WO2022061958A1 - 一种油泥无害化、资源化集成处理方法和系统 - Google Patents

一种油泥无害化、资源化集成处理方法和系统 Download PDF

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Publication number
WO2022061958A1
WO2022061958A1 PCT/CN2020/119426 CN2020119426W WO2022061958A1 WO 2022061958 A1 WO2022061958 A1 WO 2022061958A1 CN 2020119426 W CN2020119426 W CN 2020119426W WO 2022061958 A1 WO2022061958 A1 WO 2022061958A1
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Prior art keywords
sludge
oil
pyrolysis
hot water
waste heat
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English (en)
French (fr)
Inventor
刘志永
陈星星
易柏军
张文志
夏斌
余怀德
胡华利
孙碧玉
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Aerospace Kaitian Environmental Technology Co Ltd
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Aerospace Kaitian Environmental Technology Co Ltd
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/10—Treatment of sludge; Devices therefor by pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/10—Energy recovery
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/40—Valorisation of by-products of wastewater, sewage or sludge processing

Definitions

  • the invention belongs to the technical field of hazardous waste treatment, and in particular relates to an integrated treatment method and system for the innocence and resource utilization of oil sludge.
  • Oily sludge is listed in the "National Hazardous Waste List” (2016 Ministry of Environmental Protection Order No. 39) H08 hazardous waste , the reason is that this type of sludge contains various teratogenic and carcinogenic toxic substances”, such as benzene series, phenol, onion, energy, etc. The reduction, harmlessness and resource treatment of oily sludge is imminent. In terms of domestic technology research, there are fewer cases of successful introduction of foreign technology.
  • oily sludge treatment technologies include conditioning-mechanical dehydration process, heat treatment process (chemical hot washing, incineration, thermal desorption), biological Treatment methods (land tillage, composting, bioreactor), solvent extraction technology and comprehensive utilization of oily sludge, etc.
  • heat treatment process chemical hot washing, incineration, thermal desorption
  • biological Treatment methods land tillage, composting, bioreactor
  • solvent extraction technology comprehensive utilization of oily sludge, etc.
  • industry such as Canada MG Engineering Company, the mechanical dehydration process is used with its own proprietary medicament, the Dutch Gifos Company adopts the conditioning-mechanical dehydration + biological treatment method, and the German HILLER company adopts the conditioning-mechanical dehydration; Singapore
  • CLEANSEAS company adopts the process of mechanical dehydration + American ADTU thermal desorption.
  • the mainstream oil sludge treatment processes used in domestic oil fields are pyrolysis, incineration and thermal washing to treat oily sludge.
  • Hot-washing treatment of oily sludge can only be used for resource utilization. It has poor adaptability to raw materials and does not meet the pollutant discharge standards.
  • the incineration method has the advantages of maximum reduction, harmlessness, and strong adaptability to raw materials, it also has the advantages of There are disadvantages of high energy consumption, high equipment investment, and high technological requirements, and the crude oil in the sludge cannot be recovered, resulting in waste of resources.
  • the pyrolysis method can recover most of the crude oil by indirect pyrolysis at 500°C-600°C, the oil content in the treated sludge is still high, which cannot meet the current national emission standards. Condensate gas emissions do not meet the latest emission standards.
  • the purpose of the present invention is to provide an integrated treatment method and system for the innocence and resource utilization of oil sludge, so as to reduce the cost of oil sludge treatment and realize the innocuous, resourceful and integrated treatment of oil sludge.
  • the present invention solves the above problems through the following technical means.
  • a harmless and resourceful integrated treatment method for oil sludge comprising the following steps.
  • S1 classify and store the sludge to be treated.
  • step S3 Perform primary mechanical extrusion separation on the oily sludge after hot water rinsing and crushing. After extrusion and dehydration, the sludge is returned to step S1 for temporary storage, and the sludge-containing oily water separated by the primary mechanical extrusion is heated and added to medicament, stirring, and then centrifugation again, the water separated by centrifugation is used for the hot water rinsing in step S2, the oil separated by centrifugation is temporarily stored in the oil storage tank, and the sludge separated by centrifugation is returned to step S1 and the initial mechanical extrusion The sludge separated by pressure is temporarily stored in the same area.
  • step S4 granulating and drying the sludge separated twice, and performing pyrolysis and incineration treatment on the sludge particles after the granulation and drying; after the steam generated due to the evaporation of the sludge during the drying process is condensed into water, it is used for the processing in step S2. Hot water leaching; waste gas generated during drying is used as combustion air for pyrolysis incineration.
  • waste heat generated by the pyrolysis incineration treatment is recycled and utilized by the waste heat boiler.
  • a part of the steam generated by the waste heat boiler is used for steam power generation, a part is used for heating and heating with hot water sprayed in step S2, and a part is used for granulation in step S4. Dry heating, granulation and drying use indirect heat exchange, and steam condensate water is returned to the waste heat boiler for recycling.
  • the pyrolysis temperature is 700-850°C
  • the pyrolysis is carried out in a reducing atmosphere
  • the reducing atmosphere controls the excess air coefficient to be 0.5-0.75
  • the slag generated by the pyrolysis is cooled and then transported out for comprehensive utilization.
  • the combustible gas produced by pyrolysis enters the secondary combustion chamber with the flue gas for secondary combustion, and the secondary combustion heats up to 1100-1200 °C.
  • the waste heat of the secondary combustion flue gas is recycled by the waste heat boiler.
  • step S2 the water temperature of the hot water rinsing is 80-90° C., and the mass ratio of the sprayed hot water to the sludge is 1:1-2:1.
  • step S3 during centrifugation again, the temperature of the muddy oily water is heated to 85-95°C.
  • An integrated treatment system for harmless and resourceful sludge including an integrated sludge storage tank for sludge storage, an sludge grab crane for grabbing and delivering sludge to various processing equipment, a crusher for sludge crushing, Hot water spraying device for hot water spraying of crushed sludge, slag remover for primary mechanical extrusion separation, sludge buffer pool for temporary storage of initially separated sludge-containing oily water, The quenching and tempering heating tank for heating the separated muddy oily water, the three-phase centrifugal separator for re-centrifugation, the oil storage tank for storing the oil that is re-centrifuged, the Sludge granulation and drying machine for granulation and drying of sludge, condenser for condensing waste gas carrying water vapor produced by evaporation of sludge during granulation and drying process, for pyrolysis and incineration of dried sludge particles Treated pyrolysis incineration equipment
  • the integrated sludge storage tank is divided into a plurality of sludge storage chambers by partition walls, a pretreatment sludge tank for storing the sludge produced by the two separations, and a drying tank for storing the granulated and dried sludge particles. Sludge pool.
  • the pyrolysis incineration equipment includes a rotary kiln and a secondary combustion chamber.
  • the slag remover is equipped with a sludge extrusion dehydration mechanism and a sludge-containing oil-water overflow mechanism.
  • rotary kiln and the secondary combustion chamber are equipped with auxiliary combustion boosters.
  • the invention discloses an integrated treatment method and system for oil sludge harmlessness and resource utilization.
  • the treatment method includes oil sludge crushing and spray hot washing, primary mechanical extrusion separation, re-centrifugation, sludge granulation and drying, drying
  • the process steps of pyrolysis incineration and waste heat recovery and utilization of oil sludge particles, the treatment system includes various treatment equipments suitable for the process steps.
  • various oilfield wastes can be centrally treated on a large scale, and the crude oil recovery rate can reach more than 85%; all the wastewater generated by the sludge treatment is recycled, and the wastewater is zero-discharged; the sludge particles are deficient in the reducing atmosphere.
  • Oxygen pyrolysis and slag discharge can be used for comprehensive utilization of building materials.
  • the waste heat of pyrolysis and incineration can be used to produce steam for power generation and system heating. The whole process not only reduces the cost of sludge treatment, but also realizes the harmless and resourceful use of sludge. and scale processing.
  • the integrated processing method and system can receive and process various oily wastes, including: landing oily sludge, clearing oily sludge, oily sludge generated by the existing resource treatment process, oily sludge collection and transportation packaging, oilfield operation labor protection supplies, etc. ; It can realize large-scale centralized disposal of sludge; it can save construction investment, reduce floor space, save energy consumption, reduce treatment costs, improve clean production, and reduce pollutant emissions.
  • the second is: the crude oil recovery rate of the integrated treatment method and system reaches more than 85%; the waste water generated by the sludge treatment is all recycled, and the waste water is zero discharged; the sludge particles are pyrolyzed under anoxic conditions above 700°C in a reducing atmosphere, and the slag is discharged. It is brick red, its oil content is below 1 ⁇ , and the reduction rate on hot ignition is less than 5%, which meets the requirements of the latest national and industry emission standards, and the slag discharge can be comprehensively used in building materials production.
  • the third is: the high-temperature flue gas generated by pyrolysis and incineration is used for steam production in waste heat boilers. Except for part of it is used for process production and heating and heating, most of it is used for power generation.
  • the fourth is: the flue gas produced by pyrolysis incineration is purified, and the emission concentration of flue gas pollutants meets the requirements of the "Pollution Control Standards for Hazardous Waste Incineration" (the second draft for comments replaces GB18484-2001).
  • FIG. 1 is a schematic diagram of system connection according to an embodiment of the present invention.
  • This embodiment provides an integrated treatment method for oil sludge that is harmless and resourceful, including the following steps.
  • S1 classify and store the sludge to be treated.
  • step S3 Perform primary mechanical extrusion separation on the oily sludge after hot water rinsing and crushing, return the initially separated sludge to step S1 for temporary storage after extrusion and dehydration, and heat the sludge-containing oily water separated by the initial mechanical extrusion to 85 °C, add chemicals, stir, and then perform centrifugation again, the water separated by centrifugation is used for hot water rinsing in step S2, the oil separated by centrifugation is temporarily stored in the oil storage tank, and the sludge separated by centrifugation is returned to step S1 It is temporarily stored in the same area as the sludge separated by the initial mechanical extrusion.
  • step S4 granulating and drying the sludge separated twice, and performing pyrolysis and incineration treatment on the sludge particles after the granulation and drying; after the steam generated due to the evaporation of the sludge during the drying process is condensed into water, it is used for the processing in step S2.
  • Hot water leaching the waste gas generated during the drying process is used as combustion-supporting air for pyrolysis incineration; the pyrolysis temperature is 700 °C, and the pyrolysis is carried out in a reducing atmosphere.
  • the reducing atmosphere controls the excess air coefficient to be 0.5, and the pyrolysis After the slag is cooled, it is transported to the outside for comprehensive utilization.
  • the combustible gas generated by pyrolysis enters the secondary combustion chamber with the flue gas for secondary combustion, and the secondary combustion heats up to 1100 °C.
  • the excess air coefficient is controlled at 1.4, and the waste heat of the secondary combustion flue gas is recycled and utilized by the waste heat boiler.
  • waste heat generated by the pyrolysis incineration treatment is recycled and utilized by the waste heat boiler.
  • a part of the steam generated by the waste heat boiler is used for steam power generation, a part is used for heating and heating with hot water sprayed in step S2, and a part is used for granulation in step S4. Dry heating, granulation and drying use indirect heat exchange, and steam condensate water is returned to the waste heat boiler for recycling.
  • This embodiment provides an integrated treatment method for oil sludge that is harmless and resourceful, including the following steps.
  • S1 classify and store the sludge to be treated.
  • step S3 Perform primary mechanical extrusion separation on the oily sludge after hot water rinsing and crushing, return to step S1 for temporary storage after extrusion and dehydration, and heat the sludge-containing oily water separated by the primary mechanical extrusion to 90 °C °C, add chemicals, stir, and then perform centrifugation again, the water separated by centrifugation is used for hot water rinsing in step S2, the oil separated by centrifugation is temporarily stored in the oil storage tank, and the sludge separated by centrifugation is returned to step S1 It is temporarily stored in the same area as the sludge separated by the initial mechanical extrusion.
  • step S4 granulating and drying the sludge separated twice, and performing pyrolysis and incineration treatment on the sludge particles after the granulation and drying; after the steam generated due to the evaporation of the sludge during the drying process is condensed into water, it is used for the processing in step S2.
  • Hot water leaching the waste gas generated during the drying process is used as combustion-supporting air for pyrolysis incineration; the pyrolysis temperature is 800 °C, and the pyrolysis is carried out in a reducing atmosphere.
  • the reducing atmosphere controls the excess air coefficient at 0.6, and the pyrolysis produces After the slag is cooled, it is transported to the outside for comprehensive utilization.
  • the combustible gas generated by pyrolysis enters the secondary combustion chamber with the flue gas for secondary combustion, and the secondary combustion heats up to 1150 °C.
  • the excess air coefficient is controlled at 1.45, and the waste heat of the secondary combustion flue gas is recycled and utilized by the waste heat boiler.
  • waste heat generated by the pyrolysis incineration treatment is recycled and utilized by the waste heat boiler.
  • a part of the steam generated by the waste heat boiler is used for steam power generation, a part is used for heating and heating with hot water sprayed in step S2, and a part is used for granulation in step S4. Dry heating, granulation and drying use indirect heat exchange, and steam condensate water is returned to the waste heat boiler for recycling.
  • This embodiment provides an integrated treatment method for oil sludge that is harmless and resourceful, including the following steps.
  • S1 classify and store the sludge to be treated.
  • step S3 Perform primary mechanical extrusion separation on the oily sludge after hot water rinsing and crushing, return the initially separated sludge to step S1 for temporary storage after extrusion and dehydration, and heat the muddy oily water separated by the primary mechanical extrusion to 95 °C, add chemicals, stir, and then perform centrifugation again, the water separated by centrifugation is used for hot water rinsing in step S2, the oil separated by centrifugation is temporarily stored in the oil storage tank, and the sludge separated by centrifugation is returned to step S1 It is temporarily stored in the same area as the sludge separated by the initial mechanical extrusion.
  • step S4 granulating and drying the sludge separated twice, and performing pyrolysis and incineration treatment on the sludge particles after the granulation and drying; after the steam generated due to the evaporation of the sludge during the drying process is condensed into water, it is used for the processing in step S2.
  • Hot water leaching the waste gas generated during the drying process is used as combustion-supporting air for pyrolysis incineration; the pyrolysis temperature is 850 °C, and the pyrolysis is carried out in a reducing atmosphere.
  • the reducing atmosphere controls the excess air coefficient at 0.75, and the pyrolysis produces After the slag is cooled, it is transported to the outside for comprehensive utilization.
  • the combustible gas generated by pyrolysis enters the secondary combustion chamber with the flue gas for secondary combustion, and the secondary combustion heats up to 1200 °C.
  • the excess air coefficient is controlled at 1.5, and the waste heat of the secondary combustion flue gas is recycled and utilized by the waste heat boiler.
  • waste heat generated by the pyrolysis incineration treatment is recycled and utilized by the waste heat boiler.
  • a part of the steam generated by the waste heat boiler is used for steam power generation, a part is used for heating and heating with hot water sprayed in step S2, and a part is used for granulation in step S4. Dry heating, granulation and drying use indirect heat exchange, and steam condensate water is returned to the waste heat boiler for recycling.
  • this embodiment provides an integrated treatment system for oil sludge harmlessness and resource utilization, including an oil sludge comprehensive storage tank 1 for oil sludge storage, and oil sludge for grabbing and sending oil sludge to various processing equipment.
  • the integrated sludge storage tank 1 is divided into a plurality of sludge storage chambers by partition walls, a pretreated sludge tank for storing sludge that is separated from oil and water again, and a drying sludge tank for storing sludge particles.
  • the hot water spray device includes a hot water tank 8 and a spray device with a hot water nozzle connected to the hot water tank, and the hot water nozzle is arranged above the crushing cavity of the crusher.
  • a heating coil is arranged on the outside of the quenching and tempering heating tank 6, and the quenching and tempering heating tank is equipped with a stirring mechanism.
  • the pyrolysis incineration equipment 12 includes a rotary kiln and a secondary combustion chamber.
  • the slag remover 4 is equipped with a sludge extrusion dehydration mechanism and a sludge-containing oil-water overflow mechanism.
  • the crusher 3 is a shearing crusher, and the slag remover is a Martin slag remover.
  • the rotary kiln is equipped with an auxiliary combustion booster.
  • various oily solid wastes such as landing sludge, cleaning sludge, oily sludge generated by the existing "conditioning + centrifugation" treatment process, and oily sludge collection and transportation packaging, oil field labor protection supplies, etc.
  • landing sludge, cleaning sludge, oily sludge generated by the existing "conditioning + centrifugation" treatment process, and oily sludge collection and transportation packaging, oil field labor protection supplies, etc. are transported by dump trucks to After weighing and measuring, it enters the sludge comprehensive storage tank 1, and is stored in the sludge storage room by classification; the sludge grab crane 2 adopts a multi-lobed grab bucket, which has both bag breaking efficiency and prevents adhesion; various raw sludges are mixed.
  • the particle size after crushing can be less than 20mm.
  • the ratio of back-mixing hot water can be adjusted between 1 and 2 depending on the leaching requirements; the crushed and homogenized sludge falls into the Martin type slag remover 4, and the Martin type slag remover 4 performs the primary oil-water separation on the oil-water and sludge, and the sludge
  • the slag is initially dehydrated by the pressure of the slag extrusion dehydration mechanism, and the water content of the slag can reach below 45%.
  • the solid content of mud-containing oil and water is below 5%.
  • the temperature of the fluidized sludge in the sludge buffer pool 5 is about 50°C, and is sent to the quenching and tempering heating tank 6 by a screw pump.
  • the average moisture content of the temporarily stored sludge in the pretreatment sludge tank is about 45%. It is picked up by the sludge grab crane 2 and put into the feeding system to feed into the sludge granulator and dryer 10.
  • the superheated steam is indirectly heated in the sludge granulator and dryer.
  • the oil content of sludge particles is about 10%, and its low calorific value is less than 4600kJ/kg, and its calorific value is low.
  • the sludge particles are picked up by the sludge grab crane 2 and put into the feeding system to enter the pyrolysis and incineration equipment 12 for pyrolysis and incineration.
  • the pyrolysis and incineration equipment 12 includes a counter-flow rotary kiln and a secondary combustion chamber.
  • the rotary kiln is heated to 700 ⁇ At 850°C, pyrolysis is carried out in a reducing atmosphere.
  • the reducing atmosphere controls the excess air coefficient to be 0.5 to 0.75 to ensure that the waste gas generated by the sludge granulation and drying machine 10 can be fully digested.
  • the auxiliary burner is also located at the end of the kiln.
  • the high temperature and oxygen-rich environment at the end of the kiln can ensure that the slag discharge combustibles are fully digested.
  • the slag discharge is cooled to below 200 °C by the slag cooler 17 and shipped out for comprehensive utilization; the combustible gas produced by pyrolysis
  • the gas enters the secondary combustion chamber, and the secondary combustion chamber is heated to 1100 ⁇ 1200 °C with auxiliary fuel supplementary combustion.
  • the flue gas residence time is ⁇ 2s, and the excess air coefficient at the secondary combustion chamber outlet is controlled at 1.4 ⁇ 1.5, in order to facilitate complete combustion and Dioxins are completely decomposed at high temperature.
  • the high-temperature flue gas at the outlet of the second combustion chamber enters the waste heat boiler 13 for waste heat utilization to produce superheated steam.
  • the superheated steam pressure of the waste heat boiler 13 is 2.5MPa, the superheated steam temperature is 400°C, and the exhaust gas temperature is less than 200°C; part of the superheated steam generated by the waste heat boiler 13 is used for For heat supply, part of it is used for power generation by the steam turbine generator set 16. In addition to meeting the power consumption of the factory, there is also a part of the power generated by the grid.
  • the waste water produced by the three-phase centrifugal separator 7 and the condenser 11 is not only recycled into the hot water tank 8, but also has a surplus.
  • the circulating cooling water system is supplemented with water, and the waste water is zero discharged.
  • the integrated treatment method and system for the harmless and resourceful oil sludge in this embodiment draws on the advanced experience and research and test results of the existing hazardous waste incineration treatment technology and domestic waste incineration treatment technology , forming an optimized combination process of "hot washing + conditioning centrifugation + sludge drying + pyrolysis incineration + waste heat resource utilization", which well solves the limitations and small scale of the existing sludge treatment technology. And there are many problems such as relative dispersion and substandard pollutant discharge.

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Abstract

本发明公开了一种油泥无害化、资源化集成处理方法和系统，该处理方法，包括油泥破碎和喷淋热洗、初次机械挤压分离、再次离心分离、泥渣造粒干化、油泥颗粒热解焚烧和余热回收利用的工艺步骤，该处理系统，包括与工艺步骤相适应的各种处理设备。采用本申请的处理方法和系统，能规模化集中处理各类油田废弃物，原油回收率达到85%以上；油泥处理所产生的废水全部循环利用，废水零排放；油泥颗粒在还原性气氛下缺氧热解，排渣可用于建材等综合利用，热解焚烧的余热可用于生产蒸汽发电和系统供热，整个处理过程，不仅降低了油泥处理成本，而且实现了油泥的无害化、资源化和规模化处理。

Description

一种油泥无害化、资源化集成处理方法和系统 技术领域
本发明属于危险废弃物处理技术领域、具体涉及一种油泥无害化化、资源化集成处理方法和系统。
 背景技术
我国石油开采和炼制行业每年产生的油泥达数百万吨，而且每年还在快速增长，含油污泥被列为《国家危险废物名录》（2016环保部令第39号）H08类危险废弃物，原因就是该类油泥含有各种致畸、致癌的有毒物质”，如苯系物、酚、蔥、能类等。含油污泥减量化、无害化、资源化处理已迫在眉睫，在这方面国内的技术研究较少，国外技术成功引进的案例更少。
含油污泥种类繁多、性质复杂，相应的处理技术和设备也呈现多元化趋势，目前含油污泥处理技术有调质-机械脱水工艺、热处理工艺（化学热洗、焚烧、热解吸）、生物处理法（地耕法、堆肥法、生物反应器）、溶剂萃取技术以及对含油污泥的综合利用等。国外目前如加拿大MG工程公司采用的是机械脱水工艺配自己专有的药剂，荷兰吉福斯公司采用的是调质－机械脱水＋生物处理法，德国HILLER公司采用的是调质－机械脱水；新加坡的CLEANSEAS公司则采用机械脱水＋美国ADTU热解吸的工艺，实验室研究表明溶剂萃取也能达到污泥处理要求，但是溶剂萃取目前只局限于实验室研究，很难达到工业化应用。因此，国外现阶段应用较多并且比较成功的是采用物理法、化学法(离心分离加化学药剂处理)相结合，即调质－机械脱水工艺，该技术比较成熟，在欧美各地的油田应用广泛并且处理效果好。该方法的不足是处理效果会受污泥来源的影响，对于污泥中含有大量的砖瓦、草根、塑料等杂物需要配套预处理设备和工艺。
目前国内油田采用的油泥处理主流工艺为热解法、焚烧法和热洗处理含油污泥。热洗处理含油污泥仅能简单做到资源化，对原料适应性差，污染物排放不达标；焚烧法虽然有最大程度的减量化、无害化，对原料适应性强的优点，但是也存在能耗高，设备投资高，工艺技术要求高的缺点，并且污泥中的原油得不到回收，产生了资源浪费。热解法在500℃－600℃间接热解虽然能够大部分回收原油，但是处理后污泥中含油量仍然较高，达不到国家现行排放标准要求，同时高温气相生成的二恶英随不凝气体排放达不到最新排放标准要求。
根据《危险废物处置工程技术导则》（HJ 2042-2014）“易燃性废物宜优先选择焚烧处置技术，并应根据焚烧条件选择预处理方式”；《危险废物焚烧污染控制标准》（二次征求意见稿代替GB18484—2001）其排渣热灼减率和烟气排放标准较GB18484—2001标准有了提高，虽未正式发布实施，但于行业已起到倒逼技术升级的作用。
 技术问题
有鉴于此，本发明的目的是提供一种油泥无害化、资源化集成处理方法和系统，以便降低油泥处理成本，实现油泥的无害化、资源化和集成化处理。
 技术解决方案
本发明通过以下技术手段解决上述问题。
一种油泥无害化、资源化集成处理方法，包括如下步骤。
S1：将待处理油泥分类贮存。
S2：将贮存的待处理油泥混配后进行破碎，一边破碎，一边进行热水淋洗。
S3：将经过热水淋洗、破碎后的油泥进行初次机械挤压分离，初次分离出的泥渣在挤压脱水后返回步骤S1暂存，初次机械挤压分离出的含泥油水加热并加入药剂、搅拌，然后再次进行离心分离，离心分离出的水用于步骤S2中的热水淋洗，离心分离出的油进贮油罐暂存，离心分离出的油泥返回步骤S1与初次机械挤压分离出的泥渣同区域暂存。
S4：将两次分离出的泥渣进行造粒干化，造粒干化后油泥颗粒进行热解焚烧处理；干化过程中因油泥蒸发产生的蒸汽冷凝成水后，用于步骤S2中的热水淋洗；干化过程中产生的废气作为热解焚烧处理的助燃空气。
S5：将热解焚烧处理产生的余热经余热锅炉回收利用，余热锅炉产生的蒸汽一部分用于蒸汽发电、一部分用于步骤S2中的喷淋热水加热升温、一部分用于步骤S4中的造粒干化加热，造粒干化采用间接换热，蒸汽凝结水回余热锅炉循环利用。
进一步，步骤S4中，热解温度为700～850℃，在还原性气氛下进行热解，还原性气氛控制过剩空气系数在0.5～0.75，热解产生的排渣经冷却后外运综合利用，热解产生的可燃气随烟气进二燃室二次燃烧，二次燃烧升温至1100～1200℃，在此温度下烟气停留时间≥2s，二次燃烧过剩空气系数控制在1.4～1.5，二次燃烧的烟气余热经余热锅炉回收利用。
进一步，步骤S2中，热水淋洗的水温在80～90℃，喷淋热水与油泥的质量比例为1:1～2:1。
进一步，步骤S3中，再次离心分离时，含泥油水的温度加热至85～95℃。
一种油泥无害化、资源化集成处理系统，包括用于油泥贮存的油泥综合贮存池、用于将油泥抓取并送至各处理设备的油泥抓斗起重机、用于油泥破碎的破碎机、用于对破碎的油泥进行热水喷淋的热水喷淋装置、用于初次机械挤压分离的除渣机、用于初次分离出的含泥油水暂存的油泥缓存池、用于对初次分离出的含泥油水进行加热的调质加热罐、用于再次离心分离的三相离心分离机、用于对再次离心分离出的油进行贮存的贮油罐、用于对两次分离出的泥渣进行造粒干化的油泥造粒干化机、用于对造粒干化过程中携带油泥蒸发产生的水蒸汽的废气进行冷凝的冷凝器、用于对干化油泥颗粒进行热解焚烧处理的热解焚烧设备、与热解焚烧设备的排渣口配套使用的冷渣机、用于对热解焚烧设备的余热进行回收利用的余热锅炉、用于余热锅炉尾部烟气净化的烟气净化成套设备、用于净化烟气排出的烟囱、利用余热锅炉的蒸汽发电的汽轮发电机组；所述热水喷淋装置包括热水罐以及与热水罐连通的带热水喷嘴的喷淋设备，所述热水喷嘴布置在破碎机的破碎腔上方。进一步，所述调质加热罐的外部设置有加热盘管，调质加热罐配套有搅拌机构。
进一步，所述油泥综合贮存池被隔墙分隔成多个油泥贮存室、用于对两次分离产生的泥渣进行贮存的预处理油泥池以及用于对造粒干化油泥颗粒进行贮存的干化油泥池。
进一步，所述热解焚烧设备包括回转窑和二燃室。
进一步，所述除渣机配套有泥渣挤压脱水机构和含泥油水溢流机构。
进一步，所述回转窑和二燃室配套有辅助助燃器。
 有益效果
本发明的有益效果。
本发明公开了一种油泥无害化、资源化集成处理方法和系统，该处理方法，包括油泥破碎和喷淋热洗、初次机械挤压分离、再次离心分离、泥渣造粒干化、干化油泥颗粒热解焚烧和余热回收利用的工艺步骤，该处理系统，包括与工艺步骤相适应的各种处理设备。采用本申请的处理方法和系统，能规模化集中处理各类油田废弃物，原油回收率达到85%以上；油泥处理所产生的废水全部循环利用，废水零排放；油泥颗粒在还原性气氛下缺氧热解，排渣可用于建材等综合利用，热解焚烧的余热可生产蒸汽用于发电和系统供热，整个处理过程不仅降低了油泥处理成本，而且实现了油泥的无害化、资源化和规模化处理。
更加具体来说，本发明的优点体现在如下方面。
一是：本集成处理方法和系统可以接收处理各种含油废弃物，包括：落地油泥、清於油泥、现有资源化处理工艺产生的含油污泥、油泥收集运输包装物、油田作业劳保用品等；可实现油泥规模化集中处置；可节省建设投资、减少占地面积、节约能源消耗、降低处理成本、提高清洁生产、减少污染物排放。
二是：本集成处理方法和系统的原油回收率达到85%以上；油泥处理所产生的废水全部循环利用，废水零排放；油泥颗粒在700℃以上、还原性气氛下缺氧热解，排渣呈砖红色，其含油率在1‰以下，热灼减率小于5%，满足国家和行业最新排放标准要求，排渣可综合利用于建材生产。
三是：热解焚烧产生的高温烟气用于余热锅炉生产蒸汽，除部分用于工艺生产和采暖供热外，大部分用于发电，可实现厂用电全部自供并有余电上网。
四是：热解焚烧产生的烟气经净化工艺，烟气污染物排放浓度满足《危险废物焚烧污染控制标准》（二次征求意见稿代替GB18484—2001）要求。
 附图说明
下面结合附图和实施例对本发明作进一步描述。
图1为本发明实施例的系统连接示意图。
图中标号：1-油泥综合贮池，2-油泥抓斗起重机，3-破碎机，4-除渣机，5-油泥缓存池，6-调质加热罐，7-三相离心分离机，8-热水罐，9-贮油罐，10-油泥造粒干化机，11-冷凝器，12-热解焚烧设备，13-余热锅炉，14-烟气净化成套设备，15-烟囱，16-汽轮发电机组，17-冷渣机。
 本发明的实施方式
下面通过附图和实施例对本发明进一步详细说明。通过这些说明，本发明的特点和优点将变得更为清楚明确。显然,所描述的实施例仅是本发明的一部分实施例,而不是全部的实施例。
实施例 1。
本实施例提供了一种油泥无害化、资源化集成处理方法，包括如下步骤。
S1：将待处理油泥分类贮存。
S2：将贮存的待处理油泥混配后进行破碎，一边破碎，一边进行热水淋洗；热水淋洗的水温在80℃，喷淋热水与油泥的质量比例为1:1。
S3：将经过热水淋洗、破碎后的油泥进行初次机械挤压分离，初次分离出的泥渣在挤压脱水后返回步骤S1暂存，初次机械挤压分离出的含泥油水加热至85℃，并加入药剂、搅拌，然后再次进行离心分离，离心分离出的水用于步骤S2中的热水淋洗，离心分离出的油进贮油罐暂存，离心分离出的油泥返回步骤S1与初次机械挤压分离出的泥渣同区域暂存。
S4：将两次分离出的泥渣进行造粒干化，造粒干化后油泥颗粒进行热解焚烧处理；干化过程中因油泥蒸发产生的蒸汽冷凝成水后，用于步骤S2中的热水淋洗；干化过程中产生的废气作为热解焚烧处理的助燃空气；热解温度为700℃，在还原性气氛下进行热解，还原性气氛控制过剩空气系数在0.5，热解产生的排渣经冷却后外运综合利用，热解产生的可燃气随烟气进二燃室二次燃烧，二次燃烧升温至1100℃，在此温度下烟气停留时间≥2s，二次燃烧过剩空气系数控制在1.4，二次燃烧的烟气余热经余热锅炉回收利用。
S5：将热解焚烧处理产生的余热经余热锅炉回收利用，余热锅炉产生的蒸汽一部分用于蒸汽发电、一部分用于步骤S2中的喷淋热水加热升温、一部分用于步骤S4中的造粒干化加热，造粒干化采用间接换热，蒸汽凝结水回余热锅炉循环利用。
实施例 2。
本实施例提供了一种油泥无害化、资源化集成处理方法，包括如下步骤。
S1：将待处理油泥分类贮存。
S2：将贮存的待处理油泥混配后进行破碎，一边破碎，一边进行热水淋洗；热水淋洗的水温在85℃，喷淋热水与油泥的质量比例为1:1.5。
S3：将经过热水淋洗、破碎后的油泥进行初次机械挤压分离，初次分离出的泥渣在挤压脱水后返回步骤S1暂存，初次机械挤压分离出的含泥油水加热至90℃，并加入药剂、搅拌，然后再次进行离心分离，离心分离出的水用于步骤S2中的热水淋洗，离心分离出的油进贮油罐暂存，离心分离出的油泥返回步骤S1与初次机械挤压分离出的泥渣同区域暂存。
S4：将两次分离出的泥渣进行造粒干化，造粒干化后油泥颗粒进行热解焚烧处理；干化过程中因油泥蒸发产生的蒸汽冷凝成水后，用于步骤S2中的热水淋洗；干化过程中产生的废气作为热解焚烧处理的助燃空气；热解温度为800℃，在还原性气氛下进行热解，还原性气氛控制过剩空气系数在0.6，热解产生的排渣经冷却后外运综合利用，热解产生的可燃气随烟气进二燃室二次燃烧，二次燃烧升温至1150℃，在此温度下烟气停留时间≥2s，二次燃烧过剩空气系数控制在1.45，二次燃烧的烟气余热经余热锅炉回收利用。
S5：将热解焚烧处理产生的余热经余热锅炉回收利用，余热锅炉产生的蒸汽一部分用于蒸汽发电、一部分用于步骤S2中的喷淋热水加热升温、一部分用于步骤S4中的造粒干化加热，造粒干化采用间接换热，蒸汽凝结水回余热锅炉循环利用。
实施例 3。
本实施例提供了一种油泥无害化、资源化集成处理方法，包括如下步骤。
S1：将待处理油泥分类贮存。
S2：将贮存的待处理油泥混配后进行破碎，一边破碎，一边进行热水淋洗；热水淋洗的水温在90℃，喷淋热水与油泥的质量比例为2:1。
S3：将经过热水淋洗、破碎后的油泥进行初次机械挤压分离，初次分离出的泥渣在挤压脱水后返回步骤S1暂存，初次机械挤压分离出的含泥油水加热至95℃，并加入药剂、搅拌，然后再次进行离心分离，离心分离出的水用于步骤S2中的热水淋洗，离心分离出的油进贮油罐暂存，离心分离出的油泥返回步骤S1与初次机械挤压分离出的泥渣同区域暂存。
S4：将两次分离出的泥渣进行造粒干化，造粒干化后油泥颗粒进行热解焚烧处理；干化过程中因油泥蒸发产生的蒸汽冷凝成水后，用于步骤S2中的热水淋洗；干化过程中产生的废气作为热解焚烧处理的助燃空气；热解温度为850℃，在还原性气氛下进行热解，还原性气氛控制过剩空气系数在0.75，热解产生的排渣经冷却后外运综合利用，热解产生的可燃气随烟气进二燃室二次燃烧，二次燃烧升温至1200℃，在此温度下烟气停留时间≥2s，二次燃烧过剩空气系数控制在1.5，二次燃烧的烟气余热经余热锅炉回收利用。
S5：将热解焚烧处理产生的余热经余热锅炉回收利用，余热锅炉产生的蒸汽一部分用于蒸汽发电、一部分用于步骤S2中的喷淋热水加热升温、一部分用于步骤S4中的造粒干化加热，造粒干化采用间接换热，蒸汽凝结水回余热锅炉循环利用。
实施例 4。
如图1所示，本实施例提供了一种油泥无害化、资源化集成处理系统，包括用于油泥贮存的油泥综合贮存池1、用于将油泥抓取并送至各处理设备的油泥抓斗起重机2、用于油泥破碎的破碎机3、用于对破碎的油泥进行热水喷淋的热水喷淋装置、用于初次油水分离的除渣机4、用于初次油水分离出的含泥油水暂存的油泥缓存池5、用于对初次油水分离出的含泥油水进行加热的调质加热罐6、用于再次油水分离的三相离心分离机7、用于对再次油水分离出的油进行贮存的贮油罐9、用于对再次油水分离出的泥渣进行干燥造粒的油泥造粒干化机10、用于对干燥造粒过程中因油泥蒸发产生的蒸汽进行冷凝的冷凝器11、用于对干燥造粒过程中产生的油泥颗粒进行热解焚烧处理的热解焚烧设备12、与热解焚烧设备12的排渣口配套使用的冷渣机17、用于对热解焚烧设备12的余热进行回收利用的余热锅炉13、用于余热锅炉13烟气净化的烟气净化成套设备14、用于净化烟气排出的烟囱15、利用余热锅炉的蒸汽发电的汽轮发电机组16。
所述油泥综合贮存池1被隔墙分隔成多个油泥贮存室、用于对再次油水分离的泥渣进行贮存的预处理油泥池以及用于对油泥颗粒进行贮存的干化油泥池。
所述热水喷淋装置包括热水罐8以及与热水罐连通的带热水喷嘴的喷淋设备，所述热水喷嘴布置在破碎机的破碎腔上方。
所述调质加热罐6的外部设置有加热盘管，调质加热罐配套有搅拌机构。
所述热解焚烧设备12包括回转窑和二燃室。
所述除渣机4配套有泥渣挤压脱水机构和含泥油水溢流机构。
所述破碎机3为剪切式破碎机，所述除渣机为马丁除渣机。
所述回转窑配套有辅助助燃器。
具体工作时，落地油泥、清於油泥、现有“调质+离心”处理工艺产生的含油污泥及油泥收集运输包装物、油田作业劳保用品等各种含油固体废弃物由自卸汽车运输到厂，经称重计量进入油泥综合贮池1，通过油泥贮存室分类存放；油泥抓斗起重机2采用多瓣式抓斗，既有破袋效能又可以防止粘附；将各种原料油泥混配抓入剪切式破碎机3的进料系统，进料系统连续均匀向剪切式破碎机3给料，将含杂物油泥破碎，破碎后的粒度可小于20mm，在剪切式破碎机3的破碎腔上方的特定位置设有热水喷嘴，采用80～90℃回掺热水对含油污泥进行热淋洗，既可起到一次均化调质作用，又可将原油淋洗出来，回掺热水比例视淋洗需求在1～2之间可调；破碎均化后的油泥落入马丁式除渣机4，马丁式除渣机4对油水和泥渣进行初次油水分离，泥渣在推挤出渣过程中受到泥渣挤压脱水机构的压力挤压而初步脱水，出渣含水量可达到45%以下，含泥油水经过含泥油水溢流机构自流入油泥缓存池5，含泥油水含固率在5%以下。
油泥缓存池5中的流化油泥温度约50℃，经螺杆泵送入调质加热罐6，调质加热罐6外部设置加热盘管，可保持稳定的传热效率，调质加热罐顶设有搅拌机构，加入药剂促进油水分离，油泥加热到90℃，泵送进入三相离心分离机7进行油、水、渣分离，油中含水小于10%，水中含油小于0.5%，泥渣中含油5%以下、含水约75%；分离出的水进热水罐8循环使用，分离出的油进贮油罐9暂存，分离出的泥渣进油泥综合贮池1中的预处理油泥池。
预处理油泥池内暂存的油泥平均含水率约45%，经油泥抓斗起重机2抓起放入进料系统给入油泥造粒干化机10，过热蒸汽在油泥造粒干化机内间接加热油泥颗粒，蒸汽放出热量后凝结成水进余热锅炉13循环使用；干化油泥颗粒进入干化油泥池内暂存，干化油泥颗粒含水率小于25%；干化系统流通空气将油泥蒸发的水份带出，通过冷凝器11将油泥蒸发的水蒸汽冷却成水，冷凝器的冷却水采用循环冷却水，冷凝产生的废水作为回掺热水循环利用；干燥造粒时，冷却的空气含有挥发性有机气体，该气体进入热解焚烧设备12作为助燃空气。
油泥颗粒含油率约10%，其低位发热值小于4600kJ/kg，热值低。油泥颗粒经油泥抓斗起重机2抓起放入进料系统进入热解焚烧设备12热解焚烧，热解焚烧设备12包括逆流式回转窑和二燃室，回转窑加入辅助燃料燃烧升温到700～850℃，在还原性气氛下进行热解，还原性气氛控制过剩空气系数在0.5～0.75，保证能全部消化油泥造粒干化机10产生的废气，助燃空气在逆流式回转窑窑尾进入，辅助燃烧器也设窑尾处，窑尾高温和富氧环境可保证排渣可燃物充分消解，排渣经冷渣机17冷却到200℃以下外运综合利用；热解产生的可燃气体随烟气进入二燃室，二燃室采用辅助燃料补燃升温至1100～1200℃，在此温度下烟气停留时间≥2s，二燃室出口过剩空气系数控制在1.4～1.5，以利于完全燃烧和二恶英高温彻底分解。
二燃室出口高温烟气进入余热锅炉13进行余热利用，生产过热蒸汽，余热锅炉13过热蒸汽压力2.5MPa、过热蒸汽温度400℃，排烟温度小于200℃；余热锅炉13产生的过热蒸汽一部分用于供热，一部分用于汽轮发电机组16发电，所发电力除满足厂用电外，还有一部分电力上网。余热锅炉13排出的烟气经烟气净化成套设备14净化处理后，达到《危险废物焚烧污染控制标准》（二次征求意见稿代替GB18484—2001）烟气排放指标要求，通过烟囱15排放大气。
三相离心分离机7、冷凝器11产出的废水除进热水罐8循环使用外，还有一部分富余，这一部分富余废水经废水处理后中水达到工业循环水补充水水质指标，用于循环冷却水系统补充水，废水零排放。
本实施方式的油泥无害化、资源化集成处理方法和系统，在整合现有油泥处理技术优点的基础上，借鉴现有危废焚烧处理技术、生活垃圾焚烧处理技术的先进经验和研究试验成果，形成一种“热洗+调质离心+油泥干化+热解焚烧+余热资源利用”的优化组合工艺，很好地解决了现有油泥处理技术存在的处理油泥种类有局限性、规模小且相对分散、污染物排放不达标等诸多问题。
最后说明的是，以上实施例仅用以说明本发明的技术方案而非限制，尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的宗旨和范围，其均应涵盖在本发明的权利要求范围当中。

Claims (10)

  1. 一种油泥无害化、资源化集成处理方法，其特征在于，包括如下步骤：
    S1：将待处理油泥分类贮存；
    S2：将贮存的待处理油泥混配后进行破碎，一边破碎，一边进行热水淋洗；
    S3：将经过热水淋洗、破碎后的油泥进行初次机械挤压分离，初次分离出的泥渣在挤压脱水后返回步骤S1暂存，初次机械挤压分离出的含泥油水加热并加入药剂、搅拌，然后再次进行离心分离，离心分离出的水用于步骤S2中的热水淋洗，离心分离出的油进贮油罐暂存，离心分离出的油泥返回步骤S1与初次机械挤压分离出的泥渣同区域暂存；
    S4：将两次分离出的泥渣进行造粒干化，造粒干化后油泥颗粒进行热解焚烧处理；干化过程中因油泥蒸发产生的蒸汽冷凝成水后，用于步骤S2中的热水淋洗；干化过程中产生的废气作为热解焚烧处理的助燃空气；
    S5：将热解焚烧处理产生的余热经余热锅炉回收利用，余热锅炉产生的蒸汽一部分用于蒸汽发电、一部分用于步骤S2中的喷淋热水加热升温、一部分用于步骤S4中的造粒干化加热，造粒干化采用间接换热，蒸汽凝结水回余热锅炉循环利用。
  2. 根据权利要求1所述的油泥无害化、资源化集成处理方法，其特征在于：步骤S4中，热解温度为700～850℃，在还原性气氛下进行热解，还原性气氛控制过剩空气系数在0.5～0.75，热解产生的排渣经冷却后外运综合利用，热解产生的可燃气随烟气进二燃室二次燃烧，二次燃烧升温至1100～1200℃，在此温度下烟气停留时间≥2s，二次燃烧过剩空气系数控制在1.4～1.5，二次燃烧的烟气余热经余热锅炉回收利用。
  3. 根据权利要求1所述的油泥无害化、资源化集成处理方法，其特征在于：步骤S2中，热水淋洗的水温在80～90℃，喷淋热水与油泥的质量比例为1:1～2:1。
  4. 根据权利要求1所述的油泥无害化、资源化集成处理方法，其特征在于：步骤S3中，再次离心分离时，含泥油水的温度加热至85～95℃。
  5. 一种油泥无害化、资源化集成处理系统，其特征在于：包括用于油泥贮存的油泥综合贮存池（1）、用于将油泥抓取并送至各处理设备的油泥抓斗起重机（2）、用于油泥破碎的破碎机（3）、用于对破碎的油泥进行热水喷淋的热水喷淋装置、用于初次机械挤压分离的除渣机（4）、用于初次分离出的含泥油水暂存的油泥缓存池（5）、用于对初次分离出的含泥油水进行加热的调质加热罐（6）、用于再次离心分离的三相离心分离机（7）、用于对再次离心分离出的油进行贮存的贮油罐（9）、用于对两次分离出的泥渣进行造粒干化的油泥造粒干化机（10）、用于对造粒干化过程中携带油泥蒸发产生的水蒸汽的废气进行冷凝的冷凝器（11）、用于对干化油泥颗粒进行热解焚烧处理的热解焚烧设备（12）、与热解焚烧设备的排渣口配套使用的冷渣机（17）、用于对热解焚烧设备（12）的余热进行回收利用的余热锅炉（13）、用于余热锅炉（13）尾部烟气净化的烟气净化成套设备（14）、用于净化烟气排出的烟囱（15）、利用余热锅炉（13）的蒸汽发电的汽轮发电机组（16）；所述热水喷淋装置包括热水罐（8）以及与热水罐连通的带热水喷嘴的喷淋设备，所述热水喷嘴布置在破碎机（3）的破碎腔上方。
  6. 根据权利要求5所述的油泥无害化、资源化集成处理系统，其特征在于：所述调质加热罐（6）的外部设置有加热盘管，调质加热罐（6）配套有搅拌机构。
  7. 根据权利要求5所述的油泥无害化、资源化集成处理系统，其特征在于：所述油泥综合贮存池（1）被隔墙分隔成多个油泥贮存室、用于对两次分离的泥渣进行贮存的预处理油泥池以及用于对造粒干化油泥颗粒进行贮存的干化油泥池。
  8. 根据权利要求5所述的油泥无害化、资源化集成处理系统，其特征在于：所述热解焚烧设备（12）包括回转窑和二燃室。
  9. 根据权利要求5所述的油泥无害化、资源化集成处理系统，其特征在于：所述除渣机（4）配套有泥渣挤压脱水机构和含泥油水溢流机构。
  10. 根据权利要求8所述的油泥无害化、资源化集成处理系统，其特征在于：所述回转窑和二燃室配套有辅助助燃器。
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