CN101861136B (en) | 2012-11-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008801165466A Expired - Fee Related CN101861136B (en) | 2007-11-21 | 2008-09-08 | Wet forming compact composition containing volatile silicone oil and silicone resin |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101135252B1 (en) |
| CN (1) | CN101861136B (en) |
| WO (1) | WO2009066862A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101141983B1 (en) * | 2009-08-05 | 2012-05-07 | 한국세라믹기술원 | Boron nitride powder comprising nanoporous silicified phospholipid layers that can impregnate physiologically active material for cosmetic composition and manufacturing method thereof |
| CN102753136B (en) * | 2009-11-20 | 2016-08-03 | 株式会社爱茉莉太平洋 | Comprise the make-up composition of inorganic powder |
| CN104825346A (en) * | 2015-05-04 | 2015-08-12 | 上海彤颜实业有限公司 | Silicone-containing water-in-oil BB cream |
| KR101997584B1 (en) * | 2017-07-14 | 2019-07-08 | 코스맥스 주식회사 | Method for molding solid cosmetic composition including gelling agents |
Citations (8)
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|---|---|---|---|---|
| US5073364A (en) * | 1990-06-19 | 1991-12-17 | Revlon, Inc. | Pressed powder cosmetic product |
| CN1134661A (en) * | 1993-10-02 | 1996-10-30 | 普罗格特和甘布尔公司 | Cosmetic make-up compositions |
| JP2000281533A (en) * | 1999-03-30 | 2000-10-10 | Pola Chem Ind Inc | Coated powder and composition containing the same |
| US6482441B1 (en) * | 1999-07-08 | 2002-11-19 | Miyoshi Kasei, Inc. | Coated powder having super-dispersibility and cosmetic containing the same |
| CN1383806A (en) * | 2001-04-10 | 2002-12-11 | 莱雅公司 | Double-coating makeup method and cosmetics kit including one first and one second composite |
| CN1394134A (en) * | 2000-08-30 | 2003-01-29 | 莱雅公司 | Matt cosmetic composition comprising non-volatile hydrocarbon oil and inert particulate phase |
| KR20030052004A (en) * | 2001-12-20 | 2003-06-26 | 주식회사 엘지생활건강 | Poder typed color cosmetic |
| US6964773B1 (en) * | 2000-11-22 | 2005-11-15 | L'oreal S.A. | Transfer resistant anhydrous cosmetic composition |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4160273B2 (en) * | 2001-03-30 | 2008-10-01 | 株式会社資生堂 | Powder cosmetic and method for producing the same |
| US6811770B2 (en) * | 2001-04-10 | 2004-11-02 | L'oreal | Two-coat make-up process and a make-up kit containing first and second compositions |
-
2007
- 2007-11-21 KR KR1020070119349A patent/KR101135252B1/en active IP Right Grant
-
2008
- 2008-09-08 CN CN2008801165466A patent/CN101861136B/en not_active Expired - Fee Related
- 2008-09-08 WO PCT/KR2008/005299 patent/WO2009066862A1/en active Application Filing
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5073364A (en) * | 1990-06-19 | 1991-12-17 | Revlon, Inc. | Pressed powder cosmetic product |
| CN1134661A (en) * | 1993-10-02 | 1996-10-30 | 普罗格特和甘布尔公司 | Cosmetic make-up compositions |
| JP2000281533A (en) * | 1999-03-30 | 2000-10-10 | Pola Chem Ind Inc | Coated powder and composition containing the same |
| US6482441B1 (en) * | 1999-07-08 | 2002-11-19 | Miyoshi Kasei, Inc. | Coated powder having super-dispersibility and cosmetic containing the same |
| CN1394134A (en) * | 2000-08-30 | 2003-01-29 | 莱雅公司 | Matt cosmetic composition comprising non-volatile hydrocarbon oil and inert particulate phase |
| US6964773B1 (en) * | 2000-11-22 | 2005-11-15 | L'oreal S.A. | Transfer resistant anhydrous cosmetic composition |
| CN1383806A (en) * | 2001-04-10 | 2002-12-11 | 莱雅公司 | Double-coating makeup method and cosmetics kit including one first and one second composite |
| KR20030052004A (en) * | 2001-12-20 | 2003-06-26 | 주식회사 엘지생활건강 | Poder typed color cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090052719A (en) | 2009-05-26 |
| WO2009066862A1 (en) | 2009-05-28 |
| CN101861136A (en) | 2010-10-13 |
| KR101135252B1 (en) | 2012-04-12 |
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