CN101798465A - Composite material capable of releasing volatile substances persistently and preparation method thereof - Google Patents
Composite material capable of releasing volatile substances persistently and preparation method thereof Download PDFInfo
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- CN101798465A CN101798465A CN 201010125267 CN201010125267A CN101798465A CN 101798465 A CN101798465 A CN 101798465A CN 201010125267 CN201010125267 CN 201010125267 CN 201010125267 A CN201010125267 A CN 201010125267A CN 101798465 A CN101798465 A CN 101798465A
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Abstract
The invention discloses a composite material capable of releasing volatile substances persistently and a preparation method thereof. The composite material is prepared from the following main components in parts by weight: 10-50 parts of aqueous resin, 50-180 parts of natural fiber, 3-8 parts of water-solubility hardening agent, 8-15 parts of phase transfer catalyst, 50-150 parts of filler, 2-9 parts of volatile substance and 100-200 parts of water. The invention uses the natural fiber and common high molecular materials as carriers of the volatile substances, has simple preparation and low production cost and can be decomposed directly in a natural state.
Description
Technical field
The present invention relates to a kind of matrix material and preparation method thereof, but relate to matrix material of a kind of releasing volatile substances persistently and preparation method thereof particularly.
Background technology
In the volatile matter, volatile oil can distribute happy smell, but uses volatile oil to volatilize easily merely, and fragrance can not be lasting; Similarly, drive (killing) worm effective ingredient and also have easy volatilization, the unabiding problem of drug effect.For prolonging volatile oil and driving (killing) worm effective ingredient action time, existing mode is to use special polymeric carrier material to reduce volatile substances, as make the mosquito repellent paster and the mosquito repellent crystalline substance freezes etc., but it not only makes complexity, cost height, and a large amount of macromolecular material that uses can't directly decompose under state of nature.
Summary of the invention
But the object of the present invention is to provide a kind of matrix material of releasing volatile substances persistently, the present invention is with natural fiber and the common high molecular materials carrier as volatile matter, not only make simple, production cost is low, and can under state of nature, directly decompose.
In order to reach above-mentioned purpose, solution of the present invention is:
But a kind of matrix material of releasing volatile substances persistently, it is characterized in that it is by mainly comprising the preparation of following components in weight portions: 100～200 parts in 10～50 parts of water-base resins, 50～180 parts in natural fiber, 3～8 parts of water-soluble stiffening agents, 8～15 parts of phase-transfer catalysts, 50～150 parts of fillers, 2～9 parts of volatile matter and water.
In a preferred embodiment of the present invention, described water-base resin is by mainly comprising following components in weight portions preparation: 4～20 parts of 10～100 parts of non-aqueous resins and water-based initiators.The concrete preparation method of water-base resin is as follows: the non-aqueous Resins, epoxy of said ratio is put into reactor with the water-based initiator mix, obtained in 1～2 hour at 120～160 ℃ of compressive reactions.This part content has been open in detail in 200910310409.2 the patent application at the patentee's number of patent application, no longer carefully states at this.Described non-aqueous resin is selected from least a in resol, unsaturated polyester, acrylic resin, polyurethane resin, Resins, epoxy or other associated resin, and makes aqueous phenolic aldehyde resin, water-based unsaturated polyester, water-borne acrylic resin, aqueous polyurethane resin, aqueous epoxy resins or other relevant water-base resins respectively.Preferably, described water-base resin is an aqueous epoxy resins, and described aqueous epoxy resins is at least a in Water-borne modification bisphenol A epoxide resin, Water-borne modification phenol aldehyde type epoxy resin or the Water-borne modification dilution type Resins, epoxy.Further preferably, described Water-borne modification bisphenol A epoxide resin is at least a in E51, E20, E44, E41, Epon828, BE188, CYD128 or other the relevant Resins, epoxy; Described Water-borne modification phenol aldehyde type epoxy resin is at least a in F51, F20, F44, F41 or other the relevant Resins, epoxy; Described Water-borne modification dilution type Resins, epoxy is at least a in ethylene glycol bisthioglycolate glycidyl ester, butyleneglycol 2-glycidyl ester, propylene glycol 2-glycidyl ester, glycerol 2-glycidyl ester or the glycidyl allyl ether.Described water-based initiator is selected from Sodium Persulfate, Potassium Persulphate, 4,4-azo two (4-cyanopentanoic acid), 4,4-azo two (4-cyanopentanoic acid sodium), 4, at least a in 4-azo two (4-cyano group amylalcohol), methylethyl ketone peroxides, cyclohexanone peroxide or other the relevant initiators.
Described natural fiber is selected from least a in xylon, flaxen fiber, cotton fibre, bamboo fibers, vine fiber ti, straw fiber, sea-weed fibre, Pericarppium arachidis hypogaeae, rice husk, paper, straw, wheat tangerine, Caulis Sacchari sinensis fiber, Exocarpium cocois (Cocos nucifera L), leaf, duricrust shell, melon seed cases, coffee grounds, tealeaf residue, Chinese medicine slag or other the relevant natural fibers.Preferably, described natural fiber is xylon (wood powder).Among the present invention, natural fiber need be ground into powder in advance, is then used again.
Described water-soluble stiffening agent is the stiffening agent of aqueous epoxy resins, it is only be restricted to must have water-soluble, and can with the Resins, epoxy commissure, specifically can be selected from trolamine, quadrol, diethylenetriamine, Triethylenetetramine (TETA), tetren, polyvinylamine, phenolic aldehyde amine, 2,4,6-three (dimethylamino methyl) phenol, aqueous polyurethane, aqueous polyamide, policapram, dicyanamide, boron trifluoride-amine complex, dislike boron heterocycle boron amide complex compound, the water-based polyureas, polyetheramine (Jeffamine), hexanediamine, amine end-blocking water-based polyimide, ammoniacal liquor, diethylin is for propylamine, water-soluble aromatic amine, isophorone diamine, thiocarbamide, mercaptan amine, at least a in thiocarbamide-polyamine condenses or other the relevant stiffening agents.Preferably, aforesaid water-soluble stiffening agent is at least a of diethylenetriamine, polyvinylamine, mercaptan amine or policapram.
Described phase-transfer catalyst is at least a in crown ether, polyoxyethylene glycol, quaternary amine, quaternary alkylphosphonium salt, sulfonium salt or arsenic salt, cave ether, bromination Shi six alkyl San Ding Ji Phosphonium, Tetrabutyl amonium bromide, methyl trioctylphosphine ammonium chloride or other related compound.Preferably, described phase-transfer catalyst is a polyoxyethylene glycol.Because in the aqueous epoxy resin emulsion, epoxide functional groups is at oil phase, and the functional group of water-based stiffening agent is at water, carries out catalysis between the two-phase because of needing phase-transfer catalyst a bit.The epoxide functional groups that act as the catalysis oil phase of phase-transfer catalyst and the reaction of the stiffening agent of water are " oil-in-water " state with " water-in-oil " state-transition.
Described filler is selected from least a in silica flour, stone flour, pottery powder, silica powder, native powder, starch, titanium dioxide, clay powder, carbon black, nano-carbon powder, nano clay, Graphite Powder 99, Graphene, animal excrement powder, glass powder, sand, glass fiber powder, carbon fiber powder, plastic waste powder, cement, rubble, useless foaming rubber powder, wax powder, asphalt powder, wood charcoal powder, kaolin powder, talcum powder or other associated materials.Preferably, described filler is the clay powder.
Described volatile matter is the wormer of expelling parasite significant quantity and/or the essence of sense of smell significant quantity, described wormer is selected from and drives the ant agent, anophelifuge, drive a kind of in roach agent or the fly-killing agent, it specifically can be the evil spirit of going out, N, benzamide between the N-diethyl, the O-phthalic ester, mentha camphor, camphor, K-othrin, Simpleleaf Shrub Chastetree Fruit, Leaf of Camphortree juice, pyrethrin, dimethirn, dimethyl phthalate, Ricefield eel bone liquid, tortoise bone liquid, soft-shelled turtle bone liquid, Deltamethrin, OP-10, Permanone, Tetramethrin, esbiothrin, acetofenate, pulvis flores pyrethri, pamorusa oil, indoles, propine chrysanthemum ester, the methylbenzyl chrysanthemumic acid, mustard oil, acetofenate, Ro 7-5050, the enemy receives quick, Oleum Bulbus Allii, at least a in lemon quintessence oil or other the relevant wormers.Preferably, described wormer be to go out evil spirit, N, at least a between the N-diethyl in benzamide, mentha camphor, camphor or the pamorusa oil.Further preferably, described wormer is N, benzamide between the N-diethyl.
Described essence is selected from least a in santal oil, cream jasmin france, jasmine sesame oil, chypre sesame oil, chypre compound, lemon flavour, coffee essence, grapefruit essence, rose compound, lavandula angustifolia essence, sandalwood fragrance, shaddock essence, white orchid essence, osmanthus flower fragrance or the lily essence.Preferably, described essence is at least a in cream jasmin france, chypre compound, lemon flavour, grapefruit essence, rose compound or the lavandula angustifolia essence.
In the further embodiment of the present invention, also comprise the emulsifying agent of 1～5 part (by weight ratio), described emulsifying agent is a sodium laurylsulfonate.
In the further embodiment of the present invention, also comprise 1～2 part of (by weight ratio) volatile aids, described volatile aids is selected from least a in Syzygium aromaticum stem oil, Radix Aucklandiae oil, elm leaf oil, hawthorn leaf oil, Oleum Cinnamomi, Oil of Eucalyptus, Pinus pumilio oil, Japan cypress oil, Herba Menthae Rotundifoliae oil, shiu oil or the cedar(wood)oil.
But another object of the present invention provides a kind of preparation method of matrix material of releasing volatile substances persistently.
But a kind of preparation method of matrix material of releasing volatile substances persistently is characterized in that, comprises following step:
1) gets the raw materials ready according to above-mentioned component and weight proportion;
2) water, water-base resin and water-soluble stiffening agent are added in the stirred pot, water-base resin and water-soluble stiffening agent be scattered in form emulsion in the water, then add phase-transfer catalyst, natural fiber and filler and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form solid support material;
3) volatile matter is added carrier absorption.
Unless name especially, the implication of employed here all technology and scientific terminology is identical with the common implication of understanding of the technical field of the invention those skilled in the art.Equally, all publication, patent application, patent and other bibliographys are all introduced the present invention as a reference referred in this.
Compared with prior art, the present invention has following characteristics:
1) the present invention is with natural fiber and the common high molecular materials carrier as volatile matter, not only make simple, production cost is low, and can under state of nature, directly decompose;
2) the present invention is scattered in water-base resin and water-soluble stiffening agent and forms emulsion in the water, then add phase-transfer catalyst, natural fiber and filler, treat the moistening natural fiber post-heating pressurization of emulsion, make water evaporates, water-base resin solidifies, and above-mentioned substance is bonded to matrix material, then adds volatile matter (insect repellent and/or essence) and absorbs acquisition, therefore, making method of the present invention is simple and do not need expensive processing units;
3) product that contains anophelifuge need not heat, and need not switch on, and need not light a fire, and does not directly contact skin and can reach good repelling effect;
4) product is originally as solid, and convenient transportation can directly reclaim after the use, clean environment firendly, and can be processed into Any shape.
Embodiment
Embodiment 1
Get Water-borne modification bisphenol A epoxide resin E51 (water-base resin) 20g, wood powder (natural fiber) 100g, diethylenetriamine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 10g, clay powder (filler) 100g by weight, evil spirit (insect repellent) 1g, cream jasmin france (essence) 5g and water 200g go out.
This wherein, water-based bisphenol A epoxide resin E51 obtains by following mode: get bisphenol A epoxide resin E51 15g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with bisphenol A epoxide resin E51 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin E51 and diethylenetriamine are added in the stirred pot, Water-borne modification bisphenol A epoxide resin E51 and diethylenetriamine be scattered in form emulsion in the water, then add wood powder, polyoxyethylene glycol and clay powder and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.The evil of will going out spirit and cream jasmin france add the sheet material carrier absorption.
Detection method: the sheet material that will be absorbed with go out evil spirit and cream jasmin france is placed in mosquito gathering zone territory, a few place;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: the mosquito repellent time length is 4 days, and the fragrance time length is 1.5 months.
Embodiment 2
Get Water-borne modification bisphenol A epoxide resin E20 (water-base resin) 20g, wood powder (natural fiber) 100g, diethylenetriamine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 10g, clay powder (filler) 100g, N by weight, benzamide between the N-diethyl (insect repellent) 1g, cream jasmin france (essence) 1g and water 200g.
This wherein, water-based bisphenol A epoxide resin E20 obtains by following mode: get bisphenol A epoxide resin E20 19g and 4, two (4-cyanopentanoic acid) 1g of 4-azo get the raw materials ready, with bisphenol A epoxide resin E20 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin E20 and diethylenetriamine are added in the stirred pot, Water-borne modification bisphenol A epoxide resin E20 and diethylenetriamine be scattered in form emulsion in the water, then add wood powder, polyoxyethylene glycol and clay powder and mix, mix back pressurized, heated to 180 a ℃ oven dry with kneader and form the sheet material solid support material.With cream jasmin france and N, benzamide adds the sheet material carrier absorption between the N-diethyl.
Detection method: will be absorbed with cream jasmin france and N, the sheet material of benzamide is placed in mosquito gathering zone territory, a few place between the N-diethyl;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of mosquito repellent is 4 days, and the fragrance time length is 1.2 months.
Embodiment 3
Get Water-borne modification bisphenol A epoxide resin E44 (water-base resin) 20g, wood powder (natural fiber) 100g, diethylenetriamine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 10g, clay powder (filler) 100g, mentha camphor (insect repellent) 1g, cream jasmin france (essence) 5g and water 200g by weight.
This wherein, water-based bisphenol A epoxide resin E44 obtains by following mode: get bisphenol A epoxide resin E44 15g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with bisphenol A epoxide resin E44 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin E44 and diethylenetriamine are added in the stirred pot, Water-borne modification bisphenol A epoxide resin E44 and diethylenetriamine be scattered in form emulsion in the water, then add wood powder, polyoxyethylene glycol and clay powder and mix, mix back pressurized, heated to 160 a ℃ oven dry with kneader and form the sheet material solid support material.Cream jasmin france and mentha camphor are added the sheet material carrier absorption.
Detection method: the sheet material that will be absorbed with cream jasmin france and mentha camphor is placed in mosquito gathering zone territory, a few place;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of mosquito repellent is 5 days, and the fragrance time length is 1.4 months.
Embodiment 4
Get Water-borne modification bisphenol A epoxide resin E41 (water-base resin) 20g, wood powder (natural fiber) 100g, diethylenetriamine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 10g, clay powder (filler) 100g, camphor (insect repellent) 1g, cream jasmin france (essence) 5g and water 200g by weight.
This wherein, water-based bisphenol A epoxide resin E41 obtains by following mode: get bisphenol A epoxide resin E41 15g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with bisphenol A epoxide resin E41 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin E41 and diethylenetriamine are added in the stirred pot, Water-borne modification bisphenol A epoxide resin E41 and diethylenetriamine be scattered in form emulsion in the water, then add wood powder, polyoxyethylene glycol and clay powder and mix, mix back pressurized, heated to 120 a ℃ oven dry with kneader and form the sheet material solid support material.Cream jasmin france and camphor are added the sheet material carrier absorption.
Detection method: the sheet material that will be absorbed with cream jasmin france and camphor is placed in mosquito gathering zone territory, a few place;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of mosquito repellent is 5 days, and the fragrance time length is 1.4 months.
Embodiment 5
Get Water-borne modification bisphenol A epoxide resin Epon828 (water-base resin) 20g, wood powder (natural fiber) 100g, diethylenetriamine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 10g, clay powder (filler) 100g, pamorusa oil (insect repellent) 1g, cream jasmin france (essence) 5g and water 200g by weight.
This wherein, water-based bisphenol A epoxide resin Epon828 obtains by following mode: get bisphenol A epoxide resin Epon828 15g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with bisphenol A epoxide resin Epon828 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin Epon828 and diethylenetriamine are added in the stirred pot, Water-borne modification bisphenol A epoxide resin Epon828 and diethylenetriamine be scattered in form emulsion in the water, then add wood powder, polyoxyethylene glycol and clay powder and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.Cream jasmin france and pamorusa oil are added the sheet material carrier absorption.
Detection method: the sheet material that will be absorbed with cream jasmin france and pamorusa oil is placed in mosquito gathering zone territory, a few place;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of mosquito repellent is 5 days, and the fragrance time length is 1.2 months.
Embodiment 6
Get Water-borne modification bisphenol A epoxide resin BE188 (water-base resin) 20g, wood powder (natural fiber) 100g, diethylenetriamine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 10g, clay powder (filler) 100g, N by weight, benzamide between the N-diethyl (insect repellent) 1g, chypre compound (essence) 5g and water 200g.
This wherein, water-based bisphenol A epoxide resin BE188 obtains by following mode: get bisphenol A epoxide resin BE18815g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with bisphenol A epoxide resin BE188 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin BE188 and diethylenetriamine are added in the stirred pot, Water-borne modification bisphenol A epoxide resin BE188 and diethylenetriamine be scattered in form emulsion in the water, then add wood powder, polyoxyethylene glycol and clay powder and mix, mix back pressurized, heated to 130 a ℃ oven dry with kneader and form the sheet material solid support material.With chypre compound and N, benzamide adds the sheet material carrier absorption between the N-diethyl.
Detection method: will be absorbed with chypre compound and N, the sheet material of benzamide is placed in mosquito gathering zone territory, a few place between the N-diethyl;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of mosquito repellent is 4 days, and the fragrance time length is 1.2 months.
Embodiment 7
Get Water-borne modification bisphenol A epoxide resin CYD128 (water-base resin) 30g, wood powder (natural fiber) 100g, diethylenetriamine (water-soluble stiffening agent) 3g, polyoxyethylene glycol (phase-transfer catalyst) 10g, clay powder (filler) 100g, N by weight, benzamide between the N-diethyl (insect repellent) 4g, lemon flavour (essence) 4g, Radix Aucklandiae oil 2g and water 200g.
This wherein, water-based bisphenol A epoxide resin CYD128 obtains by following mode: get bisphenol A epoxide resin CYD12820g and 4, two (4-cyanopentanoic acid) 10g of 4-azo get the raw materials ready, with bisphenol A epoxide resin CYD128 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin CYD128 and diethylenetriamine are added in the stirred pot, Water-borne modification bisphenol A epoxide resin CYD128 and diethylenetriamine be scattered in form emulsion in the water, then add wood powder, polyoxyethylene glycol and clay powder and mix, mix back pressurized, heated to 130 a ℃ oven dry with kneader and form the sheet material solid support material.With lemon flavour, Radix Aucklandiae oil and N, benzamide adds the sheet material carrier absorption between the N-diethyl.
Detection method: will be absorbed with chypre compound and N, the sheet material of benzamide is placed in mosquito gathering zone territory, a few place between the N-diethyl;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of mosquito repellent is 5 days, and the fragrance time length is 1.2 months.
Embodiment 8
Get Water-borne modification phenol aldehyde type epoxy resin F51 (water-base resin) 10g, wood powder (natural fiber) 50g, diethylenetriamine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 15g, clay powder (filler) 150g, N by weight, benzamide between the N-diethyl (insect repellent) 3g, grapefruit essence (essence) 6g, Syzygium aromaticum stem oil 1g and water 100g.
This wherein, Water-borne modification phenol aldehyde type epoxy resin F51 obtains by following mode: get phenol aldehyde type epoxy resin F51 7g and 4, two (4-cyanopentanoic acid) 3g of 4-azo get the raw materials ready, with phenol aldehyde type epoxy resin F51 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification phenol aldehyde type epoxy resin F51 and diethylenetriamine are added in the stirred pot, Water-borne modification phenol aldehyde type epoxy resin F51 and diethylenetriamine be scattered in form emulsion in the water, then add wood powder, polyoxyethylene glycol and clay powder and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.With grapefruit essence, Syzygium aromaticum stem oil and N, benzamide adds the sheet material carrier absorption between the N-diethyl.
Detection method: will be absorbed with grapefruit essence and N, the sheet material of benzamide is placed in mosquito gathering zone territory, a few place between the N-diethyl;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of mosquito repellent is 5 days, and the fragrance time length is 1.3 months.
Embodiment 9
Get Water-borne modification phenol aldehyde type epoxy resin F20 (water-base resin) 30g, wood powder (natural fiber) 100g, sodium laurylsulfonate 5g, diethylenetriamine (water-soluble stiffening agent) 8g, polyoxyethylene glycol (phase-transfer catalyst) 12g, clay powder (filler) 50g, N by weight, benzamide between the N-diethyl (insect repellent) 2g, rose compound (essence) 5g and water 150g.
This wherein, Water-borne modification phenol aldehyde type epoxy resin F20 obtains by following mode: get phenol aldehyde type epoxy resin F20 15g and 4, two (4-cyanopentanoic acid) 15g of 4-azo get the raw materials ready, with phenol aldehyde type epoxy resin F20 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification phenol aldehyde type epoxy resin F20, diethylenetriamine and sodium laurylsulfonate are added in the stirred pot, Water-borne modification phenol aldehyde type epoxy resin F20, diethylenetriamine and sodium laurylsulfonate be scattered in form emulsion in the water, then add wood powder, polyoxyethylene glycol and clay powder and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.With rose compound and N, benzamide adds the sheet material carrier absorption between the N-diethyl.
Detection method: will be absorbed with rose compound and N, the sheet material of benzamide is placed in mosquito gathering zone territory, a few place between the N-diethyl;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of mosquito repellent is 4 days, and the fragrance time length is 1.6 months.
Embodiment 10
Get Water-borne modification phenol aldehyde type epoxy resin F44 (water-base resin) 20g, flaxen fiber (natural fiber) 100g, sodium laurylsulfonate 1g, polyvinylamine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 10g, stone flour (filler) 100g, N by weight, benzamide between the N-diethyl (insect repellent) 1g, lavandula angustifolia essence (essence) 5g and water 200g.Flaxen fiber needs to use later on being ground into powder.
This wherein, Water-borne modification phenol aldehyde type epoxy resin F44 obtains by following mode: get phenol aldehyde type epoxy resin F4415g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with phenol aldehyde type epoxy resin F44 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification phenol aldehyde type epoxy resin F44, polyvinylamine and sodium laurylsulfonate are added in the stirred pot, Water-borne modification phenol aldehyde type epoxy resin F44 and polyvinylamine be scattered in form emulsion in the water, then add flaxen fiber, polyoxyethylene glycol and stone flour and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.With lavandula angustifolia essence and N, benzamide adds the sheet material carrier absorption between the N-diethyl.
Detection method: will be absorbed with lavandula angustifolia essence and N, the sheet material of benzamide is placed in mosquito gathering zone territory, a few place between the N-diethyl;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of mosquito repellent is 3 days, and the fragrance time length is 1.4 months.
Embodiment 11
Get Water-borne modification phenol aldehyde type epoxy resin F41 (water-base resin) 20g, flaxen fiber (natural fiber) 100g, polyvinylamine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 10g, stone flour (filler) 100g, lavandula angustifolia essence (essence) 5g and water 200g by weight.Flaxen fiber needs to use later on being ground into powder.
This wherein, Water-borne modification phenol aldehyde type epoxy resin F41 obtains by following mode: get phenol aldehyde type epoxy resin F41 15g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with phenol aldehyde type epoxy resin F41 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification phenol aldehyde type epoxy resin F41 and polyvinylamine are added in the stirred pot, Water-borne modification phenol aldehyde type epoxy resin F41 and polyvinylamine be scattered in form emulsion in the water, then add flaxen fiber, polyoxyethylene glycol and stone flour and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.Lavandula angustifolia essence is added the sheet material carrier absorption.
Detection method and result: the sheet material that will be absorbed with lavandula angustifolia essence is placed in indoor as the fragrance source, and the fragrance time length is 1.4 months.
Embodiment 12
Get Water-borne modification phenol aldehyde type epoxy resin F41 (water-base resin) 20g, cotton fibre (natural fiber) 100g, mercaptan amine (water-soluble stiffening agent) 5g, polyoxyethylene glycol (phase-transfer catalyst) 10g, pottery powder (filler) 100g, rose compound (essence) 5g and water 200g by weight.Cotton fibre needs to use later on being ground into powder.
This wherein, Water-borne modification phenol aldehyde type epoxy resin F41 obtains by following mode: get phenol aldehyde type epoxy resin F41 15g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with phenol aldehyde type epoxy resin F41 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification phenol aldehyde type epoxy resin F41 and mercaptan amine are added in the stirred pot, Water-borne modification phenol aldehyde type epoxy resin F41 and mercaptan amine is scattered in forms emulsion in the water, then add cotton fibre, polyoxyethylene glycol and pottery powder and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.Rose compound is added the sheet material carrier absorption.
Detection method and result: the sheet material that will be absorbed with rose compound is placed in indoor as the fragrance source, and the fragrance time length is 1.4 months.
Embodiment 13
Get Water-borne modification bisphenol A epoxide resin E51 (water-base resin) 50g, bamboo fibers (natural fiber) 50g, mercaptan amine (water-soluble stiffening agent) 8g, polyoxyethylene glycol (phase-transfer catalyst) 10g, silica powder (filler) 100g, lemon flavour (essence) 5g and water 200g by weight.Bamboo fibers needs to use later on being ground into powder.
This wherein, Water-borne modification bisphenol A epoxide resin E51 obtains by following mode: get bisphenol A epoxide resin E51 45g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with bisphenol A epoxide resin E51 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin E51 and mercaptan amine are added in the stirred pot, Water-borne modification bisphenol A epoxide resin E51 and mercaptan amine is scattered in forms emulsion in the water, then add bamboo fibers, polyoxyethylene glycol and silica powder and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.Lemon flavour is added the sheet material carrier absorption.
Detection method and result: the sheet material that will be absorbed with lemon flavour is placed in indoor as the fragrance source, and the fragrance time length is 1.3 months.
Embodiment 14
Get Water-borne modification bisphenol A epoxide resin E51 (water-base resin) 20g, vine fiber ti (natural fiber) 180g, policapram (water-soluble stiffening agent) 6g, crown ether (phase-transfer catalyst) 15g, glass powder (filler) 150g, grapefruit essence (essence) 5g and water 200g by weight.Vine fiber ti needs to use later on being ground into powder.
This wherein, Water-borne modification bisphenol A epoxide resin E51 obtains by following mode: get bisphenol A epoxide resin E51 15g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with bisphenol A epoxide resin E51 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin E51 and policapram are added in the stirred pot, Water-borne modification bisphenol A epoxide resin E51 and policapram be scattered in form emulsion in the water, then add vine fiber ti, crown ether and glass powder and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.Grapefruit essence is added the sheet material carrier absorption.
Detection method and result: the sheet material that will be absorbed with grapefruit essence is placed in indoor as the fragrance source, and the fragrance time length is 1.4 months.
Embodiment 15
Get Water-borne modification bisphenol A epoxide resin E51 (water-base resin) 30g, Exocarpium cocois (Cocos nucifera L) (natural fiber) 150g, policapram (water-soluble stiffening agent) 3g, quaternary amine (phase-transfer catalyst) 12g, kaolin (filler) 50g, chypre compound (essence) 6g and water 150g by weight.Exocarpium cocois (Cocos nucifera L) needs to use later on being ground into powder.
This wherein, Water-borne modification bisphenol A epoxide resin E51 obtains by following mode: get bisphenol A epoxide resin E51 25g and 4, two (4-cyanopentanoic acid) 5g of 4-azo get the raw materials ready, with bisphenol A epoxide resin E51 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin E51 and policapram are added in the stirred pot, Water-borne modification bisphenol A epoxide resin E51 and policapram be scattered in form emulsion in the water, then add coconut shell powder, quaternary amine and kaolin and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.Chypre compound is added the sheet material carrier absorption.
Detection method and result: the sheet material that will be absorbed with chypre compound is placed in indoor as the fragrance source, and the fragrance time length is 1.3 months.
Embodiment 16
Get Water-borne modification bisphenol A epoxide resin E51 (water-base resin) 10g, straw (natural fiber) 50, policapram (water-soluble stiffening agent) 4g, quaternary alkylphosphonium salt (phase-transfer catalyst) 8g, charcoal (filler) 50g, cream jasmin france (essence) 3g and water 100g by weight.Straw needs to use later on being ground into powder.
This wherein, Water-borne modification bisphenol A epoxide resin E51 obtains by following mode: get bisphenol A epoxide resin E51 8g and 4, two (4-cyanopentanoic acid) 2g of 4-azo get the raw materials ready, with bisphenol A epoxide resin E51 and 4,4-azo two (4-cyanopentanoic acid) is put into reactor and is mixed, and obtains after 1 hour at 150 ℃ of compressive reactions.
Above-mentioned water, Water-borne modification bisphenol A epoxide resin E51 and policapram are added in the stirred pot, Water-borne modification bisphenol A epoxide resin E51 and policapram be scattered in form emulsion in the water, then add straw, quaternary alkylphosphonium salt and charcoal and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form the sheet material solid support material.Cream jasmin france is added the sheet material carrier absorption.
Detection method and result: the sheet material that will be absorbed with cream jasmin france is placed in indoor as the fragrance source, and the fragrance time length is 1.3 months.
Reference examples 1
Get N, (insect repellent) 1g of benzamide between the N-diethyl and lavandula angustifolia essence (essence) 5g uniform mixing, product in contrast.
Detection method: reference substance directly is placed in mosquito gathering zone territory, a few place;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of expelling parasite is 1 day, and the fragrance time length is 3 days.
Reference examples 2
Get go out evil spirit (insect repellent) 1g and lavandula angustifolia essence (essence) 5g uniform mixing, product in contrast.
Detection method: reference substance directly is placed in mosquito gathering zone territory, a few place;
Repelling effect basis for estimation: be placed with 1cm
3The 3m of sheet material
3Human body lured mosquito 30 minutes in the zone, and average per person lures and obtains the adult mosquito number and be no more than 1, is judged to be effectively;
The result: effective time length of expelling parasite is 1 day, and the fragrance time length is 3 days.
Reference examples 3
Get lavandula angustifolia essence (essence) 5g product in contrast.
Detection method and result: reference substance directly is placed in indoor, the fragrance time length is 3 days.
Reference examples 4
Get grapefruit essence (essence) 5g product in contrast.
Detection method and result: reference substance directly is placed in indoor, the fragrance time length is 2 days.
Reference examples 5
Get lemon flavour (essence) 5g product in contrast.
Detection method and result: reference substance directly is placed in indoor, the fragrance time length is 2 days.
Reference examples 6
Get cream jasmin france (essence) 5g product in contrast.
Detection method and result: reference substance directly is placed in indoor, the fragrance time length is 3 days.
The foregoing description is a preferred implementation of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and the principle, substitutes, combination, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (9)
1. but the matrix material of a releasing volatile substances persistently, it is characterized in that it is by mainly comprising the preparation of following components in weight portions: 100～200 parts in 10～50 parts of water-base resins, 50～180 parts in natural fiber, 3～8 parts of water-soluble stiffening agents, 8～15 parts of phase-transfer catalysts, 50～150 parts of fillers, 2～9 parts of volatile matter and water.
2. but according to the matrix material of the releasing volatile substances persistently described in the claim 1, it is characterized in that:
Described water-base resin is at least a in aqueous phenolic aldehyde resin, water-based unsaturated polyester, water-borne acrylic resin, aqueous polyurethane resin or the aqueous epoxy resins;
Described natural fiber is selected from least a in xylon, flaxen fiber, cotton fibre, bamboo fibers, vine fiber ti, straw fiber, sea-weed fibre, Pericarppium arachidis hypogaeae, rice husk, paper, straw, wheat tangerine, Caulis Sacchari sinensis fiber, Exocarpium cocois (Cocos nucifera L), leaf, duricrust shell, melon seed cases, coffee grounds, tealeaf residue or the Chinese medicine slag;
Described water-soluble stiffening agent is selected from trolamine, quadrol, diethylenetriamine, Triethylenetetramine (TETA), tetren, polyvinylamine, phenolic aldehyde amine, 2,4,6-three (dimethylamino methyl) phenol, aqueous polyurethane, aqueous polyamide, policapram, dicyanamide, boron trifluoride-amine complex, dislike boron heterocycle boron amide complex compound, the water-based polyureas, polyetheramine, hexanediamine, amine end-blocking water-based polyimide, ammoniacal liquor, diethylin is for propylamine, water-soluble aromatic amine, isophorone diamine, thiocarbamide, at least a in mercaptan amine or thiocarbamide-polyamine condenses;
Described phase-transfer catalyst is at least a in crown ether, polyoxyethylene glycol, quaternary amine, quaternary alkylphosphonium salt, sulfonium salt or arsenic salt, cave ether, bromination Shi six alkyl San Ding Ji Phosphonium, Tetrabutyl amonium bromide or the methyl trioctylphosphine ammonium chloride;
Described filler is selected from least a in silica flour, stone flour, pottery powder, silica powder, native powder, starch, titanium dioxide, clay powder, carbon black, nano-carbon powder, nano clay, Graphite Powder 99, Graphene, animal excrement powder, glass powder, sand, glass fiber powder, carbon fiber powder, plastic waste powder, cement, rubble, useless foaming rubber powder, wax powder, asphalt powder, wood charcoal powder, kaolin powder or the talcum powder;
Described volatile matter is the wormer of expelling parasite significant quantity and/or the essence of sense of smell significant quantity.
3. but according to the matrix material of the releasing volatile substances persistently described in the claim 2, it is characterized in that:
Described water-base resin is preferably aqueous epoxy resins, and described aqueous epoxy resins is at least a in Water-borne modification bisphenol A epoxide resin, Water-borne modification phenol aldehyde type epoxy resin or the dilution type Resins, epoxy;
Described natural fiber is an xylon;
Described water-soluble stiffening agent is at least a of diethylenetriamine, polyvinylamine, mercaptan amine or policapram;
Described phase-transfer catalyst is a polyoxyethylene glycol;
Described filler is the clay powder;
Described wormer is selected from and drives ant agent, anophelifuge, drives a kind of in roach agent or the fly-killing agent;
Described essence is selected from least a in santal oil, cream jasmin france, jasmine sesame oil, chypre sesame oil, chypre compound, lemon flavour, coffee essence, grapefruit essence, rose compound, lavandula angustifolia essence, sandalwood fragrance, shaddock essence, white orchid essence, osmanthus flower fragrance or the lily essence.
4. but according to the matrix material of the releasing volatile substances persistently described in the claim 3, it is characterized in that:
Described Water-borne modification bisphenol A epoxide resin is at least a among E51, E20, E44, E41, Epon828, BE188 or the CYD128; Described Water-borne modification phenol aldehyde type epoxy resin is at least a among F51, F20, F44 or the F41; Described dilution type Resins, epoxy is at least a in ethylene glycol bisthioglycolate glycidyl ester, butyleneglycol 2-glycidyl ester, propylene glycol 2-glycidyl ester, glycerol 2-glycidyl ester or the glycidyl allyl ether;
Described wormer is selected from the evil spirit of going out, N, and benzamide, O-phthalic ester, mentha camphor, camphor, K-othrin, Simpleleaf Shrub Chastetree Fruit, Leaf of Camphortree juice, pyrethrin, dimethirn, dimethyl phthalate, Ricefield eel bone liquid, tortoise bone liquid, soft-shelled turtle bone liquid, Deltamethrin, OP-10, Permanone, Tetramethrin, esbiothrin, acetofenate, pulvis flores pyrethri, pamorusa oil, indoles, propine chrysanthemum ester, methylbenzyl chrysanthemumic acid, mustard oil, acetofenate, Ro 7-5050, enemy receive at least a in quick, Oleum Bulbus Allii or the lemon quintessence oil between the N-diethyl;
Described essence is selected from least a in cream jasmin france, chypre compound, lemon flavour, grapefruit essence, rose compound or the lavandula angustifolia essence.
5. but according to the matrix material of the releasing volatile substances persistently described in the claim 4, it is characterized in that: described wormer be to go out evil spirit, N, at least a between the N-diethyl in benzamide, mentha camphor, camphor or the pamorusa oil.
6. but according to the matrix material of the releasing volatile substances persistently described in the claim 5, it is characterized in that: described wormer is N, benzamide between the N-diethyl.
7. but according to the matrix material of the releasing volatile substances persistently described in the claim 1,2,3,4,5 or 6, it is characterized in that: also comprise 1～5 part emulsifying agent, described emulsifying agent is a sodium laurylsulfonate.
8. but according to the matrix material of the releasing volatile substances persistently described in the claim 7, it is characterized in that: also comprise 1～2 part volatile aids, described volatile aids is selected from least a in Syzygium aromaticum stem oil, Radix Aucklandiae oil, elm leaf oil, hawthorn leaf oil, Oleum Cinnamomi, Oil of Eucalyptus, Pinus pumilio oil, Japan cypress oil, Herba Menthae Rotundifoliae oil, shiu oil or the cedar(wood)oil.
9. but the preparation method of the matrix material of a releasing volatile substances persistently is characterized in that, comprises following step:
1) gets the raw materials ready according to component and weight proportion in the claim 1,2,3,4,5 or 6;
2) water, water-base resin and water-soluble stiffening agent are added in the stirred pot, water-base resin and water-soluble stiffening agent be scattered in form emulsion in the water, then add phase-transfer catalyst, natural fiber and filler and mix, mix back pressurized, heated to 150 a ℃ oven dry with kneader and form solid support material;
3) volatile matter is added carrier absorption.
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