WO2023166240A1 - Toothed gear for bicycles or other systems having a similar transmission - Google Patents

Toothed gear for bicycles or other systems having a similar transmission Download PDF

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Publication number
WO2023166240A1
WO2023166240A1 PCT/ES2023/070120 ES2023070120W WO2023166240A1 WO 2023166240 A1 WO2023166240 A1 WO 2023166240A1 ES 2023070120 W ES2023070120 W ES 2023070120W WO 2023166240 A1 WO2023166240 A1 WO 2023166240A1
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WIPO (PCT)
Prior art keywords
toothed gear
fibers
bicycles
teeth
discontinuous
Prior art date
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PCT/ES2023/070120
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Spanish (es)
French (fr)
Inventor
Roland Baides Martinez
Original Assignee
Gemini Composites, S.L.
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Publication date
Application filed by Gemini Composites, S.L. filed Critical Gemini Composites, S.L.
Publication of WO2023166240A1 publication Critical patent/WO2023166240A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D15/00Producing gear wheels or similar articles with grooves or projections, e.g. control knobs
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16HGEARING
    • F16H55/00Elements with teeth or friction surfaces for conveying motion; Worms, pulleys or sheaves for gearing mechanisms
    • F16H55/02Toothed members; Worms
    • F16H55/06Use of materials; Use of treatments of toothed members or worms to affect their intrinsic material properties

Definitions

  • the invention refers to a toothed gear for bicycles or other similar transmission systems that contributes, to the function for which it is intended, advantages and characteristics, which are described in detail later. .
  • the object of the present invention falls on a toothed gear for bicycles or other similar transmission systems in which it is constituted as an essential element of said movement transmission, which presents the innovative characteristic of being made of discontinuous carbon fiber, or other composite materials.
  • discontinuous fibers known as "Discontinous Fiber Composites” (DFC)
  • DFC Discontinous Fiber Composites
  • the field of application of the present invention falls within the field of transmission systems that include toothed gears.
  • carbon fiber which is a lightweight and highly resistant material, is used in various structural and mechanical parts of a bicycle.
  • the manufacturing processes for carbon fiber parts currently used are based on the use of compounds from sheets that contain continuous, woven or unidirectional fibers. (See Figures 2-A and 2-B).
  • epoxy-based carbon fiber is a composite material (composite). Like all “composites”, it is made from a binder matrix and a reinforcing fiber. Since its structural distribution depends on the directionality of the fibers that reinforce it, and they are usually found in a specific order, it is an anisotropic material. (See Figures 1).
  • Epoxy-based carbon fiber composite is a material that must go through a curing process during the manufacturing process of a part. There are different types of raw material that can be purchased depending on each need and supplier.
  • this anisotropic composite material depend on the directionality of the fibers that reinforce it, in this case, the carbon fiber (reinforcement). These fibers have the capacity to withstand large axial tensile stresses, with very little deformation, which makes the composite a very rigid and resistant material.
  • the fibers do not present a good behavior to other stresses such as compression, bending or shear axial stresses.
  • the structural behavior of the fiber decreases and it is the matrix (epoxy resin) that absorbs a large part of the stresses, generating cracks, breaks or breaks in the composite material. It is for this reason that, for a correct manufacturing of a carbon fiber part, it is important to anticipate how the fibers will be directed, especially in the critical areas of the part where it may suffer more pronounced stresses.
  • the critical stresses to which a toothed gear is usually subjected are located at the end of the teeth, generated by other elements of the transmission system such as a chain, in a tangential direction to the circular movement of the gear itself. and in the opposite direction of its rotation.
  • pre-impregnated with resin or "prepreg" is a material that is served in sheets, where the fibers are perfectly ordered and arranged according to a certain pattern, which can be unidirectional, or woven together throughout the sheet.
  • the matrix generally raw epoxy resin, binds the fibers together, forming a joint sheet.
  • a pattern For the manufacture of a piece with continuous carbon sheets, a pattern must be designed for the desired piece, and mold it onto said pre-impregnated sheets. Once the patterns have been obtained, they must be arranged in the mold of the piece, taking into account the directionality of the fiber in each of the layers. Finally, the mold must be closed with a certain pressure to compact the material and subject it to a temperature curing process.
  • the geometry of a part is not obtained only from the laminate, but once a part is cured with excess material, it is partially or totally machined.
  • the different layers of continuous carbon that make up the piece are arranged in a different way between them, with the aim that they always meet. fibers in the optimum orientation in the areas susceptible to critical stresses.
  • the use of sheets of continuous carbon fiber implies that in the protruding areas (teeth) the carbon fibers remain mostly in a non-optimal orientation, and cut, or either by the design of the pattern, or by machining after curing, nullifying the continuous character of the fiber in those areas, compromising its structural behavior. (See Figures 5 and 6).
  • each tooth of the toothed gear manufactured by the "prepreg" continuous carbon laminate method is not optimal in terms of the structure of the carbon fibers, since the distribution of the fibers would be different in each case.
  • each tooth of the toothed wheel as it is a circular element.
  • DFC Discontinous Fiber Composites
  • this group of materials is served as a composite of discontinuous carbon fibers, also pre-impregnated with a binder (matrix), generally Epoxy resin, in sheet format or SMC (Sheet Molding Compund) or in mass format or BMC (Bulk Molding Compound).
  • matrix generally Epoxy resin
  • SMC Sheet Molding Compund
  • BMC Body Molding Compound
  • DFC discontinuous fiber composites
  • the objective of the present invention is, therefore, to provide the market with a toothed gear with the advantages of carbon fiber produced by DFC compression molding, improving the behavior of this material in critical areas of the part, such as the of the teeth.
  • the toothed gear that the invention proposes is configured as the ideal solution to the aforementioned objective, with the characteristic details that make it possible and that distinguish it conveniently included in the final claims that accompany this description.
  • toothed gear for bicycles or other similar transmission systems which is distinguished by being manufactured by compression molding of discontinuous fiber composite materials also known as DFC, preferably discontinuous carbon fiber.
  • said part is suitable for constituting a toothed gear thanks to the fact that the carbon fiber material, instead of being laminated layer by layer and made up of layers of continuous fibers with carbon threads arranged unidirectionally and/or woven, as It would be usual, it is made by compression molding a compound of discontinuous fibers together, where the fibers are dragged, by the pressure exerted inside the mold, up to the interior cavity of each one of the gear teeth.
  • the gear presents a structural improvement with respect to a gear laminated with continuous fiber, since the orientation and distribution of the fibers, obtained thanks to the pressure that the mold provides, corresponds very similarly to the structural orientation. of ideal fibers described in Figure 4-B, which they must have in order for them to present optimal behavior in the face of the efforts to which a gear is subjected.
  • Figure number 1 Shows a schematic view of the representation of the parts that make up the material constituting the carbon fiber or other fiber composite material as reinforcement;
  • Figures number 2-A, 2-B, 2-C and 2-D.- Show a schematic representation of the different types of carbon fiber with pre-impregnated resin that can be found commercially;
  • Figures number 3-A, 3-B and 3-C.- Show respective schematic views of the DFC compression molding phases, showing respectively the initial arrangement of the material in the center of the mold and its distributed arrangement throughout the mold after having received pressure;
  • figures number 4-A and 4-B.- Show, respectively, a schematic representation of a toothed gear with the chain, and enlarged detail A of the toothed area showing, by means of double arrow lines, the ideal orientation of the fibers and, by means of a bold arrow, the force exerted by the chain on the teeth;
  • Figures number 5-A and 5-B.- Show respective views, in elevation and section, respectively, of an example of toothed gear, according to a hypothetical embodiment of the gear obtained
  • a toothed gear for bicycles or other similar transmission systems made from a circular part (1).
  • Radially equipped with a plurality of teeth (1 a) it is distinguished by the fact that said part (1) is made of a composite material with discontinuous reinforcing fibers, known as DFC (discontinuous fiber composite material), preferably discontinuous fibers carbon, obtained by compression molding or compression molding.
  • DFC discontinuous fiber composite material
  • said piece (1) is obtained from a portion of composite material (5) formed by a binder, thermosetting or thermoplastic polymeric matrix (2), and fiber reinforcement, normally carbon, consisting of discontinuous threads (3). and disordered, whose threads (3), once the part (1) is obtained, are oriented mostly randomly in the center of said part and in a continuous and concentric way towards each of the teeth (1 a).
  • the material is placed in the mold in a random arrangement, and by compressing the mold in the central area, the material continues to remain in this position, providing a quasi-isotropic behavior, but in the area of the teeth, the material is pushed, leaving the fibers concentrically oriented and more continuous with the shape of the teeth.
  • the carbon fiber with which the toothed gear (1) of the invention is made is a material composed of a binder matrix (2), usually epoxy thermosetting resin, and a structural reinforcement consisting of carbon fiber or threads (3).
  • FIGS 2-A, 2-B, 2-C and 2-D show, schematically, the different types of carbon fiber with pre-impregnated resin that can be found commercially.
  • Figure 2-A shows how, in an example of a UD (unidirectional) sheet (4), the carbon fiber threads (3) are continuous and are all oriented in the same direction.
  • Figure 2-B shows how, in another example of sheet (4), the carbon fiber threads (3) are continuous and intertwined in an orderly fashion.
  • FIG 2-C it can be seen how, in another example of sheet (4) of discontinuous fibers (SMC), the carbon fiber threads (3) are discontinuous, of a determined length and are disordered throughout the entire length of the sheet. leaf.
  • SMC discontinuous fibers
  • FIG 2-D it can be seen how, in an example of a mass of discontinuous fibers (BMC), the carbon fiber threads (3) are discontinuous, of a determined length and are disordered throughout a mass ( 2) that binds them together, generally Epoxy resin.
  • BMC discontinuous fibers
  • the DFC compression molding phases can be seen schematically, showing respectively the initial arrangement of the material in the center of the mold and the arrangement distributed throughout the mold after receiving pressure.
  • said material (5) is placed in the mold (6) in the amount of volume required, and is subjected to high temperature and high tonnage by means of a press, whose pressure force is represented in figure 3-B by arrow (p).
  • the temperature causes the resin to become viscous, and thanks to the distribution and size of these fibers, the composite material (5) allows the pressure (p) to be distributed throughout the geometry of the mold (6).
  • FIG. 5A a hypothetical embodiment of a laminated carbon toothed gear (1 ') is observed, that is, obtained by laminating several layers, for example, an anterior (a) an intermediate (b ) and a later one (c) of sheets (4) pre-impregnated with carbon fiber with continuous unidirectional threads (3).
  • Figure 5-B shows a sectional view according to section B-B indicated in Figure 5-A.
  • figures 6-A, 6-B and 6-C the different expected direction of the wires (3) in each of the layers can be observed.
  • the raw material (5) is arranged in the central part of the mold (6) with the shape of the piece without actually covering the edges where the teeth will form (1 a). It can be seen in the detail of figure 7-B how the carbon wires (3) are short and disordered.
  • the toothed gear (1) can be seen, in this case a bicycle chainring, in the final position, once the mold has been closed. It can be seen how the material (5) by pressure moves to the ends of the piece, dragging the short carbon threads (3) into each tooth (1 a), this being the property that makes the toothed gear (1 ) of carbon presents a structural improvement with respect to a laminated gear with sheets of continuous fiber, since the orientation and distribution of the fibers is practically identical to the ideal orientation shown in figure 4-B.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Thermal Sciences (AREA)
  • Moulding By Coating Moulds (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

Disclosed is a toothed gear for bicycles or other systems having a similar transmission in which same is an essential element for transmitting the movement. The toothed gear is formed by a circular part (1) provided radially with a plurality of teeth (1a), wherein the part (1) is made of a discontinuous fibre-reinforced composite (DFC) material produced by compression moulding. Preferably, the part (1) is produced from a portion of composite material (5) formed by a binding, thermostable or thermoplastic polymer matrix (2) and fibre reinforcement consisting of discontinuous and disordered threads (3). Once the part (1) has been produced, the threads (3) are arranged mostly randomly in the centre thereof and in the outer area continuously and concentrically towards each of the teeth (1a).

Description

ENGRANAJE DENTADO PARA BICICLETAS U OTROS SISTEMAS DE TRANSMISIÓN SIMILAR TOOTH GEAR FOR BICYCLES OR OTHER SIMILAR TRANSMISSION SYSTEMS
MEMORIA DESCRIPTIVA DESCRIPTIVE MEMORY
OBJETO DE LA INVENCIÓN OBJECT OF THE INVENTION
La invención, tal como expresa el enunciado de la presente memoria descriptiva, se refiere a un engranaje dentado para bicicletas u otros sistemas de transmisión similar que aporta, a la función a que se destina, ventajas y características, que se describen en detalle más adelante. The invention, as expressed in the statement of this descriptive report, refers to a toothed gear for bicycles or other similar transmission systems that contributes, to the function for which it is intended, advantages and characteristics, which are described in detail later. .
El objeto de la presente invención recae en un engranaje dentado para bicicletas u otros sistemas de transmisión similar en que se constituya como elemento esencial de dicha transmisión del movimiento, que presenta la innovadora particularidad de estar fabricado en fibra de carbono discontinua, u otros materiales compuestos con fibras discontinuas, conocidos como “Discontinous Fiber Composites” (DFC), proporcionando a dicho engranaje las ventajas de una mejor distribución estructural y por lo tanto, mayor resistencia, especialmente en la zona de los dientes, frente a los engranajes de fibra de carbono convencionales (u otros materiales compuestos con fibras) que se utilizan actualmente, y de menor ligereza que sus precedentes metálicos. The object of the present invention falls on a toothed gear for bicycles or other similar transmission systems in which it is constituted as an essential element of said movement transmission, which presents the innovative characteristic of being made of discontinuous carbon fiber, or other composite materials. with discontinuous fibers, known as "Discontinous Fiber Composites" (DFC), providing said gear with the advantages of a better structural distribution and, therefore, greater resistance, especially in the area of the teeth, compared to carbon fiber gears. conventional (or other composite materials with fibers) that are currently used, and less light than their metallic precedents.
CAMPO DE APLICACIÓN DE LA INVENCIÓN FIELD OF APPLICATION OF THE INVENTION
El campo de aplicación de la presente invención se enmarca en el sector de los sistemas de transmisión que incluyan engranajes dentados. The field of application of the present invention falls within the field of transmission systems that include toothed gears.
ANTECEDENTES DE LA INVENCIÓN BACKGROUND OF THE INVENTION
Como es sabido, actualmente las bicicletas incorporan muchas innovaciones que las hacen ser mucho más competitivas. En este sentido, el peso de las partes o elementos de la misma es un factor esencial, sin embargo, se debe garantizar la resistencia necesaria para que cumpla la función prevista. As is known, bicycles currently incorporate many innovations that make them much more competitive. In this sense, the weight of the parts or its elements is an essential factor, however, the necessary resistance must be guaranteed to fulfill its intended function.
Por ello, la fibra de carbono, que es un material ligero y altamente resistente, se utiliza en diversas partes estructurales y mecánicas de una bicicleta. Los procesos de fabricación de piezas de fibra de carbono utilizados actualmente se basan en la utilización de compuestos a partir de láminas que contienen fibras continuas, tejidas o unidireccionales. (Véanse Figuras 2-A y 2-B). For this reason, carbon fiber, which is a lightweight and highly resistant material, is used in various structural and mechanical parts of a bicycle. The manufacturing processes for carbon fiber parts currently used are based on the use of compounds from sheets that contain continuous, woven or unidirectional fibers. (See Figures 2-A and 2-B).
Como es sabido, la fibra de carbono en base epoxi es un material compuesto (composite). Como todos los “composites”, está fabricado a partir de una matriz aglutinante y una fibra de refuerzo. Puesto que su distribución estructural depende de la direccionalidad de las fibras que lo refuerzan, y suelen encontrarse con un orden específico, se trata de un material anisotrópico. (Véase Figuras 1 ). As is known, epoxy-based carbon fiber is a composite material (composite). Like all "composites", it is made from a binder matrix and a reinforcing fiber. Since its structural distribution depends on the directionality of the fibers that reinforce it, and they are usually found in a specific order, it is an anisotropic material. (See Figures 1).
El composite de fibra de carbono en base epoxi es un material que debe pasar por un proceso de curación durante el proceso de manufactura de una pieza. Existen distintas tipologías de material en crudo que pueden adquirirse en función de cada necesidad y proveedor. Epoxy-based carbon fiber composite is a material that must go through a curing process during the manufacturing process of a part. There are different types of raw material that can be purchased depending on each need and supplier.
Las propiedades mecánicas de este material compuesto anisotrópico dependen de la direccionalidad de las fibras que lo refuerzan, en este caso, de la fibra de carbono (refuerzo). Estas fibras, tienen capacidad de soportar grandes esfuerzos axiales a tracción, con muy poca deformación, lo que hace del compuesto un material muy rígido y resistente. The mechanical properties of this anisotropic composite material depend on the directionality of the fibers that reinforce it, in this case, the carbon fiber (reinforcement). These fibers have the capacity to withstand large axial tensile stresses, with very little deformation, which makes the composite a very rigid and resistant material.
Por contra, las fibras no presentan un buen comportamiento a otros esfuerzos como por ejemplo esfuerzos axiales de compresión, flexión o cizalla. En estos casos, el comportamiento estructural de la fibra disminuye y es la matriz (resina epoxi) la que absorbe gran parte de las tensiones, generándose grietas, roturas o quiebros en el material compuesto. Es por esta razón, que, para una correcta fabricación de una pieza de fibra de carbono, es importante prever cómo se direccionarán las fibras, sobre todo en las zonas críticas de la pieza dónde pueda llegar a sufrir esfuerzos más pronunciados. On the contrary, the fibers do not present a good behavior to other stresses such as compression, bending or shear axial stresses. In these cases, the structural behavior of the fiber decreases and it is the matrix (epoxy resin) that absorbs a large part of the stresses, generating cracks, breaks or breaks in the composite material. It is for this reason that, for a correct manufacturing of a carbon fiber part, it is important to anticipate how the fibers will be directed, especially in the critical areas of the part where it may suffer more pronounced stresses.
Los esfuerzos críticos a los que, habitualmente, un engranaje dentado es sometido, se sitúan en el extremo de los dientes, generados por parte de otros elementos del sistema de transmisión como pueden ser una cadena, en dirección tangente al movimiento circular del mismo engranaje, y en sentido contrario a su rotación. The critical stresses to which a toothed gear is usually subjected are located at the end of the teeth, generated by other elements of the transmission system such as a chain, in a tangential direction to the circular movement of the gear itself. and in the opposite direction of its rotation.
Por ello, para que durante la fase más crítica del funcionamiento de un engranaje dentado de fibra de carbono, la estructura de las fibras trabajen óptimamente, la orientación y distribución ideales de dichas fibras debe ser concéntrica a la geometría, tal como se muestra en la figura 4. De lo contrario, cualquier otra orientación de la fibra impedirá que ésta trabaje a tracción, sometiéndola mayohtahamente a esfuerzos de flexión, compresión y cizalla, y por lo tanto, comprometiéndola a ser no óptima. Therefore, so that during the most critical phase of the operation of a carbon fiber toothed gear, the structure of the fibers works optimally, the ideal orientation and distribution of said fibers must be concentric to the geometry, as shown in the figure. figure 4. Otherwise, any other orientation of the fiber will prevent it from working in traction, subjecting it to greater bending, compression and shear stresses, and therefore, compromising it to be non-optimal.
Una de las tipologías más comunes para la producción de piezas técnicas son las láminas de fibra de carbono continuas pre impregnadas con resina o “prepreg”. Se trata de un material que se sirve en laminas, dónde las fibras se encuentran perfectamente ordenadas y dispuestas según un patrón determinado, que puede ser de forma unidireccional, o tejidas entre sí a lo largo de la lámina. La matriz, generalmente resina Epoxi en crudo, aglutina las fibras formando una lámina solidaria. (Véanse Figuras 2-A y 2-B) One of the most common typologies for the production of technical parts are the continuous sheets of carbon fiber pre-impregnated with resin or "prepreg". It is a material that is served in sheets, where the fibers are perfectly ordered and arranged according to a certain pattern, which can be unidirectional, or woven together throughout the sheet. The matrix, generally raw epoxy resin, binds the fibers together, forming a joint sheet. (See Figures 2-A and 2-B)
Para la manufactura de una pieza con láminas de carbono continuo, se debe diseñar un patronaje de la pieza deseada, y plasmarlo sobre dichas láminas pre impregnadas. Una vez obtenidos los patrones, se deben disponer en el molde de la pieza, teniendo en cuenta la direccionalidad de la fibra en cada una de las capas. Finalmente, el molde debe cerrarse con una presión determinada para compactar el material y someterlo a un proceso de curado por temperatura. For the manufacture of a piece with continuous carbon sheets, a pattern must be designed for the desired piece, and mold it onto said pre-impregnated sheets. Once the patterns have been obtained, they must be arranged in the mold of the piece, taking into account the directionality of the fiber in each of the layers. Finally, the mold must be closed with a certain pressure to compact the material and subject it to a temperature curing process.
En algunos casos, la geometría de una pieza no se obtiene solo a partir del laminado, sino que una vez curada una pieza con material sobrante, se mecaniza parcial o totalmente. In some cases, the geometry of a part is not obtained only from the laminate, but once a part is cured with excess material, it is partially or totally machined.
Independientemente de si la pieza es mecanizada a posteriori o no, para que la distribución estructural de una pieza quede correctamente, las distintas capas de carbono continuo que conforman la pieza se disponen direccionadas de forma distinta entre ellas, con el objetivo de que siempre se encuentren fibras en la orientación óptima en las zonas susceptibles de sufrir esfuerzos críticos. Regardless of whether the piece is machined after the fact or not, in order for the structural distribution of a piece to be correct, the different layers of continuous carbon that make up the piece are arranged in a different way between them, with the aim that they always meet. fibers in the optimum orientation in the areas susceptible to critical stresses.
Para la fabricación de un engranaje dentado, o cualquier otra geometría con salientes concéntricos, el uso de láminas de fibra de carbono continua implica que en las zonas salientes (dientes) las fibras de carbono queden mayohtahamente en una orientación no óptima, y recortadas, o bien por el diseño del patronaje, o bien por el mecanizado posterior al curado, anulando en esas zonas el carácter continuado de la fibra, comprometiendo su comportamiento estructural. (Véanse las Figuras 5 y 6). For the manufacture of a toothed gear, or any other geometry with concentric protrusions, the use of sheets of continuous carbon fiber implies that in the protruding areas (teeth) the carbon fibers remain mostly in a non-optimal orientation, and cut, or either by the design of the pattern, or by machining after curing, nullifying the continuous character of the fiber in those areas, compromising its structural behavior. (See Figures 5 and 6).
Por ello, la estructura resultante en los dientes de un engranaje dentado fabricado por el método de laminado de carbono continuo “prepreg” no es la óptima en cuanto a la estructura de las fibras de carbono, ya que la distribución de las fibras quedarían distintas en cada diente de la rueda dentada al tratarse esta de un elemento circular. For this reason, the resulting structure in the teeth of a toothed gear manufactured by the "prepreg" continuous carbon laminate method is not optimal in terms of the structure of the carbon fibers, since the distribution of the fibers would be different in each case. each tooth of the toothed wheel as it is a circular element.
Otro tipo de fabricación, mucho menos común de piezas de fibra de carbono es el moldeo por compresión DFC (Discontinous Fiber Composites). Habitualmente, este grupo de materiales se sirven como un compuesto de fibras discontinuas de carbono, también preimpregnadas con un aglutinante (matriz), generalmente resina Epoxi, en formato de lámina o SMC (Sheet Molding Compund) o bien en formato de masa o BMC (Bulk Molding Compound). Las fibras de carbono en estos compuestos son más cortas (según proveedor) y se encuentran dispuestas aleatoriamente, haciendo una mezcla homogénea y no ordenada, con una distribución estructural más semejable a la de un material ¡sotrópico. (Véanse Figuras 2-C y 2-D) Another, much less common type of manufacturing of carbon fiber parts is DFC (Discontinous Fiber Composites) compression molding. Usually, this group of materials is served as a composite of discontinuous carbon fibers, also pre-impregnated with a binder (matrix), generally Epoxy resin, in sheet format or SMC (Sheet Molding Compund) or in mass format or BMC (Bulk Molding Compound). The carbon fibers in these composites are shorter (depending on the supplier) and are randomly arranged, making a homogeneous and non-ordered mixture, with a structural distribution more similar to that of an isotropic material. (See Figures 2-C and 2-D)
La manufactura mediante compuestos de fibras discontinuas (DFC) se realiza con un molde específico, dispuesto de un sistema de calefacción, accionado con una prensa. Dicho molde dispone esencialmente de dos elementos, la mitad de cavidad y la mitad de fuerza o punzón que, por sus características, ejercen una presión determinada en el material, permitiendo que éste conforme la geometría de la pieza deseada. Manufacturing using discontinuous fiber composites (DFC) is carried out with a specific mould, fitted with a heating system, activated by a press. Said mold essentially has two elements, the cavity half and the force or punch half which, due to their characteristics, exert a certain pressure on the material, allowing it to conform to the geometry of the desired part.
En el moldeo por compresión de DFC, una carga de material en crudo, de masa y volumen determinados, se coloca en la mitad de cavidad del molde. El sistema de calefacción del molde permite que, con la temperatura, la resina aglutinante del compuesto se vuelva viscosa. Mediante una prensa, la mitad de fuerza del molde o punzón se introduce en la mitad de cavidad transmitiendo una alta presión al material y, gracias a la distribución y tamaño de las fibras discontinuas, el material compuesto es repartido a lo largo de toda la geometría del molde, pudiéndose llenar geometrías complejas. (Véanse Figuras 3-A, 3-B y 3-C) In DFC compression molding, a charge of raw material, of given mass and volume, is placed in the middle of the mold cavity. The mold's heating system allows the binder resin in the compound to become viscous with temperature. Using a press, half the force of the mold or punch is introduced into half the cavity, transmitting high pressure to the material and, thanks to the distribution and size of the discontinuous fibers, the composite material is distributed along the entire geometry. of the mold, being able to fill complex geometries. (See Figures 3-A, 3-B and 3-C)
El objetivo de la presente invención es, pues, proporcionar al mercado un engranaje dentado con las ventajas de la fibra de carbono producida mediante el moldeo por compresión de DFC, mejorando el comportamiento de este material en las zonas críticas de la pieza, como son la de los dientes. The objective of the present invention is, therefore, to provide the market with a toothed gear with the advantages of carbon fiber produced by DFC compression molding, improving the behavior of this material in critical areas of the part, such as the of the teeth.
Por otra parte, y como referencia al estado actual de la técnica, al menos por parte del solicitante, se desconoce la existencia de ningún otro engranaje dentado de carbono para bicicleta, ni ninguna otra invención de aplicación similar, que presente unas características técnicas, y constitutivas ¡guales o semejantes a las que presenta el que aquí se reivindica. EXPLICACIÓN DE LA INVENCIÓN On the other hand, and as a reference to the current state of the art, at least by the applicant, the existence of any other carbon toothed gear for bicycles is unknown, nor any other invention of similar application, which presents technical characteristics, and constitutive equal or similar to those presented by the one claimed here. EXPLANATION OF THE INVENTION
El engranaje dentado que la invención propone se configura como la solución idónea al objetivo anteriormente señalado, estando los detalles caracteñzadores que lo hacen posible y que lo distinguen convenientemente recogidos en las reivindicaciones finales que acompañan a la presente descripción. The toothed gear that the invention proposes is configured as the ideal solution to the aforementioned objective, with the characteristic details that make it possible and that distinguish it conveniently included in the final claims that accompany this description.
Concretamente, lo que la invención propone, como se ha apuntado anteriormente, es un engranaje dentado para bicicletas u otros sistemas de transmisión similar, el cual se distingue por estar fabricado por moldeo por compresión de materiales compuestos de fibra discontinua también conocidos como DFC, preferentemente de fibra de carbono discontinua. Specifically, what the invention proposes, as previously noted, is a toothed gear for bicycles or other similar transmission systems, which is distinguished by being manufactured by compression molding of discontinuous fiber composite materials also known as DFC, preferably discontinuous carbon fiber.
Más concretamente, dicha pieza es apta para constituir un engranaje dentado gracias a que el material de fibra de carbono, en lugar de ser laminado capa por capa y estar constituido por capas de fibras continuas con hilos de carbono dispuestos unidireccionalmente y/o tejidos, como sería lo habitual, está conformado mediante moldeo por compresión de un compuesto de fibras discontinuas entre sí, donde las fibras son arrastradas, por la presión ejercida dentro del molde, hasta la cavidad interior de cada uno de los dientes del engranaje. More specifically, said part is suitable for constituting a toothed gear thanks to the fact that the carbon fiber material, instead of being laminated layer by layer and made up of layers of continuous fibers with carbon threads arranged unidirectionally and/or woven, as It would be usual, it is made by compression molding a compound of discontinuous fibers together, where the fibers are dragged, by the pressure exerted inside the mold, up to the interior cavity of each one of the gear teeth.
Con ello se consigue ventajosamente que el engranaje presente una mejora estructural respecto a un engranaje laminado con fibra continua, ya que la orientación y distribución de las fibras, obtenida gracias a la presión que el molde proporciona, se corresponde con gran similitud a la orientación estructural de fibras ideal descrita en la Figura 4-B, que deben tener para que presenten un comportamiento óptimo frente a los esfuerzos a los que un engranaje es sometido. With this, it is advantageously achieved that the gear presents a structural improvement with respect to a gear laminated with continuous fiber, since the orientation and distribution of the fibers, obtained thanks to the pressure that the mold provides, corresponds very similarly to the structural orientation. of ideal fibers described in Figure 4-B, which they must have in order for them to present optimal behavior in the face of the efforts to which a gear is subjected.
DESCRIPCIÓN DE LOS DIBUJOS Para complementar la descripción que se está realizando y con objeto de ayudar a una mejor comprensión de las características de la invención, se acompaña a la presente memoria descriptiva, como parte integrante de la misma, un juego de planos en los que con carácter ilustrativo y no limitativo se ha representado lo siguiente: DESCRIPTION OF THE DRAWINGS To complement the description that is being made and in order to help a better understanding of the characteristics of the invention, this specification is attached, as an integral part of it, a set of drawings in which, for illustrative and non-limiting, the following has been represented:
La figura número 1 Muestra una vista esquemática de la representación de las partes que conforman el material constitutivo de la fibra de carbono u otro material compuesto de fibras como refuerzo; las figuras número 2-A, 2-B, 2-C y 2-D.- Muestran una representación esquemática de las distintas tipologías de fibra de carbono con resina pre impregnada que pueden encontrarse de forma comercial; las figuras número 3-A, 3-B y 3-C.- Muestran sendas vistas esquemáticas de las fases de moldeo por compresión de DFC, mostrando respectivamente la disposición inicial del material en el centro del molde y la disposición repartida del mismo por todo el molde tras haber recibido presión; las figuras número 4-A y 4-B.- Muestran, respectivamente, una representación esquemática de un engranaje dentado con la cadena, y el detalle A ampliado de la zona dentada mostrando, mediante líneas de doble flecha, la orientación ideal de las fibras y, mediante flecha negrita, la fuerza que ejerce la cadena sobre los dientes; las figuras número 5-A y 5-B.- Muestran sendas vistas, en alzado y sección respectivamente de un ejemplo de engranaje dentado, según una hipotética realización del engranaje obtenido mediante laminado; las figuras número 6-A, 6-B y 6-C.- Muestran respectivas vistas de las diferentes capas de laminado que comprende el engranaje de la figura 5-B, apreciándose las diferentes orientaciones de las fibras entre capas, siendo unidireccionales cada una de ellas; las figuras número 7-A, 7-B.- Muestran, respectivamente, una vista en alzado de la representación de la disposición inicial del material crudo en el centro de la pieza para la obtención del engranaje dentado de fibra de carbono con SMC, según la invención, y el detalle ampliado de dicho material con hilos cortos desordenados en distintas orientaciones; y las figuras número 8-A y 8-B.- Muestran, respectivamente, una vista en alzado de la pieza obtenida conformante del engranaje dentado de carbono objeto de la invención, y un detalle ampliado de la zona de los dientes, donde se muestra la orientación de las fibras. Figure number 1 Shows a schematic view of the representation of the parts that make up the material constituting the carbon fiber or other fiber composite material as reinforcement; Figures number 2-A, 2-B, 2-C and 2-D.- Show a schematic representation of the different types of carbon fiber with pre-impregnated resin that can be found commercially; Figures number 3-A, 3-B and 3-C.- Show respective schematic views of the DFC compression molding phases, showing respectively the initial arrangement of the material in the center of the mold and its distributed arrangement throughout the mold after having received pressure; figures number 4-A and 4-B.- Show, respectively, a schematic representation of a toothed gear with the chain, and enlarged detail A of the toothed area showing, by means of double arrow lines, the ideal orientation of the fibers and, by means of a bold arrow, the force exerted by the chain on the teeth; Figures number 5-A and 5-B.- Show respective views, in elevation and section, respectively, of an example of toothed gear, according to a hypothetical embodiment of the gear obtained by rolling; Figures number 6-A, 6-B and 6-C.- Show respective views of the different layers of laminate comprising the gear of Figure 5-B, appreciating the different orientations of the fibers between layers, each of them being unidirectional; Figures number 7-A, 7-B.- Show, respectively, an elevation view of the representation of the initial arrangement of the raw material in the center of the piece to obtain the carbon fiber toothed gear with SMC, according to the invention, and the enlarged detail of said material with disordered short threads in different orientations; and figures number 8-A and 8-B.- They show, respectively, an elevation view of the part obtained that makes up the carbon toothed gear object of the invention, and an enlarged detail of the area of the teeth, where it is shown the orientation of the fibers.
REALIZACIÓN PREFERENTE DE LA INVENCIÓN PREFERRED EMBODIMENT OF THE INVENTION
A la vista de las mencionadas figuras, y de acuerdo con la numeración adoptada, se puede observar en ellas que lo que la invención propone es un engranaje dentado para bicicletas u otros sistemas de transmisión similar, constituido a partir de una pieza (1 ) circular dotada radialmente de una pluralidad de dientes (1 a), se distingue por el hecho de que dicha pieza (1 ) es de un material compuesto con fibras de refuerzo discontinuas, conocido de DFC (material compuesto de fibras discontinuas), preferentemente de fibras discontinuas de carbono, obtenida mediante moldeo por compresión o compresión molding. In view of the aforementioned figures, and in accordance with the numbering adopted, it can be seen that what the invention proposes is a toothed gear for bicycles or other similar transmission systems, made from a circular part (1). Radially equipped with a plurality of teeth (1 a), it is distinguished by the fact that said part (1) is made of a composite material with discontinuous reinforcing fibers, known as DFC (discontinuous fiber composite material), preferably discontinuous fibers carbon, obtained by compression molding or compression molding.
De preferencia, dicha pieza (1 ) es obtenida a partir una porción de material compuesto (5) formado por una matriz poliméhca (2) aglutinante, termoestable o termoplástica, y refuerzo de fibras, normalmente de carbono, consistente en hilos (3) discontinuos y desordenados, cuyos hilos (3), una vez obtenida la pieza (1 ), quedan orientados mayohtariamente de forma aleatoria en el centro de dicha pieza y de una manera continua y concéntrica hacia cada uno de los dientes (1 a). El material se coloca en el molde con una disposición aleatoria, y mediante la compresión del molde en la zona central el material sigue quedando en esta posición aportando un comportamiento cuasi Isotropico, pero en la zona de los dientes, el material se empuja quedando las fibras orientadas concéntricamente y más continua con la forma de los dientes. Preferably, said piece (1) is obtained from a portion of composite material (5) formed by a binder, thermosetting or thermoplastic polymeric matrix (2), and fiber reinforcement, normally carbon, consisting of discontinuous threads (3). and disordered, whose threads (3), once the part (1) is obtained, are oriented mostly randomly in the center of said part and in a continuous and concentric way towards each of the teeth (1 a). The material is placed in the mold in a random arrangement, and by compressing the mold in the central area, the material continues to remain in this position, providing a quasi-isotropic behavior, but in the area of the teeth, the material is pushed, leaving the fibers concentrically oriented and more continuous with the shape of the teeth.
Atendiendo a la figura 1 se observa, representado de manera esquemática, cómo la fibra de carbono con que está fabricado el engranaje dentado (1 ) de la invención es un material compuesto de una matriz aglutinante (2), habitualmente resina termoestable epoxi, y un refuerzo estructural consistente en fibra o hilos (3) de carbono. Considering figure 1, it can be seen, schematically represented, how the carbon fiber with which the toothed gear (1) of the invention is made is a material composed of a binder matrix (2), usually epoxy thermosetting resin, and a structural reinforcement consisting of carbon fiber or threads (3).
En las figuras número 2-A, 2-B, 2-C y 2-D se aprecian, de manera esquemática las distintas tipologías de fibra de carbono con resina pre impregnada que pueden encontrarse de forma comercial. Figures 2-A, 2-B, 2-C and 2-D show, schematically, the different types of carbon fiber with pre-impregnated resin that can be found commercially.
En la figura 2-A se aprecia cómo, en un ejemplo de lámina (4) UD (uní direccional), los hilos (3) de fibra de carbono son continuos y están todos orientados en la misma dirección. Figure 2-A shows how, in an example of a UD (unidirectional) sheet (4), the carbon fiber threads (3) are continuous and are all oriented in the same direction.
En la figura 2-B se aprecia cómo, en otro ejemplo de lámina (4), los hilos (3) de fibra de carbono son continuos y se encuentran entrelazados entre sí de forma ordenada. Figure 2-B shows how, in another example of sheet (4), the carbon fiber threads (3) are continuous and intertwined in an orderly fashion.
En la figura 2-C se aprecia cómo, en otro ejemplo de lámina (4) de fibras discontinuas (SMC), los hilos (3) de fibra de carbono son discontinuos, de longitud determinada y se encuentran desordenados a lo largo de toda la lámina. In figure 2-C it can be seen how, in another example of sheet (4) of discontinuous fibers (SMC), the carbon fiber threads (3) are discontinuous, of a determined length and are disordered throughout the entire length of the sheet. leaf.
Y en la figura 2-D se aprecia cómo, en un ejemplo de masa de fibras discontinuas (BMC), los hilos (3) de fibra de carbono son discontinuos, de longitud determinada y se encuentran desordenados a lo largo de toda una masa (2) que los aglutina, generalmente resina Epoxi. Por su parte, atendiendo a las figuras número 3-A, 3-B y 3-C se aprecian de manera esquemática, las fases de moldeo por compresión de DFC, mostrando respectivamente la disposición inicial del material en el centro del molde y la disposición repartida del mismo por todo el molde tras haber recibido presión. And in figure 2-D it can be seen how, in an example of a mass of discontinuous fibers (BMC), the carbon fiber threads (3) are discontinuous, of a determined length and are disordered throughout a mass ( 2) that binds them together, generally Epoxy resin. On the other hand, looking at figures 3-A, 3-B and 3-C, the DFC compression molding phases can be seen schematically, showing respectively the initial arrangement of the material in the center of the mold and the arrangement distributed throughout the mold after receiving pressure.
En este caso, para la obtención de las piezas, se coloca dicho material (5) en el molde (6) en la cantidad de volumen necesaria, y es sometido a elevada temperatura y a un alto tonelaje mediante una prensa, cuya fuerza de presión está representada en la figura 3-B mediante flecha (p). La temperatura hace que la resina se vuelva viscosa, y gracias a la distribución y tamaño de estas fibras, el material (5) compuesto permite que con la presión (p) se pueda repartir por toda la geometría del molde (6). In this case, to obtain the pieces, said material (5) is placed in the mold (6) in the amount of volume required, and is subjected to high temperature and high tonnage by means of a press, whose pressure force is represented in figure 3-B by arrow (p). The temperature causes the resin to become viscous, and thanks to the distribution and size of these fibers, the composite material (5) allows the pressure (p) to be distributed throughout the geometry of the mold (6).
Atendiendo a las figuras 4-A y 4-B se observa cómo, en el caso de un engranaje dentado (1 ) para bicicleta donde los dientes (1 a) verán tensionados por la cadena (7), para que los hilos (3) reciban mayormente fuerzas de tracción, la posición ideal de los mismos sería radial en el centro de la pieza y de forma continua hacia cada uno de los dientes (1 a), tal como muestra la línea de trazo representada en la figura 4-B. Looking at figures 4-A and 4-B, it can be seen how, in the case of a toothed gear (1) for a bicycle where the teeth (1 a) will be tensioned by the chain (7), so that the threads (3) receive the most traction forces, their ideal position would be radial in the center of the part and continuously towards each of the teeth (1 a), as shown by the traced line represented in figure 4-B.
Atendiendo a las figuras 5-A y 5-B, se observa una hipotética realización de engranaje dentado de carbono laminado (1 ’), es decir, obtenido mediante laminado de varias capas, por ejemplo, una anterior (a) una intermedia (b) y una posterior (c) de láminas (4) pre impregnadas de fibra de carbono con hilos (3) continuos unidireccionales. La figura 5-B muestra una vista en sección según el corte B-B señalado en la figura 5-A. Y en las figuras 6-A, 6-B y 6-C se observa la distinta dirección prevista de los hilos (3) en cada una de las capas. Considering figures 5-A and 5-B, a hypothetical embodiment of a laminated carbon toothed gear (1 ') is observed, that is, obtained by laminating several layers, for example, an anterior (a) an intermediate (b ) and a later one (c) of sheets (4) pre-impregnated with carbon fiber with continuous unidirectional threads (3). Figure 5-B shows a sectional view according to section B-B indicated in Figure 5-A. And in figures 6-A, 6-B and 6-C the different expected direction of the wires (3) in each of the layers can be observed.
Como se puede apreciar, aunque se combinen las tres capas (a, b, c), representadas en las figuras 6-A, 6-B y 6-C, las fibras o hilos (3) de carbono no se distribuyen como el caso ideal que muestra la figura 4-B, por lo que se fuerza al material a trabajar de un modo no óptimo. Además, con el corte de las láminas a distintas angulaciones, la mayoría de las fibras o hilos (3) que quedan en la zona de los dientes (1 a), que es la parte crítica de la pieza, están cortadas y carecen de continuidad con el conjunto, comprometiendo el carácter estructural del composite. As can be seen, even if the three layers (a, b, c) are combined, represented in figures 6-A, 6-B and 6-C, the carbon fibers or threads (3) are not distributed as is the case. ideal shown in Figure 4-B, so it is forced to the material to be worked in a non-optimal way. In addition, with the cutting of the sheets at different angles, most of the fibers or threads (3) that remain in the area of the teeth (1 a), which is the critical part of the piece, are cut and lack continuity. with the whole, compromising the structural character of the composite.
Atendiendo a las figuras 7-A a 8-B, se observa cómo, cuando el engranaje dentado (1 ), como es el caso del engranaje objeto de la presente invención, consiste en una pieza de material compuesto obtenida mediante moldeo por compresión de DFC, se consigue que las fibras o hilos (3) de carbono sigan la orientación ideal mostrada en la figura 4-B. Considering figures 7-A to 8-B, it can be seen how, when the toothed gear (1), as is the case of the gear object of the present invention, consists of a piece of composite material obtained by compression molding of DFC , it is achieved that the carbon fibers or threads (3) follow the ideal orientation shown in figure 4-B.
Más concretamente, como se ve en las figuras 7-A y 7-B, en una instancia inicial, el material (5) crudo se dispone en la parte central del molde (6) con la forma de la pieza sin llegar a cubrir los bordes donde se formarán los dientes (1 a). Se puede apreciar en el detalle de la figura 7-B cómo los hilos (3) de carbono son cortos y están desordenados. More specifically, as can be seen in figures 7-A and 7-B, in an initial instance, the raw material (5) is arranged in the central part of the mold (6) with the shape of the piece without actually covering the edges where the teeth will form (1 a). It can be seen in the detail of figure 7-B how the carbon wires (3) are short and disordered.
Por último, atendiendo a las figuras 8-A y 8-B se puede observar el engranaje dentado (1 ), en este caso un plato de bicicleta, en la posición final, una vez cerrado el molde. Se aprecia cómo el material (5) por presión se desplaza hasta los extremos de la pieza, arrastrando los hilos (3) cortos de carbono hacia adentro de cada diente (1 a), siendo esta la propiedad que hace que el engranaje dentado (1 ) de carbono presente una mejora estructural respecto a un engranaje laminado con láminas de fibra continua, ya que la orientación y distribución de las fibras es prácticamente idéntica a la orientación ideal que se muestra en la figura 4-B. Finally, looking at figures 8-A and 8-B, the toothed gear (1) can be seen, in this case a bicycle chainring, in the final position, once the mold has been closed. It can be seen how the material (5) by pressure moves to the ends of the piece, dragging the short carbon threads (3) into each tooth (1 a), this being the property that makes the toothed gear (1 ) of carbon presents a structural improvement with respect to a laminated gear with sheets of continuous fiber, since the orientation and distribution of the fibers is practically identical to the ideal orientation shown in figure 4-B.
Descrita suficientemente la naturaleza de la presente invención, así como la manera de ponerla en práctica, no se considera necesario hacer más extensa su explicación para que cualquier experto en la materia comprenda su alcance y las ventajas que de ella se derivan. Having sufficiently described the nature of the present invention, as well as the way of putting it into practice, it is not considered necessary to make its explanation more extensive so that any expert in the field understands its scope and the advantages derived from it.

Claims

REIVINDICACIONES 1 Engranaje dentado para bicicletas u otros sistemas de transmisión similar en que se constituya como elemento esencial de dicha transmisión del movimiento, que, constituido a partir de una pieza (1 ) circular dotada radialmente de una pluralidad de dientes (1 a), está caracterizado por el hecho de que dicha pieza CLAIMS 1 Toothed gear for bicycles or other similar transmission systems in which it is constituted as an essential element of said movement transmission, which, constituted from a circular part (1) radially equipped with a plurality of teeth (1 a), is characterized by the fact that said piece
(1 ) es de un material compuesto de fibras de refuerzo discontinuas o DFC obtenida mediante moldeo por compresión. (1) is a composite material of discontinuous reinforcing fibers or DFC obtained by compression molding.
2.- Engranaje dentado para bicicletas u otros sistemas de transmisión similar, según la reivindicación 1 , caracterizado porque dicha pieza (1 ) es obtenida a partir una porción de material compuesto (5) formado por una matriz poliméhca2. Toothed gear for bicycles or other similar transmission systems, according to claim 1, characterized in that said part (1) is obtained from a portion of composite material (5) formed by a polymeric matrix.
(2) aglutinante, termoestable o termoplástica, y refuerzo de fibras consistente en hilos (3) discontinuos y desordenados, cuyos hilos (3), una vez obtenida la pieza (1 ), quedan orientados mayohtahamente de forma aleatoria en el centro de dicha pieza y en la zona exterior de una manera continua y concéntrica hacia cada uno de los dientes (1 a). . (2) binder, thermosetting or thermoplastic, and fiber reinforcement consisting of discontinuous and disordered threads (3), whose threads (3), once the piece (1) is obtained, are oriented mostly randomly in the center of said piece and in the outer zone in a continuous and concentric way towards each of the teeth (1 a). .
3.- Engranaje dentado para bicicletas u otros sistemas de transmisión similar, según la reivindicación 1 ó 2, caracterizado porque las fibras de refuerzo discontinuas del material compuesto de la piza (1 ) son de carbono. 3. Toothed gear for bicycles or other similar transmission systems, according to claim 1 or 2, characterized in that the discontinuous reinforcing fibers of the composite material of the piece (1) are made of carbon.
PCT/ES2023/070120 2022-03-03 2023-03-03 Toothed gear for bicycles or other systems having a similar transmission WO2023166240A1 (en)

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ES202230358U ES1289256Y (en) 2022-03-03 2022-03-03 TOOTHED GEAR FOR BICYCLES OR OTHER SIMILAR TRANSMISSION SYSTEMS
ESU202230358 2022-03-03

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55134108A (en) * 1979-04-06 1980-10-18 Toyota Motor Corp Production of gear by powder metallurgy
CN101421340A (en) * 2006-02-24 2009-04-29 东丽株式会社 Fiber-reinforced thermoplastic resin molded article, molding material, and method for production of the molded article
CN107380340A (en) * 2016-04-11 2017-11-24 福克斯制造有限公司 Bicycle front wheel
US20200200253A1 (en) * 2018-12-18 2020-06-25 Fox Factory, Inc. Chainring
CN212709833U (en) * 2020-07-09 2021-03-16 深圳市健坤运动器材有限公司 Carbon fiber alclad structure tooth piece

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55134108A (en) * 1979-04-06 1980-10-18 Toyota Motor Corp Production of gear by powder metallurgy
CN101421340A (en) * 2006-02-24 2009-04-29 东丽株式会社 Fiber-reinforced thermoplastic resin molded article, molding material, and method for production of the molded article
CN107380340A (en) * 2016-04-11 2017-11-24 福克斯制造有限公司 Bicycle front wheel
US20200200253A1 (en) * 2018-12-18 2020-06-25 Fox Factory, Inc. Chainring
CN212709833U (en) * 2020-07-09 2021-03-16 深圳市健坤运动器材有限公司 Carbon fiber alclad structure tooth piece

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