WO2022183587A1 - Inverted adsorption precipitation system and process based on classification and recovery of carbon sources - Google Patents

Inverted adsorption precipitation system and process based on classification and recovery of carbon sources Download PDF

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WO2022183587A1
WO2022183587A1 PCT/CN2021/092145 CN2021092145W WO2022183587A1 WO 2022183587 A1 WO2022183587 A1 WO 2022183587A1 CN 2021092145 W CN2021092145 W CN 2021092145W WO 2022183587 A1 WO2022183587 A1 WO 2022183587A1
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activated sludge
tank
adsorption tank
sludge
sewage
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Chinese (zh)
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张建
梁爽
王宁
孙丰凯
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Shandong University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1205Particular type of activated sludge processes
    • C02F3/1215Combinations of activated sludge treatment with precipitation, flocculation, coagulation and separation of phosphates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Definitions

  • the invention belongs to the technical field of environmental protection and sewage treatment, and in particular relates to an inverted adsorption precipitation system and process based on carbon source classification and recovery.
  • the granular carbon source that is easy to precipitate generally has a larger particle size, accounting for about 30% of the carbon source in the sewage, and this part of the carbon source can pass through. Precipitation is directly recycled, and the carbon sources that are not easy to precipitate are colloidal particles and dissolved carbon sources with small particle size in the sewage, accounting for about 70%. source organic carbon for recovery.
  • the recovery and recycling process of carbon sources in sewage is generally divided into three steps: first, the sewage is treated by grids and grit chambers to remove the garbage and sediment in it, providing a basis for recycling carbon sources in sewage; second, through Different carbon source recovery processes recover the carbon source in the sewage; finally, the recovered carbon source can be converted into resources and energy through anaerobic digestion and other methods.
  • the recovery process of carbon source is the core of the whole process, and its innovation and improvement are of great significance to the realization of sewage recycling.
  • the traditional activated sludge method is currently the most widely used sewage treatment technology. It utilizes the metabolism of activated sludge microorganisms to achieve longer sludge retention time (5-7d) and hydraulic retention time (>2h), lower organic Under the conditions of load (0.2-0.4kgBOD 5 /kgMLSS/d) and sufficient oxygen (DO>2mg/L), a large amount of carbon sources in sewage can be mineralized, and the effective recovery of carbon sources in sewage cannot be realized. "It makes the traditional activated sludge process unsustainable.
  • the high-load activated sludge method is currently the mainstream process for recycling carbon sources in sewage, which consists of a front adsorption tank and a rear sedimentation tank. After the sewage is pretreated by the grille and the grit chamber, it first enters the adsorption tank to be mixed with the activated sludge, adsorbed or absorbed by the activated sludge, and precipitated and concentrated in the sedimentation tank, and finally discharged through the excess sludge for recycling.
  • the high-load activated sludge method utilizes activated sludge under extremely short sludge retention time (0.3-0.5d), hydraulic retention time (30min) and extremely high organic load (2-6kg BOD 5 /kgMLSS/d).
  • the biological flocculation adsorption and precipitation concentration realize the enrichment and recovery of carbon sources in sewage, but the inventor found that such a recovery process is a mixed recovery of carbon sources in sewage (that is, various forms of carbon sources in sewage are mixed in sewage. At the same time, it is absorbed or absorbed by the sludge and then recovered), such a recovery method leads to the loss of a large amount of carbon sources (the lost carbon source accounts for about 30-50% of the total carbon source), and the carbon source recovery rate is very low, about 30%.
  • the present invention provides an inverted adsorption precipitation system and process based on the classification and recovery of carbon sources.
  • the overall process consists of a pre-sedimentation tank and a rear activated sludge adsorption tank.
  • the pre-sedimentation tank is mainly for the recovery of particulate carbon sources that are easy to precipitate in sewage, and the recycling cost of particulate carbon sources is minimized through the simplest precipitation method.
  • the removal of particulate carbon source significantly reduces the load pressure of the post-activated sludge adsorption tank, and on the other hand, the post-activated sludge adsorption tank can only adsorb and recover the remaining colloidal and dissolved carbon sources in the sewage. Efficiency is significantly improved.
  • the present invention provides an inverted adsorption and sedimentation system based on the classification and recovery of carbon sources, including: a sloping plate sedimentation tank and an activated sludge adsorption tank, wherein,
  • the bottom of the inclined plate sedimentation tank is funnel-shaped, the lowest end of the bottom is connected with the sludge pipe, the upper part of the middle is provided with a inclined plate, the side is provided with a first water inlet pipe, and the water inlet position is provided with a baffle plate , so that the influent water enters from the middle and lower part of the inclined plate sedimentation tank; a perforated overflow pipe is arranged above the inclined plate;
  • the activated sludge adsorption tank is filled with activated sludge, one end of the second water inlet pipe is connected with the perforated overflow pipe, and the other end is connected with the lower end of the activated sludge adsorption tank; the lower end of the activated sludge adsorption tank is provided with aeration
  • the bottom is provided with a sludge discharge port, and the water outlet is located in the middle of the activated sludge adsorption tank.
  • the present invention provides an inverted adsorption tank precipitation process based on carbon source classification and recovery, comprising the following steps:
  • the sewage to be treated is first precipitated by the inclined plate sedimentation tank to recover the easy-to-precipitate carbon source, and then the initially purified sewage overflows to the bottom of the activated sludge adsorption tank. Under the adsorption and absorption of the activated sludge, the carbon source in the sewage is recovered. ;
  • the sewage to be treated is the sewage that has been treated by the grille and the grit chamber to remove the garbage and sediment therein.
  • the present invention proposes the concept of classification and recovery of carbon sources in sewage, By adjusting the positions of the sedimentation tank and adsorption tank in the activated sludge process with high load, a pre-sedimentation-post-adsorption process is created to realize the classification and recovery of carbon sources in sewage.
  • the pre-sedimentation tank After the domestic sewage is treated by the grille and the grit chamber, a large amount of garbage and sediment are removed, and then it enters the pre-sedimentation tank, where the easy-to-precipitate particulate carbon source is precipitated and concentrated at the bottom of the pre-sedimentation tank in the simplest way.
  • the colloidal dissolved carbon source that is not easy to precipitate in the effluent of the pre-sedimentation tank occupies the main body, and is mixed with the sludge in the post-adsorption tank and transferred to the sludge phase, which is also discharged in the same way as excess sludge. Recycling, through the innovation of pre-precipitation-post-adsorption process, the classification and recovery of carbon sources can be realized, and the recovery rate of carbon sources in sewage can be effectively improved.
  • the process uses pre-precipitation-post-adsorption to classify and recover the carbon sources in the sewage under their respective favorable conditions. Compared with the 30%-50% in the prior art, the carbon source recovery rate can be effectively improved by at least 20%.
  • the process adopts intermittent operation mode, which can effectively reduce aeration energy consumption and reduce operating costs.
  • FIG. 1 is a schematic structural diagram of an inverted adsorption precipitation system based on carbon source classification and recovery provided in Example 1 of the present invention.
  • 1- Inlet water pump 2- First water inlet pipe, 3- Inclined plate sedimentation tank, 4- Perforated overflow pipe, 5- Activated sludge adsorption tank, 6- Water outlet pipe, 7- Aeration pump, 8- Micro Hole aeration plate, 9-sludge pump, 10-sludge pipe, 11-outlet pump.
  • the present invention provides an inverted adsorption and sedimentation system based on the classification and recovery of carbon sources, including: a sloping plate sedimentation tank and an activated sludge adsorption tank, wherein,
  • the bottom of the inclined plate sedimentation tank is funnel-shaped, the lowest end of the bottom is connected with the sludge pipe, the upper part of the middle is provided with a inclined plate, the side is provided with a first water inlet pipe, and the water inlet position is provided with a baffle plate , so that the influent water enters from the middle and lower part of the inclined plate sedimentation tank; a perforated overflow pipe is arranged above the inclined plate;
  • the activated sludge adsorption tank is filled with activated sludge, one end of the second water inlet pipe is connected with the perforated overflow pipe, and the other end is connected with the lower end of the activated sludge adsorption tank; the lower end of the activated sludge adsorption tank is provided with aeration
  • the bottom is provided with a sludge discharge port, and the water outlet is located in the middle of the activated sludge adsorption tank.
  • the aeration pan is a microporous aeration pan.
  • the effective volume of the inclined plate sedimentation tank is 40-60% of the activated sludge adsorption tank.
  • the inclination angle of the inclined plate in the inclined plate sedimentation tank is 50°-70°, preferably 60°.
  • the distance between the inclined plates in the inclined plate sedimentation tank is 3-5 cm.
  • the mud bucket volume of the inclined plate sedimentation tank is 15%-25% of the mud bucket volume of the inclined plate sedimentation tank.
  • the diameter-to-depth ratio of the activated sludge adsorption tank is 1:6-12, preferably 1:10.
  • the present invention provides an inverted adsorption tank precipitation process based on carbon source classification and recovery, comprising the following steps:
  • the sewage to be treated is first precipitated by the inclined plate sedimentation tank to recover the easy-to-precipitate carbon source, and then the initially purified sewage overflows to the bottom of the activated sludge adsorption tank. Under the adsorption and absorption of the activated sludge, the carbon source in the sewage is recovered. ;
  • the sewage to be treated is the sewage that has been treated by the grille and the grit chamber to remove the garbage and sediment therein.
  • the influent of the process of the present invention is ordinary domestic sewage, which has been treated by grids and grit chambers to remove a large amount of garbage and sediment.
  • Colloidal COD is about 35-60mg/L
  • dissolved COD is about 60-100mg/L
  • SS is about 150-200mg/L.
  • the process of the invention is used for recycling and processing carbon sources in urban domestic sewage, and the recovered carbon sources can be used for anaerobic fermentation production capacity.
  • the process setting of pre-precipitation-post-adsorption mainly has the following functions: (1) Through the process setting of pre-precipitation-post-adsorption, the easy-to-precipitate carbon source and the difficult-to-precipitate carbon source in the sewage can be separated in their respective advantageous positions.
  • the recovery rate of carbon source can be significantly improved by recycling under the condition of carbon source; (2) the easy-to-precipitate carbon source can be recovered by direct precipitation, which can reduce the carbon source load of the post-adsorption tank while saving the cost of recycling, and free up the post-adsorption
  • the adsorption site of activated sludge in the pool improves the recovery rate of carbon sources that are not easy to precipitate, thereby improving the overall process carbon source recovery rate;
  • the particle size of the carbon source in the sewage after pre-precipitation becomes smaller, and the small particle colloid It can promote activated sludge to convert carbon sources into endogenous organic carbon such as polyhydroxyalkanoates (PHA), and improve the recovery rate of dissolved carbon sources in the process; (4) Improve the recovery rate of carbon sources It can increase the content of carbon sources in excess sludge, thereby increasing the production capacity potential of excess sludge during anaerobic digestion, and promoting the resource and energy conversion of carbon sources in sewage.
  • PHA polyhydroxy
  • the pre-sedimentation tank greatly reduces the recovery cost of easy-to-precipitate carbon sources.
  • the pool recycles carbon sources that are not easy to precipitate in a targeted manner, which significantly improves the recovery rate of carbon sources in sewage.
  • the inoculation concentration of activated sludge in the activated sludge adsorption tank is 4-8 g/L, preferably 6 g/L, and the inoculation volume is half of the effective volume of the activated sludge adsorption tank.
  • the dissolved oxygen content in the activated sludge adsorption tank is 0.5-2.0 mg/L, preferably 0.5-1.0 mg/L.
  • the inverted adsorption tank precipitation process based on carbon source classification and recovery specifically includes the following steps:
  • Start-up stage add aerobic activated sludge to the activated sludge adsorption tank, and the sludge is taken from the end of the aerobic tank of the sewage treatment plant; turn on the water, and adopt the SBR operation mode.
  • the inclined plate sedimentation tank and the activated sludge The sludge adsorption tank does not discharge excess sludge;
  • the inclined plate sedimentation tank discharges sludge once a day, and the sludge discharge is equivalent to the sludge hopper volume of the sedimentation tank; the activated sludge adsorption tank gradually increases the discharge of excess sludge every day, so that it is Reach the set SRT within 1-2 weeks;
  • Stable operation stage When the SRT of the activated sludge adsorption tank reaches the set value stably, it enters the stable operation stage; in this stage, the sewage to be treated is first precipitated in the inclined plate sedimentation tank to recover the easy-to-precipitate carbon source, and then the sewage after preliminary purification It overflows to the bottom of the activated sludge adsorption tank, and under the adsorption and absorption of activated sludge, the carbon source in the sewage is recovered.
  • the SBR operation of the inclined plate sedimentation tank is divided into two stages: inflow and idle.
  • the inflow stage is 15-25min, and the idle stage is 40-50min.
  • the SBR operation of the activated sludge adsorption tank is divided into four stages: water inflow, aeration, sedimentation, water effluent and idle.
  • the water inflow and aeration stages are 15-25min, and the DO is 0.5-1.0mg/L;
  • the precipitation stage is 15-25min;
  • the effluent stage is 15-25min.
  • volume exchange rate of the activated sludge adsorption tank is 40-60%, and the idle stage is 4-10min, which is used to discharge excess sludge.
  • the SRT in the activated sludge adsorption tank is 1-3d.
  • the end of the start-up phase is marked when the sludge growth of the activated sludge adsorption tank reaches 0.3-0.5 g/L/d;
  • the end of the sludge age debugging phase is marked as the SRT of the continuous 3d activated sludge adsorption tank is 2.5-3.5d, and the sludge concentration in the activated sludge adsorption tank is 2-3 g/L.
  • the sludge concentration (MLSS) of the activated sludge adsorption tank is 2-3 g/L
  • the organic matter concentration in the sludge (MLVSS) is 1.4-2.4 g/L
  • the organic matter content in the sludge (MLVSS/MLSS) ) is 0.7-0.8.
  • COD, NH 3 -N, TN, TP were determined according to standard methods, COD was determined by potassium dichromate method, NH 3 -N was determined by nano-spectrophotometry, TN was determined by potassium persulfate oxidation-ultraviolet spectrophotometry, TP Molybdenum antimony anti-spectrophotometry was used.
  • the device composition mainly includes an inlet pump 1, a first water inlet pipe 2, a sloping plate sedimentation tank 3, a perforated overflow pipe 4, and a rear activated sewage Sludge adsorption tank 5, outlet pipe 6, aeration pump 7, microporous aeration plate 8, sludge pump 9, sludge pipe 10 and outlet pump 11.
  • the front sedimentation tank adopts the inclined plate sedimentation tank 3, and its effective volume is 50% of the effective volume of the rear activated sludge adsorption tank 5.
  • the inclined plate inclination angle is 60°, the distance between the inclined plates is 4 cm, and the volume of the mud bucket is about the same as that of the inclined plate. 20% of the volume of sedimentation tank 3.
  • the effective volume of the rear activated sludge adsorption tank 5 is twice the effective volume of the inclined plate sedimentation tank 3.
  • the diameter-to-depth ratio of the activated sludge adsorption tank 5 is 1:10.
  • the rear activated sludge adsorption tank is an SBR adsorption tank. Entered from the bottom of the pool and discharged from the middle of the pool, the pool contains activated sludge.
  • An inverted adsorption and precipitation process based on the classification and recovery of carbon sources. It operates intermittently and a cycle lasts 65 minutes: the front inclined plate sedimentation tank is fed for 20 minutes, idle for 45 minutes, and the rear activated sludge adsorption tank is fed with water + aeration for 20 minutes and sedimentation for 20 minutes. , out of water for 20min, idle for 5min.
  • the sewage first enters the inclined plate sedimentation tank to enrich and recycle the carbon sources that are easy to precipitate in the sewage.
  • the effluent from the inclined plate sedimentation tank enters the activated sludge adsorption tank, where it is mixed with the sludge and aerated at the same time.
  • the DO is controlled at 0.5-1 mg. /L, to promote activated sludge adsorption and absorption of carbon sources that are not easy to precipitate in sewage; in the precipitation stage, the mud level of the adsorption tank drops by more than 50% within 20 minutes; in the effluent stage, 50% of the supernatant in the adsorption tank is discharged within 20 minutes; in the idle stage, The excess sludge in the inclined plate sedimentation tank and the adsorption tank is discharged, and the SRT of the inclined plate sedimentation tank is controlled to be 1d, and the SRT of the adsorption tank is 3d.
  • the domestic sewage treated by the process comes from the domestic sewage of a school in the north.
  • the total COD concentration of the influent is 150.3 ⁇ 20.6mg/L
  • the total COD concentration of the effluent of the inclined plate sedimentation tank is 108.2 ⁇ 14.8mg/L
  • the total COD of the effluent of the activated sludge adsorption tank The concentration is 37.5 ⁇ 12.1mg/L.
  • the recovery rate of carbon source in the whole process is 60%.
  • An inverted adsorption and precipitation process based on the classification and recovery of carbon sources. It operates intermittently and a cycle lasts 65 minutes: the front inclined plate sedimentation tank is fed for 20 minutes, idle for 45 minutes, and the rear activated sludge adsorption tank is fed with water + aeration for 20 minutes and sedimentation for 20 minutes. , out of water for 20min, idle for 5min.
  • the sewage first enters the inclined plate sedimentation tank to enrich and recycle the carbon sources that are easy to precipitate in the sewage.
  • the effluent from the inclined plate sedimentation tank enters the activated sludge adsorption tank, where it is mixed with the sludge and aerated at the same time.
  • the DO is controlled at 0.5-1 mg. /L, to promote activated sludge adsorption and absorption of carbon sources that are not easy to precipitate in sewage; in the precipitation stage, the mud level of the adsorption tank drops by more than 50% within 20 minutes; in the effluent stage, 50% of the supernatant in the adsorption tank is discharged within 20 minutes; in the idle stage, Discharge the excess sludge in the inclined plate sedimentation tank and the adsorption tank, and control the SRT of the inclined plate sedimentation tank to be 1d and the SRT of the adsorption tank to be 2d.
  • This process treats domestic sewage in a northern city.
  • the total COD concentration of the influent water is 300.6 ⁇ 30.8mg/L, the ammonia nitrogen concentration is 31.8 ⁇ 2.9mg/L, the total nitrogen concentration is 51.6 ⁇ 3.3mg/L, and the total phosphorus concentration is 6.5 ⁇ 1.2 mg/L;
  • the total COD concentration of the effluent of this process is 69.3 ⁇ 15.6mg/L, the ammonia nitrogen concentration is 27.8 ⁇ 2.1mg/L, the total nitrogen concentration is 47.6 ⁇ 2.4mg/L, and the total phosphorus concentration is 5.9 ⁇ 1.3mg/L ;
  • the carbon source recovery rate of this process can reach more than 70%.

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Abstract

Disclosed in the present invention are an inverted adsorption precipitation system and process based on classification and recovery of carbon sources. Sewage to be treated first passes through a front-mounted inclined plate precipitation tank to recover particulate carbon sources, and then enters a rear-mounted micro-aerobic aeration activated sludge adsorption tank to adsorb and recover colloids and dissolved carbon sources in the sewage, wherein the sewage to be treated is sewage treated by a grating and a grit chamber to remove garbage and silt therein. In the whole process, the aeration energy consumption of the activated sludge adsorption tank is further reduced in an intermittent operation mode. The front-mounted precipitation tank is mainly used for recovering the particulate carbon sources which are easy to settle in the sewage, and the recovery costs of the particulate carbon sources are reduced to the maximum extent by means of the simplest precipitation mode. The removal of the particulate carbon sources remarkably reduces the load pressure of the rear-mounted activated sludge adsorption tank, such that the rear-mounted activated sludge adsorption tank only recovers the residual colloids and dissolved carbon sources in the sewage, the recovery capacity is greatly improved, and the recovery efficiency is remarkably improved.

Description

一种基于碳源分类回收的倒置吸附沉淀系统及工艺An inverted adsorption precipitation system and process based on carbon source classification and recovery 技术领域technical field

本发明属于环境保护和污水处理技术领域,具体涉及一种基于碳源分类回收的倒置吸附沉淀系统及工艺。The invention belongs to the technical field of environmental protection and sewage treatment, and in particular relates to an inverted adsorption precipitation system and process based on carbon source classification and recovery.

背景技术Background technique

公开该背景技术部分的信息仅仅旨在增加对本发明的总体背景的理解,而不必然被视为承认或以任何形式暗示该信息构成已经成为本领域一般技术人员所公知的现有技术。The information disclosed in this Background section is only for enhancement of understanding of the general background of the invention and should not necessarily be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person of ordinary skill in the art.

人口的迅速增长以及城市化的快速发展使得污水排放量迅猛增长,污水是资源的有效载体,其中蕴含着大量的碳源,对这些碳源进行充分回收及资源转化,是实现污水处理能源中和与可持续发展的重要途径。污水中各种形态的碳源(颗粒态(粒径>12μm)、胶体态(粒径0.45-12μm)和溶解态(粒径<0.45μm))分别占总体碳源的50%、20%和30%左右,颗粒态碳源又可分为易沉淀和不易沉淀两种,易沉淀的颗粒态碳源一般粒径较大,约占污水中碳源的30%左右,这部分碳源可通过沉淀作用直接回收利用,不易沉淀的碳源为污水中粒径较小的颗粒胶体及溶解态碳源,约占70%左右,这部分碳源需要通过污泥吸附沉淀以及污泥吸收转化为内源有机碳进行回收。The rapid growth of population and the rapid development of urbanization have led to a rapid increase in sewage discharge. Sewage is an effective carrier of resources, which contains a large number of carbon sources. Fully recycling these carbon sources and converting resources is the key to achieving energy neutralization in sewage treatment. important way to sustainable development. Various forms of carbon sources in sewage (particle state (particle size > 12 μm), colloidal state (particle size 0.45-12 μm) and dissolved state (particle size < 0.45 μm)) accounted for 50%, 20% and 50% of the total carbon source, respectively. About 30%, the granular carbon source can be divided into two types: easy to precipitate and difficult to precipitate. The granular carbon source that is easy to precipitate generally has a larger particle size, accounting for about 30% of the carbon source in the sewage, and this part of the carbon source can pass through. Precipitation is directly recycled, and the carbon sources that are not easy to precipitate are colloidal particles and dissolved carbon sources with small particle size in the sewage, accounting for about 70%. source organic carbon for recovery.

污水中碳源的回收及资源化过程一般分为三步:首先,污水经格栅和沉砂池处理,将其中的垃圾和泥沙去除,为回收污水中的碳源提供基础;其次,通过不同的碳源回收工艺对污水中的碳源进行回收;最后,回收的碳源可通过厌氧消化等方式实现资源、能源的转化。其中,碳源的回收工艺是整个过程中的 核心,其创新改进对实现污水资源化具有重要意义。The recovery and recycling process of carbon sources in sewage is generally divided into three steps: first, the sewage is treated by grids and grit chambers to remove the garbage and sediment in it, providing a basis for recycling carbon sources in sewage; second, through Different carbon source recovery processes recover the carbon source in the sewage; finally, the recovered carbon source can be converted into resources and energy through anaerobic digestion and other methods. Among them, the recovery process of carbon source is the core of the whole process, and its innovation and improvement are of great significance to the realization of sewage recycling.

传统活性污泥法是目前应用最广泛的污水处理技术,利用活性污泥微生物的新陈代谢作用,在较长的污泥停留时间(5-7d)和水力停留时间(>2h),较低的有机负荷(0.2-0.4kgBOD 5/kgMLSS/d)以及充足的氧气(DO>2mg/L)条件下将污水中大量的碳源矿化,无法实现污水中碳源的有效回收,“以能耗能”使得传统活性污泥法不具有可持续发展的潜力。 The traditional activated sludge method is currently the most widely used sewage treatment technology. It utilizes the metabolism of activated sludge microorganisms to achieve longer sludge retention time (5-7d) and hydraulic retention time (>2h), lower organic Under the conditions of load (0.2-0.4kgBOD 5 /kgMLSS/d) and sufficient oxygen (DO>2mg/L), a large amount of carbon sources in sewage can be mineralized, and the effective recovery of carbon sources in sewage cannot be realized. "It makes the traditional activated sludge process unsustainable.

高负荷活性污泥法是目前回收污水中碳源的主流工艺,由前置的吸附池和后置的沉淀池组成。污水经格栅和沉砂池预处理后,先进入吸附池中与活性污泥混合,被活性污泥吸附或吸收,并在沉淀池中沉淀浓缩,最终通过剩余污泥排放进行回收利用。高负荷活性污泥法在极短的污泥停留时间(0.3-0.5d)、水力停留时间(30min)和极高的有机负荷(2-6kg BOD 5/kgMLSS/d)下,利用活性污泥的生物絮凝吸附作用及沉淀浓缩实现污水中碳源的富集回收,但发明人发现,这样的回收过程是对污水中碳源的一种混合回收(即污水中各种形态的碳源混合在一起被污泥吸附或吸收后回收),这样的回收方式导致大量碳源流失(流失的碳源约占总碳源的30-50%),碳源回收率很低,约30%左右。 The high-load activated sludge method is currently the mainstream process for recycling carbon sources in sewage, which consists of a front adsorption tank and a rear sedimentation tank. After the sewage is pretreated by the grille and the grit chamber, it first enters the adsorption tank to be mixed with the activated sludge, adsorbed or absorbed by the activated sludge, and precipitated and concentrated in the sedimentation tank, and finally discharged through the excess sludge for recycling. The high-load activated sludge method utilizes activated sludge under extremely short sludge retention time (0.3-0.5d), hydraulic retention time (30min) and extremely high organic load (2-6kg BOD 5 /kgMLSS/d). The biological flocculation adsorption and precipitation concentration realize the enrichment and recovery of carbon sources in sewage, but the inventor found that such a recovery process is a mixed recovery of carbon sources in sewage (that is, various forms of carbon sources in sewage are mixed in sewage. At the same time, it is absorbed or absorbed by the sludge and then recovered), such a recovery method leads to the loss of a large amount of carbon sources (the lost carbon source accounts for about 30-50% of the total carbon source), and the carbon source recovery rate is very low, about 30%.

发明内容SUMMARY OF THE INVENTION

针对现有技术中存在的技术问题,本发明提供一种基于碳源分类回收的倒置吸附沉淀系统及工艺。整体工艺由前置的沉淀池和后置的活性污泥吸附池组成。前置的沉淀池主要针对污水中易沉淀的颗粒态碳源进行回收,通过最简单的沉淀方式最大限度地降低了颗粒态碳源的回收成本。颗粒态碳源的去除一方面显著降低了后置活性污泥吸附池的负荷压力,另一方面使得后置活性污泥吸附池只针对污水中剩余的胶体及溶解态碳源进行吸附回收,回收效率显著提升。Aiming at the technical problems existing in the prior art, the present invention provides an inverted adsorption precipitation system and process based on the classification and recovery of carbon sources. The overall process consists of a pre-sedimentation tank and a rear activated sludge adsorption tank. The pre-sedimentation tank is mainly for the recovery of particulate carbon sources that are easy to precipitate in sewage, and the recycling cost of particulate carbon sources is minimized through the simplest precipitation method. On the one hand, the removal of particulate carbon source significantly reduces the load pressure of the post-activated sludge adsorption tank, and on the other hand, the post-activated sludge adsorption tank can only adsorb and recover the remaining colloidal and dissolved carbon sources in the sewage. Efficiency is significantly improved.

为解决以上技术问题,本发明的以下一个或多个实施例提供了如下技术方案:In order to solve the above technical problems, the following one or more embodiments of the present invention provide the following technical solutions:

第一方面,本发明提供一种基于碳源分类回收的倒置吸附沉淀系统,包括:斜板沉淀池和活性污泥吸附池,其中,In the first aspect, the present invention provides an inverted adsorption and sedimentation system based on the classification and recovery of carbon sources, including: a sloping plate sedimentation tank and an activated sludge adsorption tank, wherein,

所述斜板沉淀池的底部为漏斗状,底部的最低端与污泥管连接,其中部靠上的部位设置有斜板,其侧面设置有第一进水管,进水位置设有挡流板,使进水从斜板沉淀池中下部进入;斜板的上方设置有穿孔溢流管;The bottom of the inclined plate sedimentation tank is funnel-shaped, the lowest end of the bottom is connected with the sludge pipe, the upper part of the middle is provided with a inclined plate, the side is provided with a first water inlet pipe, and the water inlet position is provided with a baffle plate , so that the influent water enters from the middle and lower part of the inclined plate sedimentation tank; a perforated overflow pipe is arranged above the inclined plate;

活性污泥吸附池,其内部填充有活性污泥,第二进水管的一端与穿孔溢流管连通,另一端与活性污泥吸附池的下端连通;活性污泥吸附池的下端设置有曝气盘,且底部设置有排泥口,出水口位于活性污泥吸附池中部。The activated sludge adsorption tank is filled with activated sludge, one end of the second water inlet pipe is connected with the perforated overflow pipe, and the other end is connected with the lower end of the activated sludge adsorption tank; the lower end of the activated sludge adsorption tank is provided with aeration The bottom is provided with a sludge discharge port, and the water outlet is located in the middle of the activated sludge adsorption tank.

第二方面,本发明提供一种基于碳源分类回收的倒置吸附池沉淀工艺,包括如下步骤:In the second aspect, the present invention provides an inverted adsorption tank precipitation process based on carbon source classification and recovery, comprising the following steps:

待处理污水先经斜板沉淀池沉淀回收易沉淀碳源,然后初步净化后的污水溢流至活性污泥吸附池的底部,在活性污泥的吸附和吸收作用下,回收污水中的碳源;The sewage to be treated is first precipitated by the inclined plate sedimentation tank to recover the easy-to-precipitate carbon source, and then the initially purified sewage overflows to the bottom of the activated sludge adsorption tank. Under the adsorption and absorption of the activated sludge, the carbon source in the sewage is recovered. ;

所述待处理污水为经过格栅和沉砂池处理去除其中垃圾和泥沙后的污水。The sewage to be treated is the sewage that has been treated by the grille and the grit chamber to remove the garbage and sediment therein.

与现有技术相比,本发明的以上一个或多个技术方案取得了以下有益效果:Compared with the prior art, the above one or more technical solutions of the present invention have achieved the following beneficial effects:

针对现有的高负荷活性污泥法没有对各种形态的碳源进行分类回收,致使大量碳源流失,工艺碳源回收率低等问题,本发明提出了污水中碳源分类回收的理念,通过对调高负荷活性污泥法中沉淀池和吸附池的位置,创建前置沉淀-后置吸附工艺来实现污水中碳源的分类回收。生活污水经过格栅和沉砂池处理后,去除了大量的垃圾和泥沙,之后进入前置沉淀池,其中易沉淀的颗粒态 碳源以最简单的方式沉淀浓缩在前置沉淀池底部,通过剩余污泥排出回收,前置沉淀池的出水中不易沉淀的胶体溶解态碳源占据主体,与后置吸附池中的污泥混合后转移至污泥相,同样以剩余污泥排放的方式回收利用,通过前置沉淀-后置吸附工艺创新可实现碳源的分类回收,有效提高污水中碳源的回收率。Aiming at the problems that the existing high-load activated sludge method does not classify and recover various forms of carbon sources, resulting in the loss of a large amount of carbon sources and the low recovery rate of carbon sources in the process, the present invention proposes the concept of classification and recovery of carbon sources in sewage, By adjusting the positions of the sedimentation tank and adsorption tank in the activated sludge process with high load, a pre-sedimentation-post-adsorption process is created to realize the classification and recovery of carbon sources in sewage. After the domestic sewage is treated by the grille and the grit chamber, a large amount of garbage and sediment are removed, and then it enters the pre-sedimentation tank, where the easy-to-precipitate particulate carbon source is precipitated and concentrated at the bottom of the pre-sedimentation tank in the simplest way. Through the discharge and recovery of excess sludge, the colloidal dissolved carbon source that is not easy to precipitate in the effluent of the pre-sedimentation tank occupies the main body, and is mixed with the sludge in the post-adsorption tank and transferred to the sludge phase, which is also discharged in the same way as excess sludge. Recycling, through the innovation of pre-precipitation-post-adsorption process, the classification and recovery of carbon sources can be realized, and the recovery rate of carbon sources in sewage can be effectively improved.

前置沉淀池回收污水中易沉淀的碳源可节约20%左右的回收成本;后置吸附池间歇微氧运行(DO=0.5-1.0mg/L),可有效减少碳源矿化10%以上,降低30%左右的运行能耗,减少约15%的运行成本。The pre-sedimentation tank recovers the easily precipitated carbon sources in sewage, which can save about 20% of the recovery cost; the post-adsorption tank operates intermittently with micro-oxygen (DO=0.5-1.0mg/L), which can effectively reduce the mineralization of carbon sources by more than 10% , reduce the operating energy consumption by about 30%, and reduce the operating cost by about 15%.

工艺通过前置沉淀-后置吸附将污水中的碳源在各自有利的条件下分类回收,与现有技术的30%-50%相比,至少可有效提高碳源回收率20%以上。The process uses pre-precipitation-post-adsorption to classify and recover the carbon sources in the sewage under their respective favorable conditions. Compared with the 30%-50% in the prior art, the carbon source recovery rate can be effectively improved by at least 20%.

工艺采用间歇运行方式,可有效降低曝气能耗,减少运行成本。The process adopts intermittent operation mode, which can effectively reduce aeration energy consumption and reduce operating costs.

附图说明Description of drawings

构成本发明的一部分的说明书附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。The accompanying drawings forming a part of the present invention are used to provide further understanding of the present invention, and the exemplary embodiments of the present invention and their descriptions are used to explain the present invention, and do not constitute an improper limitation of the present invention.

图1是本发明实施例1提供的一种基于碳源分类回收的倒置吸附沉淀系统的结构示意图。FIG. 1 is a schematic structural diagram of an inverted adsorption precipitation system based on carbon source classification and recovery provided in Example 1 of the present invention.

其中:1-进水泵,2-第一进水管,3-斜板沉淀池,4-穿孔溢流管,5-活性污泥吸附池,6-出水管,7-曝气泵,8-微孔曝气盘,9-污泥泵,10-污泥管,11-出水泵。Among them: 1- Inlet water pump, 2- First water inlet pipe, 3- Inclined plate sedimentation tank, 4- Perforated overflow pipe, 5- Activated sludge adsorption tank, 6- Water outlet pipe, 7- Aeration pump, 8- Micro Hole aeration plate, 9-sludge pump, 10-sludge pipe, 11-outlet pump.

具体实施方式Detailed ways

应该指出,以下详细说明都是示例性的,旨在对本发明提供进一步的说明。除非另有指明,本文使用的所有技术和科学术语具有与本发明所属技术领域的普通技术人员通常理解的相同含义。It should be noted that the following detailed description is exemplary and intended to provide further explanation of the invention. Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.

需要注意的是,这里所使用的术语仅是为了描述具体实施方式,而非意图 限制根据本发明的示例性实施方式。如在这里所使用的,除非上下文另外明确指出,否则单数形式也意图包括复数形式,此外,还应当理解的是,当在本说明书中使用术语“包含”和/或“包括”时,其指明存在特征、步骤、操作、器件、组件和/或它们的组合。It should be noted that the terminology used herein is for the purpose of describing specific embodiments only, and is not intended to limit the exemplary embodiments according to the present invention. As used herein, unless the context clearly dictates otherwise, the singular is intended to include the plural as well, furthermore, it is to be understood that when the terms "comprising" and/or "including" are used in this specification, it indicates that There are features, steps, operations, devices, components and/or combinations thereof.

第一方面,本发明提供一种基于碳源分类回收的倒置吸附沉淀系统,包括:斜板沉淀池和活性污泥吸附池,其中,In the first aspect, the present invention provides an inverted adsorption and sedimentation system based on the classification and recovery of carbon sources, including: a sloping plate sedimentation tank and an activated sludge adsorption tank, wherein,

所述斜板沉淀池的底部为漏斗状,底部的最低端与污泥管连接,其中部靠上的部位设置有斜板,其侧面设置有第一进水管,进水位置设有挡流板,使进水从斜板沉淀池中下部进入;斜板的上方设置有穿孔溢流管;The bottom of the inclined plate sedimentation tank is funnel-shaped, the lowest end of the bottom is connected with the sludge pipe, the upper part of the middle is provided with a inclined plate, the side is provided with a first water inlet pipe, and the water inlet position is provided with a baffle plate , so that the influent water enters from the middle and lower part of the inclined plate sedimentation tank; a perforated overflow pipe is arranged above the inclined plate;

活性污泥吸附池,其内部填充有活性污泥,第二进水管的一端与穿孔溢流管连通,另一端与活性污泥吸附池的下端连通;活性污泥吸附池的下端设置有曝气盘,且底部设置有排泥口,出水口位于活性污泥吸附池中部。The activated sludge adsorption tank is filled with activated sludge, one end of the second water inlet pipe is connected with the perforated overflow pipe, and the other end is connected with the lower end of the activated sludge adsorption tank; the lower end of the activated sludge adsorption tank is provided with aeration The bottom is provided with a sludge discharge port, and the water outlet is located in the middle of the activated sludge adsorption tank.

在一些实施例中,所述曝气盘为微孔曝气盘。In some embodiments, the aeration pan is a microporous aeration pan.

在一些实施例中,所述斜板沉淀池的有效容积为活性污泥吸附池的40-60%。In some embodiments, the effective volume of the inclined plate sedimentation tank is 40-60% of the activated sludge adsorption tank.

进一步的,所述斜板沉淀池中的斜板倾角为50°-70°,优选为60°。Further, the inclination angle of the inclined plate in the inclined plate sedimentation tank is 50°-70°, preferably 60°.

进一步的,所述斜板沉淀池中的斜板间距为3-5cm。Further, the distance between the inclined plates in the inclined plate sedimentation tank is 3-5 cm.

进一步的,所述斜板沉淀池的泥斗容积为斜板沉淀池泥斗容积的15%-25%。Further, the mud bucket volume of the inclined plate sedimentation tank is 15%-25% of the mud bucket volume of the inclined plate sedimentation tank.

在一些实施例中,活性污泥吸附池的径深比为1:6-12,优选为1:10。In some embodiments, the diameter-to-depth ratio of the activated sludge adsorption tank is 1:6-12, preferably 1:10.

第二方面,本发明提供一种基于碳源分类回收的倒置吸附池沉淀工艺,包括如下步骤:In the second aspect, the present invention provides an inverted adsorption tank precipitation process based on carbon source classification and recovery, comprising the following steps:

待处理污水先经斜板沉淀池沉淀回收易沉淀碳源,然后初步净化后的污水 溢流至活性污泥吸附池的底部,在活性污泥的吸附和吸收作用下,回收污水中的碳源;The sewage to be treated is first precipitated by the inclined plate sedimentation tank to recover the easy-to-precipitate carbon source, and then the initially purified sewage overflows to the bottom of the activated sludge adsorption tank. Under the adsorption and absorption of the activated sludge, the carbon source in the sewage is recovered. ;

所述待处理污水为经过格栅和沉砂池处理去除其中垃圾和泥沙后的污水。The sewage to be treated is the sewage that has been treated by the grille and the grit chamber to remove the garbage and sediment therein.

本发明工艺进水为普通生活污水,经过了格栅和沉砂池处理,去除了大量垃圾和泥沙,工艺进水总COD约200-300mg/L,颗粒态COD约100-140mg/L,胶体态COD约35-60mg/L,溶解态COD约60-100mg/L,SS约150-200mg/L。The influent of the process of the present invention is ordinary domestic sewage, which has been treated by grids and grit chambers to remove a large amount of garbage and sediment. Colloidal COD is about 35-60mg/L, dissolved COD is about 60-100mg/L, and SS is about 150-200mg/L.

本发明工艺用于回收处理城市生活污水中的碳源,回收的碳源可用于厌氧发酵产能。The process of the invention is used for recycling and processing carbon sources in urban domestic sewage, and the recovered carbon sources can be used for anaerobic fermentation production capacity.

前置沉淀-后置吸附的工艺设置主要有以下作用:(1)通过前置沉淀-后置吸附的工艺设置,可将污水中易沉淀的碳源与不易沉淀的碳源分开在各自有利的条件下进行回收,可显著提升碳源回收率;(2)易沉淀的碳源通过直接沉淀进行回收,在节约回收成本的同时,可减轻后置吸附池的碳源负荷,空出后置吸附池中活性污泥的吸附点位,提升不易沉淀的碳源的回收率,进而提升整体工艺碳源回收率;(3)经过前置沉淀后的污水碳源粒径变小,以小颗粒胶体和溶解态为主,可以促进活性污泥将碳源转化为聚羟基脂肪酸酯(PHA)等内源有机碳,提升工艺对溶解性碳源的回收率;(4)碳源回收率的提高可提升剩余污泥中碳源的含量,进而提升剩余污泥厌氧消化时的产能潜力,促进污水中碳源的资源能源转化。The process setting of pre-precipitation-post-adsorption mainly has the following functions: (1) Through the process setting of pre-precipitation-post-adsorption, the easy-to-precipitate carbon source and the difficult-to-precipitate carbon source in the sewage can be separated in their respective advantageous positions. The recovery rate of carbon source can be significantly improved by recycling under the condition of carbon source; (2) the easy-to-precipitate carbon source can be recovered by direct precipitation, which can reduce the carbon source load of the post-adsorption tank while saving the cost of recycling, and free up the post-adsorption The adsorption site of activated sludge in the pool improves the recovery rate of carbon sources that are not easy to precipitate, thereby improving the overall process carbon source recovery rate; (3) The particle size of the carbon source in the sewage after pre-precipitation becomes smaller, and the small particle colloid It can promote activated sludge to convert carbon sources into endogenous organic carbon such as polyhydroxyalkanoates (PHA), and improve the recovery rate of dissolved carbon sources in the process; (4) Improve the recovery rate of carbon sources It can increase the content of carbon sources in excess sludge, thereby increasing the production capacity potential of excess sludge during anaerobic digestion, and promoting the resource and energy conversion of carbon sources in sewage.

通过前置沉淀-后置吸附的工艺设置实现了污水中易沉淀的碳源和不易沉淀的碳源的分类回收,前置沉淀池极大的降低了易沉淀碳源的回收成本,后置吸附池针对性的对不易沉淀的碳源进行回收,显著提升了污水中碳源的回收率。Through the pre-precipitation-post-adsorption process setting, the classification and recovery of easy-to-precipitate carbon sources and difficult-to-precipitate carbon sources in sewage are realized. The pre-sedimentation tank greatly reduces the recovery cost of easy-to-precipitate carbon sources. The pool recycles carbon sources that are not easy to precipitate in a targeted manner, which significantly improves the recovery rate of carbon sources in sewage.

在一些实施例中,所述活性污泥吸附池中活性污泥的接种浓度为4-8g/L, 优选为6g/L,接种体积为活性污泥吸附池有效容积的一半。In some embodiments, the inoculation concentration of activated sludge in the activated sludge adsorption tank is 4-8 g/L, preferably 6 g/L, and the inoculation volume is half of the effective volume of the activated sludge adsorption tank.

在一些实施例中,经过曝气,使活性污泥吸附池中的溶解氧含量为0.5-2.0mg/L,优选为0.5-1.0mg/L。In some embodiments, after aeration, the dissolved oxygen content in the activated sludge adsorption tank is 0.5-2.0 mg/L, preferably 0.5-1.0 mg/L.

在一些实施例中,所述基于碳源分类回收的倒置吸附池沉淀工艺,具体包括如下步骤:In some embodiments, the inverted adsorption tank precipitation process based on carbon source classification and recovery specifically includes the following steps:

启动阶段:向活性污泥吸附池中投加好氧活性污泥,污泥取自污水处理厂好氧池末端;开启进水,采用SBR运行方式,在该阶段,斜板沉淀池和活性污泥吸附池不排放剩余污泥;Start-up stage: add aerobic activated sludge to the activated sludge adsorption tank, and the sludge is taken from the end of the aerobic tank of the sewage treatment plant; turn on the water, and adopt the SBR operation mode. At this stage, the inclined plate sedimentation tank and the activated sludge The sludge adsorption tank does not discharge excess sludge;

泥龄调试阶段:采用SBR运行方式,斜板沉淀池每天排放一次污泥,污泥排放量与沉淀池泥斗容积相当;活性污泥吸附池每天逐步增加剩余污泥的排放量,使其在1-2周内达到设定的SRT;Sludge age debugging stage: using SBR operation mode, the inclined plate sedimentation tank discharges sludge once a day, and the sludge discharge is equivalent to the sludge hopper volume of the sedimentation tank; the activated sludge adsorption tank gradually increases the discharge of excess sludge every day, so that it is Reach the set SRT within 1-2 weeks;

稳定运行阶段:当活性污泥吸附池的SRT稳定达到设定值后,进入稳定运行阶段;在该阶段,待处理污水先经斜板沉淀池沉淀回收易沉淀碳源,然后初步净化后的污水溢流至活性污泥吸附池的底部,在活性污泥的吸附和吸收作用下,回收污水中的碳源。Stable operation stage: When the SRT of the activated sludge adsorption tank reaches the set value stably, it enters the stable operation stage; in this stage, the sewage to be treated is first precipitated in the inclined plate sedimentation tank to recover the easy-to-precipitate carbon source, and then the sewage after preliminary purification It overflows to the bottom of the activated sludge adsorption tank, and under the adsorption and absorption of activated sludge, the carbon source in the sewage is recovered.

进一步的,斜板沉淀池的SBR运行分为进水和闲置两个阶段,进水阶段为15-25min,闲置阶段为40-50min。Further, the SBR operation of the inclined plate sedimentation tank is divided into two stages: inflow and idle. The inflow stage is 15-25min, and the idle stage is 40-50min.

进一步的,活性污泥吸附池的SBR运行分为进水、曝气、沉淀、出水和闲置四个阶段,其中,进水和曝气阶段为15-25min,DO为0.5-1.0mg/L;沉淀阶段为15-25min;出水阶段为15-25min。Further, the SBR operation of the activated sludge adsorption tank is divided into four stages: water inflow, aeration, sedimentation, water effluent and idle. Among them, the water inflow and aeration stages are 15-25min, and the DO is 0.5-1.0mg/L; The precipitation stage is 15-25min; the effluent stage is 15-25min.

更进一步的,活性污泥吸附池的体积交换率为40-60%,闲置阶段为4-10min,用于排放剩余污泥。Further, the volume exchange rate of the activated sludge adsorption tank is 40-60%, and the idle stage is 4-10min, which is used to discharge excess sludge.

更进一步的,活性污泥吸附池中的SRT为1-3d。Further, the SRT in the activated sludge adsorption tank is 1-3d.

在一些实施例中,启动阶段结束的标志为活性污泥吸附池的污泥增长量达到0.3-0.5g/L/d;In some embodiments, the end of the start-up phase is marked when the sludge growth of the activated sludge adsorption tank reaches 0.3-0.5 g/L/d;

在一些实施例中,泥龄调试阶段结束的标志为连续3d活性污泥吸附池的SRT为2.5-3.5d,且活性污泥吸附池中的污泥浓度为2-3g/L。In some embodiments, the end of the sludge age debugging phase is marked as the SRT of the continuous 3d activated sludge adsorption tank is 2.5-3.5d, and the sludge concentration in the activated sludge adsorption tank is 2-3 g/L.

在一些实施例中,活性污泥吸附池的污泥浓度(MLSS)为2-3g/L,污泥中有机质浓度(MLVSS)为1.4-2.4g/L,污泥中有机质含量(MLVSS/MLSS)为0.7-0.8。In some embodiments, the sludge concentration (MLSS) of the activated sludge adsorption tank is 2-3 g/L, the organic matter concentration in the sludge (MLVSS) is 1.4-2.4 g/L, and the organic matter content in the sludge (MLVSS/MLSS) ) is 0.7-0.8.

实施例中所述实验方法,如无特殊说明,均为常规方法;所述试剂和材料,如无特殊说明,均可从商业途径获得。The experimental methods described in the examples are conventional methods unless otherwise specified; the reagents and materials can be obtained from commercial sources unless otherwise specified.

测定方法:COD、NH 3-N、TN、TP根据标准方法测定,COD采用重铬酸钾法,NH 3-N采用纳式分光光度法,TN采用过硫酸钾氧化-紫外分光光度法,TP采用钼锑抗分光光度法。 Determination method: COD, NH 3 -N, TN, TP were determined according to standard methods, COD was determined by potassium dichromate method, NH 3 -N was determined by nano-spectrophotometry, TN was determined by potassium persulfate oxidation-ultraviolet spectrophotometry, TP Molybdenum antimony anti-spectrophotometry was used.

实施例1Example 1

如图1所示,一种基于碳源分类回收的倒置吸附沉淀工艺,其装置组成主要包括进水泵1、第一进水管2、斜板沉淀池3、穿孔溢流管4、后置活性污泥吸附池5、出水管6、曝气泵7、微孔曝气盘8、污泥泵9、污泥管10和出水泵11。As shown in Figure 1, an inverted adsorption and precipitation process based on carbon source classification and recovery, the device composition mainly includes an inlet pump 1, a first water inlet pipe 2, a sloping plate sedimentation tank 3, a perforated overflow pipe 4, and a rear activated sewage Sludge adsorption tank 5, outlet pipe 6, aeration pump 7, microporous aeration plate 8, sludge pump 9, sludge pipe 10 and outlet pump 11.

前置沉淀池采用斜板沉淀池3,其有效容积为后置活性污泥吸附池5有效容积的50%,斜板倾角为60°,斜板间距为4厘米,泥斗容积约为斜板沉淀池3容积的20%。后置活性污泥吸附池5有效容积为斜板沉淀池3有效容积的两倍,活性污泥吸附池5的径深比为1:10,后置活性污泥吸附池为SBR吸附池,污水从池底进入从池中部排出,池中含有活性污泥。The front sedimentation tank adopts the inclined plate sedimentation tank 3, and its effective volume is 50% of the effective volume of the rear activated sludge adsorption tank 5. The inclined plate inclination angle is 60°, the distance between the inclined plates is 4 cm, and the volume of the mud bucket is about the same as that of the inclined plate. 20% of the volume of sedimentation tank 3. The effective volume of the rear activated sludge adsorption tank 5 is twice the effective volume of the inclined plate sedimentation tank 3. The diameter-to-depth ratio of the activated sludge adsorption tank 5 is 1:10. The rear activated sludge adsorption tank is an SBR adsorption tank. Entered from the bottom of the pool and discharged from the middle of the pool, the pool contains activated sludge.

一种基于碳源分类回收的倒置吸附沉淀工艺,间歇运行,一个周期持续 65min:前置斜板沉淀池进水20min,闲置45min,后置活性污泥吸附池进水+曝气20min,沉淀20min,出水20min,闲置5min。进水阶段,污水先进入斜板沉淀池,富集回收污水中易沉淀的碳源,斜板沉淀池出水进入活性污泥吸附池,与污泥混合同时进行曝气,DO控制在0.5-1mg/L,促进活性污泥吸附吸收污水中不易沉淀的碳源;沉淀阶段,吸附池泥位20min内下降50%以上;出水阶段,20min内排出吸附池50%体积的上清液;闲置阶段,排放斜板沉淀池及吸附池的剩余污泥,控制斜板沉淀池的SRT为1d,吸附池的SRT为3d。工艺处理的生活污水来自北方某学校生活污水,进水总COD浓度为150.3±20.6mg/L,斜板沉淀池出水总COD浓度为108.2±14.8mg/L,活性污泥吸附池的出水总COD浓度为37.5±12.1mg/L,经过COD质量平衡,整体工艺碳源的回收率为60%。An inverted adsorption and precipitation process based on the classification and recovery of carbon sources. It operates intermittently and a cycle lasts 65 minutes: the front inclined plate sedimentation tank is fed for 20 minutes, idle for 45 minutes, and the rear activated sludge adsorption tank is fed with water + aeration for 20 minutes and sedimentation for 20 minutes. , out of water for 20min, idle for 5min. In the water inlet stage, the sewage first enters the inclined plate sedimentation tank to enrich and recycle the carbon sources that are easy to precipitate in the sewage. The effluent from the inclined plate sedimentation tank enters the activated sludge adsorption tank, where it is mixed with the sludge and aerated at the same time. The DO is controlled at 0.5-1 mg. /L, to promote activated sludge adsorption and absorption of carbon sources that are not easy to precipitate in sewage; in the precipitation stage, the mud level of the adsorption tank drops by more than 50% within 20 minutes; in the effluent stage, 50% of the supernatant in the adsorption tank is discharged within 20 minutes; in the idle stage, The excess sludge in the inclined plate sedimentation tank and the adsorption tank is discharged, and the SRT of the inclined plate sedimentation tank is controlled to be 1d, and the SRT of the adsorption tank is 3d. The domestic sewage treated by the process comes from the domestic sewage of a school in the north. The total COD concentration of the influent is 150.3±20.6mg/L, the total COD concentration of the effluent of the inclined plate sedimentation tank is 108.2±14.8mg/L, and the total COD of the effluent of the activated sludge adsorption tank The concentration is 37.5±12.1mg/L. After COD mass balance, the recovery rate of carbon source in the whole process is 60%.

实施例2Example 2

一种基于碳源分类回收的倒置吸附沉淀工艺,间歇运行,一个周期持续65min:前置斜板沉淀池进水20min,闲置45min,后置活性污泥吸附池进水+曝气20min,沉淀20min,出水20min,闲置5min。进水阶段,污水先进入斜板沉淀池,富集回收污水中易沉淀的碳源,斜板沉淀池出水进入活性污泥吸附池,与污泥混合同时进行曝气,DO控制在0.5-1mg/L,促进活性污泥吸附吸收污水中不易沉淀的碳源;沉淀阶段,吸附池泥位20min内下降50%以上;出水阶段,20min内排出吸附池50%体积的上清液;闲置阶段,排放斜板沉淀池及吸附池的剩余污泥,控制斜板沉淀池的SRT为1d,吸附池的SRT为2d。该工艺处理北方某城市生活污水,进水总COD浓度为300.6±30.8mg/L,氨氮浓度为31.8±2.9mg/L,总氮浓度为51.6±3.3mg/L,总磷浓度为6.5±1.2mg/L;该工艺的出水总COD浓度为69.3±15.6mg/L,氨氮浓度为27.8±2.1mg/L,总氮浓 度为47.6±2.4mg/L,总磷浓度为5.9±1.3mg/L;经COD质量平衡该工艺碳源的回收率可达70%以上。An inverted adsorption and precipitation process based on the classification and recovery of carbon sources. It operates intermittently and a cycle lasts 65 minutes: the front inclined plate sedimentation tank is fed for 20 minutes, idle for 45 minutes, and the rear activated sludge adsorption tank is fed with water + aeration for 20 minutes and sedimentation for 20 minutes. , out of water for 20min, idle for 5min. In the water inlet stage, the sewage first enters the inclined plate sedimentation tank to enrich and recycle the carbon sources that are easy to precipitate in the sewage. The effluent from the inclined plate sedimentation tank enters the activated sludge adsorption tank, where it is mixed with the sludge and aerated at the same time. The DO is controlled at 0.5-1 mg. /L, to promote activated sludge adsorption and absorption of carbon sources that are not easy to precipitate in sewage; in the precipitation stage, the mud level of the adsorption tank drops by more than 50% within 20 minutes; in the effluent stage, 50% of the supernatant in the adsorption tank is discharged within 20 minutes; in the idle stage, Discharge the excess sludge in the inclined plate sedimentation tank and the adsorption tank, and control the SRT of the inclined plate sedimentation tank to be 1d and the SRT of the adsorption tank to be 2d. This process treats domestic sewage in a northern city. The total COD concentration of the influent water is 300.6±30.8mg/L, the ammonia nitrogen concentration is 31.8±2.9mg/L, the total nitrogen concentration is 51.6±3.3mg/L, and the total phosphorus concentration is 6.5±1.2 mg/L; the total COD concentration of the effluent of this process is 69.3±15.6mg/L, the ammonia nitrogen concentration is 27.8±2.1mg/L, the total nitrogen concentration is 47.6±2.4mg/L, and the total phosphorus concentration is 5.9±1.3mg/L ; After COD mass balance, the carbon source recovery rate of this process can reach more than 70%.

以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.

Claims (10)

一种基于碳源分类回收的倒置吸附沉淀系统,其特征在于:包括:斜板沉淀池和活性污泥吸附池,其中,An inverted adsorption and sedimentation system based on the classification and recovery of carbon sources, characterized in that it comprises: a sloping plate sedimentation tank and an activated sludge adsorption tank, wherein, 所述斜板沉淀池的底部为漏斗状,底部的最低端与污泥管连接,其中部靠上的部位设置有斜板,其侧面设置有第一进水管,进水位置设有挡流板,使进水从斜板沉淀池中下部进入;斜板的上方设置有穿孔溢流管;The bottom of the inclined plate sedimentation tank is funnel-shaped, the lowest end of the bottom is connected with the sludge pipe, the upper part of the middle is provided with a inclined plate, the side is provided with a first water inlet pipe, and the water inlet position is provided with a baffle plate , so that the influent water enters from the middle and lower part of the inclined plate sedimentation tank; a perforated overflow pipe is arranged above the inclined plate; 活性污泥吸附池,其内部填充有活性污泥,第二进水管的一端与穿孔溢流管连通,另一端与活性污泥吸附池的下端连通;活性污泥吸附池的下端设置有曝气盘,且底部设置有排泥口,出水口位于活性污泥吸附池中部。The activated sludge adsorption tank is filled with activated sludge, one end of the second water inlet pipe is connected with the perforated overflow pipe, and the other end is connected with the lower end of the activated sludge adsorption tank; the lower end of the activated sludge adsorption tank is provided with aeration The bottom is provided with a sludge discharge port, and the water outlet is located in the middle of the activated sludge adsorption tank. 根据权利要求1所述的基于碳源分类回收的倒置吸附沉淀系统,其特征在于:所述曝气盘为微孔曝气盘。The inverted adsorption and sedimentation system based on carbon source classification and recovery according to claim 1, wherein the aeration disk is a microporous aeration disk. 根据权利要求1所述的基于碳源分类回收的倒置吸附沉淀系统,其特征在于:所述斜板沉淀池的有效容积为活性污泥吸附池的40-60%;The inverted adsorption and sedimentation system based on carbon source classification and recovery according to claim 1, characterized in that: the effective volume of the inclined plate sedimentation tank is 40-60% of the activated sludge adsorption tank; 进一步的,所述斜板沉淀池中的斜板倾角为50°-70°,优选为60°;Further, the inclination angle of the inclined plate in the inclined plate sedimentation tank is 50°-70°, preferably 60°; 进一步的,所述斜板沉淀池中的斜板间距为3-5cm;Further, the distance between the inclined plates in the inclined plate sedimentation tank is 3-5cm; 进一步的,所述斜板沉淀池的泥斗容积为斜板沉淀池泥斗容积的15%-25%。Further, the mud bucket volume of the inclined plate sedimentation tank is 15%-25% of the mud bucket volume of the inclined plate sedimentation tank. 根据权利要求1所述的基于碳源分类回收的倒置吸附沉淀系统,其特征在于:活性污泥吸附池的径深比为1:6-12,优选为1:10。The inverted adsorption and sedimentation system based on carbon source classification and recovery according to claim 1, characterized in that: the diameter-to-depth ratio of the activated sludge adsorption tank is 1:6-12, preferably 1:10. 一种基于碳源分类回收的倒置吸附池沉淀工艺,其特征在于:包括如下步骤:A kind of inverted adsorption tank precipitation process based on carbon source classification and recovery, is characterized in that: comprises the following steps: 待处理污水先经斜板沉淀池沉淀回收易沉淀碳源,然后初步净化后的污水溢流至活性污泥吸附池的底部,在活性污泥的吸附和吸收作用下,回收污水中的碳源;The sewage to be treated is first precipitated by the inclined plate sedimentation tank to recover the easy-to-precipitate carbon source, and then the initially purified sewage overflows to the bottom of the activated sludge adsorption tank. Under the adsorption and absorption of the activated sludge, the carbon source in the sewage is recovered. ; 所述待处理污水为经过格栅和沉砂池处理去除其中垃圾和泥沙后的污水。The sewage to be treated is the sewage that has been treated by the grille and the grit chamber to remove the garbage and sediment therein. 根据权利要求5所述的基于碳源分类回收的倒置吸附池沉淀工艺,其特征在于:所述活性污泥吸附池中活性污泥的接种浓度为4-8g/L,优选为6g/L,接种体积为活性污泥吸附池有效容积的一半。The inverted adsorption tank sedimentation process based on carbon source classification and recovery according to claim 5, characterized in that: the inoculation concentration of activated sludge in the activated sludge adsorption tank is 4-8 g/L, preferably 6 g/L, The inoculation volume is half of the effective volume of the activated sludge adsorption tank. 根据权利要求5所述的基于碳源分类回收的倒置吸附池沉淀工艺,其特征在于:经过曝气,使活性污泥吸附池中的溶解氧含量为0.5-2.0mg/L,优选为0.5-1.0mg/L。The inverted adsorption tank sedimentation process based on carbon source classification and recovery according to claim 5, characterized in that: after aeration, the dissolved oxygen content in the activated sludge adsorption tank is 0.5-2.0 mg/L, preferably 0.5-2.0 mg/L. 1.0mg/L. 根据权利要求5所述的基于碳源分类回收的倒置吸附池沉淀工艺,其特征在于:具体包括如下步骤:The inverted adsorption tank precipitation process based on carbon source classification and recovery according to claim 5, is characterized in that: specifically comprises the following steps: 启动阶段:向活性污泥吸附池中投加好氧活性污泥,污泥取自污水处理厂好氧池末端;开启进水,采用SBR运行方式,在该阶段,斜板沉淀池和活性污泥吸附池不排放剩余污泥;Start-up stage: add aerobic activated sludge to the activated sludge adsorption tank, and the sludge is taken from the end of the aerobic tank of the sewage treatment plant; turn on the water, and adopt the SBR operation mode. At this stage, the inclined plate sedimentation tank and the activated sludge The sludge adsorption tank does not discharge excess sludge; 泥龄调试阶段:采用SBR运行方式,斜板沉淀池每天排放一次污泥,污泥排放量与沉淀池泥斗容积相当;活性污泥吸附池每天逐步增加剩余污泥的排放量,使其在1-2周内达到设定的SRT;Sludge age debugging stage: using SBR operation mode, the inclined plate sedimentation tank discharges sludge once a day, and the sludge discharge is equivalent to the sludge hopper volume of the sedimentation tank; the activated sludge adsorption tank gradually increases the discharge of excess sludge every day, so that it is Reach the set SRT within 1-2 weeks; 稳定运行阶段:当活性污泥吸附池的SRT稳定达到设定值后,进入稳定运行阶段;在该阶段,待处理污水先经斜板沉淀池沉淀回收易沉淀碳源,然后初步净化后的污水溢流至活性污泥吸附池的底部,在活性污泥的吸附和吸收作用下,回收污水中的碳源;Stable operation stage: When the SRT of the activated sludge adsorption tank reaches the set value stably, it enters the stable operation stage; in this stage, the sewage to be treated is first precipitated in the inclined plate sedimentation tank to recover the easy-to-precipitate carbon source, and then the sewage after preliminary purification It overflows to the bottom of the activated sludge adsorption tank, and under the adsorption and absorption of activated sludge, the carbon source in the sewage is recovered; 进一步的,斜板沉淀池的SBR运行分为进水和闲置两个阶段,进水阶段为15-25min,闲置阶段为40-50min;Further, the SBR operation of the inclined plate sedimentation tank is divided into two stages: inflow and idle, the inflow stage is 15-25min, and the idle stage is 40-50min; 进一步的,活性污泥吸附池的SBR运行分为进水、曝气、沉淀、出水和闲置四个阶段,其中,进水和曝气阶段为15-25min,DO为0.5-1.0mg/L;沉淀阶 段为15-25min;出水阶段为15-25min;Further, the SBR operation of the activated sludge adsorption tank is divided into four stages: water inflow, aeration, sedimentation, water effluent and idle. Among them, the water inflow and aeration stages are 15-25min, and the DO is 0.5-1.0mg/L; The precipitation stage is 15-25min; the effluent stage is 15-25min; 更进一步的,活性污泥吸附池的体积交换率为40-60%,闲置阶段为4-10min,用于排放剩余污泥;Further, the volume exchange rate of the activated sludge adsorption tank is 40-60%, and the idle stage is 4-10min, which is used to discharge excess sludge; 更进一步的,活性污泥吸附池中的SRT为1-3d。Further, the SRT in the activated sludge adsorption tank is 1-3d. 根据权利要求8所述的基于碳源分类回收的倒置吸附池沉淀工艺,其特征在于:启动阶段结束的标志为活性污泥吸附池的污泥增长量达到0.3-0.5g/L/d,泥龄调试阶段结束的标志为连续3d活性污泥吸附池的SRT为2.5-3.5d,且活性污泥吸附池中的污泥浓度为2-3g/L。The inverted adsorption tank sedimentation process based on carbon source classification and recovery according to claim 8, characterized in that: the sign of the end of the start-up stage is that the sludge growth in the activated sludge adsorption tank reaches 0.3-0.5g/L/d, and the sludge The sign of the end of the ageing debugging stage is that the SRT of the continuous 3d activated sludge adsorption tank is 2.5-3.5d, and the sludge concentration in the activated sludge adsorption tank is 2-3g/L. 根据权利要求8所述的基于碳源分类回收的倒置吸附池沉淀工艺,其特征在于:活性污泥吸附池的污泥浓度为2-3g/L,污泥中有机质浓度为1.4-2.4g/L,污泥中有机质含量为0.7-0.8。The inverted adsorption tank sedimentation process based on carbon source classification and recovery according to claim 8, characterized in that: the sludge concentration of the activated sludge adsorption tank is 2-3g/L, and the organic matter concentration in the sludge is 1.4-2.4g/L. L, the organic matter content in the sludge is 0.7-0.8.
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