WO2022222090A1 - Ink - Google Patents
Ink Download PDFInfo
- Publication number
- WO2022222090A1 WO2022222090A1 PCT/CN2021/088911 CN2021088911W WO2022222090A1 WO 2022222090 A1 WO2022222090 A1 WO 2022222090A1 CN 2021088911 W CN2021088911 W CN 2021088911W WO 2022222090 A1 WO2022222090 A1 WO 2022222090A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polymer
- mass
- ink
- parts
- dispersion
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 claims abstract description 134
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 90
- 150000007514 bases Chemical class 0.000 claims abstract description 21
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 16
- 125000003118 aryl group Chemical group 0.000 claims abstract description 11
- 125000000524 functional group Chemical group 0.000 claims abstract description 6
- 239000006185 dispersion Substances 0.000 claims description 97
- 238000000034 method Methods 0.000 claims description 77
- 239000000049 pigment Substances 0.000 claims description 65
- 239000011347 resin Substances 0.000 claims description 55
- 229920005989 resin Polymers 0.000 claims description 55
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 38
- 239000002245 particle Substances 0.000 claims description 37
- 239000000178 monomer Substances 0.000 claims description 34
- 238000007639 printing Methods 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 22
- -1 alkali metal salt Chemical class 0.000 claims description 19
- 238000007641 inkjet printing Methods 0.000 claims description 17
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 150000008065 acid anhydrides Chemical class 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 134
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 47
- 125000000129 anionic group Chemical group 0.000 description 30
- 229920002554 vinyl polymer Polymers 0.000 description 30
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 24
- 238000005406 washing Methods 0.000 description 20
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 16
- 239000004744 fabric Substances 0.000 description 16
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 14
- 238000004040 coloring Methods 0.000 description 14
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 14
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 9
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 230000003287 optical effect Effects 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 239000010452 phosphate Substances 0.000 description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 7
- 230000002209 hydrophobic effect Effects 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000000080 wetting agent Substances 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- 238000002835 absorbance Methods 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 239000003505 polymerization initiator Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000005856 abnormality Effects 0.000 description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- NJRXVEJTAYWCQJ-UHFFFAOYSA-N thiomalic acid Chemical compound OC(=O)CC(S)C(O)=O NJRXVEJTAYWCQJ-UHFFFAOYSA-N 0.000 description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- CYKDLUMZOVATFT-UHFFFAOYSA-N ethenyl acetate;prop-2-enoic acid Chemical compound OC(=O)C=C.CC(=O)OC=C CYKDLUMZOVATFT-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 125000004437 phosphorous atom Chemical group 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920005792 styrene-acrylic resin Polymers 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- JWTGRKUQJXIWCV-UHFFFAOYSA-N 1,2,3-trihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(O)C(O)CO JWTGRKUQJXIWCV-UHFFFAOYSA-N 0.000 description 1
- YAOJJEJGPZRYJF-UHFFFAOYSA-N 1-ethenoxyhexane Chemical compound CCCCCCOC=C YAOJJEJGPZRYJF-UHFFFAOYSA-N 0.000 description 1
- IOSXLUZXMXORMX-UHFFFAOYSA-N 1-ethenoxypentane Chemical compound CCCCCOC=C IOSXLUZXMXORMX-UHFFFAOYSA-N 0.000 description 1
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 1
- UVHXEHGUEKARKZ-UHFFFAOYSA-N 1-ethenylanthracene Chemical compound C1=CC=C2C=C3C(C=C)=CC=CC3=CC2=C1 UVHXEHGUEKARKZ-UHFFFAOYSA-N 0.000 description 1
- WPMHMYHJGDAHKX-UHFFFAOYSA-N 1-ethenylpyrene Chemical compound C1=C2C(C=C)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 WPMHMYHJGDAHKX-UHFFFAOYSA-N 0.000 description 1
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- NTINFTOOVNKGIU-UHFFFAOYSA-N 2-(2-hydroxyethoxycarbonyl)benzoic acid Chemical compound OCCOC(=O)C1=CC=CC=C1C(O)=O NTINFTOOVNKGIU-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- QSOMQGJOPSLUAZ-UHFFFAOYSA-N 2-ethenylbuta-1,3-dienylbenzene Chemical compound C=CC(C=C)=CC1=CC=CC=C1 QSOMQGJOPSLUAZ-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- UXYAJXBVMZFRMS-UHFFFAOYSA-N 2-hydroxy-1,3,2$l^{5}-dioxaphosphepane 2-oxide Chemical compound OP1(=O)OCCCCO1 UXYAJXBVMZFRMS-UHFFFAOYSA-N 0.000 description 1
- FFZQJAHBHYRHSU-UHFFFAOYSA-N 2-hydroxy-1,3,2$l^{5}-dioxaphosphinane 2-oxide Chemical compound OP1(=O)OCCCO1 FFZQJAHBHYRHSU-UHFFFAOYSA-N 0.000 description 1
- FHHPEPGEFKOMOF-UHFFFAOYSA-N 2-hydroxy-1,3,2lambda5-dioxaphosphetane 2-oxide Chemical compound OP1(=O)OCO1 FHHPEPGEFKOMOF-UHFFFAOYSA-N 0.000 description 1
- RYRDKOIZZRUCMC-UHFFFAOYSA-N 2-hydroxy-4-methyl-1,3,2$l^{5}-dioxaphospholane 2-oxide Chemical compound CC1COP(O)(=O)O1 RYRDKOIZZRUCMC-UHFFFAOYSA-N 0.000 description 1
- KWTKVFXDPKATDW-UHFFFAOYSA-N 2-methyl-3-oxopent-4-enoic acid Chemical compound OC(=O)C(C)C(=O)C=C KWTKVFXDPKATDW-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- SEILKFZTLVMHRR-UHFFFAOYSA-N 2-phosphonooxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(O)=O SEILKFZTLVMHRR-UHFFFAOYSA-N 0.000 description 1
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical class C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- VFXXTYGQYWRHJP-UHFFFAOYSA-N 4,4'-azobis(4-cyanopentanoic acid) Chemical compound OC(=O)CCC(C)(C#N)N=NC(C)(CCC(O)=O)C#N VFXXTYGQYWRHJP-UHFFFAOYSA-N 0.000 description 1
- UZDMJPAQQFSMMV-UHFFFAOYSA-N 4-oxo-4-(2-prop-2-enoyloxyethoxy)butanoic acid Chemical compound OC(=O)CCC(=O)OCCOC(=O)C=C UZDMJPAQQFSMMV-UHFFFAOYSA-N 0.000 description 1
- KSLLMGLKCVSKFF-UHFFFAOYSA-N 5,12-dihydroquinolino[2,3-b]acridine-6,7,13,14-tetrone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C(=O)C(C(=O)C1=CC=CC=C1N1)=C1C2=O KSLLMGLKCVSKFF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 229920005692 JONCRYL® Polymers 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- PGEHNUUBUQTUJB-UHFFFAOYSA-N anthanthrone Chemical compound C1=CC=C2C(=O)C3=CC=C4C=CC=C5C(=O)C6=CC=C1C2=C6C3=C54 PGEHNUUBUQTUJB-UHFFFAOYSA-N 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- MYONAGGJKCJOBT-UHFFFAOYSA-N benzimidazol-2-one Chemical compound C1=CC=CC2=NC(=O)N=C21 MYONAGGJKCJOBT-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 239000004318 erythorbic acid Substances 0.000 description 1
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229940017705 formaldehyde sulfoxylate Drugs 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- ZKIAYSOOCAKOJR-UHFFFAOYSA-M lithium;2-phenylethenesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 ZKIAYSOOCAKOJR-UHFFFAOYSA-M 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- XMYQHJDBLRZMLW-UHFFFAOYSA-N methanolamine Chemical group NCO XMYQHJDBLRZMLW-UHFFFAOYSA-N 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- ZUHZZVMEUAUWHY-UHFFFAOYSA-N n,n-dimethylpropan-1-amine Chemical compound CCCN(C)C ZUHZZVMEUAUWHY-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- SFBTTWXNCQVIEC-UHFFFAOYSA-N o-Vinylanisole Chemical compound COC1=CC=CC=C1C=C SFBTTWXNCQVIEC-UHFFFAOYSA-N 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007717 redox polymerization reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000010352 sodium erythorbate Nutrition 0.000 description 1
- 239000004320 sodium erythorbate Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
Definitions
- the present invention relates to an ink which can be used in various printing methods including, for example, an inkjet printing method.
- an ink containing, for example, a pigment can be used when printing images of letters, pictures, patterns, or the like on recording media including cloths such as woven fabric, nonwoven fabric, and knitted fabric, plain paper, and coated paper.
- an ink which is obtained by mixing a binder resin and other additives into an aqueous pigment dispersion containing a pigment at a high concentration, which is diluted with water as needed.
- a printing ink which has a polyurethane resin as a binder resin, used in printing on a cloth has been known (see, for example, Patent Literature 1) .
- a method using an inkjet recording apparatus As a printing method for the ink on a recording medium, for example, a method using an inkjet recording apparatus has been known.
- the printing method using an inkjet recording apparatus has advantages in that the formation of a printing plate for each picture or pattern to be printed is not needed, and that the cost and the time to delivery in small-size lot printing can be reduced, and thus the use of the method in the production of fiber products, such as clothes and a curtain, is studied.
- printed surfaces may come into contact with each other or the printed surfaces may come into contact with other articles during a printing process or a process of use, or may be washed together with a detergent liquid.
- the printed surface may be peeled off or rubbed over time, resulting in poor appearance.
- the aforementioned problems can also occur when plain paper or coated paper is used as a recording medium.
- the printed surface and a conveying roll come into contact with each other inside a printer, the printed surface may be rubbed, resulting in poor appearance of a printed matter.
- a problem to be solved by the invention is to provide an ink which has rub fastness at a level where the printed surface will not be peeled off or rubbed even when, for example, printed surfaces come into contact with each other or the printed surfaces come into contact with other articles and the like during the printing process on fiber products such as clothing or a recording medium such as plain paper, or during the process of using the printed matter, and has discharge stability at a level that will not cause clogging of an ink nozzle or abnormalities in the ink discharge direction of an inkjet recording apparatus, and also form a printed image or the like having washing fastness at a level where the image will not be removed from a recording medium, such as a cloth, even when, for example, washed with water, warm water, or in a liquid containing a detergent or the like.
- the inventors of the invention have solved the problems by an ink in which a polymer (B) having an aromatic ring structure is dispersed in water (C) by a polymer (A) having a carboxyl group or a functional group in which a carboxyl group is neutralized by some basic compounds and a structural unit represented by the following general formula (1) .
- the ink of the invention can be used in the production of a printed matter having excellent rub fastness and remarkable washing fastness. Moreover, since the ink has discharge stability at a level that will not cause clogging of an ink nozzle or abnormalities in the ink discharge direction of an inkjet recording apparatus, the ink can be suitably used for inkjet printing on a recording medium such as a cloth.
- the ink of the invention is an ink in which a polymer (B) having an aromatic ring structure is dispersed in water (C) by a polymer (A) having a carboxyl group or a functional group in which a carboxyl group is neutralized by some basic compounds and a structural unit represented by the following general formula (1) .
- the ink of the invention By using the ink of the invention, it is possible to produce a printed matter having excellent rub fastness even when the drying time after printing is short while maintaining good discharge stability of the ink, and having high coloring property when printed on a recording medium such as plain paper. Moreover, the printed matter obtained by using the ink of the invention not only has excellent rub fastness when the drying time after printing is short as described above, but also has further excellent rub fastness by being sufficiently dried. Moreover, by using the ink of the invention, it is possible to produce a printed matter having washing fastness at a very high level while maintaining good discharge stability of the ink even when it is used in printing on a cloth.
- the polymer (A) is used to stably disperse the polymer (B) in water (C) . Therefore, unlike a pigment-dispersing resin to be described later, the polymer (A) does not substantially contribute to the improvement of the dispersibility of a pigment to be described later in water (C) .
- the polymer (A) and the polymer (B) exist in a form of particles in water (C) .
- the particles of the polymer (A) exist on the surface of the particles of the polymer (B) , thus forming one dispersion (X) .
- the polymer (A) may be in a state of being adsorbed on the surface of the particles of the polymer (B) .
- the polymer (A) may be in a state where a film is formed on the surface of the particles of the polymer (B) .
- the dispersed particle size of the dispersion (X) is preferably in the range of 20 nm to 1000 nm, more preferably in the range of 200 nm to 600 nm, and particularly preferably in the range of 240 nm to 500 nm in view of preventing the deterioration of ink discharge stability due to an increase in ink viscosity and, in particular, preventing kogation (a phenomenon in which components contained in ink are adsorbed on heated parts in the head and hinder the generation of bubbles which should have been a driving force for ink discharge) of thermal-type inkjet printing heads.
- the volume average particle size refers to a value measured by a dynamic light scattering method.
- the dispersion (X) containing the polymer (A) and the polymer (B) plays a role as a so-called binder resin.
- a binder resin is generally used for the purpose of improving the rub fastness and washing fastness of a printed matter.
- a binder resin having a volume average particle size of about 5 nm to 20 nm is conventionally used.
- the binder resin having a very small volume average particle size as described above tends to increase the dynamic viscosity of the ink, and as a result, the discharge stability of the ink may be lowered.
- the emulsion resin is usually produced by an emulsion polymerization method using an emulsifier, and thus the emulsion resin contains an emulsifier.
- the emulsifier may cause the aforementioned kogation.
- the dispersed particle size of the dispersion (X) is controlled to be larger than that of a conventional one, and thus it is possible to maintain good ink discharge stability and produce a printed matter having excellent rub fastness. Moreover, it is possible to produce a printed matter having washing fastness at a very high level by being used in printing on a cloth. Moreover, since the ink of the invention can reduce the amount of the emulsifier used as described above, the ink has an effect that it is unlikely to cause kogation even when applied to a thermal-type inkjet printing method.
- the ink of the invention does not exclude the use of emulsifiers as described above.
- the content of the emulsifier is preferably in the range of 0 to 1%by mass, more preferably in the range of 0 to 0.5%by mass, further more preferably in the range of 0 to 0.01%by mass, and particularly preferably 0%by mass, based on the total amount of the ink of the invention.
- polymer (A) a polymer having a carboxyl group or a functional group in which a carboxyl group is neutralized by some basic compounds and a structural unit represented by the following general formula (1) is used.
- the functional group –SO 3 M in the structural unit represented by the general formula (1) represents a sulfonic acid group or a sulfonic acid alkali metal salt group.
- polymer (A) a polymer obtained by radical polymerization of a monomer having a polymerizable unsaturated double bond may be used as the polymer (A) .
- a vinyl monomer having a carboxyl group for introducing a carboxyl group into the polymer (A) and a vinyl monomer for introducing the structure represented by the general formula (1) into the polymer (A) may be used in combination, with other vinyl monomers as needed.
- vinyl monomer having a carboxyl group for example, acrylic acid, methacrylic acid, ⁇ -carboxyethyl (meth) acrylate, 2- (meth) acryloyl propionic acid, crotonic acid, itaconic acid, maleic acid, fumaric acid, itaconic acid half ester, maleic acid half ester, ⁇ - (meth) acryloyloxyethyl hydrogen succinate, ⁇ - (meth) hydroxyethyl hydrogen phthalate, salts thereof, and acid anhydrides such as maleic anhydride may be used alone or in combination of two or more. Among them, it is preferable to use acrylic acid and methacrylic acid in view of obtaining a printed matter having excellent rub fastness and having high coloring property when printed on a recording medium such as plain paper.
- the vinyl monomer having a carboxyl group is preferably used, based on the total amount of the monomers used in the production of the polymer (A) , in the range of 1%by mass to 80%by mass, more preferably in the range of 5%by mass to 70%by mass, and is preferably used in the range of 10 to 50%by mass in view of obtaining an ink capable of producing a printed matter having all of more excellent rub fastness, washing fastness and coloring property.
- the vinyl monomer for introducing the structural unit represented by the general formula (1) into the polymer (A) for example, styrene sulfonic acid, an alkali metal salt of styrene sulfonic acid, or the like may be used.
- alkali metal salt of styrene sulfonic acid a sodium styrene sulfonate, a lithium styrene sulfonate, or the like may be used.
- the vinyl monomer for introducing the structural unit represented by the general formula (1) into the polymer (A) is preferably used, based on the total amount of the monomers used in the production of the polymer (A) , in the range of 1%by mass to 90%by mass, and is preferably used in the range of 40 to 90%by mass in view of obtaining an ink capable of producing a printed matter having both more excellent rub fastness and coloring property.
- a monomer having a phosphorus atom may be used as the other monomers that can be used in the production of the polymer (A) .
- Examples of the monomer having a phosphorus atom include 2- (meth) acryloyloxyethyl acid phosphate (for example, “Light Ester P-1M” , “Light Acrylate P-1A” , etc. manufactured by Kyoeisha Chemical Co., Ltd. ) , bis (2- (meth) acryloyloxyethyl) acid phosphate, phosphate ester of polyalkylene glycol mono (meth) acrylate such as phosphate ester of polyethylene glycol monomethacrylate (for example, “Sipomer PAM100” , “Sipomer PAM4000” , etc. manufactured by Rhodia Nicca, Ltd.
- 2- (meth) acryloyloxyethyl acid phosphate for example, “Light Ester P-1M” , “Light Acrylate P-1A” , etc. manufactured by Kyoeisha Chemical Co., Ltd.
- phosphate ester of polyethylene glycol monoacrylate for example, “Sipomer PAM5000” , etc. manufactured by Rhodia Nicca, Ltd.
- phosphate ester of polypropylene glycol monomethacrylate for example, “Sipomer PAM200” , etc. manufactured by Rhodia Nicca, Ltd.
- phosphate ester of polypropylene glycol monoacrylate for example, “Sipomer PAM300” etc. manufactured by Rhodia Nicca, Ltd.
- alkylene phosphate (meth) acrylate such as methylene phosphate (meth) acrylate, trimethylene phosphate (meth) acrylate, propylene phosphate (meth) acrylate, and tetramethylene phosphate (meth) acrylate, etc.
- examples of the other monomers include (meth) acrylic acid esters such as methyl (meth) acrylate, n-butyl (meth) acrylate, isobutyl (meth) acrylate, t-butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, hexyl (meth) acrylate, cyclohexyl (meth) acrylate, octyl (meth) acrylate, nonyl (meth) acrylate, dodecyl (meth) acrylate, stearyl (meth) acrylate, isobornyl (meth) acrylate, dicyclopentanyl (meth) acrylate, phenyl (meth) acrylate, and benzyl (meth) acrylate; vinyl esters such as vinyl acetate, vinyl propionate, vinyl butyrate, and vinyl versatate; vinyl ethers such as methyl vinyl ether,
- the polymer (A) may be produced by, for example, supplying a mixture of the aforementioned vinyl monomers in a lump or in a divided manner in the presence of water (C) or, when necessary, a polymerization initiator or a chain transfer agent, and subjecting the mixture to radical polymerization.
- polymerization initiator examples include persulfates such as potassium persulfate, sodium persulfate, and ammonium persulfate, peroxides such as benzoyl peroxide, cumene hydroperoxide, and t-butyl hydroperoxide, hydrogen peroxide, redox polymerization initiators combining the aforementioned peroxide and a reducing agent, azo-based initiators such as 4, 4’-azobis (4-cyanovaleric acid) and 2, 2’-azobis (2-amidinopropane) dihydrochloride, etc.
- the reducing agent examples include ascorbic acid, erythorbic acid, sodium erythorbate, a metal salt of formaldehyde sulfoxylate, sodium thiosulfate, and sodium bisulfite.
- ammonium persulfate is preferably used as the polymerization initiator in view of improving the production efficiency of the polymer (A) .
- chain transfer agent examples include thiomalic acid, thioglycerin and the like, and these may be used alone or in combination of two or more. It is preferable to use thiomalic acid in view of obtaining an ink capable of producing a printed matter having excellent dispersion stability and excellent coloring property.
- the production of the polymer (A) is usually preferably carried out in a temperature of 30°C to 100°C for 1 hour to 40 hours.
- the polymer (A) is preferably produced in the presence of an inert gas such as nitrogen gas in order to promptly polymerize the vinyl monomers.
- the polymer (A) may be neutralized by mixing with some basic compounds as a neutralizing agent, when necessary, after the polymerization of the monomers.
- Examples of the basic compound include alkali metal compounds such as sodium hydroxide and potassium hydroxide; alkaline earth metal compounds such as calcium hydroxide and calcium carbonate; ammonia; organic amines such as monomethylamine, dimethylamine, trimethylamine, monoethylamine, diethylamine, triethylamine, monopropylamine, dimethylpropylamine, monoethanolamine, diethanolamine, dimethylethanolamine, triethanolamine, ethylenediamine, and diethylenetriamine, etc. These may be used alone or in combination of two or more, and it is preferable to use ammonia or aqueous ammonia in view of obtaining an ink capable of producing a printed matter having excellent dispersion stability and excellent coloring property.
- alkali metal compounds such as sodium hydroxide and potassium hydroxide
- alkaline earth metal compounds such as calcium hydroxide and calcium carbonate
- ammonia organic amines such as monomethylamine, dimethylamine, trimethylamine, monoethylamine, diethylamine
- a composition in which the polymer (A) is dissolved or dispersed in water (C) can be produced by the above method.
- the polymer (A) obtained by the above method it is preferable to use a polymer having a weight average molecular weight of 1000 to 20000, and it is preferable to use a polymer having a weight average molecular weight of 3000 to 15000 in view of obtaining an ink capable of producing a printed matter having all of more excellent rub fastness, washing fastness and coloring property.
- the polymer (B) a polymer having an aromatic ring structure is used.
- a printed matter obtained by using the ink of the invention can be imparted with excellent rub fastness.
- the aromatic ring structure is used preferably in the range of 5%by mass to 70%by mass, more preferably in the range of 10%by mass to 50%by mass based on the total amount of the polymer (B) , and the aromatic ring structure in the range of 10%by mass to 40%by mass is preferably used in view of obtaining a printed matter having more excellent washing fastness and rub fastness.
- aromatic ring structure for example, a structure derived from styrene or the like can be mentioned. Among them, a structure derived from styrene is preferred in view of obtaining a printed matter having washing fastness at a very high level.
- the polymer (B) preferably contains the structure represented by the following general formula (2) , based on the total amount of the polymer (B) , in the range of 30%by mass to 90%by mass, more preferably in the range of 40%by mass to 80%by mass, and preferably in the range of 40%by mass to 70%by mass in view of obtaining a printed matter having more excellent washing fastness and rub fastness.
- R 1 and R 2 in the general formula (2) represents a alkyl group having 2 to 5 carbon atoms.
- polymer (B) examples include various polymers such as a vinyl polymer (b) , polyurethane, and polyester. Among them, it is preferable to use the vinyl polymer (b) as the polymer (B) .
- vinyl polymer (b) a polymer of vinyl monomers such as styrene, or (meth) acrylic monomers or the like can be used.
- styrene As the vinyl monomer, styrene, ⁇ -methylstyrene, vinylnaphthalene, vinylanthracene, vinylpyrene, vinyltoluene or the like can be used for introducing the aromatic ring structure into the polymer (B) .
- Styrene is preferably used in view of obtaining a printed matter having washing fastness at a very high level.
- the (meth) acrylic monomer it is preferable to use ethyl (meth) acrylate, n-butyl (meth) acrylate, isobutyl (meth) acrylate, t-butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, hexyl (meth) acrylate in view of introducing the structural unit represented by the general formula (2) into the polymer (B) .
- (meth) acrylic monomer in addition to the ethyl (meth) acrylate or the like, other vinyl monomers may be used as needed, and examples thereof include (meth) acrylic acid esters such as methyl (meth) acrylate, cyclohexyl (meth) acrylate, octyl (meth) acrylate, nonyl (meth) acrylate, dodecyl (meth) acrylate, stearyl (meth) acrylate, isobornyl (meth) acrylate, dicyclopentanyl (meth) acrylate, phenyl (meth) acrylate, and benzyl (meth) acrylate, and vinyl monomers having a hydroxyl group such as 2-hydroxyethyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate.
- acrylic acid esters such as methyl (meth) acrylate, cyclohexyl (meth) acrylate, oc
- the vinyl polymer (b) can be produced by polymerizing a mixture of vinyl monomers containing the ethyl (meth) acrylate.
- the ink of the invention is an ink in which the polymer (B) is dispersed in water (C) by the polymer (A) . Therefore, the polymer (B) is preferably produced in the presence of the polymer (A) in view of obtaining an ink capable of producing a printed matter having excellent dispersion stability and excellent rub fastness.
- examples of a method for producing the polymer (B) include a method of supplying an (meth) acrylic monomer or the like included in the vinyl polymer (b) in a lump or in a divided manner to a composition in which the polymer (A) is dissolved or dispersed in water (C) , and subjecting the mixture to polymerization.
- the ink of the invention preferably contains the polymer (A) and the polymer (B) in a total amount, based on the total amount of the ink, in the range of 0.1%by mass to 30%by mass, more preferably in the range of 0.1%by mass to 20%by mass, and particularly preferably in the range of 0.5%by mass to 10%by mass in view of obtaining an ink capable of producing a printed matter having more excellent rub fastness.
- the mass ratio of the polymer (A) to the polymer (B) [polymer (A) /polymer (B) ] is preferably in the range of 1/100 to 30/100, and more preferably in the range of 1/100 to 20/100 in view of obtaining an ink capable of producing a printed matter having more excellent rub fastness.
- the water (C) pure water such as ion-exchanged water, ultra-filtered water, reverse-osmosed membrane treated water, and distilled water, or ultrapure water can be used.
- water water sterilized by irradiation with ultraviolet rays or by addition of hydrogen peroxide or the like is preferably used because it is possible to prevent the generation of fungi or bacteria when the ink of the invention is stored for a long period of time.
- the water (C) is preferably contained in the range of 40%by mass to 95%by mass, and more preferably contained in the range of 50%by mass to 90%by mass in view of obtaining an ink capable of producing a printed matter having both more excellent rub fastness and coloring property.
- An ink containing, in addition to the polymer (A) , the polymer (B) , and water (C) , other components as needed can be used as the ink of the invention.
- the other components include a coloring material such as a pigment and a dye, a pigment-dispersing resin, a binder resin other than the polymer (A) and the polymer (B) , a solvent other than the water (C) , a wetting agent, a lubricant, an alkaline agent, a pH adjustor, a surfactant, an antiseptic agent, a chelating agent, a plasticizer, an antioxidant, a wax, an ultraviolet light absorber, and the like.
- a binder resin other than the polymer (A) and the polymer (B) a vinyl-based copolymer having an anionic group, such as the polyester resin having an anionic group, an epoxy resin having an anionic group, a urethane resin having an anionic group, an acrylic acid resin having an anionic group, a maleic acid resin having an anionic group, a styrene resin having an anionic group, and a polyvinyl acetic acid-based resin having an anionic group.
- a urethane resin having an anionic group in view of obtaining an ink capable of producing a printed matter having more excellent rub fastness and washing fastness.
- an organic pigment or an inorganic pigment can be used alone or in combination of two or more.
- organic pigment examples include quinacridone pigments, quinacridone quinone pigments, dioxazine pigments, phthalocyanine pigments, phthalone pigments, isoindolinone pigments, methane/azomethine pigments, azo pigments, disazo pigments, anthrapymidin pigments, anthanthrone pigments, indanthrone pigments, flavanthrone pigments, perylene pigments, diketopyrrolopyrrole pigments, perinone pigments, quinophthalone pigments, anthraquinone pigments, thioindigo pigments, benzimidazolone pigments, azo lake pigments, insoluble azo pigments, condensed azo pigments, etc.
- the inorganic pigment examples include titanium dioxide, zinc oxide, iron oxide, chromium oxide, iron black, cobalt blue, alumina white, iron oxide yellow, viridian, zinc sulfide, lithobon, cadmium yellow, vermilion, cadmium red, chrome yellow, molybdate orange, zinc chromate, strontium chromate, white carbon, clay, talc, ultramarine, precipitated barium sulfate, barite powder, calcium carbonate, white lead, dark blue, manganese violet, carbon black, aluminum powder, pearl pigments, etc.
- a pigment which can be self-dispersed in water can also be used as the pigment.
- the pigment is preferably used, based on the total amount of the ink, in the range of 0.1%by mass to 20%by mass, and more preferably used in the range of 1%by mass to 10%by mass in view of obtaining an ink having excellent storage stability and having excellent discharge stability when applied to an inkjet printing method.
- the pigment When the pigment is used as the coloring material, it is preferable to use a pigment-dispersing resin in order to stably disperse the pigment in the water (C) .
- the pigment-dispersing resin imparts dispersion stability to the pigment in water (C) by adsorbing around the particles of the pigment.
- a pigment-dispersing resin having an anionic group can be used as the pigment-dispersing resin.
- the anionic group include a carboxyl group, a sulfonate group, a phosphate group, etc.
- a resin having a hydrophobic structural unit and a hydrophilic structural unit derived from an anionic group is particularly preferable to use as the pigment-dispersing resin having an anionic group in view of obtaining an ink having a high degree of freedom in designing a structure that maintains the stability of the ink of the invention and capable of forming a printed matter having excellent coloring property when printed on plain paper.
- the pigment-dispersing resin can use a resin having a structural unit derived from styrene and a structural unit derived from acrylic acid.
- the resin having a hydrophobic structural unit and a hydrophilic structural unit derived from an anionic group it is preferable to use a resin having an acid value in the range of 60 to 300 mgKOH/g, and suitable in the range of 100 to 250 mgKOH/g in view of balancing pigment dispersibility, ink stability, and high print density.
- the resin having a hydrophobic structural unit and a hydrophilic structural unit derived from an anionic group it is preferable to use a resin having a weight average molecular weight in the range of 3000 to 50000, more preferably in the range of 4000 to 40000, further more preferably in the range of 5000 to 30000, and particularly preferably in the range of 5000 to 20000.
- the resin having a hydrophobic structural unit and a hydrophilic structural unit derived from an anionic group is preferably a resin that can have water dispersibility by neutralizing the anionic group, and preferably a resin that has the ability to form stable aqueous dispersion particles under the action of some basic compounds serving as a neutralizing agent without using a dispersion stabilizer such as an emulsifier.
- an inorganic basic compound or an organic basic compound may be used as the basic compound that can be used for neutralizing the anionic group. It is preferable to use an inorganic basic compound as the basic compound in view of obtaining an ink having more excellent storage stability.
- alkali metal hydroxides, ammonium hydroxides and the like can be used, and alkali metal hydroxides such as potassium hydroxides and sodium hydroxides are preferably used in view of imparting the pigment with more excellent dispersion stability.
- an aqueous solution in which the inorganic basic compound has been previously dissolved or dispersed in water with a concentration of 10%by mass to 60%by mass can be used.
- examples of the organic basic compound include amines such as methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, diethanolamine, and triethanolamine. These amines are generally in a liquid state, and thus can be used as they are.
- the neutralization rate of the resin having an anionic group is preferably 50%or more, more preferably 70%or more, in view of improving the dispersion rate in water (C) and ensuring good dispersion stability and long-term storage stability.
- the upper limit of the neutralization rate is not particularly limited; however, it is preferably 200%or less, more preferably 120%or less so that, substantially, the ink is stable and does not gel even when stored for a long period of time.
- the neutralization rate refers to a value calculated by the following formula.
- Neutralization rate (%) [ ⁇ mass of basic compound (g) ⁇ 56.11 ⁇ 1000 ⁇ / ⁇ acid value of pigment-dispersing resin (mgKOH/g) ⁇ equivalent of basic compound ⁇ mass of pigment-dispersing resin (g) ⁇ ] ⁇ 100
- the pigment-dispersing resin for example, a vinyl-based copolymer having an anionic group such as the polyester resin having an anionic group, an epoxy resin having an anionic group, a urethane resin having an anionic group, an acrylic acid resin having an anionic group, a maleic acid resin having an anionic group, a styrene resin having an anionic group, and a polyvinyl acetic acid-based resin having an anionic group can be used.
- a vinyl-based copolymer having an anionic group such as the polyester resin having an anionic group, an epoxy resin having an anionic group, a urethane resin having an anionic group, an acrylic acid resin having an anionic group, a maleic acid resin having an anionic group, a styrene resin having an anionic group, and a polyvinyl acetic acid-based resin having an anionic group can be used.
- pigment-dispersing resin examples include poly (meth) acrylic acid, vinyl acetate-acrylic acid ester copolymers, acrylic acid-acrylic acid alkyl ester copolymers, styrene- (meth) acrylic acid copolymers, styrene- (meth) acrylic acid-acrylic acid alkyl ester copolymers, styrene-maleic acid copolymers, vinyl acetate-maleic acid ester copolymers, vinyl acetate-crotonic acid copolymers, and vinyl acetate-acrylic acid copolymers.
- wetting agent examples include ethers of polyhydric alcohols such as ethylene glycol and glycerol, ethers of polyhydric alcohols such as ethylene glycol monoethyl ether and ethylene glycol monobutyl ether; polyoxyalkylene adducts of glycerin; nitrogen-containing heterocyclic compounds such as N-methyl-2-pyrrolidone and ⁇ -butyrolactone; amides such as N, N-dimethylformamide; organic amines such as triethylamine, sulfur-containing compounds such as dimethyl sulfoxide, propylene carbonate, ethylene carbonate, etc., and these may be used alone or in combination of two or more.
- polyhydric alcohols such as ethylene glycol and glycerol
- ethers of polyhydric alcohols such as ethylene glycol monoethyl ether and ethylene glycol monobutyl ether
- polyoxyalkylene adducts of glycerin nitrogen-containing heterocycl
- the wetting agent it is preferable to use a wetting agent having a high boiling point in order to uniformly disperse the pigment and the pigment-dispersing resin, and it is more preferable to use polyhydric alcohols such as ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, triethylene glycol, polyethylene glycol, polypropylene glycol, glycerin, and polyethylene oxide adduct of glycerin.
- polyhydric alcohols such as ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, triethylene glycol, polyethylene glycol, polypropylene glycol, glycerin, and polyethylene oxide adduct of glycerin.
- the wetting agent is preferably used in the range of 10%by mass to 1000%by mass, more preferably 30%by mass to 200%by mass, based on the total amount of the pigment.
- an ink containing the pigment and the pigment-dispersing resin is used as the ink of the invention
- a method for producing the ink of the invention for example, a production method of mixing an aqueous pigment dispersion obtained by mixing the pigment, the pigment-dispersing resin, and water (C) in advance, with a composition containing the polymer (A) , the polymer (B) , and water (C) can be mentioned.
- the aqueous pigment dispersion can be produced by going through, for example, a step [1] of kneading a composition containing the pigment, the pigment-dispersing resin, and some basic compounds or a wetting agent as needed, and a step [2] of diluting and dispersing the kneaded product obtained in step [1] in water (C) , etc.
- the affinity of the pigment-dispersing resin with the pigment becomes extremely good, the dispersion stability of the aqueous pigment dispersion is improved, and it is possible to improve the gloss, durability, water resistance and the like of a printed matter formed by printing the ink obtained by using the pigment dispersion on a recording medium.
- an apparatus such as a roll mill, a Henschel mixer, a pressure kneader, and a planetary mixer can be used.
- An apparatus such as a Henschel mixer, a pressure kneader, and a planetary mixer which has a stirring tank that can be sealed and stirring blades is preferably used because it is possible to keep the solid content ratio of the composition in the step [1] constant and obtain a kneaded product having a good dispersed state.
- a planetary mixer is preferably used because the kneading treatment can be performed in a wide range of viscosity regions.
- step [2] is a step of diluting and dispersing the kneaded product obtained in the step [1] in water (C) .
- the aqueous pigment dispersion obtained by the above method is preferably subjected to a centrifugal separation treatment or a filtration treatment to remove coarse particles or agglomerated particles derived from raw materials of the pigment and the like, in view of preventing the occurrence of clogging of the ink nozzle when the ink of the invention is applied to an inkjet printing method.
- the ink of the invention there can be mentioned a method of mixing the aqueous pigment dispersion obtained by the above method and a composition in which the polymer (B) is dispersed in water (C) by the polymer (A) and stirring for 30 to 90 minutes, etc.
- the ink of the invention obtained by the above method for example, it is preferable to use an ink having a viscosity in the range of 1 mPa ⁇ sec to 10 mPa ⁇ sec. In particular, it is more preferable to use an ink having a viscosity of 1 mPa ⁇ sec to 6 mPa ⁇ sec in the case where the ink of the invention is discharged by an inkjet printing method which will be described later.
- the ink of the invention can be used for printing on a recording medium.
- Examples of the recording medium include coated paper having an ink absorbing layer which easily absorbs the ink solvent and fixes pigments and the like on the surface, coated paper provided with a layer that does not easily absorb the ink solvent, plain paper, cloth, etc.
- an inkjet printer capable of duplex printing is used for printing on a recording medium
- a single-sided printed matter with on one side (front side) of the recording medium printed is dried for a certain period of time, and is then inverted by a conveying roll and a reversing mechanism inside the printer to have the other side (back side) of the single-sided printed matter printed.
- the conveying roll or the like comes into contact with the printed side of the single-sided printed matter, the printed side may be scratched, causing deterioration of print quality.
- duplex printing is performed on coated paper, which is less likely to absorb the solvent in the ink as compared with plain paper, there is a concern that the print quality may be deteriorated.
- the ink of the invention is excellent in rub fastness even in duplex printing on coat paper or plain paper, and thus it is not easily scratched, and further, it is possible to effectively prevent a deterioration in coloring property when printed on plain paper.
- the ink of the invention can be suitably used for printing using a cloth as the recording medium.
- the polymer (B) dispersed in water (C) by the polymer (A) contained in the ink of the invention has a high affinity with fibers constituting the cloth due to the influence of the aromatic ring structure.
- the ink does not easily come off from the cloth even when the printed matter is washed with water, warm water, or a detergent liquid, and it is possible to maintain a printed image having a high color density even after washing.
- the ink having high affinity with the cloth is always slightly hydrophobic, it is sometimes not suitable for inkjet printing method.
- the ink of the invention can be used to produce a printed matter having washing fastness at a very high level without compromising the excellent discharge stability even when inkjet printing method is used.
- the printed matter printed using the ink of the invention can have both excellent rub fastness, washing fastness and high coloring property.
- the ink of the invention can be applied to various printing methods, it can be suitably used exclusively for printing by an inkjet printing method.
- Examples of the inkjet printing method include a continuous injection type (a charge control type, a spray type, etc. ) , an on-demand type (a piezo method, a thermal method, an electrostatic suction method, etc. ) , etc., and the ink of the invention is suitable for printing by a thermal type inkjet printing method.
- this water-based ink for inkjet recording basically enables extremely stable ink discharge, and further, can achieve excellent scratch resistance and rub fastness of a formed image.
- the contents in the polymerization vessel were cooled to 40°C or lower and mixed with aqueous ammonia to obtain an aqueous solution (I-1) of a polymer (A-1) .
- a mixture forming a polymer (B-1) including 65 parts by mass of ethyl acrylate, 5 parts by mass of styrene, and 30 parts by mass of 2-hydroxyethyl methacrylate, and 5 parts by mass of a 10 mass%ammonium persulfate aqueous solution were added dropwise for 4 hours to the aqueous solution (I-1) of the polymer (A-1) which had been adjusted to 80°C, and were maintained for 1 hour to allow polymerization.
- aqueous ammonia was supplied to the reaction vessel to adjust the pH of the contents to 7, and the reaction vessel was mixed for 1 hour, so that a dispersion (II-1) having a non-volatile content of 40%by mass in which the polymer (B-1) was dispersed in water by the polymer (A-1) was obtained.
- the volume average particle size of dispersing elements contained in the dispersion (II-1) was 350 nm.
- the volume average particle size was calculated using NANOTRAC WAVE II manufactured by MicrotracBEL Corp. First, the dispersion was diluted 1000 times with ion-exchanged water. Then, approximately 4 ml of the diluted dispersion was placed in a cell, and the volume average particle size (MV) was measured by detecting scattered light of laser light in an environment of 25°C using the NANOTRAC WAVE II manufactured by MicrotracBEL Corp. The volume average particle size was measured three times to calculate an average value (integer) . The value obtained by truncating the first digit of the average value was taken as the value of the volume average particle size (unit: nm) .
- a dispersion (II-2) having a non-volatile content of 40%by mass in which a polymer (B-2) was dispersed in water by a polymer (A-2) was obtained by the same method as in Synthetic Example 1 except that 65 parts by mass of ethyl acrylate was changed to 65 parts by mass of n-butyl acrylate.
- the volume average particle size of dispersing elements contained in the dispersion (II-2) was 310 nm.
- a dispersion (II-3) having a non-volatile content of 40%by mass in which a polymer (B-3) was dispersed in water by a polymer (A-3) was obtained by the same method as in Synthetic Example 1 except that 65 parts by mass of ethyl acrylate was changed to 65 parts by mass of isobutyl acrylate.
- the volume average particle size of dispersing elements contained in the dispersion (II-3) was 320 nm.
- a dispersion (II-4) having a non-volatile content of 40%by mass in which a polymer (B-4) was dispersed in water by a polymer (A-4) was obtained by the same method as in Synthetic Example 1 except that the amount of ethyl acrylate used was changed from 65 parts by mass to 40 parts by mass and the amount of styrene used was changed from 5 parts by mass to 30 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-4) was 370 nm.
- a dispersion (II-5) having a non-volatile content of 40%by mass in which a polymer (B-5) was dispersed in water by a polymer (A-5) was obtained by the same method as in Synthetic Example 1 except that the amount of ethyl acrylate used was changed from 65 parts by mass to 40 parts by mass, the amount of styrene used was changed from 5 parts by mass to 30 parts by mass, and aqueous potassium hydroxide solution was used instead of aqueous ammonia to adjust the pH to 7.
- the volume average particle size of dispersing elements contained in the dispersion (II-5) was 340 nm.
- a dispersion (II-6) having a non-volatile content of 40%by mass in which a polymer (B-6) was dispersed in water by a polymer (A-6) was obtained by the same method as in Synthetic Example 1 except that the amount of methacrylic acid used was changed from 4.51 parts by mass to 1.03 parts by mass, 65 parts by mass of ethyl acrylate was changed to 71 parts by mass of n-butyl acrylate, the amount of styrene used was changed from 5 parts by mass to 19 parts by mass, and the amount of 2-hydroxyethyl methacrylate used was changed from 30 parts by mass to 10 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-6) was 340 nm.
- a dispersion (II-7) having a non-volatile content of 40%by mass in which a polymer (B-7) was dispersed in water by a polymer (A-7) was obtained by the same method as in Synthetic Example 1 except that 65 parts by mass of ethyl acrylate was changed to 71 parts by mass of n-butyl acrylate, the amount of styrene used was changed from 5 parts by mass to 19 parts by mass, and the amount of 2-hydroxyethyl methacrylate used was changed from 30 parts by mass to 10 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-7) was 380 nm.
- a dispersion (II-8) having a non-volatile content of 40%by mass in which a polymer (B-8) was dispersed in water by a polymer (A-8) was obtained by the same method as in Synthetic Example 1 except that the amount of methacrylic acid used was changed from 4.51 parts by mass to 1.03 parts by mass, the amount of ethyl acrylate used was changed from 65 parts by mass to 68 parts by mass, the amount of styrene used was changed from 5 parts by mass to 12 parts by mass, and the amount of 2-hydroxyethyl methacrylate used was changed from 30 parts by mass to 20 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-8) was 310 nm.
- a dispersion (II-9) having a non-volatile content of 40%by mass in which a polymer (B-9) was dispersed in water by a polymer (A-9) was obtained by the same method as in Synthetic Example 1 except that the amount of methacrylic acid used was changed from 4.51 parts by mass to 1.03 parts by mass, the amount of ethyl acrylate used was changed from 65 parts by mass to 68 parts by mass, the amount of styrene used was changed from 5 parts by mass to 12 parts by mass, and 30 parts by mass of 2-hydroxyethyl methacrylate was changed to 20 parts by mass of 3-hydroxypropyl methacrylate.
- the volume average particle size of dispersing elements contained in the dispersion (II-9) was 400 nm.
- a dispersion (II-10) having a non-volatile content of 40%by mass in which a polymer (B-10) was dispersed in water by a polymer (A-10) was obtained by the same method as in Synthetic Example 1 except that the amount of methacrylic acid used was changed from 4.51 parts by mass to 1.03 parts by mass, 65 parts by mass of ethyl acrylate was changed to 47 parts by mass of n-butyl acrylate, and the amount of styrene used was changed from 5 parts by mass to 23 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-10) was 280 nm.
- a dispersion (II-11) having a non-volatile content of 40%by mass in which a polymer (B-11) was dispersed in water by a polymer (A-11) was obtained by the same method as in Synthetic Example 1 except that 5 parts by mass of styrene was changed to 5 parts by mass of methyl methacrylate.
- the volume average particle size of dispersing elements contained in the dispersion (II-11) was 470nm.
- a dispersion (II-12) having a non-volatile content of 40%by mass in which a polymer (B-12) was dispersed in water by a polymer (A-12) was obtained by the same method as in Synthetic Example 11 except that the amount of methacrylic acid used was changed from 4.51 parts by mass to 1.03 parts by mass, the amount of ethyl acrylate used was changed from 65 parts by mass to 68 parts by mass, the amount of methyl methacrylate used was changed from 5 parts by mass to 12 parts by mass, and the amount of 2-hydroxyethyl methacrylate used was changed from 30 parts by mass to 20 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-12) was 320 nm.
- a dispersion (II-13) having a non-volatile content of 40%by mass in which a polymer (B-13) was dispersed in water by a polymer (A-13) was obtained by the same method as in Synthetic Example 11 except that the amount of methacrylic acid used was changed from 4.51 parts by mass to 1.03 parts by mass, the amount of ethyl acrylate used was changed from 65 parts by mass to 71 parts by mass, the amount of methyl methacrylate used was changed from 5 parts by mass to 19 parts by mass, and the amount of 2-hydroxyethyl methacrylate used was changed from 30 parts by mass to 10 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-13) was 290 nm.
- a dispersion (II-14) having a non-volatile content of 40%by mass in which a polymer (B-14) was dispersed in water by a polymer (A-14) was obtained by the same method as in Synthetic Example 11 except that the amount of methacrylic acid used was changed from 4.51 parts by mass to 1.03 parts by mass, and the pH was adjusted to 7 using an aqueous potassium hydroxide solution instead of using aqueous ammonia.
- the volume average particle size of dispersing elements contained in the dispersion (II-14) was 440 nm.
- a dispersion (II-15) having a non-volatile content of 40%by mass in which a polymer (B-15) was dispersed in water by a polymer (A-15) was obtained by the same method as in Synthetic Example 11 except that the amount of ethyl acrylate used was changed from 65 parts by mass to 40 parts by mass, and the amount of methyl methacrylate used was changed from 5 parts by mass to 30 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-15) was 390 nm.
- a dispersion (II-16) having a non-volatile content of 40%by mass in which a polymer (B-16) was dispersed in water by a polymer (A-16) was obtained by the same method as in Synthetic Example 11 except that the amount of methacrylic acid used was changed from 4.51 parts by mass to 1.03 parts by mass, the amount of ethyl acrylate used was changed from 65 parts by mass to 47 parts by mass, and the amount of methyl methacrylate used was changed from 5 parts by mass to 23 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-16) was 350 nm.
- a dispersion (II-18) of a polymer (A-18) having a non-volatile content of 40%by mass and an acid value of 25 mgKOH/g was obtained by the same method as in Synthetic Example 17 except that the amount of H12MDI used was changed from 181.7 parts by mass to 111.0 parts by mass, the amount of DMPA used was changed from 59.3 parts by mass to 23.2 parts by mass, and the amount of the 25 mass%aqueous potassium hydroxide solution used was changed from 94.4 parts by mass to 36.8 parts by mass.
- the volume average particle size of dispersing elements contained in the dispersion (II-18) was 5 nm.
- JONCRYL PDX-6137A manufactured by BASF SE, a styrene acrylic resin aqueous solution having a weight average molecular weight of 16,000, an acid value of 220 to 250, a glass transition point of 100°C, pH 7.8, and a non-volatile content of about 29%by mass
- a magenta pigment FASTOGEN Super Magenta RY, manufactured by DIC Corporation
- magenta aqueous pigment dispersing liquid having a magenta pigment concentration of 14.5%by mass and a concentration of triethylene glycol of 100%by mass with respect to the magenta pigment.
- the pH of the mixture was adjusted to be in the range of 9 to 9.8 using a 5 mass%aqueous potassium hydroxide solution, and the mixture was filtered through a filter having a pore size of 5 to 10 ⁇ m to obtain a total of 70 parts by mass of water-based ink M1 (magenta pigment concentration 3%by mass) .
- a water-based ink M2 was obtained by the same method as in Example 1 except that the dispersion (II-2) was used instead of the dispersion (II-1) .
- a water-based ink M3 was obtained by the same method as in Example 1 except that the dispersion (II-3) was used instead of the dispersion (II-1) .
- a water-based ink M4 was obtained by the same method as in Example 1 except that the dispersion (II-4) was used instead of the dispersion (II-1) .
- a water-based ink M5 was obtained by the same method as in Example 1 except that the dispersion (II-5) was used instead of the dispersion (II-1) .
- a water-based ink M6 was obtained by the same method as in Example 1 except that the dispersion (II-6) was used instead of the dispersion (II-1) .
- a water-based ink M7 was obtained by the same method as in Example 1 except that the dispersion (II-7) was used instead of the dispersion (II-1) .
- a water-based ink M8 was obtained by the same method as in Example 1 except that the dispersion (II-8) was used instead of the dispersion (II-1) .
- a water-based ink M9 was obtained by the same method as in Example 1 except that the dispersion (II-9) was used instead of the dispersion (II-1) .
- a water-based ink M10 was obtained by the same method as in Example 1 except that the dispersion (II-10) was used instead of the dispersion (II-1) .
- a water-based ink M11 was obtained by the same method as in Example 1 except that the dispersion (II-11) was used instead of the dispersion (II-1) .
- a water-based ink M12 was obtained by the same method as in Example 1 except that the dispersion (II-12) was used instead of the dispersion (II-1) .
- a water-based ink M13 was obtained by the same method as in Example 1 except that the dispersion (II-13) was used instead of the dispersion (II-1) .
- a water-based ink M14 was obtained by the same method as in Example 1 except that the dispersion (II-14) was used instead of the dispersion (II-1) .
- a water-based ink M15 was obtained by the same method as in Example 1 except that the dispersion (II-15) was used instead of the dispersion (II-1) .
- a water-based ink M16 was obtained by the same method as in Example 1 except that the dispersion (II-16) was used instead of the dispersion (II-1) .
- a water-based ink M17 was obtained by the same method as in Example 1 except that HYDRAN WLS-210 manufactured by DIC Corporation was used instead of the dispersion (II-1) .
- a water-based ink M18 was obtained by the same method as in Example 1 except that the dispersion (II-17) was used instead of the dispersion (II-1) .
- a water-based ink M19 was obtained by the same method as in Example 1 except that the dispersion (II-18) was used instead of the dispersion (II-1) .
- a water-based ink M20 was obtained by the same method as in Example 1 except that ion-exchanged water was used instead of the dispersion (II-1) .
- the printed paper was placed and attached on the rubbing area of fastness rubbing tester (RT-300S manufactured by Daiei Kagaku Seiki MFG. Co., Ltd. ) by plastic tape, and the surface of the printed paper was rubbed to-and-fro with a rubbing peg that was covered with another piece of the brochure &flyer paper under the condition of a loading weight of 200 g.
- fastness rubbing tester R-300S manufactured by Daiei Kagaku Seiki MFG. Co., Ltd.
- the rubbed surface of the printed paper was scanned and converted into image data, and the number of pixels in the remaining part of the color was counted. Referring to the entire area of the image was counted as 100 pixels, it was determined that the larger the number of pixels in the remaining part of the color is better the rub fastness.
- A The number of pixels in the remaining color part was more than 60.
- the number of pixels in the remaining color part was 40 or more and 60 or less.
- the number of pixels in the remaining color part was 20 or more and 40 or less.
- the ink obtained in Comparative Example 10 was filled in an ink cartridge.
- the ink was printed on an OHP sheet (a sheet with a layer that absorbs ink on the surface of the film) for inkjet with a print density of 100%using a commercially available thermal-jet inkjet printer to obtain a printed matter.
- a maximum absorbance (Abs 0 ) of the printed matter was measured with an ultraviolet and visible spectrophotometer (JASCO Corporation V-660 type) using the unprinted part of the OHP sheet as a reference.
- the inks were respectively printed on an OHP sheet for inkjet with a print density of 100%using a commercially available thermal-jet inkjet printer to obtain printed matters.
- a maximum absorbance (Abs 1 ) of the printed matters was measured with an ultraviolet and visible spectrophotometer (JASCO Corporation V-660 type) using the unprinted part of the OHP sheet as a reference.
- the ink obtained in Comparative Example 10 was applied to commercially available plain paper using bar coater No. 3, dried in an environment of 25°C for 1 hour, and then the optical density as benchmark (OD 0 ) of the printed area was measured by an integrating sphere spectrophotometer X-Rite (X-Rite, Inc. ) .
- a 5 cm ⁇ 5 cm square cotton cloth was immersed in the ink obtained in Examples and Comparative Examples and was dried at 150°C for 5 minutes to obtain a test samples. Then, the optical density (OD 0 ) of the test samples were measured using an integrating sphere spectrophotometer X-Rite.
- test samples were immersed in a detergent liquid at 50°C based on JIS L0844: 2011 for 30 minutes, and then the detergent liquid and the test samples were stirred for 1 minute with a food mixer. The samples were washed with water and dried at room temperature. Then, the optical density (OD 1 ) of the test samples were measured using an integrating sphere spectrophotometer X-Rite.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
Description
Claims (9)
- An ink in which a polymer (B) having an aromatic ring structure is dispersed in water (C) by a polymer (A) having a carboxyl group or a functional group in which a carboxyl group is neutralized by some basic compounds and a structural unit represented by the following general formula (1) .(M in the general formula (1) represents a hydrogen atom or an alkali metal. )
- The ink according to claim 1, wherein the polymer (A) is a polymer of a monomer mixture including a monomer having a carboxyl group or an acid anhydride thereof, and an alkali metal salt of styrene sulfonic acid.
- The ink according to claim 1 or 2, wherein the polymer (B) has a structural unit derived from styrene.
- The ink according to any one of claims 1 to 3, wherein a mass ratio of the polymer (A) to the polymer (B) [polymer (A) /polymer (B) ] is in a range of 1/100 to 30/100.
- The ink according to any one of claims 1 to 4, wherein the polymer (A) and the polymer (B) are contained in a total amount in a range of 0.1%by mass to 30%by mass, based on the total amount of the ink.
- The ink according to any one of claims 1 to 5, wherein a dispersion, in which the polymer (B) is dispersed in water (C) by the polymer (A) , has a volume average particle size of 20 nm to 1000 nm.
- The ink according to any one of claims 1 to 6, further including a pigment and a pigment-dispersing resin for dispersing the pigment in the water (C) .
- The ink according to any one of claims 1 to 7, which is used for printing in an inkjet printing method.
- The ink according to claim 8, wherein the inkjet printing method is a thermal type inkjet printing method.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2023538764A JP7448097B2 (en) | 2021-04-22 | 2021-04-22 | ink |
CN202180095198.4A CN117043287A (en) | 2021-04-22 | 2021-04-22 | Printing ink |
PCT/CN2021/088911 WO2022222090A1 (en) | 2021-04-22 | 2021-04-22 | Ink |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2021/088911 WO2022222090A1 (en) | 2021-04-22 | 2021-04-22 | Ink |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2022222090A1 true WO2022222090A1 (en) | 2022-10-27 |
Family
ID=83723622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2021/088911 WO2022222090A1 (en) | 2021-04-22 | 2021-04-22 | Ink |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP7448097B2 (en) |
CN (1) | CN117043287A (en) |
WO (1) | WO2022222090A1 (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6262152B1 (en) * | 1998-10-06 | 2001-07-17 | E. I. Du Pont De Nemours And Company | Particles dispersed w/polymer dispersant having liquid soluble and cross-linkable insoluble segments |
CN102675962A (en) * | 2011-03-16 | 2012-09-19 | 富士胶片株式会社 | Ink composite, ink group and inkjet imaging method |
US20130083117A1 (en) * | 2011-09-29 | 2013-04-04 | Fujifilm Corporation | Image forming method |
CN105418865A (en) * | 2015-12-23 | 2016-03-23 | 南京东开化工科技有限公司 | Novel high-molecular-block dispersing agent, preparation method and application thereof |
US20180216289A1 (en) * | 2015-08-03 | 2018-08-02 | Agfa Nv | Aqueous inkjet printing liquids |
CN112585013A (en) * | 2018-09-12 | 2021-03-30 | Dic株式会社 | Method for producing inkjet printed material |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008063475A (en) | 2006-09-08 | 2008-03-21 | Nippon Zeon Co Ltd | Polymer latex, resin for aqueous ink and resin composition for aqueous ink |
JP2010090191A (en) | 2008-10-03 | 2010-04-22 | Canon Inc | Water-based ink for use in inkjet printing, ink tank, recording unit, device and method for inkjet recording, and method for manufacturing water-based ink for inkjet printing |
JP5076187B2 (en) | 2008-12-22 | 2012-11-21 | 曙ブレーキ工業株式会社 | Drum brake device |
-
2021
- 2021-04-22 CN CN202180095198.4A patent/CN117043287A/en active Pending
- 2021-04-22 WO PCT/CN2021/088911 patent/WO2022222090A1/en active Application Filing
- 2021-04-22 JP JP2023538764A patent/JP7448097B2/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6262152B1 (en) * | 1998-10-06 | 2001-07-17 | E. I. Du Pont De Nemours And Company | Particles dispersed w/polymer dispersant having liquid soluble and cross-linkable insoluble segments |
CN102675962A (en) * | 2011-03-16 | 2012-09-19 | 富士胶片株式会社 | Ink composite, ink group and inkjet imaging method |
US20130083117A1 (en) * | 2011-09-29 | 2013-04-04 | Fujifilm Corporation | Image forming method |
US20180216289A1 (en) * | 2015-08-03 | 2018-08-02 | Agfa Nv | Aqueous inkjet printing liquids |
CN105418865A (en) * | 2015-12-23 | 2016-03-23 | 南京东开化工科技有限公司 | Novel high-molecular-block dispersing agent, preparation method and application thereof |
CN112585013A (en) * | 2018-09-12 | 2021-03-30 | Dic株式会社 | Method for producing inkjet printed material |
Also Published As
Publication number | Publication date |
---|---|
JP2023553506A (en) | 2023-12-21 |
JP7448097B2 (en) | 2024-03-12 |
CN117043287A (en) | 2023-11-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US9133359B2 (en) | Maintenance liquid for inkjet recording, ink set for inkjet recording, image forming method, and maintenance method | |
US20070157849A1 (en) | Recording liquids | |
CN106471070A (en) | Typography | |
CN107201082A (en) | Ink and its production method and ink storage container, printing process and printing equipment | |
JP6197494B2 (en) | Ink jet recording ink, ink cartridge, ink jet recording method, and ink jet recording apparatus | |
JP2022170110A (en) | Colorant dispersion, ink, ink set, and coated object | |
JP7395197B2 (en) | White pigment dispersion and related technology | |
JP7448097B2 (en) | ink | |
US20140378606A1 (en) | Aqueous pigment dispersions with components to interact with cellulose | |
WO2022126586A1 (en) | Ink | |
JP7135806B2 (en) | Inkjet ink, printed matter | |
US20070054979A1 (en) | Formulations and their use in the coloration of substrates | |
JP7139779B2 (en) | Inkjet ink and printed matter | |
EP3030619A2 (en) | Aqueous inkjet inks containing polymeric binders with components to interact with cellulose | |
JP7147992B2 (en) | ink | |
EP3030344A2 (en) | Aqueous pigment dispersions with components to interact with cellulose | |
JP6979142B1 (en) | Polymer dispersants and their manufacturing methods, water-based pigment dispersions, and water-based inkjet inks | |
JP7540427B2 (en) | Colorant dispersions, inks, ink sets, and prints | |
JP2024037025A (en) | Inkjet printing method | |
CN116137841A (en) | Coloring dispersion for inkjet, ink for inkjet recording, and inkjet recording method | |
EP4389833A1 (en) | Aqueous inkjet compositions including polymeric thickener | |
JP2008231131A (en) | Ink for inkjet |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 21937331 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2023538764 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 202180095198.4 Country of ref document: CN |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 21937331 Country of ref document: EP Kind code of ref document: A1 |