WO2022007525A1 - 一种基于多功能池的污水处理工艺 - Google Patents
一种基于多功能池的污水处理工艺 Download PDFInfo
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- WO2022007525A1 WO2022007525A1 PCT/CN2021/095722 CN2021095722W WO2022007525A1 WO 2022007525 A1 WO2022007525 A1 WO 2022007525A1 CN 2021095722 W CN2021095722 W CN 2021095722W WO 2022007525 A1 WO2022007525 A1 WO 2022007525A1
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- tank
- water
- mud
- sludge
- denitrification
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- 239000010865 sewage Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 120
- 239000010802 sludge Substances 0.000 claims abstract description 69
- 238000000926 separation method Methods 0.000 claims abstract description 51
- 238000004062 sedimentation Methods 0.000 claims abstract description 36
- 230000029087 digestion Effects 0.000 claims abstract description 23
- 239000007788 liquid Substances 0.000 claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000001301 oxygen Substances 0.000 claims abstract description 14
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 14
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 239000010813 municipal solid waste Substances 0.000 claims abstract description 4
- 239000004576 sand Substances 0.000 claims abstract description 4
- 239000002893 slag Substances 0.000 claims description 18
- 238000010992 reflux Methods 0.000 claims description 17
- 239000006228 supernatant Substances 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 238000012856 packing Methods 0.000 claims description 8
- 241000894006 Bacteria Species 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 239000013049 sediment Substances 0.000 claims description 6
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 230000003750 conditioning effect Effects 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 230000003834 intracellular effect Effects 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 claims description 2
- 230000001546 nitrifying effect Effects 0.000 claims description 2
- 239000005416 organic matter Substances 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 abstract description 3
- 238000005191 phase separation Methods 0.000 abstract description 3
- 238000001556 precipitation Methods 0.000 abstract description 3
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000011499 joint compound Substances 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/02—Settling tanks with single outlets for the separated liquid
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/02—Biological treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
Definitions
- the invention belongs to the technical field of water treatment.
- the current sewage treatment process has the following shortcomings: 1. Except for the MBR process, a larger sedimentation tank is required, which leads to a large area for sewage treatment; 2. The utilization rate of denitrifying carbon sources is low, which makes it difficult to denitrify nitrogen; 3. The sludge output is large, and the sludge treatment cost is high;
- the invention uses a mud-water separation tank and a reflux tank to replace the secondary sedimentation tank, which saves the floor space; adopts two-stage denitrification to make full use of the carbon source of the raw water; the multi-functional tank has the effect of sludge digestion, greatly reduces the sludge output, and produces volatilization. Sexual fatty acids can be used to supplement denitrifying carbon sources.
- the existing continuous flow sewage treatment process generally sets up a secondary sedimentation tank with a large area at the back end of the secondary biochemical industry.
- the high investment cost and floor area of the secondary sedimentation tank greatly increase the total cost of sewage treatment, and the secondary sedimentation tank
- the function of the tank is only for solid-liquid separation, and it basically has no biochemical ability. If there is a dead corner of sedimentation, it is easy to cause the phenomenon of mud running in the secondary sedimentation tank, and reverse ammonia nitrogen in the effluent, which will seriously affect the effluent index.
- the invention of the invention is a new type of sewage treatment process.
- the secondary sedimentation tank occupies a large area and the denitrification carbon source is insufficient
- a multi-functional tank and a mud-water separation tank are developed.
- the secondary sedimentation tank unit is cancelled, and the carbon source in the raw water is fully utilized to achieve full and thorough denitrification and denitrification without the need for segmented water inflow.
- a sewage treatment process based on a multifunctional pool characterized in that:
- the sewage is discharged through the pre-sedimentation tank (1), the multifunctional tank (2), the biochemical tank (3), the mud-water separation tank (4), the reflux tank (5), and the advanced treatment unit (6) in sequence;
- the pre-sedimentation tank (1) is used to remove the garbage, impurities and sand in the sewage. After being treated by the pre-sedimentation tank, the sewage enters the multi-purpose tank (2);
- the multifunctional pool (2) is divided into three parts:
- the first part is the adjustment tank unit (2.1), and the hydraulic retention time of the adjustment tank is 8-12h;
- the second part is the first-stage denitrification unit (2.2), which has a stirrer and packing, and the sludge concentration on the packing reaches 0.1-0.8 mg/cm 2 ; the biofilm is cultivated on the packing to enrich the anammox bacteria and the reaction Nitrifying bacteria;
- the supernatant after the sludge digestion is mixed with the influent of the conditioning tank unit (2.1) in the primary denitrification unit (2.2), and the sludge digestion unit (2.3) Nitrate in the supernatant, intracellular carbon source and (2.1) organic matter in the raw water of the conditioning tank undergo denitrification on the surface of the biofilm on the first-stage denitrification unit (2.2) packing, ammonia nitrogen in the supernatant, nitrite Partial anaerobic ammonium oxidation reaction with ammonia nitrogen in raw water to remove part of total nitrogen,
- the third part is the sludge digestion unit (2.3), which has a stirrer, which is used to digest the return sludge of the sludge water separation tank and the return tank, and the dissolved oxygen is controlled below 0.5mg/L;
- the supernatant enters the second part of the first-level denitrification unit (2.2), and after preliminary denitrification is carried out in the second part of the first-level denitrification unit (2.2), the same
- the biochemical pool (3) includes an anoxic section (3.1), an aerobic section (3.2), the dissolved oxygen in the anoxic section (3.1) is less than 0.5 mg/L, the dissolved oxygen in the aerobic section (3.2) is less than 5 mg/l, and the residence time
- the anoxic and aerobic sections are respectively 2-5h: 6-10h;
- the effluent from the biochemical tank (3) enters the mud-water separation tank (4), the dissolved oxygen in the supernatant liquid after passing through the mud-water separation tank is reduced to 0.5-1mg/L, and the sludge concentration at the bottom is increased by more than 400%; then it enters the reflux tank (5) in turn. and advanced treatment unit (6); mud-water separation pool (4), reflux pool (5) and 5%-10% of the sludge at the bottom of the advanced treatment unit (6) is discharged, and 70%-85% is returned to (3.1) biochemical Pool, 10%-20% return to (2.3) the sludge digestion unit of the multifunctional pool.
- the structure of the mud-water separation tank (4) is as follows:
- a water distributor (4.1)
- a mud-water separator (4.2)
- a baffle plate (4.3)
- a mud bucket (4.4)
- the influent water flows into the mud-water separation tank (4) from top to bottom on the left side of the baffle plate, and then rises into the pool after passing through the baffle plate.
- the sludge is deposited in the bottom mud hopper, the supernatant is above, and then the supernatant flows into the mud-water separator (4.2) for further mud-water separation; a number of mud-water separators are arranged in the mud-water separation pool, and all water is passed through the mud-water separator.
- the mud-water separator flows out; in addition, a mud hopper is set at the bottom of the mud-water separation tank, and the sedimented sludge is collected by the mud hopper, discharged or returned.
- the structure of the mud-water separator includes a water inlet hole (4.2.1), a movable mud discharge valve plate (4.2.2), a pre-sediment inclined plate area (4.2.3), a horizontal pipe sedimentation area (4.2.4), and a slag discharge area. area (4.2.5), slag tank (4.2.6), water outlet (4.2.7);
- the water inlet hole (4.2.1) consists of several holes arranged in parallel on the side of the equipment, and the inlet water flows into the pre-sinking inclined plate area (4.2.3) through the holes,
- the pre-settled inclined plate area is composed of several parallel inclined plates.
- the inclined plate is inclined at an angle of 45-60°. There is a gap of 5-10 cm between the bottom and the side of the inclined plate. After the mud-water mixture flows in, the sludge slides into the bottom through the inclined plate. ;
- the rear end of the pre-sinking inclined plate area is connected to the horizontal tube sedimentation area (4.2.4).
- the horizontal tube sedimentation area 4.2.4.
- the Chinese Invention Patent Horizontal Tube Precipitation and Separation Device 200610123752.2, CN 100551482C, announced on October 21, 2009,
- the slag discharge area (4.2.5) is behind the sedimentation area of the horizontal pipe.
- the slag discharge area is an independent space.
- the upper part of the end of the slag discharge area is the slag discharge tank (4.2.6).
- the floating sludge after passing through the horizontal pipe flows into the slag discharge groove. discharge;
- the rear end of the slag tank is the water outlet (4.2.7), the water outlet is an independent space, and the water outlet is connected to a drain pipe outside;
- the water outlet and the slag discharge area are separated by a clapboard, and a number of holes are arranged at the lower part of the clapboard for drainage;
- a movable sludge discharge valve plate (4.2.2) is set at the bottom of the mud-water separator.
- the movable mud-discharge valve plate is used to close the bottom space. When the valve plate is opened, the sedimented sludge is discharged into the mud bucket of the mud-water separation tank;
- the mud-water mixture in the aerobic tank flows into the pre-sediment inclined plate area through the water inlet, the air bubbles escape from the top of the pre-sediment inclined plate, the activated sludge settles to the bottom of the inclined plate, and the water flows into the horizontal pipe sedimentation tank, where further processing is completed in the horizontal pipe sedimentation tank.
- the floating sludge is discharged through the sludge discharge tank, the water is discharged through the drainage area, and the sinking sludge is discharged at the bottom.
- FIG. 1 is a schematic diagram of the system of the present invention.
- Figure 2a is a schematic top view of a mud-water separation tank.
- Figure 2b is a schematic side view of a mud-water separation tank.
- Figure 2c is a schematic perspective view of a mud-water separation tank.
- Figure 3 is a schematic diagram of a mud-water separator.
- a multifunctional tank in the present invention has three functions of regulation, denitrification and sludge digestion at the same time.
- the influent water first enters the adjustment zone, and then enters the first-level denitrification zone after the water quality and quantity are adjusted.
- the return sludge first returns to the sludge digestion zone, and then enters the first-level denitrification zone after the sludge is digested, and then enters the water and reflux liquid.
- preliminary denitrification is carried out in the primary denitrification zone, and 10%-20% of the reflux liquid in the reflux tank is returned to the primary denitrification unit for supplementing nitrate and nitrite.
- a sludge discharge port is set at the bottom of the sludge digestion area to discharge the digested sludge ;
- the mud-water separation tank adopts an independent high-load sedimentation tank, which uses a combination of inclined plate sedimentation and horizontal tube sedimentation to realize the three-phase separation of mud, water and gas, and realizes the preliminary sedimentation and separation of sludge in this tank, and Dissolved oxygen can be removed.
- the return tank adopts the form of vertical flow sedimentation tank to further remove the mud-water mixture initially precipitated by the mud-water separation tank, and return the deoxygenated mud-water mixture to the anoxic area of the biochemical tank to prevent the dissolved oxygen in the anoxic area from passing through. high.
- the mixed liquid reflux is divided into two sections. Most of the mixed liquid (return ratio of 100-200%) is deoxygenated in the reflux tank and then returned to the anoxic area of the biochemical tank, and a small part of the bottom sludge (about 5-10%) is separated from the mud and water. The pool returns to the sludge digestion zone.
- a sewage treatment process based on a multifunctional pool belongs to the field of sewage treatment.
- the process consists of pre-sedimentation tank, multi-functional tank, A/O biochemical tank, mud-water separation tank, reflux tank and advanced treatment unit.
- the influent water goes through the pre-sedimentation tank to remove impurities such as garbage and sand, and then enters the multi-functional tank.
- enter the biochemical pool which adopts traditional A/O and AA/O processes. Secondary denitrification and nitrification are carried out in the tank.
- the mud-water separation tank and conduct three-phase separation of mud, water and gas in the mud-water separation tank.
- the separated sludge is partially returned to the third area of the multi-functional tank for digestion, and the internal carbon source, internal carbon source and The carbon sources in the raw water are mixed, and the first-stage denitrification is carried out in the second zone, and the second-stage denitrification is carried out in the denitrification zone of the biochemical tank.
- the two-stage denitrification improves the carbon source utilization rate and denitrification efficiency of the denitrification.
- Denitrification adopts pure biofilm method, which can better enrich denitrification bacteria, anammox bacteria and other bacteria species with denitrification function.
- Secondary denitrification adopts the combination of activated sludge and biofilm method to ensure denitrification efficiency. meet the target.
- the mixed liquid after the mud-water separation enters the reflux tank, the back-flow tank performs deep precipitation on the effluent of the mud-water separation tank, and returns a large proportion of the mixed liquid after deoxygenation of the mud-water separation tank to the denitrification zone to realize denitrification and prevent the denitrification zone from dissolving. If the oxygen is too high, the effluent will be discharged up to the standard after passing through the advanced treatment unit.
Abstract
Description
Claims (3)
- 一种基于多功能池的污水处理工艺,其特征在于:污水依次经预沉池(1),多功能池(2),生化池(3),泥水分离池(4),回流池(5),深度处理单元(6)后排出;预沉池(1)用于去除污水中的垃圾,杂质,砂子,经预沉池处理后,污水进入多功能池(2);多功能池(2)分为三部分:第一部分为调节池单元(2.1),调节池水力停留时间为8-12h;第二部分是一级反硝化单元(2.2),具有搅拌器和填料,填料上污泥浓度达到0.1-0.8mg/cm 2;填料上培养生物膜,用来富集厌氧氨氧化细菌和反硝化细菌;第三部分污泥消解单元(2.3)中,经污泥消解后的上清液同调节池单元(2.1)的进水在一级反硝化单元(2.2)混合,污泥消解单元(2.3)上清液中的硝酸盐、胞内碳源和(2.1)调节池原水中的有机物在一级反硝化单元(2.2)填料上的生物膜表面进行反硝化反应,上清液中的氨氮,亚硝酸盐和原水中的氨氮进行部分厌氧氨氧化反应,进而去除一部分总氮,第三部分是污泥消解单元(2.3),具有搅拌器,用于消解泥水分离池和回流池的回流污泥,溶解氧控制在0.5mg/L以下;回流液进入污泥消解单元(2.3)经消解后,上清液进入第二部分一级反硝化单元(2.2),在第二部分一级反硝化单元(2.2)进行初步反硝化后,同进水一起在一级反硝化单元(2.2)流出,一级反硝化单元溶解氧0.5mg/L以下,停留时间1-2h,随后进入生化池(3);生化池(3)包括缺氧段(3.1),好氧段(3.2),缺氧段(3.1)的溶解氧小于0.5mg/L,好氧段(3.2)溶解氧小于5mg/l,停留时间缺氧、好氧段分别为2-5h:6-10h;生化池(3)出水进入泥水分离池(4),经过泥水分离池后的上清液溶解氧降低到0.5-1mg/L,底部污泥浓度提高400%以上;然后依次进入回流池(5)和深度处理单元(6);泥水分离池(4),回流池(5)和深度处理单元(6)底部的污泥5%-10%排走,70%-85%回流到(3.1)生化池,10%-20%回流到(2.3)多功能池的污泥消解单元。
- 根据权利要求1所述的污水处理工艺,其特征在于,泥水分离池(4)结构如下:包括布水器(4.1),泥水分离器(4.2),挡板(4.3)和泥斗(4.4),进水经布水器均匀布水后,自上而下流入泥水分离池(4),泥水分离池中间设置未插入底部的挡板(4.3),进水在挡板左侧自上而下流到泥水分离池(4)池内,经过挡板后再上升到池内,此时,进水经过初步分离,其中的污泥沉淀到底部泥斗,上清液在上方,随后上清液流入泥水分离器(4.2)进行进一步泥水分离;在泥水分离池内设置有若干泥水分离器,所有水都经泥水分离器流出;此外在泥水分离池底部设置泥斗,沉淀的污泥经泥斗收集,排出或回流。
- 根据权利要求1所述的污水处理工艺,其特征在于:泥水分离器结构包括进水孔(4.2.1),活动排泥阀板(4.2.2),预沉斜板区(4.2.3),水平管沉淀区(4.2.4),排渣区(4.2.5),出渣槽(4.2.6),出水端(4.2.7);进水孔(4.2.1)由在设备侧边平行排列的若干孔组成,进水经孔流入预沉斜板区(4.2.3),预沉斜板区由若干平行排列的斜板组成,斜板倾斜角度45-60°,斜板底部与侧边留有5-10cm的空隙,泥水混合物流入后,污泥经斜板滑入底部;预沉斜板区后端连接水平管沉淀区(4.2.4),水平管沉淀区的结构参见中国发明专利:水平管沉淀分离装置200610123752.2,CN 100551482C,公告日2009年10月21日,水平管沉淀区后边是排渣区(4.2.5),排渣区是一个独立空间,排渣区末端上部是出渣槽(4.2.6),经过水平管后的浮泥流入出渣槽后排出;出渣槽后端是出水端(4.2.7),出水端是个独立空间,出水端外部接排水管;出水端和排渣区之间由隔板分隔,隔板下部排列有若干孔用于排水;泥水分离器的底部设置活动排泥阀板(4.2.2),活动排泥阀板用于封闭底部空间,当阀板打开后把沉淀污泥排入泥水分离池的泥斗中;好氧池的泥水混合液经进水口流入预沉斜板区,气泡从预沉斜板上方逸出,活性污泥沉淀到斜板底部,水流入水平管沉淀池,在水平管沉淀池内完成进一步 固液分离后,上浮的污泥经排泥槽排除,水经过排水区排出,下沉的污泥在底部排出。
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