CA2160682C

CA2160682C - Method of disposal of hot water soluble garments and like fabrics

Info

Publication number: CA2160682C
Application number: CA002160682A
Authority: CA
Inventors: Travis W. Honeycutt
Original assignee: Individual
Current assignee: Individual
Priority date: 1993-04-29
Filing date: 1994-04-28
Publication date: 2001-08-14
Anticipated expiration: 2014-04-28
Also published as: EP0701490A4; JPH08509659A; WO1994025189A1; EP0701490A1; CA2160682A1; JP2001286848A

Abstract

A method of disposing of garments after use. The garments, linens, drapes, towels and other useful articles are provided as woven, non-woven, knitted or otherwise formed fabric of thermoplastic polyvinyl alcohol polymer fiber, the fiber being water soluble only at temperatures above approximately 37 °C and preferably above 50 °C. After use, the fabric is subjected to water at a sufficient temperature to substantially dissolve the fabric whereupon the water and dissolved fabric are subjected to disposal.

Description

~ WO94125189 2i 6~68~ PCT~Sg4/04761 METHOD OF DISPOSAL OF
HOT WATER SOLUBLE GARMENTS AND LIKE FABRICS

TECHNICAL FIELD OF THE I~v~ ON
The present invention involves a method of disposing S of garments after use. Specifically, the garments are composed of non-woven, woven, knitted or otherwise formed film or fabric of thermoplastic polymer or fiber which are water soluble at temperatures only above approximately normal human body temperature (37C).
BACKGROUND OF THE lN V ~ N~l~loN
Hospital patient care generates considerable ~uantities of infectious medical waste in primary and acute care facilities. There has been a general conversion from reusable, cleanable items, to disposable items over the last three decades. These conversions were made to promote antiseptic t~chniques in patient care and to decrease the potential for cross-infections between patients, staff and the general public. Recent federal and state government regulations such as the Medical Waste Tracking Act of 1988 and OSHA Medical Facility rules have resulted in a substantial increase in medical waste that must be classified as "infectious."
When a patient is admitted to a hospital, the patient produces approximately 55 pounds of medical waste per day.
Approximately 20~ of this waste is infectious. The current stated objective of the American Hospital Association and the Centers for Disease Control is to treat medical waste as soon as it is generated. Both organizations recognize that medical waste is primarily an occupational hazard for health care workers and not an environmental problem. The best way to deal with infectious medical waste is to disinfect it at the point of generation and dispose of the treated medical waste with minimum handling and storage on premises.
The need for an effective way to dispose of medical waste has been highlighted by the amendment made to 29 C.F.R.
1910.1030 which provides for the federal regulation under the Occupational Safety And Health Act, 29 U.S.C. 655, 657 to WO94/25189 21~ ~ ~ 8 2 PCT~S94/04761 control bloodborne pathogens. Specifically, the Act calls for the establishment of an exposure control plan, the containment of specimens of blood or other potentially infectious materials and the general tightening of precautionary measures to minimize the spread of disease. A safe and effective way to dispose of hospital waste in the form of soiled garments and apparel would greatly facilitate ~compliance with the above-referenced Act. -~
As a result, consumption of me~ical disposable woven lo or non-woven products has been growing at a rate of approximately~10% a year. In 1988, sales totaled approximately 1.155 Billion Dollars. It is projected that by 1992, sales of medical disposable non-woven products will reach 1.54 Billion Dollars.
Disposable medical fabrics are generally currently composed of thermoplastic fibers such as polyethylene, polypropylene, polyesters, polyamides and acrylics. These fabrics can also include mixtures of thermoset fibers such as polyamides, polyarimids and cellulosics. They are typically 10-100 grams per square yard in weight and can be woven, knitted or otherwise formed by methods well known to those in the textile arts while the non-wovens can be thermobonded, hydroentangled, wet laid or needle punched and films can be formed by blow or cast extrusion or by solution casting.
Although there is clearly a benefit in the use of disposables in the medical arts by avoiding the necessity of human contact with medical waste which is necessary in the cleaning of comparable reusables, non-biodegradable disposables are posing a problem which is only now being recognized. Landfill sites are becoming increasingly burdened with disposables which do not biodegrade for hundreds of years, if ever. As landfill sites become fully exploited, new sites must be found which are rightfully opposed by residents located proximate to proposed site locations.
It is clear that others have produced useful articles which at least break down or are caused to change their physical confirmation when subjected to hot aqueous solutions.
For example, U.S. Patent No. 3,314,809 teaches the production of transparent flexible films from hydroxypropyl cellulose ~ W094/25189 21 6 a6S2 PCT~S94/04761 which is taught to be "insoluble in water until the water reaches a temperature of about 60 C." However, hydroxypropyl cellulose, unlike polyvinyl alcohol, does not solubilize in water but simply breaks down forming a cellulose derivative t 5 residue.
The prior art has recognized uses for polyvinyl alcohol compositions in the manufacture of water soluble useful articles. For example, U.S. Patent No. 3,413,229 teaches the production of water soluble bags or pouches from 10 which packets or the like are produced containing such materials as detergents, bleaches, insecticides, medicinals, chemicals, dyes, pigments, industrial additives and other materials. It is taught that the contents of the packets are dispersed merely by dropping the packets into water whereupon 15 the bags dissolve and release their contents into aqueous dispersions. However, the referenced patent teaches the production of such films which are both hot and cold water soluble.
Additional references, such as U.S. Patent No.
3,859,125 teach the production of layered articles which include coatings of polyvinyl alcohol. The subject reference teaches coating polyvinyl alcohol on a paper membrane whereby it is taught that the coated paper is soluble in either high or low temperature water. Again, it is incorrect to believe that a cellulose sheet material would be "soluble" in an aqueous solution. At best, cellulose merely disperses.
Similarly, U.S. Patent No. 4,343,133 teaches the coating of polyvinyl alcohol onto a non-woven fiber sheet impregnated with latices of polyvinyl acetate in the manufacture of a premoistened towelette which can be disposed of by flushing in plain water without danger of clogging a plumbing system.
There has been the teaching of various medical related products which are generally in the form of articles coated with polyvinyl alcohol employed to enhance disposal.
For example, European Patent Application No. 87310534.0 (Publication No. 0272816) teaches the production of an ostomy pouch which can be disposed of in a toilet bowel. The pouch is constructed from laminants of water swellable cold water insoluble films and water-resistant tissue paper. Similarly, WO94125189 i 216 0 6 ~ 2 PCT~S94/04761 U.K. Patent Application No. 2211088 teaches the production of a liner for a bed pan or urine bottle made of polyvinyl alcohol. It is taught that the liner may be disposed of by treatment with water at a temperature above that which it dissolves.
Both U.K. Patent No. 1,187,690 and Japanese Patent No. 72041741 teach the production of stand alone polyvinyl alcohol films which are water soluble. The U.K. patent teaches the production of hospital bags~and packing material for such products as detergents and agricultural chemicals while the Japanese patent teaches the use of polyvinyl alcohol films to make laundry bags which dissolve releasing soiled garments contained therein. However, neither reference teaches the unique films of the present invention which can be configured into useful garments and like materials and which are soluble in aqueous solutions only above a threshold value.
It is a desire in the creation of the present invention to provide a method of disposing of garments, linens, drapes, towels and other useful articles after use while avoiding additional burdens being placed upon landfill disposal sites.
It is yet a further desire to provide a method of disposing of garments, linens, drapes, towels and other useful articles after use such that the garment can be solubilized and medical waste substantially sterilized in a single operation.
These and further desires will be more readily appreciated while considering the following disclosure and appended claims.
SUMMARY OF THE INVENTION
The present invention involves a method of disposing of garments after use which comprises providing the garments as sheets or as woven, non-woven, knitted or otherwise formed fabric of thermoplastic polymer or fiber. The polymer or fabric garments are water soluble only at temperatures above approximately the normal body temperature (37C). The garments, linens, drapes, towels and other useful articles composed of said polymer formulation are subjected to water PCT~S94/04761 ~ WO94/25189 2 1 6 ~ 6 8 2 at a sufficient temperature to substantially dissolve the garments whereupon the water and dissolved polymer are subjected to disposal.

DETAILED DESCRIPTION OF THE INVENTION
The present invention deals with the disposal of film or fabric configured into such garments and articles as drapes, towels, covers, overwraps, gowns, head coverings, face masks, shoe coverings, CSR wraps, sponges, dressings, tapes, underpads, diapers, wash cloths, sheets, pillow covers, napkins and woven, non-woven, or otherwise formed fabric. Such products are generally employed in the medical industry both in hospitals, outpatient facilities and home environments.
Many of these products generally come into contact with human bodily fluids and their disposal and disinfection has become a matter of major concern in light of the lack of biodegradability of prior products and the potential spread of human fluid-born diseases such as hepatitis B and AIDS.
In order to cope with these difficulties, it is proposed that polymer or fabric employed in the manufacture of such items be composed of polymer films and/or fibers which are soluble in hot aqueous baths, including water, either alone or with the addition of surfactants, salts and bleaches above 37C and preferably above 50C. Such fibers or sheets would be insoluble in cold to warm baths below 37C, the average temperature of the human body. Ideally, the polymer or fabric would be soluble in baths only above 50C, and, most preferably the polymer or fabric garments would be soluble only in aqueous media between 80C to 90C.
Garments which are soluble in aqueous media below 37OC are useless as inadvertent secretion of bodily fluids such as blood and urine would cause the polymer to solubilize.
Working with polymer which dissolves only at higher temperatures such as above 50C or, ideally between 80C and 90C would prevent inadvertent solubilization yet remain ideal in practicing the present invention. It is contemplated that disposal in a hot water bath such as a washing machine at or near the boiling point of water dedicated solely to solubilizing garments, linens, drapes, towels and other useful W094/25189 216 ~ 6 8 2 PCT~S94/04761 articles produced herein would also be an effective disinfecting media. As such, two objectives would be accomplished, namely, that the polymer or sheets would be di~infected and would be solubilized for disposal through the sewer system. Not only would this lessen the burden now being r imposed upon current landfill sites but liguid sewer disposal would prove a comparative low cost technique in ridding the -user of such used garments.
Polymer or sheet mat~rials useful in practicing the lo present method comprise p~1yvinyl alcohol with or without acetyl groups, cross-linked or uncross-linked. The garments are comprised of polyvinyl alcohol homopolymer that has been highly crystallized by post drawing or heat annealing. Ideal for use in the present invention would be a highly crystallized, at least approximately 98% saponified polyvinyl acetate. Commercially, polyvinyl alcohol sold under the trademark Vinex 1003TM and 1002~ by Air Products could be used herein. Useful fibers are typically 0.5 denier to 5.0 denier and are preferably from 1.0-2.0 denier and most preferably sized at 1.2-1.5 denier. A commercially available product for use in the present invention is either type T-B
(VEE 1290) or type T-5 (VPB 101) which are each available from Kuralon as its PVA fiber. This material is sold in 44mm lengths. The T-B product is sized at 1.2 denier while the T-5 product is sold in 38mm staple lengths of 1.5 denier.
The fabric useful in practicing the present invention can be constructed by any well known technique for making woven, non-woven, knitted or otherwise formed fabric.
Such non-woven tech~iques useful in practicing the present invention include spun bonding, melt blowing or wet laying, hydroentangling with cold water and/or thermally bonding with 30-70% of the surface melted to form, for example, a diamond pattern. When products, such as diapers, are configured of sheets of suitable thermoplastic material, the sheets are approximately 1 to 6 mils in thickness and more preferably 1 to 3 mils in thickness and most preferably approximately 1.5 mils in thickness. Suitable non-woven fabric or sheets are approximately from 15g/yd2 to 200g/yd2 in weight and more preferably from 20g/yd2 to 70g/2 and most preferably from ~ W09412~189 7 216 0 6 8 2 PCT~S94/04761 25g/yd2 to 80g/yd2. Knitted or woven fabrics are approximately 50% heavier as needed for binding tapes, cuffs and related appendages.
As noted in U.K. Patent No. l,187,690, it is desirable to maintain a minimum level of moisture content of polyvinyl alcohol pellets prior to melt extrusion. The reference teaches that if moisture content of a film composition exceedæ two percent by weight, steam evolves during the melt extrusion leading to the formation of fine holes or cavities in the film.
However, while the present invention also contemplates drying to a level of approximately 0.5% (wt.) water or less the polyvinyl alcohol pellets before extrusion and, subsequent to the film formation, moisture is lS reintroduced back into the film to prevent brittleness and maintain usefulness. It is contemplated that the final PVA
film have between 1.5 to 15% (wt.), preferably 5 to 10% (wt.) and most preferably approximately 7.5% (wt.) moisture content.
In order to further enhance the usability of sheet material produced principally of polyvinyl alcohol, it is contemplated that an anti-blocking agent be employed to reduce hydrogen bonding between adjacent hydroxyl groups on separate sheets. Suitable anti--blocking agents are members selected from the group consisting of silicon dioxide (Sioz) polymer, talc, calcium carbonate and fumed hydrophilic SiO2. Such material should be employed between O.l to 5.0% (wt.) and most preferably between 2 to 3% (wt.) based upon the weight of the polyvinyl alcohol.
As noted previously, polymer or sheet material useful in practicing the present invention is comprised of polyvinyl alcohol with or without acetyl groups, cross-linked or uncross-linked. It is proposed that the polyvinyl alcohol be substantially fully hydrolyzed, that is, having 98% or greater hydrolyzed acetyl groups.
For the sake of adequate mechanical strength, polyvinyl alcohol-based sheet material should have a degree of polymerization of at least 700 and no greater than approximately 1500. Ideally, such materials should have a degree of polymerization of approximately 900 and be wo 94~2~189 2 ~ 6 0 ~ ~ 2 ~ PCT~S94/04761 substantially crystallized.
It is also noted that in producing polyvinyl alcohol resins from the saponification of polyvinyl acetate, impurities such as sodium acetate and sodium sulfate are found in the resin. To provide a suitable film material, such impurities must be kept below 1/2% (wt.) and preferably below 1/4% (wt.) of the polyvinyl alcohol resin. This can be accomplished with a methanol water rinse or extraction.
To enhance the manufa~cture of suitable polyvinyl alcohol resin-based film materials, suitable quantities of a plasticizer are necessary. It is contemplated that up to 15~
(wt.) of a suitable plasticizer such as glycerine or polyethylene glycol be employed to assist in providing a smooth melt extrusion from the polyvinyl alcohol-based pellets.

~ W094/25189 9 PCT~S94/04761 ~"" 21~0~82~
As examples the following fabric samples were manufactured on conventional thermal bonding equipment.

I.D. TL-0079.0 79.1 79.2 080.0 0080.1 Fibre Kuralon T-5 PVA (1.5 denier, 38 mm staple le~gth) 5 Pattern No. 2 2 2 Fabric Wt.
(gms/sq.yd) 27 44 47 35 43 ~hickness (mil) 15 12 17 14 16 Tensiles-10 (Grab-lbs) Dry MD 8.3 11.7 16.6 13.8 16.1 Wet MD 3.2 4.8 4.6 3.1 6.0 ~EY CD 2.0 2.3 4.3 3.8 5.2 Wet CD 1.0 1.5 1.7 1.3 2.3 Elongation(%) ~ry MD 11 10 12 12 11 pry CD 48 30 38 19 22 Mullen Burst (p8i) Dry 11 15 19 13 16 Wet 10 14 19 13 15 I.D. TL-0079.0 79.1 79.2 080.0 0080.1 Hanle-0-Meter (gms) 84 244 432 173 244 Trap Tear-MD1.7 2.1 3.5 2.7 2.9 CD 0.4 0.4 0.8 0.6 0.7 SUBSTlll~E SHEET (RULE 2~

1 0 PCT~S94/04761 W094/25189 ~ 21 ~ Q ~ ~ 2 It was found that the above-manufactured fabric displayed nearly identical physical properties similar to fabric manufactured from polyester and polypropylene. However, the fabric manufactured above was unaffected by cool or warm water (23-37C) but when exposed to hot water (80-90C), immediately dissolved.
It is oftentimes desirable that the film be colored with pigments or dyes such as azo or anthraquinone molecules.
U eful dyes include acids, basics, disperse, reactives and vats. The pigments and dyes should be employed in an amount between approximately 0.25 to 3.0% (wt.) based upon the weight of the polymeric polyvinyl alcohol.
Surprisingly, it has been found that the incorporation of a water repellent within the polyvinyl alcohol film or fabric is quite a useful adjunct to minimize surface attack by liquid moisture at a temperature lower than that at which solubility occurs. It has been found that even with polyvinyl alcohol films and fabrics which become water soluble only at elevated temperatures, when exposed to water, the surface of such material tends to take on a slick "feel"
and the use of water repellents tends to minimize this effect.
Suitable repellents include fluorocarbons offered by the Minnesota Mining and Manufacturing Co. sold under its trademarks FC 824 and 808. These materials are useful in the range of between 0.1 to 2.0% (wt.) based upon the weight of the polyvinyl alcohol polymer.

Claims

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:

1. A method of disposing of useful articles of garments, linens, drapes, and towels after use, comprising providing the useful articles as a stand alone thermoplastic polymer fabric of polyvinyl alcohol including polyvinyl alcohol fiber that has been highly crystallized by postdrawing or by heat annealing, is water soluble only at temperatures above 37°C and insoluble at temperatures below 37°C, and subjecting said articles after use to an aqueous bath to dissolve said articles whereupon said dissolved polymer is subjected to disposal, said polyvinyl alcohol polymer being produced from at least 98% saponified polyvinyl acetate.

2. The method of claim 1, wherein said fabric is woven, non-woven or knitted of said thermoplastic polymer.

3. The method of claim 1, wherein said thermoplastic polymer fabric is water soluble only at temperatures between 80°C and 90°C.

4. The method of claim 1, wherein said thermoplastic polymer fabric is water soluble at only temperatures above 50°C.

5. The method of claim 1, wherein said fiber is thermally bonded after hydroentanglement.

6. The method of claim 1, wherein 30-700 of the fabric surface is melted by thermal bonding.

7. The method of claim 1, wherein said polyvinyl alcohol polymer contains an anti-blocking agent comprised of a member selected from the group consisting of silicon dioxide polymer, talc, calcium carbonate and fumed hydrophilic silicon dioxide, said anti-blocking agent being contained in said polyvinyl alcohol in an amount between 2 to 3 wt.%, having a degree of polymerization of 900 and wherein any contaminants contained within said polymer of polyvinyl alcohol are maintained below 0.5 wt. %.

8. The method of claim 1, wherein said polyvinyl alcohol polymer further contains up to 15 wt.% of a plasticizer and wherein said plasticizer comprises a member selected from the group consisting of glycerine and polyethylene glycol.

9. The method of claim 1, wherein said fabric includes a coloring pigment or coloring dye, said coloring pigment comprises a member selected from the group consisting of an azo and anthraquinone molecule and wherein said coloring pigment or coloring dye is contained within said polymeric fabric in an amount of 0.25 to 3.0 wt. %.

10. The method of claim 1, wherein said polymeric fabric includes a water repellent agent said water repellent agent is contained within said polymeric fabric in an amount of 0.1 to 2.0 wt. %.

11. A method of disposing of useful articles after use, comprising providing the useful articles as a stand alone thermoplastic polymer fabric of polyvinyl alcohol including polyvinyl alcohol fiber that has been highly crystallized by postdrawing or by heat annealing, is water soluble only at temperatures above 37°C and insoluble at temperatures below 37°C, said thermoplastic polymer fabric being configured into a member selected from the group consisting of drapes, towels, covers, overwraps, gowns, head covers, face masks, shoe coverings, CSR wraps, sponges, dressings, tapes, underpads, diapers, wash cloths, sheets, pillow covers and napkins, and subjecting said articles after use to an aqueous bath to dissolve said articles whereupon said dissolved polymer is subjected to disposal, said polyvinyl alcohol polymer being produced from at least 98% saponified polyvinyl acetate.

12. Useful articles characterized as being water soluble only at temperatures above 37°C., said useful articles comprised of polymeric fabric of polyvinyl alcohol including polyvinyl alcohol fiber that has been highly crystallized by postdrawing or by heat annealing, said fabric or fiber being configured into one or more members selected from the group consisting of drapes, towels, covers, overwraps, gowns, head covers, face masks, shoe coverings, CSR wraps, sponges, dressings, tapes, underpads, diapers, wash cloths, sheets, pillow covers and napkins, said polyvinyl alcohol polymer being produced from crystalline at least 98% saponified polyvinyl acetate.

13. The useful articles of claim 12, wherein said polyvinyl alcohol polymer contains an anti-blocking agent comprised of a member selected from the group consisting of silicon dioxide polymer, talc, calcium carbonate and fumed hydrophilic silicon dioxide, said anti-blocking agent is contained in said polyvinyl alcohol in an amount between 2 to 3 wt.% said polyvinyl alcohol polymer has a degree of polymerization of 900, said polyvinyl alcohol polymer further contains up to 15 wt. % of a plasticizer, said plasticizer selected from the group consisting of glycerine and polyethylene glycol, any contaminants contained within said polymer of polyvinyl alcohol are maintained below 0.5 wt.o and said fabric is woven, non-woven or knitted of said thermoplastic polymer fiber.

14. The useful articles of claim 12, wherein said thermoplastic polymer is water soluble only at temperatures above 50°C.

15. The useful articles of claim 12, wherein said fabric is composed of a non-woven thermoplastic polymer of polyvinyl alcohol having a weight of 25-80g/yd2, said fiber is 0.5-5.0 denier in size, said fabric being prepared from said fiber by spun bonding; melt blowing, wet laying and hydroentangling said fiber, or thermally bonding said fiber.

16. The useful articles of claim 12, wherein said fabric is thermally bonded after hydroentanglement of said fiber.

17. The useful articles of claim 12, wherein 30-70% of the fabric surface is melted by thermal bonding.

18. The useful articles of claim 12, wherein said fabric includes a coloring pigment or coloring dye, said coloring pigment comprising a member selected from the group consisting of an azo and anthraquinone molecule, said coloring pigment or coloring dye being contained with said polymeric fabric in an amount of 0.25 to 3.0 wt.%.

19. The useful articles of claim 12, wherein said polymeric fabric includes a water repellent agent, said water repellent agent is contained within said polymeric fabric in an amount of 0.1 to 2.0 wt. %.