WO2025066493A1 - Gas capture and storage system and method - Google Patents

Gas capture and storage system and method Download PDF

Info

Publication number
WO2025066493A1
WO2025066493A1 PCT/CN2024/107327 CN2024107327W WO2025066493A1 WO 2025066493 A1 WO2025066493 A1 WO 2025066493A1 CN 2024107327 W CN2024107327 W CN 2024107327W WO 2025066493 A1 WO2025066493 A1 WO 2025066493A1
Authority
WO
WIPO (PCT)
Prior art keywords
gas
unit
desorption
inlet
outlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/CN2024/107327
Other languages
French (fr)
Chinese (zh)
Inventor
杨浩然
李珂
李晓波
刘娅琼
陈秋燕
胡兴雷
何志军
魏冕
周蕊
陈萍萍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Marine Diesel Engine Research Institute
Original Assignee
Shanghai Marine Diesel Engine Research Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Marine Diesel Engine Research Institute filed Critical Shanghai Marine Diesel Engine Research Institute
Publication of WO2025066493A1 publication Critical patent/WO2025066493A1/en
Anticipated expiration legal-status Critical
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

Definitions

  • the present application relates to but is not limited to the field of ship exhaust purification.
  • an embodiment of the present application provides a gas capture and storage system, comprising:
  • An absorption unit wherein the absorption unit has a first inlet and a first outlet, the carbon-containing flue gas is fed into the absorption unit from the first inlet, the carbon-containing flue gas contains carbon dioxide, the carbon-containing flue gas contacts with the absorption liquid in the absorption unit to form a first solution, and the first solution is fed out from the first outlet;
  • a desorption unit wherein the desorption unit has a second inlet, and the first solution delivered from the first outlet is delivered to the desorption unit from the second inlet;
  • a gas transfer unit wherein the gas transfer unit is used to feed a desorption gas into the desorption unit, wherein the desorption gas contacts the first solution to complete the desorption of at least part of the carbon dioxide to form a second solution, and the second solution is fed from the desorption unit to the absorption unit.
  • a circulation unit is further included, wherein the circulation unit includes a first circulation pump, wherein an inlet of the first circulation pump is connected to the first outlet, and an outlet of the first circulation pump is connected to the second inlet.
  • the circulation unit includes a second circulation pump, the absorption unit has a third inlet, the desorption unit has a second outlet, the inlet of the second circulation pump is connected to the second outlet, and the outlet of the second circulation pump is connected to the third inlet.
  • the circulation unit includes a heat exchanger, and the heat exchanger is connected to the outlet of the first circulation pump and the outlet of the second circulation pump respectively.
  • the heat exchanger has a first heat exchange outlet, which is connected to the second inlet; the heat exchanger has a second heat exchange outlet, which is connected to the third inlet.
  • the circulation unit includes a first heater, and the first heater is arranged between the first heat exchange outlet and the second inlet.
  • the circulation unit includes a cooler, and the cooler is arranged between the second heat exchange outlet and the third inlet.
  • the gas transfer unit comprises a membrane separator
  • the desorption unit has a third outlet
  • the inlet of the membrane separator is connected to the third outlet.
  • the gas transfer unit includes a condenser, which is arranged between the membrane separator and the third outlet.
  • the gas transfer unit comprises a second heater
  • the desorption unit has a fourth inlet
  • the second heater is arranged between the membrane separator and the fourth inlet.
  • the gas delivery unit has a fifth inlet for introducing desorption gas.
  • the present application also provides a gas capture method, comprising:
  • the carbon-containing flue gas is sent to an absorption unit, wherein the absorption unit contains an absorption liquid, the carbon-containing flue gas contains carbon dioxide, and the absorption liquid forms a first solution after contacting the carbon-containing flue gas;
  • the first solution is fed into a desorption unit, and a gas transmission unit feeds a desorption gas into the desorption unit to desorb carbon dioxide in the first solution;
  • the first solution after desorption forms a second solution, and the second solution is sent from the desorption unit to the absorption unit.
  • the absorption unit has a first air pressure, and the pressure range of the first air pressure is 0.8 to 1.2 bar.
  • the absorption unit has a first temperature, and the first temperature ranges from 30 to 40°C.
  • the desorption unit has a second gas pressure, and the pressure range of the second gas pressure is 0.8 to 1.2 bar.
  • the desorption unit has a second temperature, and the second temperature ranges from 80 to 90°C.
  • FIG1 is a schematic diagram of the gas stripping desorption principle of the double membrane theory
  • FIG2 is a schematic diagram of the structure of a gas capture and storage system in an embodiment of the present application.
  • FIG3 is a schematic flow chart of a gas capture method in an embodiment of the present application.
  • nitrogen or solvent vapor without solute is used as a carrier gas to blow CO2 from the absorbed liquid.
  • the gas phase CO2 partial pressure is reduced, thereby increasing the mass transfer driving force of the desorption process, so that CO2 can be continuously desorbed from the absorbent rich liquid.
  • the advantage of gas lift desorption of CO2 is that it requires low energy consumption, promotes the CO2 desorption reaction rate, reduces the CO2 desorption reaction temperature, thereby reducing the energy consumption of the CO2 desorption process and reducing the system operation cost; and the greater the amount of gas introduced, the greater the amount of CO2 desorbed.
  • the captured and desorbed CO2 needs to be stored in the ship's storage tank and subsequently transported and utilized.
  • the present application provides a gas capture and storage system, as shown in Figure 2, comprising: an absorption unit 100, the absorption unit 100 has a first inlet 101 and a first outlet 102, the carbon-containing flue gas is fed into the absorption unit 100 from the first inlet 101, the carbon-containing flue gas contains carbon dioxide, the carbon-containing flue gas contacts with the absorption liquid in the absorption unit 100 to form a first solution, and the first solution is sent out from the first outlet 102; a desorption unit 200, the desorption unit 200 has a second inlet 201, the first solution sent out from the first outlet 102 is fed into the desorption unit 200 from the second inlet 201; a gas transfer unit 300, the gas transfer unit 300 is used to feed desorption gas into the desorption unit 200, the desorption gas contacts with the first solution, completes the desorption of at least part of the carbon dioxide, forms a second solution, and the second solution is fed from the desorption unit 200 into the absorption unit 100.
  • the gas capture and storage system of the present application utilizes the desorption gas to reduce the partial pressure of carbon dioxide in the desorption system while ensuring the complete functionality of the ship power carbon capture system, thereby promoting the desorption reaction of carbon dioxide, reducing the regeneration energy consumption of the desorption system, and reducing the system operating costs, which can further promote the application of carbon capture technology in the field of ship carbon emission reduction.
  • the gas capture storage system further comprises a circulation unit 400 , wherein the circulation unit 400 comprises a first circulation pump 401 , wherein an inlet of the first circulation pump 401 is connected to the first outlet 102 and the second inlet 201 .
  • the main structure of the absorption unit 100 is an absorption tower, which has a first inlet 101 for introducing carbon-containing flue gas.
  • the first inlet 101 is located below the absorption tower, and the carbon-containing flue gas is introduced into the bottom of the absorption tower from the first inlet 101, and the carbon-containing flue gas flows from bottom to top in the absorption tower.
  • the absorption unit 100 has a third inlet 103.
  • the third The inlet is located above the absorption tower, and the absorption liquid is sprayed from the absorption tower from top to bottom.
  • the carbon-containing flue gas enters from the bottom of the absorption tower and flows upward to complete the adsorption of the carbon-containing flue gas by the absorption liquid, wherein the carbon dioxide in the carbon-containing flue gas is adsorbed by the absorption liquid to form a first solution (rich liquid).
  • fillers may be arranged in the absorption tower to increase the contact area between the absorption liquid and the carbon-containing flue gas and the adsorption efficiency.
  • the fillers may be selected from one or more of corrugated plates, ceramic fillers, and metal fillers.
  • the fillers may be bulk or structured fillers.
  • the form, size, model and specification of the filler can be selected based on parameters such as the actual CO2 removal efficiency, pressure drop requirements in the absorption tower, liquid flooding rate requirements and operating conditions.
  • the absorption liquid includes an organic amine solution, and single or mixed organic amine solutions such as MEA (ethanolamine), MDEA (2-methyl-diethylaminoethanolamine), and DEA (diethanolamine) may be used.
  • organic amine solutions such as MEA (ethanolamine), MDEA (2-methyl-diethylaminoethanolamine), and DEA (diethanolamine) may be used.
  • the clean flue gas is discharged from the top of the absorption tower.
  • the main structure of the desorption unit 200 is a desorption tower 210, and the first solution (rich liquid, absorption liquid that has absorbed CO2 ) in the desorption tower 210 is sent into the desorption tower 210 under the action of a pump group.
  • a second inlet 201 is provided on the desorption tower 210, and the first solution is fed into the desorption tower from the second inlet 201.
  • the second inlet 201 is located above the desorption tower 210, and the first solution is fed into the desorption tower 210 from the top of the desorption tower 210.
  • a desorption gas is simultaneously introduced into the desorption tower 210, and the desorption gas may be nitrogen or solvent vapor without solute.
  • the desorption tower 210 has a fourth inlet 204, and the desorption gas is introduced into the desorption tower 210 through the fourth inlet 204.
  • the fourth inlet 204 is disposed inside the desorption tower 210. The rich liquid is desorbed in the desorption tower 210, and CO 2 is released again to form a second solution (lean liquid).
  • the desorption tower 210 has a second outlet 202 .
  • the second outlet 202 is located at the bottom of the desorption tower 210 , and the second solution is fed into the absorption tower 110 through the second outlet 202 .
  • the desorption tower 210 has a third outlet 203.
  • the third outlet 203 is located at the top of the desorption tower 210.
  • the third outlet 203 is used to send out the product gas located in the desorption tower 210.
  • the product gas of the third outlet 203 at the top of the desorption tower 210 includes CO 2 , N 2 and a small amount of water vapor are fed into the gas transfer unit 300 .
  • the gas transfer unit 300 also includes a condenser 302, which is arranged between the membrane separator 301 and the third outlet 203.
  • the condenser 302 is used to separate water vapor in the product gas, and the separated condensed water vapor is sent to the desorption tower 210 for circulation to supplement the water vapor evaporation loss in the desorption tower 210.
  • the gas transfer unit 300 includes a second heater 303
  • the desorption unit 200 has a fourth inlet 204
  • the second heater 303 is arranged between the membrane separator 301 and the fourth inlet 204, and is used to heat the desorption gas sent into the desorption tower 210 to maintain the temperature in the desorption tower 210.
  • the second heater 303 is an electric heater.
  • the temperature of the desorption gas heated by the second heater 303 is between 85 and 95°C, such as 90°C.
  • the gas transfer unit 300 has a fifth inlet 304, which is used to feed desorption gas.
  • the fifth inlet 304 is located between the second heater 303 and the membrane separator 301.
  • nitrogen can be fed into the fifth inlet 304, which enters the second heater 303 together with the nitrogen sent from the membrane separator 301 for heating, and then is sent into the desorption tower 210 to supplement or adjust the amount of desorption gas sent into the desorption tower 210.
  • the capture storage system of the present application further includes a circulation unit 400, which includes a first circulation pump 401, the inlet of the first circulation pump 401 is connected to the first outlet 102, and the second inlet 201 is connected.
  • the first circulation pump 401 is a rich liquid circulation pump.
  • the circulation unit 400 includes a second circulation pump 402, the absorption unit 100 has a third inlet 103, the desorption unit 200 has a second outlet 202, the inlet of the second circulation pump 402 is connected to the second outlet 202, and the outlet of the second circulation pump 402 is connected to the third inlet 103.
  • the second circulation pump 402 is a lean liquid circulation pump.
  • the circulation unit 400 includes a heat exchanger 403, which is connected to the outlet of the first circulation pump 401 and the outlet of the second circulation pump 402 respectively, and the heat exchanger 403 has a first heat exchange outlet 4031, and the first heat exchange outlet 4031 is connected to the second inlet 201; the heat exchanger 403 has a second heat exchange outlet 4032, and the second heat exchange outlet 4032 is connected to the third inlet 103.
  • the temperature range of the first solution sent from the outlet of the first circulation pump 401 to the heat exchanger 403 is 30-40°C. After heat exchange in the heat exchanger 403, the temperature of the rich liquid sent from the first heat exchange outlet 4031 of the heat exchanger 403 is about 75-85°C, such as 80°C.
  • the temperature range of the second solution sent from the outlet of the second circulation pump 402 to the heat exchanger 403 is 85-95°C, such as 90°C.
  • the temperature of the lean liquid sent from the second heat exchange outlet 4032 of the heat exchanger 403 is about 45-55°C, such as 50°C.
  • the circulation unit 400 includes a first heater 404 disposed between the first heat exchange outlet 4031 and the second inlet 201.
  • the first heater 404 is used to heat the first solution sent from the heat exchanger 403 to a desired temperature, such as from 80°C to 90°C.
  • the circulation unit 400 includes a cooler 405, which is disposed between the second heat exchange outlet 4032 and the third inlet 103.
  • the cooler 405 is used to reduce the temperature of the second solution entering the absorption tower 110, such as reducing the temperature of the second solution from 50°C to 40°C.
  • a gas capture method using the gas capture storage system shown in FIG2 includes:
  • the carbon-containing flue gas is sent to the absorption unit 100, which contains an absorption liquid.
  • the carbon-containing flue gas includes carbon dioxide.
  • a first solution is formed; the first solution is sent to the desorption unit 200, and the gas transfer unit 300 sends desorption gas to the desorption unit 200 to desorb the carbon dioxide in the first solution; the first solution after desorption forms a second solution, and the second solution is sent from the desorption unit 200 to the absorption unit 100.
  • the high-temperature ship exhaust gas containing CO 2 first flows through the absorption tower 110, where the ship exhaust gas and the absorption liquid are subjected to countercurrent convection mass transfer, and then the clean exhaust gas is discharged from the top of the absorption tower 110.
  • the rich liquid is heated by the heat exchanger 403 under the action of the pump group and enters the desorption tower 210 from the top.
  • the rich liquid enters the tower from the top, and the nitrogen enters the tower from the bottom after being heated by the first heater 404.
  • the rich liquid is desorbed under the action of the hot nitrogen and CO 2 is released again.
  • the product gas (CO 2 +N2 + a small amount of water vapor) at the top outlet of the desorption tower passes through the condenser 302 and the membrane separator 301,
  • the purified high-purity CO 2 gas will be discharged from the system for the next step of storage.
  • the separated nitrogen gas will then enter the desorption tower 210 from the lower part of the desorption tower 210 through the membrane separator 301 and the first heater 404 to continue the next cycle.
  • the absorption liquid is an organic amine solution.
  • the present application uses an organic amine solution to chemically absorb and desorb CO 2 in carbon-containing flue gas.
  • the desorption gas is nitrogen.
  • Nitrogen stripping is used for desorption to reduce the CO 2 partial pressure in the desorption tower 210 environment and promote the desorption reaction.
  • the positive reaction (absorption) of this process occurs at room temperature 30-40°C and normal pressure, and the reverse reaction (desorption) occurs at a lower temperature 80-90°C and normal pressure.
  • the absorption tower 110 has a first gas pressure, and the pressure range of the first gas pressure is 0.8 to 1.2 bar, such as the first gas pressure is 1 bar.
  • the optimal gas pressure of the absorption tower 110 of the present application is 1 bar, and the entire system does not need to apply any pressure, which reduces the pressure on components such as the circulation pump in the circulation unit 400.
  • nitrogen gas is used to reduce the CO2 gas partial pressure in the desorption tower 210, promote the CO2 desorption reaction, reduce the system regeneration energy consumption, and cut the system operating cost.
  • the absorption tower 110 has a first temperature, and the first temperature ranges from 30 to 40°C.
  • the desorption tower 210 has a second air pressure, and the pressure range of the second air pressure is 0.8 to 1.2 bar, such as 1 bar.
  • the optimal air pressure of the desorption tower 210 of the present application is 1 bar, and the entire system does not need to apply any pressure, which reduces the pressure of components such as the circulation pump in the circulation unit 400 and the amount of the pump group, and reduces the construction difficulty.
  • the desorption tower 210 has a second temperature, and the second temperature range is 80 to 90°C.
  • the present application adopts nitrogen stripping to desorb CO 2 , and there is no need to heat the absorption liquid to the desorption temperature of 110-120° C., which reduces the energy consumption demand on the ship side and ensures the functional integrity of the system.
  • carbon dioxide is captured by:
  • the carbon-containing flue gas is sent to the absorption unit 100.
  • the absorption unit 100 contains an absorption liquid.
  • the carbon-containing flue gas contains carbon dioxide. After the absorption liquid contacts the carbon-containing flue gas, a first solution is formed.
  • the absorption liquid in the absorption tower 110 is an organic amine solution.
  • the temperature in the absorption tower is 40° C. and the air pressure in the absorption tower 110 is 1 bar.
  • the first solution After the first solution is heat exchanged in the heat exchanger 403, it is sent to the desorption unit 200.
  • the temperature of the first solution after heat exchange in the heat exchanger 403 rises from 40°C to 80°C.
  • the first heater 404 When the temperature in the desorption tower 210 is maintained at 80°C, the first heater 404 does not need to be heated.
  • the rich solution is heated to 90°C by the first heater 404 and sent to the desorption tower 210.
  • the gas transfer unit 300 feeds desorption gas into the desorption unit 200.
  • the desorption gas is nitrogen.
  • the nitrogen is heated to 90° C. by the second heater 303 and fed to the desorption tower 210 from bottom to top for desorbing carbon dioxide in the first solution.
  • the temperature of the desorption tower 210 is maintained at 80-90° C. and the pressure is 1 bar. In this embodiment, the temperature of the desorption tower 210 is maintained at 90° C.
  • the first solution after desorption forms a second solution.
  • the temperature of the second solution drops from 90°C to 50°C.
  • the second solution is cooled to 40°C by a cooler arranged between the heat exchanger 403 and the third inlet 103 of the absorption tower 110 and is sent to the absorption tower 110.
  • the product gas sent out from the third outlet 203 of the desorption tower 210 is cooled to 30° C. by the condenser 302 and sent to the nitrogen membrane separator.
  • the carbon dioxide separated by the nitrogen membrane separator is sent to the next process, and the separated nitrogen enters the cycle again.
  • Table 1 which compares the energy consumption of carbon dioxide desorption in Table 1 with the energy consumption of the gas lift desorption method of the present application: the setting parameters of the absorption tower are the same, the difference between the carbon dioxide desorption and the present application is that no gas transfer unit is set, the temperature range of the desorption tower in the carbon dioxide desorption method is 110-120°C, and the pressure is 1.5bar, and the temperature range of the desorption tower of the present application is 80-90°C, and the pressure is 1bar.
  • Table 2 Energy consumption of gas stripping desorption in this application Note 1: The energy consumption in Table 2 is calculated based on 150Nm 3 /h product gas; the sensible heat of 40 to 80 includes the total energy consumption of the first heater and the second heater;
  • the present application captures carbon dioxide in carbon-containing flue gas by a gas stripping desorption method, which can greatly reduce the energy consumption of the system, reduce the temperature of the rich liquid sent into the desorption tower 210 by the circulation unit 400, and reduce the energy consumption of the entire system.
  • the present application can not only separate carbon dioxide and desorption gas through a nitrogen membrane separator, but also the separated carbon dioxide can directly liquefy and store the product gas that meets the pressure without adding a separate pressurizing device.
  • the present application reduces the desorption pressure of carbon dioxide by sending the desorption gas into the desorption tower 210.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present application discloses a gas capture and storage system and a method. The gas capture and storage system of the present application comprises: an absorption unit, a desorption unit, and a gas transfer unit. A carbon-containing flue gas is fed into the absorption unit, and comes into contact with an absorption liquid in the absorption unit to form a first solution, and the first solution is fed into the desorption unit. A desorption gas is fed into the desorption unit by means of the gas transfer unit, and comes into contact with the first solution to complete desorption of at least part of carbon dioxide to form a second solution, and the second solution is fed into the absorption unit.

Description

一种气体捕集储存系统及方法A gas capture storage system and method

本申请要求于2023年09月28日提交中国专利局、申请号为202311284358.7、发明名称为“一种气体捕集储存系统及方法”的中国专利申请的优先权,其全部内容通过引用结合在本申请中。This application claims the priority of the Chinese patent application filed with the China Patent Office on September 28, 2023, with application number 202311284358.7 and invention name “A Gas Capture and Storage System and Method”, the entire contents of which are incorporated by reference into this application.

技术领域Technical Field

本申请涉及但不限于船舶尾气净化领域。The present application relates to but is not limited to the field of ship exhaust purification.

背景技术Background Art

船舶碳捕集封存后处理技术以其减排力度大、对船舶运行工况匹配性好、经济性等优势已成为船舶排放的重要技术路线。Ship carbon capture and storage post-processing technology has become an important technical route for ship emissions due to its advantages such as large emission reduction capabilities, good matching with ship operating conditions, and economy.

技术解决方案Technical Solutions

第一方面,本申请实施例提供一种气体捕集储存系统,包括:In a first aspect, an embodiment of the present application provides a gas capture and storage system, comprising:

吸收单元,所述吸收单元具有第一进口和第一出口,含碳烟气自所述第一进口送入所述吸收单元,所述含碳烟气中含有二氧化碳,所述含碳烟气与所述吸收单元内的吸收液接触,形成第一溶液,所述第一溶液自所述第一出口送出;An absorption unit, wherein the absorption unit has a first inlet and a first outlet, the carbon-containing flue gas is fed into the absorption unit from the first inlet, the carbon-containing flue gas contains carbon dioxide, the carbon-containing flue gas contacts with the absorption liquid in the absorption unit to form a first solution, and the first solution is fed out from the first outlet;

解吸单元,所述解吸单元具有第二进口,所述第一出口送出的第一溶液自所述第二进口送入所述解吸单元;A desorption unit, wherein the desorption unit has a second inlet, and the first solution delivered from the first outlet is delivered to the desorption unit from the second inlet;

气体传送单元,所述气体传送单元用于向所述解吸单元中送入解吸气体,所述解吸气体与所述第一溶液接触,完成至少部分所述二氧化碳的解吸,形成第二溶液,所述第二溶液自所述解吸单元送入所述吸收单元。A gas transfer unit, wherein the gas transfer unit is used to feed a desorption gas into the desorption unit, wherein the desorption gas contacts the first solution to complete the desorption of at least part of the carbon dioxide to form a second solution, and the second solution is fed from the desorption unit to the absorption unit.

可选的,还包括循环单元,所述循环单元包括第一循环泵,所述第一循环泵的进口与所述第一出口连通,所述第一循环泵的出口与所述第二进口连通。Optionally, a circulation unit is further included, wherein the circulation unit includes a first circulation pump, wherein an inlet of the first circulation pump is connected to the first outlet, and an outlet of the first circulation pump is connected to the second inlet.

可选的,所述循环单元包括第二循环泵,所述吸收单元具有第三进口,所述解吸单元具有第二出口,所述第二循环泵的进口与所述第二出口连通,所述第二循环泵的出口与所述第三进口连通。Optionally, the circulation unit includes a second circulation pump, the absorption unit has a third inlet, the desorption unit has a second outlet, the inlet of the second circulation pump is connected to the second outlet, and the outlet of the second circulation pump is connected to the third inlet.

可选的,所述循环单元包括换热器,所述换热器分别与所述第一循环泵的出口和所述第二循环泵的出口连通。 Optionally, the circulation unit includes a heat exchanger, and the heat exchanger is connected to the outlet of the first circulation pump and the outlet of the second circulation pump respectively.

可选的,所述换热器具有第一换热出口,所述第一换热出口与所述第二进口连通;所述换热器具有第二换热出口,所述第二换热出口与所述第三进口连通。Optionally, the heat exchanger has a first heat exchange outlet, which is connected to the second inlet; the heat exchanger has a second heat exchange outlet, which is connected to the third inlet.

可选的,所述循环单元包括第一加热器,所述第一加热器设置于所述第一换热出口与所述第二进口之间。Optionally, the circulation unit includes a first heater, and the first heater is arranged between the first heat exchange outlet and the second inlet.

可选的,述循环单元包括冷却器,所述冷却器设置于所述第二换热出口与所述第三进口之间。Optionally, the circulation unit includes a cooler, and the cooler is arranged between the second heat exchange outlet and the third inlet.

可选的,所述气体传送单元包括膜分离器,所述解吸单元具有第三出口,所述膜分离器的进口与所述第三出口连通。Optionally, the gas transfer unit comprises a membrane separator, the desorption unit has a third outlet, and the inlet of the membrane separator is connected to the third outlet.

可选的,所述气体传送单元包括冷凝器,所述冷凝器设置于所述膜分离器与所述第三出口之间。Optionally, the gas transfer unit includes a condenser, which is arranged between the membrane separator and the third outlet.

可选的,所述气体传送单元包括第二加热器,所述解吸单元具有第四进口,所述第二加热器设置于所述膜分离器与所述第四进口之间。Optionally, the gas transfer unit comprises a second heater, the desorption unit has a fourth inlet, and the second heater is arranged between the membrane separator and the fourth inlet.

可选的,所述气体传送单元具有第五进口,所述第五进口用于送入解吸气体。Optionally, the gas delivery unit has a fifth inlet for introducing desorption gas.

第二方面,本申请还提供了一种气体捕集方法,包括:In a second aspect, the present application also provides a gas capture method, comprising:

含碳烟气送入吸收单元,所述吸收单元中具有吸收液,所述含碳烟气中包括二氧化碳,所述吸收液与所述含碳烟气接触后,形成第一溶液;The carbon-containing flue gas is sent to an absorption unit, wherein the absorption unit contains an absorption liquid, the carbon-containing flue gas contains carbon dioxide, and the absorption liquid forms a first solution after contacting the carbon-containing flue gas;

所述第一溶液送入解吸单元,气体传送单元向所述解吸单元中送入解吸气体,用于解吸所述第一溶液中的二氧化碳;The first solution is fed into a desorption unit, and a gas transmission unit feeds a desorption gas into the desorption unit to desorb carbon dioxide in the first solution;

经解吸后的第一溶液形成第二溶液,所述第二溶液自所述解吸单元送入所述吸收单元。The first solution after desorption forms a second solution, and the second solution is sent from the desorption unit to the absorption unit.

可选的,所述吸收单元具有第一气压,所述第一气压的压力范围为0.8~1.2bar。Optionally, the absorption unit has a first air pressure, and the pressure range of the first air pressure is 0.8 to 1.2 bar.

可选的,所述吸收单元具有第一温度,所述第一温度的范围为30~40℃。Optionally, the absorption unit has a first temperature, and the first temperature ranges from 30 to 40°C.

可选的,所述解吸单元具有第二气压,所述第二气压的压力范围为0.8~1.2bar。Optionally, the desorption unit has a second gas pressure, and the pressure range of the second gas pressure is 0.8 to 1.2 bar.

可选的,所述解吸单元具有第二温度,所述第二温度的范围为80~90℃。 Optionally, the desorption unit has a second temperature, and the second temperature ranges from 80 to 90°C.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

为了更清楚地说明本申请实施例中的技术方案,下面将对实施例描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本申请的一些实施例,对于本领域技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present application, the drawings required for use in the description of the embodiments will be briefly introduced below. Obviously, the drawings described below are only some embodiments of the present application. For those skilled in the art, other drawings can be obtained based on these drawings without creative work.

图1为双膜理论的气提解吸原理图;FIG1 is a schematic diagram of the gas stripping desorption principle of the double membrane theory;

图2为本申请实施例中气体捕集储存系统的结构示意图;FIG2 is a schematic diagram of the structure of a gas capture and storage system in an embodiment of the present application;

图3为本申请实施例中气体捕集方法的流程示意图。FIG3 is a schematic flow chart of a gas capture method in an embodiment of the present application.

具体实施方式DETAILED DESCRIPTION

下面将结合本申请实施例和附图对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。另外,在本申请的描述中,术语“包括”是指“包括但不限于”。用语第一、第二、第三等仅仅作为标示使用,并没有强加数字要求或建立顺序。本申请的各种实施例可以以一个范围的型式存在;应当理解,以一范围型式的描述仅仅是因为方便及简洁,不应理解为对本申请范围的硬性限制;因此,应当认为所述的范围描述已经具体公开所有可能的子范围以及该范围内的单一数值。例如,应当认为从1到6的范围描述已经具体公开子范围,例如从1到3,从1到4,从1到5,从2到4,从2到6,从3到6等,以及所数范围内的单一数字,例如1、2、3、4、5及6,此不管范围为何皆适用。另外,每当在本文中指出数值范围,是指包括所指范围内的任何引用的数字(分数或整数)。The technical solutions in the embodiments of the present application will be described clearly and completely below in combination with the embodiments of the present application and the accompanying drawings. Obviously, the described embodiments are only part of the embodiments of the present application, not all of the embodiments. Based on the embodiments in the present application, all other embodiments obtained by those skilled in the art without creative work are within the scope of protection of the present application. In addition, in the description of the present application, the term "including" means "including but not limited to". The terms first, second, third, etc. are used only as markings, and no numerical requirements or order are imposed. Various embodiments of the present application may exist in the form of a range; it should be understood that the description in the form of a range is only for convenience and simplicity, and should not be understood as a hard limit to the scope of the present application; therefore, it should be considered that the range description has specifically disclosed all possible sub-ranges and single values within the range. For example, it should be considered that the range description from 1 to 6 has specifically disclosed sub-ranges, such as from 1 to 3, from 1 to 4, from 1 to 5, from 2 to 4, from 2 to 6, from 3 to 6, etc., as well as single numbers within the numbered range, such as 1, 2, 3, 4, 5 and 6, which are applicable regardless of the range. Additionally, whenever a numerical range is indicated herein, it is meant to include any cited numeral (fractional or integral) within the indicated range.

气提解吸CO2基本原理气提解吸是基于双膜理论,如图1所示。双膜理论认为相互接触的气液两相之间存在一个相界面,两侧分别存在气膜和液膜。在解吸过程中,气膜与液膜的浓度梯度即为CO2在气相和液相之间的传质推动力,由于气液两相CO2分压不同,在压力差的推动下,CO2由分子扩散的方式到达液膜,进而经过相界面进入气膜,从而使得CO2从吸收富液中解吸出来。因此,采用不含溶质的氮气或溶剂蒸汽作为载气,将CO2从吸收液中吹 出,降低气相CO2分压,从而提高解吸过程的传质推动力,从而使得CO2可持续从吸收富液中解吸出来。气提解吸CO2优势在于所需能耗较低,推进CO2解吸反应速率、降低CO2解吸反应温度,从而减少CO2解吸过程能量消耗,降低系统运行成本;而且通入的气量越大,解吸出来的CO2量也越大。但是由于船舶运行环境限制,捕集解吸后的CO2需要在船上储罐内进行储存及后续转运利用,该过程对CO2的纯度仍有较高要求。船舶碳捕集封存后处理技术以其减排力度大、对船舶运行工况匹配性好、经济性等优势已成为船舶排放的重要技术路线。虽然该技术可以实现大规模碳减排,但存在着系统解吸能耗高的问题,难以满足实际船舶的应用需求。Basic principle of gas stripping desorption of CO2 Gas stripping desorption is based on the double membrane theory, as shown in Figure 1. The double membrane theory believes that there is a phase interface between the gas and liquid phases in contact with each other, with a gas film and a liquid film on both sides. During the desorption process, the concentration gradient between the gas film and the liquid film is the driving force for mass transfer of CO2 between the gas phase and the liquid phase. Due to the different CO2 partial pressures in the gas and liquid phases, under the impetus of the pressure difference, CO2 reaches the liquid film by molecular diffusion, and then enters the gas film through the phase interface, thereby desorbing CO2 from the absorbed rich liquid. Therefore, nitrogen or solvent vapor without solute is used as a carrier gas to blow CO2 from the absorbed liquid. The gas phase CO2 partial pressure is reduced, thereby increasing the mass transfer driving force of the desorption process, so that CO2 can be continuously desorbed from the absorbent rich liquid. The advantage of gas lift desorption of CO2 is that it requires low energy consumption, promotes the CO2 desorption reaction rate, reduces the CO2 desorption reaction temperature, thereby reducing the energy consumption of the CO2 desorption process and reducing the system operation cost; and the greater the amount of gas introduced, the greater the amount of CO2 desorbed. However, due to the limitations of the ship's operating environment, the captured and desorbed CO2 needs to be stored in the ship's storage tank and subsequently transported and utilized. This process still has high requirements for the purity of CO2 . Ship carbon capture and storage post-processing technology has become an important technical route for ship emissions due to its advantages such as large emission reduction, good matching with ship operating conditions, and economy. Although this technology can achieve large-scale carbon emission reduction, there is a problem of high system desorption energy consumption, which is difficult to meet the application needs of actual ships.

为了解决现有技术存在的问题,本申请提供了一种气体捕集储存系统,如图2所示,包括:吸收单元100,吸收单元100具有第一进口101和第一出口102,含碳烟气自第一进口101送入吸收单元100,含碳烟气中含有二氧化碳,含碳烟气与吸收单元100内的吸收液接触,形成第一溶液,第一溶液自第一出口102送出;解吸单元200,解吸单元200具有第二进口201,第一出口102送出的第一溶液自第二进口201送入解吸单元200;气体传送单元300,气体传送单元300用于向解吸单元200中送入解吸气体,解吸气体与第一溶液接触,完成至少部分二氧化碳的解吸,形成第二溶液,第二溶液自解吸单元200送入吸收单元100。本申请的气体捕集储存系统在保障船舶动力碳捕集系统完整功能的同时利用解吸气体降低解吸系统内的二氧化碳的分压,促进二氧化碳的解吸反应发生,降低解吸系统再生能耗,降低了系统运行成本,可进一步推进碳捕集技术在船舶碳减排领域应用。In order to solve the problems existing in the prior art, the present application provides a gas capture and storage system, as shown in Figure 2, comprising: an absorption unit 100, the absorption unit 100 has a first inlet 101 and a first outlet 102, the carbon-containing flue gas is fed into the absorption unit 100 from the first inlet 101, the carbon-containing flue gas contains carbon dioxide, the carbon-containing flue gas contacts with the absorption liquid in the absorption unit 100 to form a first solution, and the first solution is sent out from the first outlet 102; a desorption unit 200, the desorption unit 200 has a second inlet 201, the first solution sent out from the first outlet 102 is fed into the desorption unit 200 from the second inlet 201; a gas transfer unit 300, the gas transfer unit 300 is used to feed desorption gas into the desorption unit 200, the desorption gas contacts with the first solution, completes the desorption of at least part of the carbon dioxide, forms a second solution, and the second solution is fed from the desorption unit 200 into the absorption unit 100. The gas capture and storage system of the present application utilizes the desorption gas to reduce the partial pressure of carbon dioxide in the desorption system while ensuring the complete functionality of the ship power carbon capture system, thereby promoting the desorption reaction of carbon dioxide, reducing the regeneration energy consumption of the desorption system, and reducing the system operating costs, which can further promote the application of carbon capture technology in the field of ship carbon emission reduction.

在一些实施例中,气体捕集储存系统还包括循环单元400,循环单元400包括第一循环泵401,第一循环泵401的进口与第一出口102连通,第二进口201连通。In some embodiments, the gas capture storage system further comprises a circulation unit 400 , wherein the circulation unit 400 comprises a first circulation pump 401 , wherein an inlet of the first circulation pump 401 is connected to the first outlet 102 and the second inlet 201 .

在一些实施例中,吸收单元100的主体结构为吸收塔,吸收塔具有用于含碳烟气送入的第一进口101,在一些实施例中,第一进口101位于吸收塔的下方,含碳烟气自第一进口101送入吸收塔的下方,含碳烟气在吸收塔中自下向上流动。In some embodiments, the main structure of the absorption unit 100 is an absorption tower, which has a first inlet 101 for introducing carbon-containing flue gas. In some embodiments, the first inlet 101 is located below the absorption tower, and the carbon-containing flue gas is introduced into the bottom of the absorption tower from the first inlet 101, and the carbon-containing flue gas flows from bottom to top in the absorption tower.

在一些实施中,吸收单元100具有第三进口103,在一些实施例中,第三 进口位于吸收塔的上方,吸收液从吸收塔自上往下喷淋,含碳烟气自吸收塔底部进入向上流动,完成吸收液对于含碳烟气的吸附,其中,含碳烟气中的二氧化碳被吸收液吸附,形成第一溶液(富液)。In some implementations, the absorption unit 100 has a third inlet 103. In some embodiments, the third The inlet is located above the absorption tower, and the absorption liquid is sprayed from the absorption tower from top to bottom. The carbon-containing flue gas enters from the bottom of the absorption tower and flows upward to complete the adsorption of the carbon-containing flue gas by the absorption liquid, wherein the carbon dioxide in the carbon-containing flue gas is adsorbed by the absorption liquid to form a first solution (rich liquid).

在一些实施中,吸收塔内可布置填料,用于增加吸收液与含碳烟气的接触面积和吸附效率,在一些具体实施例中,填料可以选择波纹板、陶瓷填料、金属填料中的一种或者多种。填料可使用散装或规整填料。In some implementations, fillers may be arranged in the absorption tower to increase the contact area between the absorption liquid and the carbon-containing flue gas and the adsorption efficiency. In some specific embodiments, the fillers may be selected from one or more of corrugated plates, ceramic fillers, and metal fillers. The fillers may be bulk or structured fillers.

在一些实施例中,填料的形式、尺寸、型号与规格可根据实际脱除CO2效率、吸收塔内压降要求、液泛率要求和运行工况等参数进行选择。In some embodiments, the form, size, model and specification of the filler can be selected based on parameters such as the actual CO2 removal efficiency, pressure drop requirements in the absorption tower, liquid flooding rate requirements and operating conditions.

在一些实施例中,吸收液包括有机胺类溶液,可采用MEA(乙醇胺)、MDEA(2-甲基-二乙氨基乙醇胺)、DEA(二乙醇胺)等单一或混合有机胺溶液。In some embodiments, the absorption liquid includes an organic amine solution, and single or mixed organic amine solutions such as MEA (ethanolamine), MDEA (2-methyl-diethylaminoethanolamine), and DEA (diethanolamine) may be used.

在一些实施例中,含碳烟气经过吸收液吸附后,洁净烟气自吸收塔顶部排出。In some embodiments, after the carbon-containing flue gas is adsorbed by the absorption liquid, the clean flue gas is discharged from the top of the absorption tower.

在一些实施例中,解吸单元200的主体结构为解吸塔210,位于解吸塔210内的第一溶液(富液,吸收过CO2的吸收液)在泵组的作用下送入解吸塔210内。In some embodiments, the main structure of the desorption unit 200 is a desorption tower 210, and the first solution (rich liquid, absorption liquid that has absorbed CO2 ) in the desorption tower 210 is sent into the desorption tower 210 under the action of a pump group.

在一些实施例中,解吸塔210上设置有第二进口201,第一溶液自第二进口201送入解吸塔,在一些实施例中,第二进口201位于解吸塔210上方,第一溶液自解吸塔210的塔顶送入解吸塔210中。In some embodiments, a second inlet 201 is provided on the desorption tower 210, and the first solution is fed into the desorption tower from the second inlet 201. In some embodiments, the second inlet 201 is located above the desorption tower 210, and the first solution is fed into the desorption tower 210 from the top of the desorption tower 210.

在一些实施例中,解吸塔210内同时送入解吸气体,解吸气体可以为不含溶质的氮气或溶剂蒸汽。在一些实施例中,解吸塔210具有第四进口204,解吸气体通过第四进口204送入解吸塔210内,在一些具体实施例中,第四进口204设置于解吸塔210的内部。富液在解吸塔210内解吸,重新释放出CO2,形成第二溶液(贫液)。In some embodiments, a desorption gas is simultaneously introduced into the desorption tower 210, and the desorption gas may be nitrogen or solvent vapor without solute. In some embodiments, the desorption tower 210 has a fourth inlet 204, and the desorption gas is introduced into the desorption tower 210 through the fourth inlet 204. In some specific embodiments, the fourth inlet 204 is disposed inside the desorption tower 210. The rich liquid is desorbed in the desorption tower 210, and CO 2 is released again to form a second solution (lean liquid).

在一些实施例中,解吸塔210具有第二出口202,在一些实施例中,第二出口202位于解吸塔210底部,第二溶液通过第二出口202送入吸收塔110。In some embodiments, the desorption tower 210 has a second outlet 202 . In some embodiments, the second outlet 202 is located at the bottom of the desorption tower 210 , and the second solution is fed into the absorption tower 110 through the second outlet 202 .

在一些实施例中,解吸塔210具有第三出口203,在一些实施例中,第三出口203位于解吸塔210顶部,第三出口203用于送出位于解吸塔210内的产品气。在一些具体应用例中,解吸塔210顶部的第三出口203的产品气包括 CO2、N2和少量水蒸气,送入气体传送单元300。In some embodiments, the desorption tower 210 has a third outlet 203. In some embodiments, the third outlet 203 is located at the top of the desorption tower 210. The third outlet 203 is used to send out the product gas located in the desorption tower 210. In some specific application examples, the product gas of the third outlet 203 at the top of the desorption tower 210 includes CO 2 , N 2 and a small amount of water vapor are fed into the gas transfer unit 300 .

在一些实施例中,气体传送单元300包括膜分离器301,膜分离器301的进口与第三出口203连通,膜分离器301在一些实施例中为氮气膜分离器,同于将氮气和二氧化碳分离,分离出的二氧化碳为高纯气体,送入储罐储存。膜分离器301分离出的氮气再次送入解吸塔210中进行循环。在一些实施例中,膜分离器301配有自增压装置,将产品气压力提升,过膜分离装置后,若满足船上液化模块需求,可取消传统的压缩模块,直接将满足压力的产品气液化储存。In some embodiments, the gas transfer unit 300 includes a membrane separator 301, the inlet of the membrane separator 301 is connected to the third outlet 203, and the membrane separator 301 is a nitrogen membrane separator in some embodiments, which is used to separate nitrogen and carbon dioxide. The separated carbon dioxide is a high-purity gas and is sent to a storage tank for storage. The nitrogen separated by the membrane separator 301 is sent to the desorption tower 210 again for circulation. In some embodiments, the membrane separator 301 is equipped with a self-pressurizing device to increase the pressure of the product gas. After passing through the membrane separation device, if the requirements of the liquefaction module on the ship are met, the traditional compression module can be cancelled, and the product gas that meets the pressure can be directly liquefied and stored.

为了实现产品气的提纯,气体传送单元300还包括冷凝器302,冷凝器302设置于膜分离器301与第三出口203之间,冷凝器302用于将产品气中的水蒸气进行分离,分离出的冷凝水汽送入解吸塔210内循环,补充解吸塔210内的水汽蒸发损失。In order to purify the product gas, the gas transfer unit 300 also includes a condenser 302, which is arranged between the membrane separator 301 and the third outlet 203. The condenser 302 is used to separate water vapor in the product gas, and the separated condensed water vapor is sent to the desorption tower 210 for circulation to supplement the water vapor evaporation loss in the desorption tower 210.

在一些实施例中,气体传送单元300包括第二加热器303,解吸单元200具有第四进口204,第二加热器303设置于膜分离器301之间与第四进口204之间,用于加热送入解吸塔210内的解吸气体,维持解吸塔210内的温度,在一些具体实施例方式中,第二加热器303为电加热器,在一些具体实施例中,经过第二加热器303加热的解吸气体的温度在85~95℃,如90℃。In some embodiments, the gas transfer unit 300 includes a second heater 303, the desorption unit 200 has a fourth inlet 204, and the second heater 303 is arranged between the membrane separator 301 and the fourth inlet 204, and is used to heat the desorption gas sent into the desorption tower 210 to maintain the temperature in the desorption tower 210. In some specific embodiments, the second heater 303 is an electric heater. In some specific embodiments, the temperature of the desorption gas heated by the second heater 303 is between 85 and 95°C, such as 90°C.

在一些实施例中,气体传送单元300具有第五进口304,第五进口304用于送入解吸气体,在一些具体实施例中,第五进口304位于第二加热器303和膜分离器301之间,如第五进口304可以送入氮气,与从膜分离器301送出的氮气一起进入第二加热器303中进行加热,随后送入解吸塔210内,用于补充或者调整解吸塔210内送入的解吸气体的用量。In some embodiments, the gas transfer unit 300 has a fifth inlet 304, which is used to feed desorption gas. In some specific embodiments, the fifth inlet 304 is located between the second heater 303 and the membrane separator 301. For example, nitrogen can be fed into the fifth inlet 304, which enters the second heater 303 together with the nitrogen sent from the membrane separator 301 for heating, and then is sent into the desorption tower 210 to supplement or adjust the amount of desorption gas sent into the desorption tower 210.

在一些实施例中,本申请的捕集储存系统还包括循环单元400,循环单元400包括第一循环泵401,第一循环泵401的进口与第一出口102连通,第二进口201连通,在一些实施例中,第一循环泵401为富液循环泵。In some embodiments, the capture storage system of the present application further includes a circulation unit 400, which includes a first circulation pump 401, the inlet of the first circulation pump 401 is connected to the first outlet 102, and the second inlet 201 is connected. In some embodiments, the first circulation pump 401 is a rich liquid circulation pump.

循环单元400包括第二循环泵402,吸收单元100具有第三进口103,解吸单元200具有第二出口202,第二循环泵402的进口与第二出口202连通,第二循环泵402的出口与第三进口103连通,在一些实施例中,第二循环泵402为贫液循环泵。 The circulation unit 400 includes a second circulation pump 402, the absorption unit 100 has a third inlet 103, the desorption unit 200 has a second outlet 202, the inlet of the second circulation pump 402 is connected to the second outlet 202, and the outlet of the second circulation pump 402 is connected to the third inlet 103. In some embodiments, the second circulation pump 402 is a lean liquid circulation pump.

为了调节送入吸收塔110和解吸塔210中的贫/富液的温度,循环单元400包括换热器403,换热器403分别与第一循环泵401的出口和第二循环泵402的出口连通,换热器403具有第一换热出口4031,第一换热出口4031与第二进口201连通;换热器403具有第二换热出口4032,第二换热出口4032与第三进口103连通。In order to adjust the temperature of the lean/rich liquid sent into the absorption tower 110 and the desorption tower 210, the circulation unit 400 includes a heat exchanger 403, which is connected to the outlet of the first circulation pump 401 and the outlet of the second circulation pump 402 respectively, and the heat exchanger 403 has a first heat exchange outlet 4031, and the first heat exchange outlet 4031 is connected to the second inlet 201; the heat exchanger 403 has a second heat exchange outlet 4032, and the second heat exchange outlet 4032 is connected to the third inlet 103.

在一些实施例中,自第一循环泵401出口送入换热器403的第一溶液的温度范围在30~40℃,经过换热器403换热后,自换热器403的第一换热出口4031送出的富液的温度为75~85℃左右,如80℃。In some embodiments, the temperature range of the first solution sent from the outlet of the first circulation pump 401 to the heat exchanger 403 is 30-40°C. After heat exchange in the heat exchanger 403, the temperature of the rich liquid sent from the first heat exchange outlet 4031 of the heat exchanger 403 is about 75-85°C, such as 80°C.

在一些实施例中,自第二循环泵402出口送入换热器403的第二溶液的温度范围在85~95℃,如90℃,经过换热器403换热后,自换热器403的第二换热出口4032送出的贫液的温度为45~55℃左右,如50℃。In some embodiments, the temperature range of the second solution sent from the outlet of the second circulation pump 402 to the heat exchanger 403 is 85-95°C, such as 90°C. After heat exchange in the heat exchanger 403, the temperature of the lean liquid sent from the second heat exchange outlet 4032 of the heat exchanger 403 is about 45-55°C, such as 50°C.

在一些实施例中,循环单元400包括第一加热器404,第一加热器404设置于第一换热出口4031与第二进口201之间。第一加热器404用于加热自换热器403送出的第一溶液,将第一溶液加热至所需温度,如从80℃加热至90℃。In some embodiments, the circulation unit 400 includes a first heater 404 disposed between the first heat exchange outlet 4031 and the second inlet 201. The first heater 404 is used to heat the first solution sent from the heat exchanger 403 to a desired temperature, such as from 80°C to 90°C.

在一些实施例中,循环单元400包括冷却器405,冷却器405设置于第二换热出口4032与第三进口103之间,冷却器405用于降低进入吸收塔110内的第二溶液的温度,如将第二溶液的温度从50℃降至40℃。In some embodiments, the circulation unit 400 includes a cooler 405, which is disposed between the second heat exchange outlet 4032 and the third inlet 103. The cooler 405 is used to reduce the temperature of the second solution entering the absorption tower 110, such as reducing the temperature of the second solution from 50°C to 40°C.

如图3所示,利用如图2所示的气体捕集储存系统的气体捕集方法,包括:As shown in FIG3 , a gas capture method using the gas capture storage system shown in FIG2 includes:

含碳烟气送入吸收单元100,吸收单元100中具有吸收液,含碳烟气中包括二氧化碳,吸收液与含碳烟气接触后,形成第一溶液;第一溶液送入解吸单元200,气体传送单元300向解吸单元200中送入解吸气体,用于解吸第一溶液中的二氧化碳;经解吸后的第一溶液形成第二溶液,第二溶液自解吸单元200送入吸收单元100。The carbon-containing flue gas is sent to the absorption unit 100, which contains an absorption liquid. The carbon-containing flue gas includes carbon dioxide. After the absorption liquid contacts the carbon-containing flue gas, a first solution is formed; the first solution is sent to the desorption unit 200, and the gas transfer unit 300 sends desorption gas to the desorption unit 200 to desorb the carbon dioxide in the first solution; the first solution after desorption forms a second solution, and the second solution is sent from the desorption unit 200 to the absorption unit 100.

在一些具体应用例中,含有CO2的高温船舶尾气首先流经吸收塔110中,在吸收塔110中船舶尾气与吸收液进行逆流对流传质,随后洁净尾气经由吸收塔110顶部排出。富液在泵组作用下经由换热器403加热后有顶部进入解吸塔210。在解吸塔210内,富液从上部进入塔内,氮气经由第一加热器404加热后从下部进入塔内,富液在热氮气的作用下进行解吸,重新释放出CO2。解吸塔顶部出口的产品气(CO2+N2+少量水蒸气)经过冷凝器302和膜分离器301, 提纯的高纯度CO2气体将被排出该系统,进行下一步储存。分离后的氮气经由膜分离器301和第一加热器404再从解吸塔210下部进入解吸塔210继续下一个循环。In some specific application examples, the high-temperature ship exhaust gas containing CO 2 first flows through the absorption tower 110, where the ship exhaust gas and the absorption liquid are subjected to countercurrent convection mass transfer, and then the clean exhaust gas is discharged from the top of the absorption tower 110. The rich liquid is heated by the heat exchanger 403 under the action of the pump group and enters the desorption tower 210 from the top. In the desorption tower 210, the rich liquid enters the tower from the top, and the nitrogen enters the tower from the bottom after being heated by the first heater 404. The rich liquid is desorbed under the action of the hot nitrogen and CO 2 is released again. The product gas (CO 2 +N2 + a small amount of water vapor) at the top outlet of the desorption tower passes through the condenser 302 and the membrane separator 301, The purified high-purity CO 2 gas will be discharged from the system for the next step of storage. The separated nitrogen gas will then enter the desorption tower 210 from the lower part of the desorption tower 210 through the membrane separator 301 and the first heater 404 to continue the next cycle.

在一些具体实施例中,吸收液为有机胺溶液,本申请采用有机胺溶液对含碳烟气中CO2进行化学吸收与解吸,解吸气体为氮气,采用氮气汽提解吸,降低解吸塔210环境中CO2分压,促进解吸反应发生。该过程正反应(吸收)发生在常温30-40℃和常压环境下,逆反应(解吸)发生在较低温度80-90℃和常压环境下。In some specific embodiments, the absorption liquid is an organic amine solution. The present application uses an organic amine solution to chemically absorb and desorb CO 2 in carbon-containing flue gas. The desorption gas is nitrogen. Nitrogen stripping is used for desorption to reduce the CO 2 partial pressure in the desorption tower 210 environment and promote the desorption reaction. The positive reaction (absorption) of this process occurs at room temperature 30-40°C and normal pressure, and the reverse reaction (desorption) occurs at a lower temperature 80-90°C and normal pressure.

在具体应用例中,吸收塔110具有第一气压,第一气压的压力范围为0.8~1.2bar,如第一气压为1bar。本申请的吸收塔110的最佳气压为1bar,整个系统无需施加任何压力,降低了对于循环单元400中循环泵等的元件压力。此外,利用氮气气体降低解吸塔210内CO2气体分压,促进CO2解吸反应发生,降低系统再生能耗,削减了系统运行成本。在具体应用例中,吸收塔110内具有第一温度,第一温度的范围为30~40℃。In a specific application example, the absorption tower 110 has a first gas pressure, and the pressure range of the first gas pressure is 0.8 to 1.2 bar, such as the first gas pressure is 1 bar. The optimal gas pressure of the absorption tower 110 of the present application is 1 bar, and the entire system does not need to apply any pressure, which reduces the pressure on components such as the circulation pump in the circulation unit 400. In addition, nitrogen gas is used to reduce the CO2 gas partial pressure in the desorption tower 210, promote the CO2 desorption reaction, reduce the system regeneration energy consumption, and cut the system operating cost. In a specific application example, the absorption tower 110 has a first temperature, and the first temperature ranges from 30 to 40°C.

在具体应用例中,解吸塔210具有第二气压,第二气压的压力范围为0.8~1.2bar,如第二气压为1bar。本申请的解吸塔210的最佳气压为1bar,整个系统无需施加任何压力,降低了对于循环单元400中循环泵等的元件压力和泵组的用量,降低了施工难度。在具体应用例中,解吸塔210具有第二温度,第二温度的范围为80~90℃。In a specific application example, the desorption tower 210 has a second air pressure, and the pressure range of the second air pressure is 0.8 to 1.2 bar, such as 1 bar. The optimal air pressure of the desorption tower 210 of the present application is 1 bar, and the entire system does not need to apply any pressure, which reduces the pressure of components such as the circulation pump in the circulation unit 400 and the amount of the pump group, and reduces the construction difficulty. In a specific application example, the desorption tower 210 has a second temperature, and the second temperature range is 80 to 90°C.

本申请的采用氮气气提解吸CO2,无需将吸收液加热至解吸温度110-120℃,减少了对船端的能耗需求,保证了系统功能完整性。The present application adopts nitrogen stripping to desorb CO 2 , and there is no need to heat the absorption liquid to the desorption temperature of 110-120° C., which reduces the energy consumption demand on the ship side and ensures the functional integrity of the system.

在一些具体实施例中,通过以下方法捕集二氧化碳:In some specific embodiments, carbon dioxide is captured by:

含碳烟气送入吸收单元100,吸收单元100中具有吸收液,含碳烟气中包括二氧化碳,吸收液与含碳烟气接触后,形成第一溶液,吸收塔110内的吸收液为有机胺溶液,吸收塔内的温度为40℃,吸收塔110内的气压为1bar;The carbon-containing flue gas is sent to the absorption unit 100. The absorption unit 100 contains an absorption liquid. The carbon-containing flue gas contains carbon dioxide. After the absorption liquid contacts the carbon-containing flue gas, a first solution is formed. The absorption liquid in the absorption tower 110 is an organic amine solution. The temperature in the absorption tower is 40° C. and the air pressure in the absorption tower 110 is 1 bar.

第一溶液经过换热器403换热后,送入解吸单元200,经过换热器403换热后的第一溶液的温度由40℃升至80℃;当解吸塔210内的温度维持在80℃,则此时第一加热器404无需加热,当解吸塔210内的温度维持在90℃,则通过第一加热器404将富液加热至90℃送至解吸塔210内; After the first solution is heat exchanged in the heat exchanger 403, it is sent to the desorption unit 200. The temperature of the first solution after heat exchange in the heat exchanger 403 rises from 40°C to 80°C. When the temperature in the desorption tower 210 is maintained at 80°C, the first heater 404 does not need to be heated. When the temperature in the desorption tower 210 is maintained at 90°C, the rich solution is heated to 90°C by the first heater 404 and sent to the desorption tower 210.

气体传送单元300向解吸单元200中送入解吸气体,解吸气体为氮气,通过第二加热器303将氮气加热至90℃,自下而上送入解吸塔210,用于解吸第一溶液中的二氧化碳,解吸塔210的温度维持在80~90℃,气压为1bar,在本实施例中,解吸塔210的温度维持在90℃,The gas transfer unit 300 feeds desorption gas into the desorption unit 200. The desorption gas is nitrogen. The nitrogen is heated to 90° C. by the second heater 303 and fed to the desorption tower 210 from bottom to top for desorbing carbon dioxide in the first solution. The temperature of the desorption tower 210 is maintained at 80-90° C. and the pressure is 1 bar. In this embodiment, the temperature of the desorption tower 210 is maintained at 90° C.

经解吸后的第一溶液形成第二溶液,第二溶液经过换热器403换热后,第二溶液经过换热器403换热后,温度从90℃降低至50℃,随后,通过设置在换热器403和吸收塔110的第三进口103之间的冷却器冷却至40℃送入吸收塔110。The first solution after desorption forms a second solution. After the second solution passes through the heat exchanger 403 for heat exchange, the temperature of the second solution drops from 90°C to 50°C. Subsequently, the second solution is cooled to 40°C by a cooler arranged between the heat exchanger 403 and the third inlet 103 of the absorption tower 110 and is sent to the absorption tower 110.

自解吸塔210的第三出口203送出的产品气经冷凝器302冷却至30℃送入氮气膜分离器,经过氮气膜分离器分离的二氧化碳送入下一程序,分离的氮气再次进入循环。The product gas sent out from the third outlet 203 of the desorption tower 210 is cooled to 30° C. by the condenser 302 and sent to the nitrogen membrane separator. The carbon dioxide separated by the nitrogen membrane separator is sent to the next process, and the separated nitrogen enters the cycle again.

请参见表1所示,表1中的二氧化碳解吸的能耗和本申请气提解吸方法的能耗作对比:吸收塔的设置参数相同,二氧化碳解吸与本申请的不同之处在于,不设置气体传送单元,二氧化碳解吸方法中的解吸塔内的温度范围为110~120℃,压力为1.5bar,本申请的解吸塔的温度范围为80-90℃,压力为1bar。Please refer to Table 1, which compares the energy consumption of carbon dioxide desorption in Table 1 with the energy consumption of the gas lift desorption method of the present application: the setting parameters of the absorption tower are the same, the difference between the carbon dioxide desorption and the present application is that no gas transfer unit is set, the temperature range of the desorption tower in the carbon dioxide desorption method is 110-120°C, and the pressure is 1.5bar, and the temperature range of the desorption tower of the present application is 80-90°C, and the pressure is 1bar.

表1 不同工艺能耗对比
Table 1 Comparison of energy consumption of different processes

表2 本申请中气提解吸能耗


注1:表2的能耗是以150Nm3/h产品气进行计算;显热40~80包括了第一加热器和第二加热器
的能耗总和;
Table 2 Energy consumption of gas stripping desorption in this application


Note 1: The energy consumption in Table 2 is calculated based on 150Nm 3 /h product gas; the sensible heat of 40 to 80 includes the total energy consumption of the first heater and the second heater;

从表1和表2的结果可以看出,本申请通过气提解吸方法捕集含碳烟气中的二氧化碳,可以大幅降低系统能耗,降低了循环单元400送入解吸塔210内的富液的温度,降低了整个系统的能耗。且本申请通过氮气膜分离器,不仅可以分离二氧化碳和解吸气体,且分离出的二氧化碳可以直接将满足压力的产品气液化储存,无需单独增加加压装置。且本申请通过解吸气体送入解吸塔210,降低了二氧化碳的解吸压力。It can be seen from the results of Table 1 and Table 2 that the present application captures carbon dioxide in carbon-containing flue gas by a gas stripping desorption method, which can greatly reduce the energy consumption of the system, reduce the temperature of the rich liquid sent into the desorption tower 210 by the circulation unit 400, and reduce the energy consumption of the entire system. In addition, the present application can not only separate carbon dioxide and desorption gas through a nitrogen membrane separator, but also the separated carbon dioxide can directly liquefy and store the product gas that meets the pressure without adding a separate pressurizing device. In addition, the present application reduces the desorption pressure of carbon dioxide by sending the desorption gas into the desorption tower 210.

在上述实施例中,对各个实施例的描述都各有侧重,某个实施例中没有详述的部分,可以参见其他实施例的相关描述。In the above embodiments, the description of each embodiment has its own emphasis. For parts that are not described in detail in a certain embodiment, reference can be made to the relevant descriptions of other embodiments.

以上对本申请实施例所提供的一种气体捕集储存系统及方法进行了详细介绍,本文中应用了具体个例对本申请的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本申请的方法及其核心思想;同时,对于本领域的技术人员,依据本申请的思想,在具体实施方式及应用范围上均会有改变之处,综上所述,本说明书内容不应理解为对本申请的限制。The above is a detailed introduction to a gas capture and storage system and method provided in the embodiments of the present application. Specific examples are used herein to illustrate the principles and implementation methods of the present application. The description of the above embodiments is only used to help understand the method of the present application and its core idea. At the same time, for those skilled in the art, according to the idea of the present application, there will be changes in the specific implementation methods and application scope. In summary, the content of this specification should not be understood as a limitation on the present application.

图中附图标记:100-吸收单元,110-吸收塔101-第一进口,102-第一出口,103-第三进口,200-解吸单元,210-解吸塔,201-第二进口,202-第二出口,203-第三出口,204-第四进口,300-气体传送单元,301-膜分离器,302-冷凝器,303-第二加热器,304-第五进口,400-循环单元,401-第一循环泵,402-第二循环泵,403-换热器,4031-第一换热出口,4032-第二换热出口,404-第一加热器,405-冷却器。 Reference numerals in the figure: 100-absorption unit, 110-absorption tower 101-first inlet, 102-first outlet, 103-third inlet, 200-desorption unit, 210-desorption tower, 201-second inlet, 202-second outlet, 203-third outlet, 204-fourth inlet, 300-gas transfer unit, 301-membrane separator, 302-condenser, 303-second heater, 304-fifth inlet, 400-circulation unit, 401-first circulation pump, 402-second circulation pump, 403-heat exchanger, 4031-first heat exchange outlet, 4032-second heat exchange outlet, 404-first heater, 405-cooler.

Claims (18)

一种气体捕集储存系统,包括:A gas capture storage system, comprising: 吸收单元(100),所述吸收单元(100)具有第一进口(101)和第一出口(102),含碳烟气自所述第一进口(101)送入所述吸收单元(100),所述含碳烟气中含有二氧化碳,所述含碳烟气与所述吸收单元(100)内的吸收液接触,形成第一溶液,所述第一溶液自所述第一出口(102)送出;An absorption unit (100), the absorption unit (100) having a first inlet (101) and a first outlet (102), carbon-containing flue gas is fed into the absorption unit (100) from the first inlet (101), the carbon-containing flue gas contains carbon dioxide, the carbon-containing flue gas contacts with an absorption liquid in the absorption unit (100) to form a first solution, and the first solution is fed out from the first outlet (102); 解吸单元(200),所述解吸单元(200)具有第二进口(201),所述第一出口(102)送出的第一溶液自所述第二进口(201)送入所述解吸单元(200);A desorption unit (200), wherein the desorption unit (200) has a second inlet (201), and the first solution delivered from the first outlet (102) is delivered to the desorption unit (200) from the second inlet (201); 气体传送单元(300),所述气体传送单元(300)用于向所述解吸单元(200)中送入解吸气体,所述解吸气体与所述第一溶液接触,完成至少部分所述二氧化碳的解吸,形成第二溶液,所述第二溶液自所述解吸单元(200)送入所述吸收单元(100)。A gas transfer unit (300), wherein the gas transfer unit (300) is used to feed a desorption gas into the desorption unit (200), wherein the desorption gas contacts the first solution to complete the desorption of at least a portion of the carbon dioxide to form a second solution, and the second solution is fed from the desorption unit (200) into the absorption unit (100). 根据权利要求1所述的气体捕集储存系统,其中还包括循环单元(400),所述循环单元(400)包括第一循环泵(401),所述第一循环泵(401)的进口与所述第一出口(102)连通,所述第一循环泵(401)的出口与所述第二进口(201)连通。The gas capture storage system according to claim 1, further comprising a circulation unit (400), wherein the circulation unit (400) comprises a first circulation pump (401), wherein the inlet of the first circulation pump (401) is connected to the first outlet (102), and the outlet of the first circulation pump (401) is connected to the second inlet (201). 根据权利要求2所述的气体捕集储存系统,其中,所述循环单元(400)包括第二循环泵(402),所述吸收单元(100)具有第三进口(103),所述解吸单元(200)具有第二出口(202),所述第二循环泵(402)的进口与所述第二出口(202)连通,所述第二循环泵(402)的出口与所述第三进口(103)连通。The gas capture storage system according to claim 2, wherein the circulation unit (400) comprises a second circulation pump (402), the absorption unit (100) has a third inlet (103), the desorption unit (200) has a second outlet (202), the inlet of the second circulation pump (402) is connected to the second outlet (202), and the outlet of the second circulation pump (402) is connected to the third inlet (103). 根据权利要求3所述的气体捕集储存系统,其中,所述循环单元(400)包括换热器(403),所述换热器(403)分别与所述第一循环泵(401)的出口和所述第二循环泵(402)的出口连通。The gas capture storage system according to claim 3, wherein the circulation unit (400) comprises a heat exchanger (403), and the heat exchanger (403) is respectively connected to the outlet of the first circulation pump (401) and the outlet of the second circulation pump (402). 根据权利要求4所述的气体捕集储存系统,其中,所述换热器(403)具有第一换热出口(4031),所述第一换热出口(4031)与所述第二进口(201)连通;所述换热器(403)具有第二换热出口(4032),所述第二换热出口(4032)与所述第三进口(103)连通。The gas capture storage system according to claim 4, wherein the heat exchanger (403) has a first heat exchange outlet (4031), and the first heat exchange outlet (4031) is connected to the second inlet (201); the heat exchanger (403) has a second heat exchange outlet (4032), and the second heat exchange outlet (4032) is connected to the third inlet (103). 根据权利要求5所述的气体捕集储存系统,其中,所述循环单元(400) 包括第一加热器(404),所述第一加热器(404)设置于所述第一换热出口(4031)与所述第二进口(201)之间。The gas capture storage system according to claim 5, wherein the circulation unit (400) It comprises a first heater (404), wherein the first heater (404) is arranged between the first heat exchange outlet (4031) and the second inlet (201). 根据权利要求5或6所述的气体捕集储存系统,其中,所述循环单元(400)包括冷却器(405),所述冷却器(405)设置于所述第二换热出口(4032)与所述第三进口(103)之间。The gas capture storage system according to claim 5 or 6, wherein the circulation unit (400) comprises a cooler (405), and the cooler (405) is arranged between the second heat exchange outlet (4032) and the third inlet (103). 根据权利要求5-7中任一项所述的气体捕集储存系统,其中,所述气体传送单元(300)包括膜分离器(301),所述解吸单元(200)具有第三出口(203),所述膜分离器(301)的进口与所述第三出口(203)连通。The gas capture storage system according to any one of claims 5 to 7, wherein the gas transfer unit (300) comprises a membrane separator (301), the desorption unit (200) has a third outlet (203), and the inlet of the membrane separator (301) is connected to the third outlet (203). 根据权利要求8所述的气体捕集储存系统,其中,所述气体传送单元(300)包括冷凝器(302),所述冷凝器(302)设置于所述膜分离器(301)与所述第三出口(203)之间。The gas capture storage system according to claim 8, wherein the gas transfer unit (300) comprises a condenser (302), and the condenser (302) is arranged between the membrane separator (301) and the third outlet (203). 根据权利要求8或9所述的气体捕集储存系统,其中,所述气体传送单元(300)包括第二加热器(303),所述解吸单元(200)具有第四进口(204),所述第二加热器(303)设置于所述膜分离器(301)与所述第四进口(204)之间。The gas capture storage system according to claim 8 or 9, wherein the gas transfer unit (300) comprises a second heater (303), the desorption unit (200) has a fourth inlet (204), and the second heater (303) is arranged between the membrane separator (301) and the fourth inlet (204). 根据权利要求8-10中任一项所述的气体捕集储存系统,其中,所述气体传送单元(300)具有第五进口(304),所述第五进口(304)用于送入解吸气体。The gas capture storage system according to any one of claims 8 to 10, wherein the gas transfer unit (300) has a fifth inlet (304), and the fifth inlet (304) is used to feed the desorption gas. 一种气体捕集方法,包括:A gas capture method comprising: 含碳烟气送入吸收单元(100),所述吸收单元(100)中具有吸收液,所述含碳烟气中包括二氧化碳,所述吸收液与所述含碳烟气接触后,形成第一溶液;The carbon-containing flue gas is fed into an absorption unit (100), wherein the absorption unit (100) contains an absorption liquid, the carbon-containing flue gas contains carbon dioxide, and the absorption liquid forms a first solution after contacting the carbon-containing flue gas; 所述第一溶液送入解吸单元(200),气体传送单元(300)向所述解吸单元(200)中送入解吸气体,用于解吸所述第一溶液中的二氧化碳;The first solution is fed into a desorption unit (200), and a gas transmission unit (300) feeds a desorption gas into the desorption unit (200) for desorbing carbon dioxide in the first solution; 经解吸后的第一溶液形成第二溶液,所述第二溶液自所述解吸单元(200)送入所述吸收单元(100)。The first solution after desorption forms a second solution, and the second solution is sent from the desorption unit (200) to the absorption unit (100). 根据权利要求12所述的气体捕集方法,其中,所述吸收单元(100)具有第一气压,所述第一气压的压力范围为0.8~1.2bar。The gas capture method according to claim 12, wherein the absorption unit (100) has a first gas pressure, and the pressure range of the first gas pressure is 0.8 to 1.2 bar. 根据权利要求12所述的气体捕集方法,其中,所述吸收单元(100)具 有第一温度,所述第一温度的范围为30~40℃。The gas capture method according to claim 12, wherein the absorption unit (100) has There is a first temperature, and the first temperature ranges from 30 to 40°C. 根据权利要求12所述的气体捕集方法,其中,所述吸收单元(100)具有第一气压,所述第一气压的压力范围为0.8~1.2bar,所述吸收单元(100)具有第一温度,所述第一温度的范围为30~40℃。The gas capture method according to claim 12, wherein the absorption unit (100) has a first gas pressure, the pressure range of the first gas pressure is 0.8 to 1.2 bar, and the absorption unit (100) has a first temperature, the first temperature range is 30 to 40°C. 根据权利要求12-15中任一项所述的气体捕集方法,其中,所述解吸单元(200)具有第二气压,所述第二气压的压力范围为0.8~1.2bar。The gas capture method according to any one of claims 12 to 15, wherein the desorption unit (200) has a second gas pressure, and the pressure range of the second gas pressure is 0.8 to 1.2 bar. 根据权利要求12-15中任一项所述的气体捕集方法,其中,所述解吸单元(200)具有第二温度,所述第二温度的范围为80~90℃。The gas capture method according to any one of claims 12 to 15, wherein the desorption unit (200) has a second temperature, and the second temperature ranges from 80 to 90°C. 根据权利要求12-15中任一项所述的气体捕集方法,其中,所述解吸单元(200)具有第二气压,所述第二气压的压力范围为0.8~1.2ba,所述解吸单元(200)具有第二温度,所述第二温度的范围为80~90℃。 The gas capture method according to any one of claims 12 to 15, wherein the desorption unit (200) has a second gas pressure, the pressure range of the second gas pressure is 0.8 to 1.2 bar, and the desorption unit (200) has a second temperature, the second temperature range is 80 to 90°C.
PCT/CN2024/107327 2023-09-28 2024-07-24 Gas capture and storage system and method Pending WO2025066493A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202311284358.7A CN117180928A (en) 2023-09-28 2023-09-28 A gas capture and storage system and method
CN202311284358.7 2023-09-28

Publications (1)

Publication Number Publication Date
WO2025066493A1 true WO2025066493A1 (en) 2025-04-03

Family

ID=88985067

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2024/107327 Pending WO2025066493A1 (en) 2023-09-28 2024-07-24 Gas capture and storage system and method

Country Status (2)

Country Link
CN (1) CN117180928A (en)
WO (1) WO2025066493A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117180928A (en) * 2023-09-28 2023-12-08 中国船舶集团有限公司第七一一研究所 A gas capture and storage system and method
CN118022500A (en) * 2024-03-29 2024-05-14 大连理工大学 Ship carbon capture integrated circulation device and working method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102985161A (en) * 2010-07-09 2013-03-20 美国碳捕集与利用技术开发公司 A gas pressurized separation column and process to generate a high pressure product gas
WO2015076859A1 (en) * 2013-11-22 2015-05-28 Eliot Gerber Production of electric power from fossil fuel with almost zero air pollution
CN110152489A (en) * 2019-05-27 2019-08-23 重庆大学 The carbon dioxide capture system and method recycled based on steam turbine exhaust heat
CN218544490U (en) * 2022-05-31 2023-02-28 华能营口热电有限责任公司 Flue gas waste heat recovery device of coupling carbon entrapment
CN218637003U (en) * 2022-10-31 2023-03-17 福建龙净环保股份有限公司 Flue gas carbon dioxide capture system
CN117180928A (en) * 2023-09-28 2023-12-08 中国船舶集团有限公司第七一一研究所 A gas capture and storage system and method

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101185825A (en) * 2007-09-14 2008-05-28 江苏惠利特环保设备有限公司 Oil gas recovery method and device using absorption method and membrane separating method integration technology
CN101830462B (en) * 2010-06-03 2012-05-23 清华大学 A method for CO2 capture using a combination of dimethyl carbonate absorption and membrane desorption

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102985161A (en) * 2010-07-09 2013-03-20 美国碳捕集与利用技术开发公司 A gas pressurized separation column and process to generate a high pressure product gas
WO2015076859A1 (en) * 2013-11-22 2015-05-28 Eliot Gerber Production of electric power from fossil fuel with almost zero air pollution
CN110152489A (en) * 2019-05-27 2019-08-23 重庆大学 The carbon dioxide capture system and method recycled based on steam turbine exhaust heat
CN218544490U (en) * 2022-05-31 2023-02-28 华能营口热电有限责任公司 Flue gas waste heat recovery device of coupling carbon entrapment
CN218637003U (en) * 2022-10-31 2023-03-17 福建龙净环保股份有限公司 Flue gas carbon dioxide capture system
CN117180928A (en) * 2023-09-28 2023-12-08 中国船舶集团有限公司第七一一研究所 A gas capture and storage system and method

Also Published As

Publication number Publication date
CN117180928A (en) 2023-12-08

Similar Documents

Publication Publication Date Title
WO2025066493A1 (en) Gas capture and storage system and method
CN102985161B (en) The separation equipment and process thereof of producing gases at high pressure is purged by gas pressurized
CN114768488A (en) A coal-fired unit flue gas carbon dioxide capture system
CN103463955B (en) A kind of technique of separation and recovery carbon dioxide from industrial tail gas
CN110115910A (en) A kind of energy-saving carbon dioxide capture system and method
CN102413901B (en) Apparatus and method for compressing co2, system and method for separating and recovering co2
CN109999618A (en) A system and method for separating carbon dioxide from a medium and high pressure gas source
CN114963218A (en) Flue gas waste heat recovery device and method coupled with carbon capture
CN114917726B (en) CO (carbon monoxide) 2 Trapping device
CN212166984U (en) CO2 capture system
CN106362551A (en) System and technology for trapping CO2 in smoke
CN105749728B (en) Method and apparatus for capturing carbon dioxide
CN219539893U (en) Carbon dioxide trapping system and carbon dioxide treatment system
WO2024104091A1 (en) Energy-saving system and process for flue gas decarbonization and deoxygenation
WO2009155790A1 (en) System and method for separating carbon dioxide
CN202844827U (en) Smoke gas desulfurization system
CN117000005A (en) A system and method for capturing carbon dioxide in flue gas
CN119034434A (en) Carbon dioxide phase change absorbent, capture system and method
CN115463521A (en) A low energy consumption carbon capture device and method
CN103157346B (en) Low-temperature rectisol and CO 2trapping coupling process and system
CN117771889A (en) Double-tower serial carbon dioxide trapping system
CN111054187A (en) Recovery system and gas recovery method
CN118698282A (en) A composite amine absorption system suitable for low partial pressure CO2 capture and purification and a CO2 capture and purification device
CN220418200U (en) Carbon dioxide capturing and recycling modularized device for ground oil-gas engineering
US9962655B2 (en) Acid gas capture system and method saving energy by cooling absorbent, which has passed reboiler, by means of steam condensate

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 24870047

Country of ref document: EP

Kind code of ref document: A1