AU2014201719B2 - Well tools operable via thermal expansion resulting from reactive materials - Google Patents

Abstract

Methods of actuating a well tool can include releasing chemical energy from at least one portion of a reactive material, thermally expanding a substance in response to the 5 released chemical energy, and applying pressure to a piston as a result of thermally expanding the substance, thereby actuating the well tool, with these steps being repeated for each of multiple actuations of the well tool. A well tool actuator can include a substance contained in a chamber, one 10 or more portions of a reactive material from which chemical energy is released, and a piston to which pressure is applied due to thermal expansion of the substance in response to each release of chemical energy. A well tool actuator which can be actuated multiple times may include 15 multiple portions of a gas generating reactive material, and a piston to which pressure is applied due to generation of the gas. - - 12 30-- - A - 40 -- -- 14

Description

5 WELL TOOLS OPERABLE VIA THERMAL EXPANSION RESULTING FROM REACTIVE MATERIALS 10 TECHNICAL FIELD This disclosure relates generally to equipment utilized and operations performed in conjunction with a subterranean well and, in an example described below, more particularly provides well tools operable via thermal expansion resulting 15 from reactive materials. BACKGROUND Power for actuating downhole well tools can be supplied 20 from a variety of sources, such as batteries, compressed gas, etc. However, even though advancements have been made in supplying power for actuation of well tools, the various conventional means each have drawbacks (e.g., temperature limitations, operational safety, etc.) . Therefore, it will 25 be appreciated that improvements are needed in the art of actuating downhole well tools.

-2 SUMMARY In the disclosure below, well tool actuators and associated methods are provided which bring improvements to the art. One example is described below in 5 which a substance is thermally expanded to actuate a well tool. In one aspect there is provided a fluid sampler including: a chamber defined by a piston slidingly engaged in a well tool, wherein the chamber is configured to receive a fluid; a valve disposed in communication with the chamber and configured to selectively allow the fluid to be received into the chamber through the valve and to be discharged 10 from the chamber through the valve; a reactive material disposed in communication with the piston and configured to release chemical energy when activated to thermally expand the fluid to pressurize the chamber. In another aspect, there is provided a method including the steps of: positioning a fluid sampler within a well, wherein the fluid sampler includes: a chamber defined by a 15 piston slidingly engaged in a well tool; a valve disposed in communication with the chamber and configured to selectively allow fluid communication between an exterior of the fluid sampler and the chamber; and a reactive material disposed in communication with the piston and configured to pressurize the chamber upon activation; obtaining a sample of fluid in the chamber; releasing chemical energy from the reactive material to 20 generate a pressure; and transmitting the pressure to the sample through the piston. In yet another aspect, there is provided a method including the steps of: positioning a fluid sampler within a well, wherein the fluid sampler includes: a chamber defined by a piston slidingly engaged in a well tool; a valve disposed in communication with the chamber and configured to selectively allow fluid communication between an 25 exterior of the fluid sampler and the chamber; and a plurality of portions of a reactive material disposed in communication with the piston and configured to pressurize the chamber upon activation; obtaining a sample of fluid in the chamber; releasing chemical energy from at least one of the portions of the reactive material to generate a first pressure; transmitting the first pressure to the sample through the piston; releasing 30 chemical energy from at least one additional portion of the reactive material to generate a second pressure; and transmitting the second pressure to the sample through the piston. In a further aspect, a method of actuating a well tool multiple times in a well can include, for each of multiple actuations of the well tool while the well tool remains 20/08/15,dh-21595 - specipg2 - cdm.docx,2 -3 positioned in the well, performing the following set of steps: a) generating gas from at least one portion of a reactive material; and b) applying pressure to a piston as a result of generating gas from the portion of the reactive 5 material, thereby actuating the well tool. In a still further aspect, a well tool actuator is disclosed which includes multiple portions of a reactive material which generates gas; and a piston to which pressure is applied due to generation of gas by the reactive 10 material. These and other features, advantages and benefits will become apparent to one of ordinary skill in the art upon careful consideration of the detailed description of representative examples below and the accompanying drawings, 15 in which similar elements are indicated in the various figures using the same reference numbers. BRIEF DESCRIPTION OF THE DRAWINGS 20 FIG. 1 is a schematic partially cross-sectional view of a well system which can embody principles of the present disclosure. FIG. 2 is an enlarged scale schematic cross-sectional view of a well tool actuator which may be used in the system 25 of FIG. 1. FIGS. 3-5 are schematic cross-sectional views of another configuration of the well tool actuator, the actuator being depicted in various stages of actuation.

-4 FIGS. 6-8 are schematic cross-sectional views of another configuration of the well tool actuator, the actuator being depicted in various stages of actuation. FIGS. 9 & 10 are schematic cross-sectional views of 5 another configuration of the well tool actuator, the actuator being depicted prior to and after actuation. DETAILED DESCRIPTION Representatively illustrated in FIG. 1 are a well 10 system 10 and associated methods which embody principles of the present disclosure. The well system 10 includes a casing string or other type of tubular string 12 installed in a wellbore 14. A liner string or other type of tubular string 16 has been secured to the tubular string 12 by use 15 of a liner hanger or other type of well tool 18. The well tool 18 includes an anchoring device 48 and an actuator 50. The actuator 50 sets the anchoring device 48, so that the tubular string 16 is secured to the tubular string 12. The well tool 18 may also include a sealing 20 device (such as the sealing device 36 described below) for sealing between the tubular strings 12, 16 if desired. The well tool 18 is one example of a wide variety of well tools which may incorporate principles of this disclosure. Other types of well tools which may incorporate 25 the principles of this disclosure are described below. However, it should be clearly understood that the principles of this disclosure are not limited to use only with the well tools described herein, and these well tools may be used in other well systems and in other methods without departing 30 from the principles of this disclosure.

-5 In addition to the well tool 18, the well system 10 includes well tools 20, 22, 24, 26, 28 and 30. The well tool 20 includes a flow control device (for example, a valve or choke, etc.) for controlling flow between an interior and 5 exterior of a tubular string 32. As depicted in FIG. 1, the well tool 20 also controls flow between the interior of the tubular string 32 and a formation or zone 34 intersected by an extension of the wellbore 14. The well tool 22 is of the type known to those skilled 10 in the art as a packer. The well tool 22 includes a sealing device 36 and an actuator 38 for setting the sealing device, so that it prevents flow through an annulus 40 formed between the tubular strings 16, 32. The well tool 22 may also include an anchoring device (such as the anchoring 15 device 48 described above) for securing the tubular string 32 to the tubular string 16, if desired. The well tool 24 includes a flow control device (for example, a valve or choke, etc.) for controlling flow between the annulus 40 and the interior of the tubular 20 string 32. As depicted in FIG. 1, the well tool 24 is positioned with a well screen assembly 42 in the wellbore 14. Preferably, the flow control device of the well tool 24 allows the tubular string 32 to fill as it is lowered into the well (so that the flow does not have to pass through the 25 screen assembly 42, which might damage or clog the screen) and then, after installation, the flow control device closes (so that the flow of fluid from a zone 44 intersected by the wellbore 14 to the interior of the tubular string is filtered by the screen assembly). 30 The well tool 26 is of the type known to those skilled in the art as a firing head. The well tool 26 is used to -6 detonate perforating guns 46. Preferably, the well tool 26 includes features which prevent the perforating guns 46 from being detonated until they have been safely installed in the well. 5 The well tool 28 is of the type known to those skilled in the art as a cementing shoe or cementing valve. Preferably, the well tool 28 allows the tubular string 16 to fill with fluid as it is being installed in the well, and then, after installation but prior to cementing the tubular 10 string in the well, the well tool permits only one-way flow (for example, in the manner of a check valve). The well tool 30 is of the type known to those skilled in the art as a formation isolation valve or fluid loss control valve. Preferably, the well tool 30 prevents 15 downwardly directed flow (as viewed in FIG. 1) through an interior flow passage of the tubular string 32, for example, to prevent loss of well fluid to the zone 44 during completion operations. Eventually, the well tool 30 is actuated to permit downwardly directed flow (for example, to 20 allow unrestricted access or flow therethrough). Although only the actuators 38, 50 have been described above for actuating the well tools 18, 22, it should be understood that any of the other well tools 20, 24, 26, 28, 30 may also include actuators. However, it is not necessary 25 for any of the well tools 18, 20, 22, 24, 26, 28, 30 to include a separate actuator in keeping with the principles of this disclosure. It should also be understood that any type of well tool can be actuated using the principles of this disclosure. 30 For example, inaddition to the well tools 18, 20, 22, 24, 26, 28, 30 described above, various types of production -7 valves, formation fluid samplers, packers, plugs, liner hangers, sand control devices, safety valves, etc., can be actuated. The principles of this disclosure can be utilized in drilling tools, wireline tools, slickline tools, tools 5 that are dropped in the well, tools that are pumped in the well, or any other type of well tool. Referring additionally now to FIG. 2, a well tool actuator 54 which embodies principles of this disclosure is representatively illustrated. The actuator 54 is used to 10 actuate a well tool 56. The well tool 56 may be any of the well tools 18, 20, 22, 24, 26, 28, 30 described above, or any other type of well tool. The actuator 54 may be used for any of the actuators 38, 50 in the system 10, or the actuator 54 may be used in any other well system. 15 As depicted in FIG. 2, the actuator 54 includes an annular piston 58 which separates two annular chambers 60, 62. A thermally expandable substance 64 is disposed in each chamber 60, 62. The substance 64 could comprise a gas (such as, argon or nitrogen, etc.), a liquid (such as, water or 20 alcohol, etc.) and/or a solid. Portions 66 of a reactive material 68 are used to thermally expand the substance 64 and thereby apply a differential pressure across the piston 58. The piston 58 may in some embodiments displace as a result of the biasing 25 force due to the differential pressure across the piston to thereby actuate the well tool 56, or the biasing force may be used to actuate the well tool without requiring much (if any) displacement of the piston. A latching mechanism (not shown) could restrict 30 movement of the piston 58 until activation of the reactive material 68. For example, there could be a shear pin - 8 initially preventing displacement of the piston 58, so that the differential pressure across the piston has to increase to a predetermined level for the shear pin to shear and release the piston for displacement. Alternatively, or in 5 addition, an elastomeric element (such as an o-ring on the piston 58) may be used to provide friction to thereby hold the piston in position prior to activation of the reactive material 68. In the example of FIG. 2, chemical energy may be 10 released from one of the portions 66 of the reactive material 68 on a lower side of the piston 58 to cause thermal expansion of the substance 64 in the lower chamber 62. This thermal expansion of the substance 64 in the lower chamber 62 will cause an increased pressure to be applied to 15 a lower side of the piston 58, thereby biasing the piston upward and actuating the well tool 56 in one manner (e.g., closing a valve, setting an anchoring device, etc.). The piston 58 may displace upward to actuate the well tool 56 in response to the biasing force generated by the thermally 20 expanded substance 64. Chemical energy may then be released from one of the portions 66 of the reactive material 68 on an upper side of the piston 58 to cause thermal expansion of the substance 64 in the upper chamber 60. This thermal expansion of the 25 substance 64 in the upper chamber 60 will cause an increased pressure to be applied to an upper side of the piston 58, thereby biasing the piston downward and actuating the well tool 56 in another manner (e.g., opening a valve, unsetting an anchoring device, etc.) . The piston 58 may displace 30 downward to actuate the well tool 56 in response to the biasing force generated by the thermally expanded substance 64.

-9 In one beneficial feature of the actuator 54 as depicted in FIG. 2, this method of actuating the well tool 56 may be repeated as desired. For this purpose, multiple portions 66 of the reactive material 68 are available for 5 causing thermal expansion of the substance 64 both above and below the piston 58. Although only two portions 66 are visible in FIG. 2 positioned above and below the piston 58, any number of portions may be used, as desired. The portions 66 may be 10 radially distributed in the ends of the chambers 60, 62 (as depicted in FIG. 2), the portions could be positioned on only one side of the piston 58 (with passages being used to connect some of the portions to the opposite side of the piston), the portions could be stacked longitudinally, etc. 15 Thus, it will be appreciated that the portions 66 of the reactive material 68 could be located in any positions relative to the piston 58 and chambers 60, 62 in keeping with the principles of this disclosure. As depicted in FIG. 2, multiple portions 66 of the 20 reactive material 68 are used for expanding the substance 64 in the chamber 60, and a similar multiple portions 66 are used for expanding the substance 64 in the chamber 62. However, in other examples, each portion 66 of reactive material 68 could be used to expand a substance in a 25 respective separate chamber, so that the portions do not "share" a chamber. A passage 70 is provided for gradually equalizing pressure across the piston 58 after the substance 64 has been expanded in either of the chambers 60, 62. The passage 30 70 may be in the form of an orifice or other type of restrictive passage which permits sufficient pressure - 10 differential to be created across the piston 58 for actuation of the well tool 56 when the substance 64 is expanded in one of the chambers 60, 62. After the well tool 56 has been actuated, pressure in the chambers 60, 62 is 5 equalized via the passage 70, thereby providing for subsequent actuation of the well tool, if desired. The reactive material 68 is preferably a material which is thermally stable and non-explosive. A suitable material is known as thermite (typically provided as a mixture of 10 powdered aluminum and iron oxide or copper oxide, along with an optional binder). When heated to ignition temperature, an exothermic reaction takes place in which the aluminum is oxidized and elemental iron or copper results. Ignition heat may be 15 provided in the actuator 54 by electrical current (e.g., supplied by batteries 72) flowing through resistance elements (not visible in FIG. 2) in the portions 66. However, note that any source of ignition heat (e.g., detonators, fuses, etc.) may be used in keeping with the 20 principles of this disclosure. The reactive material 68 preferably produces substantial heat as chemical energy is released from the material. This heat is used to thermally expand the substance 64 and thereby apply pressure to the piston 58 to 25 actuate the well tool 56. Heating of the substance 64 may cause a phase change in the substance (e.g., liquid to gas, solid to liquid, or solid to gas), in which case increased thermal expansion can result. Release of chemical energy from the reactive material 30 68 may also result in increased pressure itself (e.g., due to release of products of combustion, generation of gas, - 11 etc.). Alternatively, activation of the reactive material 68 may produce pressure primarily as a result of gas generation, rather than production of heat. Note that thermite is only one example of a suitable 5 reactive material which may be used for the reactive material 68 in the actuator 54. Other types of reactive materials may be used in keeping with the principles of this disclosure. Any type of reactive material from which sufficient chemical energy can be released may be used for 10 the reactive material 68. Preferably, the reactive material 68 comprises no (or only a minimal amount of) explosive. For example, a propellant could be used for the reactive material 68. In various examples, the reactive material 68 may 15 comprise an explosive, a propellant and/or a flammable solid, etc. The reactive material 68 may function exclusively or primarily as a gas generator, or as a heat generator. Electronic circuitry 74 may be used to control the 20 selection and timing of ignition of the individual portions 66. Operation of the circuitry 74 may be telemetry controlled (e.g., by electromagnetic, acoustic, pressure pulse, pipe manipulation, any wired or wireless telemetry method, etc.) . For example, a sensor 76 could be connected 25 to the circuitry 74 and used to detect pressure, vibration, electromagnetic radiation, stress, strain, or any other signal transmission parameter. Upon detection of an appropriate telemetry signal, the circuitry 74 would ignite an appropriate one or more of the portions 66 to thereby 30 actuate the well tool 56.

- 12 Note that the reactive material 68 is not necessarily electrically activated. For example, the reactive material 68 could be mechanically activated (e.g., by impacting a percussive detonator), or heated to activation temperature 5 by compression (e.g., upon rupturing a rupture disk at a preselected pressure, a piston could compress the reactive material 68 in a chamber). Referring additionally now to FIGS. 3-5, another configuration of the actuator 54 is representatively and 10 schematically illustrated. As depicted in FIGS. 3-5, only a single portion 66 of the reactive material 68 is used, but multiple portions could be used, as described more fully below. In the example of FIGS. 3-5, the substance 64 comprises 15 water, which is prevented from boiling at downhole temperatures by a biasing device 78 which pressurizes the water. The biasing device 78 in this example comprises a gas spring (such as a chamber 80 having pressurized nitrogen gas therein), but other types of biasing devices (such as a 20 coil or wave spring, etc.) may be used, if desired. In this example, the substance 64 is compressed by the biasing device 78 prior to conveying the well tool into the well. In other examples, the substance 64 (such as water) could be prevented from boiling prematurely by preventing 25 displacement of the piston 58. Shear pins, a release mechanism, high friction seals, etc. may be used to prevent or restrict displacement of the piston 58. Of course, if the anticipated downhole temperature does not exceed the boiling (or other phase change) temperature of the substance 30 64, then it is not necessary to provide any means to prevent boiling (or other phase change) of the substance.

- 13 In FIG. 3, the actuator 54 is depicted at a surface condition, in which the nitrogen gas is pressurized to a relatively low pressure, sufficient to prevent the water from boiling at downhole temperatures, but not sufficiently 5 high to create a safety hazard at the surface. For example, at surface the nitrogen gas could be pressurized to approximately 10 bar (-150 psi). In FIG. 4, the actuator 54 is depicted at a downhole condition, in which chemical energy has been released from 10 the reactive material 68, thereby thermally expanding the substance 64 and applying a pressure differential across the piston 58. In this example, the piston 58 does not displace appreciably (or at all) when the well tool 56 is actuated. However, preliminary calculations suggest that substantial 15 force can be generated to actuate the well tool 56, for example, resulting from up to approximately 7000 bar (~105,000 psi) pressure differential being created across the piston 58. In FIG. 5, the actuator 54 is depicted at a downhole 20 condition, in which chemical energy has been released from the reactive material 68, thereby thermally expanding the substance 64 and applying a pressure differential across the piston 58, as in the example of FIG. 4. However, in the example of FIG. 5, the piston 58 displaces in response to 25 the thermal expansion of the substance 64, in order to actuate the well tool 56. Depending on the amount of displacement of the piston 58, approximately 750-1900 bar (~10-25,000 psi) pressure differential may remain across the piston 58 at the end of its displacement. 30 Multiple actuations of the well tool 56 may be accomplished by allowing the substance 64 to cool, thereby - 14 relieving (or at least reducing) the thermal expansion of the substance 64 and, thus, the pressure differential across the piston 58. When the substance 64 is sufficiently cooled, another portion 66 of the reactive material 68 may 5 be ignited to again cause thermal expansion of the substance 64. For this purpose, multiple portions 66 of the reactive material 68 may be connected to, within, or otherwise communicable with, the chamber 60. In the example of FIG. 5, the piston 58 will displace 10 downward each time the substance 64 is thermally expanded, and the piston will displace upward each time the substance is allowed to cool. The batteries 72, electronic circuitry 74 and sensor 76 may be used as described above to selectively and individually control ignition of each of 15 multiple portions 66 of the reactive material 68. In some applications, it may be desirable to incorporate a latching mechanism or friction producer to prevent displacement of the piston 58 when the substance 64 cools. For example, in a formation fluid sampler, a one-way 20 latch mechanism would be useful to maintain pressure on a sampled formation fluid as it is retrieved to the surface. The substance 64 and portion 66 shape can be configured to control the manner in which chemical energy is released from the substance. For example, a grain size of the 25 substance 64 can be increased or reduced, the composition can be altered, etc., to control the amount of heat generated and the rate at which the heat is generated. As another example, the portion 66 can be more distributed (e.g., elongated, shaped as a long rod, etc.) to slow the 30 rate of heat generation, or the portion can be compact - 15 (e.g., shaped as a sphere or cube, etc.) to increase the rate of heat generation. Referring additionally now to FIGS. 6-8, another configuration of the actuator 54 is representatively and 5 schematically illustrated. The configuration of FIGS. 6-8 is similar in many respects to the configuration of FIGS. 3 5. However, a significant difference in the configuration of FIGS. 6-8 is that the biasing device 78 utilizes hydrostatic pressure in the well to compress or pressurize 10 the substance 64. In the example of FIGS. 6-8, the substance 64 comprises a gas, such as nitrogen. However, other thermally expandable substances may be used in the configuration of FIGS. 6-8, if desired. 15 In FIG. 6, the actuator 54 is depicted in a surface condition, prior to being conveyed into the well. Preferably the substance 64 is pressurized in the chamber 60. For example, if nitrogen gas is used for the substance 64, the gas can conveniently be pressurized to approximately 20 200 bar (-3,000 psi) at the surface using conventional equipment. In FIG. 7, the actuator 54 is depicted in a downhole condition, i.e., after the actuator has been conveyed into the well. Hydrostatic pressure enters the chamber 80 via a 25 port 82 and, depending on the particular pressures, the piston areas exposed to the pressures, etc., the piston 58 displaces upward relative to its FIG. 6 configuration. This further compresses the substance 64 in the chamber 60. If, instead of nitrogen gas, the substance 64 comprises water or 30 another substance which would otherwise undergo a phase change at downhole temperatures, this compression of the - 16 substance by the hydrostatic pressure in the chamber 80 can prevent the phase change occurring prematurely or otherwise undesirably. Hydrostatic pressure in the chamber 80 is only one type 5 of biasing device which may be used to compress the substance 64 in the chamber 60. The substance 64 could also, or alternatively, be mechanically compressed (e.g., using a coiled or wave spring to bias the piston 58 upward) or otherwise compressed (e.g., using a compressed fluid 10 spring in the chamber 80) in keeping with the principles of this disclosure. If a biasing device such as a spring is used, the substance 64 can be compressed prior to conveying the well tool into the well. An initial actuation or arming of the well tool 56 may 15 occur when the piston 58 displaces upward from the FIG. 6 configuration to the FIG. 7 configuration. Alternatively, the well tool 56 may only actuate when the piston 58 displaces downward. In FIG. 8, the piston 58 has displaced downward from 20 the FIG. 7 configuration, due to release of chemical energy from the reactive material 68. This energy heats the substance 64 and causes it to thermally expand, thereby increasing pressure in the chamber 60 and biasing the piston 58 downward. 25 As with the configuration of FIGS. 3-5, multiple actuations of the well tool 56 may be accomplished with the configuration of FIGS. 6-8 by allowing the substance 64 to cool, thereby relieving (or at least reducing) the thermal expansion of the substance 64. The hydrostatic pressure in 30 the chamber 80 can then bias the piston 58 to displace upward (e.g., to or near its FIG. 7 position). When the - 17 substance 64 is sufficiently cooled, another portion 66 of the reactive material 68 may be ignited to again cause thermal expansion of the substance 64. For this purpose, multiple portions 66 of the reactive material 68 may be 5 connected to, within, or otherwise communicable with, the chamber 60. Referring additionally now to FIGS. 9 and 10, another configuration of the actuator 54 is representatively and schematically illustrated. The configuration of FIGS. 9 and 10 10 is similar in many respects to the configurations of FIGS. 3-8. However, one significant difference is that, in the configuration of FIGS. 9 and 10, thermal expansion of the substance 64 is used to compress a sample of formation fluid 84 in the chamber 80 (e.g., to maintain the formation 15 fluid pressurized as it is retrieved to the surface, and to thereby prevent a phase change from occurring in the formation fluid as it is retrieved to the surface). The well tool 56 in this example comprises a formation fluid sampler of the type well known to those skilled in the 20 art. However, in the example of FIGS. 9 and 10, the formation fluid sample 84 is received into the chamber 80 via a passage 86 and a valve 88, with the valve being closed after the formation fluid sample is received into the chamber. Note that the valve 88 is another type of well 25 tool which can be actuated using the principles of this disclosure. In FIG. 9, the actuator 54 is depicted as the formation fluid sample 84 is being received into the chamber 80. The valve 88 is open, and the formation fluid sample 84 flows 30 via the passage 86 and valve into the chamber 80, thereby displacing the piston 58 upward and compressing the - 18 substance 64 in the chamber 60. Preferably, a metering device (not shown) is used to limit a displacement speed of the piston 58, so that the sample 84 received in the chamber 80 remains representative of its state when received from 5 the formation. The substance 64 may or may not be pressurized prior to the formation fluid sample 84 being received into the chamber 80. For example, if the substance 64 comprises a gas (such as nitrogen gas), the substance could conveniently 10 be pressurized to approximately 200 bar (~3,000 psi) at the surface using conventional equipment, prior to conveying the actuator 54 and well tool 56 into the well. In FIG. 10, the formation fluid sample 84 has been received into the chamber 80, and the valve 88 has been 15 closed. Chemical energy has then been released from the reactive material 68, thereby heating and thermally expanding the substance 64. The piston 58 transmits pressure between the chambers 60, 80. In this manner, the formation fluid sample 84 will remain pressurized as the 20 actuator 54 and well tool 56 are retrieved to the surface. In situations where the substance 64 could cool and undesirably reduce pressure applied to the sample 84 as the well tool is retrieved to the surface, a latching mechanism (not shown) may be used to maintain pressure in the chamber 25 80 as the well tool is conveyed out of the well. Alternatively, or in addition, a check valve (not shown) and a compressible fluid can be used to maintain pressure on the sample 84 when the substance 64 cools. Multiple portions 66 of the reactive material 68 could 30 be provided in the example of FIGS. 9 & 10 so that, as the well tool is retrieved from the well, additional portions of - 19 the reactive material could be activated as needed to maintain a desired pressure on the sample 84. A pressure sensor (not shown) could be used to monitor pressure on the sample 84 and, when the pressure decreases to a 5 predetermined level as the substance 64 cools, an additional portion 66 of the reactive material 68 could be activated. In this embodiment, the reactive material 68 preferably functions primarily as a gas generator, rather than as a heat generator. In that case, the substance 64 may not be 10 used, since pressure in the chamber 60 can be generated by production of gas from the reactive material. The substance 64 is also not required in any of the other embodiments described above, if the reactive material 68 can generate sufficient pressure due to gas production when the reactive 15 material is activated. In each of the examples described above in which multiple portions 66 of reactive material 68 may be used, note that the portions can be isolated from each other (for example, to prevent activation of one portion from causing 20 activation or preventing activation of another portion). A phenolic material is one example of a suitable material which could serve to isolate the multiple portions 66 from each other. Furthermore, each of the portions 66 of reactive 25 material 68 described above could be encapsulated (for example, to prevent contamination or oxidation of the reactive material by the working fluid). It may now be fully appreciated that the above disclosure provides several advancements to the art of 30 actuating downhole well tools. In examples described above, well tools are actuated in a convenient, effective and - 20 efficient manner, without necessarily requiring use of explosives or highly pressurized containers at the surface. In some of the examples described above, the actuators can be remotely controlled via telemetry, and the actuators can 5 be operated multiple times downhole. The above disclosure provides a method of actuating a well tool 56 in a well. The method can include: a) releasing chemical energy from at least one portion 66 of a reactive material 68; b) thermally expanding a substance 64 10 in response to the released chemical energy; and c) applying pressure to a piston 58 as a result of thermally expanding the substance 64, thereby actuating the well tool 56. The method can also include the above listed set of steps multiple times while the well tool 56 is positioned 15 downhole. The method can include allowing the substance 64 to cool between each successive set of steps. The method can include reducing pressure applied to the piston 58 as a result of allowing the substance 64 to cool. 20 The method can include displacing the piston 58 as a result of allowing the substance 64 to cool. The method can include displacing the piston 58 in one direction as a result of applying pressure to the piston 58; and displacing the piston 58 in an opposite direction as a 25 result of allowing the substance 64 to cool after thermally expanding the substance. The method can include compressing the substance 64 due to hydrostatic pressure while conveying the well tool 56 into the well.

- 21 The method can include compressing a formation fluid sample 84 as a result of applying pressure to the piston 58. The thermally expanding step can include changing a phase of the substance 64. 5 The step of releasing chemical energy can include oxidizing an aluminum component of the reactive material 68. Also provided by the above disclosure is a method of actuating a well tool 56 multiple times in a well. The method can include, for each of multiple actuations of the 10 well tool 56, performing the following set of steps: a) releasing chemical energy from at least one portion 66 of a reactive material 68; b) thermally expanding a substance 64 in response to the released chemical energy; and 15 c) applying pressure to a piston 58 as a result of thermally expanding the substance 64, thereby actuating the well tool 56. The above disclosure also describes a well tool actuator 54 which can include a substance 64 contained in a 20 chamber 60, one or more portions 66 of a reactive material 68 from which chemical energy is released, and a piston 58 to which pressure is applied due to thermal expansion of the substance 64 in response to release of chemical energy from the reactive material 68. 25 Hydrostatic pressure in a well may compress the substance 64 in the chamber 60. The piston 58 may displace in response to the applied pressure.

- 22 Chemical energy may be released from multiple portions 66 individually. Chemical energy released from the reactive material 68 in a first one of the portions 66 may cause thermal 5 expansion of the substance 64 in the chamber 60, and chemical energy released from the reactive material 68 in a second one of the portions 66 may cause thermal expansion of the substance 64 in another chamber 62. The piston 58 may displace in one direction in response to thermal expansion 10 of the substance 64 in the first chamber 60, and the piston 58 may displace in an opposite direction in response to thermal expansion of the substance 64 in the second chamber 62. The actuator 54 may include a passage 70 which 15 equalizes pressure across the piston 58. The substance 64 may comprise a solid, liquid and/or a gas. The reactive material 68 may comprise aluminum and at least one of iron oxide and copper oxide. 20 The above disclosure also provides a method of actuating a well tool 56 multiple times in a well, the method comprising: for each of multiple actuations of the well tool 56 while the well tool 56 remains positioned in the well, performing the following set of steps: a) 25 generating gas from at least one portion 66 of a reactive material 68; and b) applying pressure to a piston 58 as a result of generating gas from the portion 66 of the reactive material 68, thereby actuating the well tool 56. The method may include allowing the gas to cool between 30 each successive set of steps. The pressure applied to the - 23 piston may be reduced as a result of allowing the gas to cool. The piston may displace as a result of allowing the gas to cool. The piston may displace in one direction as a result of 5 each step of applying pressure to the piston, and the piston may displace in an opposite direction as a result of allowing the gas to cool. Also described in the above disclosure is a well tool actuator 54 which includes multiple portions 66 of a 10 reactive material 68 which generates gas, and a piston 58 to which pressure is applied due to generation of gas by the reactive material 68. The piston 58 may displace in response to the applied pressure. The gas may be generated from the multiple 15 portions 66 individually and/or sequentially. The piston 58 may displace in one direction in response to generation of gas from a first one of the portions 66 of reactive material 68, and the piston may displace in an opposite direction in response to generation of gas from a 20 second one of the portions 66 of reactive material 68. The well tool actuator 54 can include a passage 70 which equalizes pressure across the piston 58. It is to be understood that the various examples described above may be utilized in various orientations, 25 such as inclined, inverted, horizontal, vertical, etc., and in various configurations, without departing from the principles of the present disclosure. The embodiments illustrated in the drawings are depicted and described merely as examples of useful applications of the principles -24 of the disclosure, which are not limited to any specific details of these embodiments. In the above description of the representative examples of the disclosure, directional terms, such as "above," "below," "upper," "lower," "upward," "downward," etc., are used for convenience in referring to the accompanying 5 drawings. The above-described upward and downward displacements of the piston 58 are merely for illustrative purposes, and the piston 58 may displace in any direction(s) in keeping with the principles of this disclosure. Of course, a person skilled in the art would, upon a careful consideration of the above description of representative embodiments, readily appreciate that many 10 modifications, additions, substitutions, deletions, and other changes may be made to these specific embodiments, and such changes are within the scope of the principles of the present disclosure. Accordingly, the foregoing detailed description is to be clearly understood as being given by way of illustration and example only, the spirit and scope of the present invention being limited solely by the appended claims and 15 their equivalents. Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", and variations such as "comprises" and "comprising", will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or 20 group of integers or steps. The reference to any prior art in this specification is not, and should not, be taken as an acknowledgment or any form or suggestion that the prior art forms part of the common general knowledge in Australia. This Application is a divisional of the present applicant's Australian Patent 25 Application No. 2010341610, and the whole contents thereof are incorporated herein by reference. 20/03/14,dh-21595 - specipg24 - edn.docx,24

Claims (20)

1. A fluid sampler including: a chamber defined by a piston slidingly engaged in a well tool, wherein the 5 chamber is configured to receive a fluid; a valve disposed in communication with the chamber and configured to selectively allow the fluid to be received into the chamber through the valve and to be discharged from the chamber through the valve; a reactive material disposed in communication with the piston and 10 configured to release chemical energy when activated to thermally expand the fluid to pressurize the chamber.

2. The fluid sampler of claim 1 further including a metering device configured to limit a displacement speed of the piston. 15

3. The fluid sampler of claim 1 further including a latching mechanism to maintain pressure on the chamber.

4. The fluid sampler of claim 1 further including a plurality of reactive 20 material portions disposed in communication with the piston and configured to pressure the chamber upon activation.

5. The fluid sampler of claim 4 further including a pressure sensor configured to monitor the pressure of formation fluid in the chamber and activate one or more 25 portions of the reactive material to maintain the pressure of the fluid sample.

6. The fluid sampler of claim 4 wherein each of the plurality of reactive material portions are encapsulated. 30

7. A method including the steps of: positioning a fluid sampler within a well, wherein the fluid sampler includes: 20/08/15,dh-21595 - claims - cdm.docx,25 - 26 a chamber defined by a piston slidingly engaged in a well tool; a valve disposed in communication with the chamber and configured to selectively allow fluid communication between an exterior of the fluid sampler and the chamber; and 5 a reactive material disposed in communication with the piston and configured to pressurize the chamber upon activation; obtaining a sample of fluid in the chamber; releasing chemical energy from the reactive material to generate a pressure; and 10 transmitting the pressure to the sample through the piston.

8. The method of claim 7 further including limiting a displacement speed of the piston to maintain the sample in a representative state as received. 15

9. The method of claim 7 further including maintaining pressure on the chamber using a latching mechanism, a check valve, or both.

10. The method of claim 7, wherein the reactive material includes a plurality of portions of reactive material, and wherein releasing chemical energy from the 20 reactive material comprises selectively activating at least one of the portions of reactive material.

11. The method of claim 7 wherein releasing chemical energy from the reactive material includes generating a gas from the reactive material. 25

12. The method of claim 7 wherein releasing chemical energy from the reactive material includes oxidizing an aluminum component of the reactive material.

13. The method of claim 7 wherein the reactive material includes aluminum and 30 at least one substance selected from the group consisting of: iron oxide and copper oxide. 20/08/15,dli-21595 - claims - edm.doex,26 -27

14. A method including the steps of: positioning a fluid sampler within a well, wherein the fluid sampler includes: a chamber defined by a piston slidingly engaged in a well tool; 5 a valve disposed in communication with the chamber and configured to selectively allow fluid communication between an exterior of the fluid sampler and the chamber; and a plurality of portions of a reactive material disposed in communication with the piston and configured to pressurize the chamber upon activation; 10 obtaining a sample of fluid in the chamber; releasing chemical energy from at least one of the portions of the reactive material to generate a first pressure; transmitting the first pressure to the sample through the piston; releasing chemical energy from at least one additional portion of the 15 reactive material to generate a second pressure; and transmitting the second pressure to the sample through the piston.

15. The method of claim 14 wherein releasing chemical energy from at least one of the portions of the reactive material includes generating a gas from the 20 reactive material.

16. The method of claim 14 further including retrieving the fluid sampler from the well. 25

17. The method of claim 14 wherein the plurality of portions of the reactive material are isolated from each other.

18. The method of claim 14 at least one of the plurality of portions of the reactive material is encapsulated. 30

19. The method of claim 14 wherein the reactive material includes an explosive, a propellant, a flammable solid, or any combination thereof. 20/08/15,dh-21595 - claims - cdi.docx,27 -28

20. The method of claim 14 wherein the reactive material includes aluminum and at least one substance selected from the group consisting of: iron oxide and copper oxide. 20/08/15,dh-21595 - claims - edin.docx,28