ZA200407048B - Foams made from water-absorbing, basic polymers, method for the production and utilization thereof. - Google Patents
Foams made from water-absorbing, basic polymers, method for the production and utilization thereof. Download PDFInfo
- Publication number
- ZA200407048B ZA200407048B ZA200407048A ZA200407048A ZA200407048B ZA 200407048 B ZA200407048 B ZA 200407048B ZA 200407048 A ZA200407048 A ZA 200407048A ZA 200407048 A ZA200407048 A ZA 200407048A ZA 200407048 B ZA200407048 B ZA 200407048B
- Authority
- ZA
- South Africa
- Prior art keywords
- water
- foams
- polymers
- absorbing
- basic
- Prior art date
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- 229920000642 polymer Polymers 0.000 title claims abstract description 132
- 239000006260 foam Substances 0.000 title claims abstract description 118
- 238000000034 method Methods 0.000 title claims description 27
- 239000000203 mixture Substances 0.000 claims abstract description 92
- 239000004971 Cross linker Substances 0.000 claims abstract description 64
- 230000002378 acidificating effect Effects 0.000 claims abstract description 40
- 239000000017 hydrogel Substances 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000004132 cross linking Methods 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 16
- 238000005187 foaming Methods 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 13
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 239000004872 foam stabilizing agent Substances 0.000 claims abstract description 9
- 210000001124 body fluid Anatomy 0.000 claims abstract description 8
- 239000010839 body fluid Substances 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 5
- 206010052428 Wound Diseases 0.000 claims abstract description 4
- 208000027418 Wounds and injury Diseases 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims abstract description 4
- 239000005022 packaging material Substances 0.000 claims abstract description 4
- 239000003973 paint Substances 0.000 claims abstract description 4
- 239000003566 sealing material Substances 0.000 claims abstract description 4
- 239000002689 soil Substances 0.000 claims abstract description 4
- 239000000366 soil substitute Substances 0.000 claims abstract description 4
- 238000009423 ventilation Methods 0.000 claims abstract description 4
- 239000002699 waste material Substances 0.000 claims abstract description 4
- 229920002873 Polyethylenimine Polymers 0.000 claims description 22
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical group NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 15
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 11
- 229920000962 poly(amidoamine) Polymers 0.000 claims description 10
- 238000006386 neutralization reaction Methods 0.000 claims description 5
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 claims description 3
- 229920002959 polymer blend Polymers 0.000 claims description 3
- UVIDMSMLNGZCSV-UHFFFAOYSA-N 2-ethenylguanidine Chemical group NC(=N)NC=C UVIDMSMLNGZCSV-UHFFFAOYSA-N 0.000 claims description 2
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 150000001253 acrylic acids Chemical class 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 description 27
- -1 N-vinylimidazoline Chemical class 0.000 description 26
- 150000002148 esters Chemical class 0.000 description 26
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 25
- 239000002253 acid Substances 0.000 description 25
- 229940117927 ethylene oxide Drugs 0.000 description 25
- 239000007795 chemical reaction product Substances 0.000 description 20
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- 239000000047 product Substances 0.000 description 18
- 239000000178 monomer Substances 0.000 description 17
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical group C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 14
- 150000007513 acids Chemical class 0.000 description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 13
- 150000001298 alcohols Chemical class 0.000 description 12
- 150000001991 dicarboxylic acids Chemical class 0.000 description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 11
- 239000007864 aqueous solution Substances 0.000 description 11
- 238000001035 drying Methods 0.000 description 11
- 230000007062 hydrolysis Effects 0.000 description 11
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- 125000004432 carbon atom Chemical group C* 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
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- 239000007789 gas Substances 0.000 description 9
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- 229920001515 polyalkylene glycol Polymers 0.000 description 9
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- 150000003839 salts Chemical class 0.000 description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000011780 sodium chloride Substances 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
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- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
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- 229920002125 Sokalan® Polymers 0.000 description 5
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- 150000003863 ammonium salts Chemical class 0.000 description 5
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- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 4
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- HXVJQEGYAYABRY-UHFFFAOYSA-N 1-ethenyl-4,5-dihydroimidazole Chemical class C=CN1CCN=C1 HXVJQEGYAYABRY-UHFFFAOYSA-N 0.000 description 3
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/30—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/05—Elimination by evaporation or heat degradation of a liquid phase
- C08J2201/0504—Elimination by evaporation or heat degradation of a liquid phase the liquid phase being aqueous
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/02—Foams characterised by their properties the finished foam itself being a gel or a gel being temporarily formed when processing the foamable composition
- C08J2205/022—Hydrogel, i.e. a gel containing an aqueous composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Graft Or Block Polymers (AREA)
- Materials For Medical Uses (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10204980 | 2002-02-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200407048B true ZA200407048B (en) | 2005-09-05 |
Family
ID=27674578
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200407048A ZA200407048B (en) | 2002-02-06 | 2004-09-03 | Foams made from water-absorbing, basic polymers, method for the production and utilization thereof. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7838567B2 (zh) |
| EP (1) | EP1476501B1 (zh) |
| JP (1) | JP4170917B2 (zh) |
| KR (1) | KR20040091010A (zh) |
| CN (1) | CN1264902C (zh) |
| AT (1) | ATE371698T1 (zh) |
| AU (1) | AU2003244473A1 (zh) |
| BR (1) | BR0307224A (zh) |
| DE (1) | DE50308061D1 (zh) |
| WO (1) | WO2003066716A1 (zh) |
| ZA (1) | ZA200407048B (zh) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10247241A1 (de) | 2002-10-10 | 2004-04-22 | Basf Ag | Superabsorbierender Schaum, Verfahren zu seiner Herstellung und seine Verwendung |
| DE102005018922A1 (de) * | 2005-04-22 | 2006-10-26 | Stockhausen Gmbh | Mit Polykationen oberflächenbehandeltes wasserabsorbierendes Polymergebilde |
| KR100664290B1 (ko) * | 2006-02-27 | 2007-01-04 | 엘지전자 주식회사 | 의류 건조기의 건조 드럼 |
| WO2008139973A1 (ja) * | 2007-05-09 | 2008-11-20 | Idemitsu Technofine Co., Ltd. | 紫外線硬化型コート剤および成形品 |
| DE102007056264A1 (de) * | 2007-11-08 | 2009-07-16 | Arpadis Deutschland Gmbh | Bodenverbesserungsmittel und seine Verwendung |
| CN101868336B (zh) * | 2007-11-15 | 2014-03-26 | 巴斯夫欧洲公司 | 表面具有图形符号的超吸收性泡沫 |
| US8852558B2 (en) * | 2008-03-11 | 2014-10-07 | Materials Modification, Inc. | In situ formation of an artificial blockage to control bleeding by polymer expansion with hydrogen peroxide and platinum catalyst |
| US9707251B2 (en) | 2008-03-11 | 2017-07-18 | Materials Modification, Inc. | Siloxane-based artificial blockage to control bleeding |
| US8828358B2 (en) * | 2008-03-11 | 2014-09-09 | Materials Modifications, Inc. | In situ formation of an artificial blockage to control bleeding by polymer expansion with hydrogen peroxide |
| EP2271596B1 (de) * | 2008-04-29 | 2012-04-25 | Basf Se | Elastischer anorganisch-organischer hybridschaumstoff |
| KR101541344B1 (ko) * | 2008-12-05 | 2015-08-03 | 삼성전자주식회사 | 메모리 장치 및 메모리 장치의 제어 방법 |
| EP2399944B2 (en) * | 2009-02-17 | 2019-08-07 | Nippon Shokubai Co., Ltd. | Polyacrylic acid-based water-absorbing resin powder and method for producing the same |
| US8822557B2 (en) * | 2009-10-27 | 2014-09-02 | Basf Se | Elastic inorganic-organic hybrid foam |
| CN102665772B (zh) | 2009-11-23 | 2016-08-03 | 巴斯夫欧洲公司 | 制备吸水性聚合物泡沫的方法 |
| EP2525842B1 (en) | 2010-01-22 | 2017-03-22 | KCI Licensing, Inc. | Devices, systems, and methods for instillation of foamed fluid with negative pressure wound therapy |
| US20120296297A1 (en) * | 2011-05-18 | 2012-11-22 | Achille Di Cintio | Feminine hygiene absorbent articles comprising water-absorbing polymeric foams |
| KR102086052B1 (ko) * | 2016-12-27 | 2020-03-06 | 주식회사 엘지화학 | 고흡수성 수지 및 이의 제조 방법 |
| JP2022104701A (ja) * | 2020-12-29 | 2022-07-11 | ユニ・チャーム株式会社 | 複合吸収体及び衛生用品 |
| JP2022104698A (ja) * | 2020-12-29 | 2022-07-11 | ユニ・チャーム株式会社 | 複合吸収体及び衛生用品 |
| WO2023049784A1 (en) * | 2021-09-23 | 2023-03-30 | Kim Junsoo | Entangled polymer networks |
| CN114377188B (zh) * | 2022-01-14 | 2023-01-10 | 宋金华 | 一种超吸水生物基泡沫材料及其制备方法和应用 |
| CN116141566A (zh) * | 2023-02-26 | 2023-05-23 | 四川大学 | 一种利用聚合物溶液在高压气体中制备聚合物泡沫的方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4087199A (en) * | 1976-11-22 | 1978-05-02 | General Electric Company | Ceramic turbine shroud assembly |
| US4411594A (en) * | 1979-06-30 | 1983-10-25 | Rolls-Royce Limited | Support member and a component supported thereby |
| FR2576301B1 (fr) * | 1985-01-24 | 1992-03-13 | Europ Propulsion | Procede de preparation de materiaux refractaires poreux, produits nouveaux ainsi obtenus et leurs applications a la preparation d'anneaux de turbine abradables |
| DE19540951A1 (de) | 1995-11-03 | 1997-05-07 | Basf Ag | Wasserabsorbierende, schaumförmige, vernetzte Polymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19607529A1 (de) * | 1996-02-28 | 1997-09-04 | Basf Ag | Absorberelement aus superabsorbierenden Schäumen mit anisotropem Quellverhalten |
| US5981689A (en) * | 1997-11-19 | 1999-11-09 | Amcol International Corporation | Poly(vinylamine)-based superabsorbent gels and method of manufacturing the same |
| US5962578A (en) * | 1997-11-19 | 1999-10-05 | Amcol International Corporation | Poly(dialkylaminoalkyl (meth)acrylamide)-based superabsorbent gels |
| US6087448A (en) * | 1997-11-19 | 2000-07-11 | Amcol International Corporation | Solid superabsorbent material containing a poly(vinylguanidine) and an acidic water-absorbing resin |
| US6072101A (en) * | 1997-11-19 | 2000-06-06 | Amcol International Corporation | Multicomponent superabsorbent gel particles |
| US6222091B1 (en) * | 1997-11-19 | 2001-04-24 | Basf Aktiengesellschaft | Multicomponent superabsorbent gel particles |
| US6025404A (en) * | 1998-02-20 | 2000-02-15 | The Dow Chemical Company | Rapid set latexes and foamed articles prepared therefrom |
| DE19809540A1 (de) | 1998-03-05 | 1999-09-09 | Basf Ag | Wasserabsorbierende, schaumförmige, vernetzte Polymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19909214A1 (de) * | 1999-03-03 | 2000-09-07 | Basf Ag | Wasserabsorbierende, schaumförmige, vernetzte Polymerisate mit verbesserter Verteilungswirkung, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP2002542364A (ja) | 1999-04-20 | 2002-12-10 | ビーエーエスエフ アクチェンゲゼルシャフト | ヒドロゲル形成ポリマー混合物 |
| US6997673B2 (en) * | 2003-12-11 | 2006-02-14 | Honeywell International, Inc. | Gas turbine high temperature turbine blade outer air seal assembly |
-
2003
- 2003-01-30 DE DE50308061T patent/DE50308061D1/de not_active Expired - Lifetime
- 2003-01-30 WO PCT/EP2003/000927 patent/WO2003066716A1/de active IP Right Grant
- 2003-01-30 AU AU2003244473A patent/AU2003244473A1/en not_active Abandoned
- 2003-01-30 JP JP2003566083A patent/JP4170917B2/ja not_active Expired - Fee Related
- 2003-01-30 EP EP03737290A patent/EP1476501B1/de not_active Expired - Lifetime
- 2003-01-30 CN CNB038032627A patent/CN1264902C/zh not_active Expired - Fee Related
- 2003-01-30 AT AT03737290T patent/ATE371698T1/de not_active IP Right Cessation
- 2003-01-30 BR BR0307224-0A patent/BR0307224A/pt not_active IP Right Cessation
- 2003-01-30 KR KR10-2004-7012090A patent/KR20040091010A/ko not_active Application Discontinuation
- 2003-01-30 US US10/502,212 patent/US7838567B2/en not_active Expired - Fee Related
-
2004
- 2004-09-03 ZA ZA200407048A patent/ZA200407048B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1476501B1 (de) | 2007-08-29 |
| BR0307224A (pt) | 2004-12-07 |
| CN1628145A (zh) | 2005-06-15 |
| AU2003244473A1 (en) | 2003-09-02 |
| WO2003066716A1 (de) | 2003-08-14 |
| EP1476501A1 (de) | 2004-11-17 |
| KR20040091010A (ko) | 2004-10-27 |
| US7838567B2 (en) | 2010-11-23 |
| US20050070616A1 (en) | 2005-03-31 |
| JP2005521757A (ja) | 2005-07-21 |
| CN1264902C (zh) | 2006-07-19 |
| JP4170917B2 (ja) | 2008-10-22 |
| ATE371698T1 (de) | 2007-09-15 |
| DE50308061D1 (de) | 2007-10-11 |
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