ZA200304763B - Method for preparing latex. - Google Patents
Method for preparing latex. Download PDFInfo
- Publication number
- ZA200304763B ZA200304763B ZA200304763A ZA200304763A ZA200304763B ZA 200304763 B ZA200304763 B ZA 200304763B ZA 200304763 A ZA200304763 A ZA 200304763A ZA 200304763 A ZA200304763 A ZA 200304763A ZA 200304763 B ZA200304763 B ZA 200304763B
- Authority
- ZA
- South Africa
- Prior art keywords
- preparation
- latices
- monomers
- polymer
- weight
- Prior art date
Links
- 229920000126 latex Polymers 0.000 title claims description 98
- 238000000034 method Methods 0.000 title claims description 57
- 239000004816 latex Substances 0.000 title claims description 27
- 239000000178 monomer Substances 0.000 claims description 95
- 229920000642 polymer Polymers 0.000 claims description 58
- 239000003999 initiator Substances 0.000 claims description 52
- 239000006185 dispersion Substances 0.000 claims description 46
- 238000006116 polymerization reaction Methods 0.000 claims description 44
- 238000002360 preparation method Methods 0.000 claims description 40
- 238000010899 nucleation Methods 0.000 claims description 23
- 239000002245 particle Substances 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 12
- 238000009826 distribution Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 8
- 238000010526 radical polymerization reaction Methods 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 239000002952 polymeric resin Substances 0.000 claims description 6
- 229920003002 synthetic resin Polymers 0.000 claims description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 150000005690 diesters Chemical class 0.000 claims 2
- 229920001944 Plastisol Polymers 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 1
- -1 phthalic acid diesters Chemical class 0.000 claims 1
- 239000004999 plastisol Substances 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 238000011084 recovery Methods 0.000 claims 1
- 239000002270 dispersing agent Substances 0.000 description 32
- 239000003995 emulsifying agent Substances 0.000 description 26
- 239000007788 liquid Substances 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 12
- 239000003638 chemical reducing agent Substances 0.000 description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000003213 activating effect Effects 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 150000001451 organic peroxides Chemical class 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 150000008049 diazo compounds Chemical class 0.000 description 2
- 238000005549 size reduction Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Pretreatment Of Seeds And Plants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0017073A FR2818649B1 (fr) | 2000-12-21 | 2000-12-21 | Procede de preparation de latex |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200304763B true ZA200304763B (en) | 2004-09-20 |
Family
ID=8858238
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200304763A ZA200304763B (en) | 2000-12-21 | 2003-06-19 | Method for preparing latex. |
Country Status (30)
Country | Link |
---|---|
US (1) | US7067578B2 (sk) |
EP (1) | EP1358228B1 (sk) |
JP (1) | JP4275411B2 (sk) |
KR (1) | KR100854014B1 (sk) |
CN (1) | CN100434446C (sk) |
AT (1) | ATE376561T1 (sk) |
AU (2) | AU2002229689B2 (sk) |
BR (1) | BR0116386B1 (sk) |
CA (1) | CA2432539C (sk) |
CZ (1) | CZ20031714A3 (sk) |
DE (1) | DE60131099T2 (sk) |
DK (1) | DK1358228T3 (sk) |
ES (1) | ES2295234T3 (sk) |
FR (1) | FR2818649B1 (sk) |
HU (1) | HUP0500959A3 (sk) |
IL (1) | IL156481A0 (sk) |
ME (1) | MEP41708A (sk) |
MX (1) | MXPA03005652A (sk) |
MY (1) | MY129839A (sk) |
NO (1) | NO330325B1 (sk) |
PL (1) | PL202977B1 (sk) |
PT (1) | PT1358228E (sk) |
RS (1) | RS50950B (sk) |
RU (1) | RU2289594C2 (sk) |
SI (1) | SI1358228T1 (sk) |
SK (1) | SK287478B6 (sk) |
TW (1) | TW583196B (sk) |
UA (1) | UA77953C2 (sk) |
WO (1) | WO2002050140A2 (sk) |
ZA (1) | ZA200304763B (sk) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004532903A (ja) * | 2001-01-10 | 2004-10-28 | ソルヴェイ | ハロポリマーの製造方法及び得られるハロポリマー |
WO2016061110A1 (en) | 2014-10-13 | 2016-04-21 | Avery Dennison Corporation | Vinyl acetate-ethylene / acrylic polymer emulsions and products and methods relating thereto |
KR101898320B1 (ko) * | 2015-12-16 | 2018-10-04 | 주식회사 엘지화학 | 염화비닐계 중합체, 이의 제조방법 및 이를 포함하는 플라스티졸 |
KR102237955B1 (ko) * | 2018-10-08 | 2021-04-08 | 주식회사 엘지화학 | 염화비닐계 중합체 중합용 조성물 및 이를 이용한 염화비닐계 중합체의 제조방법 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE152347C (sk) * | ||||
FR2044364A5 (sk) * | 1969-05-19 | 1971-02-19 | Pechiney Saint Gobain | |
US3935151A (en) * | 1973-10-10 | 1976-01-27 | Borden, Inc. | Blended latex binder for exterior paints with wet primed adhesion |
HU173513B (hu) * | 1975-04-30 | 1979-05-28 | Rhone Poulenc Ind | Sposob polimerizacii vinilkhlorida v sshitojj mikrosuspensii |
US4327003A (en) * | 1975-08-30 | 1982-04-27 | Industrial Technology Research Institute | Polymerization process for the production of PVC latex and paste resin |
US4168373A (en) * | 1975-11-24 | 1979-09-18 | Borden, Inc. | Removal of residual vinyl chloride monomer from polyvinyl chloride latex |
SE430896B (sv) * | 1979-12-06 | 1983-12-19 | Kema Nord Ab | Forfarande for polymerisation av vinylklorid i nervaro av en stabiliserande polymerlatex |
DE3132694C2 (de) * | 1981-08-19 | 1983-06-16 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von rieselfähigen, nicht klebenden Vinylchloridpfropfpolymeren |
US4654392A (en) * | 1985-07-12 | 1987-03-31 | The Goodyear Tire & Rubber Company | BHA in vinyl chloride polymerization |
KR100191378B1 (ko) * | 1989-09-18 | 1999-06-15 | 후루타 다케시 | 비닐 클로라이드 수지를 제조하기위한 미세현탁중합법 |
BE1004570A3 (fr) * | 1990-09-17 | 1992-12-15 | Solvay | Procede pour la production de latex plurimodaux de polymeres du chlorure de vinyle. |
DE4443752A1 (de) * | 1994-12-08 | 1996-06-13 | Vinnolit Kunststoff Gmbh | Verfahren zur radikalischen Polymerisation ethylenisch ungesättigter Monomere in wäßrigem Medium |
CN1165150A (zh) * | 1995-11-22 | 1997-11-19 | 三菱化学株式会社 | 氯乙烯聚合物水分散体 |
EP0810241A1 (fr) * | 1996-05-31 | 1997-12-03 | Elf Atochem S.A. | Latex bipopulé de copolymères du chlorure de vinyle, son procédé de fabrication et ses applications |
JP3563234B2 (ja) * | 1997-05-16 | 2004-09-08 | 新第一塩ビ株式会社 | 塩化ビニル系重合体ラテックスの製造方法 |
US6277954B2 (en) * | 1999-09-14 | 2001-08-21 | Kaneka Corporation | Method of stripping for latex of vinyl chloride paste resin, stripping apparatus, and vinyl chloride paste resin latex having low concentration of residual monomer |
-
2000
- 2000-12-21 FR FR0017073A patent/FR2818649B1/fr not_active Expired - Fee Related
-
2001
- 2001-12-20 AU AU2002229689A patent/AU2002229689B2/en not_active Ceased
- 2001-12-20 MY MYPI20015791A patent/MY129839A/en unknown
- 2001-12-20 ES ES01990596T patent/ES2295234T3/es not_active Expired - Lifetime
- 2001-12-20 JP JP2002552030A patent/JP4275411B2/ja not_active Expired - Fee Related
- 2001-12-20 DK DK01990596T patent/DK1358228T3/da active
- 2001-12-20 EP EP01990596A patent/EP1358228B1/fr not_active Expired - Lifetime
- 2001-12-20 MX MXPA03005652A patent/MXPA03005652A/es active IP Right Grant
- 2001-12-20 HU HU0500959A patent/HUP0500959A3/hu unknown
- 2001-12-20 KR KR1020037008222A patent/KR100854014B1/ko not_active IP Right Cessation
- 2001-12-20 IL IL15648101A patent/IL156481A0/xx not_active IP Right Cessation
- 2001-12-20 DE DE60131099T patent/DE60131099T2/de not_active Expired - Lifetime
- 2001-12-20 PL PL362406A patent/PL202977B1/pl not_active IP Right Cessation
- 2001-12-20 PT PT01990596T patent/PT1358228E/pt unknown
- 2001-12-20 SK SK798-2003A patent/SK287478B6/sk not_active IP Right Cessation
- 2001-12-20 CZ CZ20031714A patent/CZ20031714A3/cs unknown
- 2001-12-20 AU AU2968902A patent/AU2968902A/xx active Pending
- 2001-12-20 CN CNB01822802XA patent/CN100434446C/zh not_active Expired - Fee Related
- 2001-12-20 BR BRPI0116386-8A patent/BR0116386B1/pt not_active IP Right Cessation
- 2001-12-20 ME MEP-417/08A patent/MEP41708A/xx unknown
- 2001-12-20 US US10/450,533 patent/US7067578B2/en not_active Expired - Fee Related
- 2001-12-20 RU RU2003122229/04A patent/RU2289594C2/ru not_active IP Right Cessation
- 2001-12-20 RS YUP-572/03A patent/RS50950B/sr unknown
- 2001-12-20 UA UA2003076825A patent/UA77953C2/uk unknown
- 2001-12-20 TW TW090131719A patent/TW583196B/zh not_active IP Right Cessation
- 2001-12-20 SI SI200130799T patent/SI1358228T1/sl unknown
- 2001-12-20 AT AT01990596T patent/ATE376561T1/de active
- 2001-12-20 CA CA2432539A patent/CA2432539C/en not_active Expired - Fee Related
- 2001-12-20 WO PCT/EP2001/015381 patent/WO2002050140A2/fr active IP Right Grant
-
2003
- 2003-06-19 ZA ZA200304763A patent/ZA200304763B/en unknown
- 2003-06-20 NO NO20032843A patent/NO330325B1/no not_active IP Right Cessation
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