AR115495A1 - HETEROCYCLIC DERIVATIVES WITH SUBSTITUENTS CONTAINING ACTIVE SULFUR AS PESTICIDES - Google Patents

HETEROCYCLIC DERIVATIVES WITH SUBSTITUENTS CONTAINING ACTIVE SULFUR AS PESTICIDES

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Publication number
AR115495A1
AR115495A1 ARP190101547A ARP190101547A AR115495A1 AR 115495 A1 AR115495 A1 AR 115495A1 AR P190101547 A ARP190101547 A AR P190101547A AR P190101547 A ARP190101547 A AR P190101547A AR 115495 A1 AR115495 A1 AR 115495A1
Authority
AR
Argentina
Prior art keywords
alkyl
formula
group
haloalkyl
compounds
Prior art date
Application number
ARP190101547A
Other languages
Spanish (es)
Inventor
Daniel Emery
Vikas Sikervar
Sebastian Rendler
Andrew Edmunds
Michel Muehlebach
Indira Sen
Original Assignee
Syngenta Crop Protection Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Crop Protection Ag filed Critical Syngenta Crop Protection Ag
Publication of AR115495A1 publication Critical patent/AR115495A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/04—Ortho-condensed systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Los compuestos de fórmula (1), donde los sustituyentes son como se definen en la reivindicación 1, y las sales, estereoisómeros, enantiómeros, tautómeros y N-óxidos agroquímicamente aceptables de estos compuestos. Además, la presente se refiere a composiciones agroquímicas que comprenden compuestos de fórmula (1), a la preparación de estas composiciones y al uso de los compuestos o las composiciones en agricultura u horticultura para combatir, prevenir o controlar plagas de animales, incluyendo artrópodos y, en particular, insectos, nematodos, moluscos o representantes del orden Acarina. Reivindicación 1: Un compuesto de fórmula (1), donde A es CH o N; X es S, SO o SO₂; R¹ es alquilo C₁₋₄; R⁷ y R⁸ son, independientemente entre sí, alquilo C₁₋₆, haloalquilo C₁₋₆, cicloalquilo C₃₋₆, cianoalquilo C₁₋₆ o alcoxi C₁₋₄alquilo C₁₋₄; o R⁷ y R⁸, junto con el átomo de azufre al que están unidos, forman un sistema anular heterocíclico saturado de cuatro a seis miembros, donde dicho sistema anular puede estar mono- o polisustituido con sustituyentes seleccionados a partir del grupo constituido por halógeno, ciano, alquilo C₁₋₄, alcoxi C₁₋₄ y haloalquilo C₁₋₄; y dicho sistema anular puede contener un heteroátomo adicional seleccionado a partir del grupo constituido por nitrógeno, oxígeno y azufre; n es 0 ó 1; R⁹ es hidrógeno o alquilo C₁₋₄; Q es un radical seleccionado a partir del grupo constituido por la fórmula Q¹ a Q¹¹, del grupo de fórmulas (2), donde la flecha indica el punto de unión al anillo que incorpora el radical A; y donde X¹ es O, S o NR⁵, donde R⁵ es alquilo C₁₋₄; R² es halógeno, haloalquilo C₁₋₆, haloalquilsulfanilo C₁₋₄, haloalquilsulfinilo C₁₋₄, haloalquilsulfonilo C₁₋₄ o haloalcoxi C₁₋₆; G¹ es N o CH; R³ es haloalquilo C₁₋₆ o haloalquenilo C₂₋₆; R⁴ es un radical seleccionado del grupo que consiste en R³, OR³, SR³, S(O)R³, SO₂R³, OSO₂R³, N(H)R³, N(CH₃)R³, CH₂OR³, C(O)R³, CON(H)R³, CON(CH₃)R³, N(H)COR³, N(CH₃)COR³; o una sal, estereoisómero, enantiómero, tautómero o N-óxido agroquímicamente aceptables de un compuesto de la fórmula (1).The compounds of formula (1), where the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of these compounds. Furthermore, the present refers to agrochemical compositions comprising compounds of formula (1), to the preparation of these compositions and to the use of the compounds or compositions in agriculture or horticulture to combat, prevent or control pests of animals, including arthropods and , in particular, insects, nematodes, mollusks or representatives of the order Acarina. Claim 1: A compound of formula (1), where A is CH or N; X is S, SO or SO₂; R¹ is C₁₋₄ alkyl; R⁷ and R⁸ are independently C alkyl, C₁₋₆ haloalkyl, C₃₋₆ cycloalkyl, C₁₋₆ cyanoalkyl or C₁₋₄ alkoxy C₁₋₄alkyl; or R⁷ and R⁸, together with the sulfur atom to which they are attached, form a saturated heterocyclic ring system of four to six members, where said ring system can be mono- or polysubstituted with substituents selected from the group consisting of halogen, cyano , C₁₋₄ alkyl, C₁₋₄ alkoxy, and C₁₋₄ haloalkyl; and said ring system may contain an additional heteroatom selected from the group consisting of nitrogen, oxygen, and sulfur; n is 0 or 1; R⁹ is hydrogen or C₁₋₄ alkyl; Q is a radical selected from the group consisting of the formula Q¹ to Q¹¹, from the group of formulas (2), where the arrow indicates the point of attachment to the ring incorporating the radical A; and where X¹ is O, S or NR⁵, where R⁵ is C₁₋₄ alkyl; R² is halogen, C₁₋₆ haloalkyl, C₁₋₄ haloalkylsulfanyl, C₁₋₄ haloalkylsulfinyl, C₁₋₄ haloalkylsulfonyl or C₁₋₆ haloalkoxy; G¹ is N or CH; R³ is C₁₋₆ haloalkyl or C₂₋₆ haloalkenyl; R⁴ is a radical selected from the group consisting of R³, OR³, SR³, S (O) R³, SO₂R³, OSO₂R³, N (H) R³, N (CH₃) R³, CH₂OR³, C (O) R³, CON (H) R³, CON (CH₃) R³, N (H) COR³, N (CH₃) COR³; or an agrochemically acceptable salt, stereoisomer, enantiomer, tautomer or N-oxide of a compound of formula (1).

ARP190101547A 2018-06-06 2019-06-05 HETEROCYCLIC DERIVATIVES WITH SUBSTITUENTS CONTAINING ACTIVE SULFUR AS PESTICIDES AR115495A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IN201811021199 2018-06-06

Publications (1)

Publication Number Publication Date
AR115495A1 true AR115495A1 (en) 2021-01-27

Family

ID=66821248

Family Applications (1)

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Country Status (3)

Country Link
AR (1) AR115495A1 (en)
TW (1) TW202000028A (en)
WO (1) WO2019234160A1 (en)

Families Citing this family (3)

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WO2019234160A1 (en) 2019-12-12
TW202000028A (en) 2020-01-01

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