ZA200807984B - Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use - Google Patents
Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their useInfo
- Publication number
- ZA200807984B ZA200807984B ZA200807984A ZA200807984A ZA200807984B ZA 200807984 B ZA200807984 B ZA 200807984B ZA 200807984 A ZA200807984 A ZA 200807984A ZA 200807984 A ZA200807984 A ZA 200807984A ZA 200807984 B ZA200807984 B ZA 200807984B
- Authority
- ZA
- South Africa
- Prior art keywords
- organic acid
- hydroxymethylfurfural
- acid esters
- synthesis
- esters
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
- C07D307/48—Furfural
- C07D307/50—Preparation from natural products
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Saccharide Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06075565A EP1834951A1 (en) | 2006-03-10 | 2006-03-10 | Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200807984B true ZA200807984B (en) | 2009-10-28 |
Family
ID=36956006
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200807984A ZA200807984B (en) | 2006-03-10 | 2008-09-17 | Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use |
Country Status (13)
Country | Link |
---|---|
US (1) | US8242293B2 (pt) |
EP (5) | EP2050742B1 (pt) |
JP (1) | JP2009529551A (pt) |
CN (1) | CN101421259A (pt) |
AT (3) | ATE473218T1 (pt) |
AU (1) | AU2007224708B2 (pt) |
BR (1) | BRPI0707099A2 (pt) |
CA (2) | CA2645060C (pt) |
DE (1) | DE602007006649D1 (pt) |
MY (1) | MY145760A (pt) |
UA (1) | UA98615C2 (pt) |
WO (1) | WO2007104515A1 (pt) |
ZA (1) | ZA200807984B (pt) |
Families Citing this family (76)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007007629A1 (de) * | 2007-02-16 | 2008-08-21 | Evonik Degussa Gmbh | Verfahren zur Herstellung von 5-Hydroxymethyl-furfural über 5-Acyloxymethyl-furfural als Zwischenprodukt |
WO2009030512A2 (en) | 2007-09-07 | 2009-03-12 | Furanix Technologies B.V. | Hydroxymethylfurfural ethers and esters prepared in ionic liquids |
EP2034005A1 (en) * | 2007-09-07 | 2009-03-11 | Furanix Technologies B.V | Fuel additive concentrate derived from a biomass resource |
US20090156841A1 (en) * | 2007-12-12 | 2009-06-18 | Sanborn Alexandra J | Conversion of carbohydrates to hydroxymethylfurfural (hmf) and derivatives |
US8865921B2 (en) | 2009-10-07 | 2014-10-21 | Furanix Technologies B.V. | Method for the preparation of 2,5-furandicarboxylic acid and for the preparation of the dialkyl ester of 2,5-furandicarboxylic acid |
CA2773640C (en) | 2009-10-07 | 2019-09-10 | Furanix Technologies B.V. | Method for the preparation of 2,5-furandicarboxylic acid and esters thereof |
US8871957B2 (en) * | 2010-04-15 | 2014-10-28 | Korea Institute Of Industrial Technology | Metal catalyst composition for producing furfural derivatives from raw materials of lignocellulosic biomass, and method for producing furfural derivatives using the composition |
CN103270028B (zh) | 2010-12-21 | 2015-11-25 | 纳幕尔杜邦公司 | 由釜馏物或糖浆中的支链不可发酵糖制备糠醛的方法 |
NL2005928C2 (en) * | 2010-12-28 | 2012-07-02 | Furanix Technologies Bv | Process for the conversion of a carbohydrate-containing feedstock. |
FR2975396B1 (fr) * | 2011-05-16 | 2013-12-27 | Centre Nat Rech Scient | Procede de preparation de 5-hydroxymethylfurfural |
US9199958B2 (en) | 2011-05-24 | 2015-12-01 | Eastman Chemical Company | Oxidation process to produce a crude and/or purified carboxylic acid product |
US8796477B2 (en) | 2011-05-24 | 2014-08-05 | Eastman Chemical Company | Oxidation process to produce a crude and/or purified carboxylic acid product |
US8846960B2 (en) | 2011-05-24 | 2014-09-30 | Eastman Chemical Company | Oxidation process to produce a crude and/or purified carboxylic acid product |
US8791277B2 (en) | 2011-05-24 | 2014-07-29 | Eastman Chemical Company | Oxidation process to produce a crude and/or purified carboxylic acid product |
US8791278B2 (en) | 2011-05-24 | 2014-07-29 | Eastman Chemical Company | Oxidation process to produce a crude and/or purified carboxylic acid product |
CN102326728B (zh) * | 2011-06-30 | 2012-12-19 | 山东香驰健源生物科技有限公司 | 一种除去果葡糖浆中的5-羟甲基糠醛的方法 |
DE102012200086A1 (de) * | 2011-09-30 | 2013-04-04 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung von Furanverbindungen aus nachwachsenden Rohstoffen |
ES2442633T3 (es) * | 2011-09-30 | 2014-02-12 | Kemira Oyj | Composición respetuosa con el medio ambiente, adecuada para curtido del cuero, que comprende zeolita |
IN2014CN03466A (pt) * | 2011-10-12 | 2015-07-03 | Novozymes As | |
CN102442982B (zh) * | 2011-12-06 | 2014-03-19 | 中国科学院青岛生物能源与过程研究所 | 一种由糖制备呋喃二甲醇二烷基醚的方法 |
US9156802B2 (en) | 2011-12-13 | 2015-10-13 | Basf Se | Separating off 5-hydroxymethylfurfural (HMF) from reaction solutions by steam distillation |
US9169227B2 (en) | 2011-12-13 | 2015-10-27 | Basf Se | Production of 5 hydroxymethyulfurfural (HMF) from hexose solutions in the presence of steam |
CA2856173A1 (en) | 2011-12-13 | 2013-06-20 | Basf Se | Separating off 5-hydroxymethylfurfural (hmf) from reaction solutions by steam distillation |
HUE034627T2 (en) | 2011-12-13 | 2018-02-28 | Basf Se | Process for the preparation of 5-hydroxymethylfurfural (HMF) from saccharide solutions in the presence of a solvent having a boiling point (normal pressure, brief: low boiling point) of more than 60 Co; |
HUE033363T2 (en) | 2011-12-13 | 2017-11-28 | Basf Se | Process for the preparation of 5-hydroxymethylfurfurol (HMF) from hexose solutions in the presence of steam |
US9162998B2 (en) | 2011-12-13 | 2015-10-20 | Basf Se | Preparation of 5-hydroxymethylfurfural (HMF) from saccharide solutions in the presence of a solvent having a boiling point greater than 60° C. and less than 200° C. (at standard pressure, called low boiler for short) |
CA2859898A1 (en) | 2011-12-28 | 2013-07-04 | E. I. Du Pont De Nemours And Company | Process for the production of furfural |
BR112014015988A8 (pt) | 2011-12-28 | 2017-07-04 | Du Pont | processo |
EP2797685A2 (en) | 2011-12-28 | 2014-11-05 | Furanix Technologies B.V | Process for carrying out a reaction involving a liquid reaction mixture |
WO2013102027A1 (en) | 2011-12-28 | 2013-07-04 | E. I. Du Pont De Nemours And Company | Process for the production of furfural |
US9181210B2 (en) | 2011-12-28 | 2015-11-10 | E I Du Pont De Nemours And Company | Processes for making furfurals |
JP2015504069A (ja) * | 2012-01-10 | 2015-02-05 | アーチャー−ダニエルズ−ミッドランド カンパニー | エタノールへの直接発酵に好適な未反応の糖類の回収とともに、糖類からhmfおよびhmf誘導体を製造する方法 |
KR101374219B1 (ko) | 2012-03-18 | 2014-03-13 | 서울대학교산학협력단 | 알킬암모늄아세테이트염을 이용한 새로운 5-아세트옥시메틸푸르푸랄의 제조방법 |
US8748479B2 (en) | 2012-06-22 | 2014-06-10 | Eastman Chemical Company | Process for purifying crude furan 2,5-dicarboxylic acid using hydrogenation |
US8969404B2 (en) | 2012-06-22 | 2015-03-03 | Eastman Chemical Company | Purifying crude furan 2,5-dicarboxylic acid by hydrogenation |
US8809556B2 (en) | 2012-07-20 | 2014-08-19 | Eastman Chemical Company | Oxidation process to produce a purified carboxylic acid product via solvent displacement and post oxidation |
US9029580B2 (en) | 2012-07-20 | 2015-05-12 | Eastman Chemical Company | Oxidation process to produce a purified carboxylic acid product via solvent displacement and post oxidation |
US8772513B2 (en) | 2012-08-30 | 2014-07-08 | Eastman Chemical Company | Oxidation process to produce a crude dry carboxylic acid product |
NL2009674C2 (en) | 2012-10-22 | 2014-04-23 | Furanix Technologies Bv | Process for the preparation of benzene derivatives. |
CN102911142B (zh) * | 2012-10-24 | 2015-04-22 | 复旦大学 | 一种制备5-羟甲基糠醛的方法 |
US8916719B2 (en) | 2012-11-20 | 2014-12-23 | Eastman Chemical Company | Process for producing dry purified furan-2,5-dicarboxylic acid with oxidation off-gas treatment |
US9156805B2 (en) | 2012-11-20 | 2015-10-13 | Eastman Chemical Company | Oxidative purification method for producing purified dry furan-2,5-dicarboxylic acid |
US8916720B2 (en) | 2012-11-20 | 2014-12-23 | Eastman Chemical Company | Process for producing dry purified furan-2,5-dicarboxylic acid with oxidation off-gas treatment |
WO2014158554A1 (en) * | 2013-03-14 | 2014-10-02 | Archer Daniels Midland Company | Process for making hmf from sugars with reduced byproduct formation, and improved stability hmf compositions |
WO2014197195A2 (en) | 2013-06-06 | 2014-12-11 | California Institute Of Technology | Diels-alder reactions catalyzed by lewis acid containing solids: renewable production of bio-plastics |
EP2813494A1 (de) | 2013-06-12 | 2014-12-17 | Basf Se | Verfahren zur Herstellung von 5-Hydroxymethylfurfural (HMF) |
DE102013106530A1 (de) * | 2013-06-21 | 2014-12-24 | Christoph Pallua | Krebsmedikament |
DE102013223496A1 (de) | 2013-11-18 | 2015-05-21 | Tesa Se | Neuartiges Polyester geeignet zur Herstellung von Trägermaterialien für Klebebändern |
CA2937506C (en) | 2014-01-27 | 2022-12-20 | Rennovia Inc. | Conversion of fructose-containing feedstocks to hmf-containing product |
US9604202B2 (en) | 2014-05-08 | 2017-03-28 | Eastman Chemical Company | Furan-2,5-dicarboxylic acid purge process |
US9943834B2 (en) | 2014-05-08 | 2018-04-17 | Eastman Chemical Company | Furan-2,5-dicarboxylic acid purge process |
US9388351B2 (en) | 2014-06-18 | 2016-07-12 | Phillips 66 Company | Furfural to fuel |
KR101671770B1 (ko) * | 2014-09-02 | 2016-11-03 | 한국생산기술연구원 | 마이크로파를 이용한 5-아세트옥시메틸푸르푸랄의 신규한 제조방법 |
US10081611B2 (en) * | 2014-11-21 | 2018-09-25 | Archer Daniels Midland Company | Method for acid-catalyzed acylation of the reduction products of 5-hydroxymethyl furfural |
ES2900753T3 (es) | 2015-02-10 | 2022-03-18 | Furanix Technologies Bv | Composición de combustible que comprende huminas |
EP3317262B1 (en) * | 2015-07-01 | 2020-04-22 | Furanix Technologies B.V | Process for the preparation of a furfural derivative comprising neutralizing an acid reaction mixture |
CN107912039B (zh) | 2015-07-01 | 2021-11-05 | 福兰尼克斯科技公司 | 用于制备糠醛衍生物的方法 |
WO2017034985A1 (en) * | 2015-08-21 | 2017-03-02 | Gfbiochemicals Limited | Process to prepare hydroxymethylfurfural derivatives |
EP3368597B1 (en) | 2015-10-26 | 2019-08-28 | Synvina C.V. | Humins-containing foam |
BR112018008741A8 (pt) | 2015-11-04 | 2019-02-26 | Basf Se | ?processo para a preparação do ácido e utilização de um éster de ácido? |
CA3003764A1 (en) | 2015-11-04 | 2017-05-11 | Basf Se | A process for preparing a mixture comprising 5-(hydroxymethyl)furfural and specific hmf esters |
WO2017076947A1 (en) | 2015-11-04 | 2017-05-11 | Basf Se | Process for preparing furan-2,5-dicarboxylic acid |
WO2017098296A1 (en) | 2015-12-11 | 2017-06-15 | SOCIETE ANONYME DES EAUX MINERALES D'EVIAN et en abrégé "S.A.E.M.E" | Pet polymer with an anti-crystallization comonomer that can be bio-sourced |
JP7458147B2 (ja) | 2016-01-13 | 2024-03-29 | ストラ エンソ オーユーイー | 2,5-フランジカルボン酸ならびにその中間体および誘導体の製造方法 |
WO2018062995A1 (en) | 2016-09-29 | 2018-04-05 | Avantium Knowledge Centre B.V. | Process for the modification of humins |
CN110191923B (zh) | 2017-01-17 | 2021-11-09 | 福兰尼克斯科技公司 | 包含从碳水化合物的脱水获得的胡敏素的沥青组合物 |
WO2019014382A1 (en) | 2017-07-12 | 2019-01-17 | Stora Enso Oyj | PURIFIED PRODUCTS OF THE 2.5-FURANDICARBOXYLIC ACID PATHWAY |
EP3728710B1 (en) | 2017-12-22 | 2022-04-27 | Furanix Technologies B.V. | A fibre |
EP3810583B1 (en) * | 2018-06-22 | 2024-04-03 | Council of Scientific and Industrial Research | Process for 5-hydroxymethylfurfural (5-hmf) synthesis from carbohydrates |
CN109111414B (zh) * | 2018-09-06 | 2020-11-06 | 沈阳化工大学 | 一种琼脂糖转化联产5-羟甲基糠醛和乙酰丙酸的方法 |
CN110152743B (zh) * | 2019-06-19 | 2020-06-09 | 中国科学院大连化学物理研究所 | 一种固体酸催化剂及其在超临界co2-甲醇体系中合成5-羟甲基糠醛的应用 |
CN112830907B (zh) * | 2019-12-20 | 2022-03-22 | 中国科学院宁波材料技术与工程研究所 | 制备5-羟甲基糠醛的方法 |
CN111057594B (zh) * | 2019-12-30 | 2021-10-29 | 李旭 | 一种醇基燃料添加剂的制备方法 |
WO2023066577A1 (en) | 2021-10-21 | 2023-04-27 | Furanix Technologies B.V. | Process for the preparation of a furfural derivative |
WO2023166503A1 (en) | 2022-03-01 | 2023-09-07 | Celluflux Ltd. | Synthesis of 5-acetoxymethyl furfural in the presence of recyclable salt catalysts |
CN117069869B (zh) * | 2023-10-17 | 2024-01-02 | 山东力宏宝冠纤维素有限公司 | 柔性羧甲基纤维素醚及其制备方法以及负极极片和电池 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US925812A (en) * | 1909-01-26 | 1909-06-22 | Watson & Mcdaniel Company | Fluid-pressure regulator. |
IT597932A (pt) * | 1957-10-11 | |||
GB925812A (en) * | 1958-09-05 | 1963-05-08 | Merck & Co Inc | Novel ester of hydroxymethylfurfural and process for its preparation |
US4339245A (en) * | 1980-10-24 | 1982-07-13 | Phillips Petroleum Company | Motor fuel |
DE3502802A1 (de) * | 1985-01-29 | 1986-07-31 | Ernst 7504 Weingarten Kirchgässner | Verfahren zur besseren und umweltfreundlicheren nutzung von treibstoffen |
DE3601281A1 (de) | 1986-01-17 | 1987-07-23 | Sueddeutsche Zucker Ag | Verfahren zur herstellung von 5-hydroxymethylfurfural einschliesslich eines kristallinen produktes unter ausschliesslicher verwendung von wasser als loesungsmittel |
DE3621517A1 (de) * | 1986-06-27 | 1988-01-07 | Klaus Dipl Chem Dr Garves | Darstellung von alkoxymethylfurfuralen und alkyllevulinaten aus cellulose oder lignocellulosen oder staerke und alkoholen |
FR2670209B1 (fr) | 1990-12-07 | 1995-04-28 | Commissariat Energie Atomique | Procede de preparation d'hydroxymethyl-5 furfural par catalyse heterogene. |
US6603026B2 (en) * | 2001-08-07 | 2003-08-05 | Gene E. Lightner | Heterocyclic compounds produced from biomass |
-
2006
- 2006-03-10 AT AT09151759T patent/ATE473218T1/de not_active IP Right Cessation
- 2006-03-10 EP EP09151759A patent/EP2050742B1/en not_active Not-in-force
- 2006-03-10 EP EP06075565A patent/EP1834951A1/en not_active Withdrawn
- 2006-03-10 EP EP09151758A patent/EP2053047A1/en not_active Withdrawn
-
2007
- 2007-03-12 CA CA2645060A patent/CA2645060C/en not_active Expired - Fee Related
- 2007-03-12 MY MYPI20083490A patent/MY145760A/en unknown
- 2007-03-12 JP JP2008558698A patent/JP2009529551A/ja active Pending
- 2007-03-12 AT AT09165171T patent/ATE529416T1/de not_active IP Right Cessation
- 2007-03-12 WO PCT/EP2007/002146 patent/WO2007104515A1/en active Search and Examination
- 2007-03-12 DE DE602007006649T patent/DE602007006649D1/de active Active
- 2007-03-12 CN CNA2007800083549A patent/CN101421259A/zh active Pending
- 2007-03-12 EP EP09165171A patent/EP2105439B1/en not_active Revoked
- 2007-03-12 BR BRPI0707099-3A patent/BRPI0707099A2/pt not_active IP Right Cessation
- 2007-03-12 AT AT07723191T patent/ATE468330T1/de not_active IP Right Cessation
- 2007-03-12 US US12/282,288 patent/US8242293B2/en active Active
- 2007-03-12 CA CA2893566A patent/CA2893566C/en not_active Expired - Fee Related
- 2007-03-12 AU AU2007224708A patent/AU2007224708B2/en not_active Ceased
- 2007-03-12 EP EP07723191A patent/EP2001859B1/en not_active Not-in-force
- 2007-12-03 UA UAA200811992A patent/UA98615C2/uk unknown
-
2008
- 2008-09-17 ZA ZA200807984A patent/ZA200807984B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
EP2050742A1 (en) | 2009-04-22 |
JP2009529551A (ja) | 2009-08-20 |
EP2001859B1 (en) | 2010-05-19 |
WO2007104515A1 (en) | 2007-09-20 |
EP1834951A1 (en) | 2007-09-19 |
US8242293B2 (en) | 2012-08-14 |
CA2645060A1 (en) | 2007-09-20 |
DE602007006649D1 (de) | 2010-07-01 |
ATE468330T1 (de) | 2010-06-15 |
EP2053047A1 (en) | 2009-04-29 |
CA2893566C (en) | 2016-08-02 |
EP2105439A1 (en) | 2009-09-30 |
AU2007224708B2 (en) | 2011-10-06 |
ATE473218T1 (de) | 2010-07-15 |
BRPI0707099A2 (pt) | 2011-04-19 |
CA2893566A1 (en) | 2007-09-20 |
MY145760A (en) | 2012-04-13 |
ATE529416T1 (de) | 2011-11-15 |
EP2001859A1 (en) | 2008-12-17 |
US20090306415A1 (en) | 2009-12-10 |
AU2007224708A1 (en) | 2007-09-20 |
EP2050742B1 (en) | 2010-07-07 |
CN101421259A (zh) | 2009-04-29 |
UA98615C2 (uk) | 2012-06-11 |
CA2645060C (en) | 2015-10-06 |
EP2105439B1 (en) | 2011-10-19 |
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