WO2022077961A1 - Solid-state button battery - Google Patents

Solid-state button battery Download PDF

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Publication number
WO2022077961A1
WO2022077961A1 PCT/CN2021/104296 CN2021104296W WO2022077961A1 WO 2022077961 A1 WO2022077961 A1 WO 2022077961A1 CN 2021104296 W CN2021104296 W CN 2021104296W WO 2022077961 A1 WO2022077961 A1 WO 2022077961A1
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WO
WIPO (PCT)
Prior art keywords
casing
electrically connected
conductor
solid
hole
Prior art date
Application number
PCT/CN2021/104296
Other languages
French (fr)
Chinese (zh)
Inventor
陈志勇
Original Assignee
广东微电新能源有限公司
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Publication date
Application filed by 广东微电新能源有限公司 filed Critical 广东微电新能源有限公司
Publication of WO2022077961A1 publication Critical patent/WO2022077961A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/102Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
    • H01M50/109Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure of button or coin shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/54Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present invention relates to the technical field of button batteries, and more particularly, to a solid-state button battery.
  • the current button battery uses electrolyte as a conductive medium. Due to the liquid nature of the electrolyte, it is prone to problems such as insufficient safety of electrolyte leakage, combustion and even explosion.
  • An object of the present invention is to provide a solid state button battery.
  • a solid-state button battery includes a housing and a battery cell;
  • the casing includes a first casing, a second casing and an insulating member, at least one of the first casing and the second casing forms a groove structure, and the first casing and the second casing form a groove structure.
  • the two shells are snapped together to form an inner cavity, and the insulating member is arranged between the first shell and the second shell;
  • the battery core is arranged in the inner cavity, and the battery core includes positive electrode sheets and negative electrode sheets arranged alternately and stacked, and an isolation layer is arranged between the adjacent positive electrode sheets and the negative electrode sheets.
  • the surface of the sheet and the negative electrode sheet is provided with a solid electrolyte layer;
  • the negative electrode sheet is provided with a first conductor
  • the positive electrode sheet is provided with a second conductor
  • the first conductor is electrically connected to the first casing
  • the second conductor is electrically connected to the second casing.
  • the first conductor includes a first branch conductor disposed on the side wall of the negative electrode sheet, the first branch conductor is electrically connected to the first casing, and the second conductor includes a first branch conductor disposed on the side wall of the negative electrode sheet.
  • a second branch conductor on the side wall of the positive electrode sheet, the second branch conductor is electrically connected to the second casing.
  • first current collector is electrically connected to the first casing
  • second current collector is electrically connected to the second casing
  • the first current collector is provided with a first conductive portion, and the first conductive portion is electrically connected to the first branch conductor;
  • the second current collector is provided with a second conductive portion, and the second conductive portion is electrically connected to the second branch conductor.
  • the first current collector is opposite to the top of the cell, the first conductive portion is opposite to the side wall of the cell, the second current collector is opposite to the bottom of the cell, The second conductive portion is opposite to the sidewall of the cell.
  • it further includes a first insulating pad and a second insulating pad, the first insulating pad is located between the first housing and the battery core, and a first escape area is provided on the first insulating pad, The first branch conductor is electrically connected to the first casing through the first escape area, the second insulating pad is located between the second casing and the battery core, and the second insulating pad is located between the second casing and the battery core.
  • a second escape area is provided on the pad, and the second branch conductor passes through the second escape area and is electrically connected to the second shell.
  • the negative electrode plate is provided with a first through hole and a second through hole
  • the first conductor includes a first conductor layer disposed in the first through hole, and the first conductor layer is connected to the first through hole.
  • the first casing is electrically connected
  • the second through hole is provided with a first insulating layer;
  • the positive electrode plate is provided with a third through hole and a fourth through hole
  • the second conductor includes a second conductor layer disposed in the fourth through hole, the second conductor layer and the second shell electrical connection
  • the third through hole is provided with a second insulating layer
  • the first through hole is opposite to the third through hole to form a first channel
  • the second through hole is opposite to the fourth through hole to form a second channel
  • a first conductive column is provided in the first channel, the first conductive column is electrically connected to the first conductor layer, and the first conductive column is electrically connected to the first casing, so A second conductive column is arranged in the second channel, the second conductive column is electrically connected to the second conductor layer, and the second conductive column is electrically connected to the second casing.
  • the first conductive column extends out of the first channel to be electrically connected to the first casing
  • the second conductive column extends out of the second channel to be electrically connected to the second casing
  • it also includes a third insulating pad and a fourth insulating pad, the third insulating pad is located between the first housing and the battery core, and a third escape area is provided on the third insulating pad, The first conductive column is electrically connected to the first casing through the third escape area, the fourth insulating pad is located between the second casing and the battery core, and the fourth insulating pad A fourth escape area is provided on the pad, and the second conductive column passes through the fourth escape area and is electrically connected to the second shell.
  • the first casing includes a top plate and a first side wall, the first side wall is disposed around the top plate, the second casing includes a second side wall and a bottom plate, the second side wall The insulating member is disposed around the bottom plate, and the insulating member is disposed between the first side wall and the second side wall.
  • the solid-state button battery has a simple structure and is more secure.
  • FIG. 1 is a schematic structural diagram of a casing in a solid-state button battery according to an embodiment of the present disclosure.
  • FIG. 2 is one of the structural schematic diagrams of the cross-section of the solid-state button battery according to an embodiment of the present disclosure.
  • FIG. 3 is an enlarged view of A in FIG. 2 .
  • FIG. 4 is a schematic structural diagram of a cross-section of a solid-state button battery in an embodiment of the present disclosure.
  • FIG. 5 is a schematic structural diagram of a cross-section of a solid-state button battery in an embodiment of the present disclosure.
  • FIG. 6 is a schematic structural diagram of a cell in an embodiment of the present disclosure.
  • a solid-state button battery is provided, as shown in FIGS. 1-3 , the solid-state button battery includes a casing 1 and a battery cell 2 ;
  • the casing 1 includes a first casing 11, a second casing 12 and an insulating member 3. At least one of the first casing 11 and the second casing 12 forms a groove structure, and the first casing 11 and the second casing 12 form a groove structure.
  • the casing 11 and the second casing 12 are buckled to form an inner cavity 10 , and the insulating member 3 is arranged between the first casing 11 and the second casing 12 ;
  • the battery cell 2 is arranged in the inner cavity 10 , and the battery core 2 includes positive electrode sheets 22 and negative electrode sheets 21 arranged alternately and stacked, and the adjacent positive electrode sheets 22 and the negative electrode sheets 21 are arranged between the adjacent positive electrode sheets 22 and the negative electrode sheets 21 .
  • the negative electrode sheet 21 is provided with a first conductor
  • the positive electrode sheet 22 is provided with a second conductor
  • the first conductor is electrically connected to the first casing 11
  • the second conductor is connected to the second conductor.
  • the housing 12 is electrically connected.
  • the numbers of the positive electrode sheets 22 and the negative electrode sheets 21 in the battery cell 2 are set according to actual requirements.
  • the surfaces of the positive electrode sheet 22 and the negative electrode sheet 21 are coated with solid electrolyte to form a solid electrolyte layer, for example, the coated solid electrolyte may be a polymer solid electrolyte.
  • the polymer solid electrolyte can be polyethylene oxide (PEO), polyacrylonitrile (PAN), polyvinylidene fluoride (PVDF), polymethyl methacrylate (PMMA), polypropylene oxide (PPO), polyvinylidene fluoride (PVDF) Vinyl Chloride (PVDC).
  • the coated solid electrolyte may also be a sulfide electrolyte, an oxide electrolyte, or the like.
  • Each first conductor electrically connects the corresponding negative electrode sheet 21 with the first case 11
  • each second conductor electrically connects the corresponding positive electrode sheet 22 with the second case 12 , so that each of the cells 2 is electrically connected.
  • Each negative electrode piece 21 is connected to the first casing 11 to form the negative electrode of the solid state button battery
  • each positive electrode piece 22 is connected to the second housing 12 to form the positive electrode of the solid state button battery.
  • the structure of the solid-state button battery is simple, and the solid-state electrolyte can avoid problems such as electrolyte leakage, burning and even explosion of the button battery. Improves the safety of using button batteries.
  • the first conductor includes a first branch conductor 211 a disposed on the side wall of the negative electrode sheet 21 , and the first branch conductor 211 a is connected to the first branch conductor 211 a.
  • a casing 11 is electrically connected
  • the second conductor includes a second branch conductor 221 a disposed on the side wall of the positive electrode sheet 22 , and the second branch conductor 221 a is electrically connected to the second casing 12 .
  • the first branch conductor 211a drawn from the side wall of the negative electrode sheet 21 and the second branch conductor 221a drawn from the side wall of the positive electrode sheet 22 connect the cell 2 with the first case 11 and the second case Body 12 is turned on.
  • the first branch conductor 211a and the second branch conductor 221a do not occupy space on the thickness of the solid-state button battery, thereby reducing the thickness and size of the solid-state button battery, making the solid-state button battery more compact and lightweight.
  • the first branch conductor 211a and the second branch conductor 221a are both wires, the wires on the negative electrode sheet 21 are drawn out to be electrically connected to the first casing 11, and the wires on the positive electrode sheet 22 are drawn out and electrically connected to the second casing 12 connect. It can be that the wires on the pole pieces of the same polarity are electrically connected to the corresponding casing after being connected to each other, or that each wire on the pole piece is electrically connected to the corresponding casing respectively.
  • first branch conductor 211a and the second branch conductor 221a are both conductive parts, and the first branch conductor 211a on each negative electrode sheet 21 is electrically connected to the first casing 11 through the conductive parts.
  • the second branch conductor 221a on each positive electrode sheet 22 is electrically connected to the second casing 12 .
  • the solid-state button battery further includes a first current collector 41 and a second current collector 42 , and the first current collector 41 is electrically connected to the first casing 11 . , the second current collector 42 is electrically connected to the second casing 12;
  • the first current collector 41 is provided with a first conductive portion 411, and the first conductive portion 411 is electrically connected to the first branch conductor 211a;
  • the second current collector 42 is provided with a second conductive portion 421, and the second conductive portion 421 is electrically connected to the second branch conductor 221a.
  • the first current collector 41 is electrically connected to the first casing 11 , and the first branch conductor 211 a conducts with the first current collector 41 through the first conductive portion 411 , so that the first branch conductor 211 a and the first casing 11 are electrically connected. electrical connection structure.
  • the second current collector 42 is electrically connected to the second casing 42 , and the second branch conductor 221 a is electrically connected to the second current collector 42 through the second conductive portion 421 , so that the second branch conductor 221 a is electrically connected to the second casing 12 . electrical connection structure.
  • an electrical connection is formed between the first branch conductor 211a and the first housing 11 through the first current collector 41 and the first conductive portion 411, which can simplify the structure of the first branch conductor 211a and avoid multiple first branch conductors 211a.
  • a conductor 211a forms a complicated connection structure with the first casing 11 .
  • the second current collector 42 and the second conductive portion 411 form an electrical connection between the second branch conductor 221a and the second housing 12, which can simplify the structure of the second branch conductor 221a and avoid multiple second branch conductors 221a and the second branch conductor 221a.
  • the housing 12 forms a complex connection structure.
  • the first current collector 41 is opposite to the top of the battery core 2
  • the first conductive portion 411 is opposite to the side wall of the battery core 2
  • the second current collector 42 is opposite to the battery core 2
  • the bottom of the core 2 is opposite to each other
  • the second conductive portion 421 is opposite to the side wall of the battery core 2 .
  • the first conductive portion 411 conducts the first branch conductor 211 a located on the side wall of the cell 2 with the partial structure of the first casing 11 located on the top of the cell 2 through the first current collector 41 .
  • the second conductive portion 421 conducts the second branch conductor 221 a located on the side wall of the cell 2 with the partial structure of the second casing 12 located at the bottom of the cell 2 through the second current collector 42 .
  • the structure formed by the first current collector 41 and the first conductive portion 411 , and the structure formed by the second current collector 42 and the second conductive portion 421 occupy less space in the inner cavity 10 and save the space of the inner cavity 10 . volume of space.
  • the cross-sections of the first current collector 41 and the first conductive portion 411 are L-shaped structures, the first current collector 41 forms one side of the L-shaped structure, and the first conductive portion 411 forms the other side.
  • the structures of the first current collector 41 and the first conductive portion 411 can fit the structure of the cell 2 to reduce the space occupied.
  • the cross section of the second current collector 42 and the second conductive portion 421 is an L-shaped structure, the second current collector 42 forms one side of the L-shaped structure, and the second conductive portion 421 forms the other side. In this way, the structure of the second current collector 42 and the second conductive portion 421 can fit the structure of the cell 2 to reduce the space occupied.
  • the solid-state button battery further includes a first insulating pad 51 and a second insulating pad 52 , the first insulating pad 51 is located between the first housing 11 and the battery Between the cores 2, the first insulating pad 51 is provided with a first escape area, the first branch conductor 211a passes through the first escape area and is electrically connected to the first shell 11, and the second The insulating pad 52 is located between the second casing 12 and the battery cell 2 , a second escape area is provided on the second insulating pad 52 , and the second branch conductor 221 a passes through the second escape area It is electrically connected to the second housing 12 .
  • the first insulating pad 51 forms insulation between the battery cell 2 and the first casing 11 to prevent the first casing 11 and the positive electrode sheet 22 from being conductive and short-circuited, so that the first branch conductor on the negative electrode sheet 21 is not short-circuited.
  • 211a can be electrically connected with the first casing 11 to be electrically connected.
  • the second insulating pad 52 forms insulation between the battery cell 2 and the second casing 12 to prevent the second casing 12 and the negative electrode sheet 21 from being conductive and short-circuited, so that the second branch conductor 221a on the positive electrode sheet 22 can be connected to the second casing.
  • the body 12 conducts to form an electrical connection.
  • a part of the first insulating pad 51 is located on the top of the cell 2, and the other part is located on the side wall of the cell 2, respectively on the first current collector 41 and the first conductive part Insulation is formed between 411 and the cell 2 .
  • the first escape area is disposed on the part of the side wall of the cell 2 , so that the first branch conductor 211 a can pass through the first escape area and be electrically connected to the first conductive portion 411 .
  • the number and specific positions of the first avoidance areas are set corresponding to the first branch conductors 211a.
  • a part of the structure of the second insulating pad 52 is located at the bottom of the cell 2, and the other part is located at the side wall of the cell 2, respectively at the second current collector 42 and the second conductive part Insulation is formed between 421 and the cell 2 , and the second escape area is provided on the part of the side wall of the cell 2 , so that the second branch conductor 221 a can pass through the second escape area and be electrically connected to the second conductive portion 421 .
  • the number and specific positions of the second avoidance areas are set corresponding to the second branch conductors 221a.
  • the negative electrode sheet 21 is provided with a first through hole and a second through hole, and the first conductor includes a first through hole disposed in the first through hole.
  • a conductor layer 211b, the first conductor layer 211b is electrically connected to the first casing 11, and a first insulating layer 212 is provided in the second through hole;
  • the positive electrode sheet 22 is provided with a third through hole and a fourth through hole, the second conductor includes a second conductor layer 221b disposed in the fourth through hole, and the second conductor layer 221b is connected to the fourth through hole.
  • the two housings 12 are electrically connected, and the third through hole is provided with a second insulating layer 222;
  • the first through hole is opposite to the third through hole to form a first channel
  • the second through hole is opposite to the fourth through hole to form a second channel.
  • the first channel only the first conductor layer 211b is connected to the negative electrode sheet 21, and the third through hole on the positive electrode sheet 22 is provided with a second insulating layer 222 to form insulation.
  • the second channel can only conduct conduction with the positive electrode sheet 22 through the second conductor layer 221b, and a first insulating layer 212 is provided in the second through hole of the negative electrode sheet 21 to form insulation.
  • through holes are provided on the positive electrode sheet 22 and the negative electrode sheet 21, and a conductor layer is provided in the corresponding through hole, so that the conductor layer is connected to the corresponding casing.
  • the first channel is provided with a first conductive column 71, the first conductive column 71 is electrically connected to the first conductor layer 211b, and the first conductive column 71 is connected to the first casing 11 Electrical connection
  • the second channel is provided with a second conductive column 72, the second conductive column 72 is electrically connected to the second conductor layer 221b, and the second conductive column 72 is connected to the second shell 12 Electrical connections.
  • the first conductive pillars 71 can conduct electrical connection between all the first conductor layers 211b in the first channel and the first casing 11 , so that the electrical connection structure between the negative electrode sheet 21 and the first casing 11 is simpler.
  • the second conductive pillars 72 can conduct electrical connection between all the second conductor layers 221b in the second channel and the second casing 12 , so that the electrical connection structure between the positive electrode sheet 22 and the second casing 12 is simpler.
  • the first case 11 only needs to be electrically connected to the first conductive pillars 71 , and can be electrically connected to all the negative electrode sheets 21
  • the second case 12 only needs to be electrically connected to the second conductive pillars 72 , and can be electrically connected to all the positive electrode sheets 22 is on.
  • the first conductive post 71 protrudes from the first channel to be electrically connected to the first housing 11
  • the second conductive post 72 protrudes from the second channel and the second The housing 12 is electrically connected.
  • the extension of the first conductive column 71 from the first channel can make the electrical connection structure between the first conductive column 71 and the first casing 11 simpler, and no additional structure is required.
  • the second conductive column 72 extending out of the second channel makes the electrical connection structure between the second conductive column 72 and the second casing 12 simpler, and no additional structure is required.
  • the solid-state button battery further includes a third insulating pad 53 and a fourth insulating pad 54 , and the third insulating pad 53 is located between the first housing 11 and the battery cell. 2, the third insulating pad 53 is provided with a third escape area, the first conductive post 71 is electrically connected to the first housing 11 through the third escape area, and the fourth insulating The pad 54 is located between the second casing 12 and the battery core 2 , a fourth escape area is provided on the fourth insulating pad 54 , and the second conductive column 72 passes through the fourth escape area and The second housing 12 is electrically connected.
  • the third insulating pad 53 forms insulation between the battery cell 2 and the first casing 11 to avoid short circuit between the positive electrode sheet 22 of the battery cell 2 and the first casing 11 .
  • the third escape area prevents the third insulating pad 53 from affecting the electrical connection between the first conductive pillar 71 and the first casing 11 .
  • the fourth insulating pad 54 can prevent the negative electrode sheet 21 of the battery cell 2 from being short-circuited with the second casing 12 .
  • the fourth escape area prevents the fourth insulating pad 54 from affecting the electrical connection between the second conductive pillar 72 and the second casing 12 .
  • the direct electrical connection between the first conductive column 71 and the first casing 11 and the direct electrical connection between the second conductive column 72 and the second casing 12 can save the space of the inner cavity 10 .
  • a third current collector 43 is disposed between the third insulating pad 53 and the first casing 11 , and the first conductive column 71 forms an electrical connection with the first casing 11 through the third current collector 43 . connect.
  • a fourth current collector 44 is disposed between the fourth insulating pad 54 and the second casing 12 , and the second conductive column 72 is electrically connected to the second casing 12 through the fourth current collector 44 .
  • the provision of the third current collector 43 can increase the structural strength between the first conductive column 71 and the first casing 11 .
  • the fourth current collector 44 can increase the structural strength between the second conductive pillars 72 and the second casing 12 .
  • the first housing 11 includes a top plate 110 and a first side wall 111 , the first side wall 111 is disposed around the top plate 110 , and the second The housing 12 includes a second side wall 121 and a bottom plate 120 , the second side wall 121 is disposed around the bottom plate 120 , and the insulating member 3 is disposed between the first side wall 111 and the second side wall 121 . between.
  • the top plate 110 and the first side wall 111 are enclosed to form a groove structure of the first casing 11
  • the bottom plate 120 and the second side wall 121 are enclosed to form a groove structure of the second casing 12
  • the first The casing 11 and the second casing 12 are snapped together to form an inner cavity.
  • the negative electrode sheet 21 in the battery cell 2 is electrically connected to the top plate 110 through the first conductor, so that the top plate 110 has a negative polarity.
  • the positive electrode sheet 22 is electrically connected to the base plate 120 through the second conductor, so that the base plate 120 has a positive polarity.
  • a part of the structure on the top plate 110 is exposed to the outside of the casing 1 and can be electrically connected, and the negative electrode sheet 21 is electrically connected to the part of the structure, so that the part of the structure forms the negative electrode of the battery.
  • a part of the structure on the bottom plate 120 is exposed to the outside of the casing 1 and can be electrically connected, and the positive electrode sheet 22 is electrically connected to the part of the structure, so that the part of the structure forms the positive electrode of the battery.

Abstract

A solid-state button battery, the solid-state button battery comprising a housing (1) and a cell (2). The housing (1) comprises a first housing (11), a second housing (12) and an insulating member (3), wherein at least one of the first housing (11) and the second housing (12) is formed with a slot structure, and the first housing (11) is fastened to the second housing (12) to form an inner cavity (10); and the insulating member (3) is arranged between the first housing (11) and the second housing (12). The cell (2) is arranged in the inner cavity (10). The cell (2) comprises positive plates (22) and negative plates (21), which are alternately arranged in a stacked manner, wherein isolation layers (23) are arranged between the positive plates (22) and the negative plates (21), which are adjacent to each other; and surfaces of the positive plates (22) and the negative plates (21) are all provided with solid-state electrolyte layers. The negative plates (21) are provided with first conductors (211), and the positive plates (22) are provided with second conductors (221), wherein the first conductors (211) are electrically connected to the first housing (11), and the second conductors (221) are electrically connected to the second housing (12). The solid-state button battery has a simple structure and high safety.

Description

固态纽扣电池Solid state button battery 技术领域technical field
本发明涉及纽扣电池技术领域,更具体地,本发明涉及一种固态纽扣电池。The present invention relates to the technical field of button batteries, and more particularly, to a solid-state button battery.
背景技术Background technique
目前的纽扣电池采用电解液作为导电介质,由于电解液为液态的特性,容易出现电解液泄露、燃烧甚至爆炸等安全性不足的问题。The current button battery uses electrolyte as a conductive medium. Due to the liquid nature of the electrolyte, it is prone to problems such as insufficient safety of electrolyte leakage, combustion and even explosion.
发明内容SUMMARY OF THE INVENTION
本发明的一个目的是提供一种固态纽扣电池。An object of the present invention is to provide a solid state button battery.
根据本发明的一个方面,提供一种固态纽扣电池,该固态纽扣电池包括壳体和电芯;According to one aspect of the present invention, a solid-state button battery is provided, the solid-state button battery includes a housing and a battery cell;
所述壳体包括第一壳体、第二壳体和绝缘件,所述第一壳体与所述第二壳体中的至少一个形成凹槽结构,所述第一壳体与所述第二壳体扣合形成内腔,所述绝缘件设置在所述第一壳体与所述第二壳体之间;The casing includes a first casing, a second casing and an insulating member, at least one of the first casing and the second casing forms a groove structure, and the first casing and the second casing form a groove structure. The two shells are snapped together to form an inner cavity, and the insulating member is arranged between the first shell and the second shell;
所述电芯设置于所述内腔中,所述电芯包括交替且层叠设置的正极片和负极片,相邻的所述正极片与所述负极片之间设置有隔离层,所述正极片和所述负极片的表面均设有固态电解质层;The battery core is arranged in the inner cavity, and the battery core includes positive electrode sheets and negative electrode sheets arranged alternately and stacked, and an isolation layer is arranged between the adjacent positive electrode sheets and the negative electrode sheets. The surface of the sheet and the negative electrode sheet is provided with a solid electrolyte layer;
所述负极片上设有第一导体,所述正极片上设有第二导体,所述第一导体与所述第一壳体电连接,所述第二导体与所述第二壳体电连接。The negative electrode sheet is provided with a first conductor, the positive electrode sheet is provided with a second conductor, the first conductor is electrically connected to the first casing, and the second conductor is electrically connected to the second casing.
可选地,所述第一导体包括设置于所述负极片的侧壁上的第一支导体,所述第一支导体与所述第一壳体电连接,所述第二导体包括设置于所述正极片的侧壁上的第二支导体,所述第二支导体与所述第二壳体电连接。Optionally, the first conductor includes a first branch conductor disposed on the side wall of the negative electrode sheet, the first branch conductor is electrically connected to the first casing, and the second conductor includes a first branch conductor disposed on the side wall of the negative electrode sheet. A second branch conductor on the side wall of the positive electrode sheet, the second branch conductor is electrically connected to the second casing.
可选地,还包括第一集流体和第二集流体,所述第一集流体与所述第一壳体电连接,所述第二集流体与所述第二壳体电连接;Optionally, further comprising a first current collector and a second current collector, the first current collector is electrically connected to the first casing, and the second current collector is electrically connected to the second casing;
所述第一集流体设有第一导电部,所述第一导电部与所述第一支导体电连接;The first current collector is provided with a first conductive portion, and the first conductive portion is electrically connected to the first branch conductor;
所述第二集流体设有第二导电部,所述第二导电部与所述第二支导体电连接。The second current collector is provided with a second conductive portion, and the second conductive portion is electrically connected to the second branch conductor.
可选地,所述第一集流体与所述电芯的顶部相对,所述第一导电部与所述电芯的侧壁相对,所述第二集流体与所述电芯的底部相对,所述第二导电部与所述电芯的侧壁相对。Optionally, the first current collector is opposite to the top of the cell, the first conductive portion is opposite to the side wall of the cell, the second current collector is opposite to the bottom of the cell, The second conductive portion is opposite to the sidewall of the cell.
可选地,还包括第一绝缘垫和第二绝缘垫,所述第一绝缘垫位于所述第一壳体与所述电芯之间,所述第一绝缘垫上设有第一避让区,所述第一支导体穿过所述第一避让区与所述第一壳体电连接,所述第二绝缘垫位于所述第二壳体与所述电芯之间,所述第二绝缘垫上设有第二避让区,所述第二支导体穿过所述第二避让区与所述第二壳体电连接。Optionally, it further includes a first insulating pad and a second insulating pad, the first insulating pad is located between the first housing and the battery core, and a first escape area is provided on the first insulating pad, The first branch conductor is electrically connected to the first casing through the first escape area, the second insulating pad is located between the second casing and the battery core, and the second insulating pad is located between the second casing and the battery core. A second escape area is provided on the pad, and the second branch conductor passes through the second escape area and is electrically connected to the second shell.
可选地,所述负极片设有第一通孔和第二通孔,所述第一导体包括设置于所述第一通孔内的第一导体层,所述第一导体层与所述第一壳体电连接,所述第二通孔内设有第一绝缘层;Optionally, the negative electrode plate is provided with a first through hole and a second through hole, the first conductor includes a first conductor layer disposed in the first through hole, and the first conductor layer is connected to the first through hole. The first casing is electrically connected, and the second through hole is provided with a first insulating layer;
所述正极片设有第三通孔和第四通孔,所述第二导体包括设置于所述第四通孔内的第二导体层,所述第二导体层与所述第二壳体电连接,所述第三通孔内设有第二绝缘层;The positive electrode plate is provided with a third through hole and a fourth through hole, the second conductor includes a second conductor layer disposed in the fourth through hole, the second conductor layer and the second shell electrical connection, the third through hole is provided with a second insulating layer;
所述第一通孔与所述第三通孔相对,以形成第一通道,所述第二通孔与所述第四通孔相对,以形成第二通道。The first through hole is opposite to the third through hole to form a first channel, and the second through hole is opposite to the fourth through hole to form a second channel.
可选地,所述第一通道内设有第一导电柱,所述第一导电柱与所述第一导体层电连接,所述第一导电柱与所述第一壳体电连接,所述第二通道内设有第二导电柱,所述第二导电柱与所述第二导体层电连接,所述第二导电柱与所述第二壳体电连接。Optionally, a first conductive column is provided in the first channel, the first conductive column is electrically connected to the first conductor layer, and the first conductive column is electrically connected to the first casing, so A second conductive column is arranged in the second channel, the second conductive column is electrically connected to the second conductor layer, and the second conductive column is electrically connected to the second casing.
可选地,所述第一导电柱伸出所述第一通道与所述第一壳体电连接,所述第二导电柱伸出所述第二通道与所述第二壳体电连接。Optionally, the first conductive column extends out of the first channel to be electrically connected to the first casing, and the second conductive column extends out of the second channel to be electrically connected to the second casing.
可选地,还包括第三绝缘垫和第四绝缘垫,所述第三绝缘垫位于所述第一壳体与所述电芯之间,所述第三绝缘垫上设有第三避让区,所述第一导电柱穿过所述第三避让区与所述第一壳体电连接,所述第四绝缘垫位于 所述第二壳体与所述电芯之间,所述第四绝缘垫上设有第四避让区,所述第二导电柱穿过所述第四避让区与所述第二壳体电连接。Optionally, it also includes a third insulating pad and a fourth insulating pad, the third insulating pad is located between the first housing and the battery core, and a third escape area is provided on the third insulating pad, The first conductive column is electrically connected to the first casing through the third escape area, the fourth insulating pad is located between the second casing and the battery core, and the fourth insulating pad A fourth escape area is provided on the pad, and the second conductive column passes through the fourth escape area and is electrically connected to the second shell.
可选地,所述第一壳体包括顶板和第一侧壁,所述第一侧壁围绕所述顶板设置,所述第二壳体包括第二侧壁和底板,所述第二侧壁围绕所述底板设置,所述绝缘件设置于所述第一侧壁与所述第二侧壁之间。Optionally, the first casing includes a top plate and a first side wall, the first side wall is disposed around the top plate, the second casing includes a second side wall and a bottom plate, the second side wall The insulating member is disposed around the bottom plate, and the insulating member is disposed between the first side wall and the second side wall.
本发明的一个技术效果在于,该固态纽扣电池结构简单,更具安全性。One technical effect of the present invention is that the solid-state button battery has a simple structure and is more secure.
通过以下参照附图对本发明的示例性实施例的详细描述,本发明的其它特征及其优点将会变得清楚。Other features and advantages of the present invention will become apparent from the following detailed description of exemplary embodiments of the present invention with reference to the accompanying drawings.
附图说明Description of drawings
构成说明书的一部分的附图描述了本发明的实施例,并且连同说明书一起用于解释本发明的原理。The accompanying drawings, which form a part of the specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention.
图1是本公开一个实施例中固态纽扣电池中壳体的结构示意图。FIG. 1 is a schematic structural diagram of a casing in a solid-state button battery according to an embodiment of the present disclosure.
图2是本公开一个实施例中固态纽扣电池剖面的结构示意图之一。FIG. 2 is one of the structural schematic diagrams of the cross-section of the solid-state button battery according to an embodiment of the present disclosure.
图3是图2中A的放大图。FIG. 3 is an enlarged view of A in FIG. 2 .
图4是本公开一个实施例中固态纽扣电池剖面的结构示意图之一。FIG. 4 is a schematic structural diagram of a cross-section of a solid-state button battery in an embodiment of the present disclosure.
图5是本公开一个实施例中固态纽扣电池剖面的结构示意图之一。FIG. 5 is a schematic structural diagram of a cross-section of a solid-state button battery in an embodiment of the present disclosure.
图6是本公开一个实施例中电芯的结构示意图。FIG. 6 is a schematic structural diagram of a cell in an embodiment of the present disclosure.
附图标记说明:Description of reference numbers:
1-壳体,10-内腔,11-第一壳体,110-顶板,111-第一侧壁,12-第二壳体,120-底板,121-第二侧壁,2-电芯,21-负极片,211-第一导体,211a-第一支导体,211b-第一导体层,212-第一绝缘层,22-正极片,221-第二导体,221a-第二支导体,221b-第二导体层,222-第二绝缘层,23-隔离层,3-绝缘件,41-第一集流体,42-第二集流体,43-第三集流体,44-第四集流体,51-第一绝缘垫,52-第二绝缘垫,53-第三绝缘垫,54-第四绝缘垫,71-第一导电柱,72-第二导电柱。1-shell, 10-inner cavity, 11-first shell, 110-top plate, 111-first side wall, 12-second shell, 120-bottom plate, 121-second side wall, 2-cell , 21-negative electrode sheet, 211-first conductor, 211a-first branch conductor, 211b-first conductor layer, 212-first insulating layer, 22-positive electrode sheet, 221-second conductor, 221a-second branch conductor , 221b-second conductor layer, 222-second insulating layer, 23-isolation layer, 3-insulator, 41-first current collector, 42-second current collector, 43-third current collector, 44-fourth Current collector, 51-first insulating pad, 52-second insulating pad, 53-third insulating pad, 54-fourth insulating pad, 71-first conductive column, 72-second conductive column.
具体实施方式Detailed ways
现在将参照附图来详细描述本发明的各种示例性实施例。应注意到: 除非另外具体说明,否则在这些实施例中阐述的部件和步骤的相对布置、数字表达式和数值不限制本发明的范围。Various exemplary embodiments of the present invention will now be described in detail with reference to the accompanying drawings. It should be noted that the relative arrangement of components and steps, numerical expressions and numerical values set forth in these embodiments do not limit the scope of the invention unless specifically stated otherwise.
以下对至少一个示例性实施例的描述实际上仅仅是说明性的,决不作为对本发明及其应用或使用的任何限制。The following description of at least one exemplary embodiment is merely illustrative in nature and is in no way intended to limit the invention, its application, or uses.
对于相关领域普通技术人员已知的技术和设备可能不作详细讨论,但在适当情况下,所述技术和设备应当被视为说明书的一部分。Techniques and devices known to those of ordinary skill in the relevant art may not be discussed in detail, but where appropriate, such techniques and devices should be considered part of the specification.
在这里示出和讨论的所有例子中,任何具体值应被解释为仅仅是示例性的,而不是作为限制。因此,示例性实施例的其它例子可以具有不同的值。In all examples shown and discussed herein, any specific values should be construed as illustrative only and not limiting. Accordingly, other instances of the exemplary embodiment may have different values.
应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步讨论。It should be noted that like numerals and letters refer to like items in the following figures, so once an item is defined in one figure, it does not require further discussion in subsequent figures.
在本公开的一个实施例中,提供了一种固态纽扣电池,如图1-图3所示,该固态纽扣电池包括壳体1和电芯2;In an embodiment of the present disclosure, a solid-state button battery is provided, as shown in FIGS. 1-3 , the solid-state button battery includes a casing 1 and a battery cell 2 ;
所述壳体1包括第一壳体11、第二壳体12和绝缘件3,所述第一壳体11与所述第二壳体12中的至少一个形成凹槽结构,所述第一壳体11与所述第二壳体12扣合形成内腔10,所述绝缘件3设置在所述第一壳体11与所述第二壳体12之间;The casing 1 includes a first casing 11, a second casing 12 and an insulating member 3. At least one of the first casing 11 and the second casing 12 forms a groove structure, and the first casing 11 and the second casing 12 form a groove structure. The casing 11 and the second casing 12 are buckled to form an inner cavity 10 , and the insulating member 3 is arranged between the first casing 11 and the second casing 12 ;
所述电芯2设置于所述内腔10中,所述电芯2包括交替且层叠设置的正极片22和负极片21,相邻的所述正极片22与所述负极片21之间设置有隔离层23,所述正极片22和所述负极片21的表面均设有固态电解质层;The battery cell 2 is arranged in the inner cavity 10 , and the battery core 2 includes positive electrode sheets 22 and negative electrode sheets 21 arranged alternately and stacked, and the adjacent positive electrode sheets 22 and the negative electrode sheets 21 are arranged between the adjacent positive electrode sheets 22 and the negative electrode sheets 21 . There is an isolation layer 23, and the surfaces of the positive electrode sheet 22 and the negative electrode sheet 21 are provided with solid electrolyte layers;
所述负极片21上设有第一导体,所述正极片22上设有第二导体,所述第一导体与所述第一壳体11电连接,所述第二导体与所述第二壳体12电连接。The negative electrode sheet 21 is provided with a first conductor, the positive electrode sheet 22 is provided with a second conductor, the first conductor is electrically connected to the first casing 11 , and the second conductor is connected to the second conductor. The housing 12 is electrically connected.
电芯2中的正极片22和负极片21的数量根据实际需求设置。在正极片22和负极片21的表面均涂覆固态电解质,以形成固态电解质层,例如,涂覆的固态电解质可以是聚合物固态电解质。聚合物固态电解质可以是聚环氧乙烷(PEO)、聚丙烯腈(PAN)、聚偏氟乙烯(PVDF)、聚甲基丙烯酸甲酯 (PMMA)、聚环氧丙烷(PPO)、聚偏氯乙烯(PVDC)。涂覆的固态电解质还可以是硫化物电解质、氧化物电解质等。The numbers of the positive electrode sheets 22 and the negative electrode sheets 21 in the battery cell 2 are set according to actual requirements. The surfaces of the positive electrode sheet 22 and the negative electrode sheet 21 are coated with solid electrolyte to form a solid electrolyte layer, for example, the coated solid electrolyte may be a polymer solid electrolyte. The polymer solid electrolyte can be polyethylene oxide (PEO), polyacrylonitrile (PAN), polyvinylidene fluoride (PVDF), polymethyl methacrylate (PMMA), polypropylene oxide (PPO), polyvinylidene fluoride (PVDF) Vinyl Chloride (PVDC). The coated solid electrolyte may also be a sulfide electrolyte, an oxide electrolyte, or the like.
每个第一导体使对应的负极片21与第一壳体11形成电连接,每个第二导体使对应的正极片22与第二壳体12形成电连接,从而使电芯2中的每个负极片21与第一壳体11导通形成固态纽扣电池的负极,每个正极片22与第二壳体12导通形成固态纽扣电池的正极。Each first conductor electrically connects the corresponding negative electrode sheet 21 with the first case 11 , and each second conductor electrically connects the corresponding positive electrode sheet 22 with the second case 12 , so that each of the cells 2 is electrically connected. Each negative electrode piece 21 is connected to the first casing 11 to form the negative electrode of the solid state button battery, and each positive electrode piece 22 is connected to the second housing 12 to form the positive electrode of the solid state button battery.
在该实施例中,固态纽扣电池的结构简单,固态的电解质能够避免纽扣电池出现电解液泄露、燃烧甚至爆炸等问题。提高了使用纽扣电池的安全性。In this embodiment, the structure of the solid-state button battery is simple, and the solid-state electrolyte can avoid problems such as electrolyte leakage, burning and even explosion of the button battery. Improves the safety of using button batteries.
在一个实施例中,如图2,图3所示,所述第一导体包括设置于所述负极片21的侧壁上的第一支导体211a,所述第一支导体211a与所述第一壳体11电连接,所述第二导体包括设置于所述正极片22的侧壁上的第二支导体221a,所述第二支导体221a与所述第二壳体12电连接。In one embodiment, as shown in FIG. 2 and FIG. 3 , the first conductor includes a first branch conductor 211 a disposed on the side wall of the negative electrode sheet 21 , and the first branch conductor 211 a is connected to the first branch conductor 211 a. A casing 11 is electrically connected, the second conductor includes a second branch conductor 221 a disposed on the side wall of the positive electrode sheet 22 , and the second branch conductor 221 a is electrically connected to the second casing 12 .
在该实施例中,在负极片21的侧壁位置引出的第一支导体211a和正极片22的侧壁位置引出的第二支导体221a将电芯2与第一壳体11和第二壳体12导通。第一支导体211a和第二支导体221a不会占用固态纽扣电池厚度上的空间,减小了固态纽扣电池的厚度尺寸,使固态纽扣电池能够更加小巧轻便。In this embodiment, the first branch conductor 211a drawn from the side wall of the negative electrode sheet 21 and the second branch conductor 221a drawn from the side wall of the positive electrode sheet 22 connect the cell 2 with the first case 11 and the second case Body 12 is turned on. The first branch conductor 211a and the second branch conductor 221a do not occupy space on the thickness of the solid-state button battery, thereby reducing the thickness and size of the solid-state button battery, making the solid-state button battery more compact and lightweight.
例如,第一支导体211a和第二支导体221a均为导线,负极片21上的导线引出后与第一壳体11电连接,以及正极片22上的导线引出后与第二壳体12电连接。可以是相同极性的极片上的导线相互导通后与对应的壳体电连接,也可以是极片上每根导线分别与对应的壳体电连接。For example, the first branch conductor 211a and the second branch conductor 221a are both wires, the wires on the negative electrode sheet 21 are drawn out to be electrically connected to the first casing 11, and the wires on the positive electrode sheet 22 are drawn out and electrically connected to the second casing 12 connect. It can be that the wires on the pole pieces of the same polarity are electrically connected to the corresponding casing after being connected to each other, or that each wire on the pole piece is electrically connected to the corresponding casing respectively.
例如,第一支导体211a和第二支导体221a均为导电部件,通过导电部件将每个负极片21上的第一支导体211a与第一壳体11导通。将每个正极片22上的第二支导体221a与第二壳体12导通。For example, the first branch conductor 211a and the second branch conductor 221a are both conductive parts, and the first branch conductor 211a on each negative electrode sheet 21 is electrically connected to the first casing 11 through the conductive parts. The second branch conductor 221a on each positive electrode sheet 22 is electrically connected to the second casing 12 .
在一个实施例中,如图2,图3所示,该固态纽扣电池还包括第一集流体41和第二集流体42,所述第一集流体41与所述第一壳体11电连接,所述第二集流体42与所述第二壳体12电连接;In one embodiment, as shown in FIG. 2 and FIG. 3 , the solid-state button battery further includes a first current collector 41 and a second current collector 42 , and the first current collector 41 is electrically connected to the first casing 11 . , the second current collector 42 is electrically connected to the second casing 12;
所述第一集流体41设有第一导电部411,所述第一导电部411与所述 第一支导体211a电连接;The first current collector 41 is provided with a first conductive portion 411, and the first conductive portion 411 is electrically connected to the first branch conductor 211a;
所述第二集流体42设有第二导电部421,所述第二导电部421与所述第二支导体221a电连接。The second current collector 42 is provided with a second conductive portion 421, and the second conductive portion 421 is electrically connected to the second branch conductor 221a.
第一集流体41与第一壳体11电连接,第一支导体211a通过第一导电部411与第一集流体41导通,从而形成第一支导体211a与第一壳体11导通后的电连接结构。The first current collector 41 is electrically connected to the first casing 11 , and the first branch conductor 211 a conducts with the first current collector 41 through the first conductive portion 411 , so that the first branch conductor 211 a and the first casing 11 are electrically connected. electrical connection structure.
第二集流体42与第二壳体42电连接,第二支导体221a通过第二导电部421与第二集流体42导通,从而形成第二支导体221a与第二壳体12导通后的电连接结构。The second current collector 42 is electrically connected to the second casing 42 , and the second branch conductor 221 a is electrically connected to the second current collector 42 through the second conductive portion 421 , so that the second branch conductor 221 a is electrically connected to the second casing 12 . electrical connection structure.
在该实施例中,通过第一集流体41和第一导电部411在第一支导体211a与第一壳体11之间形成电连接,能够简化第一支导体211a的结构,避免多个第一支导体211a与第一壳体11形成复杂的连接结构。In this embodiment, an electrical connection is formed between the first branch conductor 211a and the first housing 11 through the first current collector 41 and the first conductive portion 411, which can simplify the structure of the first branch conductor 211a and avoid multiple first branch conductors 211a. A conductor 211a forms a complicated connection structure with the first casing 11 .
第二集流体42和第二导电部411在第二支导体221a与第二壳体12之间形成电连接,能够简化第二支导体221a的结构,避免多个第二支导体221a与第二壳体12形成复杂的连接结构。The second current collector 42 and the second conductive portion 411 form an electrical connection between the second branch conductor 221a and the second housing 12, which can simplify the structure of the second branch conductor 221a and avoid multiple second branch conductors 221a and the second branch conductor 221a. The housing 12 forms a complex connection structure.
可选地,所述第一集流体41与所述电芯2的顶部相对,所述第一导电部411与所述电芯2的侧壁相对,所述第二集流体42与所述电芯2的底部相对,所述第二导电部421与所述电芯2的侧壁相对。Optionally, the first current collector 41 is opposite to the top of the battery core 2 , the first conductive portion 411 is opposite to the side wall of the battery core 2 , and the second current collector 42 is opposite to the battery core 2 . The bottom of the core 2 is opposite to each other, and the second conductive portion 421 is opposite to the side wall of the battery core 2 .
第一导电部411通过第一集流体41将位于电芯2侧壁的第一支导体211a与位于电芯2顶部的第一壳体11的部分结构导通。第二导电部421通过第二集流体42将位于电芯2侧壁的第二支导体221a与位于电芯2底部的第二壳体12的部分结构导通。The first conductive portion 411 conducts the first branch conductor 211 a located on the side wall of the cell 2 with the partial structure of the first casing 11 located on the top of the cell 2 through the first current collector 41 . The second conductive portion 421 conducts the second branch conductor 221 a located on the side wall of the cell 2 with the partial structure of the second casing 12 located at the bottom of the cell 2 through the second current collector 42 .
在该例子中,第一集流体41和第一导电部411形成的结构,以及第二集流体42和第二导电部421形成的结构占用内腔10的空间更小,节省了内腔10的空间体积。In this example, the structure formed by the first current collector 41 and the first conductive portion 411 , and the structure formed by the second current collector 42 and the second conductive portion 421 occupy less space in the inner cavity 10 and save the space of the inner cavity 10 . volume of space.
例如,第一集流体41和第一导电部411的剖面呈L形结构,第一集流体41形成L形结构的一条边,第一导电部411形成另一条边。这样使第一集流体41和第一导电部411的结构能够贴合电芯2的结构,以减小占用的空间。For example, the cross-sections of the first current collector 41 and the first conductive portion 411 are L-shaped structures, the first current collector 41 forms one side of the L-shaped structure, and the first conductive portion 411 forms the other side. In this way, the structures of the first current collector 41 and the first conductive portion 411 can fit the structure of the cell 2 to reduce the space occupied.
第二集流体42与第二导电部421的剖面呈L型结构,第二集流体42形成L形结构的一条边,第二导电部421形成另一条边。这样使第二集流体42和第二导电部421的结构能够贴合电芯2的结构,以减小占用的空间。The cross section of the second current collector 42 and the second conductive portion 421 is an L-shaped structure, the second current collector 42 forms one side of the L-shaped structure, and the second conductive portion 421 forms the other side. In this way, the structure of the second current collector 42 and the second conductive portion 421 can fit the structure of the cell 2 to reduce the space occupied.
在一个实施例中,如图2中所示,该固态纽扣电池还包括第一绝缘垫51和第二绝缘垫52,所述第一绝缘垫51位于所述第一壳体11与所述电芯2之间,所述第一绝缘垫51上设有第一避让区,所述第一支导体211a穿过所述第一避让区与所述第一壳体11电连接,所述第二绝缘垫52位于所述第二壳体12与所述电芯2之间,所述第二绝缘垫52上设有第二避让区,所述第二支导体221a穿过所述第二避让区与所述第二壳体12电连接。In one embodiment, as shown in FIG. 2 , the solid-state button battery further includes a first insulating pad 51 and a second insulating pad 52 , the first insulating pad 51 is located between the first housing 11 and the battery Between the cores 2, the first insulating pad 51 is provided with a first escape area, the first branch conductor 211a passes through the first escape area and is electrically connected to the first shell 11, and the second The insulating pad 52 is located between the second casing 12 and the battery cell 2 , a second escape area is provided on the second insulating pad 52 , and the second branch conductor 221 a passes through the second escape area It is electrically connected to the second housing 12 .
在该实施例中,第一绝缘垫51在电芯2与第一壳体11之间形成绝缘,避免第一壳体11与正极片22导通短路,使负极片21上的第一支导体211a能够与第一壳体11导通形成电连接。第二绝缘垫52在电芯2与第二壳体12之间形成绝缘,避免第二壳体12与负极片21导通短路,使正极片22上的第二支导体221a能够与第二壳体12导通形成电连接。In this embodiment, the first insulating pad 51 forms insulation between the battery cell 2 and the first casing 11 to prevent the first casing 11 and the positive electrode sheet 22 from being conductive and short-circuited, so that the first branch conductor on the negative electrode sheet 21 is not short-circuited. 211a can be electrically connected with the first casing 11 to be electrically connected. The second insulating pad 52 forms insulation between the battery cell 2 and the second casing 12 to prevent the second casing 12 and the negative electrode sheet 21 from being conductive and short-circuited, so that the second branch conductor 221a on the positive electrode sheet 22 can be connected to the second casing. The body 12 conducts to form an electrical connection.
例如,在设置有第一集流体41的实施例中,第一绝缘垫51的一部分结构位于电芯2顶部,另一部分位于电芯2侧壁,分别在第一集流体41和第一导电部411与电芯2之间均形成绝缘。第一避让区设置在位于电芯2侧壁的部分,使第一支导体211a能够穿过第一避让区与第一导电部411电连接。第一避让区的数量和具体位置对应第一支导体211a设置。For example, in the embodiment provided with the first current collector 41, a part of the first insulating pad 51 is located on the top of the cell 2, and the other part is located on the side wall of the cell 2, respectively on the first current collector 41 and the first conductive part Insulation is formed between 411 and the cell 2 . The first escape area is disposed on the part of the side wall of the cell 2 , so that the first branch conductor 211 a can pass through the first escape area and be electrically connected to the first conductive portion 411 . The number and specific positions of the first avoidance areas are set corresponding to the first branch conductors 211a.
在设置有第二集流体42的实施例中,第二绝缘垫52的一部分结构位于电芯2的底部,另一部分位于电芯2的侧壁,分别在第二集流体42和第二导电部421与电芯2之间形成绝缘,第二避让区设置在位于电芯2侧壁的部分,使第二支导体221a能够穿过第二避让区与第二导电部421电连接。第二避让区的数量和具体位置对应第二支导体221a设置。In the embodiment provided with the second current collector 42, a part of the structure of the second insulating pad 52 is located at the bottom of the cell 2, and the other part is located at the side wall of the cell 2, respectively at the second current collector 42 and the second conductive part Insulation is formed between 421 and the cell 2 , and the second escape area is provided on the part of the side wall of the cell 2 , so that the second branch conductor 221 a can pass through the second escape area and be electrically connected to the second conductive portion 421 . The number and specific positions of the second avoidance areas are set corresponding to the second branch conductors 221a.
在一个实施例中,如图4-图6所示,所述负极片21设有第一通孔和第二通孔,所述第一导体包括设置于所述第一通孔内的第一导体层211b,所述第一导体层211b与所述第一壳体11电连接,所述第二通孔内设有第一绝缘层212;In one embodiment, as shown in FIGS. 4-6 , the negative electrode sheet 21 is provided with a first through hole and a second through hole, and the first conductor includes a first through hole disposed in the first through hole. A conductor layer 211b, the first conductor layer 211b is electrically connected to the first casing 11, and a first insulating layer 212 is provided in the second through hole;
所述正极片22设有第三通孔和第四通孔,所述第二导体包括设置于 所述第四通孔内的第二导体层221b,所述第二导体层221b与所述第二壳体12电连接,所述第三通孔内设有第二绝缘层222;The positive electrode sheet 22 is provided with a third through hole and a fourth through hole, the second conductor includes a second conductor layer 221b disposed in the fourth through hole, and the second conductor layer 221b is connected to the fourth through hole. The two housings 12 are electrically connected, and the third through hole is provided with a second insulating layer 222;
所述第一通孔与所述第三通孔相对,以形成第一通道,所述第二通孔与所述第四通孔相对,以形成第二通道。在第一通道内只能通过第一导体层211b与负极片21导通,正极片22上的第三通孔内设置有第二绝缘层222形成绝缘。第二通道内只能通过第二导体层221b与正极片22导通,负极片21的第二通孔内设置有第一绝缘层212形成绝缘。The first through hole is opposite to the third through hole to form a first channel, and the second through hole is opposite to the fourth through hole to form a second channel. In the first channel, only the first conductor layer 211b is connected to the negative electrode sheet 21, and the third through hole on the positive electrode sheet 22 is provided with a second insulating layer 222 to form insulation. The second channel can only conduct conduction with the positive electrode sheet 22 through the second conductor layer 221b, and a first insulating layer 212 is provided in the second through hole of the negative electrode sheet 21 to form insulation.
在该实施例中,通过在正极片22和负极片21上设置通孔,并在对应的通孔内设置导体层,使导体层与对应的壳体导通。这样不需要从电芯2的外部设置导通正极片22与第二壳体12的结构,以及不需要在电芯2外部设置导通负极片21与第一壳体12的结构,减小了固态纽扣电池内部的结构所占用的空间,能够减小固态纽扣电池的体积。In this embodiment, through holes are provided on the positive electrode sheet 22 and the negative electrode sheet 21, and a conductor layer is provided in the corresponding through hole, so that the conductor layer is connected to the corresponding casing. In this way, it is not necessary to provide a structure for conducting the positive electrode sheet 22 and the second casing 12 from the outside of the battery cell 2, and there is no need to provide a structure for conducting the negative electrode sheet 21 and the first casing 12 outside the battery cell 2, which reduces the need for The space occupied by the structure inside the solid-state button battery can reduce the volume of the solid-state button battery.
可选地,所述第一通道内设有第一导电柱71,所述第一导电柱71与所述第一导体层211b电连接,所述第一导电柱71与所述第一壳体11电连接,所述第二通道内设有第二导电柱72,所述第二导电柱72与所述第二导体层221b电连接,所述第二导电柱72与所述第二壳体12电连接。Optionally, the first channel is provided with a first conductive column 71, the first conductive column 71 is electrically connected to the first conductor layer 211b, and the first conductive column 71 is connected to the first casing 11 Electrical connection, the second channel is provided with a second conductive column 72, the second conductive column 72 is electrically connected to the second conductor layer 221b, and the second conductive column 72 is connected to the second shell 12 Electrical connections.
第一导电柱71能够将第一通道内的所有第一导体层211b与第一壳体11导通形成电连接,使负极片21与第一壳体11之间的电连接结构更加简单。第二导电柱72能够将第二通道内的所有第二导体层221b与第二壳体12导通形成电连接,使正极片22与第二壳体12之间的电连接结构更加简单。The first conductive pillars 71 can conduct electrical connection between all the first conductor layers 211b in the first channel and the first casing 11 , so that the electrical connection structure between the negative electrode sheet 21 and the first casing 11 is simpler. The second conductive pillars 72 can conduct electrical connection between all the second conductor layers 221b in the second channel and the second casing 12 , so that the electrical connection structure between the positive electrode sheet 22 and the second casing 12 is simpler.
例如,第一壳体11只需要与第一导电柱71电连接,既可与所有负极片21导通,第二壳体12只需要与第二导电柱72电连接,既可与所有正极片22导通。For example, the first case 11 only needs to be electrically connected to the first conductive pillars 71 , and can be electrically connected to all the negative electrode sheets 21 , and the second case 12 only needs to be electrically connected to the second conductive pillars 72 , and can be electrically connected to all the positive electrode sheets 22 is on.
在一个实施例中,所述第一导电柱71伸出所述第一通道与所述第一壳体11电连接,所述第二导电柱72伸出所述第二通道与所述第二壳体12电连接。In one embodiment, the first conductive post 71 protrudes from the first channel to be electrically connected to the first housing 11 , and the second conductive post 72 protrudes from the second channel and the second The housing 12 is electrically connected.
第一导电柱71伸出第一通道能够使第一导电柱71与第一壳体11间的电连接结构更加简单,不需要设置另外的结构。第二导电柱72伸出第二 通道使第二导电柱72与第二壳体12之间的电连接结构更加简单,不需要设置另外的结构。The extension of the first conductive column 71 from the first channel can make the electrical connection structure between the first conductive column 71 and the first casing 11 simpler, and no additional structure is required. The second conductive column 72 extending out of the second channel makes the electrical connection structure between the second conductive column 72 and the second casing 12 simpler, and no additional structure is required.
在一个实施例中,如图4所示,该固态纽扣电池还包括第三绝缘垫53和第四绝缘垫54,所述第三绝缘垫53位于所述第一壳体11与所述电芯2之间,所述第三绝缘垫53上设有第三避让区,所述第一导电柱71穿过所述第三避让区与所述第一壳体11电连接,所述第四绝缘垫54位于所述第二壳体12与所述电芯2之间,所述第四绝缘垫54上设有第四避让区,所述第二导电柱72穿过所述第四避让区与所述第二壳体12电连接。In one embodiment, as shown in FIG. 4 , the solid-state button battery further includes a third insulating pad 53 and a fourth insulating pad 54 , and the third insulating pad 53 is located between the first housing 11 and the battery cell. 2, the third insulating pad 53 is provided with a third escape area, the first conductive post 71 is electrically connected to the first housing 11 through the third escape area, and the fourth insulating The pad 54 is located between the second casing 12 and the battery core 2 , a fourth escape area is provided on the fourth insulating pad 54 , and the second conductive column 72 passes through the fourth escape area and The second housing 12 is electrically connected.
在该实施例中,第三绝缘垫53在电芯2与第一壳体11之间形成绝缘,避免电芯2的正极片22与第一壳体11短路。第三避让区使第三绝缘垫53不会影响第一导电柱71与第一壳体11的电连接。第四绝缘垫54能够避免电芯2的负极片21与第二壳体12短路。第四避让区使第四绝缘垫54不会影响第二导电柱72与第二壳体12的电连接。In this embodiment, the third insulating pad 53 forms insulation between the battery cell 2 and the first casing 11 to avoid short circuit between the positive electrode sheet 22 of the battery cell 2 and the first casing 11 . The third escape area prevents the third insulating pad 53 from affecting the electrical connection between the first conductive pillar 71 and the first casing 11 . The fourth insulating pad 54 can prevent the negative electrode sheet 21 of the battery cell 2 from being short-circuited with the second casing 12 . The fourth escape area prevents the fourth insulating pad 54 from affecting the electrical connection between the second conductive pillar 72 and the second casing 12 .
第一导电柱71与第一壳体11直接电连接以及第二导电柱72与第二壳体12直接电连接能够节省内腔10的空间。The direct electrical connection between the first conductive column 71 and the first casing 11 and the direct electrical connection between the second conductive column 72 and the second casing 12 can save the space of the inner cavity 10 .
可选地,如图5所示,第三绝缘垫53与第一壳体11之间设置有第三集流体43,第一导电柱71通过第三集流体43与第一壳体11形成电连接。第四绝缘垫54与第二壳体12之间设置有第四集流体44,第二导电柱72通过第四集流体44与第二壳体12形成电连接。Optionally, as shown in FIG. 5 , a third current collector 43 is disposed between the third insulating pad 53 and the first casing 11 , and the first conductive column 71 forms an electrical connection with the first casing 11 through the third current collector 43 . connect. A fourth current collector 44 is disposed between the fourth insulating pad 54 and the second casing 12 , and the second conductive column 72 is electrically connected to the second casing 12 through the fourth current collector 44 .
设置第三集流体43能够增加第一导电柱71与第一壳体11之间的结构强度。第四集流体44能够增加第二导电柱72与第二壳体12之间的结构强度。The provision of the third current collector 43 can increase the structural strength between the first conductive column 71 and the first casing 11 . The fourth current collector 44 can increase the structural strength between the second conductive pillars 72 and the second casing 12 .
在一个实施例中,如图2-图5所示,所述第一壳体11包括顶板110和第一侧壁111,所述第一侧壁111围绕所述顶板110设置,所述第二壳体12包括第二侧壁121和底板120,所述第二侧壁121围绕所述底板120设置,所述绝缘件3设置于所述第一侧壁111与所述第二侧壁121之间。In one embodiment, as shown in FIGS. 2-5 , the first housing 11 includes a top plate 110 and a first side wall 111 , the first side wall 111 is disposed around the top plate 110 , and the second The housing 12 includes a second side wall 121 and a bottom plate 120 , the second side wall 121 is disposed around the bottom plate 120 , and the insulating member 3 is disposed between the first side wall 111 and the second side wall 121 . between.
在该实施例中,顶板110与第一侧壁111围合形成第一壳体11的凹槽结构,底板120与第二侧壁121围合形成第二壳体12的凹槽结构,第一壳体11与第二壳体12扣合形成内腔。In this embodiment, the top plate 110 and the first side wall 111 are enclosed to form a groove structure of the first casing 11 , the bottom plate 120 and the second side wall 121 are enclosed to form a groove structure of the second casing 12 , the first The casing 11 and the second casing 12 are snapped together to form an inner cavity.
电芯2中的负极片21通过第一导体与顶板110电连接,使顶板110具有负极极性。正极片22通过第二导体与底板120电连接,使底板120具有正积极性。The negative electrode sheet 21 in the battery cell 2 is electrically connected to the top plate 110 through the first conductor, so that the top plate 110 has a negative polarity. The positive electrode sheet 22 is electrically connected to the base plate 120 through the second conductor, so that the base plate 120 has a positive polarity.
例如,顶板110上设置部分结构暴露于壳体1外部,且能够导通,负极片21与该部分结构电连接,使该部分结构形成电池的负极。底板120上设置部分结构暴露于壳体1外部,且能够导通,正极片22与该部分结构电连接,使该部分结构形成电池的正极。For example, a part of the structure on the top plate 110 is exposed to the outside of the casing 1 and can be electrically connected, and the negative electrode sheet 21 is electrically connected to the part of the structure, so that the part of the structure forms the negative electrode of the battery. A part of the structure on the bottom plate 120 is exposed to the outside of the casing 1 and can be electrically connected, and the positive electrode sheet 22 is electrically connected to the part of the structure, so that the part of the structure forms the positive electrode of the battery.
上文实施例中重点描述的是各个实施例之间的不同,各个实施例之间不同的优化特征只要不矛盾,均可以组合形成更优的实施例,考虑到行文简洁,在此则不再赘述。The above embodiments focus on the differences between the various embodiments. As long as the different optimization features between the various embodiments are not contradictory, they can be combined to form a better embodiment. Repeat.
虽然已经通过示例对本发明的一些特定实施例进行了详细说明,但是本领域的技术人员应该理解,以上示例仅是为了进行说明,而不是为了限制本发明的范围。本领域的技术人员应该理解,可在不脱离本发明的范围和精神的情况下,对以上实施例进行修改。本发明的范围由所附权利要求来限定。While some specific embodiments of the present invention have been described in detail by way of example, those skilled in the art will appreciate that the above examples are provided for illustration only and not for the purpose of limiting the scope of the invention. Those skilled in the art will appreciate that modifications may be made to the above embodiments without departing from the scope and spirit of the present invention. The scope of the invention is defined by the appended claims.

Claims (10)

  1. 一种固态纽扣电池,其特征在于,包括壳体和电芯;A solid-state button battery, characterized in that it includes a shell and a battery cell;
    所述壳体包括第一壳体、第二壳体和绝缘件,所述第一壳体与所述第二壳体中的至少一个形成凹槽结构,所述第一壳体与所述第二壳体扣合形成内腔,所述绝缘件设置在所述第一壳体与所述第二壳体之间;The casing includes a first casing, a second casing and an insulating member, at least one of the first casing and the second casing forms a groove structure, and the first casing and the second casing form a groove structure. The two shells are snapped together to form an inner cavity, and the insulating member is arranged between the first shell and the second shell;
    所述电芯设置于所述内腔中,所述电芯包括交替且层叠设置的正极片和负极片,相邻的所述正极片与所述负极片之间设置有隔离层,所述正极片和所述负极片的表面均设有固态电解质层;The battery core is arranged in the inner cavity, and the battery core includes positive electrode sheets and negative electrode sheets arranged alternately and stacked, and an isolation layer is arranged between the adjacent positive electrode sheets and the negative electrode sheets. The surface of the sheet and the negative electrode sheet is provided with a solid electrolyte layer;
    所述负极片上设有第一导体,所述正极片上设有第二导体,所述第一导体与所述第一壳体电连接,所述第二导体与所述第二壳体电连接。The negative electrode sheet is provided with a first conductor, the positive electrode sheet is provided with a second conductor, the first conductor is electrically connected to the first casing, and the second conductor is electrically connected to the second casing.
  2. 根据权利要求1所述的固态纽扣电池,其特征在于,所述第一导体包括设置于所述负极片的侧壁上的第一支导体,所述第一支导体与所述第一壳体电连接,所述第二导体包括设置于所述正极片的侧壁上的第二支导体,所述第二支导体与所述第二壳体电连接。The solid-state button battery according to claim 1, wherein the first conductor comprises a first branch conductor disposed on the side wall of the negative electrode sheet, and the first branch conductor is connected to the first shell. For electrical connection, the second conductor includes a second branch conductor disposed on the side wall of the positive electrode sheet, and the second branch conductor is electrically connected to the second casing.
  3. 根据权利要求1或2所述的固态纽扣电池,其特征在于,还包括第一集流体和第二集流体,所述第一集流体与所述第一壳体电连接,所述第二集流体与所述第二壳体电连接;The solid-state button battery according to claim 1 or 2, further comprising a first current collector and a second current collector, the first current collector is electrically connected to the first casing, and the second current collector is the fluid is electrically connected to the second housing;
    所述第一集流体设有第一导电部,所述第一导电部与所述第一支导体电连接;The first current collector is provided with a first conductive portion, and the first conductive portion is electrically connected to the first branch conductor;
    所述第二集流体设有第二导电部,所述第二导电部与所述第二支导体电连接。The second current collector is provided with a second conductive portion, and the second conductive portion is electrically connected to the second branch conductor.
  4. 根据权利要求1-3任意一项所述的固态纽扣电池,其特征在于,所述第一集流体与所述电芯的顶部相对,所述第一导电部与所述电芯的侧壁相对,所述第二集流体与所述电芯的底部相对,所述第二导电部与所述电芯的侧壁相对。The solid-state button battery according to any one of claims 1-3, wherein the first current collector is opposite to the top of the cell, and the first conductive portion is opposite to the side wall of the cell , the second current collector is opposite to the bottom of the battery core, and the second conductive portion is opposite to the side wall of the battery core.
  5. 根据权利要求1-4任意一项所述的固态纽扣电池,其特征在于,还包括第一绝缘垫和第二绝缘垫,所述第一绝缘垫位于所述第一壳体与所述电芯之间,所述第一绝缘垫上设有第一避让区,所述第一支导体穿过所述第一避让区与所述第一壳体电连接,所述第二绝缘垫位于所述第二壳体与所述电芯之间,所述第二绝缘垫上设有第二避让区,所述第二支导体穿过所述第二避让区与所述第二壳体电连接。The solid-state button battery according to any one of claims 1-4, further comprising a first insulating pad and a second insulating pad, wherein the first insulating pad is located between the first shell and the battery cell A first escape area is provided on the first insulating pad, the first branch conductor passes through the first escape area and is electrically connected to the first shell, and the second insulating pad is located in the first escape area. Between the two casings and the battery core, a second escape area is provided on the second insulating pad, and the second branch conductor passes through the second escape area and is electrically connected to the second casing.
  6. 根据权利要求1-5任意一项所述的固态纽扣电池,其特征在于,所述负极片设有第一通孔和第二通孔,所述第一导体包括设置于所述第一通孔内的第一导体层,所述第一导体层与所述第一壳体电连接,所述第二通孔内设有第一绝缘层;The solid-state button battery according to any one of claims 1-5, wherein the negative electrode plate is provided with a first through hole and a second through hole, and the first conductor comprises a first through hole provided in the first through hole. a first conductor layer inside, the first conductor layer is electrically connected with the first casing, and a first insulating layer is arranged in the second through hole;
    所述正极片设有第三通孔和第四通孔,所述第二导体包括设置于所述第四通孔内的第二导体层,所述第二导体层与所述第二壳体电连接,所述第三通孔内设有第二绝缘层;The positive electrode plate is provided with a third through hole and a fourth through hole, the second conductor includes a second conductor layer disposed in the fourth through hole, the second conductor layer and the second shell electrical connection, the third through hole is provided with a second insulating layer;
    所述第一通孔与所述第三通孔相对,以形成第一通道,所述第二通孔与所述第四通孔相对,以形成第二通道。The first through hole is opposite to the third through hole to form a first channel, and the second through hole is opposite to the fourth through hole to form a second channel.
  7. 根据权利要求1-6任意一项所述的固态纽扣电池,其特征在于,所述第一通道内设有第一导电柱,所述第一导电柱与所述第一导体层电连接,所述第一导电柱与所述第一壳体电连接,所述第二通道内设有第二导电柱,所述第二导电柱与所述第二导体层电连接,所述第二导电柱与所述第二壳体电连接。The solid-state button battery according to any one of claims 1-6, wherein a first conductive column is provided in the first channel, and the first conductive column is electrically connected to the first conductor layer, so The first conductive column is electrically connected to the first shell, the second channel is provided with a second conductive column, the second conductive column is electrically connected to the second conductor layer, and the second conductive column is is electrically connected to the second housing.
  8. 根据权利要求1-7任意一项所述的固态纽扣电池,其特征在于,所述第一导电柱伸出所述第一通道与所述第一壳体电连接,所述第二导电柱伸出所述第二通道与所述第二壳体电连接。The solid-state button battery according to any one of claims 1-7, wherein the first conductive column extends out of the first channel and is electrically connected to the first casing, and the second conductive column extends The second channel is electrically connected to the second casing.
  9. 根据权利要求1-8任意一项所述的固态纽扣电池,其特征在于,还 包括第三绝缘垫和第四绝缘垫,所述第三绝缘垫位于所述第一壳体与所述电芯之间,所述第三绝缘垫上设有第三避让区,所述第一导电柱穿过所述第三避让区与所述第一壳体电连接,所述第四绝缘垫位于所述第二壳体与所述电芯之间,所述第四绝缘垫上设有第四避让区,所述第二导电柱穿过所述第四避让区与所述第二壳体电连接。The solid-state button battery according to any one of claims 1-8, further comprising a third insulating pad and a fourth insulating pad, wherein the third insulating pad is located between the first shell and the battery cell In between, a third escape area is provided on the third insulating pad, the first conductive column passes through the third escape area and is electrically connected to the first shell, and the fourth insulating pad is located in the third escape area. Between the two casings and the battery core, a fourth escape area is provided on the fourth insulating pad, and the second conductive column passes through the fourth escape area and is electrically connected to the second casing.
  10. 根据权利要求1-9任意一项所述的固态纽扣电池,其特征在于,所述第一壳体包括顶板和第一侧壁,所述第一侧壁围绕所述顶板设置,所述第二壳体包括第二侧壁和底板,所述第二侧壁围绕所述底板设置,所述绝缘件设置于所述第一侧壁与所述第二侧壁之间。The solid-state button battery according to any one of claims 1-9, wherein the first casing comprises a top plate and a first side wall, the first side wall is disposed around the top plate, and the second The housing includes a second side wall and a bottom plate, the second side wall is arranged around the bottom plate, and the insulating member is arranged between the first side wall and the second side wall.
PCT/CN2021/104296 2020-10-12 2021-07-02 Solid-state button battery WO2022077961A1 (en)

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Publication number Priority date Publication date Assignee Title
CN213242676U (en) * 2020-10-12 2021-05-18 广东微电新能源有限公司 Solid button cell
KR20230136787A (en) * 2022-03-17 2023-09-27 삼성에스디아이 주식회사 All solid secondary battery and module of the same

Citations (5)

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US3597282A (en) * 1969-07-09 1971-08-03 Gulton Ind Inc Rechargeable sealed secondary battery of the button type
CN1577940A (en) * 2003-07-23 2005-02-09 松下电器产业株式会社 Coin-shaped all solid battery
CN110752401A (en) * 2019-09-30 2020-02-04 重庆市紫建电子有限公司 Button cell and manufacturing method thereof
CN111525072A (en) * 2020-05-28 2020-08-11 瑞声科技(南京)有限公司 Button cell
CN213242676U (en) * 2020-10-12 2021-05-18 广东微电新能源有限公司 Solid button cell

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3597282A (en) * 1969-07-09 1971-08-03 Gulton Ind Inc Rechargeable sealed secondary battery of the button type
CN1577940A (en) * 2003-07-23 2005-02-09 松下电器产业株式会社 Coin-shaped all solid battery
CN110752401A (en) * 2019-09-30 2020-02-04 重庆市紫建电子有限公司 Button cell and manufacturing method thereof
CN111525072A (en) * 2020-05-28 2020-08-11 瑞声科技(南京)有限公司 Button cell
CN213242676U (en) * 2020-10-12 2021-05-18 广东微电新能源有限公司 Solid button cell

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