WO2024251840A1

WO2024251840A1 - Tab shape for a battery electrode

Info

Publication number: WO2024251840A1
Application number: PCT/EP2024/065509
Authority: WO
Inventors: Hangjune Choi; Masato Origuchi; Stéphane AUTRET
Original assignee: Automotive Cells Company SE
Current assignee: Automotive Cells Company SE
Priority date: 2023-06-07
Filing date: 2024-06-05
Publication date: 2024-12-12
Anticipated expiration: 2025-12-07
Also published as: EP4475262A1; DE212024000348U1

Abstract

The present invention relates to a battery cell comprising several electrodes (10, 15), each electrode (10) comprising a foil with a plane surface and a flexible tab (20) which projects beyond a longitudinal edge (11) of the foil along a vertical direction (X) perpendicular to a longitudinal direction (Y) The flexible tab (20) comprises two parts, a first part (28) starting from the longitudinal edge (11) of the foil extended by an adjacent second part (29), said first part (28) having a rectangular shape with two longitudinal sides (22, 22') of the same size and said second part (29) having a trapezoidal shape with two longitudinal sides (24, 24') of different sizes.

Description

TAB SHAPE FOR A BATTERY ELECTRODE

TECHNICAL FIELD OF THE INVENTION

[0001] The present invention concerns the technical field of electric batteries, in particular lithium-ion batteries which are used, among others, to power the traction chain of electric or hybrid vehicles.

[0002] More specifically, the invention relates to innovative electrode shapes which improve the manufacturability and the quality of a battery cell.

BACKGROUND

[0003] Some Lithium-ion batteries comprise several battery cells, each battery cell having an electrode stack architecture comprising of a plurality of anodes (negative electrodes) and cathodes (positive electrodes), which are composed of foil and active material coating layers, stacked against each other and separated by a separation sheet (also known as a separator). Each cathode foil (also known as a current collector and made for instance with aluminium) is covered with a cathode active material coating layer and each anode foil is covered with an anode active material coating layer.

[0004] The electrodes (i.e. cathodes and anodes) are each extended with a connecting tab consisting of a small outgrowth of foil beyond the foil plan. These tabs are flexible and are used to electrically connect all the cathodes together (and all the anodes together respectively) to external terminals of the battery to transmit the electrical energy. These tabs are usually in a small rectangle geometry with rounded corners and they extend from the longitudinal straight edge of the electrodes. All the cathode tabs are positioned at a same precise position along the longitudinal edge of the cathode. Likewise, all the anode tabs are positioned at a precise position along the longitudinal edge of the anode.

[0005] During the manufacturing process of the battery cells, the electrodes are manufactured from long metallic strips which, after different operations, are cut to obtain each electrode sheet. During these operations, the electrode strip moves through numerous guide rolls which pass along the strip. Due to their flexibility, the tabs are often bent or tilted when passing under these guide rolls. But, when the tabs have a rectangular shape, the tabs' edges/corners have multiple chances of collision with the surface of the guide rolls with a high probability of getting "folded", instead of being merely bent during these collisions. Thus, this causes a "folded tab defect" which is a fatal failure that of course lowers the productivity of the manufacturing process. This "folding" can also occur with rectangle tabs having smaller rounded corners.

[0006] Document EP4123820A1 already discloses that electrode tabs can have a trapezoidal shape instead of a rectangular shape. However, for quality control issues, it is also necessary to quickly and precisely measure the longitudinal position of the tabs along the longitudinal edge of the electrodes following their assembly in an electrode stack. Such measurements are important for checking the correct positioning of all the electrodes in the stack, but they can be difficult to obtain when the electrode tabs have a trapezoidal shape.

[0007] Therefore, one purpose of the present invention is to provide an effective, reliable, economical and easy to implement solution that enhances manufacturability and productivity, while maintaining an efficient quality control of battery electrodes.

DISCLOSURE OF THE INVENTION

[0008] In order to achieve the above purpose, the invention provides an electrode sheet for a battery cell, comprising a foil with a plane surface and a flexible tab which projects beyond a longitudinal edge of the foil along a transversal direction perpendicular to a longitudinal direction. That said flexible tab comprises two parts, a first part starting from the longitudinal edge of the foil extended by an adjacent second part, said first part having a rectangular shape with two longitudinal sides of the same size and said second part having a trapezoidal shape with two longitudinal sides of different sizes.

[0009] According to one embodiment, the second part of the tab comprises an inner longitudinal side adjacent to the first part of the tab and an outer longitudinal side, the outer side being smaller than the inner side. [0010] According to one embodiment, the first part of the tab comprises two lateral sides which are perpendicular to the longitudinal edge of the electrode foil.

[0011] According to one embodiment, the second part of the tab comprises two lateral sides, both of them being not perpendicular to the longitudinal edge of the foil.

[0012] According to one embodiment, the second part of the tab comprises two lateral sides, one side being perpendicular to the longitudinal edge of the foil and the other side being not perpendicular to the longitudinal edge of the foil.

[0013] According to one embodiment, the second part of the tab comprises two outer rounded corners.

[0014] According to one embodiment, the lateral sides of the second part of the tab meets smoothly with their corresponding lateral sides of the first part of the tab with a filleting radius which is tangential to the lateral sides of the first part and to the lateral sides of the second part.

[0015] According to one embodiment, the second part of the tab comprises two lateral sides each having two successive rounded parts, a first rounded part having a first radius extended by a second rounded part having a second radius, the first radius being greater than the second radius.

[0016] The invention also provides a battery cell comprising a plurality of such electrode sheets.

BRIEF DESCRIPTION OF FIGURES

[0017] Further features and advantages of the present invention will become apparent from the following description, with reference to the annexed figures, wherein:

- Figure 1 shows a simplified existing implementation embodiment of an electrode stack;

- Figure 2 represents a schematic perspective view of an electrode strip during the manufacturing process, with an electrode tab according to the prior art; - Figures 3a, 3b, 3c and 3d give different examples of shapes for an electrode tab,

Figure 3a showing an example according to the prior art, Figures 3b, 3c and 3d showing three embodiments according to the present invention;

- Figure 4 details the position of a cathode tab according to the invention;

- Figure 5 repeats the view of Figure 2 but with an electrode tab according to the invention.

DETAILED DESCRIPTION OF AN EMBODIMENT

[0018] With reference to Figure 1, a lithium-ion battery cell comprises at least one cathode 10 in the form of a sheet, made of aluminium foil for example, coated on both sides by a cathode active material coating layer. The battery cell also comprises at least one anode 15 in the form of a sheet, made of copper foil for example, coated on both sides by an anode active material coating layer. The anode 15 and cathode 10 are placed against each other and are separated by a separator 14 which can be, for instance, a thin and porous plastic film. The anode 15 and cathode 10 are flat and have a roughly rectangular plane.

[0019] An electrode stack of a battery cell is usually composed of a stack of such electrode sheets and thus comprises a plurality of cathodes 10 and anodes 15 which are alternately arranged and separated by a plurality of separators 14. In Figure 1, only one cathode 10 one anode 15 and one separator 14 are shown.

[0020] The cathode 10 has a longitudinal edge 11 along a longitudinal direction Y and comprises a flexible tab 20 which projects beyond the longitudinal edge 11 along a transversal direction X, which is parallel to the cathode foil plan and perpendicular to the longitudinal direction Y. This cathode tab 20 is only present on one section of the longitudinal edge 11 of the cathode 10 and is, for instance, 30-50 mm wide and around 20- 30 mm high.

[0021] Similarly, the anode 15 has a longitudinal edge 16 along the longitudinal direction Y and comprises a flexible tab 30, which projects beyond the longitudinal edge 16 along the transversal direction X. This anode tab 30 is only present on one section of the longitudinal edge 16 of the anode 15 and has approximately the same dimensions as the cathode tab 20.

[0022] The anode tab 30 is offset from the cathode tab 20 along the direction Y to avoid any contact between them in the electrode stack of the battery cell, when tabs are tilted for instance. These tabs 20 (and 30 respectively) are used to electrically connect together the electrodes 10 (and 15 respectively) to external terminals of the battery in order to transmit the electrical energy the battery cell. To facilitate these connections, the tabs 20 and 30 must be flexible.

[0023] The electrodes (anodes 15 and cathodes 10) are generally manufactured starting from long electrode strips 13 having flexible tabs arranged at regular intervals. This electrode strip 13 undergoes different manufacturing operations, prior to being cut along the transversal direction X to obtain several electrodes of the correct dimensions. As shown in Figure 2, during these operations the electrode strip 13 moves along the direction Y through a path comprising many tens of guide rolls 17 which are in a rotating movement 18 according to an axis Z, parallel to the transversal direction X and perpendicular to the longitudinal direction Y.

[0024] When tab 20 has a rectangular shape, even with rounded corners, there is a risk that, at a contact point 19 between the tab 20 and the guide roll 17, the tab 20 is not just tilted but can be folded backwards during the movement of strip 13. This causes a major defect and of course reduces the productivity of the manufacturing process.

[0025] According to the present invention, a trapezoidal geometry of the tab 20 can significantly lower the probability of the tab being folded backwards during contact between the tab 20 edge/corner and the guide roll 17 surface. Such trapezoidal geometry provides higher folding resistance compared with a rectangle geometry, even with a same level of collision impact between the tab 20 and the guide roll 17. The inclined side of the trapezoid facilitates the smooth guiding of the tab 20 by enabling gradual contact between the tab edge and the guide roll 17 surface. [0026] Furthermore, once the cathodes 10 (and respectively the anodes 15) are placed in an electrode stack, the cathode tabs 20 (and respectively the anode tabs 30) must be well aligned with each other, prior to getting assembled and welded for electrical connection of the battery cell. To verify this alignment, as shown in the example of Figure 4 for a cathode 10, the battery control quality process needs to precisely measure the position of each cathode tab 20 along the longitudinal edge 11 of the cathode 10. That is to say, measuring the distance D between a lateral side 21 of the cathode tab 20 and a transversal side 12 of the cathode 10. Said transversal side 12 of the cathode 10 is parallel to the transversal direction X and perpendicular to the longitudinal edge 11 of the cathode 10. For instance, an optical measurement system is often applied to inspect this distance D. On identifying several points on the edges 11, 20, and 21, some coordinate transformation calculations follow to get the distance D in precision at a very high speed. The distance D is, for instance, about 60 mm for the cathode tab 20.

[0027] However, if the lateral side 21 of the cathode tab 20 is not parallel to the transversal side 12 of the cathode 10, meaning that the angle between the longitudinal edge 11 and the lateral side 21 is not a right angle, then an accurate and reliable measure of the distance D will be very difficult to obtain. Distance D can vary depending, for instance, on the vertical position of the cathode 10, especially with rounded corners at the intersection between the cathode 10 and the cathode tab 20. A trapezoidal shape of the cathode tab 20, instead of a rectangular shape, would surely induce problems in measuring the distance D, and thus make the battery control quality less reliable.

[0028] Therefore, the present invention proposes a new shape for electrodes tabs which will achieve the two objectives of improving the manufacturability and productivity while maintaining a high-quality control.

[0029] The four Figures 3a, 3b, 3c and 3d show different examples of shapes for electrode tabs. Figure 3a shows an existing tab 20 having a classical rectangular shape. It comprises two straight parallel lateral sides 21, 21', which are parallel to the transversal direction X and perpendicular to the longitudinal edge 11 of the tab 20, and one longitudinal side 24, parallel to the longitudinal edge 11. The rounded corners 25 between lateral sides 21, 21' and the longitudinal side 24 are rounded with a radius for instance equal to 2 mm or even 0 mm for an easier manufacturing process, which may cause higher possibility of the "folded tab defect".

[0030] Figure 3b discloses a first embodiment of the invention. The flexible tab 20 comprises two parts, a first part 28 starting from the longitudinal edge 11 of the electrode 10 extended by an adjacent second part 29. The first part 28 has a rectangular shape with two lateral sides 21, 21' parallel to the transversal direction X and perpendicular to the longitudinal edge 11, between two longitudinal sides 22, 22' parallel to the longitudinal edge 11. These longitudinal sides 22, 22' have the same size (not taking into account the rounded corners). The two lateral sides 21, 21' of the rectangle shape part 28 have for instance a length of 5 mm.

[0031] The second part 29 of the tab 20 has a trapezoidal shape with two lateral sides 23, 23' which are inclined from the transversal direction X and not perpendicular to the longitudinal edge 11, between two longitudinal sides 24, 24', an inner longitudinal side 24' adjacent to the first part 28 of the tab 20 and an outer longitudinal side 24, which are parallel to the longitudinal edge 11. The two longitudinal sides 24, 24' have different sizes : the outer longitudinal side 24 of the tab 20 is smaller than the inner longitudinal side 24'. The sides 22' and 24' are merged. As the lateral sides 23, 23' are inclined, they come more softly into contact with a guide roll 17 during the movement of the strip 13, avoiding any backwards folding of the tab 20. Moreover, the outer round corners 25, between each lateral side 23, 23' and the outer longitudinal side 24, have a radius for instance equal to 10 mm, which is larger than the radius of the round corner 25 of Figure 3a. These outer round corners 25 also help the whole tab 20 enter into contact with a guided roll 17 more smoothly at contact point 19.

[0032] Preferably, the lateral side 23 (respectively 23') of the second part 29 of the tab 20 meets smoothly with its corresponding lateral side 21 (respectively 21') of the first part 28 of the tab 20, with a round corner between the lateral side 23 (respectively 23') of the second part 29 and its corresponding lateral side 21 (respectively 21') of the first part 28. [0033] Figure 3c discloses a second embodiment of the invention. In this embodiment, the flexible tab 20 also comprises two parts, a first part 28 starting from the longitudinal edge 11 of the electrode 10 extended by an adjacent second part 29. The first part 28 has a rectangular shape and is similar to the one described above in Figure 3b. The second part 29 is different from the one of Figure 3b. The second part 29 still has a trapezoidal shape with two lateral sides 23, 23', between two longitudinal sides 24, 24' parallel to the longitudinal edge 11, having different sizes. However, only one lateral side 23 is inclined and not perpendicular to the longitudinal edge 11, while the other lateral side 23' is perpendicular to the longitudinal edge 11, and thus parallel to the lateral side 21'. The outer longitudinal side 24 of the tab 20 is smaller than the inner longitudinal side 24'. Similar to Figure 3b, the sides 22' and 24' are merged. The outer round corner 25, between the inclined lateral side 23 and the outer longitudinal side 24, has a radius for instance equal to 10 mm.

[0034] The second embodiment of Figure 3c is suitable if, during the electrode manufacturing process, the strip 13 always moves in the same longitudinal direction Y and always comes in contact with a guide roll 17 on the same side 23 of all the tabs 20 of the strip 13. In this case, the other lateral side 23' of the second part 29 of any tab 20 does not need to be inclined from the transversal direction X.

[0035] A third embodiment of the invention is shown in Figure 3d. In this preferred embodiment, the tab 20 still comprises a rectangular first part 28 extended by an adjacent trapezoidal second part 29. The second part 29 is trapezoidal because it still comprises an inner longitudinal side 24' which is parallel to and greater than an outer longitudinal side 24. However, the two lateral sides 23, 23' of the second part 29 are not straight, but each lateral side 23 (respectively 23') is tilted and comprises two successive rounded parts, namely a first rounded part having a first radius Ra extended by a second rounded part having a second radius Rb. The first radius Ra is greater than the second radius Rb. The first rounded part is linked to the lateral side 21 (respectively 21') of the rectangular part 28 and the second rounded part is linked to the outer longitudinal side 24 of the tab 20. [0036] Compared to the first embodiment of Figure 3b, this third embodiment shown in Figure 3d provides several advantages : i) an edge gain provided by a bigger width around the middle of the tab 20 (thanks to the first rounded part having the first radius Ra) which means a higher bending stiffness of the tab 20 and less loss of the current carrying capacity of the tab 20, and ii) a bigger cut-off at the round corner 25 (thanks to the second rounded part having the second radius Rb) which means less chance of collision with the guide rolls 17 at the tab round corner 25 which is the most vulnerable to get damaged.

[0037] In this third embodiment, the first radius Ra can be around 20 to 23 mm and the second radius Rb can be around 5 to 8 mm. The rectangular first part 28 of the cathode tab 20 can be about 40 mm wide (size L of the two longitudinal sides 22, 22') and around 7 to 7,5 mm high (size Hl of the two lateral sides 21, 21'). The global height of the tab 20 (i.e. distance H2 between outer longitudinal side 24 and the longitudinal edge 11 of the foil) can be around 27 to 27,5 mm. The radius of the rounded corner between the lateral side 21 (respectively 21') and the longitudinal edge 11 can be around 2 mm.

[0038] In addition, a tab shape comprising a second trapezoidal part 29 combined with a rectangular first part 28 also gives additional benefits. For instance, the rectangular first part 28 of the tab 20 provides a slightly higher stiffness and a better electrical current carrying capacity (electrical conductivity) than a complete trapezoidal tab shape.

[0039] The scope of the present disclosure is not limited thereto, and other modifications and embodiments can be devised by those skilled in the art, without deviating from the spirit and scope of the invention described in the appended claims.

Claims

1 . Electrode sheet for a battery cell, comprising a foil with a plane surface and a flexible tab (20) which projects beyond a longitudinal edge (11) of the foil along a transversal direction (X) perpendicular to a longitudinal direction (Y), characterized in that said flexible tab (20) comprises two parts, a first part (28) starting from the longitudinal edge (11) of the foil extended by an adjacent second part (29), said first part (28) having a rectangular shape with two longitudinal sides (22, 22') of the same size and said second part (29) having a trapezoidal shape with two longitudinal sides (24, 24') of different sizes.

2. Electrode sheet according to claim 1, wherein the second part (29) of the tab (20) comprises an inner longitudinal side (24') adjacent to the first part (28) of the tab (20) and an outer longitudinal side (24), the outer side (24) being smaller than the inner side (24').

3. Electrode sheet according to claim 2, wherein the first part (28) of the tab (20) comprises two lateral sides (21, 21') which are perpendicular to the longitudinal edge (11) of the electrode foil.

4. Electrode sheet according to claim 3, wherein the second part (29) of the tab (20) comprises two lateral sides (23, 23'), both of them being not perpendicular to the longitudinal edge (11) of the foil.

5. Electrode sheet according to claim 3, wherein the second part (29) of the tab (20) comprises two lateral sides (23, 23'), one side (23') being perpendicular to the longitudinal edge (11) of the foil and the other side (23) being not perpendicular to the longitudinal edge (11) of the foil.

6. Electrode sheet according to claim 1, wherein the second part (29) of the tab (20) comprises two outer rounded corners (25).

7. Electrode sheet according to claim 4 or 5, wherein the lateral side (23, 23') of the second part (29) of the tab (20) meets smoothly with the corresponding lateral side (21, 21') of the first part (28) of the tab (20), with a round corner between the lateral side (23, 23') of the second part 29 and the corresponding lateral side (21, 21') of the first part 28.

8. Electrode sheet according to claim 3, wherein the second part (29) of the tab (20) comprises two lateral sides (23, 23') each comprising two successive rounded parts, a first rounded part having a first radius (Ra) extended by a second rounded part having a second radius (Rb), the first radius (Ra) being greater than the second radius (Rb).

9. Battery cell comprising a plurality of electrode sheets (10, 15), each electrode sheet being in accordance with one of the preceding claims.