CN101857763A - Heavy anti-corrosion clinkery epoxy powder coating - Google Patents

Heavy anti-corrosion clinkery epoxy powder coating Download PDF

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Publication number
CN101857763A
CN101857763A CN200910097616A CN200910097616A CN101857763A CN 101857763 A CN101857763 A CN 101857763A CN 200910097616 A CN200910097616 A CN 200910097616A CN 200910097616 A CN200910097616 A CN 200910097616A CN 101857763 A CN101857763 A CN 101857763A
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CN
China
Prior art keywords
corrosion
powder coating
epoxy
heavy anti
clinkery
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Pending
Application number
CN200910097616A
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Chinese (zh)
Inventor
李文静
张艳辉
薛彩琴
沈国标
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Ningbo Institute of Technology of ZJU
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Ningbo Institute of Technology of ZJU
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Priority to CN200910097616A priority Critical patent/CN101857763A/en
Publication of CN101857763A publication Critical patent/CN101857763A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a heavy anti-corrosion clinkery epoxy powder coating, which comprises the following components in part by weight: 100 parts of epoxy resin, 20 to 30 parts of curing agent, 2 to 5 parts of flatting agent and 40 to 70 parts of filler. The heavy anti-corrosion clinkery epoxy powder coating is mainly applied in the field of pipeline corrosion prevention and has the advantages of high toughness, high impact resistance, simple preparation process and suitability for mass production.

Description

Heavy anti-corrosion clinkery epoxy powder coating
Technical field
The present invention relates to pipeline corrosion protection clinkery epoxy powder coating technical field, be specifically related to a kind of heavy anti-corrosion clinkery epoxy powder coating.
Background technology
Heavy anti-corrosion clinkery epoxy powder coating, claim clinkery epoxy powder coating (FBE) again, be a kind of be that carrier transports and dispersed solids coating with the air, it is coated on the surface of steel workpiece of preheating, fusing, levelling, solidify to form uniform coating, English name is FBE.It is mainly used in pipeline corrosion protection, be a kind ofly do not contain solvent, with the film forming new anti-corrosion coating of powder melts, in the pipeline coating procedure, do not exist VOC to pollute, curing speed is fast, long service life.At that time because the condition harshness of natural gas line construction by land, circumstance complication, higher to chemical property, mechanical and physical performance and the spraying application performance demands thereof of heavy anti-corrosion clinkery epoxy powder coating, the especially shock resistance of FBE, snappiness.
Existing FBE coating material production generally adopts and is solid-state bisphenol A epoxide resin or epoxy Dyhard RU 100 powder coating under the room temperature, exist shortcomings such as degree of crosslinking is low, levelling property difference, contradiction after also existing film forming to solidify between hardness and shock resistance, the snappiness, though so at present done a few thing aspect toughness reinforcing at clinkery epoxy powder coating, but be cost with expendable material intensity, modulus and thermotolerance usually, make its physics, mechanics and thermal characteristics be subjected to very big influence, even take into account the problems referred to above, toughening effect is also not obvious.
Summary of the invention
The technical problem that the present invention solves is to overcome the above-mentioned deficiency of prior art, and a kind of shock resistance height, heavy anti-corrosion clinkery epoxy powder coating that flexility is good are provided.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: a kind of heavy anti-corrosion clinkery epoxy powder coating, form by the component of following parts by weight: Resins, epoxy 100 weight parts, solidifying agent 20~30 weight parts, flow agent 2~5 weight parts, filler 40~70 weight parts.
Above-mentioned Resins, epoxy is that weight ratio is 0.3~3: 1 novolac epoxy resin and the mixture of Resins, epoxy E-12.
Above-mentioned solidifying agent is JECP-02B or JECP-02B solidifying agent.
Above-mentioned flow agent is the polyacrylate flow agent of GLP588 silicon-dioxide absorption or the polyacrylate flow agent of the ultra-fine high dispersive silicon-dioxide absorption of GLP788.
Above-mentioned filler is that weight ratio is active micro silicon powder, mica powder, gas-phase silica, process white=15: 7.5: 1: 40 mixture.
Advantage of the present invention: E-12 Resins, epoxy is typical base-material, existing bisphenol-A phenolic composition has phenol phenolic aldehyde composition again in the linear phenolic epoxy resin molecule, there are a plurality of epoxide groups in the molecule, have that degree of crosslinking height, hardness of film height, wear resistance are good, the characteristics of favorable anti-corrosion effect; The adding of solidifying agent can make the molecule crosslinked macromole that reticulates structure of linear loop epoxy resins, thereby shows the inherent premium properties; Add flow agent and can improve appearance of coat, enhanced flow levelling; The tenacity of powder coating of the present invention, coating good toughness, shock resistance height can satisfy the requirement for anticorrosion of buried pipeline, and technology is simple, is suitable for scale production, and other performances meet SY/T 0315-97 index request.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail, but the present invention not only is confined to following examples.
Embodiment 1
Active micro silicon powder 15g, mica powder 7.5g, gas-phase silica 1g, process white 40g are joined the mixture that mixing 30min obtains mixing in high-speed mixer.
With novolac epoxy resin 60g, Resins, epoxy E-12 40g, solidifying agent JECP-02B30g, flow agent GLP5884g, said mixture joins and mixes 2min in the high-speed mixer then; The pre-mixing material adds forcing machine and melt extrudes, 90 ℃ of feeding section temperature, 100 ℃ of melt zone temperature, 110 ℃ of mixing sections, 100 ℃ of discharging sections, the forcing machine rotating speed is controlled at 80rpm, compressing tablet, cooling, fragmentation on air-cooled track type compressing tablet crusher obtain product through pulverizing, classification, cyclonic separator separation and screening in pulverising mill, removed fine powder by cyclonic separation, product granularity control: 150 μ m oversize powders≤3%, 250 μ m oversize powder≤0.2%.
Embodiment 2
Add novolac epoxy resin 75g, Resins, epoxy E-1225g, solidifying agent JECP-02B 20g, flow agent GLP5885g, other are with embodiment 1.
Embodiment 3
Add novolac epoxy resin 25g, Resins, epoxy E-12 75g, solidifying agent JECP-02B 25g, flow agent GLP588 3g, other are with embodiment 1.

Claims (5)

1. heavy anti-corrosion clinkery epoxy powder coating, it is characterized in that: the component by following parts by weight is formed: Resins, epoxy 100 weight parts, solidifying agent 20~30 weight parts, flow agent 2~5 weight parts, filler 40~70 weight parts.
2. heavy anti-corrosion clinkery epoxy powder coating according to claim 1 is characterized in that: described Resins, epoxy is that weight ratio is 0.3~3: 1 novolac epoxy resin and the mixture of Resins, epoxy E-12.
3. heavy anti-corrosion clinkery epoxy powder coating according to claim 1 is characterized in that: described solidifying agent is JECP-02B or JECP-02B solidifying agent.
4. heavy anti-corrosion clinkery epoxy powder coating according to claim 1 is characterized in that: described flow agent is the polyacrylate flow agent of GLP588 silicon-dioxide absorption or the polyacrylate flow agent of the ultra-fine high dispersive silicon-dioxide absorption of GLP788.
5. heavy anti-corrosion clinkery epoxy powder coating according to claim 1 is characterized in that: described filler is that weight ratio is active micro silicon powder, mica powder, gas-phase silica, process white=15: 7.5: 1: 40 mixture.
CN200910097616A 2009-04-11 2009-04-11 Heavy anti-corrosion clinkery epoxy powder coating Pending CN101857763A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200910097616A CN101857763A (en) 2009-04-11 2009-04-11 Heavy anti-corrosion clinkery epoxy powder coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200910097616A CN101857763A (en) 2009-04-11 2009-04-11 Heavy anti-corrosion clinkery epoxy powder coating

Publications (1)

Publication Number Publication Date
CN101857763A true CN101857763A (en) 2010-10-13

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Family Applications (1)

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CN200910097616A Pending CN101857763A (en) 2009-04-11 2009-04-11 Heavy anti-corrosion clinkery epoxy powder coating

Country Status (1)

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CN (1) CN101857763A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103497639A (en) * 2013-09-24 2014-01-08 安徽锐视光电技术有限公司 High-toughness high-leveling powder coating
CN103540220A (en) * 2013-09-26 2014-01-29 上海海隆石油化工研究所 Wear-resistant epoxy powder coating for pipeline
CN105754455A (en) * 2016-04-21 2016-07-13 宁波市七彩塑粉有限公司 Method for preparing electric insulation anticorrosion powder coating
CN105754454A (en) * 2016-04-21 2016-07-13 宁波市七彩塑粉有限公司 Electric insulation anti-corrosion powder coating
CN106634431A (en) * 2016-12-20 2017-05-10 山东东方新材料有限公司 Superhydrophobic-structure fusion-bonded epoxy powder paint and preparation method thereof
CN111073369A (en) * 2019-11-10 2020-04-28 六安强力电机有限公司 Outdoor dustproof anticorrosion three-phase asynchronous motor

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103497639A (en) * 2013-09-24 2014-01-08 安徽锐视光电技术有限公司 High-toughness high-leveling powder coating
CN103540220A (en) * 2013-09-26 2014-01-29 上海海隆石油化工研究所 Wear-resistant epoxy powder coating for pipeline
CN105754455A (en) * 2016-04-21 2016-07-13 宁波市七彩塑粉有限公司 Method for preparing electric insulation anticorrosion powder coating
CN105754454A (en) * 2016-04-21 2016-07-13 宁波市七彩塑粉有限公司 Electric insulation anti-corrosion powder coating
CN106634431A (en) * 2016-12-20 2017-05-10 山东东方新材料有限公司 Superhydrophobic-structure fusion-bonded epoxy powder paint and preparation method thereof
CN106634431B (en) * 2016-12-20 2019-06-25 山东东宏管业股份有限公司 A kind of clinkery epoxy powder coating and preparation method thereof with super-drainage structure
CN111073369A (en) * 2019-11-10 2020-04-28 六安强力电机有限公司 Outdoor dustproof anticorrosion three-phase asynchronous motor

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Application publication date: 20101013