WO2024252004A1 - A 2d material-metamaterial photodetector - Google Patents

A 2d material-metamaterial photodetector Download PDF

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Publication number
WO2024252004A1
WO2024252004A1 PCT/EP2024/065829 EP2024065829W WO2024252004A1 WO 2024252004 A1 WO2024252004 A1 WO 2024252004A1 EP 2024065829 W EP2024065829 W EP 2024065829W WO 2024252004 A1 WO2024252004 A1 WO 2024252004A1
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WIPO (PCT)
Prior art keywords
layer
contact
photodetector
resonators
lines
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PCT/EP2024/065829
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French (fr)
Inventor
Stefan Martin Köpfli
Alexander DORODNYY
Michael Baumann
Juerg Leuthold
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Eidgenoessische Technische Hochschule Zurich ETHZ
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Eidgenoessische Technische Hochschule Zurich ETHZ
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Priority to EP24731596.3A priority Critical patent/EP4725058A1/en
Publication of WO2024252004A1 publication Critical patent/WO2024252004A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/10Semiconductor bodies
    • H10F77/16Material structures, e.g. crystalline structures, film structures or crystal plane orientations
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F30/00Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors
    • H10F30/20Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors
    • H10F30/21Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors the devices being sensitive to infrared, visible or ultraviolet radiation
    • H10F30/22Individual radiation-sensitive semiconductor devices in which radiation controls the flow of current through the devices, e.g. photodetectors the devices having potential barriers, e.g. phototransistors the devices being sensitive to infrared, visible or ultraviolet radiation the devices having only one potential barrier, e.g. photodiodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/10Semiconductor bodies
    • H10F77/12Active materials
    • H10F77/122Active materials comprising only Group IV materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/20Electrodes
    • H10F77/206Electrodes for devices having potential barriers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/40Optical elements or arrangements
    • H10F77/413Optical elements or arrangements directly associated or integrated with the devices, e.g. back reflectors
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/10Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
    • G02B6/12Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
    • G02B6/12004Combinations of two or more optical elements

Definitions

  • the present invention relates to a 2D material-metamaterial photodetector.
  • the present invention relates to an infrared 2D material-metamaterial photodetector operating at infrared wavelengths.
  • the present invention relates to a high-speed 2D material-metamaterial photodetector.
  • Photodetectors convert a signal from an optical domain into an electrical domain. Requirements for photodetectors are that they must be cheap, be compact, have low power consumption, have a predefined conversion efficiency, operate in a predefined spectral broadband window and have a fast response.
  • the majority of photodetectors absorb an optical signal of a specific wavelength range and convert the absorbed optical signal in part into charge carriers.
  • the charge carriers can be detected by electrically measuring a change of a voltage or a current.
  • Infrared photodetectors operate at an infrared wavelength and are widely used in optical communication links, sensing applications, imaging, etc. Most implementations of infrared photodetectors rely on semiconductor devices. They operate by using a bandgap of an active material to absorb the optical signal, wherein a bias voltage is applied to the active material in order to extract charge carriers generated by the absorption of the optical signal. Typically, these devices rely on expensive crystalline materials that are difficult to manufacture and integrate.
  • Efficient and high-speed performance is determined by the semiconductor material. Further, they have a trade-off between active area size, saturation power and bandwidth.
  • 2D materials refer to crystalline solids consisting of a single layer of atoms. 2D materials can include more than one layer of atoms, with in-plane interatomic forces higher than out of plane forces. Research towards 2D materials as active materials in infrared photodetectors is on-going. Typically, such photodetectors rely on photonic integrated circuits (waveguides) to increase the interaction length with the 2D materials and the absorption of photons. These approaches often have limited optical saturation powers, work within a relatively narrow spectral window and come at increased costs. Furthermore, highest operation bandwidths so far have been limited to around 100 GHz and they often required a bias voltage.
  • US20220307974A1 shows that a photodetector's poor active semiconductor medium quality can be compensated by co-integration into a metamaterial perfect absorber (MPA) structure.
  • MPA metamaterial perfect absorber
  • a resonator layer simultaneously acts as electrodes.
  • An aspect of the invention relates to a photodetector, comprising: a multilayer stack comprising a resonator layer which is in contact with a 2D material layer which is in contact with an insulator spacer layer, wherein the multilayer stack is configured to absorb an optical signal and to convert the absorbed optical signal into charge carriers and to enable electrically measuring the charge carriers, wherein the 2D material layer includes one or more layers of a 2D material, wherein the resonator layer comprises first and second contact lines which have an alternating configuration, wherein the first and second contact lines include different materials, wherein at least one of the first and second contact lines has arranged resonators.
  • the photodetector enables various applications. High bandwidths are enabled.
  • the different materials of the first and second contact lines are selected such that electrical contact properties and/or 2D material layer properties are influenced or improved.
  • alternating materials in the first and second contact lines can dope a 2D material channel with a p-n profile.
  • the contact lines include a contact layer which is in contact with the 2D material layer and a capping layer which is in contact with the contact layer, wherein a material of the contact layer differs from a material of the capping layer.
  • the first contact lines include a first contact layer which is in contact with the 2D material layer and a first capping layer which is in contact with the first contact layer
  • the second contact lines include a second contact layer which is in contact with the 2D material layer and a second capping layer which is in contact with the second contact layer, wherein a material of the first contact layer differs from a material of the second contact layer and/or a material of the first capping layer differs from a material of the second capping layer.
  • the 2D material includes one or more of a graphene in case of more than one layers of a 2D material, a semiconducting material, a Van Der Waals heterostructure material, and a semimetal material.
  • the insulator spacer layer is in contact with a backside reflector layer.
  • a modified metamaterial perfect absorber is enabled.
  • the photodetector is arranged in a device architecture comprising a ground line and a signal line which are in contact with the resonator layer, wherein the insulator spacer layer is in contact with a backside reflector layer, further comprising a gate line which is in contact with the backside reflector layer, wherein there is no overlap between the gate line and the signal line. High bandwidths are enabled.
  • a 2D material insulator is arranged between the spacer layer and the 2D material layer.
  • the resonator layer includes first resonators connected to contact lines, wherein second resonators are arranged in an orthogonal fashion with respect to the first resonators, wherein the second resonators are connected to the contact lines.
  • the resonator have different geometries which are selected such that absorption in multiple bands is achieved.
  • the resonators can have different widths and/or a lengths to achieve absorption in multiple bands.
  • a frontside 2D material insulator which is in contact with the 2D material layer in a configuration which enables that the 2D material layer remains in contact with the resonator layer.
  • the resonator layer includes first contact lines connected to resonators, and wherein the resonator layer includes second contact lines without resonators.
  • the spacer layer is in contact with an optical waveguide.
  • Figs. 1A, IB, 1C show scanning electron micrographs of a photodetector according to the present invention at varying magnifications.
  • Fig. 1C' schematically shows a top view and a cross-section comprising a unit cell of a photodetector according to the present invention.
  • Fig. 2 schematically shows a top view and a cross-section of a photodetector which is incorporated in a full device architecture.
  • Fig. 3 schematically shows a cross-section view of a photodetector according to the present invention connected to a measurement instrumentation and a voltage source.
  • Fig. 4 schematically illustrates an equivalent circuit of a photodetector according to the present invention.
  • Fig. 5 schematically shows a photodetector according to the present invention with an 2D material insulator.
  • Fig. 6 schematically shows a unit cell 2 of a photodetector 8 according to the present invention with additional resonators.
  • Fig. 7A, 7B schematically show a unit cells of a photodetector 8 according to the present invention with resonators having different geometries.
  • Fig. 8 schematically shows a cross-section of a photodetector according to the present invention with a frontside 2D material insulator.
  • Fig. 9 schematically shows a unit cell of a photodetector according to the present invention enabling simplified fabrication.
  • Fig. 10, Fig. 10A schematically show a photodetector according to the present invention which is in contact with an optical waveguide.
  • Figs. 1A, IB, 1C show scanning electron micrographs of a photodetector 8 according to the present invention at varying magnifications (50 micrometer, 5 micrometer, 1 micrometer scalebars).
  • Fig. 1A shows the photodetector 8 connected to a ground line 10, to a signal line 11 and to a gate line 12.
  • the photodetector 8 is included in a full device architecture.
  • Fig. IB shows a magnified view of an active area of the photodetector 8.
  • the active area is configured to receive an optical signal in direction into a plane of Fig. IB.
  • Fig. IB shows a resonator layer 1 from the top.
  • the resonator layer 1 includes contact lines la (which will be described in more detail below), which are connected in an alternating fashion to the ground line 10 and the signal line 11.
  • a plurality of unit cells 2 can be arranged.
  • the unit cells 2 have a quadratic form.
  • the resonator layer 1 includes resonators lb, lb2.
  • first and second contact lines lai, la2 are arranged, each contacting two resonators lbl, lb2.
  • a unit cell 2 has four resonators lbl, lb2 and a first and second contact line lai, la2, wherein the first contact line lai is connected to two resonators lbl and wherein the second contact line la2 is connected to two resonators lb2.
  • Fig. 1C' schematically shows a top view and a cross-section comprising a unit cell 2 of a photodetector 8 according to the present invention.
  • the photodetector 8 comprises a multilayer stack.
  • the multilayer stack of the photodetector 8 comprises an insulator spacer layer 4, which is in contact with a 2D material layer 3, which is in contact with a resonator layer 1.
  • a backside reflector 5 can be in contact with the insulator spacer layer
  • the backside reflector layer 5 can be in contact with a substrate 6.
  • the 2D material layer 3 and the resonator layer 1 can be in contact with a frontside insulator layer 7.
  • the resonator layer 1 includes resonators lbl, lb2.
  • the resonator layer 1 includes first and second contact lines lai, la2 for connecting the resonators lbl, lb2.
  • the contact lines lai, la2 can be connected in an alternating fashion to the ground line 10 and the signal line 11.
  • the resonators lbl, lb2 can relate to dipole resonators.
  • the first and second contact lines lai, la2 have an alternating configuration comprising different materials lcl, lc2, ld2, ld2.
  • the contact lines lai, la2 include a first contact layer ldl and a second contact layer ld2 which are in contact with the 2D material layer 3, and a first capping layer lcl and a second capping layer lc2 which are respectively in contact with the first contact layer ldl and the second contact layer ld2.
  • a photodetector 8 can be fabricated by deposing the backside reflector layer 5 on a substrate, by deposing the spacer layer 4 on the backside reflector layer
  • a photodetector 8 can relate to a modified metamaterial perfect absorber (MPA).
  • MPA modified metamaterial perfect absorber
  • the resonant layer 1 provides a resonant response to the impinging optical signal.
  • the spacer layer 4 and reflector layer 5 allow for impedance correction to minimize reflection of the overall layer stack.
  • the reflector layer 5 eliminates transmission.
  • the full stack of resonant layer 1, spacer layer 4 and reflector layer 5 thereby increases the absorption of the optical signal as both transmission and reflection are minimized.
  • the multilayer stack has a spectral resonant absorption enhancement, wherein a part of the absorption can occur in the 2D material layer 3.
  • the interconnected resonators lbl, lb2 and the 2D material form a conductive channel.
  • Fig. 2 schematically shows a top view and a cross-section of a photodetector 8 which is incorporated in a full device architecture.
  • the top view of Fig. 2 corresponds to Fig. 1A.
  • the photodetector 8 is connected on one side to the ground line 10, and on an opposite side to the signal line 11, which form coplanar waveguides 9.
  • the gate line 12 is in contact with the backside reflector layer 5.
  • the gate line 12 is arranged in a recess of the substrate 6.
  • the photodetector 8 is covered with a frontside insulator layer 7.
  • the ground line 10, the signal line 11 and the gate line 12 are accessible via recesses of the frontside insulator layer 7 respectively the backside reflector layer 5. Alternatively, access via a substrate 6 is possible.
  • the active gate line 12 strikes a plane 12a which is orthogonal to the contact lines la and strikes the contact between the active layer 1 and the signal line 11. As illustrated in Fig. 2, the gate line 12 does not extend in a horizontal direction the contact between the resonator layer 1 and the signal line 11. As illustrated in Fig. 2, there is no overlap between the gate line 12 and the signal line 11. Lower parasitic capacitances and higher operation speeds are enabled.
  • Fig. 3 schematically shows a cross-section view of a photodetector 8 according to the present invention.
  • first contact lines lai and second contact lines la2 are arranged in an alternating fashion.
  • An electrical measurement instrumentation 13 is connected between the first contact lines lai and the second contact lines la2.
  • a voltage source 14 is connected between the second contact lines la2 and the backside reflector layer 5, which is used as a third terminal and designated as "gate" in the present disclosure.
  • the gate enables optimizing the photo-response and the frequency bandwidth.
  • the thickness of the spacer layer 4 can be optimized for high absorption under the constraint of a low gate-voltage (e.g. less than 10V) operation.
  • the gate-voltage is set to maximize carrier velocity which minimizes carrier transit time and maximizes the frequency response.
  • the gate-voltage does not necessarily induce high doping to minimize recombination time.
  • the gate voltage can depend on a position of a Dirac point and the metals involved.
  • the gate voltage can depend on a thickness of the spacer layer 4 and the material of the spacer layer 4.
  • Fig. 4 schematically illustrates an equivalent circuit 15 of a photodetector 8 according to the present invention.
  • the equivalent circuit 15 includes a current source l_ph which is connected in parallel to a channel resistance R_2D of the 2D material layer 3.
  • the current source l_ph is serially connected to a contact resistance R_C of the contact between the 2D material layer 3 and the resonator layer 1, a structure resistance R_S of the resonator layer 1, in particular the contact lines la and the resonators lb, and a measurement instrumentation resistance RJoad.
  • the current source l_ph relates to the generated photocurrent.
  • the measurement instrumentation resistance RJoad relates to the electrical measurement instrumentation 13 (cf. Fig. 3).
  • a measured electrical current I Joad is received at the measurement instrumentation resistance RJoad and relates to an externally detected signal of the photodetector.
  • the photodetector 8 is configured according to a procedure to maximize the measured electrical current IJoad under illumination.
  • the current of the current source l_ph can be increased by optimizing internal and external quantum efficiencies (e.g., absorption, absorption distribution, carrier transit time, etc.) of the photodetector.
  • the resistance of the channel resistance R_2D of the 2D material layer 3 can be increased (e.g., by etching of the 2D material to increase its resistance, using a semiconducting material, etc.).
  • the resistance of the channel resistance R_2D can be increased for one current direction (e.g., forming a Schottky contact to enable a diode like behavior, etc.).
  • the resistance of the structure resistance R_S can be decreased by choosing conductors with higher conductivity, by selecting different structure geometries, etc.
  • the resistance of the contact resistance R_C can be decreased by changing the composition of the resonator layer 1 with lower contact resistance, patterning of the 2D material, etc.
  • FIG. 5 schematically shows a photodetector 8 according to the present invention.
  • a 2D material insulator 4a is arranged between the spacer layer 4 and the 2D material layer 3 for improving material characteristics of the 2D material layer 3.
  • Fig. 6 schematically shows a unit cell 2 of a photodetector 8 according to the present invention.
  • the resonator layer 1 includes first resonators lbl, lb2 connected to first and second contact lines lai, la2.
  • Second resonators lbbl, lbb2 are arranged in an orthogonal fashion with respect to the first resonators lbl, lb2.
  • the second resonators lbbl, lbb2 are connected to the contact lines lai, la2.
  • the second resonators lbbl, lbb2 are arranged perpendicularly to the first resonators lbl, lb2.
  • the second resonators lbbl, lbb2 are arranged alternatingly on different sides with respect to the contact lines lai, la2.
  • Perpendicularly oriented resonators lbl, lbbl, lb2, lbb2 enable polarization independent resonant enhancement of the absorption, where alternatingly contacting the second resonators lbbl, lbb2 enables more efficient carrier extraction.
  • Fig. 7A, 7B schematically show a unit cells 2 of a photodetector 8 according to the present invention.
  • Fig. 7A shows a unit cell 2 with first resonators lb and second resonators lbb connected to connection lines la.
  • Fig. 7B shows a unit cell 2 with first resonators lb, second resonators lbb and third resonators lbbb connected to connection lines la.
  • the first, second, third resonators lb, lbb, lbbb have different geometries for enabling a multiresonant enhancement of the spectral absorption and photocurrent generation, which can be used for detection of light over a broader spectral range or for selective detection of specific wavelength regions.
  • more than just 3 variations of resonators can be arranged in general.
  • Fig. 8 schematically shows a cross-section of a photodetector 8 according to the present invention.
  • a frontside 2D material insulator 7a is arranged between the frontside reflector layer and the 2D material layer 3.
  • the frontside 2D material insulator 7 is configured that the active 2D material layer 3 remains in contact with the resonator layer 1, but properties of the active 2D material layer 3 can be beneficially changed.
  • the growth of the encapsulation layer 7 can be promoted by the inclusion of the 2D material insulator 7a.
  • Fig. 9 schematically shows a unit cell 2 of a photodetector 8 according to the present invention.
  • the resonant layer 1 includes first and second contact lines lai, la2. At the first contact lines lai, resonators lbl are arranged. The second contact lines la2 are without resonators. All contact lines lai, la2 include a first contact layer ldl which is in contact with the 2D material layer, and first capping layer lcl arranged on the first contact layer ldl. Thus, the contact lines lai, la2 have the same structure. Fabrication requires one fabrication step less, and is therefore simplified.
  • Figs. 10, 10A schematically show a photodetector 8 which is in contact with an optical waveguide 16.
  • the photodetector 8 includes a spacer layer 4, a 2D material layer 3 and a resonator layer 1.
  • the resonator layer 1 is linear (e.g., has 6x1 unit cells 2).
  • the resonator layer 1 includes a first contact line lai which includes a first capping layer lcl, which is in contact with a first contact layer ldl, which is in contact with the 2D material layer 3.
  • the optical waveguide 16 is arranged on a substrate 2.
  • an optical waveguide cladding/planarization 18 is arranged.
  • an insulator layer 7 is in contact with the first capping layer lcl, the second capping layer ld2 and the 2D material layer 3.
  • a gate layer 12 is in contact with the insulator layer 7.
  • second contact lines la2 are arranged which include a second contact layer ld2 is in contact with the 2D material layer 3, and a second capping layer lc2 is in contact with the second contact layer.
  • the optical waveguide cladding/planarization 18 and the waveguide 16 are disposed on the substrate 6, the spacer layer 4 disposed on the optical waveguide cladding/planarization 18 and the waveguide 16, the 2D material layer 3 is disposed on the spacer layer 4, the first and second contact layer ldl, ld2 are disposed on the 2D material layer 3, the first and second capping layer lcl, lc2 are disposed on the first and second contact layer ldl, ld2, the insulator layer 7 is disposed on the 2D material 3 and the first contact layer ldl and the first capping layer lcl, and the gate layer 12 is disposed on the insulator layer 7.
  • the second contact layer ld2 and/or the second capping layer lc2 can be connected to a ground line, the contact line la of the resonator layer 1 can be connected to a signal line, and the gate layer 12 is in contact with a gate line.
  • the resonant layer 1 provides a resonant response to the impinging optical signal 17 which is guided by the optical waveguide 16.
  • the resonant layer 1 confines the optical field, induces absorption in the 2D material layer 3.
  • a signal line 11 can be in contact with the resonant layer 1.
  • Fig. 10 illustrates ground lines as end contacts left and right, but repeating elements of resonators 1 can be used as ground lines as presented in the photodetector 8.
  • the resonator layer 1 can include and is not limited to gold, silver, aluminum, copper, palladium, tungsten, platinum, titanium, chromium, nickel, etc.
  • the contact lines la, lai, la2 can include and is not limited to gold, silver, aluminum, copper, palladium, tungsten, platinum, titanium, chromium, nickel, etc.
  • the resonators lb, lbl, lb2, lbb, lbb2, lbb2, lbbb can include and is not limited to gold, silver, aluminum, copper, palladium, tungsten, platinum, titanium, chromium, nickel, etc.
  • the shape of these resonators may include but is not limited to dipole antenna, bow-tie antenna, leaf clover, patch antenna,... .
  • the first contact layer ldl and/or the second contact layer ld2 can include and is not limited to gold, silver, etc.
  • the first contact layer ldl and the second contact layer ld2 of different contact lines lai, la2 can include alternating materials.
  • the first capping layer lcl and/or the second capping layer lc2 can include and is not limited to gold, silver, etc.
  • the first contact layer ldl, the second contact layer ld2, the first capping layer lcl, and/or the second capping layer lc2 can enable n- and p-type contact doping.
  • a 2D material channel can be doped with a p-n profile.
  • the 2D material layer 3 with one or more layers of a 2D material could e.g. be realized by transition metal dichalcogenide (TMDCs), semiconducting or metallic dichalcogenides, perovskite-type and many other monolayered materials. Examples of which are e.g. PtSe2 platinum diselenide, PdSe2 palladium diselenide, MoTe2 molybdenum ditelluride, MoS2, WSe2, etc. Likewise it could be realized by any of the following materials such as monocrystalline graphene, multilayer graphene stack, rotationally stacked graphene, graphene nanoribbons. Further, it could be realized by a stacking a combination of all of the above forming so-called Van der Waals heterostructures, etc. For example, the 2D material layer 3 can absorb infrared light.
  • TMDCs transition metal dichalcogenide
  • semiconducting or metallic dichalcogenides perovskite-type and many other monolayered materials.
  • the spacer layer 4 can include and is not limited to aluminum oxide, hafnium oxide, silicon oxide, silicon nitride, titanium oxide, etc.
  • the 2D material insulator 4a can e.g. include but is not limited to hBN.
  • the frontside insulator layer 7 can include and is not limited to aluminum oxide, hafnium oxide, silicon oxide, silicon nitride, titanium oxide, etc.

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Abstract

A photodetector (8) comprises: a multilayer stack comprising a resonator layer (1) which is in contact with a 2D material layer (3) which is in contact with an insulator spacer layer (4), wherein the multilayer stack is configured to absorb an optical signal and to convert the absorbed optical signal into charge carriers and to enable electrically measuring the charge carriers, wherein the 2D material layer (3) includes one or more layers of a 2D material, wherein the resonator layer (1) comprises first and second contact lines (1a1, 1a2) which have an alternating configuration, wherein the first and second contact lines (1a1, 1a2) include different materials, wherein at least one of the first and second contact lines (1a, 1a2) has arranged resonators (1b, 1b1, 1b2, 1bb, 1bb1, 1bb2, 1bbb).

Description

A 2D MATERIAL-METAMATERIAL PHOTODETECTOR
FIELD OF THE INVENTION
The present invention relates to a 2D material-metamaterial photodetector. In particular, the present invention relates to an infrared 2D material-metamaterial photodetector operating at infrared wavelengths. In particular, the present invention relates to a high-speed 2D material-metamaterial photodetector.
BACKGROUND ART
Photodetectors convert a signal from an optical domain into an electrical domain. Requirements for photodetectors are that they must be cheap, be compact, have low power consumption, have a predefined conversion efficiency, operate in a predefined spectral broadband window and have a fast response. The majority of photodetectors absorb an optical signal of a specific wavelength range and convert the absorbed optical signal in part into charge carriers. The charge carriers can be detected by electrically measuring a change of a voltage or a current.
Infrared photodetectors operate at an infrared wavelength and are widely used in optical communication links, sensing applications, imaging, etc. Most implementations of infrared photodetectors rely on semiconductor devices. They operate by using a bandgap of an active material to absorb the optical signal, wherein a bias voltage is applied to the active material in order to extract charge carriers generated by the absorption of the optical signal. Typically, these devices rely on expensive crystalline materials that are difficult to manufacture and integrate.
Efficient and high-speed performance is determined by the semiconductor material. Further, they have a trade-off between active area size, saturation power and bandwidth.
2D materials refer to crystalline solids consisting of a single layer of atoms. 2D materials can include more than one layer of atoms, with in-plane interatomic forces higher than out of plane forces. Research towards 2D materials as active materials in infrared photodetectors is on-going. Typically, such photodetectors rely on photonic integrated circuits (waveguides) to increase the interaction length with the 2D materials and the absorption of photons. These approaches often have limited optical saturation powers, work within a relatively narrow spectral window and come at increased costs. Furthermore, highest operation bandwidths so far have been limited to around 100 GHz and they often required a bias voltage.
2D materials belong to the class of nanomaterials. Nanomaterials can be broadly classified by the total number of their nanoscopic dimensions. If all three dimensions of a material are nano-sized, it would be called a 0D (zero-dimensional) material, more commonly known as a nanoparticle. If two dimensions of a material are nanosized, with the other dimension much larger (much like a piece of string shrunk down to a tiny size), then this is a ID material or 'nanotube/nanowire'. If only one dimension is nano-sized, it would be a 2D material - resembling a large, but very thin sheet (like a piece of paper). Finally, if a material does not have any dimensions that are small enough to be considered nano-sized, then it is not a nanomaterial. Instead, it should be referred to as a 'bulk' material.
US20220307974A1 shows that a photodetector's poor active semiconductor medium quality can be compensated by co-integration into a metamaterial perfect absorber (MPA) structure. A resonator layer simultaneously acts as electrodes.
S. M. Koepfli et al., >500 GHz Bandwidth Graphene Photodetector Enabling Highest- Capacity Plasmonic-to-Plasmonic Links, 2022 European Conference on Optical Communication (ECOC), Basel, Switzerland, 2022, pp. 1-4 discloses a metamaterial enhanced graphene photodetector. Graphene is placed in a metamaterial perfect absorber (MPA). High-speed operation under near-infrared illumination is enabled by combining an interconnected resonator MPA with graphene. Alternating contact metals in the resonator layer enable zero-bias operation.
DISCLOSURE OF THE INVENTION
There may be a need for an improved 2D material-metamaterial photodetector. In particular, there may be a need for an improved 2D material-metamaterial photodetector with improved efficiency. In particular, there may be a need for an improved 2D material-metamaterial photodetector with improved noise characteristics. In particular, there may be a need for an improved 2D material- metamaterial photodetector with improved spectral adaptability. In particular, there may be a need for an improved 2D material-metamaterial photodetector with improved polarization sensitivity. In particular, there may be a need for an improved 2D material-metamaterial photodetector with improved fabricability.
Such a need may be met with the subject-matter of the independent claims. Advantageous embodiments are defined in the dependent claims.
Ideas underlying embodiments of the present invention may be interpreted as being based, inter alia, on the following observations and recognitions.
An aspect of the invention relates to a photodetector, comprising: a multilayer stack comprising a resonator layer which is in contact with a 2D material layer which is in contact with an insulator spacer layer, wherein the multilayer stack is configured to absorb an optical signal and to convert the absorbed optical signal into charge carriers and to enable electrically measuring the charge carriers, wherein the 2D material layer includes one or more layers of a 2D material, wherein the resonator layer comprises first and second contact lines which have an alternating configuration, wherein the first and second contact lines include different materials, wherein at least one of the first and second contact lines has arranged resonators. The photodetector enables various applications. High bandwidths are enabled.
In some embodiments, the different materials of the first and second contact lines are selected such that electrical contact properties and/or 2D material layer properties are influenced or improved. For example, alternating materials in the first and second contact lines can dope a 2D material channel with a p-n profile.
In some embodiments, the contact lines include a contact layer which is in contact with the 2D material layer and a capping layer which is in contact with the contact layer, wherein a material of the contact layer differs from a material of the capping layer.
In some embodiments, the first contact lines include a first contact layer which is in contact with the 2D material layer and a first capping layer which is in contact with the first contact layer, and the second contact lines include a second contact layer which is in contact with the 2D material layer and a second capping layer which is in contact with the second contact layer, wherein a material of the first contact layer differs from a material of the second contact layer and/or a material of the first capping layer differs from a material of the second capping layer.
In some embodiments, the 2D material includes one or more of a graphene in case of more than one layers of a 2D material, a semiconducting material, a Van Der Waals heterostructure material, and a semimetal material.
In some embodiments, the insulator spacer layer is in contact with a backside reflector layer. For example, a modified metamaterial perfect absorber is enabled.
In some embodiments, the photodetector is arranged in a device architecture comprising a ground line and a signal line which are in contact with the resonator layer, wherein the insulator spacer layer is in contact with a backside reflector layer, further comprising a gate line which is in contact with the backside reflector layer, wherein there is no overlap between the gate line and the signal line. High bandwidths are enabled.
In some embodiments, the insulator spacer layer is in contact with a backside reflector layer, wherein the resonator layer includes first contact lines and second contact lines having different materials and being arranged in an alternating fashion, wherein an electrical measurement instrumentation is connected between the first contact lines and the second contact lines, and wherein a voltage source is connected to the second contact lines and to the backside reflector layer, wherein the voltage of the voltage source is adjusted to maximize charge carrier velocity. High bandwidths are enabled. In some embodiments, the photodetector is configured according to a procedure to optimize a measured electrical current on the basis of an equivalent circuit of the photodetector.
In some embodiments, a 2D material insulator is arranged between the spacer layer and the 2D material layer.
In some embodiments, the resonator layer includes first resonators connected to contact lines, wherein second resonators are arranged in an orthogonal fashion with respect to the first resonators, wherein the second resonators are connected to the contact lines.
In some embodiments, the resonator have different geometries which are selected such that absorption in multiple bands is achieved. For example, the resonators can have different widths and/or a lengths to achieve absorption in multiple bands.
In some embodiments, a frontside 2D material insulator which is in contact with the 2D material layer in a configuration which enables that the 2D material layer remains in contact with the resonator layer.
In some embodiments, the resonator layer includes first contact lines connected to resonators, and wherein the resonator layer includes second contact lines without resonators.
In some embodiments, the spacer layer is in contact with an optical waveguide.
BRIEF DESCRIPTION OF THE DRAWINGS
In the following, advantageous embodiments of the invention will be described with reference to the enclosed drawings. However, neither the drawings nor the description shall be interpreted as limiting the invention.
Figs. 1A, IB, 1C show scanning electron micrographs of a photodetector according to the present invention at varying magnifications. Fig. 1C' schematically shows a top view and a cross-section comprising a unit cell of a photodetector according to the present invention.
Fig. 2 schematically shows a top view and a cross-section of a photodetector which is incorporated in a full device architecture.
Fig. 3 schematically shows a cross-section view of a photodetector according to the present invention connected to a measurement instrumentation and a voltage source.
Fig. 4 schematically illustrates an equivalent circuit of a photodetector according to the present invention.
Fig. 5 schematically shows a photodetector according to the present invention with an 2D material insulator.
Fig. 6 schematically shows a unit cell 2 of a photodetector 8 according to the present invention with additional resonators.
Fig. 7A, 7B schematically show a unit cells of a photodetector 8 according to the present invention with resonators having different geometries.
Fig. 8 schematically shows a cross-section of a photodetector according to the present invention with a frontside 2D material insulator.
Fig. 9 schematically shows a unit cell of a photodetector according to the present invention enabling simplified fabrication.
Fig. 10, Fig. 10A schematically show a photodetector according to the present invention which is in contact with an optical waveguide.
The figures are only schematic and not to scale. Same reference signs refer to same or similar features. MODE(S) FOR CARRYING OUT THE INVENTION
Figs. 1A, IB, 1C show scanning electron micrographs of a photodetector 8 according to the present invention at varying magnifications (50 micrometer, 5 micrometer, 1 micrometer scalebars).
Fig. 1A shows the photodetector 8 connected to a ground line 10, to a signal line 11 and to a gate line 12. Thus, the photodetector 8 is included in a full device architecture.
Fig. IB shows a magnified view of an active area of the photodetector 8. The active area is configured to receive an optical signal in direction into a plane of Fig. IB. Fig. IB shows a resonator layer 1 from the top. The resonator layer 1 includes contact lines la (which will be described in more detail below), which are connected in an alternating fashion to the ground line 10 and the signal line 11.
Fig. 1C shows a magnified view of a unit cell 2 of the photodetector 8. Figs. IB, 1C show that the photodetector 8 comprises an array of unit cells 2. Fig. 1C shows resonators lbl, lb2. Fig. 1C shows first and a second contact lines lai, la2 which are connected to the resonators lbl, lb2. The array of unit cells 2 can e.g. be quadratic, rectangular, hexagonal or linear. For example, 9x9 unit cells 2 can be arranged. For example, 12x9 or 9x12 unit cells 2 can be arranged. For example, 1x6 or 6x1 unit cells 2 can be arranged. For example, any number of unit cells 2 can be arranged.
Accordingly, a plurality of unit cells 2 can be arranged.
The unit cells 2 have a quadratic form. At the corners, the resonator layer 1 includes resonators lb, lb2. At two opposite sides, first and second contact lines lai, la2 are arranged, each contacting two resonators lbl, lb2. Accordingly, a unit cell 2 has four resonators lbl, lb2 and a first and second contact line lai, la2, wherein the first contact line lai is connected to two resonators lbl and wherein the second contact line la2 is connected to two resonators lb2.
Fig. 1C' schematically shows a top view and a cross-section comprising a unit cell 2 of a photodetector 8 according to the present invention. As schematically shown in the cross-section of Fig. 1C', the photodetector 8 comprises a multilayer stack. The multilayer stack of the photodetector 8 comprises an insulator spacer layer 4, which is in contact with a 2D material layer 3, which is in contact with a resonator layer 1.
Furthermore, a backside reflector 5 can be in contact with the insulator spacer layer
4.
Furthermore, the backside reflector layer 5 can be in contact with a substrate 6.
Furthermore, the 2D material layer 3 and the resonator layer 1 can be in contact with a frontside insulator layer 7.
As illustrated in the top view of Fig. 1C', the resonator layer 1 includes resonators lbl, lb2. The resonator layer 1 includes first and second contact lines lai, la2 for connecting the resonators lbl, lb2. As described earlier, the contact lines lai, la2 can be connected in an alternating fashion to the ground line 10 and the signal line 11. For example, the resonators lbl, lb2 can relate to dipole resonators.
As illustrated in the cross-section of Fig. 1C', the first and second contact lines lai, la2 have an alternating configuration comprising different materials lcl, lc2, ld2, ld2. In an alternating fashion, the contact lines lai, la2 include a first contact layer ldl and a second contact layer ld2 which are in contact with the 2D material layer 3, and a first capping layer lcl and a second capping layer lc2 which are respectively in contact with the first contact layer ldl and the second contact layer ld2.
For example, a photodetector 8 can be fabricated by deposing the backside reflector layer 5 on a substrate, by deposing the spacer layer 4 on the backside reflector layer
5, by deposing the 2D material layer 3 on the spacer layer 4, by deposing the resonator layer 1 on the 2D material layer 3, and by deposing frontside insulator layer 7 on the 2D material layer 3 and the resonator layer 1.
For example, a photodetector 8 can relate to a modified metamaterial perfect absorber (MPA). For example, the resonant layer 1 provides a resonant response to the impinging optical signal. The spacer layer 4 and reflector layer 5 allow for impedance correction to minimize reflection of the overall layer stack. The reflector layer 5 eliminates transmission. The full stack of resonant layer 1, spacer layer 4 and reflector layer 5 thereby increases the absorption of the optical signal as both transmission and reflection are minimized.
The multilayer stack has a spectral resonant absorption enhancement, wherein a part of the absorption can occur in the 2D material layer 3. The interconnected resonators lbl, lb2 and the 2D material form a conductive channel.
Fig. 2 schematically shows a top view and a cross-section of a photodetector 8 which is incorporated in a full device architecture. The top view of Fig. 2 corresponds to Fig. 1A. As illustrated in the top view of Fig. 2, the photodetector 8 is connected on one side to the ground line 10, and on an opposite side to the signal line 11, which form coplanar waveguides 9. As illustrated in Fig. 2, the gate line 12 is in contact with the backside reflector layer 5. For example, the gate line 12 is arranged in a recess of the substrate 6. The photodetector 8 is covered with a frontside insulator layer 7. The ground line 10, the signal line 11 and the gate line 12 are accessible via recesses of the frontside insulator layer 7 respectively the backside reflector layer 5. Alternatively, access via a substrate 6 is possible. The active gate line 12 strikes a plane 12a which is orthogonal to the contact lines la and strikes the contact between the active layer 1 and the signal line 11. As illustrated in Fig. 2, the gate line 12 does not extend in a horizontal direction the contact between the resonator layer 1 and the signal line 11. As illustrated in Fig. 2, there is no overlap between the gate line 12 and the signal line 11. Lower parasitic capacitances and higher operation speeds are enabled.
Fig. 3 schematically shows a cross-section view of a photodetector 8 according to the present invention. As described earlier and further illustrated in Fig. 3, first contact lines lai and second contact lines la2 are arranged in an alternating fashion. An electrical measurement instrumentation 13 is connected between the first contact lines lai and the second contact lines la2. A voltage source 14 is connected between the second contact lines la2 and the backside reflector layer 5, which is used as a third terminal and designated as "gate" in the present disclosure. The gate enables optimizing the photo-response and the frequency bandwidth. The thickness of the spacer layer 4 can be optimized for high absorption under the constraint of a low gate-voltage (e.g. less than 10V) operation. The gate-voltage is set to maximize carrier velocity which minimizes carrier transit time and maximizes the frequency response. The gate-voltage does not necessarily induce high doping to minimize recombination time. The gate voltage can depend on a position of a Dirac point and the metals involved. The gate voltage can depend on a thickness of the spacer layer 4 and the material of the spacer layer 4.
Fig. 4 schematically illustrates an equivalent circuit 15 of a photodetector 8 according to the present invention. The equivalent circuit 15 includes a current source l_ph which is connected in parallel to a channel resistance R_2D of the 2D material layer 3. The current source l_ph is serially connected to a contact resistance R_C of the contact between the 2D material layer 3 and the resonator layer 1, a structure resistance R_S of the resonator layer 1, in particular the contact lines la and the resonators lb, and a measurement instrumentation resistance RJoad. The current source l_ph relates to the generated photocurrent. The measurement instrumentation resistance RJoad relates to the electrical measurement instrumentation 13 (cf. Fig. 3). A measured electrical current I Joad is received at the measurement instrumentation resistance RJoad and relates to an externally detected signal of the photodetector.
According to the present invention, on the basis of the equivalent circuit 15, the photodetector 8 is configured according to a procedure to maximize the measured electrical current IJoad under illumination.
The resistance R_PD of the photodiode 8 is the sum: R_PD = R_2D + RC + R_S. Accordingly, the measured electrical current IJoad amounts to IJoad = IJoad * R_2D/(R_PD + RJoad). For example, the current of the current source l_ph can be increased by optimizing internal and external quantum efficiencies (e.g., absorption, absorption distribution, carrier transit time, etc.) of the photodetector.
For example, the resistance of the channel resistance R_2D of the 2D material layer 3 can be increased (e.g., by etching of the 2D material to increase its resistance, using a semiconducting material, etc.).
For example, the resistance of the channel resistance R_2D can be increased for one current direction (e.g., forming a Schottky contact to enable a diode like behavior, etc.).
For example, the resistance of the structure resistance R_S can be decreased by choosing conductors with higher conductivity, by selecting different structure geometries, etc.
For example, the resistance of the contact resistance R_C can be decreased by changing the composition of the resonator layer 1 with lower contact resistance, patterning of the 2D material, etc.
Fig. 5 schematically shows a photodetector 8 according to the present invention. A 2D material insulator 4a is arranged between the spacer layer 4 and the 2D material layer 3 for improving material characteristics of the 2D material layer 3.
Fig. 6 schematically shows a unit cell 2 of a photodetector 8 according to the present invention. The resonator layer 1 includes first resonators lbl, lb2 connected to first and second contact lines lai, la2. Second resonators lbbl, lbb2 are arranged in an orthogonal fashion with respect to the first resonators lbl, lb2. The second resonators lbbl, lbb2 are connected to the contact lines lai, la2. Thus, the second resonators lbbl, lbb2 are arranged perpendicularly to the first resonators lbl, lb2. In direction of the contact lines lai, la2, the second resonators lbbl, lbb2 are arranged alternatingly on different sides with respect to the contact lines lai, la2. Perpendicularly oriented resonators lbl, lbbl, lb2, lbb2 enable polarization independent resonant enhancement of the absorption, where alternatingly contacting the second resonators lbbl, lbb2 enables more efficient carrier extraction.
Fig. 7A, 7B schematically show a unit cells 2 of a photodetector 8 according to the present invention. Fig. 7A shows a unit cell 2 with first resonators lb and second resonators lbb connected to connection lines la. Fig. 7B shows a unit cell 2 with first resonators lb, second resonators lbb and third resonators lbbb connected to connection lines la. The first, second, third resonators lb, lbb, lbbb have different geometries for enabling a multiresonant enhancement of the spectral absorption and photocurrent generation, which can be used for detection of light over a broader spectral range or for selective detection of specific wavelength regions. Of course, more than just 3 variations of resonators can be arranged in general.
Fig. 8 schematically shows a cross-section of a photodetector 8 according to the present invention. A frontside 2D material insulator 7a is arranged between the frontside reflector layer and the 2D material layer 3. The frontside 2D material insulator 7 is configured that the active 2D material layer 3 remains in contact with the resonator layer 1, but properties of the active 2D material layer 3 can be beneficially changed. In addition, the growth of the encapsulation layer 7 can be promoted by the inclusion of the 2D material insulator 7a.
Fig. 9 schematically shows a unit cell 2 of a photodetector 8 according to the present invention. The resonant layer 1 includes first and second contact lines lai, la2. At the first contact lines lai, resonators lbl are arranged. The second contact lines la2 are without resonators. All contact lines lai, la2 include a first contact layer ldl which is in contact with the 2D material layer, and first capping layer lcl arranged on the first contact layer ldl. Thus, the contact lines lai, la2 have the same structure. Fabrication requires one fabrication step less, and is therefore simplified.
Figs. 10, 10A schematically show a photodetector 8 which is in contact with an optical waveguide 16. The photodetector 8 includes a spacer layer 4, a 2D material layer 3 and a resonator layer 1. The resonator layer 1 is linear (e.g., has 6x1 unit cells 2). The resonator layer 1 includes a first contact line lai which includes a first capping layer lcl, which is in contact with a first contact layer ldl, which is in contact with the 2D material layer 3. For example, the optical waveguide 16 is arranged on a substrate 2. For example, an optical waveguide cladding/planarization 18 is arranged. For example, an insulator layer 7 is in contact with the first capping layer lcl, the second capping layer ld2 and the 2D material layer 3. For example, a gate layer 12 is in contact with the insulator layer 7. At sides of the insulator layer 7, second contact lines la2 are arranged which include a second contact layer ld2 is in contact with the 2D material layer 3, and a second capping layer lc2 is in contact with the second contact layer. For example, the optical waveguide cladding/planarization 18 and the waveguide 16 are disposed on the substrate 6, the spacer layer 4 disposed on the optical waveguide cladding/planarization 18 and the waveguide 16, the 2D material layer 3 is disposed on the spacer layer 4, the first and second contact layer ldl, ld2 are disposed on the 2D material layer 3, the first and second capping layer lcl, lc2 are disposed on the first and second contact layer ldl, ld2, the insulator layer 7 is disposed on the 2D material 3 and the first contact layer ldl and the first capping layer lcl, and the gate layer 12 is disposed on the insulator layer 7. For operating the photodetector 8, the second contact layer ld2 and/or the second capping layer lc2 can be connected to a ground line, the contact line la of the resonator layer 1 can be connected to a signal line, and the gate layer 12 is in contact with a gate line.
For example, the resonant layer 1 provides a resonant response to the impinging optical signal 17 which is guided by the optical waveguide 16. The resonant layer 1 confines the optical field, induces absorption in the 2D material layer 3. A signal line 11 can be in contact with the resonant layer 1. Fig. 10 illustrates ground lines as end contacts left and right, but repeating elements of resonators 1 can be used as ground lines as presented in the photodetector 8.
The resonator layer 1 can include and is not limited to gold, silver, aluminum, copper, palladium, tungsten, platinum, titanium, chromium, nickel, etc.
The contact lines la, lai, la2 can include and is not limited to gold, silver, aluminum, copper, palladium, tungsten, platinum, titanium, chromium, nickel, etc. The resonators lb, lbl, lb2, lbb, lbb2, lbb2, lbbb can include and is not limited to gold, silver, aluminum, copper, palladium, tungsten, platinum, titanium, chromium, nickel, etc. The shape of these resonators may include but is not limited to dipole antenna, bow-tie antenna, leaf clover, patch antenna,... .
The first contact layer ldl and/or the second contact layer ld2 can include and is not limited to gold, silver, etc. The first contact layer ldl and the second contact layer ld2 of different contact lines lai, la2 can include alternating materials.
The first capping layer lcl and/or the second capping layer lc2 can include and is not limited to gold, silver, etc.
The first contact layer ldl, the second contact layer ld2, the first capping layer lcl, and/or the second capping layer lc2 can enable n- and p-type contact doping. For example, by alternating the materials of the first and second contact layer ldl, ld2 (e.g. Au and Ag), a 2D material channel can be doped with a p-n profile.
The 2D material layer 3 with one or more layers of a 2D material could e.g. be realized by transition metal dichalcogenide (TMDCs), semiconducting or metallic dichalcogenides, perovskite-type and many other monolayered materials. Examples of which are e.g. PtSe2 platinum diselenide, PdSe2 palladium diselenide, MoTe2 molybdenum ditelluride, MoS2, WSe2, etc. Likewise it could be realized by any of the following materials such as monocrystalline graphene, multilayer graphene stack, rotationally stacked graphene, graphene nanoribbons. Further, it could be realized by a stacking a combination of all of the above forming so-called Van der Waals heterostructures, etc. For example, the 2D material layer 3 can absorb infrared light.
The spacer layer 4 can include and is not limited to aluminum oxide, hafnium oxide, silicon oxide, silicon nitride, titanium oxide, etc.
The 2D material insulator 4a can e.g. include but is not limited to hBN.
The frontside insulator layer 7 can include and is not limited to aluminum oxide, hafnium oxide, silicon oxide, silicon nitride, titanium oxide, etc. Finally, it should be noted that the term "comprising" does not exclude other elements or steps and the "a" or "an" does not exclude a plurality. Also elements described in association with different embodiments may be combined. It should also be noted that reference signs in the claims should not be construed as limiting the scope of the claims.
LIST OF REFERENCE SIGNS
1 resonator layer lai first contact lines la2 second contact lines lb, lbl, lb2, lbb, lbbl, lbb2, lbbb resonators lcl first capping layer lc2 second capping layer ldl first contact layer ld2 second contact layer
2 unit cell
3 2D material layer 4 spacer layer
4a 2D material insulator layer 5 backside reflector layer
6 substrate 7 frontside insulator layer
7a frontside 2D material insulator 8 photodetector
9 coplanar waveguides 10 ground lines
11 signal line 12 gate line
12a end of gate line
13 electrical measurement instrur
Figure imgf000018_0001
itation 14 voltage source
15 equivalent circuit of photodetecto r l_ph current source
R 2D channel resistance R C contact resistance
R S structure resistance I load measured electrical current
RJoad measurement instrumentation resistance
16 optical waveguide 17 optical signal
18 optical waveguide cladding/planarization

Claims

1. A photodetector (8), comprising: a multilayer stack comprising a resonator layer (1) which is in contact with a 2D material layer (3) which is in contact with an insulator spacer layer (4), wherein the multilayer stack is configured to absorb an optical signal and to convert the absorbed optical signal into charge carriers and to enable electrically measuring the charge carriers, wherein the 2D material layer (3) includes one or more layers of a 2D material, wherein the resonator layer (1) comprises first and second contact lines (lai, la2) which have an alternating configuration, wherein the first and second contact lines (lai, la2) include different materials, wherein at least one of the first and second contact lines (la,l, la2) has arranged resonators (lb, lbl, lb2, lbb, lbbl, lbb2, lbbb).
2. The photodetector (8) according to claim 1, wherein the different materials of the first and second contact lines (lai, la2) are selected such that electrical contact properties and/or 2D material layer properties are influenced or improved.
3. The photodetector (8) according to claim 1 or 2, wherein the contact lines (la, la2) include a contact layer (ldl, ld2) which is in contact with the 2D material layer (3) and a capping layer (lcl, lc2) which is in contact with the contact layer (ldl, ld2), wherein a material of the contact layer (ldl, ld2) differs from a material of the capping layer (lcl, lc2).
4. The photodetector (8) according to one of claims 1 to 3, wherein the first contact lines (lai) include a first contact layer (ldl) which is in contact with the 2D material layer (3) and a first capping layer (lcl) which is in contact with the first contact layer (ldl), and the second contact lines (la2) include a second contact layer (ld2) which is in contact with the 2D material layer (3) and a second capping layer (lc2) which is in contact with the second contact Iayer(ld2), wherein a material of the first contact layer (ldl) differs from a material of the second contact layer (ld2) and/or a material of the first capping layer (lcl) differs from a material of the second capping layer (lc2).
5. The photodetector (8) according to one of claims 1 to 4, wherein the 2D material includes one or more of a graphene in case of more than one layers of a 2D material, a semiconducting material, a Van Der Waals heterostructure material, and a semimetal material.
6. The photodetector (8) according to one of claims 1 to 5, wherein the insulator spacer layer (4) is in contact with a backside reflector layer (5).
7. The photodetector (8) according to one of claims 1 to 6 arranged in a device architecture comprising a ground line (10) and a signal line (11) which are in contact with the resonator layer (1), wherein the insulator spacer layer (4) is in contact with a backside reflector layer (5), further comprising a gate line (12) which is in contact with the backside reflector layer (5), wherein there is no overlap between the gate line (12) and the signal line (11).
8. The photodetector (8) according to one of claims 1 to 7, wherein the insulator spacer layer (4) is in contact with a backside reflector layer (5), wherein an electrical measurement instrumentation (13) is connected between the first contact lines (lai) and the second contact lines (la2), and wherein a voltage source (14) is connected to the second contact lines (lai) and to the backside reflector layer (5), wherein the voltage of the voltage source (14) is adjusted to maximize charge carrier velocity .
9. The photodetector (8) according to one of claims 1 to 8, configured according to a procedure to maximize a measured electrical current (IJoad) on the basis of an equivalent circuit (15) of the photodetector (8) under illumination.
10. The photodetector (8) according to one of claims 1 to 9, wherein a 2D material insulator (4a) is arranged between the spacer layer (4) and the 2D material layer (3).
11. The photodetector (8) according to one of claims 1 to 10, wherein the resonator layer (1) includes first resonators (lbl, lb2) connected to the contact lines (lai, la2), wherein second resonators (lbbl, lbb2) are arranged in an orthogonal fashion with respect to the first resonators (lbl, lb2), wherein the second resonators (lbbl, lbb2) are connected to the contact lines (lai, la2).
12. The photodetector (8) according to one of claims 1 to 11, wherein the resonators (lb, lbb, lbbb) have different geometries which are selected such that absorption in multiple bands is achieved.
13. The photodetector (8) according to one of claims 1 to 12, wherein a frontside 2D material insulator (7a) which is in contact with the 2D material layer (2) in a configuration which enables that the 2D material layer (3) remains in contact with the resonator layer (1).
14. The photodetector (8) according to one of claims 1 to 13, wherein the resonator layer (1) includes first contact lines (lai) connected to resonators (lbl), and wherein the resonator layer (1) includes second contact lines (la2) without resonators.
15. The photodetector (8) according to one of claims 1 to 14, wherein the spacer layer (4) is in contact with an optical waveguide (16).
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN120882114A (en) * 2025-09-26 2025-10-31 浙大城市学院 Mo Erchao lattice-based room temperature broad spectrum infrared detector

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160351732A1 (en) * 2014-01-07 2016-12-01 Universite Paris Diderot Paris 7 Semiconductor photodetector
US20220307974A1 (en) 2019-07-01 2022-09-29 Sensirion Ag Meta-surface photodetector

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160351732A1 (en) * 2014-01-07 2016-12-01 Universite Paris Diderot Paris 7 Semiconductor photodetector
US20220307974A1 (en) 2019-07-01 2022-09-29 Sensirion Ag Meta-surface photodetector

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
GAO YUN ET AL: "Graphene-on-silicon nitride waveguide photodetector with interdigital contacts", APPLIED PHYSICS LETTERS, AMERICAN INSTITUTE OF PHYSICS, 2 HUNTINGTON QUADRANGLE, MELVILLE, NY 11747, vol. 112, no. 21, 25 May 2018 (2018-05-25), XP012228777, ISSN: 0003-6951, [retrieved on 20180525], DOI: 10.1063/1.5026303 *
KOEPFLI STEFAN M ET AL: ">500 GHz Bandwidth Graphene Photodetector Enabling Highest-Capacity Plasmonic-to-Plasmonic Links", 2022 EUROPEAN CONFERENCE ON OPTICAL COMMUNICATION (ECOC), OPTICA, 18 September 2022 (2022-09-18), pages 1 - 4, XP034252021 *
NIKOLAUS FL\"ORY ET AL: "Waveguide-integrated van der Waals heterostructure photodetector at telecom band with high speed and high responsivity", ARXIV.ORG, CORNELL UNIVERSITY LIBRARY, 201 OLIN LIBRARY CORNELL UNIVERSITY ITHACA, NY 14853, 23 April 2019 (2019-04-23), XP081172618 *
S. M. KOEPFLI ET AL.: "500 GHz Bandwidth Graphene Photodetector Enabling Highest-Capacity Plasmonic-to-Plasmonic Links", 2022 EUROPEAN CONFERENCE ON OPTICAL COMMUNICATION (ECOC, 2022, pages 1 - 4, XP034252021
SHICHAO SONG ET AL: "Great light absorption enhancement in a graphene photodetector integrated with a metamaterial perfect absorber", NANOSCALE, vol. 5, no. 20, 21 August 2013 (2013-08-21), United Kingdom, pages 9615 - 9619, XP055659963, ISSN: 2040-3364, DOI: 10.1039/c3nr03505k *
STEPHANE BOUBANGA-TOMBET ET AL: "Plasmonic instabilities and terahertz waves amplification in graphene metamaterials", ARXIV.ORG, CORNELL UNIVERSITY LIBRARY, 201 OLIN LIBRARY CORNELL UNIVERSITY ITHACA, NY 14853, 14 January 2018 (2018-01-14), XP081206427 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN120882114A (en) * 2025-09-26 2025-10-31 浙大城市学院 Mo Erchao lattice-based room temperature broad spectrum infrared detector

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