Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
  • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
  • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
  • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
  • C08G65/4006—(I) or (II) containing elements other than carbon, oxygen, hydrogen or halogen as leaving group (X)
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
  • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
  • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
  • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
  • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
  • C08L71/12—Polyphenylene oxides
  • C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L2205/00—Polymer mixtures characterised by other features
  • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
  • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Definitions

• the present invention relates to a polyether nitrile having an excellent crystallization rate during molding, a method for producing the same, and a composition thereof.
• Aromatic ether (co)polymers not only have excellent heat resistance, flame retardance, chemical resistance, and mechanical strength, but also are thermoplastic and can be molded by heating, so they can be used for injection molding and extrusion molding. It is one of the useful resins that can be used to obtain various molded products such as filaments, films, sheets, tubes, pipes, and round bars by molding methods such as heating and compression molding.
• Polyether nitrile for example, Patent Documents 1 to 4
• Patent Documents 1 to 4 which is one of aromatic ether-based (co)polymers, has the highest level of heat resistance among thermoplastic resins and is a resin with excellent mechanical strength.
• polyethernitrile which is a composition consisting only of polyethernitrile resin.
• known polyethernitrile, polyethernitrile synthesized from resorcinol and 2,6-dichlorobenzonitrile resorcinol-polyethernitrile
• polyethernitrile synthesized from hydroquinone and 2,6-dichlorobenzonitrile hydroquinone - polyethernitrile
• polyethernitrile synthesized from 4,4'-biphenol and 2,6-dichlorobenzonitrile biphenol-polyethernitrile
• Patent Document 6 Polyether nitrile using a small amount of copolymerization component has a lower cooling-down crystallization temperature than a polymer using a single component, and conversely, the crystallization rate is lower.
• An object of the present invention is to provide a polyether nitrile that can solve these problems of the conventional polyether nitrile, which has excellent heat resistance and mechanical strength, and can improve the productivity of molded products.
• polyethernitrile whose crystallization time is within a specific range, has an improved crystallization rate, and therefore can be used for molded products by thermoforming such as injection molding.
• the present invention was completed by discovering that the molding cycle during manufacturing can be shortened. Furthermore, by having a specific molecular weight range, it is necessary to have sufficient mechanical strength, and as explained in the examples below, the temperature of isothermal crystallization, the time required for crystallization, and the molecular weight of polyethernitrile By understanding the relationship between molecular weight distributions, we discovered that polyethernitrile that satisfies specific conditions has an excellent crystallization rate.
• the invention is as follows. 1. A polyether nitrile whose half-crystallization time at 275°C is 100 seconds or less when the temperature is lowered from a molten state at 370°C to 275°C at a cooling rate of 500°C per minute as determined by input-compensated differential scanning calorimetry. 2. 1. The weight average molecular weight (Mw) in terms of polystyrene measured by gel permeation chromatography analysis is 50,000 or more. Polyether nitrile as described in. 3. 2. The weight average molecular weight (Mw) and number average molecular weight (Mn) in terms of polystyrene measured by gel permeation chromatography analysis satisfy formula (i). Polyether nitrile as described in.
• the polyether nitrile has a repeating unit represented by general formula (3). ⁇ 3.
• the polyether nitrile according to any one of the above. represents a divalent group represented by general formula (1a) or general formula (1b), and r represents an integer of 1 to 4.
• R 1 each independently represents a linear or branched alkyl group having 1 to 6 carbon atoms, a cyclic alkyl group having 5 or 6 carbon atoms, or a phenyl group
• m each independently represents Indicates an integer from 0 to 4, n indicates 0 or 1, p and q indicate 0, 1 or 2, and * indicates the bonding position.
• R 1 and m are the same as defined in the general formula (1a), and Y is an oxygen atom, a sulfur atom, a sulfonyl group, a carbonyl group, an alkyliden
• the repeating unit represented by the general formula (3) is a repeating unit represented by the general formula (3').
• Polyether nitrile as described in. In the formula, R is the same as defined in general formula (3) above.
• R of the repeating unit represented by the general formula (3') is at least one group selected from the divalent groups shown in the following structure; 6. Polyether nitrile as described in. 8.1.
• polyethernitrile resin containing at least one member of the group consisting of (A) to (C) of a thermoplastic resin material (A), an additive (B), and a filler (C).
• Composition 9. 1. Mixing two or more types of raw material polyethernitrile having different weight average molecular weights. The method for producing polyethernitrile described in . 10. 9. The polyether nitrile has a repeating unit represented by general formula (3). The method for producing polyethernitrile described in .
• R represents a divalent group represented by general formula (1a) or general formula (1b), and r represents an integer of 1 to 4.
• R 1 each independently represents a linear or branched alkyl group having 1 to 6 carbon atoms, a cyclic alkyl group having 5 or 6 carbon atoms, or a phenyl group
• m each independently represents Indicates an integer from 0 to 4, n indicates 0 or 1, p and q indicate 0, 1 or 2, and * indicates the bonding position.
• R 1 and m are the same as defined in the general formula (1a), and Y is an oxygen atom, a sulfur atom, a sulfonyl group, a carbonyl group, an alkylidene group having 1 to 15 carbon atoms, or an alkylidene group having 2 to 15 carbon atoms.
• Each of the two or more types of raw material polyethernitrile having different weight average molecular weights is a raw material polyethernitrile having the same repeating unit among the repeating units represented by the general formula (3). The method for producing polyethernitrile described in . 12.
• a method for producing a polyether nitrile resin composition which comprises mixing at least one member of the group consisting of (A) to (C). 13.
• a polyethernitrile mixing step to obtain a polyethernitrile having a half crystallization time of 100 seconds or less
• the polyether nitrile obtained in the polyether nitrile mixing step and at least one of the group consisting of (A) to (C) of the thermoplastic resin material (A), the additive (B), and the filler (C). including a resin composition component mixing step of mixing seeds; 12.
• the polyether nitrile of the present invention has an improved crystallization rate, there is no need for post-treatment such as annealing in hot molding such as injection molding of polyether nitrile, which has excellent heat resistance and mechanical strength, and the molding cycle is short. Molded products can be obtained with In addition, since the crystallization rate can be improved with only the polyether nitrile resin component, there is no problem of embrittlement and excellent mechanical strength compared to polyether nitrile resin compositions that contain conventionally known crystal nucleating agents. A molded article of polyethernitrile can be provided.
• the method for producing polyethernitrile of the present invention involves mixing two or more types of raw material polyethernitrile having different weight average molecular weights, which requires a short reaction time for production, and is a rational and simple operation. Since the polyether nitrile resin composition of the present invention uses the polyether nitrile of the present invention having a fast crystallization rate, it is possible to obtain molded articles of the polyether nitrile resin composition with excellent heat resistance in a short molding cycle. can. Moreover, the polyether nitrile resin composition of the present invention has a short and reasonable reaction time for production, and can be produced by industrially simple operations.
• Mw molecular weight distribution
• Mw/Mn weight average molecular weight
• the polyether nitrile of the present invention has a half-crystallization time of 100 seconds or less at 275°C when the temperature is lowered from a molten state of 370°C to 275°C at a cooling rate of 500°C per minute, as determined by input-compensated differential scanning calorimetry. be.
• the half crystallization time is preferably 85 seconds or less, more preferably 70 seconds or less, and particularly preferably 50 seconds or less.
• Input-compensated differential scanning calorimetry is generally performed under a nitrogen atmosphere.
• the polyether nitrile of the present invention preferably has a weight average molecular weight (Mw) in terms of polystyrene measured by gel permeation chromatography (GPC) analysis of 50,000 or more. If it is less than 40,000, the mechanical strength may be poor, which is not preferable.
• Mw weight average molecular weight
• the range of the weight average molecular weight (Mw) is more preferably 50,000 or more and 1,000,000 or less, and 50,000 or more and 500,000 or less, since moldability becomes difficult. It is more preferable that it is, and it is particularly preferable that it is in the range of 50,000 or more and 300,000 or less.
• the polyether nitrile of the present invention preferably has a weight average molecular weight (Mw) and a number average molecular weight (Mn) in terms of polystyrene that satisfy formula (i), as measured by gel permeation chromatography (GPC) analysis.
• this relationship is based on the measured values of the weight average molecular weight (Mw) and molecular weight distribution (Mw/Mn) of polyethernitrile, and the temperature (T) at the time of half-crystallization time measurement, This was discovered by performing multiple regression analysis on the relationship between the measured values of half-crystallization time ( ⁇ c1/2) at that temperature.
• the half crystallization time at 275° C. will be 100 seconds or less. Further, when the relationship of formula (ii) is satisfied, the half-crystallization time at 275°C is 85 seconds or less, and more preferably, when the relationship of formula (iii) is satisfied, the half-crystallization time at 275°C is 50 seconds or less. , particularly preferred.
• repeating unit contained in the polyethernitrile of the present invention is not particularly limited, it is preferably a polyethernitrile having a repeating unit represented by general formula (3).
• a repeating unit represented by general formula (3) it may have only one type of repeating unit, or it may have two or more types of repeating units. It is preferred to have only one type of repeating unit.
• R represents a divalent group represented by general formula (1a) or general formula (1b), and r represents an integer of 1 to 4.
• R 1 each independently represents a linear or branched alkyl group having 1 to 6 carbon atoms, a cyclic alkyl group having 5 or 6 carbon atoms, or a phenyl group
• m each independently represents Indicates an integer from 0 to 4, n indicates 0 or 1, p and q indicate 0, 1 or 2, and * indicates the bonding position.
• R 1 and m are the same as defined in the general formula (1a), and Y is an oxygen atom, a sulfur atom, a sulfonyl group, a carbonyl group, an alkylidene group having 1 to 15 carbon atoms, or an alkylidene group having 2 to 15 carbon atoms.
• R 1 each independently represents a linear or branched alkyl group having 1 to 6 carbon atoms, a cyclic alkyl group having 5 or 6 carbon atoms, or a phenyl group, and A straight chain or branched alkyl group having ⁇ 4 carbon atoms, a cyclic alkyl group having 5 or 6 carbon atoms, or a phenyl group is preferable, and a straight chain or branched alkyl group having 1 to 4 carbon atoms, or a phenyl group More preferred is an alkyl group having one carbon atom, particularly a methyl group.
• m represents an integer of 0 to 4, preferably an integer of 0, 1 or 2, more preferably 0 or 1, and particularly preferably 0.
• n represents 0 or 1, and 1 is preferable.
• p and q each independently represent 0, 1 or 2, preferably 0 or 1, and particularly preferably 0.
• General formula (1a) when n is 1 and p and q are 0 is represented as general formula (1a').
• R 1 , m and * are the same as defined in general formula (1a).
• the bonding positions in general formula (1a') are preferably independently ortho or para positions with respect to the direct bonding positions of the two benzene rings, and particularly preferably both are para positions.
• R 1 When m is 1 or 2, the bonding position of R 1 is preferably the meta position with respect to the direct bonding position of the two benzene rings. Preferred embodiments of R 1 and m are the same as in general formula (1a).
• General formula (1a) when n, p and q are 0 is expressed as general formula (1a'').
• the bonding position in the general formula (1a'') is preferably a para-position or a meta-position with respect to the other bonding position, and a para-position is particularly preferable.
• a preferred embodiment of R 1 and m is a bonding position of the general formula (1a''). Same as 1a).
• preferred embodiments are general formula (1a') where n is 1 and p and q are 0, or general formula (1a'') where n, p and q are 0.
• R 1 and m in general formula (1b) are the same as defined in general formula (1a), and preferred embodiments are also the same.
• Y in general formula (1b) is an oxygen atom, a sulfur atom, a sulfonyl group, a carbonyl group, an alkylidene group having 1 to 15 carbon atoms, a fluorine-containing alkylidene group having 2 to 15 carbon atoms, or a cyclic group having 5 to 15 carbon atoms.
• alkylidene group a phenylmethylidene group, a phenylethylidene group, a phenylene group, or a fluorenylidene group
• the cyclic alkylidene group having 5 to 15 carbon atoms may contain an alkyl group as a branched chain.
• the cyclic alkylidene group includes, for example, a cyclopentylidene group (5 carbon atoms), a cyclohexylidene group (6 carbon atoms), a 3-methylcyclohexylidene group (7 carbon atoms), 4 -Methylcyclohexylidene group (7 carbon atoms), 3,3,5-trimethylcyclohexylidene group (9 carbon atoms), cycloheptylidene group (7 carbon atoms), cyclododecanylidene group (carbon number of atoms: 12), etc.
• Y in the general formula (1b) is a sulfonyl group, a carbonyl group, an alkylidene group having 1 to 6 carbon atoms, a fluorine-containing alkylidene group having 2 to 6 carbon atoms, a cyclic alkylidene group having 5 to 12 carbon atoms, or a phenylmethylidene group.
• a lydene group, a phenylethylidene group, a phenylene group, or a fluorenylidene group is preferred; a sulfonyl group, a carbonyl group, an alkylidene group having 1 to 3 carbon atoms, a fluorine-containing alkylidene group having 2 or 3 carbon atoms, and a fluorine-containing alkylidene group having 6 to 12 carbon atoms.
• a cyclic alkylidene group, a phenylmethylidene group or a fluorenylidene group is more preferable, and an alkylidene group having 3 carbon atoms, that is, a propylidene group, a fluorine-containing alkylidene group having 3 carbon atoms, that is, a fluorine-containing propylidene group, and a cyclic alkylidene group having 6 to 12 carbon atoms.
• Z in the general formula (1b) represents an oxygen atom, a sulfur atom, or no crosslinking, preferably an oxygen atom or no crosslinking, and more preferably no crosslinking.
• Ar in the general formula (1b) each independently represents an aryl group having 6 to 8 carbon atoms, and an aryl group having 6 carbon atoms is more preferable.
• R in the general formula (3) is preferably a divalent group represented by the general formula (1a), and is preferably a divalent group represented by the general formula (1a') or a divalent group represented by the general formula (1a''). It is more preferably a divalent group represented by the following structure, and particularly preferably at least one group selected from the divalent groups shown in the following structure.
• r represents an integer of 1 to 4, preferably 1 or 2, and more preferably 1.
• a repeating unit represented by general formula (3') having ether bonds at both ortho positions of the cyano group is preferred.
• R is the same as the definition of general formula (3).
• R in the general formula (3) is preferably a divalent group represented by the general formula (1a), and is preferably a divalent group represented by the general formula (1a') or a divalent group represented by the general formula (1a''). It is more preferably a divalent group represented by the following structure, and particularly preferably at least one group selected from the divalent groups shown in the following structure. (In the formula, * indicates each bonding position.)
• the method for producing polyethernitrile of the present invention includes a method of mixing two or more types of raw material polyethernitrile having different weight average molecular weights obtained by separate polycondensation reactions in advance (Method 1), and a method of directly obtaining polyethernitrile by a polycondensation reaction. Method (Method 2) is mentioned. Method 1 is preferable because the polycondensation reaction to obtain the raw material polyether nitrile used in this method is short and rational, and can be produced by easy operations.
• each of the two or more types of raw material polyethernitrile having different weight average molecular weights may be a raw material polyethernitrile obtained using the same aromatic dihydroxy compound (I) and the same dihalobenzonitrile compound (II). , is preferable because it can be mixed at the molecular level, improves the crystallization rate, and yields a strong molded product with a high degree of crystallinity.
• a raw material polyether nitrile having units is more preferable.
• the raw material polyether nitrile used in the manufacturing method 1 of polyether nitrile of the present invention contains an aromatic dihydroxy compound (I) and a dihalobenzonitrile compound (II) in the presence of a basic compound. It can be obtained by subjecting it to a polycondensation reaction.
• Polyethernitrile having a repeating unit represented by the general formula (3) is, for example, a compound represented by the general formula (1) as an aromatic dihydroxy compound (I) and a general compound as a dihalobenzonitrile compound (II). It can be obtained by using a compound represented by formula (2) and subjecting it to a polycondensation reaction in the presence of a basic compound.
• reaction formula in this case is shown below.
• R and r are the same as defined in general formula (3), and each X independently represents a halogen atom.
• the polycondensation reaction may be performed using a pre-synthesized alkali metal salt of aromatic dihydroxy compound (I) and dihalobenzonitrile compound (II).
• the aromatic dihydroxy compound (I) includes all aromatic compounds having two hydroxyl groups, but is preferably a compound represented by the general formula (1).
• R is the same as the definition of general formula (3).
• the definition and preferred embodiments of R in general formula (1) are the same as in general formula (3).
• aromatic dihydroxy compound (I) examples include hydroquinone, resorcinol, 2-phenylhydroquinone, 4,4'-biphenol, 3,3'-biphenol, 2,6-dihydroxynaphthalene, 2,7- Dihydroxynaphthalene, 1,1'-bi-2-naphthol, 2,2'-bi-1-naphthol, 1,3-bis[1-methyl-1-(4-hydroxyphenyl)ethyl]benzene, 1,4 -bis[1-methyl-1-(4-hydroxyphenyl)ethyl]benzene, 1,3-(4-hydroxybenzoylbenzene), 1,4-(4-hydroxybenzoylbenzene), 1,3-bis(4-hydroxybenzoylbenzene) -hydroxyphenoxy)benzene, 1,4-bis(4-hydroxyphenoxy)benzene, 1,4-bis(4-hydroxyphenoxy)benzene, 1,4-bis(4-hydroxyphenyl)benz
• the dihalobenzonitrile compound (II) includes all benzonitrile compounds having two halogen groups, but is preferably a compound represented by general formula (2).
• r has the same definition as in general formula (3), and each X independently represents a halogen atom.
• X in general formula (2) each independently represents a halogen atom, each independently preferably a chlorine atom, a bromine atom, or an iodine atom, and each independently a chlorine atom or a bromine atom more preferably.
• both are chlorine atoms, particularly preferably.
• r represents an integer of 1 to 4, preferably 1 or 2, and more preferably 1.
• r is 1, a structural embodiment represented by general formula (2') in which halogen atoms are bonded to both ortho positions of the cyano group is preferred.
• dihalobenzonitrile compound (II) examples include 2,6-difluorobenzonitrile, 2,5-difluorobenzonitrile, 2,4-difluorobenzonitrile, 2,6-dichlorobenzonitrile, 2 ,5-dichlorobenzonitrile, 2,4-dichlorobenzonitrile, 2,6-dibromobenzonitrile, 2,5-dibromobenzonitrile, 2,4-dibromobenzonitrile, 2,6-dinitrobenzonitrile, 2,5 -dinitrobenzonitrile, 2,4-dinitrobenzonitrile, and 1,4-dichloro-2,5-dicyanobenzene.
• reactive derivatives thereof may be used.
• 2,6-difluorobenzonitrile and 2,6-dichlorobenzonitrile are preferably used from the viewpoint of reactivity and economic efficiency. It is also possible to use two or more of these compounds in combination.
• the above-mentioned reactive derivatives are compounds that can react with aromatic dihydroxy compounds, such as those represented by the following general formula, for example, a structure derived from 2,6-dihalobenzonitrile. It means a compound derived from the reaction of two 2,6-dihalobenzonitrile or 2,6-dihalobenzonitrile and an aromatic dihydroxy compound. (In the formula, R has the same definition as in general formula (3), and X has the same definition as in general formula (2).)
• the molar ratio of the aromatic dihydroxy compound (I) to the dihalobenzonitrile compound (II) can be arbitrarily set depending on the desired molecular weight, but is usually in the range of 0.5 to 2.0.
• the molar ratio is preferably in the range of 0.9 to 1.1, and preferably 0.95 to 1.1.
• a range of 1.05 is more preferred, and a range of 0.99 to 1.01 is particularly preferred.
• the aromatic dihydroxy compound (I) and the dihalobenzonitrile compound (II) in a substantially molar ratio of 1.00.
• the molar ratio should be in the range of 0.5 to 0.9 or 1.1 to 2. The range is preferably .0.
• the aromatic dihydroxy compound (I) and the dihalobenzonitrile compound (II) may each be used in combination of two or more types, but they may improve the crystallization rate, high crystallinity, and the toughness of the resulting molded product.
• the molar ratio of the total amount of each of the aromatic dihydroxy compound (I) and the dihalobenzonitrile compound (II) is as described above.
• the basic compound may be any organic or inorganic compound as long as it promotes the desalination polycondensation reaction and does not affect quality, but inorganic compounds are preferred, and among them, alkaline Metal compounds and alkaline earth metal compounds are preferred, and alkali metal compounds are particularly preferred.
• organic bases include tetramethylammonium hydroxide, triethylamine, N,N-diisopropylethylamine, 1,1,3,3-tetramethylguanidine (TMG), N,N-dimethyl-4-aminopyridine (DMAP), 2 , 6-lutidine, pyridine, 1,8-diazabicyclo[5.4.0]-7-undecene (DBU), 1,5-diazabicyclo[4.3.0]-5-nonene (DBN), 7-methyl -1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD), 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) , 1,8-bis(dimethylaminonaphthalene) (DMAN), 1,4-diazabicyclo[2.2.2]octane (DABCO), tert-butylimino-tri(pyrrolidino)phosphorane, tert-but
• alkali metal compounds include alkali metals such as lithium, rubidium, cesium, potassium, and sodium; alkali metal hydrides such as lithium hydride, rubidium hydride, cesium hydride, potassium hydride, and sodium hydride; , alkali metal hydroxides such as lithium hydroxide, rubidium hydroxide, cesium hydroxide, potassium hydroxide and sodium hydroxide, alkali metal carbonates such as lithium carbonate, rubidium carbonate, cesium carbonate, potassium carbonate and sodium carbonate, hydrogen carbonate. Examples include alkali metal hydrogen carbonates such as lithium, rubidium hydrogen carbonate, cesium hydrogen carbonate, potassium hydrogen carbonate, and sodium hydrogen carbonate.
• alkali metal compounds having a specific surface area of 0.3 m 2 /g or more can also be used alone or in combination of two or more.
• the specific surface area of the alkali metal compound is preferably 0.8 m 2 /g or more, more preferably 1.2 m 2 /g or more.
• alkali metal carbonates such as lithium carbonate, rubidium carbonate, cesium carbonate, potassium carbonate, and sodium carbonate are preferable, and lithium carbonate, potassium carbonate, and sodium carbonate are more preferable.
• potassium carbonate and sodium carbonate having a specific surface area of 0.3 m 2 /g or more are particularly preferable.
• the amount of the basic compound used in the polycondensation reaction to obtain the raw material polyether nitrile is, for example, in the case of an alkali metal compound, usually 2 mol based on the aromatic dihydroxy compound (I) as the alkali metal ion contained. It is preferable that the amount is 2 to 4 times or more, but if it is used in large excess, side reactions such as cleavage of ether bonds will occur during polycondensation. It is more preferably used in a range of 4 times the mole, and particularly preferably in a range of 2 to 2.2 times the mole.
• reaction solvent can be used in the polycondensation reaction to obtain the raw material polyether nitrile, and it is preferable to use an aprotic solvent as the reaction solvent.
• the aprotic solvent includes N,N-dimethylacetamide, N,N-dimethylformamide, N-methyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolidinone, ⁇ -butyrolactone, Sulfolane, dimethyl sulfoxide, diethyl sulfoxide, dimethyl sulfone, diethyl sulfone, diisopropylsulfone, diphenyl sulfone, diphenyl ether, benzophenone, dialkoxybenzene (alkoxy group has 1 to 4 carbon atoms), trialkoxybenzene (alkoxy group has 1 to 4 carbon atoms) ) etc.
• polar organic solvents with a high dielectric constant such as N-methyl-2-pyrrolidone, N,N-dimethylacetamide, sulfolane, diphenylsulfone, and dimethylsulfoxide are particularly preferably used. These can also be used alone or in combination of two or more.
• the amount of the aprotic solvent used is no particular restriction on the amount of the aprotic solvent used, as long as the amount allows uniform dissolution of the raw materials and good stirring and dispersion of the alkali metal salt.
• the amount may be selected to maximize the volumetric efficiency of the polycondensation reactor based on the raw materials used and the desired polymer. Usually, it is selected in a range of 0.5 to 20 times the total weight of raw materials and alkali metal salt.
• the polycondensation reaction to obtain the raw material polyether nitrile may be carried out by dividing the steps into an oligomer formation step (A) and a polymerization step (B) and changing the reaction method for each, or it may be carried out without dividing the steps. Good too.
• the oligomer formation step (A) is a step in which an aromatic dihydroxy compound (I) and a dihalobenzonitrile compound (II) undergo a polycondensation reaction in the presence of a basic compound to form an oligomer.
• the polymer formation step (B) is a step in which the oligomer obtained in step (A) is further subjected to a polycondensation reaction to form a polymer.
• the polycondensation reaction solution of step (A) can be used as it is, or an oligomer isolated by performing step (A) separately can also be used.
• the polycondensation reaction for obtaining the polyether nitrile according to the present invention includes an operation for removing moisture generated during the desalting reaction from the system.
• the operation method is, for example, to carry out the reaction in the presence of a solvent that forms an azeotrope with water at a temperature that allows the desalting reaction to proceed, and during this process, water is distilled from the reaction mixture using a solvent that forms an azeotrope with water.
• An example of this method is to remove it. This allows the reaction to be maintained in a substantially anhydrous state.
• the temperature at which the desalting reaction begins is usually around 130°C, although it depends on the raw materials.
• reaction temperature is preferably in the range of 130 to 170°C.
• the solvent that forms an azeotrope with water include aromatic hydrocarbons such as benzene, toluene, xylene, hexane, cyclohexane, octane, chlorobenzene, dioxane, tetrahydrofuran, anisole, and phenethole. These can also be used alone or in combination of two or more.
• aromatic hydrocarbons such as benzene, toluene, xylene, hexane, cyclohexane, octane, chlorobenzene, dioxane, tetrahydrofuran, anisole, and phenethole.
• aromatic hydrocarbons such as benzene, toluene, xylene, hexane, cyclohexane, octane, chlorobenzene, dioxane, tetrahydrofuran, anisole, and phenethole.
• reaction system When continuing the reaction, it is preferable to maintain the reaction system in a substantially anhydrous state while removing water produced by the reaction. If the produced water is not sufficiently removed, a phenol skeleton by-product is formed by reaction with the dihalobenzonitrile compound (II), and only a low molecular weight product is produced. That is, in order to obtain a high molecular weight polyether nitrile, it is preferable that the reaction system be substantially anhydrous, preferably less than 0.5% by weight.
• the temperature of the polycondensation reaction to obtain the raw material polyether nitrile is in the range of 140 to 300°C. Within this range, the reaction may be continued at a constant temperature, or the temperature may be increased as the polycondensation reaction progresses.
• the oligomer formation step (A) is preferably in the range of 140 to 200°C, and preferably in the range of 150 to 170°C.
• the temperature is more preferably 155 to 165°C
• the polymerization step (B) is preferably 200 to 300°C, more preferably 210 to 270°C.
• the temperature is more preferably in the range of 210 to 240°C, and particularly preferably in the range of 215 to 230°C.
• a temperature range of 190 to 280 °C is suitable.
• the pressure may be normal pressure, higher or lower pressure.
• the polycondensation reaction is preferably carried out under an inert atmosphere, for example under a nitrogen atmosphere and at atmospheric pressure.
• the reaction time of the polycondensation reaction to obtain the raw material polyether nitrile depends on the molar ratio of the aromatic dihydroxy compound (I) and the dihalobenzonitrile compound (II) and the amount of the basic compound used, but it depends on the amount of the target polyether nitrile.
• the time can be set arbitrarily depending on the molecular weight, but it is usually 3 to 20 hours.
• the polycondensation reaction product after completion of the polycondensation reaction to obtain the raw material polyether nitrile can be used as it is as the raw material polyether nitrile, it is preferable to perform a treatment after the reaction.
• the polycondensation reaction product is extracted from the reactor, cooled and solidified, and then pulverized for the next process of washing, drying, and manufacturing of molding materials (pellets, chips), or the polycondensation reaction product is extracted from the reactor. You can directly put the material into the cleaning tank for the cleaning process, or you can inject the solvent to be used in the cleaning process described later into the reactor after the polycondensation reaction has finished, and then carry out the cleaning process in a slurry or wax state. It may be transferred to
• the washing step is a step of washing to remove salts, reaction solvents, etc. contained in the polycondensation reaction product obtained by the polycondensation reaction.
• the reaction solvent in the polycondensation reaction product is extracted and washed using a known method using a solvent such as alcohol, ketone, aromatic hydrocarbon, aliphatic hydrocarbon, water, etc., and then preferably It is preferable to wash and remove the salt generated in the desalting reaction in the polycondensation reaction product with water.
• the polycondensation reaction product in the form of pulverization, slurry, or wax is transferred to a container equipped with a stirrer, and stirred and washed with a washing solvent until the reaction solvent and salt content is below the target content. , repeat the filtration operation.
• a washing tank a pressure filter, or a centrifugal separator
• a multifunctional filtration device that can perform washing, filtration, and drying in one device may be used.
• extraction and cleaning solvents for the reaction solvent other than water include alcohols such as methanol, ethanol, propyl alcohol, isopropyl alcohol, butyl alcohol, isobutyl alcohol, sec-butyl alcohol, t-butyl alcohol, and n-amyl alcohol. , isoamyl alcohol, t-amyl alcohol, n-hexyl alcohol, cyclohexanol, n-octyl alcohol, caprylic alcohol and the like.
• alcohols such as methanol, ethanol, propyl alcohol, isopropyl alcohol, butyl alcohol, isobutyl alcohol, sec-butyl alcohol, t-butyl alcohol, and n-amyl alcohol.
• ketone examples include acetone, methyl ethyl ketone, methyl n-propyl ketone, diethyl ketone, 2-hexanone, 3-hexanone, methyl-t-butyl ketone, di-n-propyl ketone, diisopropyl ketone, diisobutyl ketone, di-n- Examples include amylketone, diacetyl, acetylacetone, cyclohexanone, benzophenone and the like.
• aliphatic hydrocarbons examples include n-hexane, 2-methylhebutane, 3-methylhebutane, 2,2-dimethylbutane, 2,3-dimethylbutane, n-hebutane, 2-methylhexane, 3 -Saturation of methylhexane, 2,2-dimethylpentane, 2,3-dimethylpentane, 2,4-dimethylpentane, 3,3-dimethylpentane, 3-ethylpentane, 2,2,3-trimethylbutane, cyclohexane, etc.
• Examples include aliphatic hydrocarbons, unsaturated hydrocarbons such as 1-hexene, 1-heptene, 1-octene, and cyclohexene.
• aromatic hydrocarbons include benzene, toluene, o-xylene, m-xylene, p-xylene, ethylbenzene, n-propylbenzene, cumene, n-butylbenzene, t-butylbenzene, styrene, and allylbenzene.
• acetone and methanol are particularly preferred in terms of operability and ease of distillation recovery of the reaction solvent after washing.
• Water is preferable for washing the alkali metal salts such as potassium chloride produced in the desalination polycondensation reaction, and acidic water containing oxalic acid or acetic acid at a low concentration may also be used.
• the conditions for this washing step include the amount of washing solvent used, the number of times of washing, and the washing temperature, which may be appropriately selected depending on the amount of residual reaction solvent and residual alkali metal salt to be removed.
• the drying step is a step of drying the polycondensation reaction product subjected to the above-mentioned washing step. After washing, the water-containing polycondensation reaction product is dried by a known method.
• a known device such as an evaporator, tray oven, or tumbler can be used.
• the target moisture content is usually 0.5% by weight or less, preferably 0.4% by weight or less, and more preferably 0.3% by weight or less.
• the conditions for this drying step may be any conditions as long as they can remove moisture at a temperature below the melting point of the polycondensation reaction product.
• the dried polycondensation reaction product is basically a powder.
• the raw material polyethernitrile may be in the form of a molding material (pellets, chips, etc.) for producing polyethernitrile molded articles.
• a molding material pellets, chips, etc.
• the powdered raw material polyethernitrile obtained as described above is heated and melted and molded into the shape of a molding material such as pellets or chips. good. It is preferable that such heating melting and molding operations are carried out under oxygen exclusion or an inert atmosphere such as nitrogen.
• melt-kneading equipment such as single-screw, twin-screw or multi-screw extruders, Banbury mixers, kneaders, rollers, etc.
• the sheet may be cut to produce molding materials such as pellets and chips.
• the industrially preferred process for producing molding materials is as follows.
• the polyether nitrile powder that has been polycondensed, crushed, washed, and vacuum-dried is directly transferred and stored in a silo sealed with nitrogen gas or the like without being exposed to the outside air.
• the material is directly passed through piping and transferred to an extruder along with nitrogen gas. Then, the polymer is melt-kneaded without contact with oxygen (air), and the molten polymer from the die is cut underwater or the strands are water-cooled to be pelletized.
• the above-mentioned operations are performed at a temperature sufficient to melt the polymer.
• the upper limit of the temperature during melt processing is 500°C or less.
• the raw material polyethernitrile obtained using biphenol and 2,6-dichlorobenzonitrile used in the example had a melting point of about 345°C, so processing should be performed at a higher temperature of 360°C or higher.
• the upper limit of the temperature is preferably 480°C or lower, more preferably 450°C or lower, even more preferably 430°C or lower, and particularly preferably 400°C or lower.
• the present invention uses the polyethernitrile of the present invention as one type of raw material polyethernitrile to be mixed, and shortens or lengthens the semi-crystallization time of the polyethernitrile used in order to obtain a desired molding cycle. It is also possible to produce polyethernitrile.
• the form of the raw material polyether nitrile to be mixed is not particularly limited, and specifically, for example, a polycondensation reaction product after the completion of the polycondensation reaction to obtain the raw material polyether nitrile, a washed product of the polycondensation reaction product, and a powder.
• a polycondensation reaction product after the completion of the polycondensation reaction to obtain the raw material polyether nitrile a washed product of the polycondensation reaction product, and a powder.
• Examples include shapes of bodies and molding materials (pellets, chips, etc.). Among these, the form of powder or molding material (pellet, chip, etc.) is preferable, and powder is particularly preferable.
• the mixture When heated and melted and mixed, the mixture may be directly subjected to the process of forming a molding material, which will be described later.
• the polyether nitrile of the present invention is obtained by such mixing, and then treated based on the above-mentioned post-reaction treatment method. It is preferable to remove salts, reaction solvents, etc. contained in the polycondensation reaction product, and to remove water contained in the polycondensation reaction product. Through such treatment, the polyether nitrile powder of the present invention can be obtained. It is preferable to carry out such a mixing operation under oxygen exclusion or under an inert atmosphere such as nitrogen in order to obtain a polyether nitrile having excellent melt fluidity.
• Method 2 In the case of the method (method 2) of directly obtaining the polyether nitrile of the present invention by polycondensation reaction, the aromatic dihydroxy compound (I) and the dihalobenzonitrile compound (II), It can be obtained by carrying out a polycondensation reaction in the presence of a basic compound.
• the types of aromatic dihydroxy compound (I), dihalobenzonitrile compound (II) and basic compound that can be used in the polycondensation reaction, the type and amount of the reaction solvent, the polycondensation reaction method, and the polycondensation reaction conditions are as described above. This is the same as the polycondensation reaction of raw material polyether nitrile.
• the aromatic dihydroxy compound (I) and the dihalobenzonitrile compound (II) may each be used in combination of two or more types, but they may improve the crystallization rate, high crystallinity, and the toughness of the resulting molded product. From this point of view, it is preferable to use only one type of each compound. When two or more types of compounds are used, the molar ratio of the total amount of each of the aromatic dihydroxy compound (I) and the dihalobenzonitrile compound (II) is as described above.
• the molar ratio of the aromatic dihydroxy compound (I) and the dihalobenzonitrile compound (II) used is substantially 1.00, and the basic compound, for example, in the case of an alkali metal compound, the alkali metal ion contained
• the polycondensation reaction is carried out using 1 mole or more of the aromatic dihydroxy compound (I).
• the polycondensation reaction time is such that the reduced viscosity of the polyethernitrile increases as the polycondensation reaction progresses, reaches a maximum, and then continues until the reduced viscosity decreases until the polyethernitrile of the present invention is obtained. You can get it by doing this.
• the polyether nitrile of the present invention is obtained by continuing the reaction for 15 to 50 hours, preferably 20 to 50 hours, depending on conditions such as the amount of the basic compound used and the reaction temperature. be able to.
• the polycondensation reaction product is extracted from the reactor, cooled and solidified, and then pulverized to produce the next washing step, drying step, and molding material (pellets, chips).
• the polycondensation reaction product extracted from the reactor can be directly put into the cleaning tank of the cleaning process, or it can be used in the cleaning process described later in the reactor after the polycondensation reaction has finished.
• the solvent may be injected and transferred to the cleaning process in a slurry or wax state.
• the washing step and drying step performed on the polycondensation reaction product after the completion of the polycondensation reaction to obtain the polyethernitrile of the present invention are performed on the polycondensation reaction product after the completion of the polycondensation reaction to obtain the above-mentioned raw material polyethernitrile. It can be carried out in the same manner as the washing step and drying step.
• the polyether nitrile of the present invention obtained by the method 1 or 2 described above can be shaped into a molding material (pellets, chips, etc.) for producing molded products.
• a molding material pellets, chips, etc.
• the polyethernitrile of the present invention obtained as described above may be heated and melted and molded into the shape of the molding material such as pellets or chips. . It is preferable that such heating melting and molding operations are carried out under oxygen exclusion or an inert atmosphere such as nitrogen.
• melt-kneading equipment such as single-screw, twin-screw or multi-screw extruders, Banbury mixers, kneaders, rollers, etc. are used to manufacture molding materials such as pellets and chips;
• the sheet may be cut to produce molding materials such as pellets and chips.
• the industrially preferred process for producing molding materials is as follows.
• the polyether nitrile powder that has been polycondensed, crushed, washed, and vacuum-dried is directly transferred and stored in a silo sealed with nitrogen gas or the like without being exposed to the outside air.
• the material is directly passed through piping and transferred to an extruder along with nitrogen gas.
• the polymer is melt-kneaded without contact with oxygen (air), and the molten polymer from the die is cut underwater or the strands are water-cooled to be pelletized.
• the above-mentioned operations are performed at a temperature sufficient to melt the polymer.
• the upper limit of the temperature during melt processing is 500°C or less.
• the polyether nitrile powder using biphenol used in the examples had a melting point of about 345°C, so it is preferable to process it at a higher temperature of 360°C or higher, and the upper limit of the temperature is:
• the temperature is preferably 480°C or lower, more preferably 450°C or lower, even more preferably 430°C or lower, and particularly preferably 400°C or lower.
• the polyether nitrile of the present invention can be made into a polyether nitrile resin composition by mixing at least one member of the group consisting of a thermoplastic resin material (A), an additive (B), and a filler (C). .
• the polyether nitrile of the present invention used here is preferably the polyether nitrile obtained by method 1.
• thermoplastic resin material (A) contained in the polyether nitrile resin composition includes, for example, high density polyethylene, medium density polyethylene, isotactic polypropylene, acrylonitrile butadiene styrene (ABS) resin, Acrylonitrile styrene (AS) resin, acrylic resin, fluororesin (polytetrafluoroethylene, etc.), polyester, polycarbonate, polyarylate, aliphatic polyamide, aromatic polyamide, polysulfone, polyether sulfone, polyether ketone, polyether ether ketone , polyphenylene sulfide, polyetherimide, polyamideimide, polyesterimide, and modified polyphenylene oxide.
• ABS acrylonitrile butadiene styrene
• AS Acrylonitrile styrene
• acrylic resin polytetrafluoroethylene, etc.
• polyester polycarbonate, polyarylate, aliphatic polyamide, aromatic polyamide, polys
• the additive (B) contained in the polyether nitrile resin composition includes, for example, a hydrophilic agent, an antioxidant, a secondary antioxidant, a flame retardant, a flame retardant aid, a plasticizer, and a lubricant. agent, mold release agent, antifogging agent, weathering stabilizer, light stabilizer, hydrolysis resistance improver, fluidity improver, ultraviolet absorber, antistatic agent, metal deactivator, near-infrared absorber, coloring agents (dyes, pigments).
• the filler (C) contained in the polyether nitrile resin composition includes various metal powders, inorganic acid metal salts (calcium carbonate, zinc borate, calcium borate, zinc stannate, sulfuric acid, etc.).
• metal oxides magnesium oxide, iron oxide, titanium oxide, zinc oxide, alumina, etc.
• metal hydroxides aluminum hydroxide, magnesium hydroxide, zirconium hydroxide, alumina water, etc.
• metal sulfides zinc sulfide, molybdenum sulfide, tungsten sulfide, etc.
• ceramic materials such as silver nanowires, carbon fibers, glass fibers, carbon nanotubes, graphene, and silica.
• the method for producing a polyethernitrile resin composition of the present invention includes mixing the polyethernitrile of the present invention with at least one member of the group consisting of a thermoplastic resin material (A), an additive (B), and a filler (C). This is the way to do it. At this time, it is preferable that the polyether nitrile is in the form of a powder or a molding material. In such a mixing method, when using the polyethernitrile of the present invention produced by method 1, when two or more raw material polyethernitrile having different weight average molecular weights are mixed, the polyethernitrile of the present invention is obtained.
• the two or more types of raw polyether nitrile are mixed with at least one member of the group consisting of (A) to (C), including a thermoplastic resin material (A), an additive (B), and a filler (C).
• the step of mixing each component is as follows: First, two or more types of raw material polyethernitrile having different weight average molecular weights are mixed by the method described above to obtain the polyethernitrile of the present invention.
• the polyethernitrile obtained in the "polyethernitrile mixing step" the thermoplastic resin material (A), the additive (B), the filler (C), and the (A) It is preferable to include a "resin composition component mixing step” of mixing at least one member of the group consisting of ) to (C).
• a "resin composition component mixing step” of mixing at least one member of the group consisting of ) to (C).
• the polyether nitrile resin composition of the present invention thus obtained can be used to produce a molding material for a polyether nitrile resin composition in the same manner as in the process for producing the above-mentioned molding material. . Since it is possible to obtain a polyether nitrile resin composition molding material with excellent melt fluidity, melt molding in the step of preparing a molding material is preferably carried out under oxygen exclusion or an inert atmosphere.
• the polyether nitrile obtained by the method of the present invention can be used as a molding material by the method described above, or can be used to manufacture molded products and parts, and has excellent heat resistance, chemical resistance, and flame retardant properties. It has high strength and mechanical properties. For example, it can be used in electrical and electronic applications such as personal computers and semiconductor parts, in automobile applications such as gears, bearings, and housings around engines, and in medical instruments and aerospace applications.
• the analysis method in the present invention is as follows. (1) Half-crystallization time Using an input-compensated differential scanning calorimeter (manufactured by PerkinElmer: DSC8500), polyethernitrile pellets obtained in the Examples and Comparative Examples described below were measured at The half-crystallization time, which is the time that is half of the total crystallization heat amount, was measured. ⁇ Conditions> Sample: 5mg Measurement atmosphere: Nitrogen Temperature control: The temperature was raised from 30°C to 370°C at a heating rate of 500°C/min, held for 3 minutes, then lowered to the measurement temperature at a cooling rate of 500°C/min, and maintained at the measurement temperature.
• the weight average molecular weight (Mw) and number average molecular weight (Mn) of the obtained polyether nitrile are determined by diluting a 1% p-chlorophenol solution of polyether nitrile 10 times with chloroform using the following method. Measured using equipment and conditions. From this value, the molecular weight distribution Mw/Mn was determined.
• Tm melting point
• Tg glass transition temperature
• DCBN 2,6-dichlorobenzonitrile
• Synthesis Example 2 powder raw material polyether nitrile (hereinafter referred to as "Raw Material Resin B”) was prepared in the same manner as in Synthesis Example 1, except that the polycondensation reaction was carried out at a temperature of 220° C. for 8.0 hours. Obtained.
• Synthesis Example 3 powder raw material polyether nitrile (hereinafter referred to as "Raw Material Resin C”) was prepared in the same manner as in Synthesis Example 1, except that the polycondensation reaction was carried out at a temperature of 220° C. for 1.0 hours. Obtained.
• Synthesis Example 4 powder raw material polyether nitrile (hereinafter referred to as "Raw Material Resin D”) was prepared in the same manner as in Synthesis Example 1, except that the polycondensation reaction was carried out at a temperature of 220° C. for 3.0 hours. Obtained.
• the polyethernitrile of Examples 1 to 3 of the present invention has a half crystallization time of 100 seconds or less at 275°C, and has a half crystallization time of 100 seconds or less compared to the conventional polyethernitrile of Comparative Examples 1 to 5.
• the crystallization time is short, and even when comparing polyether nitriles with similar weight average molecular weights (Comparative Example 1 and Examples 1 and 2, Comparative Example 2 and Example 3), the half crystallization time is significantly shortened. It became clear that the crystallization rate was significantly improved. It has also been found that the polyether nitrile of the present invention maintains a high melting point (Tm) and a high glass transition temperature (Tg).
• the polyether nitrile of the present invention is very useful because it has a fast crystallization rate and a polyether nitrile molded article having high heat resistance can be obtained in a short molding cycle. Furthermore, it was also revealed that the polyether nitrile of Examples 1 to 3 of the present invention had a high weight average molecular weight of 50,000 or more and had sufficiently excellent mechanical properties.
• FIG. 1 shows a graph of the relationship between molecular weight distribution (Mw/Mn) and weight average molecular weight (Mw), where Mw is in the range of 50,000 or more and 80,000 or less, and Mw/Mn is in the range of 0 or more and 10 or less.
• the polyether nitriles of the present invention whose half crystallization time at 275°C is within 100 seconds, the polyether nitriles of Examples 1 and 2 satisfy the relationships of formulas (i) and (ii), and the polyether nitriles of Example 3 satisfy the following conditions: Polyether nitrile satisfies the relationships of formulas (i) to (iii), and the polyether nitriles of Comparative Examples 1 to 5, whose half-crystalization time at 275°C was longer than 100 seconds, satisfy formulas (i) to (iii). It became clear that neither of the relationships was satisfied.
• the above examples are based on biphenol-polyethernitrile, which has a slow crystallization rate among polyethernitrile, so other polyethernitrile, such as resorcinol-polyethernitrile and hydroquinone-polyethernitrile, which have a faster crystallization rate, are used.
• Any polyethernitrile is included in the present invention, and a person having ordinary knowledge in the field of polyethernitrile will understand that it is a polyethernitrile with a very short half-crystallization time and a very fast crystallization rate. I can understand.
• the application of the technique of the present invention to other polyether resins that are difficult to crystallize will be readily conceivable to those skilled in the art and will be obvious from the present invention.

Landscapes

• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Polyethers (AREA)
• Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Priority Applications (4)

Applications Claiming Priority (2)

Publications (1)

Family

ID=90190960

Family Applications (1)

Country Status (6)

Cited By (1)

Citations (12)

• 2023
  • 2023-08-04 JP JP2024545496A patent/JPWO2024053304A1/ja active Pending
  • 2023-08-04 EP EP23862847.3A patent/EP4585635A1/en active Pending
  • 2023-08-04 CN CN202380062634.7A patent/CN119731238A/zh active Pending
  • 2023-08-04 WO PCT/JP2023/028547 patent/WO2024053304A1/ja not_active Ceased
  • 2023-08-04 US US19/102,764 patent/US20260055236A1/en active Pending
  • 2023-08-15 TW TW112130668A patent/TW202419520A/zh unknown

Patent Citations (12)

Also Published As

Similar Documents

Legal Events