WO2023074572A1 - 光学積層体、光学装置、光学積層体の製造方法 - Google Patents

光学積層体、光学装置、光学積層体の製造方法 Download PDF

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Publication number
WO2023074572A1
WO2023074572A1 PCT/JP2022/039303 JP2022039303W WO2023074572A1 WO 2023074572 A1 WO2023074572 A1 WO 2023074572A1 JP 2022039303 W JP2022039303 W JP 2022039303W WO 2023074572 A1 WO2023074572 A1 WO 2023074572A1
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Prior art keywords
group
optical
main surface
optical sheet
adhesive
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Ceased
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PCT/JP2022/039303
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English (en)
French (fr)
Japanese (ja)
Inventor
達也 鈴木
香 溝端
香織 新家
哲士 本田
亜樹子 田中
瑞穂 水野
繁樹 石黒
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Nitto Denko Corp
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Nitto Denko Corp
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Priority to US18/705,050 priority Critical patent/US20250035833A1/en
Priority to JP2023556399A priority patent/JPWO2023074572A1/ja
Priority to CN202280072458.0A priority patent/CN118176454A/zh
Priority to EP22886899.8A priority patent/EP4425248A4/en
Priority to KR1020247013731A priority patent/KR20240101562A/ko
Publication of WO2023074572A1 publication Critical patent/WO2023074572A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033—Means for improving the coupling-out of light from the light guide
    • G02B6/005—Means for improving the coupling-out of light from the light guide provided by one optical element, or plurality thereof, placed on the light output side of the light guide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/023—Optical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033—Means for improving the coupling-out of light from the light guide
    • G02B6/0035—Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
    • G02B6/0036—2-D arrangement of prisms, protrusions, indentations or roughened surfaces
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24—Coupling light guides
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336—Illuminating devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/42—Polarizing, birefringent, filtering
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/02—Diffusing elements; Afocal elements
    • G02B5/0205—Diffusing elements; Afocal elements characterised by the diffusing properties
    • G02B5/021—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures
    • G02B5/0231—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures the surface having microprismatic or micropyramidal shape
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/04—Prisms
    • G02B5/045—Prism arrays

Definitions

  • the present invention relates to an optical laminate and an optical device having such an optical laminate.
  • Optical sheets e.g., microlens sheets, prism sheets, brightness enhancement films (e.g., 3M Brightness Enhancement Film: BEF, (registered trademark)) are used in various optical devices (e.g., display devices and lighting devices).
  • the term "optical sheet” is not limited to the above examples, but broadly includes sheet-like optical members, and further includes, for example, diffusion plates and light guide plates.
  • sheet-like is used to include plate-like or film-like forms, regardless of the rigidity (flexibility) and thickness of the sheet.
  • Optical sheets are attached to other optical sheets or optical devices using, for example, an adhesive layer.
  • optical laminate refers to a configuration including an optical sheet and an adhesive layer or a configuration including a plurality of optical sheets.
  • adhesive is used to include pressure-sensitive adhesives (also referred to as “pressure-sensitive adhesives”).
  • Patent Document 1 discloses in Patent Document 1 an optical laminate (referred to as an "optical laminate sheet” in Patent Document 1) that can be used in display devices and lighting devices.
  • the optical laminate of Patent Document 1 has an optical sheet (for example, a microlens sheet) having an uneven structure on its surface, and an adhesive layer provided on the surface having an uneven structure. 5% to 90% of the height of the projections of the uneven structure is filled with the adhesive layer.
  • the adhesive layer is formed from an adhesive composition containing a graft polymer obtained by graft-polymerizing a chain containing a cyclic ether group-containing monomer to a (meth)acrylic polymer and a photocationic polymerization initiator or a thermosetting catalyst.
  • Patent Documents 2 and 3 disclose a light distribution structure that can be used in display devices and lighting devices and that utilizes total reflection by interfaces of a plurality of air cavities (internal spaces). By using the light distribution structures disclosed in Patent Documents 2 and 3, the degree of freedom and accuracy of light distribution control can be improved.
  • the inventor of the present invention forms the light distribution structure described in Patent Documents 2 and 3 by disposing an adhesive layer on a surface having an uneven structure of an optical sheet having an uneven structure on the surface and an adhesive layer on the surface having an uneven structure. I considered.
  • the shape and volume of the plurality of air cavities that constitute the light distribution structure change depending on the extent to which the adhesive layer penetrates into the recesses of the uneven structure, and as a result, the characteristics of the light distribution structure are affected. . Therefore, it is required to prevent the adhesive layer from entering the concave portions of the concave-convex structure.
  • the present invention has been made to solve the above problems, and an optical sheet laminated with other optical sheets without substantially affecting the shape and volume of the recesses on the surface having the uneven structure of the optical sheet. It is an object of the present invention to provide a laminate and an optical device having such an optical laminate and/or to provide a method for manufacturing such an optical laminate.
  • a first optical sheet having a first main surface having an uneven structure and a second main surface opposite to the first main surface; a second optical sheet having a third main surface disposed on the first main surface side of the first optical sheet;
  • the uneven structure of the first main surface includes a plurality of recesses and a flat portion between two recesses adjacent to each other among the plurality of recesses,
  • the optical laminate, wherein the flat portion of the first principal surface and the third principal surface are covalently bonded via a molecular adhesive.
  • the distance from the opening surface defined by the opening of the recess to the deepest part of the recess is defined as A, and the third optical sheet of the second optical sheet that enters the recess from the opening surface is used.
  • a first optical sheet having a first main surface having an uneven structure and a second main surface opposite to the first main surface; a second optical sheet having a third main surface disposed on the first main surface side of the first optical sheet;
  • the uneven structure of the first main surface includes a plurality of recesses and a flat portion between two recesses adjacent to each other among the plurality of recesses, For each of the plurality of recesses, the distance from the opening surface defined by the opening of the recess to the deepest part of the recess is defined as A, and the third optical sheet of the second optical sheet that enters the recess from the opening surface is used.
  • B/A is 0.2 or less
  • the optical laminate, wherein the distance between the flat portion and the third main surface does not exceed 500 nm.
  • the flat portion and the third main surface have at least one reactive group selected from the group consisting of hydrocarbon groups, carbonyl groups, and hydroxyl groups, forming a covalent bond with the molecular adhesive.
  • E is an arbitrary group.
  • F is an OH group or an OH yielding group.
  • -Q is -N 3 or -NR 1 (R 2 ).
  • R 1 and R 2 of —NR 1 (R 2 ) are H, a hydrocarbon group having 1 to 24 carbon atoms, or —RSi(R′)n(OA)3-n (R has 1 carbon is a chain hydrocarbon group of up to 12.
  • R' is a chain hydrocarbon group having 1 to 4 carbon atoms
  • A is H or a chain hydrocarbon group having 1 to 4 carbon atoms.
  • n is an integer from 0 to 2).
  • R 1 and R 2 may be the same or different.
  • an optical laminate laminated with another optical sheet and such an optical laminate without substantially affecting the shape and volume of the recesses on the surface having the uneven structure of the optical sheet An optical device is provided. Also, according to embodiments of the present invention, a method for manufacturing such an optical stack is provided.
  • FIG. 1 is a schematic cross-sectional view of an optical laminate 100 according to an embodiment of the invention
  • FIG. 1 is a schematic partial cross-sectional view of an optical layered body 100
  • FIG. FIG. 4 is a schematic partial cross-sectional view of an optical layered body 200 of a comparative example
  • 1 is a schematic plan view of a first optical sheet 10a included in an optical layered body according to an embodiment of the present invention
  • FIG. 4B is a schematic cross-sectional view along line 4B-4B' of the first optical sheet 10a shown in FIG. 4A;
  • optical layered body according to an embodiment of the present invention, an optical device having the optical layered body, and a method for manufacturing the optical layered body will be described.
  • Embodiments of the present invention are not limited to those exemplified below.
  • FIG. 1 shows a schematic cross-sectional view of an optical layered body 100 according to an embodiment of the present invention.
  • the optical laminate 100 includes a first optical sheet 10 having a first principal surface 12s having an uneven structure and a second principal surface 18s opposite to the first principal surface 12s, and the first principal surface 12s of the first optical sheet 10. and a second optical sheet 30 having a third major surface 32s disposed on the side thereof.
  • the second optical sheet 30 has a fourth principal surface 38s opposite to the third principal surface 32s.
  • the concave-convex structure of the first main surface 12 s includes a plurality of recesses 14 and flat portions 10 s between adjacent recesses 14 among the plurality of recesses 14 .
  • the third major surface 32s is flat, and the flat portion 10s of the first major surface 12s and the third major surface 32s are covalently bonded via the molecular adhesive 20. As shown in FIG.
  • a plurality of internal spaces 14a are defined by each of the plurality of recesses 14 of the first main surface 12s of the first optical sheet 10a and the third main surface 32s of the second optical sheet.
  • the internal space 14a is typically a void filled with air.
  • the internal space 14a may be filled with a material having a lower refractive index than the first optical sheet 10a and the second optical sheet 30 instead of air.
  • the interface formed by the internal space 14 a can cause total internal reflection (TIR) of light propagating through the optical laminate 100 .
  • the flat portion 10s and the second main surface 18s of the first main surface 12s of the first optical sheet 10, and the third main surface 32s and the fourth main surface 38s of the second optical sheet 30 are parallel to the XY plane.
  • light propagating in the -Y direction inside the second optical sheet 30 is totally internally reflected by the plurality of internal spaces 14a and directed in the Z direction orthogonal to the XY plane.
  • the first optical sheet 10 and the second optical sheet 30 are preferably made of a resin having light transmittance.
  • resin is used in a broad sense including thermoplastic resins, curable resins, elastomers and rubbers.
  • Curable resins include, for example, thermosetting resins, photocurable resins, and electron beam curable resins.
  • the resin has, for example, C—H bonds or Si—O bonds.
  • thermoplastic resins examples include cellulose-based resins such as triacetyl cellulose (TAC), polyester-based, polyvinyl alcohol-based, polycarbonate-based, polyamide-based, polyimide-based, polyethersulfone-based, polysulfone-based, polystyrene-based, Transparent resins such as polynorbornene-based, polyolefin-based, (meth)acrylic-based, and acetate-based resins can be used.
  • thermosetting resins include epoxy resins, phenol resins, and polyester resins.
  • photocurable resins examples include monomers (including oligomers) having a vinyl group, an acrylate group (including a methacrylate group), an epoxy group, an isocyanate group, or an oxetane group.
  • monomers include urethane acrylate, epoxy acrylate, ester acrylate, epoxy and vinyl ether monomers.
  • the first optical sheet 10 and the second optical sheet 30 are selected in consideration of reactivity with the molecular adhesive 20. That is, the material of the first optical sheet 10 and the second optical sheet 30 is such that at least the flat portion 10s of the first main surface 12s and the third main surface 32s can form a covalent bond through the molecular adhesive 20. is selected. If necessary, at least the flat portion 10s of the first main surface 12s and/or the third main surface 32s may be surface-modified (for example, hydroxyl groups are introduced by corona treatment).
  • the flatness of the flat portion 10s of the first main surface 12s and the third main surface 32s is preferably, for example, a surface roughness Ra of 20 nm or less, more preferably 10 nm or less, as measured by an atomic force microscope. 5 nm or less is more preferable.
  • the surface roughness Ra of the flat portion of the shaping film used in the example was about 3.9 nm, and the surface roughness Ra of the flat resin film was about 1.5 nm.
  • a resin film having a flat third main surface 32s is exemplified.
  • the portion forming the covalent bond via 20 should have the flatness described above.
  • the molecular adhesive 20 includes a first reactive group RG1 capable of forming a covalent bond with the flat portion 10s of the first main surface 12s of the first optical sheet 10, and the third main surface 32s of the second optical sheet 30. and a second reactive group RG2 capable of forming a covalent bond.
  • the first reactive group RG1 and the second reactive group are different from each other.
  • Individual molecules that make up the molecular adhesive 20 are sometimes referred to as adhesive molecules 20 .
  • the molecular adhesive 20 or the adhesive molecule 20 is used regardless of whether the state is before or after forming covalent bonds with the first optical sheet 10 and the second optical sheet 30 .
  • molecular adhesive 20 may contain components other than adhesive molecules (eg, polymerization initiators).
  • the adhesive molecule 20 includes the first reactive group RG1 capable of forming a covalent bond with the flat portion 10s of the first major surface 12s of the first optical sheet 10 and the second group of the second optical sheet 30.
  • the flat portion 10s of the first main surface 12s of the first optical sheet 10 and the third main surface of the second optical sheet 30 32 is one adhesive molecule 20, a covalent bond formed by the first reactive group RG1 of this adhesive molecule 20 and the flat portion 10s, and the second reactive group of this adhesive molecule 20. It is bound by a covalent bond formed by RG2 and the third main surface 32s.
  • the adhesive molecules 20 can be interposed in the covalent bond between the flat portion 10s of the first major surface 12s of the first optical sheet 10 and the third major surface 32s of the second optical sheet 30 .
  • the adhesive molecule 20 has a plurality of silanol groups and/or alkoxysilyl groups, the adhesive molecule 20 can form covalent bonds through reactions between the silanol groups and/or alkoxysilyl groups.
  • the adhesive molecules 20 can intervene in the covalent bond between the flat portion 10s of the first major surface 12s and the third major surface 32s of the second optical sheet 30.
  • the minimum adhesive molecules 20 intervening in the covalent bond between the flat portion 10s of the first main surface 12s and the third main surface 32s of the second optical sheet 30 are a monomolecular layer (about 1 nm thick). could be.
  • the distance between the flat portion 10s of the first main surface 12s of the first optical sheet 10 and the third main surface of the second optical sheet 30 is approximately 1 nm or more, preferably approximately 500 nm or less, more preferably approximately 100 nm or less. preferable.
  • the molecular adhesive 20 contains many adhesive molecules 20 that form such covalent bonds, it does not always form a dense layer of adhesive molecules 20 . If there are few reaction points for forming covalent bonds on the flat portion 10s of the first major surface 12s and the third major surface 32, the adhesive molecules 20 may exist sparsely.
  • the first reactive group RG1 of the adhesive molecule 20 forms a covalent bond with both the flat portion 10s of the first main surface 12s of the first optical sheet 10 and the third main surface 32s of the second optical sheet 30.
  • an adhesive molecule (hereinafter referred to as a first adhesive molecule) 20 forming a covalent bond between the flat portion 10s of the first main surface 12s of the first optical sheet 10 and the first reactive group RG1,
  • the adhesive molecule (hereinafter referred to as the second adhesive molecule) 20 forming a covalent bond between the third main surface 32s of the second optical sheet 30 and the first reactive group RG1 is the first adhesive molecule.
  • the flat portion 10s of the first main surface 12s of the first optical sheet 10 and the second optical sheet 30 are formed. and the third main surface 32s of are bonded by a covalent bond.
  • two adhesive molecules 20 are present between the flat portion 10s of the first main surface 12s of the first optical sheet 10 and the third main surface 32s of the second optical sheet 30 .
  • the distance between the flat portion 10s of the first main surface 12s of the first optical sheet 10 and the third main surface 32s of the second optical sheet 30 is approximately 2 nm or more, preferably approximately 500 nm or less, and more preferably 100 nm or less. preferable.
  • the adhesive molecule 20 has, for example, at least one reactive group selected from the group consisting of an azide group, an amino group, a mercapto group, an isocyanate group, a ureido group, an epoxy group, a silanol group, and an alkoxysilyl group.
  • An alkoxysilyl group produces a silanol group through a hydrolysis reaction.
  • the molecular adhesive 20 has, for example, an azide group as the first reactive group RG1 (or the second reactive group RG2) and a silanol group or an alkoxy group as the second reactive group RG2 (or the first reactive group RG1). It has a silyl group.
  • Adhesive molecule 20 for example, further has a triazine ring, and an azide group is attached to the triazine ring.
  • the first reactive group RG1 is an azide group or an amino group
  • the second reactive group RG2 is a silanol group or an alkoxysilyl group
  • the first reactive group forms a covalent bond with the surfaces of the first and second optical sheets. may be formed to form a covalent bond between the second reactive groups.
  • Japanese Patent No. 5083926, Japanese Patent No. 6452919 or Japanese Patent No. 6674594 can be preferably used.
  • the entire disclosure of Japanese Patent No. 5083926, Japanese Patent No. 6452919 or Japanese Patent No. 6674594 is incorporated herein by reference.
  • the adhesive molecule 20 described in Japanese Patent No. 5083926 is represented, for example, by the following general formula [I].
  • E is an arbitrary group.
  • F is an OH group or an OH yielding group.
  • -Q is -N 3 or -NR 1 (R 2 ).
  • R 1 and R 2 of —NR 1 (R 2 ) are H, a hydrocarbon group having 1 to 24 carbon atoms, or —RSi(R′)n(OA)3-n (R has 1 carbon is a chain hydrocarbon group of up to 12.
  • R' is a chain hydrocarbon group having 1 to 4 carbon atoms
  • A is H or a chain hydrocarbon group having 1 to 4 carbon atoms.
  • n is an integer from 0 to 2).
  • R 1 and R 2 may be the same or different.
  • adhesive molecules 20 having a triazine ring represented by the general formula [I] adhesive molecules 20 having an azide group and a silanol group or an alkoxysilyl group are preferable.
  • the azide group of this adhesive molecule 20 is attached to the triazine ring.
  • the adhesive molecule has an alkoxysilyl group and an azide group. It also has a triazine ring. Azide groups are preferably attached directly to the triazine ring (C atom). The number of azide groups attached to the triazine ring is, for example, one or two.
  • the OH group or OH yielding group e.g. alkoxysilyl group
  • the azide group bonded to the triazine ring (electron-localized conjugated skeleton) has high decomposition energy to nitrene. Therefore, it is less likely to be affected by near-ultraviolet rays and visible light. Therefore, the workability of ultraviolet exposure is improved.
  • a nitrene attached to a triazine ring is more stable than a nitrene that does not. Bonding between nitrenes is suppressed. Hydrogen abstraction activity for C—H bonds and addition activity for unsaturated bonds are enhanced. That is, effective reaction is possible with a small amount of exposure.
  • the alkoxysilyl group is bonded to the triazine ring (electron-localizing conjugated skeleton) via a spacer (eg, amino group, oxy group and/or hydrocarbon group). Therefore, when an adhesive molecule binds to a resin surface, the entropic effect for creating chemical bonds is enhanced in contact with the other resin surface. Improving the entropy effect increases the frequency factor term in the interfacial reaction after the resin surfaces (the surface of the first optical sheet and the surface of the second optical sheet) come into contact with each other. This results in increased opportunities for interfacial reactions. The length of the spacer is reflected in an increase in the frequency factor in interfacial reactions. And if the length of the spacer is too long, the cost will be high. In addition, the adsorption amount of adhesive molecules is reduced. Therefore, spacers of moderate length are preferred. From this point of view, adhesive molecules represented by the following general formulas [Io] [Ia] [Ib] are preferable.
  • the alkoxysilyl groups in the general formulas [Io] [Ia] [Ib] are, in most cases, OH-producing groups (OH precursors).
  • OH-producing groups OH precursors
  • it is treated with water (neutral water, acidic water, alkaline water).
  • corona discharge treatment and plasma treatment can be considered.
  • water treatment is preferred.
  • the adhesion treatment (surface treatment: modification treatment) of the optical sheets (first optical sheet and/or second optical sheet) can be performed, for example, as follows.
  • a treatment liquid (solution or dispersion) containing adhesive molecules is prepared.
  • Solvents used include water, alcohols (e.g. methanol, ethanol, isopropanol, ethylene glycol, propylene glycol, cellosolve, carbitol), ketones (e.g. acetone, methyl ethyl ketone, cyclohexanone), aromatic hydrocarbons (e.g. benzene, toluene, xylene), aliphatic hydrocarbons (e.g. hexane, octane, decane, dodecane, octadecane), esters (e.g.
  • the content of adhesive molecules is 0.0001 to 10% by weight. Particularly preferably, it is 0.001 to 2% by mass. This is because if the content of adhesive molecules is too low, the effect is poor. Conversely, the amount of reaction with the optical sheet is limited, and too much is meaningless. From such a viewpoint, the above ratio is preferable.
  • a surfactant is added to the treatment liquid as needed from the viewpoint of adjusting the surface tension.
  • nonionic surfactants e.g., nonionic surfactants composed of long-chain alkyl chains and polyethylene glycol
  • cationic surfactants e.g., quaternary ammonium salts
  • anionic surfactants e.g., organic carboxylates, sulfonates
  • the optical sheet is immersed in the treatment liquid.
  • the treatment liquid is sprayed onto the optical sheet. This causes glue molecules (molecular glue) to adhere to the surface of the optical sheet.
  • UV irradiation decomposes the azide groups of the adhesive molecules.
  • Nitrene is formed by decomposition of the azide group. This nitrene attacks the functional groups (eg, —CH 3 , —CH 2 —, —CH ⁇ , —CH ⁇ CH—) on the surface of the optical sheet.
  • hydrogen abstraction radical addition or radical addition reaction occurs, and chemical bonding occurs between the adhesive molecules and the surface of the optical sheet. Chemical bonding does not occur at the unirradiated locations.
  • a UV irradiation device for example, a high-pressure mercury UV lamp, a low-pressure mercury UV lamp, a fluorescent UV lamp (short ARC xenon lamp, chemical lamp), a metal halide lamp) is used for the ultraviolet irradiation. Then, ultraviolet rays of 200 to 450 nm are irradiated. If the amount of irradiation light is too small, the reaction will be difficult to proceed. Conversely, if the amount of irradiation light is too large, there is a risk of deterioration of the optical sheet. Therefore, the preferable amount of irradiation light (light source wavelength: 254 nm) is 1 mJ/cm 2 to 5 J/cm 2 . More preferably, it is 5 mJ/cm 2 to 1 J/cm 2 .
  • the optical sheet When the optical sheet has a complicated shape, it is effective to use a reflector in order to uniformly irradiate the optical sheet with UV light.
  • the reflecting plate include mirrors, surface-polished metal foils, Al mirror foils, SUS mirror foils, and silver-plated mirror plates.
  • the shape, size, material, etc. of the reflector are appropriately selected from the viewpoint of reflection efficiency.
  • the optical laminate 100 can be manufactured, for example, by the following manufacturing method.
  • the manufacturing method according to the embodiment of the present invention at least one of the flat portion 10s of the first optical sheet 10 and the third main surface 32s of the second optical sheet 30 is coated with an adhesive molecule represented by the above general formula [I], for example.
  • step C for example, heating is performed at a temperature of 60° C. or higher and 150° C. or lower, more preferably 80° C. or higher and 110° C. or lower.
  • the applied pressure is, for example, 0.01 MPa or more and 50 MPa or less, preferably 0.1 MPa or more and 5 MPa or less.
  • the pressurization time is, for example, 0.1 minute or more and 200 minutes or less.
  • the heating temperature and/or heating time are set in consideration of the heat resistance of the first optical sheet 10 and the second optical sheet 30 .
  • the adhesive molecules As the adhesive molecules, the adhesive molecules (molecular adhesive M) described in Japanese Patent No. 6674594 can also be used.
  • the adhesive molecule has at least one reactive group (Z ⁇ ) selected from the group consisting of an amino group (—NH 2 ), an azide group, a mercapto group, an isocyanate group, a ureido group and an epoxy group. , silanol groups, and at least one reactive group (Z ⁇ ) selected from the group consisting of groups that generate silanol groups by hydrolysis reaction.
  • the reactive group (Z ⁇ ) is preferably an amino group (--NH 2 ) or an azide group. Since the adhesive molecules containing an azide group are the same as those described in Japanese Patent No. 5083926, an embodiment using mainly adhesive molecules having amino groups will be described below.
  • the reactive group (Z ⁇ ) in the adhesive molecule can form a chemical bond with the reactive partial structure (Z ⁇ ) of the thermoplastic resin (P 1 ) in the optical sheet (first or second optical sheet). be. It is believed that this chemical bond chemically fixes the adhesive molecules to the surface of the optical sheet.
  • a chemical bond is preferably a covalent bond.
  • the thermoplastic resin (P 1 ) is, for example, at least one selected from the group consisting of olefin resins, cycloolefin resins, acrylic resins, olefin-vinyl acetate resins, olefin ionomer resins, and polyester resins. .
  • the reactive group (Z ⁇ ) in the adhesive molecule forms a chemical bond with the surface of the other optical sheet (second or first optical sheet).
  • the surface of the other optical sheet preferably has a hydroxyl group (hydroxy group) or a carboxy group (--COOH).
  • a hydroxyl group or a carboxyl group can be introduced by surface-treating the other optical sheet formed from a thermoplastic resin or a thermosetting resin. Examples of surface treatment include corona treatment, plasma treatment, ultraviolet irradiation treatment, electron beam irradiation treatment, ozone treatment, excimer ultraviolet treatment, acid treatment, and base treatment.
  • Groups that generate silanol groups by hydrolysis include groups having a partial structure represented by Si— X1 .
  • X 1 includes hydrolyzable groups such as alkoxy groups having 1 to 10 carbon atoms such as methoxy group, ethoxy group, n-propoxy group and isopropoxy group; halogen atoms such as fluorine atom, chlorine atom and bromine atom; mentioned.
  • the thickness of the molecular adhesive applied to the optical sheet is preferably 200 nm or less, more preferably 150 nm or less, even more preferably 100 nm or less, and particularly preferably 50 nm or less.
  • the thickness of the molecular adhesive is preferably 0.5 nm or more, more preferably 1 nm or more.
  • the flat portion 10s of the first main surface 12s or the third main surface Form a covalent bond with the hydrocarbon group of 32s
  • the amino group forms a covalent bond with the carbonyl carbon
  • the alkoxysilyl group forms a covalent bond with the hydroxyl group
  • the amino group forms a covalent bond with the hydroxyl group or the carboxyl group .
  • a molecular adhesive can be applied to an optical sheet, for example, as follows. For example, a molecular adhesive solution containing the molecular adhesive (M) is prepared, this solution is applied onto the optical sheet, and then the resulting coating film is dried, and the molecular adhesive is fixed to the optical sheet. process.
  • M molecular adhesive
  • the solvent used when preparing the molecular adhesive solution is not particularly limited.
  • the solvent include alcohol solvents such as methanol, ethanol, isopropanol, ethylene glycol and diethylene glycol; ketone solvents such as acetone and methyl ethyl ketone; ester solvents such as ethyl acetate and butyl acetate; halogen-containing compound solvents such as methylene chloride; Aliphatic hydrocarbon solvents such as butane and hexane; ether solvents such as tetrahydrofuran and butyl ether; aromatic compound solvents such as benzene and toluene; amide solvents such as N,N-dimethylformamide and N-methylpyrrolidone; ; and the like. These can be used individually by 1 type or in combination of 2 or more types.
  • the concentration of the molecular adhesive (adhesive molecules) in the molecular adhesive solution is not particularly limited. Its concentration is preferably 0.005 to 1.000 mol/L, more preferably 0.050 to 0.500 mol/L. By setting the concentration of the adhesive molecules to 0.005 mol/L or more, the molecular adhesive can be efficiently applied onto the optical sheet. Further, by setting the concentration to 1.000 mol/L or less, unintended reaction of the molecular adhesive solution can be suppressed, and the solution is excellent in stability.
  • the method of applying the molecular adhesive solution is not particularly limited, and any known application method can be used.
  • coating methods include spin coating, spray coating, bar coating, knife coating, roll knife coating, roll coating, blade coating, dip coating, curtain coating, die coating, and gravure coating. etc., but the bar coating method and the gravure coating method are preferred.
  • a drying mechanism for example, a batch-type drying mechanism such as an air oven, a heat roll, a hot air through mechanism (the object to be dried moves and passes through an open-type drying oven, and is heated and dried while receiving air blowing. and a continuous drying mechanism such as equipment for drying.
  • a drying mechanism for example, heaters such as high-frequency heating, heating medium circulation heaters such as oil heaters, and far-infrared heaters can also be used as drying mechanisms.
  • the drying temperature adjusted by the drying mechanism is usually 20 to 250°C, preferably 25 to 200°C, more preferably 30 to 150°C, particularly preferably 35 to 120°C.
  • the drying time is usually 1 second to 120 minutes, preferably 10 seconds to 10 minutes, more preferably 20 seconds to 5 minutes, particularly preferably 30 seconds to 3 minutes.
  • the fixing treatment can be appropriately selected according to the properties of the reactive group (Z ⁇ ) of the molecular adhesive.
  • Z ⁇ reactive group
  • chemical bonding is generated by applying the molecular adhesive onto the optical sheet, and heating accelerates the generation of the chemical bonding. Therefore, heat treatment is preferable from the viewpoint of improving productivity.
  • the heating temperature is usually 40 to 250°C, preferably 60 to 200°C, more preferably 80 to 120°C.
  • the heating time is usually 1 second to 120 minutes, preferably 1 to 60 minutes, more preferably 1 to 30 minutes.
  • the heating method is not particularly limited, and the same mechanism and device as the drying mechanism described above can be used.
  • the application of the molecular adhesive solution, the drying process, and the fixing process may be repeated multiple times.
  • FIG. 1 shows the molecular adhesive 20 only between the flat portion 10s of the first main surface 12s and the third main surface 32s for simplicity, it is not limited to this.
  • the first optical sheet 10 is immersed in a treatment liquid (solution or dispersion) containing the molecular adhesive 20, the entire first main surface 12s, that is, not only the flat portion 10s but also the concave portion 14
  • the molecular adhesive 20 may adhere and remain on the first slanted surface 16s and the second slanted surface 17s.
  • the second optical sheet 30 is immersed in a treatment liquid containing the molecular adhesive 20, the molecular adhesive 20 may adhere and remain on the entire third main surface 32s.
  • the molecular adhesive 20 even if the molecular adhesive 20 remains, it is at most a monomolecular layer of the adhesive molecules 20, so it is smaller than the wavelength of visible light (400 nm or more and less than 760 nm) and hardly affects the optical characteristics. Further, since the thickness (depth of the recesses) of the first optical sheet 10 is several ⁇ m or more, the molecular adhesive 20 is shown in FIG. small enough to be ignored. Note that the treatment liquid containing the molecular adhesive 20 can be selectively applied only to the flat portion 10s by a method such as printing.
  • the molecular adhesive 20 existing between the first optical sheet 10 and the second optical sheet 30 is at most two molecular layers thick and is thinner than the wavelength of visible light, so it is considered optically non-existent. be able to. Therefore, if the refractive indices of the first optical sheet 10 and the second optical sheet 30 are the same, the first optical sheet 10 and the second optical sheet 30 can be optically combined without an interface. can be done.
  • the difference (absolute value) in refractive index between the first optical sheet 10 and the second optical sheet 30 is, for example, preferably 0.20 or less, more preferably 0.15 or less, and even more preferably 0.10 or less.
  • the optical laminate 100 has a plurality of internal spaces 14a.
  • the plurality of internal spaces 14a are defined by each of the plurality of recesses 14 of the first main surface 12s of the first optical sheet 10a and the third main surface 32s of the second optical sheet.
  • FIG. 2 also illustrates molecular adhesive 20, but the physical length (thickness) of molecular adhesive 20 is negligibly small. Therefore, in the optical layered body 100, unlike the optical layered body 200 using the conventional adhesive layer (the adhesive layer 20C in FIG. 3), the adhesive does not enter the concave portion 14.
  • the second optical sheet 30 may be deformed by heat and pressure when it is adhered to the first optical sheet 10, and the second optical sheet 30 may enter the concave portion 14 as shown in FIG. .
  • the second optical sheet 30 having sufficiently high rigidity is selected under the bonding conditions, the second optical sheet 30 can be prevented from entering the concave portion 14 .
  • the distance from the opening plane defined by the opening 14op of the recess 14 (broken line inside the opening 14op of the recess 14 in FIG. 2) to the deepest part of the recess 14 is A, and the distance from the opening plane into the recess 14 is A.
  • B/A can be reduced to 0.2 or less as shown in examples later.
  • B/A is preferably 0.15 or less, more preferably 0.10 or less, and even more preferably 0.05 or less.
  • the second optical sheet 30 enters the recess 14 because the second optical sheet 30 bends. It has a convex shape. Therefore, if the point at which the distance from the opening surface to the third main surface 32 of the second optical sheet 30 entering the concave portion 14 has the maximum value B is defined as the most penetrating point, the most penetrating point is the first inclined surface of the concave portion 14. 16s and the second inclined surface 17s are located on the deepest side.
  • the second optical sheet 30 hardly contacts the first inclined surface 16s and/or the second inclined surface 17s of the concave portion 14, and the inner space 14a
  • the area of the first slanted surface 16s and/or the second slanted surface 17s forming the interface causing total internal reflection of .
  • the degree of penetration of the second optical sheet 30 into the concave portion 14 can be sufficiently suppressed, so that the shape of the internal space 14a can be made substantially equal to the shape of the concave portion 14. Therefore, optical characteristics (for example, light distribution characteristics) as designed can be obtained.
  • the second optical sheet 30 having a rigidity that does not enter the recesses 14 for the type of molecular adhesive and the bonding conditions. Further, even if the second optical sheet 30 does not enter the concave portion 14, the concave portion 14 may be deformed if the heat resistance of the first optical sheet 10 is not sufficient. Desired optical characteristics cannot be obtained if the concave portion 14 is deformed. Therefore, it is preferable to select the first optical sheet 10 having such rigidity (heat resistance) that the concave portions 14 are not deformed, depending on the type of molecular adhesive and the bonding conditions. It is particularly preferable that the first optical sheet 10 is formed of a cured product of a curable resin.
  • a cured product of a curable resin has a crosslinked structure, and thus is not easily deformed by heat. Therefore, it is possible to suppress the deformation of the concave portions 14 of the first optical sheet 10 when the second optical sheet 30 is heated and pressurized through the molecular adhesive. It should be noted that the concave portion 14 may be formed by conducting a preliminary experiment and predicting the deformation during adhesion.
  • FIG. 3 shows a schematic cross-sectional view of the optical laminate 200 produced using the adhesive layer 20C.
  • the second optical sheet 30 on the adhesive layer 20C is omitted.
  • the thickness of the adhesive layer 20C is generally 1 ⁇ m or more, typically 4 ⁇ m or more, and is 10 times or more greater than the thickness of the molecular adhesive 20 .
  • the surface 28Cs of the adhesive layer 20C on the side of the first optical sheet 10 penetrates into the recess 14.
  • a general thermosetting adhesive is used, the adhesive is heated and pressurized during bonding, and the adhesive softens at that time, so that the adhesive does not enter the recess 14 .
  • an adhesive pressure-sensitive adhesive
  • the adhesive since the adhesive has a low rigidity, the adhesive penetrates into the concave portion 14 due to the pressure during bonding.
  • the lower surface 28Cs of the adhesive layer 20C that has entered the recess 14 has a concave shape toward the bottom of the recess 14. This is due to the cohesive force (surface tension) of the softened adhesive (or adhesive), and the third main surface 32s of the second optical sheet 30 shown in FIG. Contrast with shape. Therefore, when bonding using the adhesive layer 20C, the distance A from the opening surface defined by the opening 14op of the concave portion 14 to the deepest portion of the concave portion 14 is defined as A, and the adhesive layer 20C entering the concave portion 14 from the opening surface.
  • the maximum penetration point is the point where the distance to the lower surface 28Cs has the maximum value B
  • the maximum penetration point is the point that contacts the first inclined surface 16s or the second inclined surface 17s of the recess 14. is either the distance B1 to the first inclined surface 16s or the distance B2 to the second inclined surface 17s in FIG.
  • the maximum distance B to the lower surface 28Cs is the distance B1 to the first inclined surface 16s or the distance B2 to the second inclined surface 17s.
  • the area of the first inclined surface 16s and/or the second inclined surface 17s forming the interface causing total internal reflection of the internal space 14Ca is reduced. become.
  • the degree of penetration into the concave portion 14 depends on the type of adhesive and the conditions (temperature, pressure, time) during bonding, but it is difficult to keep the degree of penetration low.
  • the concave shape of the lower surface 28Cs of the adhesive layer 20C depends on the shape of the concave portion 14 and the method of applying pressure (direction of stress acting on the adhesive) during lamination, but is generally asymmetrical. For example, as shown in FIG. 3, the smaller the tilt angle (the angle of the first main surface 12s of the first optical sheet 10 with respect to the flat portion 10s), the more penetration.
  • the maximum penetration point is the first inclined surface 16s of the recess 14. It becomes a point of contact, and the maximum value B is B1 in FIG.
  • B2 may be greater than B1
  • the size and shape of the internal space 14Ca defined by the concave portion 14 and the adhesive layer 20C deviate greatly from the concave portion 14, so that the optical characteristics (e.g., light distribution characteristics) ) deviates significantly from the design.
  • the first optical sheet 10 can be, for example, the optical sheet 10a shown in FIGS. 4A and 4B.
  • An optical sheet 10a having an uneven structure (a plurality of recesses 14) on its surface is sometimes referred to as a shaped film 10a.
  • the optical laminate 100 including the shaping film 10a functions as a light distribution structure described in Patent Document 2 or Patent Document 3.
  • a light source for example, an LED device
  • the side surface for example, the left side in FIG.
  • a light guide layer may be further provided on the fourth main surface 38s side of the second optical sheet 30, or the first optical sheet 10 or the optical laminate 100 may be used as the light guide layer.
  • a light guide plate having the optical stack 100 can be in various forms.
  • a light guide having such an optical layered body 100 can be used in various lighting devices.
  • the size of the recesses 14 is, for example, preferably the length L is 10 ⁇ m or more and 500 ⁇ m or less, and the width W is 1 ⁇ m or more and 100 ⁇ m. The following are preferable.
  • the depth A is preferably 1 ⁇ m or more and 100 ⁇ m or less.
  • the depth A of the concave portion 14 is preferably 20 ⁇ m or less, more preferably 12 ⁇ m or less.
  • the depth A of the concave portion 14 is preferably 4 ⁇ m or more, more preferably 6 ⁇ m or more, and even more preferably 8 ⁇ m or more.
  • the plurality of recesses 14 may be arranged periodically as shown in FIG. 4A, for example.
  • the pitch Px is, for example, 10 ⁇ m or more and 500 ⁇ m or less
  • the pitch Py is, for example, 10 ⁇ m or more and 500 ⁇ m or less.
  • the density of the plurality of recesses 14 is the ratio of the area of the plurality of recesses 14 to the area of the shaped film 10a (occupied area ratio) when the shaped film 10a is viewed from the normal direction of the main surface. It is preferably 0.3% or more from the viewpoint of obtaining.
  • the occupied area ratio of the plurality of recesses 14 is appropriately selected depending on the application, and for example, in applications requiring transparency, it is preferably 30% or less in order to obtain good visible light transmittance and haze value. It is preferably 1% or more from the viewpoint of obtaining good luminance.
  • the upper limit is more preferably 25% or less, preferably 10% or less, more preferably 5% or less in order to obtain a high visible light transmittance.
  • the occupied area ratios of the plurality of concave portions 14 may be uniform, or the occupied area ratio should increase as the distance increases so that the brightness does not decrease even if the distance from the light source increases. good too.
  • the inclination angle ⁇ a of the first inclined surface 16s is, for example, 10° or more and 70° or less.
  • the lower limit is preferably 30° or more, more preferably 45° or more. If the angle of inclination ⁇ a is less than 10°, the controllability of the light distribution may deteriorate, and the light extraction efficiency may also deteriorate. On the other hand, if the inclination angle ⁇ a exceeds 70°, it may become difficult to process the shaped film, for example.
  • the inclination angle ⁇ b of the second inclined surface 17s is, for example, 50° or more and 100° or less. The lower limit is preferably 70° or more. If the tilt angle ⁇ b is less than 50°, stray light may occur in an unintended direction.
  • the inclination angle ⁇ a of the first inclined surface 16s and the inclination angle ⁇ b of the second inclined surface 17s are angles with respect to the direction parallel to the Y direction in the cross section of the recess 14 (the cross section perpendicular to the X direction and parallel to the YZ plane). .
  • the inclination angle ⁇ a of the first inclined surface 16s is smaller than the inclination angle ⁇ b of the second inclined surface 17s.
  • the first inclined surface 16s is arranged closer to the light source than the second inclined surface 17s.
  • the cross-sectional shape of the internal space 14a (the cross-section perpendicular to the X direction and parallel to the YZ plane) has an inclination angle ⁇ a of the first inclined surface 16s, an inclination angle ⁇ b of the second inclined surface 17s, a width W, and a depth A. defined by
  • the shape of the internal space 14a (recess 14) is not limited to the illustrated one, and can be modified in various ways. By adjusting the shape, size, arrangement density, etc. of the internal space 14a (recesses 14), it is possible to adjust the distribution of light rays (light distribution) emitted from the optical laminate 100 (for example, Patent Document 2 and 3).
  • the cross-sectional shape of the concave portion 14 is not limited to this. (eg trapezoidal). Also, the shape is not limited to a polygon, and may be a shape including a curve.
  • the optical laminate 100 may further have other optical sheets.
  • a curable resin for example, a curable resin is applied onto a base layer (for example, a transparent resin film such as a PMMA film) to form an uneven structure in the curable resin layer. After that, by curing this, the shaped film 10a formed of the cured product is obtained. At this time, the shaping film 10a is integrally formed on the base material layer.
  • the optical layered body 100 may further have, for example, a light guide layer, a light diffusion layer, an antireflection layer, a low refractive index layer, a reflection layer, a hard coat layer, and the like.
  • the optical stack 100 may include an adhesive layer.
  • the optical laminate 100 can be manufactured using, for example, a roll-to-roll method.
  • a shaped film 10a having an uneven structure on the surface described with reference to FIGS. 4A and 4B was produced according to the method described in Japanese Unexamined Patent Application Publication No. 2013-524288. Specifically, the surface of a polymethyl methacrylate (PMMA) film is coated with a lacquer (Fine Cure RM-64 manufactured by Sanyo Chemical Industries, Ltd.: an acrylate-based photocurable resin), and an optical A pattern was embossed, and then the lacquer was cured (ultraviolet irradiation conditions: D bulb, 1000 mJ/cm 2 , 320 mW/cm 2 ) to produce a shaped film 10a having a desired uneven structure on its surface.
  • a lacquer Fluoret irradiation conditions: D bulb, 1000 mJ/cm 2 , 320 mW/cm 2
  • the thickness of the shaped film 10a was 20 ⁇ m.
  • the total thickness including the shaped film 10a and the PMMA film (base layer) was 60 ⁇ m, and the haze value was 3.2%.
  • the shaping film 10a and the PMMA film (base material layer) are collectively referred to as a resin film A.
  • This shaping film 10a has a plurality of concave portions 14 with a triangular cross section, each having a length L of 80 ⁇ m, a width W of 17.3 ⁇ m, and a depth A of 10 ⁇ m. are placed vacantly. Furthermore, such a pattern of recesses 14 is arranged at intervals of width D (160 ⁇ m) in the Y-axis direction.
  • Px in FIG. 4A is 340 ⁇ m and Py is 174 ⁇ m.
  • the density of the concave portions 74 on the surface of the concave-convex shaped film was 2426/cm 2 .
  • the tilt angle ⁇ a in FIG. 4B was approximately 60°, and the tilt angle ⁇ b was 85°.
  • the occupied area ratio of the concave portion 14 was 3.4%.
  • This PMMA film will be referred to as resin film B.
  • 6-(3-triethoxysilylpropyl)amino-1,3,5-triazine-2,4-diazide (included in general formula Ia) purchased from Io Kagaku Kenkyusho Co., Ltd.
  • a treatment liquid (solution) diluted with ethanol to a concentration of 0.5% by mass was used.
  • Sulfur Chemical Laboratory Co., Ltd. is the patentee of Japanese Patent No. 5083926.
  • An adhesive sheet for producing an optical laminate of a comparative example was produced as follows.
  • an acrylic polymer was prepared. 90.7 parts by mass of n-butyl acrylate (BA), 6.3 parts by mass of 4-acryloylmorpholine (ACMO), acrylic acid, and (AA) 2.7 parts by mass, 0.3 parts by mass of 4-hydroxybutyl acrylate (4HBA), 0.1 parts by mass of 2,2'-azobisisobutyronitrile as a polymerization initiator, and the total amount of monomers is 50 parts by mass. %, and nitrogen gas was introduced while gently stirring to replace nitrogen gas for 1 hour. Then, the liquid temperature in the flask was maintained at around 58°C and the polymerization reaction was carried out for 8 hours. A system polymer was obtained.
  • the acrylic polymer was obtained as an acrylic polymer solution having a solid content of 35% by mass.
  • An adhesive composition solution was applied to one side of a 38 ⁇ m-thick polyethylene terephthalate (PET) film (trade name “MRF38”, manufactured by Mitsubishi Chemical Corporation) that had been subjected to silicone release treatment to form an adhesive composition solution layer.
  • PET polyethylene terephthalate
  • MRF38 polyethylene terephthalate
  • the adhesive composition solution layer was applied so that the thickness after drying (that is, the thickness of the adhesive composition layer) was 5 ⁇ m.
  • the solvent of the adhesive composition solution layer was removed and the acrylic polymer was crosslinked with a crosslinking agent to obtain an adhesive composition layer.
  • the adhesive composition layer was laminated to the release-treated surface of a 38 ⁇ m-thick polyethylene terephthalate (PET) film (trade name “MRE38”, manufactured by Mitsubishi Chemical Corporation) that had been subjected to silicone release treatment, and the PET film/adhesive composition An adhesive sheet having a lamination structure of material layer/PET film was produced.
  • PET polyethylene terephthalate
  • Example 1 The resin film A and the resin film B were adhered using the above molecular adhesive.
  • a treatment liquid containing a molecular adhesive was applied to the surface of the shaping film 10a of the resin film A having recesses to a thickness of 16 ⁇ m. Then, it was dried at 80° C. for 1 minute and irradiated with ultraviolet rays from the side to which the molecular adhesive was applied. UV irradiation converts the azide group of the molecular adhesive to nitrene, and the nitrene reacts with hydrocarbons (eg, alkyl groups) on the surface of resin film A to form covalent bonds.
  • hydrocarbons eg, alkyl groups
  • An LED lamp manufactured by Quark Technology Co., Ltd., peak illuminance: 200 mW/cm 2
  • ultraviolet rays were irradiated so that the integrated light amount was 100 mJ/cm 2 (wavelength: 245 nm).
  • the UV illuminance was measured using a UV Power Puck (manufactured by Fusion UV Systems Japan Co., Ltd.).
  • the thickness of the molecular glue was about 40 nm.
  • the film thickness of the acrylic film coated with the molecular adhesive was measured by ellipsometry.
  • the measurement wavelength range was measured using a light source of 210 nm to 1690 nm at incident angles of 60°, 70° and 80°.
  • molecular adhesive was added to the surface of resin film B to a thickness of about 40 nm and reacted.
  • the resin film A and the resin film B were heated and pressed at 100°C and 0.5 MPa for 5 minutes using a precision press device with the surfaces to which the molecular adhesives were bonded facing each other.
  • silanol groups generated by hydrolysis of the alkoxysilyl groups of the molecular adhesive undergo coupling reactions to form covalent bonds.
  • Example 2 An optical laminate was produced in the same manner as in Example 1, except that the temperature during heating and pressing was 110°C.
  • the depth A of the concave portion 14 and the maximum penetration value B were obtained from a cross-sectional SEM image of the optical layered body.
  • a and B were obtained from cross-sectional images at a plurality of arbitrarily selected locations, and the averages are shown in Table 1.
  • the shape of the internal space in the optical layered body of Example 1 is similar to the internal space 14a shown in FIG. was On the other hand, the shape of the internal space in the optical layered body of Example 2 pressurized at a temperature higher than that of the optical layered body of Example 1 has the same shape as the internal space 14a shown in FIG. The optical sheet 30 slightly encroached on the concave portion 14 . B/A was about 0.1, which was a sufficiently small value of 0.2 or less.
  • the internal space in the optical layered body of Comparative Example 1 has the same shape as the internal space 14Ca shown in FIG. Met.
  • Curved surface followability was evaluated by sticking to the curved surface (width 30 mm x length 80 mm) of a cylindrical polymethyl methacrylate test piece with an outer diameter of 90 mm, leaving it at room temperature for 5 days, and evaluating lifting and peeling. In addition, after being left in an environment of 23° C. and 65% RH for 7 days, the film was left in an environment of 85° C. and 85% RH for 1000 hours to evaluate lifting and peeling. It was found that each of the optical laminates of Examples 1 and 2 and Comparative Example 1 has sufficient bending adhesiveness.
  • ⁇ Haze value> The haze value of each optical laminate was measured with D65 light using a haze meter (apparatus name “HZ-1”, manufactured by Suga Test Instruments Co., Ltd.). The haze value of any optical layered body slightly increased from the haze value of 3.2% of the shaping film.
  • optical layered body according to the embodiment of the present invention is widely used in optical devices such as display devices and lighting devices.

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PCT/JP2022/039303 2021-10-29 2022-10-21 光学積層体、光学装置、光学積層体の製造方法 Ceased WO2023074572A1 (ja)

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US18/705,050 US20250035833A1 (en) 2021-10-29 2022-10-21 Optical laminate, optical device, and method for producing optical laminate
JP2023556399A JPWO2023074572A1 (https=) 2021-10-29 2022-10-21
CN202280072458.0A CN118176454A (zh) 2021-10-29 2022-10-21 光学层叠体、光学装置、光学层叠体的制造方法
EP22886899.8A EP4425248A4 (en) 2021-10-29 2022-10-21 OPTICAL LAMINATE, OPTICAL DEVICE AND PROCESS FOR PRODUCING OPTICAL LAMINATE
KR1020247013731A KR20240101562A (ko) 2021-10-29 2022-10-21 광학 적층체, 광학 장치, 광학 적층체의 제조 방법

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