WO2022163880A1 - System for treating dye wastewater and high-concentration wastewater, and method therefor - Google Patents

System for treating dye wastewater and high-concentration wastewater, and method therefor Download PDF

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Publication number
WO2022163880A1
WO2022163880A1 PCT/KR2021/001108 KR2021001108W WO2022163880A1 WO 2022163880 A1 WO2022163880 A1 WO 2022163880A1 KR 2021001108 W KR2021001108 W KR 2021001108W WO 2022163880 A1 WO2022163880 A1 WO 2022163880A1
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tank
wastewater
sludge
electrolysis
treatment step
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PCT/KR2021/001108
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French (fr)
Korean (ko)
Inventor
이병관
이병기
이성주
탁성제
김찬양
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청해이엔브이 주식회사
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Publication of WO2022163880A1 publication Critical patent/WO2022163880A1/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/126Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using drum filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/15Treatment of sludge; Devices therefor by de-watering, drying or thickening by treatment with electric, magnetic or electromagnetic fields; by treatment with ultrasonic waves
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes

Definitions

  • the present invention relates to a system and method for treating dyeing wastewater and high concentration wastewater, and more particularly, to a dyeing wastewater that can simplify and simplify wastewater treatment facilities and effectively treat wastewater while minimizing the use of chemicals and to a system and method for treating high concentration wastewater.
  • a method of removing contaminants and microorganisms contained in wastewater is carried out independently or mixed with a biological method and a chemical method, and goes through a process of separating untreated residues.
  • the biological method is a method of decomposing and removing wastewater using microorganisms, and the quality of the treated water is greatly affected by the solid-liquid separation efficiency in the sedimentation tank. As a result, the grown microorganisms are precipitated in the form of sludge in the sedimentation tank, separated and removed from water.
  • Korean Patent Laid-Open Publication No. 10-2017-0101162 discloses a method for treating high concentration maintenance wastewater.
  • This high-concentration maintenance wastewater treatment method includes a wastewater pretreatment step, moving animal fats and oils that have passed through a pressurized flotation tank by the wastewater pretreatment to a batch storage tank, and 4 to 8 days so that the pH of the animal fats and oils transferred from the batch storage tank becomes neutral. It includes the step of treating during the water treatment and mixing the treated animal fats and oils in a contact aeration tank.
  • the above-described high-concentration maintenance wastewater treatment method can stably purify high-concentration maintenance wastewater
  • the wastewater passes through a screen and flows into a water collecting tank, is pretreated in a reaction tank, a neutralization tank, and a coagulation tank, and then moves to a pressurized flotation tank.
  • the supernatant water treated in the pressurized flotation tank is discharged after passing through the flow control tank, the contact aeration tank, and the settling tank.
  • Patent Publication No. 10-2017-0101162 require a large amount of chemicals such as coagulants and neutralizers during pretreatment, so there is a problem in that secondary pollution due to chemical components and the amount of sludge generated by chemicals increase. have.
  • Patent Publication No. 10-2017-0101162 has a disadvantage in that the removal efficiency of the difficult-to-decomposable substances or chromaticity contained in the dyeing wastewater is low.
  • the conventional wastewater treatment method has an excessive amount of generated sludge, which causes air pollution due to incineration of the sludge, increases the land area of landfill due to the increase in the amount of landfill, and causes secondary environmental pollution due to leachate. have.
  • the present invention has been proposed in view of the above, and a system and method for treating dyed wastewater and high-concentration wastewater that can simplify and simplify wastewater treatment facilities and effectively treat wastewater while minimizing the use of chemicals Its purpose is to provide
  • Another object of the present invention is to provide a system and method for treating dyeing wastewater and high-concentration wastewater, which can easily remove difficult-to-decompose substances or chromaticity contained in dyeing wastewater or high-concentration wastewater.
  • Another object of the present invention is to provide a system and method for treating dyed wastewater and high-concentration wastewater, which can minimize environmental pollution and reduce wastewater treatment costs by effectively reducing the amount of sludge.
  • a system for treating dyeing wastewater and high-concentration wastewater includes: a sedimentation/screen tank for removing solids contained in the wastewater introduced in the system for treating dyeing wastewater and high-concentration wastewater; a flow rate adjustment tank for adjusting the flow rate of wastewater passing through the sediment/screen tank; a primary electrolysis device that primarily performs an electrochemical treatment process of wastewater passing through the flow control tank; a pressurized flotation tank for coagulating and floating the flocs by bringing the bubbles generated from the bubble generator into contact with the wastewater that has passed through the primary electrolysis device; an anoxic tank for removing nitrogen and organic matter by denitrifying nitrate nitrogen using organic matter contained in the wastewater passed through the primary electrolysis device; an anaerobic tank to allow residual denitrification and phosphorus release by using the organic matter remaining in the wastewater passing through the anaerobic tank; a contact aeration tank configured to contact and grow microorganisms with organic matter remaining in the wastewater passing through the
  • the sludge treatment unit may include: a thickening tank configured to concentrate the sludge flowing in from the contact aeration tank and return supernatant water to the flow rate control tank; a sludge reduction device for reducing the weight by rotating the sludge discharged from the thickener at high speed; and a dehydrator for dewatering the moisture in the sludge discharged from the sludge reduction device to separate solid and liquid.
  • the contact aeration tank is configured with a first return line and a second return line to selectively return a portion of the generated sludge to the flow rate control tank or the anaerobic tank, and the membrane separation tank transfers the generated sludge to the primary electrolysis device or the A third return line and a fourth return line are configured to selectively return to the anoxic tank, and the concentration tank may include a fifth return line configured to return the generated supernatant to the flow rate control tank.
  • the primary electrolysis device and the secondary electrolysis device may include: an electrolysis body provided with an electrolysis chamber in which wastewater is introduced and accommodated; a stirrer installed in the electrolysis body; an electrolysis unit installed in the electrolysis chamber and having a plurality of positive and negative electrode plates and a pole plate mounting table on which the positive and negative plates are installed, and a power supply unit for supplying power for electrolysis to the negative electrode and positive plate; an inlet line connected to the electrolysis body; a discharge line connected to the electrolysis body and provided with a discharge control valve; a water level sensing unit installed to detect the level of wastewater flowing into the electrolysis chamber; a pressure pump for pumping wastewater to the electrolysis chamber through the inlet line; and an electrolysis device control unit for controlling the driving of the pressure-feeding pump based on the detection signal of the water level sensing unit.
  • the sludge reduction device a drive shaft rotatably installed on the base frame; a drum rotatably connected to the drive shaft and having a plurality of perforations; a drum driving means connected to generate and apply a rotational force for rotating the drum; a processing chamber disposed to surround the outside of the drum and formed with an outlet; and a plurality of plasma radiation electrodes installed in the processing chamber, and a plasma generator having a plasma generator for applying a high voltage to the plasma radiation electrodes.
  • the drum may include an inner drum which is installed on the drive shaft, rotates and has a plurality of perforations, and an outer drum which is disposed to surround the outside of the inner drum and has a plurality of perforations.
  • the drum driving means may include an internal drum driving means connected to generate and apply a rotational force to the drive shaft, and an external drum driving means connected to rotate the external drum.
  • the drive shaft includes a first drive shaft and a second drive shaft connected to one side and the other side of the inner drum, and at least one of the first drive shaft and the second drive shaft has a sludge movement path formed therein, so that the inner drum It may consist of a hollow pipe to feed the sludge into the furnace.
  • the sludge reduction device may include a magnetic field generator installed to apply a magnetic force to the sludge moving outside the hollow pipe.
  • a method for treating dyeing wastewater and high-concentration wastewater includes a screen bath treatment step of removing solids contained in the wastewater introduced by the sedimentation/screen bath; a flow rate adjustment tank processing step of adjusting the flow rate of wastewater passing through the sediment/screen tank in the flow rate adjustment tank; a primary electrolysis step of primarily removing contaminants and chromaticity by using the oxidizing power of OH radicals through the electrochemical treatment process of the wastewater passing through the flow control tank; and a pressurizing flotation tank treatment step of contacting the wastewater introduced into the pressurizing flotation tank via the primary electrolysis device with the bubbles generated by the bubble generating device so that the flocs are agglomerated and floated.
  • nitrate nitrogen is denitrified using organic matter contained in wastewater while the wastewater passing through the primary electrolysis device is retained in the anaerobic tank for 1 to 9 hours.
  • anoxic treatment step of oxidizing to remove nitrogen and organic matter an anaerobic tank treatment step of maintaining the wastewater passing through the anaerobic tank in the anaerobic tank for 4 to 8 hours and using the remaining organic matter to perform residual denitrification and phosphorus release; a contact aeration tank treatment step of forming microbial flocs by contacting and growing microorganisms with organic matter remaining while aeration of wastewater passing through the anaerobic tank in the contact aeration tank; a membrane separation tank treatment step of nitrifying and separating microorganisms from the wastewater passing through the contact aeration tank in the membrane separation tank; A secondary electrolysis step of performing a secondary electrolysis step of removing contaminants and chromaticity by using the oxidizing power of OH radicals through the electrochemical treatment process by the secondary electrolysis device of the wastewater passing through the membrane separation tank; a sump treatment step of receiving the wastewater passing through the secondary electrolysis device in the sump and discharging the supernatant; and
  • the step of treating the contact aeration tank may include selectively returning a portion of the sludge generated in the contact aeration tank to the flow rate control tank or the anoxic tank.
  • the membrane separation tank treatment step may include selectively returning a portion of the sludge generated in the membrane separation tank to the primary electrolysis device or the anoxic tank.
  • the sludge treatment step includes a thickening tank process for concentrating the sludge generated by the contact aeration tank treatment step through a settling process, a sludge reduction process for physically reducing the sludge that has undergone the concentration process, and dewatering the sludge that has undergone the sludge reduction process. It may include a dehydration process.
  • the system and method for treating dyed wastewater and high-concentration wastewater according to the present invention, a large amount of land and facility investment cost is required by connecting an electrolysis device and a pressurized flotation tank and performing a multi-stage sludge treatment process during wastewater treatment
  • facilities such as a reactor, neutralization tank and coagulation tank are unnecessary, wastewater treatment facilities can be simplified and simplified, and the use of chemicals can be reduced. There is an effect that can be done.
  • FIG. 1 is a schematic schematic diagram for explaining a system for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention
  • Figures 2a to 2c is a view for explaining the primary and secondary electrolysis apparatus applied to the system for the treatment of dyeing wastewater and high concentration wastewater according to an embodiment of the present invention
  • Figure 2a is a front view
  • Figure 2b is A front cross-sectional view showing the internal structure of the electrolysis body
  • FIG. 2C is a plan cross-sectional view.
  • Figure 3a is a view showing the front structure of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention
  • Figure 3b is a view showing the planar structure of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention
  • Figure 3c is a schematic configuration diagram for explaining the magnetic field generator of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention
  • Figure 3d is a schematic perspective view for explaining the inner drum of the sludge reduction device of the system for the treatment of dyeing wastewater and high concentration wastewater according to an embodiment of the present invention
  • Figure 3e is a schematic perspective view for explaining the external drum of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention
  • 3f is a schematic perspective view for explaining a treatment chamber of a sludge reduction device of a system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention
  • Figure 3g is a view for explaining the operation of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention
  • FIG. 4 is a process diagram for explaining a method for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention.
  • FIG. 1 is a schematic diagram for explaining a system for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention.
  • the system for treating dyeing wastewater and high-concentration wastewater is characterized in that it is configured to effectively treat wastewater while minimizing the use of chemical agents.
  • (1a) flow rate control tank (2), primary electrolysis device (3a), pressurized flotation tank (4), anoxic tank (5), anaerobic tank (6), contact aeration tank (7), membrane separation tank (8), 2
  • the primary electrolysis device 3b, the drainage tank 1b, and the sludge treatment unit 9 are provided as main components.
  • the above-mentioned main components are arranged so that flow treatment is possible, and except for some components, the detailed structures and shapes are well-known devices that are widely applied in sewage and wastewater treatment systems. It will be described in detail below with a focus on the components having .
  • the sediment/screen tank 1a is a component that removes solids contained in the inflowing wastewater, and has a conventional structure including a screen for removing materials with large particle sizes, such as sand and solids.
  • the flow rate adjustment tank 2 is a component that adjusts the flow rate of wastewater passing through the sedimentation/screen tank 1a, and may be composed of an open tank, etc., but in this embodiment, as shown in FIG. 2a, the first electrolysis device It consists of a sealed tank on which (3a) is mounted, and piping etc. are connected so that the wastewater treated by the anaerobic tank 5 may flow.
  • FIG. 2a to 2c are views for explaining the primary and secondary electrolysis devices applied to the system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention
  • FIG. 2a is a front view
  • Figure 2b is a front sectional view showing the internal structure of the electrolysis body
  • Figure 2c is a plan sectional view.
  • the primary electrolysis device 3a is a component that primarily performs an electrochemical treatment process of wastewater passing through the flow rate adjustment tank 2,
  • the oxidizing power of OH radicals By using the oxidizing power of OH radicals, contaminants, difficult-to-decompose substances, and chromaticity can be removed. Accordingly, facilities such as a neutralization tank, a reaction tank, and a coagulation tank, which were required to form flocs in the conventional wastewater treatment process, are unnecessary, and the conventional problems in which a large amount of chemicals such as a neutralizing agent and a coagulant must be input can be solved.
  • the primary electrolysis device (3a) is the electrolysis device frame 31, the electrolysis body 32, the stirrer 33, the electrolysis unit 34, the inlet line 35, and the discharge line (36) This is provided.
  • the electrolysis device frame 31 is formed by a transverse member and a vertical member to support the electrolysis body 32, and the transverse member and the vertical member are formed of a section steel material such as a square bar.
  • the electrolysis body 32 is formed in a hexahedral shape by a plate material so that an electrolysis chamber 32a in which wastewater is accommodated is provided, and is accommodated in the electrolysis body 32 from the outside as shown in FIG. 2a.
  • a see-through window (32b) for monitoring is installed so that the electrolysis unit (34) and the stirrer (33) operating state can be checked.
  • the stirrer 33 is installed in the electrolysis body 32 and stirs the sludge that is deposited on the bottom of the electrolysis chamber 32a, floats and mixes the contaminants, difficult-to-decompose substances, and chromaticity by the electrolysis unit 34 by stirring. It is designed to enhance the removal efficiency.
  • the agitator 33 is composed of a stirring motor 33a exposed to the outside, a stirring shaft 33b rotated by the stirring motor, and a blade 33c installed on the stirring shaft.
  • the electrolysis unit 34 is installed in the electrolysis chamber 32a and includes a plurality of positive electrode plates 34a and negative electrode plates 34b, and a positive electrode plate 34a and negative electrode plate 34b installed on the electrode plate mounting table 34c, negative electrode plate and positive electrode plate.
  • a power supply unit (not shown) for supplying power for electrolysis is provided.
  • the positive electrode plate 34a and the negative electrode plate 34b may be formed of an iridium plate and an aluminum plate having different electrical conductivity, but is not limited thereto.
  • the inflow line 35 is configured to introduce wastewater into the electrolysis chamber 32a, and is composed of a pipe or a hose connected to the upper portion of the electrolysis body.
  • the discharge line 36 is configured for discharging the wastewater inside the electrolysis chamber 32a to the outside, and is connected to the lower portion of the electrolysis body 32 and converts the treated wastewater into the pressurized flotation tank 2, the second electrolysis In the case of the device, it is composed of pipes or hoses that supply to the drain tank).
  • a discharge control valve 37 that opens and closes to control the discharge of wastewater is installed in the discharge line 36, and an overflow line 38 through which wastewater overflows from the electrolysis chamber 32a is discharged. this is installed
  • the overflow line 38 has one end connected to the upper portion of the electrolysis body 32 and the other end connected to the discharge line 36 .
  • the primary electrolysis device 32a electrolyzes wastewater through a water level detection unit 39 such as a water level sensor installed to detect the level of wastewater flowing into the electrolysis chamber 32a, and an inlet line 35 .
  • a water level detection unit 39 such as a water level sensor installed to detect the level of wastewater flowing into the electrolysis chamber 32a
  • An electrolysis device control unit (not shown) that controls the driving of the pressure feeding pump based on the detection signal of the pressure feeding pump 35a and the water level detecting unit 39 and controlling the opening and closing of the discharge control valve 37 to the chamber 32a. city) is composed.
  • the primary electrolysis device 32a may inject a neutralizing agent or a coagulant such as caustic soda, slaked lime, etc. when it does not reach an appropriate level by measuring the treatment quality during the treatment of wastewater.
  • the electrolysis body 32 is provided with an inlet (not shown) so that a neutralizing agent or a coagulant can be put in the upper part.
  • the reason for injecting the neutralizing agent or coagulant into the primary electrolysis device 32a as described above is that the stirrer 33 is provided therein, which has the advantage of rapidly performing the dissolution process of the chemical, and the pressurized flotation tank (4) This is to improve the efficiency of the pressurized flotation tank treatment step by being able to perform pretreatment of wastewater at the front end of the.
  • the pressure flotation tank 4 is a treatment tank for treating wastewater using microbubbles, and is provided with a bubble generator (not shown).
  • the bubble generator may be configured without any particular limitation as long as it is a device capable of generating microbubbles.
  • the bubble generator may be composed of a pressurized tank for pressurizing air and water and a bubble nozzle (not shown) for ejecting the air and water from the pressurized tank into the pressurized flotation tank 4 .
  • the above-mentioned pressurized flotation tank (4) brings the bubbles generated from the bubble generator into contact with wastewater, and the agglomerated flocs attach to and float on the exiting air bubbles so that they are removed through a post-treatment process, and the supernatant is an anaerobic tank (5) will be transferred to
  • the anoxic tank 5 is a component that removes nitrogen and organic matter by denitrifying and oxidizing nitrate nitrogen using organic matter contained in the wastewater that has passed through the primary pressurized flotation tank 4, and this anoxic tank is a special high-pressure quantum field emission circuit. It is desirable to increase the removal efficiency of pollutants by adding a device for processing pollutants by adjusting the projected dose and waveform by matching the high frequency of the variable waveform.
  • the contact aeration tank 7 is a component that contacts and grows microorganisms with the organic matter remaining in the wastewater passing through the anaerobic tank 6 to form a microbial floe and returns a part of the sludge to the flow rate control tank 2, and is formed in the form of a tank. , a nozzle (not shown) to which a pipe directed to the membrane separation tank 8 is connected, and a nozzle (not shown) to which a first transport line 72 and a second transport line 73, which will be described later, are connected.
  • the contact aeration tank 7 is configured with a first return line 72 and a second return line 73 to selectively return the generated sludge to the flow rate adjustment tank 2 or the anoxic tank 5 .
  • the membrane separation tank 8 is a component that causes nitrification and microbial separation to occur by membrane separation of the wastewater passing through the contact aeration tank 7, and is configured similarly to a known membrane separation tank applied to a sewage and wastewater treatment system. .
  • the membrane separation tank 8 includes a third return line 82 and a fourth return line 83 to selectively return the sludge generated inside to the primary electrolysis device 3a or the anoxic tank 5 .
  • the secondary electrolyzer 32 is a component that secondary performs the electrochemical treatment process of wastewater passing through the membrane separation tank 8, and similarly to the above-described primary electrolyzer 3a, the electrolysis device frame (31), the electrolysis body 32, the stirrer 33, the electrolysis unit 34, the inlet line 35, the discharge line 36, the water level detection unit 39, the pressure pump (35a), the electrolysis A device control unit (not shown) is provided.
  • the drain tank 1b is a component through which wastewater flows through the secondary electrolysis device 3b and supernatant water is discharged, and is configured similarly to a known drain tank applied to a sewage and wastewater treatment system.
  • the sludge treatment unit 9 is a component through which the sludge of the contact aeration tank 7 is introduced, concentrated and removed, and is provided with a thickener 9a, a sludge reduction device 9b, and a dehydrator 9c.
  • the thickening tank 9a is configured to concentrate the sludge flowing in from the contact aeration tank 7 and return the supernatant water to the flow rate adjustment tank 2, and to return the supernatant water generated in the thickening tank 9a to the flow rate adjustment tank 2
  • Five conveyance lines 92 are configured.
  • the dehydrator 9c is a component that dehydrates the moisture of the sludge discharged from the sludge reduction device 9b and separates the solid-liquid, and a known dehydrator used for dewatering the sludge in the sewage and wastewater treatment system is selected according to the capacity. do.
  • the above-described first conveying line to the fifth half-in line (72, 73, 82, 83, 92) is composed of a pipe or a hose, an on/off valve (not shown) for controlling the flow, and a pump for pressure feeding (not shown). ) can be installed.
  • FIG. 3A is a view showing the front structure of a sludge reduction device of a system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention
  • FIG. 3B is a dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention
  • FIG. 3A is a view showing the front structure of a sludge reduction device of a system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention
  • FIG. 3B is a dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention
  • the sludge reduction device 9b is a component that reduces the weight by rotating the sludge discharged from the thickening tank 9a at high speed, and includes a base frame 91, a drive shaft 92, a drum 93, A drum driving means (94), a processing chamber (95) and a plasma generating device (96) are provided.
  • the base frame 91 is composed of a frame structure of a substantially hexahedral shape by a plurality of vertical members 911 spaced apart and installed in the longitudinal direction, and a plurality of transverse members 912 connected to the vertical members 911.
  • the vertical member 911 and the transverse member 912 are made of a plate material or a section steel such as a square bar.
  • the base frame 91 has a rolling wheel 913 installed at the lower part for free movement, and an upper plate (not shown) may be installed on the upper part.
  • the drive shaft 92 is a component rotatably installed on the base frame 91 to rotate the drum 93, and a first drive shaft 921 connected to one side of the inner drum 931 to be described later, the inner drum ( It is comprised by the 2nd drive shaft 922 connected to the other side of 931.
  • the first drive shaft 921 is formed with a sludge flow path therein and is configured as a hollow pipe to supply sludge to the inside of the inner drum 931 , and the second drive shaft 922 is configured as a round bar having a clogged structure.
  • the hollow pipe is characterized in that the spiral moving groove 9212 is recessed into the inner surface of the pipe body in a spiral shape.
  • the spiral movement groove 9212 is formed inside the first drive shaft 921 as described above, when the sludge is pressurized by a pressure pump (not shown), which will be described later, it turns and swirls when ejected to the inner drum 931 . Since it is sprayed while generating
  • the drive shaft 92 may be changed to a form in which the second drive shaft 922 is a hollow pipe and the first drive shaft 921 is a round bar according to the amount or shape of sludge, or the first and second drive shafts It can also be configured by changing the method of configuring all of them with a hollow pipe.
  • Figure 3c is a schematic configuration diagram for explaining the magnetic field generator of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention.
  • the magnetic field generating unit 97 is configured on the first driving shaft 921, which is the part into which the sludge is introduced.
  • the magnetic field generating unit 97 is installed outside the hollow pipe to apply a magnetic force to the sludge moved to the sludge movement path of the first drive shaft 921 .
  • the magnetic field generating unit 97 may be configured by installing only a magnetic member such as a permanent magnet, but in this embodiment, electrical energy using a physical force such as vibration applied to the first drive shaft 921 when the sludge is pumped It is characterized in that it is composed of an electromotive force generating unit so that it can be used by applying it to the plasma generating unit after generating electricity.
  • the magnetic field generating unit 97 includes a plurality of magnetic members 971 installed around the outer surface of the hollow pipe (the ninth first driving shaft), and an induction coil disposed in contact with the magnetic member 971.
  • the electromotive force generating unit 972 may be configured with a circuit unit for providing the generated power to the plasma generating unit (not shown).
  • the circuit unit may be composed of a known circuit that rectifies the generated power output from the electromotive force generating unit and changes to a predetermined rated power.
  • Figure 3d is a schematic perspective view for explaining the inner drum of the sludge reduction device of the system for the treatment of dyeing wastewater and high concentration wastewater according to an embodiment of the present invention
  • Figure 3e is a dyeing wastewater and high concentration according to an embodiment of the present invention
  • It is a schematic perspective view for explaining the external drum of the sludge reduction device of the system for wastewater treatment.
  • the drum 93 is a tubular body having a plurality of perforations, which is rotatably connected to the drive shaft 92 and rotates at a high speed while dismantling the sludge floc and destroying the cell membrane. Actual sludge reduction is performed by removing water, capillary-bonded water, and pore water.
  • the drum 93 can be configured as one or three or more to perform the sludge reduction action in multiple stages, but in this embodiment, two drums are sequentially arranged inside and outside in the form of an inner cylinder and an outer cylinder. .
  • the drum 93 is rotated by connecting a first driving shaft 921 and a second driving shaft 922 to one side and the other side, and an inner drum 931 formed by perforating a plurality of perforations in a plate material, and the inside It is arranged to surround the outside of the drum 931 and consists of an external drum 932 formed by perforating a plurality of perforations in a plate material.
  • the outer drum 932 includes an outer drum body 9321 disposed to surround the inner drum 931 , and an outer drum rotating shaft extending from one side and the other side of the outer drum body 9321 to be rotatably disposed on the driving shaft 92 . (9322).
  • the external drum rotating shaft 9322 is composed of a first external drum rotating shaft 9322a rotatably disposed on the first driving shaft 921 and a second external drum rotating shaft 9322b disposed outside of the second driving shaft 922.
  • the first and second external drum rotation shafts 9322a and 322b are formed in a pipe shape, and the second external drum rotation shaft ( 9322b) is formed to have a larger diameter.
  • the inner drum 931 and the outer drum 932 are formed to have a substantially cylindrical shape, and a plurality of perforations are perforated on the surface thereof, and a plurality of concavo-convex portions (not shown) are formed to increase the sludge reduction effect. It is preferable to be
  • the drum driving means 94 is a component connected to generate and apply a rotational force for rotating the drum, and an internal drum driving means 941 for generating and applying a rotational force to the driving shaft 92 for rotation of the inner drum 931 . ) and an external drum driving means 942 connected to rotate the external drum 932 .
  • the internal drum driving means 941 is an internal drum driving motor 9411 installed on the base frame 91, a driving pulley 9412 connected to the motor shaft of the internal drum driving motor 9411, and one side of the driving pulley 9412
  • the belt 9413 to be connected, the other side of the belt 9413 is connected, and an electric pulley 9414 connected to the first drive shaft 921 is provided.
  • the external drum driving means 942 is an external drum driving motor 9421 installed on the base frame 91, a driving pulley 9422 connected to the motor shaft of the external drum driving motor 9421, and one side of the driving pulley 9422.
  • a belt 9423 to which this is connected, and an electric pulley 9424 to which the other side of the belt 9423 is connected and connected to the first external drum rotating shaft 9322a are provided.
  • the above-described inner drum driving means 941 and external drum driving means 942 rotate the inner drum 931 and the outer drum 932 so as to increase the weight loss action such as sludge floc dissolution or cell membrane destruction. It is important to configure them so that they are in opposite directions. That is, when the inner drum driving means 941 rotates the inner drum 931 clockwise, the outer drum driving means 942 rotates the outer drum 932 counterclockwise.
  • the inner drum driving means 941 and the external drum driving means 942 are the driving pulleys 9412 and 422 and the electric pulleys 9414 and 424 as power transmission means and a belt composed of the belts 9413,423 connected thereto.
  • it is configured as a power transmission method, it may also be configured as a gear power transmission method (not shown) in which power is transmitted through meshing of gears.
  • the inner drum driving motor 9411 and the external drum driving motor 9421 are configured as motors having a speed reducer to rotate the inner drum 931 and the outer drum 932 at 16,000 rpm.
  • 3F is a schematic perspective view illustrating a treatment chamber of a sludge reduction device of a system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention.
  • the processing chamber 95 is formed to surround the outside of the drum 93 to be accommodated and installed on the base frame 91, the chamber body 951 of the hexahedral shape of which the upper and lower portions are concave, the A pipe-shaped drain line 952 installed at the lower outlet of the chamber body 951 is provided.
  • the processing chamber 95 has a shaft insertion hole 953 formed on the side thereof so that the driving shaft 92 and the external drum rotating shaft 9322 are rotatably inserted and installed.
  • the plasma generator 96 includes a plurality of plasma radiation electrodes 961 installed in the processing chamber 95, and a plasma generator (not shown) for applying a high voltage to the plasma radiation electrodes 961 .
  • the plasma radiation electrode 961 is composed of a plurality of anode plasma radiation electrodes and a plurality of cathode plasma radiation electrodes, and the anode and cathode plasma radiation electrodes are installed in a socket to have a certain distance from each other and are coupled to the processing chamber 95. have.
  • the positive plasma radiation electrodes are electrically connected to the positive terminal of the plasma generator via a positive power line (not shown), and the negative plasma radiation electrodes are electrically connected to the negative terminal of the plasma generator via a negative power line (not shown). is connected with
  • the above-described plasma generating unit (not shown) can be applied without any particular limitation as long as it has excellent sterilization properties of harmful bacteria contained in sewage and wastewater.
  • the plasma generating unit may be configured as a low-temperature plasma driving unit.
  • the low-temperature plasma driving unit consists of a power supply unit (not shown) for supplying power, and a driving circuit unit (not shown) that is electrically connected to the power supply unit and applies a predetermined voltage and current to the anode and cathode plasma radiation electrodes. It is configured by applying a common low-temperature plasma driving unit used in the field of generators.
  • the sludge reduction device is provided with a rotation support means 98 to rotatably support the drive shaft 92 and the external drum rotation shaft 9322.
  • the rotation support means 98 is a component installed on the base frame 91 , and includes a first bearing block 981 , a second bearing block 982 , a third bearing block 983 , and a fourth bearing block 984 .
  • the first to fourth bearing blocks 981, 982, 983, and 984 are integrally formed with a fastening bracket that is bolted to the to-be-installed part at the lower part of the housing into which the bearing is inserted, which is commonly referred to as a pillow block. .
  • the first bearing block 981 is installed on the base frame 91 so that the bearing is connected to the first drive shaft 921 , and the second bearing block 982 is the base frame ( 91) is installed.
  • the third bearing block 983 is installed on the base frame so that the bearing is connected to one side of the first external drum rotating shaft 9322a, and the fourth bearing block 984 is the bearing connected to the second external drum rotating shaft 9322b. It is installed on the base frame as much as possible.
  • the sludge reduction device includes a pressure pump (not shown) for pumping sludge into the inner drum 931 .
  • the pressure pump is composed of a sludge pump to enable easy pumping even if the liquid contains solid materials such as sludge.
  • a discharge pipe (not shown) for example, the discharge pipe (not shown) may be configured in such a way that the high-pressure hose is hermetically connected to the inlet of the first driving shaft 921 .
  • non-explained reference numeral 9 of FIG. 3A is a control box in which a control unit (not shown) for controlling the driving of the drum driving means 94 and the plasma generating device 96 is mounted therein.
  • a control unit for controlling the driving of the drum driving means 94 and the plasma generating device 96 is mounted therein.
  • an input unit such as a power button and an on/off button, a display for displaying an operating state, etc. may be installed in the control box 99 .
  • Figure 3g is a view for explaining the operation of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention. is a floor plan.
  • the sludge is introduced into the first drive shaft 921 by the pumping action of the pressure pump (not shown), and the inner drum 931 and the outer drum 932 are formed. A weight reduction action of the sludge discharged to the treatment chamber 95 via the gas flow is performed.
  • the inner drum 931 rotates while the first drive shaft 921 is rotated as the rotational force of the inner drum driving motor 9411 is transmitted in the order of the drive pulley 9412 , the belt 9413 , and the electric pulley 9414 .
  • the rotational force of the external drum driving motor 9421 is transmitted to the external drum 932 in the order of the driving pulley 9422, the belt 9423, and the electric pulley 9424
  • the first external drum rotating shaft 9322a is rotated while the external drum 932 is rotated. perform rotational motion.
  • the sludge pumped by the pressure pump rotates along the spiral movement groove 9212 of the first drive shaft 921 and is ejected to the inner drum 931 while generating a vortex. It can increase the sludge reduction effect.
  • the intermolecular and ionic bonds are weakened by the magnetic force of the magnetic member 971, so the subsequent sludge flocs ( floc) can increase the effect of dismantling or destroying cell membranes, thereby increasing the sludge reduction effect.
  • the sludge ejected into the inner drum through the first driving shaft 921 collides with the uneven portion of the inner wall of the inner drum 931 to dismantle the sludge floc or destroy the cell membrane, and the inner drum is perforated. It is discharged to the external drum 932 through the secondary collision, and then is discharged to the processing chamber 95 through the external drum 932 .
  • the inner drum 931 and the outer drum 932 not only rotate at a high speed at 16,000 rpm, respectively, but also rotate in opposite directions to each other, so that the sludge floc dismantling or cell membrane destruction action is effectively performed.
  • harmful bacteria contained in the sludge flowing into the treatment chamber 95 are sterilized and removed through the plasma sterilization process by the plasma generator 96 . That is, as is well known, according to the operation of the plasma generating unit, a low voltage discharge phenomenon occurs between the positive and negative plasma radiation electrodes 961 to generate hydroxyl groups, and harmful bacteria are sterilized by the strong oxidation of the hydroxyl groups. At this time, the sterilization can be performed more efficiently by adjusting the interval or quantity between the positive and negative plasma radiation electrodes 961 according to the amount or type of the introduced sludge.
  • the sludge which has undergone the sludge reduction process as described above, is discharged to the outside through the pipe-shaped drain line 952 installed at the lower outlet of the chamber body 951, is transferred to the dehydrator 9c, and is subjected to a predetermined treatment process.
  • FIG. 4 is a process diagram for explaining a method for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention.
  • the method for treating dyeing wastewater and high-concentration wastewater includes a screen tank treatment step, a flow rate control tank treatment step, a primary electrolysis step, a pressure flotation tank treatment step, an anaerobic tank treatment step, The anaerobic tank treatment step, the contact aeration tank treatment step, the membrane separation tank treatment step, the secondary electrolysis step, the drainage tank treatment step, and the sludge treatment step are sequentially performed.
  • the screen bath treatment step is a step of removing the solids contained in the wastewater introduced by the sedimentation/screen bath 1a, and the residence time is 1 minute or more to remove large particle size materials such as sand and solid materials, but wastewater
  • the oil contained in the sediment is separated by the specific gravity difference between water and oil in the sedimentation/screen tank.
  • this screen bath treatment step it is possible to protect a pump, etc. provided in a subsequent treatment facility from foreign substances by separating solids or light contaminants with a large specific gravity.
  • the flow rate adjustment tank treatment step is a step in which the flow rate of wastewater passing through the sedimentation/screen tank 1a is adjusted in the flow rate adjustment tank 2, and since the incoming wastewater is not constant, when the flow rate is small, the flow rate and wastewater treatment quality are equalized The wastewater is supplied to the next step after confinement and storage until a certain amount is reached.
  • the primary electrolysis step is to first remove contaminants and chromaticity by using the oxidizing power of OH radicals generated through the electrochemical treatment process by the primary electrolysis device (3a) of wastewater passing through the flow control tank (2).
  • the mechanism of generation of OH radicals is a well-known technique, and thus a detailed description thereof will be omitted.
  • This primary electrolysis step reduces the concentration of organic matter including COD by oxidation and reduction reactions by chlorine and hydrogen gas, increases the flotation property of the sludge by the generated gas, and forms fine bubbles, so the subsequent pressurized flotation tank performance can be improved.
  • the primary electrolysis step can omit facilities such as a reaction tank, a neutralization tank, and a coagulation tank, which are essentially required as a pretreatment process of the pressure flotation tank treatment step in the conventional wastewater treatment system, and the coagulant and neutralizer used in the conventional pretreatment It is possible to reduce the amount of chemicals used, such as reducing costs, as well as reducing the amount of sludge generated due to excessive use of chemicals, thereby reducing the processing load.
  • the pressure flotation tank treatment step is a step of removing the wastewater introduced into the pressure flotation tank 4 via the primary electrolysis device 3a by contacting the microbubbles generated by the bubble generator so that the flocs are agglomerated and floated. to be.
  • the anoxic tank treatment step is a step of removing nitrogen and organic matter by denitrifying the nitrate nitrogen contained in the wastewater while retaining the wastewater passing through the pressurized flotation tank in the anoxic tank 5 for 1 to 9 hours.
  • the residence time is preferably in the range of 3 to 9 hours. Compared to the range of 1 to 3 hours, which is the residence time of the existing anaerobic tank, the residence time is maintained about 3 times or more, thereby increasing the self-extinguishing of wastewater and removing excess sludge. occurrence can be reduced.
  • the removal efficiency of pollutants by adding a device for processing pollutants by matching the high frequency of the variable waveform to the special high-pressure quantum field emission circuit in the anoxic tank 5 and adjusting the projected dose and waveform.
  • the quantum field of an appropriate wave is injected while stirring the difficult-to-decompose pollutants contained in various types of sewage and wastewater, the molecules of the polluting element dissociate with anions and cations in Electro Equilibrium. Dissociated and hydrated organic compounds or heavy metal complex ions are separated from the hydration layer and cause a Gas Like Reaction in water.
  • the anaerobic tank treatment step is an anaerobic tank treatment step in which residual denitrification and phosphorus release are made using the remaining organic matter while the wastewater passing through the anaerobic tank 5 is stayed in the anaerobic tank 6 for 4 to 8 hours.
  • the contact aeration tank treatment step is a step of forming microbial flocs by contacting and growing microorganisms with the remaining organic matter while aerating the wastewater that has passed through the anaerobic tank 6 in the contact aeration tank 7, in which living or dead microorganisms are suspended
  • Microorganisms in activated sludge act to decompose organic matter through metabolism in an aerobic environment.
  • the role of the contact aeration tank in the activated sludge method using this is that microorganisms and organic matter in the inflow wastewater come into contact with the microorganisms to grow and form microbial flocs. it works And it is desirable to design the residence time in the contact aeration tank to be 3 to 14 hours.
  • a circulation process of selectively returning a part of the sludge generated in the contact aeration tank 7 to the flow rate control tank 2 or the anoxic tank 5 is performed.
  • This circulation process increases the residence time of the sludge in the treatment process by returning a part of the sludge to the flow control tank 2 or the anoxic tank 5 to enable the sludge circulation generated by the wastewater, thereby self-extinguishing the sludge. can improve processing efficiency.
  • the membrane separation tank treatment step is a step for nitrification and microbial separation of the wastewater passing through the contact aeration tank 7 to occur in the membrane separation tank 8.
  • nitrite is used as an intermediate medium to continuously ammonium is oxidized to nitrite, and at the same time, the remaining BOD components consumed in the anoxic tank process are decomposed by aerobic microorganisms.
  • a circulation process is performed in which the sludge generated in the membrane separation tank 7 is selectively returned to the primary electrolysis device 3a or the anoxic tank 5 depending on the state.
  • This circulation process increases the residence time of the sludge in the treatment process by returning a part of the sludge to the primary electrolysis device 3a or the anoxic tank 5 to enable the sludge circulation generated by the wastewater, thereby increasing the sludge Treatment efficiency can be improved by self-extinguishing.
  • the secondary electrolysis step is to use the oxidizing power of OH radicals to secondarily remove contaminants and chromaticity through the electrochemical treatment process of the wastewater passing through the membrane separation tank (8) by the secondary electrolysis device (3b).
  • the purification efficiency of wastewater can be improved as well as the amount of chemicals such as flocculants and neutralizers can be reduced, thereby reducing costs and excessive chemical It is possible to reduce the amount of sludge generated by the use of chemicals.
  • the wastewater tank treatment step is a step of receiving the wastewater passing through the secondary electrolysis device 3b in the drain tank 1b and discharging the supernatant water.
  • the sludge treatment step is performed by using the sludge treatment unit 9 for the sludge generated from the contact aeration tank 7, and consists of a thickener process, a sludge reduction process, and a dehydrator process to concentrate, reduce and remove the sludge.
  • the thickening tank process when the sludge generated by the contact aeration tank treatment step flows into the thickening tank 9a, it is concentrated through a sedimentation process, and the settled sludge is transferred to the sludge reduction device 9b, and the supernatant is transferred to the flow rate control tank 2 It is the process of returning and reprocessing.
  • the sludge reduction process is a process of reducing sludge by the action of the sludge reduction device 9b described above, and the dehydrator process is a dehydration process performed by the dehydrator 9c.
  • the sludge cake finally discharged is taken out and buried, It undergoes post-processing such as incineration.
  • the conciseness, simplification and facility investment cost of the treatment system are reduced by applying the primary electrolysis step and the secondary electrolysis step instead of the pretreatment process. It was confirmed experimentally that the amount of chemicals such as neutralizers and coagulants can be reduced to about 50%, and this has the advantage of reducing the amount of sludge generated.
  • the system and method for treating dyeing wastewater and high-concentration wastewater according to the present invention is a technology that can simplify and simplify wastewater facilities and effectively treat wastewater while minimizing the use of chemicals, such as dyeing wastewater, sewage, high-concentration wastewater, etc. It can be used for various wastewater treatment such as

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Abstract

A system for treating dye wastewater and high-concentration wastewater, according to the present invention, can effectively treat wastewater while minimizing the use of chemicals, and includes a settling/screening tank (1a), a flowrate control tank (2), a primary electrolysis device (3a), a pressurization and flotation tank (4), an anoxic tank (5), an anaerobic tank (6), a contact aeration tank (7), a membrane separation tank (8), a secondary electrolysis device (3b), a drain tank (1b) and a sludge treatment part (9). The method for treating dye wastewater and high-concentration wastewater, according to the present invention, sequentially performs a screening tank treatment step, a flowrate control tank treatment step, a primary electrolysis step, a pressurization and flotation tank treatment step, an anoxic tank treatment step, an anaerobic tank treatment step, a contact aeration tank treatment step, a membrane separation tank treatment step, a secondary electrolysis step, a drain tank treatment step, and a sludge treatment step.

Description

염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법System and method for treatment of dyeing wastewater and high-concentration wastewater
본 발명은 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법에 관한 것으로서, 더욱 상세하게는, 폐수 처리시설을 간결, 단순화할 수 있고 화학 약품의 사용을 최소화하면서도 폐수를 효과적으로 처리할 수 있는 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법에 관한 것이다.The present invention relates to a system and method for treating dyeing wastewater and high concentration wastewater, and more particularly, to a dyeing wastewater that can simplify and simplify wastewater treatment facilities and effectively treat wastewater while minimizing the use of chemicals and to a system and method for treating high concentration wastewater.
일반적으로, 폐수에 포함된 오염물질 및 미생물을 제거하는 방법은 생물학적 방법과 화학적 방법을 독립적으로 시행하거나 혼합하여 시행하고, 처리되지 않은 잔류물질을 분리하는 과정을 거친다.In general, a method of removing contaminants and microorganisms contained in wastewater is carried out independently or mixed with a biological method and a chemical method, and goes through a process of separating untreated residues.
생물학적 방법은 오폐수를 미생물을 이용하여 분해, 제거하는 방법으로 침전지에서의 고액 분리효율에 따라 처리수질이 크게 영향을 받지만 전통적인 하수처리의 경우 호기성 생물반응조 내에서 오/폐수 중의 유기물과 영양 염류를 섭취해서 성장한 미생물이 침전조에서 슬러지 형태로 침전되어 물과 분리 및 제거되는데, 처리공정의 운전상태에 따라 침전성이 떨어질 경우 유출수의 수질을 유지하기 어려운 문제점이 있다.The biological method is a method of decomposing and removing wastewater using microorganisms, and the quality of the treated water is greatly affected by the solid-liquid separation efficiency in the sedimentation tank. As a result, the grown microorganisms are precipitated in the form of sludge in the sedimentation tank, separated and removed from water.
화학적 방법에서는 스크린 장치 등을 통해 오폐수에서 큰 입자의 오니가 분리되며, 오니가 분리된 오폐수가 반응조, 중화조, 응집조를 거치는 전처리 공정중에 다양한 화학성분을 통해 화학처리되어 PH조정이 이루어지며, 색소, 현탁물질, 난분해성 COD물질을 효과적으로 제거하나 다량의 화학성분으로 인한 2차오염과 약품으로 인한 슬러지 발생량이 증가되는 문제가 발생될 우려가 있다.In the chemical method, large particles of sludge are separated from the wastewater through a screen device, etc., and the wastewater from which the sludge is separated is chemically treated through various chemical components during the pretreatment process that goes through the reaction tank, neutralization tank, and coagulation tank to adjust the pH. Although it effectively removes pigments, suspended substances, and difficult-to-decompose COD substances, there is a concern that secondary pollution due to a large amount of chemical components and an increase in the amount of sludge generated by chemicals may occur.
한편, 염색 폐수나 고농도 폐수는 통상 전술한 생물학적 방법과 화학적 방법을 병행함으로써 처리 효율을 향상시키고자 하는 다양한 연구가 이루어지고 있다.On the other hand, various studies have been made to improve the treatment efficiency of dyeing wastewater or high-concentration wastewater by using the above-described biological and chemical methods in parallel.
예컨대, 대한민국 공개특허 공개번호 제10-2017-0101162호에는 고농도 유지 폐수 처리 방법이 개시되어 있다.For example, Korean Patent Laid-Open Publication No. 10-2017-0101162 discloses a method for treating high concentration maintenance wastewater.
이러한 고농도 유지 폐수 처리 방법은 폐수 전처리 단계, 상기 폐수 전처리에 의해 가압부상조를 통과한 동물성 유지를 회분식 저류조로 이동시키는 단계, 상기 회분식 저류조에서 이송된 동물성 유지의 pH가 중성이 되도록 4 ~ 8일 동안 처리하는 단계 및 상기 처리한 동물성 유지를 접촉폭기조에 혼화시켜 수처리하는 단계를 포함한다.This high-concentration maintenance wastewater treatment method includes a wastewater pretreatment step, moving animal fats and oils that have passed through a pressurized flotation tank by the wastewater pretreatment to a batch storage tank, and 4 to 8 days so that the pH of the animal fats and oils transferred from the batch storage tank becomes neutral. It includes the step of treating during the water treatment and mixing the treated animal fats and oils in a contact aeration tank.
전술한 고농도 유지 폐수 처리 방법은 고농도 유지 폐수를 안정적으로 정화할 수 있지만 폐수가 스크린를 통과하여 집수조로 유입되고 반응조, 중화조 및 응집조에서 전처리된 후 가압부상조로 이동된다. 가압부상조에서 처리된 상등수는 유량조정조, 접촉폭기조, 침전조 등을 경유한 후 방류하게 된다.Although the above-described high-concentration maintenance wastewater treatment method can stably purify high-concentration maintenance wastewater, the wastewater passes through a screen and flows into a water collecting tank, is pretreated in a reaction tank, a neutralization tank, and a coagulation tank, and then moves to a pressurized flotation tank. The supernatant water treated in the pressurized flotation tank is discharged after passing through the flow control tank, the contact aeration tank, and the settling tank.
전술한 공개특허 제10-2017-0101162호와 같은 종래 폐수 처리 방법은 비교적 많은 토지 점유면적이 필요하고 시설투자비가 요구되는 반응조, 중화조 및 응집조와 같은 시설이 필요하는 단점이 있다.Conventional wastewater treatment methods such as the aforementioned Patent Publication No. 10-2017-0101162 have disadvantages in that a relatively large land area is required and facilities such as a reaction tank, a neutralization tank, and a coagulation tank are required, which require facility investment costs.
그리고, 공개특허 제10-2017-0101162호와 같은 종래 폐수 처리 방법은 전처리 시에 응집제, 중화제 등의 화학약품이 다량 소요되므로 화학성분으로 인한 2차오염과 약품으로 인한 슬러지 발생량이 증가되는 문제점이 있다.In addition, conventional wastewater treatment methods such as Patent Publication No. 10-2017-0101162 require a large amount of chemicals such as coagulants and neutralizers during pretreatment, so there is a problem in that secondary pollution due to chemical components and the amount of sludge generated by chemicals increase. have.
아울러, 공개특허 제10-2017-0101162호와 같은 종래 폐수 처리 방법은 염색 폐수에 포함된 난분해성 물질이나 색도의 제거 효율이 낮은 단점이 있다.In addition, the conventional wastewater treatment method such as Patent Publication No. 10-2017-0101162 has a disadvantage in that the removal efficiency of the difficult-to-decomposable substances or chromaticity contained in the dyeing wastewater is low.
또한, 종래 폐수 처리 방법은 발생하는 슬러지의 양이 지나치게 많아서 슬러지의 소각에 따른 대기오염이 발생되고 있고, 매립량 증가에 따른 매립 토지면적 증가 및 침출수에 따른 2차적인 환경오염이 유발되는 단점이 있다.In addition, the conventional wastewater treatment method has an excessive amount of generated sludge, which causes air pollution due to incineration of the sludge, increases the land area of landfill due to the increase in the amount of landfill, and causes secondary environmental pollution due to leachate. have.
또한, 슬러지를 매립방법, 소각방법, 해양투기방법 등의 방식으로 후처리 하게 될 경우 처리비용이 상승되고, 해양 투기는 해양 오염을 유발할 뿐만 아니라 런던협약 등 국제 규약으로 금지하고 있으므로 슬러지를 감량하는 기술이 절실히 요구되고 있는 실정에 있다.In addition, if the sludge is post-processed by methods such as landfill method, incineration method, and marine dumping method, the treatment cost increases. There is an urgent need for technology.
본 발명은 상기 내용에 착안하여 제안된 것으로, 폐수 처리시설을 간결, 단순화할 수 있고 화학 약품의 사용을 최소화하면서도 폐수를 효과적으로 처리할 수 있도록 한 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법을 제공하는데 그 목적이 있다.The present invention has been proposed in view of the above, and a system and method for treating dyed wastewater and high-concentration wastewater that can simplify and simplify wastewater treatment facilities and effectively treat wastewater while minimizing the use of chemicals Its purpose is to provide
본 발명의 다른 목적은, 염색 폐수나 고농도 폐수에 포함된 난분해성 물질이나 색도를 용이하게 제거할 수 있도록 한 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법을 제공하는 것이다.Another object of the present invention is to provide a system and method for treating dyeing wastewater and high-concentration wastewater, which can easily remove difficult-to-decompose substances or chromaticity contained in dyeing wastewater or high-concentration wastewater.
본 발명의 다른 목적은, 슬러지의 양을 효과적으로 감량함으로써 환경오염을 최소화할 수 있고 오폐수처리비용을 절감할 수 있도록 한 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법을 제공하는 것이다.Another object of the present invention is to provide a system and method for treating dyed wastewater and high-concentration wastewater, which can minimize environmental pollution and reduce wastewater treatment costs by effectively reducing the amount of sludge.
상기 목적을 달성하기 위해, 본 발명에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템은 염색 폐수 및 고농도 폐수 처리를 위한 시스템에 있어서 유입되는 폐수 중에 포함된 고형물을 제거하는 침사/스크린조; 상기 침사/스크린조를 경유한 폐수의 유량을 조정하는 유량조정조; 상기 유량조정조를 경유한 폐수의 전기 화학적 처리 과정을 1차로 수행하는 1차 전기분해장치; 버블발생장치로부터 생성된 버블을 상기 1차 전기분해장치를 경유한 폐수와 접촉시켜 플록이 응집, 부상되도록 하는 가압부상조; 상기 1차 전기분해장치를 경유한 폐수 중에 포함된 유기물을 이용하여 질산성질소를 탈질산화하여 질소와 유기물을 제거하는 무산소조; 상기 무산소조를 경유한 폐수에 잔류하는 유기물을 이용하여 잔여 탈질과 인 방출이 이루어지도록 하는 혐기조; 상기 혐기조를 경유한 폐수에 잔류하는 유기물에 미생물을 접촉, 성장시켜 미생물 플록을 형성하고 슬러지 일부를 상기 유량조정조로 반송시키도록 구성된 접촉폭기조; 상기 접촉폭기조를 경유한 폐수를 막분리에 의하여 질산화 및 미생물 분리가 일어나도록 하는 막분리조; 상기 막분리조를 경유한 폐수의 전기 화학적 처리 과정을 2차로 수행하는 2차 전기분해장치; 상기 2차 전기분해장치를 경유한 폐수가 유입되고 상등수가 방류되는 배수조; 및 상기 접촉폭기조의 슬러지가 유입되어 농축, 제거되는 슬러지처리부;를 포함하는 것을 특징으로 한다.In order to achieve the above object, a system for treating dyeing wastewater and high-concentration wastewater according to the present invention includes: a sedimentation/screen tank for removing solids contained in the wastewater introduced in the system for treating dyeing wastewater and high-concentration wastewater; a flow rate adjustment tank for adjusting the flow rate of wastewater passing through the sediment/screen tank; a primary electrolysis device that primarily performs an electrochemical treatment process of wastewater passing through the flow control tank; a pressurized flotation tank for coagulating and floating the flocs by bringing the bubbles generated from the bubble generator into contact with the wastewater that has passed through the primary electrolysis device; an anoxic tank for removing nitrogen and organic matter by denitrifying nitrate nitrogen using organic matter contained in the wastewater passed through the primary electrolysis device; an anaerobic tank to allow residual denitrification and phosphorus release by using the organic matter remaining in the wastewater passing through the anaerobic tank; a contact aeration tank configured to contact and grow microorganisms with organic matter remaining in the wastewater passing through the anaerobic tank to form microbial flocs and return a portion of the sludge to the flow rate control tank; a membrane separation tank for nitrification and microbial separation by membrane separation of the wastewater passing through the contact aeration tank; a secondary electrolysis device for performing an electrochemical treatment process of wastewater passing through the membrane separation tank; a drainage tank in which wastewater passing through the secondary electrolysis device is introduced and supernatant water is discharged; and a sludge treatment unit in which the sludge of the contact aeration tank is introduced and concentrated and removed.
상기 슬러지처리부는, 상기 접촉폭기조로부터 유입되는 슬러지를 농축하고 상등수를 상기 유량조정조로 반송시키도록 구성된 농축조; 상기 농축조로부터 배출되는 슬러지를 고속 회전시켜 감량하는 슬러지 감량장치; 및 상기 슬러지 감량장치로부터 배출되는 슬러지의 수분을 탈수하여 고액 분리하는 탈수기;를 포함할 수 있다.The sludge treatment unit may include: a thickening tank configured to concentrate the sludge flowing in from the contact aeration tank and return supernatant water to the flow rate control tank; a sludge reduction device for reducing the weight by rotating the sludge discharged from the thickener at high speed; and a dehydrator for dewatering the moisture in the sludge discharged from the sludge reduction device to separate solid and liquid.
상기 접촉폭기조는 생성된 슬러지 일부를 상기 유량조정조 또는 상기 무산소조에 선택적으로 반송시키도록 제1 반송라인 및 제2 반송라인이 구성되고, 상기 막분리조는 생성된 슬러지를 상기 1차 전기분해장치 또는 상기 무산소조에 선택적으로 반송시키도록 제3 반송라인 및 제4 반송라인이 구성되고, 상기 농축조는 생성된 상등수를 상기 상기 유량조정조로 반송시키도록 제5 반송라인이 구성될 수 있다.The contact aeration tank is configured with a first return line and a second return line to selectively return a portion of the generated sludge to the flow rate control tank or the anaerobic tank, and the membrane separation tank transfers the generated sludge to the primary electrolysis device or the A third return line and a fourth return line are configured to selectively return to the anoxic tank, and the concentration tank may include a fifth return line configured to return the generated supernatant to the flow rate control tank.
상기 1차 전기분해장치 및 상기 2차 전기분해장치는, 폐수가 유입되어 수용되는 전기분해실이 마련된 전기분해본체; 상기 전기분해본체에 설치되는 교반기; 상기 전기분해실에 설치되고 다수의 양극판 및 음극판과 상기 양극판 및 음극판이 설치되는 극판설치대, 상기 음극판 및 양극판에 전기분해용 전원을 공급하는 전원부를 구비한 전기분해부; 상기 전기분해본체에 접속되는 유입라인; 상기 전기분해본체에 접속되고 배출제어밸브가 설치된 배출라인; 상기 전기분해실에 유입되는 폐수의 수위를 감지하도록 설치되는 수위감지부; 상기 유입라인을 통해 폐수를 상기 전기분해실로 압송하는 압송펌프; 및 상기 수위감지부의 감지신호를 기초로 상기 압송펌프의 구동을 제어하는 전기분해장치제어부;를 포함할 수 있다.The primary electrolysis device and the secondary electrolysis device may include: an electrolysis body provided with an electrolysis chamber in which wastewater is introduced and accommodated; a stirrer installed in the electrolysis body; an electrolysis unit installed in the electrolysis chamber and having a plurality of positive and negative electrode plates and a pole plate mounting table on which the positive and negative plates are installed, and a power supply unit for supplying power for electrolysis to the negative electrode and positive plate; an inlet line connected to the electrolysis body; a discharge line connected to the electrolysis body and provided with a discharge control valve; a water level sensing unit installed to detect the level of wastewater flowing into the electrolysis chamber; a pressure pump for pumping wastewater to the electrolysis chamber through the inlet line; and an electrolysis device control unit for controlling the driving of the pressure-feeding pump based on the detection signal of the water level sensing unit.
한편, 상기 슬러지 감량장치는, 베이스프레임에 회전 가능하게 설치되는 구동축; 상기 구동축에 회전 가능하게 접속되고 다수의 타공이 형성된 드럼; 상기 드럼을 회전시키는 회전력을 생성, 인가하도록 접속되는 드럼구동수단; 상기 드럼의 외부를 둘러싸도록 배치되고 배출구가 형성된 처리챔버; 및 상기 처리챔버에 설치되는 복수의 프라즈마방사전극, 상기 프라즈마방사전극을 고전압을 인가하는 프라즈마발생부를 구비한 프라즈마발생장치;를 포함하여 구성될 수 있다.On the other hand, the sludge reduction device, a drive shaft rotatably installed on the base frame; a drum rotatably connected to the drive shaft and having a plurality of perforations; a drum driving means connected to generate and apply a rotational force for rotating the drum; a processing chamber disposed to surround the outside of the drum and formed with an outlet; and a plurality of plasma radiation electrodes installed in the processing chamber, and a plasma generator having a plasma generator for applying a high voltage to the plasma radiation electrodes.
상기 드럼은 상기 구동축에 설치되어 회전되고 다수의 타공이 형성된 내부드럼과, 상기 내부드럼의 외부를 둘러싸도록 배치되고 다수의 타공이 형성된 외부드럼을 포함할 수 있다.The drum may include an inner drum which is installed on the drive shaft, rotates and has a plurality of perforations, and an outer drum which is disposed to surround the outside of the inner drum and has a plurality of perforations.
상기 드럼구동수단은 상기 구동축에 회전력을 생성, 인가하도록 접속되는 내부드럼구동수단과, 상기 외부드럼을 회전시키도록 접속되는 외부드럼구동수단을 포함할 수 있다.The drum driving means may include an internal drum driving means connected to generate and apply a rotational force to the drive shaft, and an external drum driving means connected to rotate the external drum.
상기 구동축은 상기 내부드럼의 일측 및 타측에 접속되는 제1 구동축과 제2 구동축으로 구성되되, 상기 제1 구동축 및 상기 제2 구동축 중에서 하나 이상은 내부에 슬러지이동로가 형성되어 상기 내부드럼의 내부로 슬러지를 공급하도록 중공파이프로 구성될 수 있다.The drive shaft includes a first drive shaft and a second drive shaft connected to one side and the other side of the inner drum, and at least one of the first drive shaft and the second drive shaft has a sludge movement path formed therein, so that the inner drum It may consist of a hollow pipe to feed the sludge into the furnace.
상기 슬러지 감량장치는, 상기 중공파이프의 외부에 이동되는 슬러지에 자기력을 인가하도록 설치되는 자장발생부를 포함하여 구성될 수 있다.The sludge reduction device may include a magnetic field generator installed to apply a magnetic force to the sludge moving outside the hollow pipe.
상기 목적을 달성하기 위해, 본 발명에 따른 염색 폐수 및 고농도 폐수 처리를 위한 방법은 침사/스크린조에 의해 유입되는 폐수 중에 포함된 고형물을 제거하는 스크린조 처리단계; 상기 침사/스크린조를 경유한 폐수의 유량을 상기 유량조정조에서 조정하는 유량조정조 처리단계; 상기 유량조정조를 경유한 폐수를 상기 1차 전기분해장치에 의한 전기 화학적 처리 과정을 통해 OH라디컬의 산화력을 이용하여 오염물질 및 색도를 1차로 제거하는 1차전기분해단계; 상기 1차 전기분해장치를 경유하여 상기 가압부상조로 유입된 폐수를 상기 버블발생장치에 의해 생성된 버블과 접촉시켜 플록이 응집, 부상되도록 하는 가압부상조 처리단계;를 구비한다.In order to achieve the above object, a method for treating dyeing wastewater and high-concentration wastewater according to the present invention includes a screen bath treatment step of removing solids contained in the wastewater introduced by the sedimentation/screen bath; a flow rate adjustment tank processing step of adjusting the flow rate of wastewater passing through the sediment/screen tank in the flow rate adjustment tank; a primary electrolysis step of primarily removing contaminants and chromaticity by using the oxidizing power of OH radicals through the electrochemical treatment process of the wastewater passing through the flow control tank; and a pressurizing flotation tank treatment step of contacting the wastewater introduced into the pressurizing flotation tank via the primary electrolysis device with the bubbles generated by the bubble generating device so that the flocs are agglomerated and floated.
그리고, 본 발명에 따른 염색 폐수 및 고농도 폐수 처리를 위한 방법은 상기 1차 전기분해장치를 경유한 폐수를 상기 무산소조에서 1 내지 9시간 동안 체류시키면서 폐수 중에 포함된 유기물을 이용하여 질산성질소를 탈질산화하여 질소와 유기물을 제거하는 무산소조 처리단계; 상기 무산소조를 경유한 폐수를 상기 혐기조에 4 내지 8시간 동안 체류시키면서 잔류하는 유기물을 이용하여 잔여 탈질과 인 방출이 이루어지도록 하는 혐기조 처리단계; 상기 혐기조를 경유한 폐수를 상기 접촉폭기조에서 폭기시키면서 잔류하는 유기물에 미생물을 접촉, 성장시켜 미생물 플록을 형성하는 접촉폭기조 처리단계; 상기 접촉폭기조를 경유한 폐수를 상기 막분리조에서 질산화 및 미생물 분리가 일어나도록 하는 막분리조 처리단계; 상기 막분리조를 경유한 폐수를 상기 2차 전기분해장치에 의한 전기 화학적 처리 과정을 통해 OH라디컬의 산화력을 이용하여 오염물질 및 색도를 2차로 제거하는 수행하는 2차전기분해단계; 상기 2차 전기분해장치를 경유한 폐수를 상기 배수조에 수용하고 상등수를 방류시키는 배수조 처리단계; 및 상기 접촉폭기조로부터 생성된 슬러지를 상기 슬러지처리부를 이용하여 농축, 감량 및 제거하는 슬러지 처리단계;를 포함한다.And, in the method for treating dyeing wastewater and high-concentration wastewater according to the present invention, nitrate nitrogen is denitrified using organic matter contained in wastewater while the wastewater passing through the primary electrolysis device is retained in the anaerobic tank for 1 to 9 hours. anoxic treatment step of oxidizing to remove nitrogen and organic matter; an anaerobic tank treatment step of maintaining the wastewater passing through the anaerobic tank in the anaerobic tank for 4 to 8 hours and using the remaining organic matter to perform residual denitrification and phosphorus release; a contact aeration tank treatment step of forming microbial flocs by contacting and growing microorganisms with organic matter remaining while aeration of wastewater passing through the anaerobic tank in the contact aeration tank; a membrane separation tank treatment step of nitrifying and separating microorganisms from the wastewater passing through the contact aeration tank in the membrane separation tank; A secondary electrolysis step of performing a secondary electrolysis step of removing contaminants and chromaticity by using the oxidizing power of OH radicals through the electrochemical treatment process by the secondary electrolysis device of the wastewater passing through the membrane separation tank; a sump treatment step of receiving the wastewater passing through the secondary electrolysis device in the sump and discharging the supernatant; and a sludge treatment step of concentrating, reducing, and removing the sludge generated from the contact aeration tank using the sludge treatment unit.
상기 접촉폭기조 처리단계는 상기 접촉폭기조에서 생성된 슬러지 일부를 상기 유량조정조 또는 상기 무산소조에 선택적으로 반송시키는 과정을 포함할 수 있다.The step of treating the contact aeration tank may include selectively returning a portion of the sludge generated in the contact aeration tank to the flow rate control tank or the anoxic tank.
상기 막분리조 처리단계는 상기 막분리조에서 생성된 슬러지 일부를 상기 1차 전기분해장치 또는 상기 무산소조에 선택적으로 반송시키는 과정을 포함할 수 있다.The membrane separation tank treatment step may include selectively returning a portion of the sludge generated in the membrane separation tank to the primary electrolysis device or the anoxic tank.
상기 슬러지 처리단계는 상기 접촉폭기조 처리단계에 의해 생성된 슬러지를 침전 과정을 통해 농축시키는 농축조 과정, 상기 농축 과정을 거친 슬러지를 물리적으로 감량하는 슬러지 감량과정, 및 상기 슬러지 감량과정을 거친 슬러지를 탈수하는 탈수과정을 포함할 수 있다.The sludge treatment step includes a thickening tank process for concentrating the sludge generated by the contact aeration tank treatment step through a settling process, a sludge reduction process for physically reducing the sludge that has undergone the concentration process, and dewatering the sludge that has undergone the sludge reduction process. It may include a dehydration process.
본 발명에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법에 의하면, 폐수의 처리시에 전기분해장치와 가압부상조를 연계 적용하고 다단의 슬러지 처리과정을 수행함으로써 많은 토지와 시설투자비가 요구되는 반응조, 중화조 및 응집조 등와 같은 시설이 불필요하여 폐수 처리시설을 간결, 단순화할 수 있고 화학 약품의 사용을 줄일 수 있으며 이를 통해 슬러지를 감량함으로써 환경오염을 최소화할 수 있고 오폐수처리비용을 절감할 수 있는 효과가 있다.According to the system and method for treating dyed wastewater and high-concentration wastewater according to the present invention, a large amount of land and facility investment cost is required by connecting an electrolysis device and a pressurized flotation tank and performing a multi-stage sludge treatment process during wastewater treatment As facilities such as a reactor, neutralization tank and coagulation tank are unnecessary, wastewater treatment facilities can be simplified and simplified, and the use of chemicals can be reduced. There is an effect that can be done.
본 발명에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법에 의하면, 전기분해 시 생성되는 OH라티칼에 의해 염색 폐수나 고농도 폐수에 포함된 난분해성 물질이나 색도를 용이하게 제거할 수 있는 효과가 있다.According to the system and method for treating dyeing wastewater and high-concentration wastewater according to the present invention, the effect that can easily remove difficult-to-decomposable substances or chromaticity contained in dyeing wastewater or high-concentration wastewater by OH radicals generated during electrolysis there is
도1은 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템을 설명하기 위한 개략적인 모식도,1 is a schematic schematic diagram for explaining a system for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention;
도2a 내지 도2c는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템에 적용되는 1차 및 2차전기분해장치를 설명하기 위한 도면으로서, 도2a는 정면도, 도2b는 전기분해본체의 내부 구조가 나타나도록 도시한 정단면도, 도2c는 평단면도이다.Figures 2a to 2c is a view for explaining the primary and secondary electrolysis apparatus applied to the system for the treatment of dyeing wastewater and high concentration wastewater according to an embodiment of the present invention, Figure 2a is a front view, Figure 2b is A front cross-sectional view showing the internal structure of the electrolysis body, FIG. 2C is a plan cross-sectional view.
도3a은 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 정면 구조를 나타낸 도면, Figure 3a is a view showing the front structure of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention;
도3b는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 평면 구조를 나타낸 도면,Figure 3b is a view showing the planar structure of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention;
도3c은 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 자장발생부를 설명하기 위한 개략적인 구성도,Figure 3c is a schematic configuration diagram for explaining the magnetic field generator of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention;
도3d는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 내부드럼를 설명하기 위한 개략적인 사시도, Figure 3d is a schematic perspective view for explaining the inner drum of the sludge reduction device of the system for the treatment of dyeing wastewater and high concentration wastewater according to an embodiment of the present invention;
도3e는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 외부드럼를 설명하기 위한 개략적인 사시도,Figure 3e is a schematic perspective view for explaining the external drum of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention;
도3f는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 처리챔버를 설명하기 위한 개략적인 사시도,3f is a schematic perspective view for explaining a treatment chamber of a sludge reduction device of a system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention;
도3g는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 작용을 설명하기 위한 도면,Figure 3g is a view for explaining the operation of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention;
도4는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 방법을 설명하기 위한 공정도이다.4 is a process diagram for explaining a method for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention.
이하, 본 발명의 바람직한 실시예를 첨부된 도면 도1 내지 도4에 의거하여 상세히 설명하되, 도1 내지 도4에 있어서 동일한 구성 요소에 대해서는 동일한 참조번호가 부여하여 설명하도록 한다.Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the accompanying drawings.
한편, 각각의 도면에서 일반적인 기술로부터 이 분야의 통상의 지식을 가진 자가 용이하게 알 수 있는 구성과 그에 대한 작용 및 효과에 대한 상세한 설명은 간략히 하거나 생략한다. 또한, 본 발명이 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법에 특징을 갖는 것이므로 이와 관련된 부분들을 중심으로 도시 및 설명하고 나머지 부분에 대한 설명은 간략화하거나 생략하도록 한다.On the other hand, in each drawing, a detailed description of a configuration that can be easily recognized by a person skilled in the art from the general technology, and an action and effect thereof will be simplified or omitted. In addition, since the present invention is characterized by a system and a method for treating dyed wastewater and high-concentration wastewater, the related parts will be mainly illustrated and described, and the description of the remaining parts will be simplified or omitted.
도1은 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템을 설명하기 위한 개략적인 모식도이다.1 is a schematic diagram for explaining a system for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention.
도1을 참조하면, 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템은 화학 약품의 사용을 최소화하면서도 폐수를 효과적으로 처리할 수 있도록 구성한 점에 특징이 있는 것으로서, 침사/스크린조(1a), 유량조정조(2), 1차 전기분해장치(3a), 가압부상조(4), 무산소조(5), 혐기조(6), 접촉폭기조(7), 막분리조(8), 2차 전기분해장치(3b), 배수조(1b), 및 슬러지처리부(9)가 주요 구성요소로 구비되어 있다. Referring to FIG. 1, the system for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention is characterized in that it is configured to effectively treat wastewater while minimizing the use of chemical agents. (1a), flow rate control tank (2), primary electrolysis device (3a), pressurized flotation tank (4), anoxic tank (5), anaerobic tank (6), contact aeration tank (7), membrane separation tank (8), 2 The primary electrolysis device 3b, the drainage tank 1b, and the sludge treatment unit 9 are provided as main components.
상기한 주요 구성요소들은 흐름 처리가 가능하도록 배치되는 것으로서 일부 구성요소를 제외하면 세부 구조나 형상은 오,폐수 처리시스템에서 많이 적용하고 있는 공지의 장치들이므로 세부 구조에 대한 구체적인 설명을 생략하고 차별점을 갖는 구성요소를 중심으로 이하 구체적으로 설명한다. The above-mentioned main components are arranged so that flow treatment is possible, and except for some components, the detailed structures and shapes are well-known devices that are widely applied in sewage and wastewater treatment systems. It will be described in detail below with a focus on the components having .
침사/스크린조(1a)는 유입되는 폐수 중에 포함된 고형물을 제거하는 구성요소로서, 모래, 고형물질 등 입자 크기가 큰 물질을 제거하는 스크린 등이 구비된 통상의 구조로 구성되어 있다.The sediment/screen tank 1a is a component that removes solids contained in the inflowing wastewater, and has a conventional structure including a screen for removing materials with large particle sizes, such as sand and solids.
유량조정조(2)는 침사/스크린조(1a)를 경유한 폐수의 유량을 조정하는 구성요소로서, 개방형 탱크 등으로 구성될 수도 있지만 본 실시예에서는 도2a에 도시된 바와 같이 제1 전기분해장치(3a)가 올려지는 밀폐형 탱크로 구성되어 있고, 무산소조(5)로 처리된 폐수를 유동시키도록 배관 등이 접속되어 있다.The flow rate adjustment tank 2 is a component that adjusts the flow rate of wastewater passing through the sedimentation/screen tank 1a, and may be composed of an open tank, etc., but in this embodiment, as shown in FIG. 2a, the first electrolysis device It consists of a sealed tank on which (3a) is mounted, and piping etc. are connected so that the wastewater treated by the anaerobic tank 5 may flow.
첨부도면, 도2a 내지 도2c는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템에 적용되는 1차 및 2차전기분해장치를 설명하기 위한 도면으로서, 도2a는 정면도, 도2b는 전기분해본체의 내부 구조가 나타나도록 도시한 정단면도, 도2c는 평단면도이다.2a to 2c are views for explaining the primary and secondary electrolysis devices applied to the system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention, FIG. 2a is a front view, Figure 2b is a front sectional view showing the internal structure of the electrolysis body, Figure 2c is a plan sectional view.
도2a 내지 도2c를 참조하면, 1차 전기분해장치(3a)는 유량조정조(2)를 경유한 폐수를 전기 화학적 처리 과정을 1차로 수행하는 구성요소로서, 폐수의 전기 화학적 반응에 따라 발생하는 OH라디컬의 산화력을 이용하여 오염물질, 난분해성물질, 색도 등을 제거할 수 있다. 이에 따라 종래 폐수 처리과정에서 플록을 형성하기 위해 갖추어야 했던 중화조, 반응조 및 응집조와 같은 시설이 불필요하고, 중화재, 응집제 등 화학약품을 대량 투입하여야 했던 종래 문제점을 해소할 수 있다.Referring to FIGS. 2A to 2C , the primary electrolysis device 3a is a component that primarily performs an electrochemical treatment process of wastewater passing through the flow rate adjustment tank 2, By using the oxidizing power of OH radicals, contaminants, difficult-to-decompose substances, and chromaticity can be removed. Accordingly, facilities such as a neutralization tank, a reaction tank, and a coagulation tank, which were required to form flocs in the conventional wastewater treatment process, are unnecessary, and the conventional problems in which a large amount of chemicals such as a neutralizing agent and a coagulant must be input can be solved.
이러한, 1차 전기분해장치(3a)는 전기분해장치프레임(31), 전기분해본체(32), 교반기(33), 전기분해부(34), 유입라인(35), 및 배출라인(36)이 구비되어 있다.This, the primary electrolysis device (3a) is the electrolysis device frame 31, the electrolysis body 32, the stirrer 33, the electrolysis unit 34, the inlet line 35, and the discharge line (36) This is provided.
전기분해장치프레임(31)은 전기분해본체(32)를 지지하기 위해 횡부재와 종부재에 의해 형성되는 것으로, 횡부재 및 종부재는 사각봉 등의 형강재로 형성된다. The electrolysis device frame 31 is formed by a transverse member and a vertical member to support the electrolysis body 32, and the transverse member and the vertical member are formed of a section steel material such as a square bar.
전기분해본체(32)는 내부에 폐수가 수용되는 전기분해실(32a)이 마련되도록 판재에 의해 육면체 형상으로 형성된 것으로서, 도2a에 도시된 바와 같이 외부에서 전기분해본체(32)의 내부에 수용되는 전기분해부(34) 및 교반기(33) 작동상태 등을 확인할 수 있도록 감시용 투시창(32b)이 설치되어 있다. The electrolysis body 32 is formed in a hexahedral shape by a plate material so that an electrolysis chamber 32a in which wastewater is accommodated is provided, and is accommodated in the electrolysis body 32 from the outside as shown in FIG. 2a. A see-through window (32b) for monitoring is installed so that the electrolysis unit (34) and the stirrer (33) operating state can be checked.
교반기(33)는 전기분해본체(32)에 설치되어 전기분해실(32a)의 바닥에 침전되는 슬러지를 교반하여 부상 및 혼합함으로써 전기분해부(34)에 의한 오염물질, 난분해성물질, 색도의 제거효율 증진작용이 발휘되도록 구성한 것이다. 교반기(33)는 외부로 노출되는 교반모터(33a)와, 이 교반모터에 의해 회전되는 교반축(33b) 및 교반축에 설치되는 블레이드(33c)로 구성되어 있다.The stirrer 33 is installed in the electrolysis body 32 and stirs the sludge that is deposited on the bottom of the electrolysis chamber 32a, floats and mixes the contaminants, difficult-to-decompose substances, and chromaticity by the electrolysis unit 34 by stirring. It is designed to enhance the removal efficiency. The agitator 33 is composed of a stirring motor 33a exposed to the outside, a stirring shaft 33b rotated by the stirring motor, and a blade 33c installed on the stirring shaft.
전기분해부(34)는 전기분해실(32a)에 설치되고 다수의 양극판(34a) 및 음극판(34b)과, 양극판(34a) 및 음극판(34b)이 설치되는 극판설치대(34c), 음극판 및 양극판에 전기분해용 전원을 공급하는 전원부(미도시)를 구비한다. 여기서, 양극판(34a) 및 음극판(34b)은 전기전도도가 서로 다른 이리듐판 및 알루미늄판으로 구성할 수 있지만 이에 제한되는 것은 아니다.The electrolysis unit 34 is installed in the electrolysis chamber 32a and includes a plurality of positive electrode plates 34a and negative electrode plates 34b, and a positive electrode plate 34a and negative electrode plate 34b installed on the electrode plate mounting table 34c, negative electrode plate and positive electrode plate. A power supply unit (not shown) for supplying power for electrolysis is provided. Here, the positive electrode plate 34a and the negative electrode plate 34b may be formed of an iridium plate and an aluminum plate having different electrical conductivity, but is not limited thereto.
유입라인(35)은 폐수를 전기분해실(32a) 내부로 유입시키기 위한 구성으로 전기분해본체의 상측 부위에 접속되는 배관이나 호스 등으로 구성된다.The inflow line 35 is configured to introduce wastewater into the electrolysis chamber 32a, and is composed of a pipe or a hose connected to the upper portion of the electrolysis body.
배출라인(36)은 전기분해실(32a) 내부의 폐수를 외부로 배출하기 위한 구성으로 전기분해본체(32) 하측 부위에 접속되어 처리과정을 거친 폐수를 가압부상조(2, 제2 전기분해장치의 경우는 배수조)로 공급하는 배관이나 호스 등으로 구성된다.The discharge line 36 is configured for discharging the wastewater inside the electrolysis chamber 32a to the outside, and is connected to the lower portion of the electrolysis body 32 and converts the treated wastewater into the pressurized flotation tank 2, the second electrolysis In the case of the device, it is composed of pipes or hoses that supply to the drain tank).
그리고 배출라인(36)에는 폐수의 배출을 제어하도록 개폐되는 배출제어밸브(37)가 설치되어 있고, 전기분해실(32a)에서 오버플로우(over flow) 되는 폐수를 배출되는 오버플로우라인(38)이 설치되어 있다. 오버플로우라인(38)은 일단이 전기분해본체(32)의 상측 부위에 접속되고 타단이 배출라인(36)에 접속되어 있다.And a discharge control valve 37 that opens and closes to control the discharge of wastewater is installed in the discharge line 36, and an overflow line 38 through which wastewater overflows from the electrolysis chamber 32a is discharged. this is installed The overflow line 38 has one end connected to the upper portion of the electrolysis body 32 and the other end connected to the discharge line 36 .
그리고, 1차 전기분해장치(32a)는 전기분해실(32a)에 유입되는 폐수의 수위를 감지하도록 설치되는 수위센서와 같은 수위감지부(39), 유입라인(35)을 통해 폐수를 전기분해실(32a)로 압송하는 압송펌프(35a), 및 수위감지부(39)의 감지신호를 기초로 압송펌프의 구동을 제어하고 배출제어밸브(37)의 개폐를 제어하는 전기분해장치제어부(미도시)가 구성되어 있다.In addition, the primary electrolysis device 32a electrolyzes wastewater through a water level detection unit 39 such as a water level sensor installed to detect the level of wastewater flowing into the electrolysis chamber 32a, and an inlet line 35 . An electrolysis device control unit (not shown) that controls the driving of the pressure feeding pump based on the detection signal of the pressure feeding pump 35a and the water level detecting unit 39 and controlling the opening and closing of the discharge control valve 37 to the chamber 32a. city) is composed.
또한, 1차 전기분해장치(32a)는 폐수의 처리과정에서 처리품질을 측정하여 적정한 수준에 도달하지 않을 경우 가성소다, 소석회 등과 같은 중화제나 응집제를 투입할 수 있다. 이를 위해 전기분해본체(32)는 상부에 중화제나 응집제를 투입할 수 있도록 투입구(미도시)가 마련되어 있다.In addition, the primary electrolysis device 32a may inject a neutralizing agent or a coagulant such as caustic soda, slaked lime, etc. when it does not reach an appropriate level by measuring the treatment quality during the treatment of wastewater. To this end, the electrolysis body 32 is provided with an inlet (not shown) so that a neutralizing agent or a coagulant can be put in the upper part.
이와 같이 1차 전기분해장치(32a)에 중화제나 응집제를 투입하는 이유는 내부에 교반기(33)가 구비되어 화학약품의 용해과정을 신속하게 수행할 수 있는 장점이 있고, 가압부상조(4)의 앞단에서 폐수의 전처리를 수행할 수 있어서 가압부상조 처리단계의 효율을 향상시키도록 하기 위함이다.The reason for injecting the neutralizing agent or coagulant into the primary electrolysis device 32a as described above is that the stirrer 33 is provided therein, which has the advantage of rapidly performing the dissolution process of the chemical, and the pressurized flotation tank (4) This is to improve the efficiency of the pressurized flotation tank treatment step by being able to perform pretreatment of wastewater at the front end of the.
한편, 가압부상조(4)는 마이크로 버블을 이용하여 폐수를 처리하는 처리조로서 버블발생장치(미도시)가 구비되어 있다. 버블발생장치는 마이크로 버블을 생성할 수 있는 장치라면 특별한 제한이 없이 구성할 수 있다. 예컨대 버블발생장치는 공기와 물을 가압 저장하는 가압탱크와 이 가압탱크의 공기와 물을 가압부상조(4) 내부로 분출되는 버블노즐(미도시)로 구성될 수 있다.On the other hand, the pressure flotation tank 4 is a treatment tank for treating wastewater using microbubbles, and is provided with a bubble generator (not shown). The bubble generator may be configured without any particular limitation as long as it is a device capable of generating microbubbles. For example, the bubble generator may be composed of a pressurized tank for pressurizing air and water and a bubble nozzle (not shown) for ejecting the air and water from the pressurized tank into the pressurized flotation tank 4 .
상기한 가압부상조(4)는 버블발생장치로부터 생성된 버블을 폐수와 접촉하도록 하고 빠져 나오는 공기 방울에 응집된 플록이 부착되어 떠오르게 함으로써 후처리 과정을 거쳐 제거되도록 하고, 상등수는 무산소조(5)로 이송시키는 과정을 거치게 된다.The above-mentioned pressurized flotation tank (4) brings the bubbles generated from the bubble generator into contact with wastewater, and the agglomerated flocs attach to and float on the exiting air bubbles so that they are removed through a post-treatment process, and the supernatant is an anaerobic tank (5) will be transferred to
무산소조(5)는 1차 가압부상조(4)를 경유한 폐수 중에 포함된 유기물을 이용하여 질산성질소를 탈질산화하여 질소와 유기물을 제거하는 구성요소로서, 이러한 무산소조는 특고압양자장 방출회로에 가변파형의 고주파를 매칭하여 투사양자량 및 파형을 조절하여 오염물질을 처리하는 장치를 부가하여 오염물질의 제거 효율을 높이는 것이 바람직하다. The anoxic tank 5 is a component that removes nitrogen and organic matter by denitrifying and oxidizing nitrate nitrogen using organic matter contained in the wastewater that has passed through the primary pressurized flotation tank 4, and this anoxic tank is a special high-pressure quantum field emission circuit. It is desirable to increase the removal efficiency of pollutants by adding a device for processing pollutants by adjusting the projected dose and waveform by matching the high frequency of the variable waveform.
접촉폭기조(7)는 혐기조(6)를 경유한 폐수에 잔류하는 유기물에 미생물을 접촉, 성장시켜 미생물 플록을 형성하고 슬러지 일부를 유량조정조(2)로 반송시키는 구성요소로서, 탱크 형태로 형성되되, 막분리조(8)로 향하는 배관이 접속되는 노즐(미도시)과, 후술되는 제1 반송라인(72) 및 제2 반송라인(73)이 접속되는 노즐(미도시)이 구비되어 있다. The contact aeration tank 7 is a component that contacts and grows microorganisms with the organic matter remaining in the wastewater passing through the anaerobic tank 6 to form a microbial floe and returns a part of the sludge to the flow rate control tank 2, and is formed in the form of a tank. , a nozzle (not shown) to which a pipe directed to the membrane separation tank 8 is connected, and a nozzle (not shown) to which a first transport line 72 and a second transport line 73, which will be described later, are connected.
그리고, 접촉폭기조(7)는 생성된 슬러지를 유량조정조(2) 또는 무산소조(5)에 선택적으로 반송시키도록 제1 반송라인(72) 및 제2 반송라인(73)이 구성되어 있다.In addition, the contact aeration tank 7 is configured with a first return line 72 and a second return line 73 to selectively return the generated sludge to the flow rate adjustment tank 2 or the anoxic tank 5 .
막분리조(8)는 접촉폭기조(7)를 경유한 폐수를 막분리에 의하여 질산화 및 미생물 분리가 일어나도록 하는 구성요소로서, 오,폐수 처리시스템에 적용되는 공지의 막분리조와 유사하게 구성한다.The membrane separation tank 8 is a component that causes nitrification and microbial separation to occur by membrane separation of the wastewater passing through the contact aeration tank 7, and is configured similarly to a known membrane separation tank applied to a sewage and wastewater treatment system. .
그리고 막분리조(8)는 내부에서 생성된 슬러지를 1차 전기분해장치(3a) 또는 무산소조(5)에 선택적으로 반송시키도록 제3 반송라인(82) 및 제4 반송라인(83)이 구성되어 있다.In addition, the membrane separation tank 8 includes a third return line 82 and a fourth return line 83 to selectively return the sludge generated inside to the primary electrolysis device 3a or the anoxic tank 5 . has been
2차 전기분해장치(32)는 막분리조(8)를 경유한 폐수의 전기 화학적 처리 과정을 2차로 수행하는 구성요소로서, 전술한 1차 전기분해장치(3a)와 유사하게 전기분해장치프레임(31), 전기분해본체(32), 교반기(33), 전기분해부(34), 유입라인(35), 배출라인(36), 수위감지부(39), 압송펌프(35a), 전기분해장치제어부(미도시)가 구비되어 있다.The secondary electrolyzer 32 is a component that secondary performs the electrochemical treatment process of wastewater passing through the membrane separation tank 8, and similarly to the above-described primary electrolyzer 3a, the electrolysis device frame (31), the electrolysis body 32, the stirrer 33, the electrolysis unit 34, the inlet line 35, the discharge line 36, the water level detection unit 39, the pressure pump (35a), the electrolysis A device control unit (not shown) is provided.
배수조(1b)는 2차 전기분해장치(3b)를 경유한 폐수가 유입되고 상등수가 방류되는 구성요소로서, 오,폐수 처리시스템에 적용되는 공지의 배수조와 유사하게 구성한다.The drain tank 1b is a component through which wastewater flows through the secondary electrolysis device 3b and supernatant water is discharged, and is configured similarly to a known drain tank applied to a sewage and wastewater treatment system.
한편, 슬러지처리부(9)는 접촉폭기조(7)의 슬러지가 유입되어 농축, 제거되는 구성요소로서, 농축조(9a), 슬러지 감량장치(9b) 및 탈수기(9c)가 구비되어 있다.On the other hand, the sludge treatment unit 9 is a component through which the sludge of the contact aeration tank 7 is introduced, concentrated and removed, and is provided with a thickener 9a, a sludge reduction device 9b, and a dehydrator 9c.
농축조(9a)는 접촉폭기조(7)로부터 유입되는 슬러지를 농축하고 상등수를 유량조정조(2)로 반송시키도록 구성된 것으로서, 농축조(9a)에서 생성된 상등수를 유량조정조(2)로 반송시키도록 제5 반송라인(92)이 구성되어 있다.The thickening tank 9a is configured to concentrate the sludge flowing in from the contact aeration tank 7 and return the supernatant water to the flow rate adjustment tank 2, and to return the supernatant water generated in the thickening tank 9a to the flow rate adjustment tank 2 Five conveyance lines 92 are configured.
탈수기(9c)는 슬러지 감량장치(9b)로부터 배출되는 슬러지의 수분을 탈수하여 고액 분리하는 구성요소로서, 오,폐수 처리시스템에 슬러지를 탈수하기 위해 이용되는 공지의 탈수기를 용량에 맞게 선정하여 구성한다.The dehydrator 9c is a component that dehydrates the moisture of the sludge discharged from the sludge reduction device 9b and separates the solid-liquid, and a known dehydrator used for dewatering the sludge in the sewage and wastewater treatment system is selected according to the capacity. do.
한편, 전술한 제1 반송라인 내지 제5 반인라인(72,73,82,83,92)은 배관이나 호스로 구성되는 것으로서 유동을 제어하기 위한 개폐밸브(미도시), 압송을 펌프(미도시) 등이 설치될 수 있다.On the other hand, the above-described first conveying line to the fifth half-in line (72, 73, 82, 83, 92) is composed of a pipe or a hose, an on/off valve (not shown) for controlling the flow, and a pump for pressure feeding (not shown). ) can be installed.
첨부도면, 도3a은 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 정면 구조를 나타낸 도면, 도3b는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 평면 구조를 나타낸 도면으로서, 이해를 돕기 위해 주요 구성요소를 단순화하여 도시하였으며 일부 구성요소는 단면 형상을 간략하게 도시하였다.3A is a view showing the front structure of a sludge reduction device of a system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention, FIG. 3B is a dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention As a drawing showing the planar structure of the sludge reduction device of the system for treatment, the main components are simplified to help understanding, and some components are briefly illustrated in cross-sectional shape.
도3a 및 도3b를 참조하면, 슬러지 감량장치(9b)는 농축조(9a)로부터 배출되는 슬러지를 고속 회전시켜 감량하는 구성요소로서, 베이스프레임(91), 구동축(92), 드럼(93), 드럼구동수단(94), 처리챔버(95) 및 프라즈마발생장치(96)가 구비되어 있다.3A and 3B, the sludge reduction device 9b is a component that reduces the weight by rotating the sludge discharged from the thickening tank 9a at high speed, and includes a base frame 91, a drive shaft 92, a drum 93, A drum driving means (94), a processing chamber (95) and a plasma generating device (96) are provided.
베이스프레임(91)은 종방향으로 이격, 설치되는 복수의 종부재(911)와, 이 종부재(911)에 연결되는 복수의 횡부재(912)에 의해 대략 육면체 형상의 틀 구조로 구성되어 있다. 여기서, 종부재(911) 및 횡부재(912)는 판재 또는 사각봉 등과 같은 형강재로 구성된다. The base frame 91 is composed of a frame structure of a substantially hexahedral shape by a plurality of vertical members 911 spaced apart and installed in the longitudinal direction, and a plurality of transverse members 912 connected to the vertical members 911. . Here, the vertical member 911 and the transverse member 912 are made of a plate material or a section steel such as a square bar.
그리고, 베이스프레임(91)은 하부에 자유로운 이동을 위해 구름바퀴(913)가 설치되어 있고, 상부에 상판(미도시)이 설치될 수 있다.In addition, the base frame 91 has a rolling wheel 913 installed at the lower part for free movement, and an upper plate (not shown) may be installed on the upper part.
구동축(92)은 드럼(93)을 회전시키기 위해 베이스프레임(91)에 회전 가능하게 설치되는 구성요소로서, 후술되는 내부드럼(931)의 일측에 접속되는 제1 구동축(921), 내부드럼(931)의 타측에 접속되는 제2 구동축(922)으로 구성되어 있다.The drive shaft 92 is a component rotatably installed on the base frame 91 to rotate the drum 93, and a first drive shaft 921 connected to one side of the inner drum 931 to be described later, the inner drum ( It is comprised by the 2nd drive shaft 922 connected to the other side of 931.
제1 구동축(921)은 내부에 슬러지이동로가 형성되어 내부드럼(931)의 내부로 슬러지를 공급하도록 중공파이프로 구성되어 있고, 제2 구동축(922)은 막힘 구조의 환봉으로 구성되어 있다.The first drive shaft 921 is formed with a sludge flow path therein and is configured as a hollow pipe to supply sludge to the inside of the inner drum 931 , and the second drive shaft 922 is configured as a round bar having a clogged structure.
상기한 중공파이프는 파이프몸체의 내면에 나선상으로 요입되는 나선형이동홈(9212)이 요입된 특징이 있다. 이와 같이 제1 구동축(921)의 내부에 나선형이동홈(9212)이 형성되어 있게 되면 후술되는 압송펌프(미도시)에 의해 슬러지가 압송될 경우 선회하게 되고 내부드럼(931)으로 분출될 때에 소용돌이를 일으키면서 분사되므로 슬러지 플록(floc) 해체나 세포막 파괴 등의 작용이 효과적으로 수행된다.The hollow pipe is characterized in that the spiral moving groove 9212 is recessed into the inner surface of the pipe body in a spiral shape. When the spiral movement groove 9212 is formed inside the first drive shaft 921 as described above, when the sludge is pressurized by a pressure pump (not shown), which will be described later, it turns and swirls when ejected to the inner drum 931 . Since it is sprayed while generating
그리고, 구동축(92)은 전술한 구조 외에도 슬러지의 양이나 형태 등에 따라 제2 구동축(922)을 중공파이프로, 제1 구동축(921)을 환봉으로 구성하는 형태로 변경하거나 제1 및 제2 구동축 모두를 중공파이프로 구성하는 방식으로도 변경하여 구성할 수 있다.In addition to the above-described structure, the drive shaft 92 may be changed to a form in which the second drive shaft 922 is a hollow pipe and the first drive shaft 921 is a round bar according to the amount or shape of sludge, or the first and second drive shafts It can also be configured by changing the method of configuring all of them with a hollow pipe.
도3c은 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 자장발생부를 설명하기 위한 개략적인 구성도이다.Figure 3c is a schematic configuration diagram for explaining the magnetic field generator of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention.
도3a 및 도3c을 참조하면, 본 발명에 따른 슬러지 감량장치는 슬러지가 유입되는 부분인 제1 구동축(921)에 자장발생부(97)가 구성되어 있다.3A and 3C, in the sludge reduction device according to the present invention, the magnetic field generating unit 97 is configured on the first driving shaft 921, which is the part into which the sludge is introduced.
자장발생부(97)는 제1 구동축(921)의 슬러지이동로로 이동되는 슬러지에 자기력을 인가하도록 중공파이프의 외부에 설치되어 있다. 그리고 자장발생부(97)는 영구자석과 같은 마그네틱부재만을 설치하여 구성할 수도 있지만 본 실시예에서는 슬러지의 압송시에 제1 구동축(921)에 가해지는 진동 등의 물리적인 힘을 이용하여 전기에너지를 발전한 후 프라즈마발생부에 인가하여 사용할 수 있도록 기전력발생부로 구성한 점에 특징이 있다.The magnetic field generating unit 97 is installed outside the hollow pipe to apply a magnetic force to the sludge moved to the sludge movement path of the first drive shaft 921 . In addition, the magnetic field generating unit 97 may be configured by installing only a magnetic member such as a permanent magnet, but in this embodiment, electrical energy using a physical force such as vibration applied to the first drive shaft 921 when the sludge is pumped It is characterized in that it is composed of an electromotive force generating unit so that it can be used by applying it to the plasma generating unit after generating electricity.
이를 위해, 자장발생부(97)는 중공파이프(9제1 구동축)의 외면 둘레에 설치되는 복수의 마그네틱부재(971)와, 마그네틱부재(971)와 접하여 배치되는 유도코일을 포함하는 기전력발생부(972)로 구성되어 있다. 그리고, 기전력발생부(972)에는 발전된 전원을 프라즈마발생부(미도시)에 제공하기 위한 회로부가 구성될 수 있다. 여기서 회로부는 기전력발생부로부터 출력되는 발전전원을 정류하고 정해진 정격전원으로 변화하는 공지의 회로로 구성될 수 있다. To this end, the magnetic field generating unit 97 includes a plurality of magnetic members 971 installed around the outer surface of the hollow pipe (the ninth first driving shaft), and an induction coil disposed in contact with the magnetic member 971. An electromotive force generating unit including (972). And, the electromotive force generating unit 972 may be configured with a circuit unit for providing the generated power to the plasma generating unit (not shown). Here, the circuit unit may be composed of a known circuit that rectifies the generated power output from the electromotive force generating unit and changes to a predetermined rated power.
도3d는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 내부드럼를 설명하기 위한 개략적인 사시도이고, 도3e는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 외부드럼를 설명하기 위한 개략적인 사시도이다.Figure 3d is a schematic perspective view for explaining the inner drum of the sludge reduction device of the system for the treatment of dyeing wastewater and high concentration wastewater according to an embodiment of the present invention, Figure 3e is a dyeing wastewater and high concentration according to an embodiment of the present invention It is a schematic perspective view for explaining the external drum of the sludge reduction device of the system for wastewater treatment.
도3a 내지 도3e를 참조하면, 드럼(93)은 다수의 타공이 형성된 통체가 구동축(92)에 회전 가능하게 접속된 것으로서 고속 회전되면서 슬러지 플록(floc) 해체 및 세포막 파괴를 통해 세포내의 화학결합수, 모관결합수, 간극수 등을 제거하여 실질적인 슬러지 감량 작용을 수행한다. 3A to 3E, the drum 93 is a tubular body having a plurality of perforations, which is rotatably connected to the drive shaft 92 and rotates at a high speed while dismantling the sludge floc and destroying the cell membrane. Actual sludge reduction is performed by removing water, capillary-bonded water, and pore water.
그리고, 드럼(93)은 1개로도 구성할 수 있고 슬러지 감량 작용을 다단으로 수행하도록 3개 이상으로 구성할 수도 있지만 본 실시예에서는 2개의 드럼이 내통 및 외통 형태로 내외측에 차례로 배치되어 있다. And, the drum 93 can be configured as one or three or more to perform the sludge reduction action in multiple stages, but in this embodiment, two drums are sequentially arranged inside and outside in the form of an inner cylinder and an outer cylinder. .
보다 구체적으로 설명하면, 드럼(93)은 일측 및 타측에 제1 구동축(921) 및 제2 구동축(922)이 접속되어 회전되고 판재에 다수의 타공이 천공되어 형성된 내부드럼(931)과, 내부드럼(931) 외부를 둘러싸도록 배치되고 판재에 다수의 타공이 천공되어 형성된 외부드럼(932)으로 구성되어 있다.More specifically, the drum 93 is rotated by connecting a first driving shaft 921 and a second driving shaft 922 to one side and the other side, and an inner drum 931 formed by perforating a plurality of perforations in a plate material, and the inside It is arranged to surround the outside of the drum 931 and consists of an external drum 932 formed by perforating a plurality of perforations in a plate material.
외부드럼(932)은 내부드럼(931)을 둘러싸도록 배치되는 외부드럼몸체(9321)와, 외부드럼몸체(9321)의 일측 및 타측에 연장되어 구동축(92)에 회전 가능하게 배치되는 외부드럼회전축(9322)으로 구성되어 있다. The outer drum 932 includes an outer drum body 9321 disposed to surround the inner drum 931 , and an outer drum rotating shaft extending from one side and the other side of the outer drum body 9321 to be rotatably disposed on the driving shaft 92 . (9322).
외부드럼회전축(9322)은 제1 구동축(921)에 회전 가능하게 배치되는 제1 외부드럼회전축(9322a)과 제2 구동축(922)의 외부에 배치되는 제2 외부드럼회전축(9322b)으로 구성되어 있다. 여기서, 제1 및 제2 외부드럼회전축(9322a,322b)은 파이프 형상으로 형성되되 제1 외부드럼회전축(9322a)의 외경이 제1 구동축(921)과의 간섭을 고려하여 제2 외부드럼회전축(9322b)에 비해 더 큰 직경을 갖도록 형성되어 있다.The external drum rotating shaft 9322 is composed of a first external drum rotating shaft 9322a rotatably disposed on the first driving shaft 921 and a second external drum rotating shaft 9322b disposed outside of the second driving shaft 922. have. Here, the first and second external drum rotation shafts 9322a and 322b are formed in a pipe shape, and the second external drum rotation shaft ( 9322b) is formed to have a larger diameter.
그리고, 내부드럼(931)과 외부드럼(932)은 대략 원통 형상을 갖도록 형성되고, 그 표면에는 다수의 타공이 천공되어 있는 동시에 슬러지 감량 효과의 상승을 위해 다수의 요철부(미도시)가 형성되는 것이 바람직하다.In addition, the inner drum 931 and the outer drum 932 are formed to have a substantially cylindrical shape, and a plurality of perforations are perforated on the surface thereof, and a plurality of concavo-convex portions (not shown) are formed to increase the sludge reduction effect. It is preferable to be
한편, 드럼구동수단(94)은 드럼을 회전시키는 회전력을 생성, 인가하도록 접속되는 구성요소로서 내부드럼(931)의 회전을 위해 구동축(92)에 회전력을 생성, 인가하는 내부드럼구동수단(941)과, 외부드럼(932)을 회전시키도록 접속되는 외부드럼구동수단(942)으로 구성되어 있다. On the other hand, the drum driving means 94 is a component connected to generate and apply a rotational force for rotating the drum, and an internal drum driving means 941 for generating and applying a rotational force to the driving shaft 92 for rotation of the inner drum 931 . ) and an external drum driving means 942 connected to rotate the external drum 932 .
내부드럼구동수단(941)은 베이스프레임(91)에 설치되는 내부드럼구동모터(9411), 내부드럼구동모터(9411)의 모터축에 접속되는 구동풀리(9412), 구동풀리(9412)에 일측이 접속되는 벨트(9413), 벨트(9413)의 타측이 접속되고 제1 구동축(921)에 접속되는 전동풀리(9414)가 구비되어 있다.The internal drum driving means 941 is an internal drum driving motor 9411 installed on the base frame 91, a driving pulley 9412 connected to the motor shaft of the internal drum driving motor 9411, and one side of the driving pulley 9412 The belt 9413 to be connected, the other side of the belt 9413 is connected, and an electric pulley 9414 connected to the first drive shaft 921 is provided.
외부드럼구동수단(942)은 베이스프레임(91)에 설치되는 외부드럼구동모터(9421), 외부드럼구동모터(9421)의 모터축에 접속되는 구동풀리(9422), 구동풀리(9422)에 일측이 접속되는 벨트(9423), 및 벨트(9423)의 타측이 접속되고 제1 외부드럼회전축(9322a)에 접속되는 전동풀리(9424)가 구비되어 있다.The external drum driving means 942 is an external drum driving motor 9421 installed on the base frame 91, a driving pulley 9422 connected to the motor shaft of the external drum driving motor 9421, and one side of the driving pulley 9422. A belt 9423 to which this is connected, and an electric pulley 9424 to which the other side of the belt 9423 is connected and connected to the first external drum rotating shaft 9322a are provided.
전술한 내부드럼구동수단(941)과 외부드럼구동수단(942)은 슬러지 플록(floc) 해체나 세포막 파괴 등의 감량작용을 상승시킬 수 있도록 내부드럼(931)과 외부드럼(932)의 회전방향이 서로 반대방향이 되도록 구성하는 것이 중요하다. 즉 내부드럼구동수단(941)이 내부드럼(931)을 시계방향으로 회전시키게 되면 외부드럼구동수단(942)은 외부드럼(932)를 반시계방향으로 회전시키도록 구성한다.The above-described inner drum driving means 941 and external drum driving means 942 rotate the inner drum 931 and the outer drum 932 so as to increase the weight loss action such as sludge floc dissolution or cell membrane destruction. It is important to configure them so that they are in opposite directions. That is, when the inner drum driving means 941 rotates the inner drum 931 clockwise, the outer drum driving means 942 rotates the outer drum 932 counterclockwise.
그리고 내부드럼구동수단(941)과 외부드럼구동수단(942)은 동력전달수단으로서 구동풀리(9412,422) 및 전동풀리(9414,424)와 여기에 접속되는 벨트(9413,423)로 구성된 벨트동력전달방식으로 구성되어 있지만, 기어의 맞물림을 통해 동력을 전달하는 기어동력전달방식(미도시)으로도 구성할 수 있다. 그리고 내부드럼구동모터(9411) 및 외부드럼구동모터(9421)는 내부드럼(931) 및 외부드럼(932)을 16,000rpm으로 회전시킬 수 있도록 감속기를 갖는 모터로 구성된다. And the inner drum driving means 941 and the external drum driving means 942 are the driving pulleys 9412 and 422 and the electric pulleys 9414 and 424 as power transmission means and a belt composed of the belts 9413,423 connected thereto. Although it is configured as a power transmission method, it may also be configured as a gear power transmission method (not shown) in which power is transmitted through meshing of gears. In addition, the inner drum driving motor 9411 and the external drum driving motor 9421 are configured as motors having a speed reducer to rotate the inner drum 931 and the outer drum 932 at 16,000 rpm.
도3f는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 처리챔버를 설명하기 위한 개략적인 사시도이다.3F is a schematic perspective view illustrating a treatment chamber of a sludge reduction device of a system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention.
도3f을 참조하면, 처리챔버(95)는 드럼(93)의 외부를 둘러싸 수용하도록 형성되어 베이스프레임(91)에 설치되는 것으로서, 상부 및 하부가 복록한 육면체 형상의 챔버본체(951), 이 챔버본체(951)의 하부 배출구에 설치된 파이프 형상의 드레인라인(952)이 구비되어 있다. 그리고 처리챔버(95)는 측면에 축삽입홀(953)이 형성되어 구동축(92) 및 외부드럼회전축(9322)이 회전 가능하게 삽입, 설치되어 있다.Referring to Figure 3f, the processing chamber 95 is formed to surround the outside of the drum 93 to be accommodated and installed on the base frame 91, the chamber body 951 of the hexahedral shape of which the upper and lower portions are concave, the A pipe-shaped drain line 952 installed at the lower outlet of the chamber body 951 is provided. In addition, the processing chamber 95 has a shaft insertion hole 953 formed on the side thereof so that the driving shaft 92 and the external drum rotating shaft 9322 are rotatably inserted and installed.
한편, 프라즈마발생장치(96)는 처리챔버(95)에 설치되는 복수의 프라즈마방사전극(961), 이 프라즈마방사전극(961)을 고전압을 인가하는 프라즈마발생부(미도시)를 포함한다. On the other hand, the plasma generator 96 includes a plurality of plasma radiation electrodes 961 installed in the processing chamber 95, and a plasma generator (not shown) for applying a high voltage to the plasma radiation electrodes 961 .
프라즈마방사전극(961)은 복수의 양극 프라즈마방사전극과 복수의 음극 프라즈마방사전극으로 구성되고, 양극 및 음극 프라즈마방사전극은 서로 간에 일정한 이격 거리를 갖도록 소켓에 설치되어 처리챔버(95)에 결합되어 있다. 여기서 양극 프라즈마방사전극들은 양극 전원라인(미도시)을 매개로 프라즈마발생부의 양극 단자에 전기적으로 연결되어 있고, 음극 프라즈마방사전극들은 음극 전원라인(미도시)을 매개로 프라즈마발생부의 음극 단자에 전기적으로 연결되어 있다.The plasma radiation electrode 961 is composed of a plurality of anode plasma radiation electrodes and a plurality of cathode plasma radiation electrodes, and the anode and cathode plasma radiation electrodes are installed in a socket to have a certain distance from each other and are coupled to the processing chamber 95. have. Here, the positive plasma radiation electrodes are electrically connected to the positive terminal of the plasma generator via a positive power line (not shown), and the negative plasma radiation electrodes are electrically connected to the negative terminal of the plasma generator via a negative power line (not shown). is connected with
전술한 프라즈마발생부(미도시)는 오,폐수에 포함된 유해균의 살균 특성이 우수하다면 특별한 제한 없이 적용할 수 있다. 예컨대 프라즈마발생부는 저온플라즈마구동부로 구성될 수 있다. 이 저온플라즈마구동부는 전원을 공급하는 전원부(미도시)와, 이 전원부와 전기적으로 연결되고 양극 및 음극 플라즈마방사전극에 소정의 전압과 전류를 인가하는 구동회로부(미도시)로 이루어진 것으로, 저온 플라즈마 발생장치 분야에서 이용되는 통상의 저온플라즈마구동부를 적용하여 구성한다.The above-described plasma generating unit (not shown) can be applied without any particular limitation as long as it has excellent sterilization properties of harmful bacteria contained in sewage and wastewater. For example, the plasma generating unit may be configured as a low-temperature plasma driving unit. The low-temperature plasma driving unit consists of a power supply unit (not shown) for supplying power, and a driving circuit unit (not shown) that is electrically connected to the power supply unit and applies a predetermined voltage and current to the anode and cathode plasma radiation electrodes. It is configured by applying a common low-temperature plasma driving unit used in the field of generators.
한편, 본 발명에 따른 슬러지 감량장치는 구동축(92) 및 외부드럼회전축(9322)을 회전 가능하게 지지하도록 회전지지수단(98)이 구비되어 있다.On the other hand, the sludge reduction device according to the present invention is provided with a rotation support means 98 to rotatably support the drive shaft 92 and the external drum rotation shaft 9322.
회전지지수단(98)은 베이스프레임(91)에 설치되는 구성요소로서, 제1 베어링블록(981), 제2 베어링블록(982), 제3 베어링블록(983) 및 제4 베어링블록(984)으로 구성되어 있다. 여기서, 제1 내지 4 베어링블록(981,982,983,984)은 베어링이 삽입되는 하우징의 하부에 피설치부에 볼트 체결되는 체결브라켓이 일체로 형성된 것으로서 통상 필로우 블록(Pillow block)으로 호칭되고 있는 것을 적용할 수 있다.The rotation support means 98 is a component installed on the base frame 91 , and includes a first bearing block 981 , a second bearing block 982 , a third bearing block 983 , and a fourth bearing block 984 . is composed of Here, the first to fourth bearing blocks 981, 982, 983, and 984 are integrally formed with a fastening bracket that is bolted to the to-be-installed part at the lower part of the housing into which the bearing is inserted, which is commonly referred to as a pillow block. .
제1 베어링블록(981)은 제1 구동축(921)에 베어링이 접속되도록 베이스프레임(91)에 설치되고, 제2 베어링블록(982)은 제2 구동축(922)에 베어링이 접속되도록 베이스프레임(91)에 설치되어 있다.The first bearing block 981 is installed on the base frame 91 so that the bearing is connected to the first drive shaft 921 , and the second bearing block 982 is the base frame ( 91) is installed.
제3 베어링블록(983)은 제1 외부드럼회전축(9322a)의 일측에 베어링이 접속되도록 베이스프레임에 설치되어 있고, 제4 베어링블록(984)은 제2 외부드럼회전축(9322b)에 베어링이 접속되도록 베이스프레임에 설치되어 있다.The third bearing block 983 is installed on the base frame so that the bearing is connected to one side of the first external drum rotating shaft 9322a, and the fourth bearing block 984 is the bearing connected to the second external drum rotating shaft 9322b. It is installed on the base frame as much as possible.
한편, 본 발명에 따른 슬러지 감량장치는 도면에 구체적으로 도시하지는 않았지만 내부드럼(931)의 내부로 슬러지를 압송하기 위한 압송펌프(미도시)가 구성되어 있다.On the other hand, although not specifically shown in the drawing, the sludge reduction device according to the present invention includes a pressure pump (not shown) for pumping sludge into the inner drum 931 .
압송펌프는 액체에 슬러지와 같이 고형물질이 포함되어 있더라도 용이한 펌핑이 가능하도록 슬러지 펌프로 구성된 것으로서, 흡입측에 슬러지의 흡입을 위한 흡입배관(미도시)이 접속되어 있고 배출측에 슬러지의 배출을 위한 배출배관(미도시)이 접속되어 있다. 예컨대 배출배관(미도시)은 고압호스를 제1 구동축(921)의 입구에 기밀적으로 접속하는 방식으로 구성할 수 있다.The pressure pump is composed of a sludge pump to enable easy pumping even if the liquid contains solid materials such as sludge. A discharge pipe (not shown) for For example, the discharge pipe (not shown) may be configured in such a way that the high-pressure hose is hermetically connected to the inlet of the first driving shaft 921 .
한편, 도3a의 미설명부호 9는 컨트롤박스로서 내부에 드럼구동수단(94), 프라즈마발생장치(96) 등의 구동을 제어하는 제어부(미도시)가 실장되어 있다. 그리고 컨트롤박스(99)에는 전원버튼 및 온/오프 버튼 등과 같은 입력부, 작동상태를 표시하는 디스플레이 등이 설치될 수 있다.On the other hand, non-explained reference numeral 9 of FIG. 3A is a control box in which a control unit (not shown) for controlling the driving of the drum driving means 94 and the plasma generating device 96 is mounted therein. In addition, an input unit such as a power button and an on/off button, a display for displaying an operating state, etc. may be installed in the control box 99 .
이하 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 작용을 간략하게 설명한다.Hereinafter, the operation of the sludge reduction device of the system for treating dyed wastewater and high-concentration wastewater according to an embodiment of the present invention will be briefly described.
첨부도면, 도3g는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 슬러지 감량장치의 작용을 설명하기 위한 도면으로서, 이해를 돕기 위해 슬러지의 처리 흐름을 지시선으로 표기한 개략적인 평면도이다.The accompanying drawings, Figure 3g is a view for explaining the operation of the sludge reduction device of the system for the treatment of dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention. is a floor plan.
도3g를 참조하면, 본 발명에 따른 슬러지 감량장치는 압송펌프(미도시)의 펌핑작용에 의해 슬러지가 제1 구동축(921)의 내부로 유입되어 내부드럼(931) 및 외부드럼(932)를 경유하여 처리챔버(95)로 배출되는 슬러지의 감량 작용이 수행된다. Referring to FIG. 3G, in the sludge reduction device according to the present invention, the sludge is introduced into the first drive shaft 921 by the pumping action of the pressure pump (not shown), and the inner drum 931 and the outer drum 932 are formed. A weight reduction action of the sludge discharged to the treatment chamber 95 via the gas flow is performed.
이때, 내부드럼(931)은 내부드럼구동모터(9411)의 회전력이 구동풀리(9412), 벨트(9413), 전동풀리(9414) 순으로 전달됨에 따라 제1 구동축(921)이 회전되면서 회전동작을 수행한다. 그리고, 외부드럼(932)은 외부드럼구동모터(9421)의 회전력이 구동풀리(9422), 벨트(9423), 전동풀리(9424) 순으로 전달됨에 따라 제1 외부드럼회전축(9322a)이 회전되면서 회전동작을 수행한다. At this time, the inner drum 931 rotates while the first drive shaft 921 is rotated as the rotational force of the inner drum driving motor 9411 is transmitted in the order of the drive pulley 9412 , the belt 9413 , and the electric pulley 9414 . carry out And, as the rotational force of the external drum driving motor 9421 is transmitted to the external drum 932 in the order of the driving pulley 9422, the belt 9423, and the electric pulley 9424, the first external drum rotating shaft 9322a is rotated while the external drum 932 is rotated. perform rotational motion.
전술한 바와 같이 압송펌프(미도시)에 의해 펌핑된 슬러지는 제1 구동축(921)의 나선형이동홈(9212)을 따라 선회하게 되어 내부드럼(931)으로 분출되는 동시에 소용돌이를 일으키면서 분사되므로 이어지는 슬러지 감량 효과를 상승시킬 수 있다.As described above, the sludge pumped by the pressure pump (not shown) rotates along the spiral movement groove 9212 of the first drive shaft 921 and is ejected to the inner drum 931 while generating a vortex. It can increase the sludge reduction effect.
또한, 제1 구동축(921)의 내부 슬러지이동로로 유입되는 슬러지는 자장발생부(97)를 통과하게 되면서 마그네틱부재(971)의 자기력에 의해 분자 상호간 결합과 이온 결합이 약화되므로 이어지는 슬러지 플록(floc) 해체나 세포막 파괴 등의 작용을 상승시켜 슬러지 감량 효과를 높힐 수 있다.In addition, as the sludge flowing into the internal sludge passage of the first drive shaft 921 passes through the magnetic field generator 97, the intermolecular and ionic bonds are weakened by the magnetic force of the magnetic member 971, so the subsequent sludge flocs ( floc) can increase the effect of dismantling or destroying cell membranes, thereby increasing the sludge reduction effect.
한편 제1 구동축(921)을 통해 내부드럼의 내부로 분출된 슬러지는 내부드럼(931) 내벽의 요철부에 부딪히면서 슬러지 플록(floc) 해체나 세포막 파괴 작용이 1차적으로 이루어지고, 내부드럼의 타공을 통해 외부드럼(932)으로 배출되어 2차적으로 충돌한 다음 외부드럼(932)을 통해 처리챔버(95)로 배출된다. 이때, 내부드럼(931)과 외부드럼(932)은 각각 16,000rpm으로 고속 회전할 뿐만 아니라 회전방향이 서로 반대방향으로 회전하므로 슬러지 플록(floc) 해체나 세포막 파괴 작용이 효과적으로 이루어지게 된다.On the other hand, the sludge ejected into the inner drum through the first driving shaft 921 collides with the uneven portion of the inner wall of the inner drum 931 to dismantle the sludge floc or destroy the cell membrane, and the inner drum is perforated. It is discharged to the external drum 932 through the secondary collision, and then is discharged to the processing chamber 95 through the external drum 932 . At this time, the inner drum 931 and the outer drum 932 not only rotate at a high speed at 16,000 rpm, respectively, but also rotate in opposite directions to each other, so that the sludge floc dismantling or cell membrane destruction action is effectively performed.
연이어, 처리챔버(95)로 유출된 슬러지에 포함된 유해균은 프라즈마발생장치(96)에 의한 프라즈마 살균처리 과정을 통해 살균, 제거된다. 즉 주지된 바와 같이 프라즈마발생부의 작동에 따라 양극 및 음극 프라즈마방사전극(961) 사이에서 저전압 방전현상이 일어나 수산기들이 생성되고 이러한 수산기의 강력한 산화작용으로 유해균이 살균된다. 이때, 유입되는 슬러지의 양이나 종류 등에 따라 양극 및 음극 프라즈마방사전극(961) 사이의 간격이나 수량을 증감하는 방식으로 조절함으로써 보다 효율적으로 살균작용을 할 수 있다.Subsequently, harmful bacteria contained in the sludge flowing into the treatment chamber 95 are sterilized and removed through the plasma sterilization process by the plasma generator 96 . That is, as is well known, according to the operation of the plasma generating unit, a low voltage discharge phenomenon occurs between the positive and negative plasma radiation electrodes 961 to generate hydroxyl groups, and harmful bacteria are sterilized by the strong oxidation of the hydroxyl groups. At this time, the sterilization can be performed more efficiently by adjusting the interval or quantity between the positive and negative plasma radiation electrodes 961 according to the amount or type of the introduced sludge.
전술한 바와 같은 슬러지 감량 과정을 거친 슬러지는 챔버본체(951)의 하부 배출구에 설치된 파이프 형상의 드레인라인(952)을 통해 외부로 배출되어 탈수기(9c)로 이송되고 정해진 처리과정을 거치게 된다.The sludge, which has undergone the sludge reduction process as described above, is discharged to the outside through the pipe-shaped drain line 952 installed at the lower outlet of the chamber body 951, is transferred to the dehydrator 9c, and is subjected to a predetermined treatment process.
이하 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템의 염색 폐수 및 고농도 폐수 처리를 위한 방법을 간략하게 설명한다.Hereinafter, a method for treating dyeing wastewater and high-concentration wastewater of the system for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention will be briefly described.
도4는 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 방법을 설명하기 위한 공정도이다.4 is a process diagram for explaining a method for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention.
도4를 참조하면, 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 방법은 스크린조 처리단계, 유량조정조 처리단계, 1차전기분해단계, 가압부상조 처리단계, 무산소조 처리단계, 혐기조 처리단계, 접촉폭기조 처리단계, 막분리조 처리단계, 2차전기분해단계, 배수조 처리단계, 및 슬러지 처리단계를 순차적으로 시행한다.4, the method for treating dyeing wastewater and high-concentration wastewater according to an embodiment of the present invention includes a screen tank treatment step, a flow rate control tank treatment step, a primary electrolysis step, a pressure flotation tank treatment step, an anaerobic tank treatment step, The anaerobic tank treatment step, the contact aeration tank treatment step, the membrane separation tank treatment step, the secondary electrolysis step, the drainage tank treatment step, and the sludge treatment step are sequentially performed.
스크린조 처리단계는 침사/스크린조(1a)에 의해 유입되는 폐수 중에 포함된 고형물을 제거하는 단계로서, 체류시간을 1분 이상으로 하여 모래 및 고형물질 등 입자 크기가 큰 물질을 제거하되, 폐수에 포함된 유분은 침사/스크린조에서 물과 기름의 비중차에 의해 분리된다. 이러한 스크린조 처리단계는 비중 큰 고형물이나 가벼운 협잡물을 분리함으로써 후속 처리 시설에 구비되는 펌프 등을 이물질로부터 보호할 수 있다.The screen bath treatment step is a step of removing the solids contained in the wastewater introduced by the sedimentation/screen bath 1a, and the residence time is 1 minute or more to remove large particle size materials such as sand and solid materials, but wastewater The oil contained in the sediment is separated by the specific gravity difference between water and oil in the sedimentation/screen tank. In this screen bath treatment step, it is possible to protect a pump, etc. provided in a subsequent treatment facility from foreign substances by separating solids or light contaminants with a large specific gravity.
유량조정조 처리단계는 침사/스크린조(1a)를 경유한 폐수의 유량을 유량조정조(2)에서 조정하는 단계로서, 유입되는 폐수가 일정하지 않기 때문에 유량이 작을 경우 유량 및 폐수의 처리 품질을 균등화 할 수 있도록 일정 양이 될 때까지 가두어 보관한 후 정해진 양을 폐수를 다음 단계로 공급한다. The flow rate adjustment tank treatment step is a step in which the flow rate of wastewater passing through the sedimentation/screen tank 1a is adjusted in the flow rate adjustment tank 2, and since the incoming wastewater is not constant, when the flow rate is small, the flow rate and wastewater treatment quality are equalized The wastewater is supplied to the next step after confinement and storage until a certain amount is reached.
1차전기분해단계는 유량조정조(2)를 경유한 폐수를 1차 전기분해장치(3a)에 의한 전기 화학적 처리 과정을 통해 생성된 OH라디칼의 산화력을 이용하여 오염물질 및 색도를 1차로 제거하는 단계로서, OH라디칼의 생성 메커니즘은 주지된 기술이므로 구체적인 설명을 생략한다.The primary electrolysis step is to first remove contaminants and chromaticity by using the oxidizing power of OH radicals generated through the electrochemical treatment process by the primary electrolysis device (3a) of wastewater passing through the flow control tank (2). As a step, the mechanism of generation of OH radicals is a well-known technique, and thus a detailed description thereof will be omitted.
이러한, 1차전기분해단계는 염소, 수소 가스에 의한 산화, 환원반응에 의해 COD를 비롯한 유기물의 농도를 저감하고, 발생가스에 의한 슬러지의 부상성을 증가시키고 미세 기포를 형성하므로 이어지는 가압부상조의 성능을 향상시킬 수 있다. 특히, 1차전기분해단계는 종래 폐수 처리시스템에서 가압부상조 처리단계의 전처리 과정으로 필수적으로 요구되던 반응조, 중화조 및 응집조와 같은 시설을 생략할 수 있고, 종래 전처리 시에 사용되는 응집제, 중화제 등의 화학약품 사용량을 줄일 수 있어서 비용 절감은 물론이고 과도한 화학약품 사용에 따른 슬러지 발생량을 저감하여 처리 부하를 저감할 수 있다.This primary electrolysis step reduces the concentration of organic matter including COD by oxidation and reduction reactions by chlorine and hydrogen gas, increases the flotation property of the sludge by the generated gas, and forms fine bubbles, so the subsequent pressurized flotation tank performance can be improved. In particular, the primary electrolysis step can omit facilities such as a reaction tank, a neutralization tank, and a coagulation tank, which are essentially required as a pretreatment process of the pressure flotation tank treatment step in the conventional wastewater treatment system, and the coagulant and neutralizer used in the conventional pretreatment It is possible to reduce the amount of chemicals used, such as reducing costs, as well as reducing the amount of sludge generated due to excessive use of chemicals, thereby reducing the processing load.
가압부상조 처리단계는 1차 전기분해장치(3a)를 경유하여 가압부상조(4)로 유입된 폐수를 버블발생장치에 의해 생성된 마이크로 버블과 접촉시켜 플록이 응집, 부상되도록 하여 제거하는 단계이다. The pressure flotation tank treatment step is a step of removing the wastewater introduced into the pressure flotation tank 4 via the primary electrolysis device 3a by contacting the microbubbles generated by the bubble generator so that the flocs are agglomerated and floated. to be.
무산소조 처리단계는 가압부상조를 경유한 폐수를 무산소조(5)에서 1 내지 9시간 동안 체류시키면서 폐수 중에 포함된 유기물의 질산성질소를 탈질산화하여 질소와 유기물을 제거하는 단계로서, 무산소조에 오폐수의 체류시간은 3 ~ 9시간의 범위로 하는 것이 바람직한데, 기존의 무산소조의 체류시간인 1 ~ 3시간의 범위와 비교하여 약 3배 이상의 체류시간을 유지함으로써 오폐수의 자체소화를 증가시켜 잉여 슬러지의 발생을 저감할 수 있다. The anoxic tank treatment step is a step of removing nitrogen and organic matter by denitrifying the nitrate nitrogen contained in the wastewater while retaining the wastewater passing through the pressurized flotation tank in the anoxic tank 5 for 1 to 9 hours. The residence time is preferably in the range of 3 to 9 hours. Compared to the range of 1 to 3 hours, which is the residence time of the existing anaerobic tank, the residence time is maintained about 3 times or more, thereby increasing the self-extinguishing of wastewater and removing excess sludge. occurrence can be reduced.
한편, 무산소조(5)에 특고압양자장 방출회로에 가변파형의 고주파를 매칭하고 투사양자량 및 파형을 조절하여 오염물질을 처리하는 장치를 부가하여 오염물질의 제거 효율을 높이는 것이 바람직하다. 각종 오,폐수등에 포함되어 있는 난분해성 오염물질을 교반(Mixing)시키면서 적절한 파동의 양자장을 주사하면 오염요소의 분자들이 음이온(Anion)과 양이온(Cation)이 전기적평형(Electro Equilibrium)을 이루며 해리(Dissociation)되어 수화되어 있는 유기화합물이나 중금속착이온(Complexion)들은 수화층과 분리되고 수중에서 유사시상반응(Gas Like Reaction)을 일으킨다. On the other hand, it is preferable to increase the removal efficiency of pollutants by adding a device for processing pollutants by matching the high frequency of the variable waveform to the special high-pressure quantum field emission circuit in the anoxic tank 5 and adjusting the projected dose and waveform. When the quantum field of an appropriate wave is injected while stirring the difficult-to-decompose pollutants contained in various types of sewage and wastewater, the molecules of the polluting element dissociate with anions and cations in Electro Equilibrium. Dissociated and hydrated organic compounds or heavy metal complex ions are separated from the hydration layer and cause a Gas Like Reaction in water.
이 상태에서 수중에 외부교반기에 의한 교반(Mixing)에 의하여 극성유기분자들이 수화층을 벗어나게 함으로써, 마치 공기중에서 휘발성유기물(VOC)이 단시간 내에 산화,분해되는 것과 같이 수중에서 유기물이나 착이온, 음이온 및 전자들이 더욱 높은 에너지 상태로 활성화되어 오염물질들의 해리와 이온화가 촉진된다. 분해되기 어려운 유기물 결합형태의 불용성 인(Phosphorus)은 오르토(Ortho)형태로 무기물화하여 용해성 슬러지로 변화되어 처리가 용이해진다. 또한 질소(Nitrogen)도 유기질소(Proteins)로 변환되어 질산화한 후 질소가스형태로 변환된 뒤 배출된다.In this state, polar organic molecules leave the hydration layer by mixing by an external stirrer in water, so that organic substances, complex ions, and negative ions in water are oxidized and decomposed in a short time, just as volatile organic substances (VOCs) in the air are oxidized and decomposed in a short time. and electrons are activated to a higher energy state to promote dissociation and ionization of contaminants. Insoluble phosphorus (Phosphorus) in the form of organic matter that is difficult to decompose is converted into soluble sludge by inorganicizing it in the form of Ortho, which makes it easier to process. In addition, nitrogen (Nitrogen) is also converted into organic nitrogen (Proteins), nitrified, and then converted into nitrogen gas and discharged.
혐기조 처리단계는 무산소조(5)를 경유한 폐수를 혐기조(6)에 4 내지 8시간 동안 체류시키면서 잔류하는 유기물을 이용하여 잔여 탈질과 인 방출이 이루어지도록 하는 혐기조 처리단계이다.The anaerobic tank treatment step is an anaerobic tank treatment step in which residual denitrification and phosphorus release are made using the remaining organic matter while the wastewater passing through the anaerobic tank 5 is stayed in the anaerobic tank 6 for 4 to 8 hours.
접촉폭기조 처리단계는 혐기조(6)를 경유한 폐수를 접촉폭기조(7)에서 폭기시키면서 잔류하는 유기물에 미생물을 접촉, 성장시켜 미생물 플록을 형성하는 단계로서, 살아있거나 죽은 미생물이 부유된 상태에 있는 활성슬러지 중의 미생물은 호기성 환경에서 유기물을 물질대사를 통해 분해시키는 작용을 하는 바, 이를 이용한 활성슬러지 공법에서 접촉폭기조의 역할은 미생물과 유입폐수 내의 유기물이 접촉되어 미생물이 성장하여 미생물 플록을 형성시키는 작용을 한다. 그리고 접촉폭기조에서의 체류시간은 3 ~ 14시간이 되도록 설계하는 것이 바람직하다.The contact aeration tank treatment step is a step of forming microbial flocs by contacting and growing microorganisms with the remaining organic matter while aerating the wastewater that has passed through the anaerobic tank 6 in the contact aeration tank 7, in which living or dead microorganisms are suspended Microorganisms in activated sludge act to decompose organic matter through metabolism in an aerobic environment. The role of the contact aeration tank in the activated sludge method using this is that microorganisms and organic matter in the inflow wastewater come into contact with the microorganisms to grow and form microbial flocs. it works And it is desirable to design the residence time in the contact aeration tank to be 3 to 14 hours.
그리고, 접촉폭기조 처리단계는 접촉폭기조(7)에서 생성된 슬러지 일부를 유량조정조(2) 또는 무산소조(5)에 선택적으로 반송시키는 순환과정을 수행한다. 이러한 순환과정은 슬러지의 일부를 유량조정조(2) 또는 무산소조(5)로 반송하여 폐수에 의해 발생된 슬러지 순환이 가능하도록 함으로써 처리공정에서의 슬러지의 체류시간을 증가시키고, 이로 인하여 슬러지의 자체 소화에 의하여 처리 효율을 향상시킬 수 있다.And, in the contact aeration tank treatment step, a circulation process of selectively returning a part of the sludge generated in the contact aeration tank 7 to the flow rate control tank 2 or the anoxic tank 5 is performed. This circulation process increases the residence time of the sludge in the treatment process by returning a part of the sludge to the flow control tank 2 or the anoxic tank 5 to enable the sludge circulation generated by the wastewater, thereby self-extinguishing the sludge. can improve processing efficiency.
막분리조 처리단계는 접촉폭기조(7)를 경유한 폐수를 막분리조(8)에서 질산화 및 미생물 분리가 일어나도록 하는 단계로서, 본 단계에서는 니트라이트(nitrite)를 중간매개체로 하여 연속적으로 암모늄을 니트라이트로 산화시키고, 동시에 무산소조 공정에서 소모되고 남은 잔존 BOD 성분을 호기성 미생물에 의하여 분해된다. The membrane separation tank treatment step is a step for nitrification and microbial separation of the wastewater passing through the contact aeration tank 7 to occur in the membrane separation tank 8. In this step, nitrite is used as an intermediate medium to continuously ammonium is oxidized to nitrite, and at the same time, the remaining BOD components consumed in the anoxic tank process are decomposed by aerobic microorganisms.
그리고, 막분리조(7)에서 생성된 슬러지를 상태에 따라 1차 전기분해장치(3a) 또는 무산소조(5)에 선택적으로 반송시키는 순환과정을 수행한다. 이러한 순환과정은 슬러지의 일부를 1차 전기분해장치(3a) 또는 무산소조(5)로 반송하여 폐수에 의해 발생된 슬러지 순환이 가능하도록 함으로써 처리공정에서의 슬러지의 체류시간을 증가시키고, 이로 인하여 슬러지의 자체소화에 의하여 처리 효율을 향상시킬 수 있다.Then, a circulation process is performed in which the sludge generated in the membrane separation tank 7 is selectively returned to the primary electrolysis device 3a or the anoxic tank 5 depending on the state. This circulation process increases the residence time of the sludge in the treatment process by returning a part of the sludge to the primary electrolysis device 3a or the anoxic tank 5 to enable the sludge circulation generated by the wastewater, thereby increasing the sludge Treatment efficiency can be improved by self-extinguishing.
2차전기분해단계는 막분리조(8)를 경유한 폐수를 2차 전기분해장치(3b)에 의한 전기 화학적 처리 과정을 통해 OH라디컬의 산화력을 이용하여 오염물질 및 색도를 2차로 제거하는 수행하는 단계로서, 전술한 1차전기분해단계를 후 공정에서 다시 한번 더 수행함에 따라 폐수의 정화효율 향상은 물론이고, 응집제, 중화제 등의 화학약품 사용량을 줄일 수 있어서 비용 절감은 물론이고 과도한 화학약품 사용에 따른 슬러지 발생량을 저감할 수 있다.The secondary electrolysis step is to use the oxidizing power of OH radicals to secondarily remove contaminants and chromaticity through the electrochemical treatment process of the wastewater passing through the membrane separation tank (8) by the secondary electrolysis device (3b). As a step to perform, as the above-mentioned primary electrolysis step is performed once again in the post process, the purification efficiency of wastewater can be improved as well as the amount of chemicals such as flocculants and neutralizers can be reduced, thereby reducing costs and excessive chemical It is possible to reduce the amount of sludge generated by the use of chemicals.
배수조 처리단계는 2차 전기분해장치(3b)를 경유한 폐수를 배수조(1b)에 수용하고 상등수를 방류시키는 단계이다.The wastewater tank treatment step is a step of receiving the wastewater passing through the secondary electrolysis device 3b in the drain tank 1b and discharging the supernatant water.
한편, 슬러지 처리단계는 접촉폭기조(7)로부터 생성된 슬러지를 슬러지처리부(9)를 이용하여 시행하는 것으로서 농축조 과정, 슬러지 감량과정, 탈수기 과정으로 구성되어 슬러지를 농축, 감량 및 제거하는 단계이다.On the other hand, the sludge treatment step is performed by using the sludge treatment unit 9 for the sludge generated from the contact aeration tank 7, and consists of a thickener process, a sludge reduction process, and a dehydrator process to concentrate, reduce and remove the sludge.
농축조 과정은 접촉폭기조 처리단계에 의해 생성된 슬러지가 농축조(9a)로 유입되면 침전 과정을 통해 농축시키는 것으로서, 침전된 슬러지는 슬러지 감량장치(9b)로 이송하고, 상등수는 유량조정조(2)의 반송하여 재처리 되도록 하는 과정이다.In the thickening tank process, when the sludge generated by the contact aeration tank treatment step flows into the thickening tank 9a, it is concentrated through a sedimentation process, and the settled sludge is transferred to the sludge reduction device 9b, and the supernatant is transferred to the flow rate control tank 2 It is the process of returning and reprocessing.
슬러지 감량과정은 전술한 슬러지 감량장치(9b)의 작용에 의해 슬러지를 감량하는 과정이고, 탈수기 과정은 탈수기(9c)에 의해 탈수 과정을 수행하는 것으로 최종 배출되는 슬러지 케익은 외부로 반출되어 매립, 소각 등의 후처리 과정을 거치게 된다.The sludge reduction process is a process of reducing sludge by the action of the sludge reduction device 9b described above, and the dehydrator process is a dehydration process performed by the dehydrator 9c. The sludge cake finally discharged is taken out and buried, It undergoes post-processing such as incineration.
상기한 바와 같이 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 방법은 전처리 과정 대신에 1차전기분해단계 및 2차전기분해단계를 적용함으로써 처리시스템의 간결, 단순화와 시설투자비를 절감할 수 있고, 중화제, 응집제 등과 같은 화학약품의 사용량을 50% 내외의 범위로 절감할 수 있음을 실험적으로 확인할 수 있었으며, 이로 인해 슬러지 발생량 또한 줄일 수 있는 장점이 있다. As described above, in the method for treating dyeing wastewater and high concentration wastewater according to an embodiment of the present invention, the conciseness, simplification and facility investment cost of the treatment system are reduced by applying the primary electrolysis step and the secondary electrolysis step instead of the pretreatment process. It was confirmed experimentally that the amount of chemicals such as neutralizers and coagulants can be reduced to about 50%, and this has the advantage of reducing the amount of sludge generated.
이상 설명한 본 발명의 일 실시예에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법의 구성 및 동작에 대해서 설명하였으나, 이는 예시적인 것으로서 본 기술분야에 통상의 지식을 가진자는 본 발명의 기술적 사상을 벗어나지 않는 범위에서 전술한 실시예의 일부를 치환 및 변형하는 것이 가능함을 이해할 수 있을 것이다.Although the configuration and operation of the system and method for dyeing wastewater and high-concentration wastewater treatment according to an embodiment of the present invention described above have been described, these are exemplary and those of ordinary skill in the art can relate to the technical spirit of the present invention It will be understood that substitution and modification of some of the above-described embodiments are possible without departing from the scope of the present invention.
따라서 본 발명의 보호범위는 특허청구범위에 기재된 발명 및 그 균등물에 미치는 것으로 이해되어야 할 것이다. Therefore, it should be understood that the protection scope of the present invention extends to the invention described in the claims and their equivalents.
본 발명에 따른 염색 폐수 및 고농도 폐수 처리를 위한 시스템 및 그 방법은 폐수시설을 간결, 단순화할 수 있고 화학 약품의 사용을 최소화하면서도 폐수를 효과적으로 처리할 수 있는 기술로서 염색 폐수, 오수, 고농도 폐수 등과 같은 각종 폐수 처리에 사용할 수 있다.The system and method for treating dyeing wastewater and high-concentration wastewater according to the present invention is a technology that can simplify and simplify wastewater facilities and effectively treat wastewater while minimizing the use of chemicals, such as dyeing wastewater, sewage, high-concentration wastewater, etc. It can be used for various wastewater treatment such as

Claims (9)

  1. 염색 폐수 및 고농도 폐수 처리를 위한 시스템에 있어서In a system for the treatment of dyeing wastewater and high-concentration wastewater
    유입되는 폐수 중에 포함된 고형물을 제거하는 침사/스크린조;a sedimentation/screen tank for removing solids contained in the inflowing wastewater;
    상기 침사/스크린조를 경유한 폐수의 유량을 조정하는 유량조정조;a flow rate adjustment tank for adjusting the flow rate of wastewater passing through the sediment/screen tank;
    상기 유량조정조를 경유한 폐수의 전기 화학적 처리 과정을 1차로 수행하는 1차 전기분해장치;a primary electrolysis device that primarily performs an electrochemical treatment process of wastewater passing through the flow control tank;
    버블발생장치로부터 생성된 버블을 상기 1차 전기분해장치를 경유한 폐수와 접촉시켜 플록이 응집, 부상되도록 하는 가압부상조;a pressurized flotation tank for contacting the bubbles generated by the bubble generator with wastewater passing through the primary electrolysis device so that the flocs are agglomerated and floated;
    상기 1차 전기분해장치를 경유한 폐수 중에 포함된 유기물을 이용하여 질산성질소를 탈질산화하여 질소와 유기물을 제거하는 무산소조;an anoxic tank for removing nitrogen and organic matter by denitrifying nitrate nitrogen using organic matter contained in the wastewater passed through the primary electrolysis device;
    상기 무산소조를 경유한 폐수에 잔류하는 유기물을 이용하여 잔여 탈질과 인 방출이 이루어지도록 하는 혐기조;an anaerobic tank to allow residual denitrification and phosphorus release using organic matter remaining in wastewater passing through the anaerobic tank;
    상기 혐기조를 경유한 폐수에 잔류하는 유기물에 미생물을 접촉, 성장시켜 미생물 플록을 형성하고 슬러지 일부를 상기 유량조정조로 반송시키도록 구성된 접촉폭기조;a contact aeration tank configured to contact and grow microorganisms with organic matter remaining in the wastewater passing through the anaerobic tank to form microbial flocs and return a portion of the sludge to the flow rate control tank;
    상기 접촉폭기조를 경유한 폐수를 막분리에 의하여 질산화 및 미생물 분리가 일어나도록 하는 막분리조;a membrane separation tank for nitrification and microbial separation by membrane separation of the wastewater passing through the contact aeration tank;
    상기 막분리조를 경유한 폐수의 전기 화학적 처리 과정을 2차로 수행하는 2차 전기분해장치; a secondary electrolysis device for performing an electrochemical treatment process of wastewater passing through the membrane separation tank;
    상기 2차 전기분해장치를 경유한 폐수가 유입되고 상등수가 방류되는 배수조; 및a drainage tank in which wastewater passing through the secondary electrolysis device is introduced and supernatant water is discharged; and
    상기 접촉폭기조의 슬러지가 유입되어 농축, 제거되는 슬러지처리부;를 포함하는 것을 특징으로 하는 염색 폐수 및 고농도 폐수 처리를 위한 시스템.A system for treating dyed wastewater and high-concentration wastewater, comprising a; a sludge treatment unit in which the sludge of the contact aeration tank is introduced and concentrated and removed.
  2. 제1항에 있어서,The method of claim 1,
    상기 슬러지처리부는,The sludge treatment unit,
    상기 접촉폭기조로부터 유입되는 슬러지를 농축하고 상등수를 상기 유량조정조로 반송시키도록 구성된 농축조;a thickening tank configured to concentrate the sludge flowing in from the contact aeration tank and return the supernatant to the flow rate control tank;
    상기 농축조로부터 배출되는 슬러지를 고속 회전시켜 감량하는 슬러지 감량장치; 및 a sludge reduction device for reducing the weight by rotating the sludge discharged from the thickener at high speed; and
    상기 슬러지 감량장치로부터 배출되는 슬러지의 수분을 탈수하여 고액 분리하는 탈수기;를 포함하는 것을 특징으로 하는 염색 폐수 및 고농도 폐수 처리를 위한 시스템.A system for treating dyed wastewater and high-concentration wastewater comprising a;
  3. 제2항에 있어서,3. The method of claim 2,
    상기 접촉폭기조에서 생성된 슬러지 일부를 상기 유량조정조 또는 상기 무산소조에 선택적으로 반송시키도록 제1 반송라인 및 제2 반송라인이 구성되고,A first return line and a second return line are configured to selectively return a portion of the sludge generated in the contact aeration tank to the flow rate adjustment tank or the anoxic tank,
    상기 막분리조에서 생성된 슬러지를 상기 1차 전기분해장치 또는 상기 무산소조에 선택적으로 반송시키도록 제3 반송라인 및 제4 반송라인이 구성되고,A third return line and a fourth return line are configured to selectively return the sludge generated in the membrane separation tank to the primary electrolysis device or the anaerobic tank,
    상기 농축조에서 생성된 상등수를 상기 상기 유량조정조로 반송시키도록 제5 반송라인이 구성된 것을 특징으로 하는 염색 폐수 및 고농도 폐수 처리를 위한 시스템.A system for treating dyeing wastewater and high-concentration wastewater, characterized in that a fifth return line is configured to return the supernatant water generated in the concentration tank to the flow rate adjustment tank.
  4. 제2항에 있어서,3. The method of claim 2,
    상기 1차 전기분해장치 및 상기 2차 전기분해장치는,The primary electrolysis device and the secondary electrolysis device,
    폐수가 유입되어 수용되는 전기분해실이 마련된 전기분해본체;an electrolysis body provided with an electrolysis chamber in which wastewater is introduced;
    상기 전기분해본체에 설치되는 교반기; a stirrer installed in the electrolysis body;
    상기 전기분해실에 설치되고 다수의 양극판 및 음극판과 상기 양극판 및 음극판이 설치되는 극판설치대, 상기 음극판 및 양극판에 전기분해용 전원을 공급하는 전원부를 구비한 전기분해부;an electrolysis unit installed in the electrolysis chamber and having a plurality of positive and negative electrode plates and a pole plate mounting table on which the positive and negative plates are installed, and a power supply unit for supplying power for electrolysis to the negative electrode and positive plate;
    상기 전기분해본체에 접속되는 유입라인; an inlet line connected to the electrolysis body;
    상기 전기분해본체에 접속되고 배출제어밸브가 설치된 배출라인;a discharge line connected to the electrolysis body and provided with a discharge control valve;
    상기 전기분해실에 유입되는 폐수의 수위를 감지하도록 설치되는 수위감지부;a water level sensing unit installed to detect the level of wastewater flowing into the electrolysis chamber;
    상기 유입라인을 통해 폐수를 상기 전기분해실로 압송하는 압송펌프; 및a pressure pump for pumping wastewater to the electrolysis chamber through the inlet line; and
    상기 수위감지부의 감지신호를 기초로 상기 압송펌프의 구동을 제어하는 전기분해장치제어부;를 포함하는 것을 특징으로 하는 염색 폐수 및 고농도 폐수 처리를 위한 시스템.The system for treating dyed wastewater and high-concentration wastewater comprising a;
  5. 제2항에 있어서,3. The method of claim 2,
    상기 슬러지 감량장치는,The sludge reduction device,
    베이스프레임에 회전 가능하게 설치되는 구동축;a drive shaft rotatably installed on the base frame;
    상기 구동축에 회전 가능하게 접속되고 다수의 타공이 형성된 드럼;a drum rotatably connected to the drive shaft and having a plurality of perforations;
    상기 드럼을 회전시키는 회전력을 생성, 인가하도록 접속되는 드럼구동수단;a drum driving means connected to generate and apply a rotational force for rotating the drum;
    상기 드럼의 외부를 둘러싸도록 배치되고 배출구가 형성된 처리챔버; 및a processing chamber disposed to surround the outside of the drum and formed with an outlet; and
    상기 처리챔버에 설치되는 복수의 프라즈마방사전극, 상기 프라즈마방사전극을 고전압을 인가하는 프라즈마발생부를 구비한 프라즈마발생장치;를 포함하는 것을 특징으로 하는 염색 폐수 및 고농도 폐수 처리를 위한 시스템.A system for treating dyed wastewater and high-concentration wastewater, comprising a plurality of plasma radiation electrodes installed in the treatment chamber, and a plasma generator having a plasma generator for applying a high voltage to the plasma radiation electrodes.
  6. 제5항에 있어서,6. The method of claim 5,
    상기 드럼은 상기 구동축에 설치되어 회전되고 다수의 타공이 형성된 내부드럼과, 상기 내부드럼의 외부를 둘러싸도록 배치되고 다수의 타공이 형성된 외부드럼을 포함하고,The drum is installed on the drive shaft and rotates and includes an inner drum having a plurality of perforations, and an outer drum arranged to surround the outside of the inner drum and having a plurality of perforations,
    상기 드럼구동수단은 상기 구동축에 회전력을 생성, 인가하도록 접속되는 내부드럼구동수단과, 상기 외부드럼을 회전시키도록 접속되는 외부드럼구동수단을 포함하는 것을 특징으로 하는 염색 폐수 및 고농도 폐수 처리를 위한 시스템.The drum driving means includes an internal drum driving means connected to generate and apply a rotational force to the drive shaft, and an external drum driving means connected to rotate the external drum. system.
  7. 제6항에 있어서,7. The method of claim 6,
    상기 구동축은 상기 내부드럼의 일측 및 타측에 접속되는 제1 구동축과 제2 구동축으로 구성되되, 상기 제1 구동축 및 상기 제2 구동축 중에서 하나 이상은 내부에 슬러지이동로가 형성되어 상기 내부드럼의 내부로 슬러지를 공급하도록 중공파이프로 구성되고,The drive shaft includes a first drive shaft and a second drive shaft connected to one side and the other side of the inner drum, and at least one of the first drive shaft and the second drive shaft has a sludge movement path formed therein, so that the inner drum It is composed of a hollow pipe to supply sludge to the furnace,
    상기 중공파이프의 외부에 이동되는 슬러지에 자기력을 인가하도록 설치되는 자장발생부를 포함하는 것을 특징으로 하는 염색 폐수 및 고농도 폐수 처리를 위한 시스템.A system for treating dyed wastewater and high-concentration wastewater, characterized in that it includes a magnetic field generator installed to apply a magnetic force to the sludge moving outside of the hollow pipe.
  8. 제1항 내지 제7항 중 어느 한 항의 염색 폐수 및 고농도 폐수 처리를 위한 시스템을 이용한 염색 폐수 및 고농도 폐수 처리를 위한 방법에 있어서,The method for treating dyeing wastewater and high concentration wastewater using the system for treating dyeing wastewater and high concentration wastewater according to any one of claims 1 to 7,
    상기 침사/스크린조에 의해 유입되는 폐수 중에 포함된 고형물을 제거하는 스크린조 처리단계;a screen bath treatment step of removing the solids contained in the wastewater introduced by the sedimentation/screen bath;
    상기 침사/스크린조를 경유한 폐수의 유량을 상기 유량조정조에서 조정하는 유량조정조 처리단계;a flow rate adjustment tank processing step of adjusting the flow rate of wastewater passing through the sediment/screen tank in the flow rate adjustment tank;
    상기 유량조정조를 경유한 폐수를 상기 1차 전기분해장치에 의한 전기 화학적 처리 과정을 통해 OH라디컬의 산화력을 이용하여 오염물질 및 색도를 1차로 제거하는 1차전기분해단계;a primary electrolysis step of primarily removing contaminants and chromaticity by using the oxidizing power of OH radicals through the electrochemical treatment process of the wastewater passing through the flow control tank;
    상기 1차 전기분해장치를 경유하여 상기 가압부상조로 유입된 폐수를 상기 버블발생장치에 의해 생성된 버블과 접촉시켜 플록이 응집, 부상되도록 하는 가압부상조 처리단계;a pressurized flotation tank treatment step of contacting the wastewater introduced into the pressurized flotation tank via the primary electrolysis device with the bubbles generated by the bubble generator to agglomerate and float the flocs;
    상기 1차 전기분해장치를 경유한 폐수를 상기 무산소조에서 1 내지 9시간 동안 체류시키면서 폐수 중에 포함된 유기물을 이용하여 질산성질소를 탈질산화하여 질소와 유기물을 제거하는 무산소조 처리단계;an anoxic tank treatment step of removing nitrogen and organic matter by denitrifying nitrate nitrogen using organic matter contained in wastewater while retaining the wastewater passing through the primary electrolysis device in the anaerobic tank for 1 to 9 hours;
    상기 무산소조를 경유한 폐수를 상기 혐기조에 4 내지 8시간 동안 체류시키면서 잔류하는 유기물을 이용하여 잔여 탈질과 인 방출이 이루어지도록 하는 혐기조 처리단계;an anaerobic tank treatment step of maintaining the wastewater passing through the anaerobic tank in the anaerobic tank for 4 to 8 hours and using the remaining organic matter to perform residual denitrification and phosphorus release;
    상기 혐기조를 경유한 폐수를 상기 접촉폭기조에서 폭기시키면서 잔류하는 유기물에 미생물을 접촉, 성장시켜 미생물 플록을 형성하는 접촉폭기조 처리단계;a contact aeration tank treatment step of forming microbial flocs by contacting and growing microorganisms with organic matter remaining while aeration of wastewater passing through the anaerobic tank in the contact aeration tank;
    상기 접촉폭기조를 경유한 폐수를 상기 막분리조에서 질산화 및 미생물 분리가 일어나도록 하는 막분리조 처리단계;a membrane separation tank treatment step of nitrifying and separating microorganisms from the wastewater passing through the contact aeration tank in the membrane separation tank;
    상기 막분리조를 경유한 폐수를 상기 2차 전기분해장치에 의한 전기 화학적 처리 과정을 통해 OH라디컬의 산화력을 이용하여 오염물질 및 색도를 2차로 제거하는 수행하는 2차전기분해단계; A secondary electrolysis step of performing a secondary electrolysis step of removing contaminants and chromaticity by using the oxidizing power of OH radicals through the electrochemical treatment process by the secondary electrolysis device of the wastewater passing through the membrane separation tank;
    상기 2차 전기분해장치를 경유한 폐수를 상기 배수조에 수용하고 상등수를 방류시키는 배수조 처리단계; 및a sump treatment step of receiving the wastewater passing through the secondary electrolysis device in the sump and discharging the supernatant; and
    상기 접촉폭기조로부터 생성된 슬러지를 상기 슬러지처리부를 이용하여 농축, 감량 및 제거하는 슬러지 처리단계;를 포함하는 것을 특징으로 하는 염색 폐수 및 고농도 폐수 처리를 위한 방법.and a sludge treatment step of concentrating, reducing, and removing the sludge generated from the contact aeration tank using the sludge treatment unit.
  9. 제8항에 있어서,9. The method of claim 8,
    상기 접촉폭기조 처리단계는 상기 접촉폭기조에서 생성된 슬러지 일부를 상기 유량조정조 또는 상기 무산소조에 선택적으로 반송시키는 과정을 포함하고,The contact aeration tank treatment step includes a process of selectively returning a part of the sludge generated in the contact aeration tank to the flow rate control tank or the anoxic tank,
    상기 막분리조 처리단계는 상기 막분리조에서 생성된 슬러지 일부를 상기 1차 전기분해장치 또는 상기 무산소조에 선택적으로 반송시키는 과정을 포함하며,The membrane separation tank treatment step includes a process of selectively returning a portion of the sludge generated in the membrane separation tank to the primary electrolysis device or the anoxic tank,
    상기 슬러지 처리단계는 상기 접촉폭기조 처리단계에 의해 생성된 슬러지를 침전 과정을 통해 농축시키는 농축조 과정, 상기 농축 과정을 거친 슬러지를 물리적으로 감량하는 슬러지 감량과정, 및 상기 슬러지 감량과정을 거친 슬러지를 탈수하는 탈수과정을 포함하는 것을 특징으로 하는 염색 폐수 및 고농도 폐수 처리를 위한 방법.The sludge treatment step includes a thickening tank process for concentrating the sludge generated by the contact aeration tank treatment step through a settling process, a sludge reduction process for physically reducing the sludge that has undergone the concentration process, and dewatering the sludge that has undergone the sludge reduction process. A method for treating dyeing wastewater and high-concentration wastewater, characterized in that it comprises a dehydration process.
PCT/KR2021/001108 2021-01-26 2021-01-27 System for treating dye wastewater and high-concentration wastewater, and method therefor WO2022163880A1 (en)

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KR19990071074A (en) * 1998-02-27 1999-09-15 최규양 Wastewater Treatment Method Using Electrochemical Reaction and Electrochemical Reactor
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Publication number Priority date Publication date Assignee Title
KR19990000168A (en) * 1997-06-03 1999-01-15 이광열 Wastewater Treatment Method and Wastewater Treatment System Using Electrolysis
KR19990071074A (en) * 1998-02-27 1999-09-15 최규양 Wastewater Treatment Method Using Electrochemical Reaction and Electrochemical Reactor
JP2005144367A (en) * 2003-11-17 2005-06-09 Sanyo Electric Co Ltd Organic waste treatment system
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