AU2000254079A1 - Method for obtaining hydrogen by partial methanol oxidation - Google Patents

Method for obtaining hydrogen by partial methanol oxidation

Info

Publication number
AU2000254079A1
AU2000254079A1 AU2000254079A AU5407900A AU2000254079A1 AU 2000254079 A1 AU2000254079 A1 AU 2000254079A1 AU 2000254079 A AU2000254079 A AU 2000254079A AU 5407900 A AU5407900 A AU 5407900A AU 2000254079 A1 AU2000254079 A1 AU 2000254079A1
Authority
AU
Australia
Prior art keywords
aluminium
copper
iii
oxide
methanol oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2000254079A
Inventor
Umberto-Michele Costantino
Jose-Luis Garcia Fierro
Luisa-Maria Gomez Sainero
Sonia Murcia Mascaros
Morena Nocchetti
Miguel-Antonio Pena Jimenez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Publication of AU2000254079A1 publication Critical patent/AU2000254079A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1223—Methanol
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The method consists of placing in contact methanol, oxygen and optionally water with a catalyst consisting of copper (II) oxide, zinc (II) oxide, aluminium (III) oxide and copper (II) and aluminium (III) spinel, with the following molar percentages of the metals with respect to the total: Cu (15-75%). Zn (5-60%) and Al (3-50%). The catalyst is obtained by adding urea to a solution of water-soluble salts of copper (II), zinc (II) and aluminium (III) by co-precipitation of the components.
AU2000254079A 2000-06-22 2000-06-22 Method for obtaining hydrogen by partial methanol oxidation Abandoned AU2000254079A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/ES2000/000221 WO2001098202A1 (en) 2000-06-22 2000-06-22 Method for obtaining hydrogen by partial methanol oxidation

Publications (1)

Publication Number Publication Date
AU2000254079A1 true AU2000254079A1 (en) 2002-01-02

Family

ID=8244240

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2000254079A Abandoned AU2000254079A1 (en) 2000-06-22 2000-06-22 Method for obtaining hydrogen by partial methanol oxidation

Country Status (11)

Country Link
US (1) US20030216255A1 (en)
EP (1) EP1298089B1 (en)
JP (1) JP2004500980A (en)
AT (1) ATE287377T1 (en)
AU (1) AU2000254079A1 (en)
BR (1) BR0017292A (en)
DE (1) DE60017611T2 (en)
DK (1) DK1298089T3 (en)
ES (1) ES2234618T3 (en)
PT (1) PT1298089E (en)
WO (1) WO2001098202A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10225945A1 (en) * 2002-06-11 2003-12-24 Basf Ag Process for the production of hydrogenous gases
JP4774197B2 (en) * 2003-05-20 2011-09-14 出光興産株式会社 Oxygen-containing hydrocarbon reforming catalyst, hydrogen or synthesis gas production method using the same, and fuel cell system
WO2008126743A1 (en) * 2007-04-10 2008-10-23 Idemitsu Kosan Co., Ltd. Catalyst precursor substance, and catalyst using the same
JP5398196B2 (en) * 2008-08-27 2014-01-29 株式会社東芝 Zinc-added reduction precipitation type copper catalyst and method for producing the same
US8529864B2 (en) 2008-09-26 2013-09-10 National Tsing Hua University Process for hydrogen production
TWI381992B (en) * 2008-09-26 2013-01-11 Nat Univ Tsing Hua Self-started process at reactor temperature for hydrogen production
WO2012105355A1 (en) * 2011-01-31 2012-08-09 住友精化株式会社 Production method for hydrogen gas
KR102233613B1 (en) * 2018-10-15 2021-03-30 재단법인 포항산업과학연구원 Catalyst for water gas shift reaction in middle temperature, preparation method thereof, and hydrogen preparation method using the same
AR123731A1 (en) 2021-10-08 2023-01-04 Villagra Guillermo Alejandro Serrano HYDROGEN - OXYGEN GAS FUEL GENERATOR EQUIPMENT APPLIED TO INTERNAL COMBUSTION ENGINES

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2220617A1 (en) * 1972-04-27 1973-11-15 Metallgesellschaft Ag METHOD FOR PRODUCTION OF HYDROGEN
NO146046L (en) * 1980-03-28
GB8521953D0 (en) * 1985-09-04 1985-10-09 Johnson Matthey Plc Catalytic hydrogen generator
GB8623482D0 (en) * 1986-09-30 1986-11-05 Johnson Matthey Plc Catalytic generation of hydrogen
JP3328845B2 (en) * 1992-10-12 2002-09-30 三菱瓦斯化学株式会社 Hydrogen production method and catalyst used for it
US5904880A (en) * 1996-12-31 1999-05-18 Exxon Chemical Patents Inc. One step conversion of methanol to hydrogen and carbon dioxide
DE19739773A1 (en) * 1997-09-10 1999-03-11 Basf Ag Process and catalyst for steam reforming of methanol

Also Published As

Publication number Publication date
DE60017611T2 (en) 2005-12-22
DK1298089T3 (en) 2005-03-21
US20030216255A1 (en) 2003-11-20
DE60017611D1 (en) 2005-02-24
WO2001098202A1 (en) 2001-12-27
ATE287377T1 (en) 2005-02-15
BR0017292A (en) 2004-01-06
PT1298089E (en) 2005-04-29
EP1298089B1 (en) 2005-01-19
EP1298089A1 (en) 2003-04-02
JP2004500980A (en) 2004-01-15
ES2234618T3 (en) 2005-07-01

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