WO2021240489A2 - Composition herbicide synergique - Google Patents

Composition herbicide synergique Download PDF

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Publication number
WO2021240489A2
WO2021240489A2 PCT/IB2021/055784 IB2021055784W WO2021240489A2 WO 2021240489 A2 WO2021240489 A2 WO 2021240489A2 IB 2021055784 W IB2021055784 W IB 2021055784W WO 2021240489 A2 WO2021240489 A2 WO 2021240489A2
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Prior art keywords
composition
present
herbicide
formulation
range
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PCT/IB2021/055784
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English (en)
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WO2021240489A3 (fr
Inventor
Vimal Alawadhi
Raajan Ailawadhi
Ajit S Gujral
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Best Agrolife Limited
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Publication of WO2021240489A2 publication Critical patent/WO2021240489A2/fr
Publication of WO2021240489A3 publication Critical patent/WO2021240489A3/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof

Definitions

  • the present invention relates a synergistic herbicidal composition comprising imidazolinone herbicide, a sulfonylurea herbicide and an aryloxyphenoxy propionate herbicide.
  • the present invention relates to the herbicidal composition of (A) Imazethapyr or a salt or adduct thereof and (B) Chlorimuron ethyl or a salt or adduct thereof and (C) Clodinafop propargyl or a salt or adduct thereof. More particularly, the present invention relates to a formulation of herbicidal composition and a method for controlling undesired vegetation.
  • herbicides have an effect against a spectrum of weeds; however, these herbicides may not be effective on certain type of other weeds, which may also be present in the crop to be protected. Therefore, there is a strong need for mixing two or more herbicides.
  • Imazethapyr (R5)-5-ethyl-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl) nicotinic acid, disclosed in US 4,798,619, is a branched chain amino acid synthesis (ALS or AHAS) inhibitor.
  • Imazethapyr is an active compound from the group of imidazolinone herbicides, which are known e.g. from Shaner, D. L., O'Conner, S. L, The Imidazolinone Herbicides, CRC Press Inc., Boca Raton, Fla. 1991 and also from The Compendium of Pesticide Common Names http://www.alanwood.net/pesticides/.
  • Imazethapyr reduces levels of valine, leucine and isoleucine, leading to disruption of protein and DNA synthesis.
  • Imazethapyr is a systemic herbicide, absorbed by the roots and foliage. Imazethapyr control many major annual and perennial grass and broad-leaved weeds.
  • Herbicide Mixture Compatibility Chart published by the government of Western Australia, Department of agriculture and food Tank, mixing imazethapyr and propaquizafop is not recommended.
  • the chart teaches that excessive crop damage or reduction in weed control may occur by the combination of both herbicides.
  • compositions comprising selected herbicides have several advantages over the use of a single herbicide including (a) an increase in the spectrum of weeds controlled or an extension of weed control over a longer period of time, (b) an improvement in crop safety by using minimum doses of selected herbicides applied in combination rather than a single high dose of one herbicide and (c) a delay in the appearance of resistant weed species to selected herbicides (Int. J. Agri. Biol., Vol. 6, No. 1, 2004, pages 209-212).
  • modem-day crop protection compositions are continually increasing, with regard, for example, to the spectrum of action, toxicity, selectivity, application rate, formation of residues, and favourable preparation ability, and since, furthermore, there may be problems, for example, with resistances, a constant task is to develop new compositions, in particular herbicidal agents, which in some areas at least help to fulfil the abovementioned requirements. Also, in particular, where different type of weeds such as grassy weeds, broad leaved weeds and sedges are required to be controlled together in a single application of herbicidal composition, which are dose friendly and efficacious and less phytotoxic to various crops & plants.
  • present invention aims to overcome the problems of the prior art and provide a synergistic herbicidal composition comprising Imazethapyr with Chlorimuron ethyl and Clodinafop Propargyl which can demonstrate excellent effects against the undesired vegetation including weeds such as grassy weeds, broad leaved weeds and sedges.
  • the main objective of the present invention is to provide a synergistic herbicidal composition effective for controlling undesired vegetation including weeds such as grassy weeds, broad leaved weeds and sedges.
  • Another objective of the present invention is to provide a synergistic herbicidal one-shot formulation effective for controlling undesired vegetation including weeds such as grassy weeds, broad leaved weeds and sedges.
  • Yet another objective of the present invention is to provide wettable powder synergistic herbicidal formulation having particle size 2-40 ⁇ s.
  • Yet another objective of the present invention is to provide a synergistic herbicidal formulation/composition which can help in controlling undesired vegetation when applying to the locus of the undesired vegetation.
  • Yet another objective of the present invention is to provide a process for the preparation of a synergistic herbicidal composition comprising the active ingredients of the present invention and excipients suitable for such a herbicidal composition.
  • the present invention related to a synergistic herbicidal composition
  • a synergistic herbicidal composition comprising: a. at least one imidazolinone herbicide; b. at least one sulfonylurea herbicide; and c. at least one aryloxyphenoxy propionate herbicide.
  • the imidazolinone herbicide is present in the range of 0.1-50% by weight
  • the sulfonylurea herbicide is present in range of 0.1-50% by weight
  • the aryloxyphenoxy propionate herbicide is present in the range of 0.1-50% by weight.
  • the imidazolinone herbicide is selected from the group consisting of mazamethabenz-methyl, imazamox, imazapic, imazapyr, imazaquin and imazethapyr or salts thereof.
  • the sulfonylurea herbicide is selected from the group consisting of chlorimuron ethyl, amidosulfuron, azimsulfuron, bensulfuron, chlorimuron ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, propyrisulfuron, prosulfuron, pyrazosulfuron, rimsulfuron, sulfometuron, sulfos
  • the aryloxyphenoxy propionate herbicide is selected from the group consisting of Clodinafop propargyl, fluazifop- propargyl, Propaquizafop, haloxyfop- propargyl and quizalofop- propargyl or salts thereof.
  • the imidazolinone herbicide is preferably imazethapyr.
  • the sulfonylurea herbicide is preferably chlorimuron ethyl.
  • the aryloxyphenoxy propionate herbicide is preferably Clodinafop propargyl.
  • the imazthapy is preferably present in the range of 0.1-10% by weight
  • the chlorimuron ethyl is preferably present in range of 0.1-2.5% by weight
  • the Clodinafop propargyl is preferably present in the range of 10-50% by weight.
  • said composition is formulated as SC (Suspension Concentrate), WG (Water Dispersible Granule), WP (Wettable Powder), OD (Oil Dispersion), EC (Emulsion Concentrate) and ME (Micro Emulsion) formulation.
  • said composition is formulation as WP (Wettable Powder) and/or OD (Oil Dispersion).
  • the said formulation is WP(Wettable Powder) formulation, which is present in the water soluble pouch made up polyvinyl alcohol and organic plastic.
  • the particle size of herbicidal formulation including the WP(Wettable Powder) formulation is in the range of 2- 40 microns.
  • the herbicidal composition comprises a safener, adjuvant (silicon based spreader), a dispersing agent, a wetting agent, an antifoaming agent, an anti-freezing agent, a filler, an anti-bacterial, adjuvant, thickener.
  • the safener is selected from the group consisting of cloquintocetl-mexyl, cyprosulfamide, dichlormid, dicyclonon and mefenpyr-diethyl or the combinations thereof, present in the range of 0.1-15% w/w.
  • the dispersing agent is selected from the group consisting of Tristyrylphenol Ethoxylate Amine salt of phosphate tristyryl phenol ethylated /Acrylic Copolymer/ Ethoxylated Tristryl phenol Sulphate, Naphthalene sulfonic acid, sodium salt condensate with formaldehyde, Ethoxylated oleyl cetyl alcohol, Polyalkelene glycol ether or the combinations thereof and present in the range of 0.5-10% w/w..
  • wetting agent is selected from the group consisting of Tristyrylphenol ethoxylate nonionic emulsifier/ Mixture of non-ionic surfactants and Alkoxylated Alcohol/Block copolymer or the combinations thereof and present in the range of 0.5-10% w/w.
  • the Antifoaming Agent is Siloxane polyalkyleneoxide present in the range of 0.01-1% w/w.
  • the Antifreezing Agent is selected from the group consisting of Glycol, Propylene Glycol, Mono ethylene glycol and Glycerin or the combinations thereof, present in the range of 0.1 to 10%w/w.
  • the filler is selected from the group consisting of Silicon Dioxide, China Clay, Kaolin, Talc or starch or the combinations thereof, present in the range of 0.1-5% w/w.
  • the anti-bacterial is selected from Benzisothiazolin-3-one or Formaldehyde or the combinations thereof, present in the range of 0.01-1% w/w.
  • the thickener is selected from the group consisting of polysaccharides or carboxymethyl cellulose or bentonite clay.
  • the adjuvant (silicon based spreader) is used for the OD (Oil Dispersion) formulation.
  • the adjuvant is selected from the silicon ethoxylated oil group.
  • In yet another embodiment of the present invention provides a method of controlling undesired vegetation by applying synergistic herbicidal composition of the present invention to the locus of the undesired vegetation of the crops and plants.
  • the crop may be selected from the group consisting of soybeans, blackgram, peanuts, green gram, pigeon pea, beans, field peas and cluster beans.
  • the herbicidal composition may be applied in an amount of 1 to 500 g/ha. In a preferred embodiment, the herbicidal composition may be applied in an amount of 125 g/ha.
  • the undesired vegetation may be selected from the group consisting Echinochloa Colona, Dinebra Arabica, Cynotis sp, Eleusine Indica, Cynodon Dactylon, Euphorbia Hirta, Amaranthus Viridis, Digeria Arvensis, Digera sp., Panicum sp., Phyllanthus sp, Commelina benghalensis L, Parthenium, Trianthema Portulacasturm, Cleome viscosa, Digera arvensis, Parthenium hysterophoms, Cynadon dactylone, Commelina bengalensis and Dinebra sp., Portulaca sp., Trianthima sp., Dactyloctenium aegyptium, Corchprus sp., Trianthema monogyna, Brachiaria sp.
  • Acalypha species such as Acalypha indica, Dinebra species such as Dinebra Arabica, Cynotis spec such as Cynotis axillaris, Parthenium spec such as Parthenium hysterophoms, Physalis spec such as Physalis minima, Digera spec such as Digera arvensis, Alopecurus myosuroides, Apera spicaventi, Brachiaria spec such as Brachiaria deflexa or Brachiaria plantaginea, Echinochloa spec such as Echinochloa colonum, Leptochloa spec such as Leptochloa fusca, Rottboellia cochinchinchinensis, Digitaria sanguinalis, Eleusine indica, Saccharum spontaneum, Cynodon dactylon, Euphorbia hirta, Euphorbia geniculata, Commelina benghalensis, Commelina communis, certain undesired Oryza spec
  • Wettable powder formulation size is in the range of 2-40m, hence the particle size plays an important role in leaf area coverage and crop safety
  • crop includes reference to whole plant, plant organ (e.g., leaves, stems, twigs, roots, trunks, limbs, shoots, fruits etc.), or plant cells.
  • locus includes not only areas where weeds may already be growing, but also areas where weeds have yet to emerge, and also to areas under cultivation.
  • agriculturally acceptable carrier means carriers of which are known and accepted in the art for the formation of formulations for agricultural or horticultural use.
  • surfactant refers to an agriculturally acceptable material which imparts emulsifiability, stability, spreading, wetting, dispersibility or other surface-modifying properties.
  • the present invention related to a synergistic herbicidal composition
  • a synergistic herbicidal composition comprising: an imidazolinone herbicide; a sulfonylurea herbicide; and an aryloxyphenoxy propionate herbicide along with a safener.
  • the an imidazolinone herbicide is present in the range of 0.1-50% by weight
  • the sulfonylurea herbicide is present in range of 0.1- 50% by weight
  • the aryloxyphenoxy propionate herbicide is present in the range of 0.1-50% by weight
  • the safener is present in the range of 0.1-15% by weight.
  • the imidazolinone herbicide is selected from the group consisting of mazamethabenz-methyl, imazamox, imazapic, imazapyr, imazaquin and imazethapyr.
  • the imidazolinone herbicide is Imazethapyr.
  • the sulfonylurea herbicide is selected from the group consisting of chlorimuron ethyl, amidosulfuron, azimsulfuron, bensulfuron, chlorimuron ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfur
  • the sulfonylurea herbicide Sulfonylurea class herbicide that inhibits acetolactate synthase, which regulates plant growth.
  • Branched chain amino acid synthesis (ASL or AHAS) inhibitor Acts by inhibiting biosynthesis of the essential amino acids valine and isoleucine, hence stopping cell division and plant growth. Crop selectivity derives from plant metabolism both by homoglutathione conjugation and by de-esterification.
  • the sulfonylurea herbicide is preferably Chlorimuron-ethyl.
  • Chlorimuron-ethyl is an ethyl ester resulting from the formal condensation of the carboxy group of chlorimuron with ethanol it is used as herbicide for the control of broad-leaved weeds in peanuts, soya beans, and other crops. It has a role as a pro-herbicide.
  • the aryloxyphenoxy propionate herbicide is selected from the group consisting of Clodinafop propargyl, fluazifop- propargyl, haloxyfop- propargyl and quizalofop- propargyl.
  • aryloxyphenoxypropionate herbicides act by inhibiting the enzyme acetyl-CoA carboxylase (ACCase) in the chloroplasts of sensitive plants.
  • ACCase acetyl-CoA carboxylase
  • the aryloxyphenoxypropionate herbicides are known as fops and are a subgroup of the acetyl-CoA inhibitor group.
  • the aryloxyphenoxy propionate herbicide is Clodinafop propargyl.
  • Clodinafop propargyl is shown to have good efficacy against the grass weeds, mediocre efficacy against the broad leaves and sedges.
  • the herbicidal formulation comprising Imazethapyr, Chlorimuron ethyl, and Clodinafop propargyl technical, or salts or esters thereof and/or combination thereof shown to have a synergistic effect on the crops and a single shot of said herbicidal composition is sufficient which provides excellent efficacy against the grass weeds, broad leaves weeds and perennial sedges as a single shot.
  • the present invention relates to a synergistic herbicidal formulation comprising composition of (A) Imazethapyr and (C) Clodinafop propargyl esters, esters, salts and/or combination thereof.
  • the present invention relates to a synergistic herbicidal formulation comprising composition of (B) Chlorimuron ethyl and (C) Clodinafop propargyl esters, esters, salts and/or combination thereof.
  • a synergistic herbicidal formulation comprising composition of (A) Imazethapyr and (B) Chlorimuron ethyl and (C) Clodinafop propargyl esters, esters, salts and/or combination thereof.
  • the synergistic herbicidal formulation comprising of Imazethapyr, Chlorimuron ethyl, and Clodinafop propargyl esters and/or combination thereof shown to have a synergistic effect on the crops and such a herbicidal composition is sufficient to show excellent efficacy against the grass weeds, broad leaves weeds and perennial sedges as a single shot.
  • the weight ratio of Imazethapyr and Chlorimuron ethyl in the composition may be from about 50: 1 to 1 :50.
  • the weight ratio of Imazethapyr and Clodinafop propargyl esters in the composition may be from about 50: 1 to 1:50.
  • the weight ratio of Chlorimuron ethyl and Clodinafop propargyl esters in the composition may be from about 50: 1 to 1:50.
  • the weight ratio of Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters in the composition may be from about 1:50 to 50: 1 to 1:50.
  • the weight ratio of Imazethapyr, Chlorimuron ethyl a and Clodinafop propargyl esters in the composition may be from about 1:50 to 50: 1 to 1:50.
  • an herbicidal formulation comprising composition Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters, and/or combination thereof including esters and salts thereof and an agriculturally acceptable carrier, is provided.
  • the composition comprises a safener, a dispersing agent, a wetting agent, an antifoaming agent, an anti-freezing agent, a filler, an anti-bacterial and thickener.
  • the herbicidal formulation may include additional other crop protection agents, for example pesticides, safeners or agents for controlling phytopathogenic fungi or bacteria.
  • the herbicidal formulation may be applied in an amount of about 0.1 to 700 liter/ha.
  • the herbicidal formulation may be applied in an amount of about 0.1 to 300 liter/ha.
  • the herbicidal formulation may be applied in an amount of about 0.1 to 50 liter/ha.
  • the herbicidal formulation may be applied in an amount of about 3.5 liter/ha. In yet another specific embodiment, the herbicidal formulation may be applied in an amount of about 2.50 liter/ha.
  • the herbicidal formulation may be applied in an amount of about 1.50 liter/ha.
  • the herbicidal formulation may be applied in an amount of about 1.00 liter/ha.
  • the herbicidal formulation may be applied in an amount of about 1 to 1000 g/ha.
  • the herbicidal formulation may be applied in an amount of about 1 to 500 g/ha.
  • the herbicidal formulation may be applied in an amount of about 125 g/ha.
  • the amount of Imazethapyr is 1 to lOOg/ha
  • Chlorimuron ethyl is 1 to lOOg/ha
  • Clodinafop propargyl esters is to lOOg/ha.
  • a herbicidal formulation comprising (i) compositions Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters; which may be applied pre-plant incorporated, pre- or post- emergence.
  • the invention in another preferred embodiment, relates to a process for preparation mixtures of a (A) Imazethapyr and (B) Chlorimuron ethyl and (C) Clodinafop propargyl and also to compositions comprising these herbicides.
  • the present invention relates to herbicidal formulation comprising composition (A) Imazethapyr and component (B) Chlorimuron ethyl and component (C) Clodinafop propargyl in ratios by weight of the active ingredients are 0.1 to 50% component (A); 0.1 to 50% component (B) and 0.1 to 50% component (C).
  • the present invention relates to herbicidal formulation comprising ratios by weight:
  • One embodiment of the present invention relates to the use of the herbicidal formulation comprising composition Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters, and/or combination thereof, are suitable for controlling a large number of harmful plants, including monocotyledonous weeds, in particular annual weeds such as gramineous weeds (grasses) including Echinochloa species such as barnyardgrass ( Echinochloa crusgalli var crus-galli ) or Echinochloa colonum, monocotyledonous weeds selected from the group consisting of Echinochloa spec such as Echinochloa colonum, Eeptochloa spec.
  • grasses gramineous weeds
  • Echinochloa species such as barnyardgrass ( Echinochloa crusgalli var crus-galli ) or Echinochloa colonum
  • Eeptochloa fusca certain undesired Oryza spec such as weedy rice or red rice ( Oryza sativa )
  • Phalaris spec such as Phalaris canariensis
  • Brachiaria spec. such as Briachiaria deflexa or Brachiaria plataginea.
  • Digitaria species such as crabgrass ( Digitaria sanguinalis), certain undesired Oryza spec such as weedy rice or red rice ( Oryza sativa ), Setaria species such as green foxtail ( Setaria viridis ) and giant foxtail ( Setaria faberil), Sorghum species such as johnsongrass ( Sorghum halepense Pers.), Avena species such as wild oats (Avena fatua), Cenchrus species such as Cenchrus echinatus, Bromus species, Eolium species, Eeptochloa spec such as Eeptochloa fusca, Phalaris species such as Phalaris canariensis, Eriochloa species, Panicum species, Brachiaria species such as Brachiaria deflexa or Brachiaria plantaginea, annual bluegrass (Poa annua), blackgrass ( Alopecurus myosuroides), Aegilops cylindrica, Agropyron re
  • the herbicidal formulation comprising composition of Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters, and/or combination thereof of the present invention are also suitable for controlling a large number of dicotyledonous weeds, in particular broad leaf weeds including Ambrosia species such as common ragweed ( Ambrosia artemisiifolia ), Anthemis species, Atriplex species,
  • Hemp sesbania Sesbania exaltata Cory
  • Anoda cristata Bidens pilosa
  • Brassica kaber Capsella bursa-pastoris
  • Centaurea cyanus Galeopsis tetrahit, Galium aparine, Helianthus annuus, Desmodium tortuosum, Kochia scoparia, Mercurialis annua, Myosotis arvensis, Papaver rhoeas, Raphanus raphanistrum, Salsola kali, Sinapis arvensis, Sonchus arvensis, Thlaspi arvense, Tagetes minuta, Richardia braslliensis, Rumex crispus, Rumex obtusifolius, Heracleaum sphondylium, Aethusa cynapium, Daucus carota, Equisetum arvense, Celosia argentea, Cynotis species such as Cynotis axil
  • Chlorimuron ethyl is particular suitable for controlling monocotyledonous weeds, preferably Echinochloa spec., Eeptochloa spec., Orysa spec., Phalaris spec., Bra strigia spec., more preferably Echinochloa spec such as Echinochloa colonum, Eeptochloa spec such as Eeptochloa fusca and Orysa spec such as Orysa sativa.
  • the herbicidal formulation comprising composition of Imazethapyr and
  • Clodinafop propargylesters is particular suitable for Echinochloa spec., Phalaris spec., Eeptochloa spec., Orysa spec., Brachiaria spec., more preferably Phalaris spec such as Phalaris canariensis, Echinochloa spec such as Echinochloa colonum, Phalaris spec such as Phalaris canariensis, Orysa spec such as Orysa sativa and Brachiaria spec such as Brachiaria plantaginea.
  • the herbicidal formulation comprising composition Chlorimuron ethyl and Clodinafop propargyl esters is in particular useful against annual and perennial grasses and broad-leaved weeds in post-emergence application.
  • the herbicidal formulation compositions of the present invention are also suitable for controlling a large number of annual and perennial sedge weeds including cyperus species such as purple nutsedge ( Cyperus rotundus L.), yellow nutsedge ( Cyperus esculentus L.), hime-kugu ( Cyperus brevifolius H.), sedge weed ( Cyperus microiria Steud), rice flatsedge ( Cyperusiria L.), and the like.
  • cyperus species such as purple nutsedge ( Cyperus rotundus L.), yellow nutsedge ( Cyperus esculentus L.), hime-kugu ( Cyperus brevifolius H.), sedge weed ( Cyperus microiria Steud), rice flatsedge ( Cyperusiria L.), and the like.
  • the herbicidal formulation comprising composition of Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters, and/or combination thereof according to the present invention are suitable for combating/controlling common harmful plants in useful plants (i.e. in crops).
  • the compositions of the present invention are generally suitable for combating/controlling undesired vegetation in Legumes (Fabaceae), including e.g. soybeans ( Glycine max), peanuts (. Arachis hypogaea ) and pulse crops such as peas including Pisum sativum, pigeon pea and cowpea, beans including broad beans ( Vicia faba), Vigna spp., and Phaseolus spp.
  • Legumes Fabaceae
  • soybeans Glycine max
  • peanuts .
  • pulse crops such as peas including Pisum sativum, pigeon pea and cowpea, beans including broad beans ( Vi
  • compositions of the invention are suitable for application in any variety of the aforementioned crop plants.
  • the herbicidal formulation comprising composition of Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters, and/or combination thereof may be applied on crops which include soybeans, blackgram, peanuts, green gram, pigeon pea, cluster beans, field peas, mung beans, dry beans, peanuts, groundnuts, snap bean, alfalfa, lettuce, beans.
  • the crop includes soybeans, groundnuts, blackgram, peanuts, green gram, pigeon pea, beans, field peas and cluster beans.
  • the mixture may be applied on tolerant or resistant mutants or transgenic crops plants such as soybean, and etc.
  • the herbicidal formulation comprising composition of Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters, and/or combination thereof, the compositions of the present invention are in particular suitable for combat- ing/controlling undesired vegetation in soybean, peanut, pea, bean, lentil, green gram, black gram, cluster bean, fenugreek, other pulse or leguminous crops.
  • compositions of the present invention are most suitable for combating/controlling undesired vegetation in soybean, peanut, pea, bean, lentil, green gram, black gram, cluster bean, fenugreek, other pulse or leguminous crops, preferably soybean ( Glycine max).
  • carrier is to be understood as meaning a natural or synthetic, organic or inorganic substance which is mixed or combined with the active compounds for better applicability, in particular for application to plants or plant parts or seeds.
  • the carrier which may be solid or liquid, is generally inert and should be suitable for use in agriculture.
  • compositions may be made at the time of use, or diluted, or else they can be concentrated compositions, or so-called "ready-to-use" compositions, that is to say, ready for marketing.
  • the formulation may be obtained by combining a synergistic amount of the active ingredients with an agriculturally acceptable carrier, a surfactant or other application-promoting adjuvant customarily employed in formulation technology.
  • the herbicidal formulation comprising composition of Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters, and/or combination thereof may be as emulsion concentrates (EC), microemulsion concentrates (MEC), suspension concentrates (SC), soluble concentrates (SL), suspoemulsion (SE), oil dispersions (OD), water dispersible granules (WDG), water soluble granules (SG) and wettable powders (WP).
  • the herbicidal formulation comprising the WP(Wettable Powder)formulation is present in the water soluble pouch made up polyvinyl alcohol and organic plastic (water soluble synthetic polymer).
  • size of the wettable powder (WP)formulation is in the range of 2-40 microns.
  • the particle size plays an important role in leaf area coverage and crop safety.
  • the present invention composition is formulated using with a safener, a dispersing agent, a wetting agent, an antifoaming agent, an anti-freezing agent, a filler, an anti-bacterial and thickener.
  • the safener used for the formulation is selected from the group consisting of cloquintocetl-mexyl, cyprosulfamide, dichlormid, dicyclonon and mefenpyr- diethyl, preferably cloquintocetl-mexyl.
  • Herbicide composition may lead to crop injury, therefore Safener is added in combination with the herbicide, so that this injury can be reduced to acceptable levels in order to avoid yield loss as a result of crop injury.
  • the dispersing agent is selected from the group consisting of Tristyrylphenol Ethoxylate Amine salt of phosphate tristyryl phenol ethylated /Acrylic Copolymer/ Ethoxylated Tristryl phenol Sulphate, Naphthalene sulfonic acid, sodium salt condensate with formaldehyde, Ethoxylated oleyl cetyl alcohol, Polyalkelene glycol ether or the combinations thereof.
  • the Wetting Agent is selected from the group consisting of Tristyrylphenol ethoxylate nonionic emulsifier/ Mixture of non-ionic surfactants and Alkoxyleted Alcohol/Block copolymer or the combinations thereof.
  • Anti-foam agents are often added either during the production stage or before filling into bottles.
  • anti-foam agents there are two types of anti-foam agents, namely silicones and non- silicones. Silicones are usually aqueous emulsions of dimethyl polysiloxane while the non- silicone anti-foam agents are water-insoluble oils, such as octanol and nonanol, or silica.
  • suitable solid or liquid carriers are: suitable liquid carriers to be used in the composition may include water, aromatic hydrocarbons such as alkylbenzenes and alkylnaphthalenes, alcohols such as methanol, cyclohexanol and decanol, ethylene glycol, polypropylene glycol and dipropropylene glycol, N,N-dimethylformamide, dimethylsulfoxide, N- alkylpyrrolidone, paraffins, oils of olive, castor, linseed, tung, sesame, com, peanut, cotton-seed, soybean, rape-seed and coconut, fatty acid esters, ketones such as cyclohexanone, 2-heptanone, isophorone and 4-hydroxy-4- methyl-2-pentanone and the like.
  • aromatic hydrocarbons such as alkylbenzenes and alkylnaphthalenes
  • alcohols such as methanol, cyclohexanol and decanol
  • Suitable solid carriers are ammonium salts and natural ground minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as finely divided silica, alumina and natural or synthetic silicates, resins, waxes, solid fertilizers, water, alcohols, especially butanol, organic solvents, mineral oils and vegetable oils, and also derivatives thereof. It is also possible to use mixtures of such carriers.
  • natural ground minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth
  • ground synthetic minerals such as finely divided silica, alumina and natural or synthetic silicates, resins, waxes, solid fertilizers, water, alcohols, especially butanol, organic solvents, mineral oils and vegetable oils, and also derivatives thereof. It is also possible to use mixtures of such carriers.
  • Solid carriers suitable for granules are: for example crushed and fractionated natural minerals, such as calcite, marble, pumice, sepiolite, dolomite, and also synthetic granules of inorganic and organic meals and also granules of organic material, such as sawdust, coconut shells, maize cobs and tobacco stalks.
  • Suitable liquefied gaseous extenders or carriers are liquids which are gaseous at ambient temperature and under atmospheric pressure, for example aerosol propellants, such as butane, propane, nitrogen and carbon dioxide.
  • Tackifiers such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules and latices, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, or else natural phospholipids, such as cephalins and lecithins and synthetic phospholipids can be used in the formulations.
  • Other possible additives are mineral and vegetable oils and waxes, optionally modified.
  • Suitable liquid solvents are essentially: aromatic compounds, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic compounds or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example mineral oil fractions, mineral and vegetable oils, alcohols, such as butanol or glycol, and also ethers and esters thereof, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulphoxide, and also water.
  • aromatic compounds such as xylene, toluene or alkylnaphthalenes
  • chlorinated aromatic compounds or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene
  • compositions according to the invention may comprise additional components, such as, for example, surfactants.
  • Suitable surfactants are emulsifiers, dispersants or wetting agents having ionic or nonionic properties, or mixtures of these surfactants. Examples of these are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic esters, taurine derivatives (preferably alkyl taurates), phosphoric esters of polyethoxylated alcohols or phenols, fatty esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates.
  • the presence of a surfactant is required if one of the active compounds and/or one of the inert carriers is insoluble in water and when the application takes place in water.
  • the proportion of surfactants is between 5 and 40 per cent by weight of the composition according to the invention.
  • colorants such as inorganic pigments, for example iron oxide, titanium oxide, Prussian blue, and organic dyes, such as alizarin dyes, azo dyes and metal phthalocyanine dyes, and trace nutrients, such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • inorganic pigments for example iron oxide, titanium oxide, Prussian blue
  • organic dyes such as alizarin dyes, azo dyes and metal phthalocyanine dyes
  • trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • additional components may also be present, for example protective colloids, binders, adhesives, thickeners, thixotropic substances, penetrants, stabilizers, sequestering agents, complex formers.
  • the active compounds can be combined with any solid or liquid additive customarily used for formulation purposes.
  • compositions according to the invention comprise between 0.05 and 99 per cent by weight, 0.01 and 98 per cent by weight, preferable between 0.1 and 95 per cent by weight, particularly preferred between 0.5 and 90 per cent by weight of the active compound combination according to the invention, very particularly preferable between 10 and 70 per cent by weight.
  • the active compound combinations or composition according to the invention can be used as such or, depending on their respective physical and/or chemical properties, in the form of their formulations or the use forms prepared therefrom, such as aerosols, capsule suspensions, cold-fogging concentrates, warm-fogging concentrates, encapsulated granules, fine granules, flowable concentrates for the treatment of seed, ready-to-use solutions, dustable powders, emulsifiable concentrates, oil-in-water emulsions, water-in-oil emulsions, macrogranules, microgranules, oil-dispersible powders, oil-miscible flowable concentrates, oil- miscible liquids, foams, pastes, pesticide-coated seed, suspension concentrates, suspoemulsion concentrates, soluble concentrates, suspensions, wettable powders, soluble powders, dusts and granules, water-soluble granules or tablets, water- soluble powders for the
  • the formulations mentioned can be prepared in a manner known per se, for example by mixing the active compounds or the active compound combinations with at least one additive.
  • Suitable additives are all customary formulation auxiliaries, such as, for example, organic solvents, extenders, solvents or diluents, solid carriers and fillers, surfactants (such as adjuvants, emulsifiers, dispersants, protective colloids, wetting agents and tackifiers), dispersants and/or binders or fixatives, preservatives, dyes and pigments, defoamers, inorganic and organic thickeners, water repellents, if appropriate siccatives and UV stabilizers, gibberellins and also water and further processing auxiliaries.
  • further processing steps such as, for example, wet grinding, dry grinding or granulation may be required.
  • Adjuvant is selected from the silicon ethoxylated oil group which is used to enhance the spreading of spray droplets on leaves faster. This activity reduces the chance of runoff but at the same time due to increased contact of area the spray solution is quickly absorbed by the treated leaves of the weeds.
  • compositions according to the invention do not only comprise ready-to-use compositions which can be applied with suitable apparatus to the plant or the seed, but also commercial concentrates which have to be diluted with water prior to use.
  • the treatment according to the invention of the plants and plant parts with the active compounds or compositions is carried out directly or by action on their surroundings, habitat or storage space using customary treatment methods, for example by dipping, spraying, atomizing, irrigating, evaporating, dusting, fogging, broadcasting, foaming, painting, spreading-on, watering (drenching), drip irrigating and, in the case of propagation material, in particular in the case of seeds, furthermore as a powder for dry seed treatment, a solution for seed treatment, a water-soluble powder for slurry treatment, by incrusting, by coating with one or more layers, etc. It is furthermore possible to apply the active compounds by the ultra-low volume method, or to inject the active compound preparation or the active compound itself into the soil.
  • the present invention furthermore comprises a method for treating seed.
  • the invention furthermore relates to seed treated according to one of the methods described in the preceding paragraph.
  • the active compounds or compositions according to the invention are especially suitable for treating seed.
  • a large part of the damage to crop plants caused by harmful organisms is triggered by an infection of the seed during storage or after sowing as well as during and after germination of the plant. This phase is particularly critical since the roots and shoots of the growing plant are particularly sensitive, and even small damage may result in the death of the plant. Accordingly, there is great interest in protecting the seed and the germinating plant by using appropriate compositions.
  • the herbicidal formulation comprising composition of Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl esters, and/or combination thereof further comprises inactive excipients including but not limited to dispersant, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, anti-microbial agent, thickener, quick coating agent or sticking agents (also referred to as “stickers” or “binders”) and buffering agent.
  • inactive excipients including but not limited to dispersant, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, anti-microbial agent, thickener, quick coating agent or sticking agents (also referred to as “stickers” or “binders”) and buffering agent.
  • Surfactants that are used as dispersants have the ability to adsorb strongly onto a particle surface and provide a charged or steric barrier to re-aggregation of particles.
  • the most commonly used surfactants are anionic, non-ionic, or mixtures of the two types.
  • the most common dispersants are sodium lignosulphonates.
  • polyelectrolytes such as sodium naphthalene sulphonate formaldehyde condensates.
  • Tristyrylphenolethoxylate phosphate esters are also used.
  • Nonionics such as alkylarylethylene oxide condensates and EO-PO block copolymers are sometimes combined with anionics as dispersants for suspension concentrates.
  • anionics such as alkylarylethylene oxide condensates and EO-PO block copolymers
  • dispersants new types of very high molecular weight polymeric surfactants have been developed as dispersants. These have very long hydrophobic ‘backbones’ and a large number of ethylene oxide chains forming the ‘teeth’ of a ‘comb’ surfactant.
  • These high molecular weight polymers can give very good long-term stability to suspension concentrates because the hydrophobic backbones have many anchoring points onto the particle surfaces.
  • dispersants used herein include but not limited to sodium lignosulphonates; sodium naphthalene sulphonate formaldehyde condensates; tristyrylphenolethoxylate phosphate esters; aliphatic alcohol ethoxylates; alky ethoxylates; EO-PO block copolymers; and graft copolymers or mixtures thereof.
  • Anti-freezing agent as used herein can be selected from the group consisting of polyethylene glycols, methoxypolyethylene glycols, polypropylene glycols, polybutylene glycols, glycerin and ethylene glycol.
  • Anti-foam agents are often added either during the production stage or before filling into bottles.
  • anti-foam agents there are two types of anti-foam agents, namely silicones and non- silicones. Silicones are usually aqueous emulsions of dimethyl polysiloxane while the non- silicone anti-foam agents are water-insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air-water interface.
  • wetting agents used in wettable powder, suspension concentrate, and water-dispersible granule formulations include but not limited to sodium lauryl sulphate; sodium dioctylsulphosuccinate; alkyl phenol ethoxylates; and aliphatic alcohol ethoxylates or mixtures thereof.
  • Suspension aid in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil. This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being treated.
  • the carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof).
  • Anti- microbial agents are used to eliminate or reduce their effect.
  • examples of such agents include, but are not limited to: propionic acid and its sodium salt; sorbic acid and its sodium or potassium salts; benzoic acid and its sodium salt; p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, l,2-benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2- methyl-4-isothiazolin-3-one, potassium sorbate, parahydroxy benzoates or mixtures thereof.Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers.
  • suspension concentrate formulations using clays and silicas.
  • these types of materials include, but are limited to, montmorillonite, e.g. bentonite; magnesium aluminum silicate; and attapulgite.
  • Water-soluble polysaccharides have been used as thickening-gelling agents for many years.
  • the types of polysaccharides most commonly used are natural extracts of seeds and seaweeds are synthetic derivatives of cellulose or mixtures thereof.
  • examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam; xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxyethyl cellulose (HEC) or mixtures thereof.
  • Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl alcohol and polyethylene oxide or mixtures.
  • the quick coating agent can be a conventionally available sticker, for example polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylate polymers and copolymers, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, poly ethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof.
  • acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly (methylmethacrylate), acrylate co-poylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetate butyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these.
  • acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly (methylmethacrylate), acrylate co-poylmers and styrene-acrylic cop
  • Biodegradable polymers that are biodegradable are also useful in the present invention.
  • a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment.
  • biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof.
  • Buffering agent as used herein is selected from group consisting of calcium hydroxyapatite, PotassiumDihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tri-calcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
  • the solvent for the formulation of the present invention may include water, water- soluble alcohols and dihydroxy alcohol ethers.
  • the water-soluble alcohol which can be used in the present invention may be lower alcohols or water-soluble macromolecular alcohols.
  • the term "lower alcohol”, as used herein, represents an alcohol having 1-4 carbon atoms, such as methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol, etc.
  • Macromolecular alcohol is not limited, as long as it may be dissolved in water in a suitable amount range, e.g., polyethylene glycol, sorbitol, glucitol, etc.
  • suitable dihydroxyalcohol ethers used in the present invention may be dihydroxy alcohol alkyl ethers or dihydroxy alcohol aryl ethers.
  • the examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, dipropylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, dipropylene glycol ethyl ether, etc.
  • dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, diethylene glycol phenyl ether, propylene glycol phenyl ether, dipropylene glycol phenyl ether, and the like. Any of the above-mentioned solvent can be used either alone or in combination thereof.
  • the raw materials used in the composition of the present invention are provided in the Table 1.
  • Example 1 Preparation of an herbicidal Composition comprising imazethapyr 10%+ Chlorimuron ethyl 1.25%+ Clodinafop Propargyl 10% SC
  • Process for the preparation suspension concentrate formulation comprising the steps of:
  • Process for the preparation suspension concentrate formulation comprising the steps of: i. preparing 2% of Gum Solution 12-18 hour prior to use by mixing demineralised water and polysaccharide. ii. homogenizing a required quantity of water, antimicrobial, and Antifoaming Agent followed by addition of polysaccharides with stirring to obtain a complete dissolution. iii. charging a vessel with required quantity of demineralized water followed by addition of required quantity of Wetting agent, dispersing agent, Filler and homogenise it for a period of ranging 45-60 minutes using high shear homogeniser. adding technical and other remaining adjuvant excluding ‘antifreeze and thickeners and homogenizing to obtain a uniform slurry. iv.
  • composition provided in the Table 3 of SC formulation can be prepared based on the above-mentioned method
  • Example 2 Preparation of an herbicidal Composition comprising imazethapyr 0.1%+ Chlorimuron ethyl 0.1%+ Clodinafop Propargyl 50 % WG
  • WG Wettable Granules
  • composition provided in the Table 4 of WG formulation can be prepared based on the above mention method
  • Example 3 Preparation of an herbicidal Composition comprising imazethapyr 10%+ Chlorimuron ethyl 1.25%+ Clodinafop Propargyl 20 % WP
  • WP wettable powder
  • Process for the preparation of wettable powder (WP) formulation comprising the steps of: i. charging the required quantity of filler, wetting agent, dispersing agent, antifoam, technical and remaining contents in premixing blender followed by homogenization for a period of 30 minutes to obtain pre- blended material ii. grinding the pre-blended material through Jet mill / air classifier mills to obtain finely grinded material iii. blending the Finely grinded material in post blender for a period of ⁇ 1- 5 hours to obtain a homogeneous material. iv. analysing the Homogeneous material. After getting approval from QC dept material is unloaded into 25 kg. HDPE bag with LDPE liner inside.
  • composition provided in the Table 6 of WP formulation can be prepared based on the above mention method
  • Example 4 Preparation of an herbicidal Composition comprising imazethapyr 10.00 %+ Chlorimuron ethyl 1.25%+ Clodinafop Propargyl 10 % EC
  • EC Emulsifiable Concentrate
  • Emulsifiable Concentrate (EC) formulation comprising the steps of: i. mixing an aromatic solvent and co-solvent into a vessel to obtain completely soluble mixture. ii. adding Technical to this solvent mixture under stirring at ambient temperature to obtain a formulation mixture iii. adding remaining emulsifier and stabilizers and contents to into this formulation mixture followed by stirring to obtain homogenized material. iv. Final product is sent for QC approval. v. After approval material is packed in required pack sizes.
  • composition provided in the Table 8 of EC formulation can be prepared based on the above mention method.
  • Example 6 Preparation of an herbicidal Composition comprising imazethapyr 10.00%+ Chlorimuron ethyl 1.25%+ Clodinafop Propargyl 20.00 % OD
  • OD oil dispersion
  • Process for the preparation of oil dispersion (OD) formulation comprising the steps of: i. Charging a required quantity of vegetable oil in vessel followed by addition of sticking agent, mix well for a period of 30 minutes using high shear homogenizer and pass-through horizontal bead mill. ii. Adding required quantity of Wetting agent, dispersing agent and Antifoam and anti-freezing agent, adjuvantand Emulsifier and homogenizing the contents for 60 minutes using high shear homogenizer. iii. Then adding the technical materials and remaining contents to obtain homogenize for further 30 minutes to obtain homogenized material iv. passing this homogenized material through horizontal bead mill to get required particle size. v. After completion of grinding cycles sample is sent to QC for A.I. & particle size analysis vi. After approval from QC, material is transferred to storage tank till packing.
  • composition provided in the Table 10 of OD formulation can be prepared based on the above mention method
  • Example 7 Preparation of an herbicidal Composition comprising imazethapyr 10.00%+ Chlorimuron ethyl 1.25 %+ Clodinafop Propargyl 10 % ME
  • Process for the preparation of ME (Micro Emulsion) formulation comprising the steps of: i. charging solvent and co-solvent into the vessel and then mix until completely soluble to obtain a mixture ii. adding technical to this solvent mixture under stirring and at ambient temperature to obtain formulation mixture iii. adding remaining emulsifier and stabilizers and other content into this formulation mixture followed by stirring to obtain homogenized iv. Final product is sent for QC approval. v. After approval material is packed in required pack sizes.
  • composition provided in the Table 12 of ME formulation can be prepared based on the above mention method
  • Soybean (Glycine max) is one of the most important commercial crops in India.
  • the crop is called “Golden Bean” or “Miracle crop” of the 21st century because of its multiple uses. It has the highest protein content (40-42 %), 20 percent oil, rich in lysine and vitamins A, B and D, also rich source of minerals and essential amino acids (Jadhav, 2014).
  • Several herbicides viz., Pendimethalin, Flutolanil, Metolachlor and Alachlor etc. were in use for controlling weeds associated in soybean, but these have not been found much effective in controlling all sort of weeds.
  • a field experiment is conducted in kharif 2018 for the two years at Khargoan in M.P. with an average annual rainfall of 850-900 mm.
  • the experiment comprising of 31 treatments including pre mixed and tank mixtures ternary combinations which were laid out in a randomized block design replicated thrice.
  • Imazethapyr lOEC at different doses 40, 60, 75, 100, g. a.i./ha
  • Chlorimuron Ethyl 25% WP @ (5, 7.5, 9.3 & 12.5 g. a.i./ha, Clodinafop propargyl 15% WP @ (267,400, 500 & 667 g. a.i./ha), and various combinations (pre mixed and tank mixtures of Imazethapyr, Chlorimuron ethyl and Clodinafop propargyl) as mentioned in the Table 13,
  • Soybean variety “JS 335” was sown at 30 x 10 cm spacing. The fertilizer dose of 25 kg N, 62.5 kg P and 25 kg K per hectare was applied to the soybean crop.
  • a spray volume of 500 litres ha 1 was used.
  • Hand weeding was done twice at 20 and 40 DAS. As per treatments, Pendimethalin 30% EC were sprayed 0-3 days after sowing. The other solo and ternary herbicides combinations & Chlorimuron Ethyl 25% WP was sprayed 12-15 days after sowing. Herbicides were sprayed with the help of a knapsack sprayer fitted with a flat-fan nozzle.
  • a quadrate of 0.25 m 2 size was selected randomly at three spots in each treatment.
  • Species wise weed count was recorded at 30 and 60 days and were expressed as number/m2 weeds collected at 30 and 60 days after the spray were dried at 70° C for 24 hours and weighed. In the succeeding crop sequence, Bengal gram was sown after the harvest of soybean crop.
  • weed control index was calculated as follows (Mani et ah, 1973 and Das, 2008). It indicates the per cent reduction in the dry weight in treated plots compared to weedy plots.
  • WCI Weed control Index
  • DWC Dry weight of weeds in control plots
  • DWT Dry weight of weeds in treated plots Weed bio-mass was drastically reduced in all the herbicidal treatments, at mediocre to high doses of ternary mixture the results were at par with two hand weeding.
  • Table 17 Crop safety of Ternary mixture of Imazethapyr, Chlorimuron ethyl & Clodinafop propargyl and impact on plant growth attributes.
  • Twice hand weeded plots were best in plant height 52.67 cm but in ternary mixtures were close second, whereas in case solo herbicide treatment the height reduced due to increased weed competition and less of herbicide treatment shock.
  • Number of branches except the control plots (6.3) were more or less ranging between 9 to 11/plant. In general plants were healthy and good canopy. Number of Soya pods in ternary herbicide treatments were also higher than the other treatments.
  • Table 18 Ternary mixture of Imazethapyr, Chlorimuron ethyl & Clodinafop propargyl and impact on yield and net returns.
  • Table 20 Effect of herbicides treatment on the succeeding crop of Bengal crop Growth parameters as well yield of succeeding crop of Bengal gram taken in the same sub plots of the experimental field shown no reduction in germination, nil phytotoxicity or injury to Bengal gram crop. In fact, the yield attributes confirmed that there is no residual impact of the ternary mixtures on the succeeding crop. Similar efficacy has been observed for the OD formulation also in terms of the above noted parameters.

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Abstract

La présente invention concerne une composition herbicide synergique comprenant un herbicide à base d'imidazolinone, un herbicide sulfonylurée et un herbicide aryloxyphénoxy propionate pour lutter contre les végétations indésirables.
PCT/IB2021/055784 2020-05-29 2021-06-29 Composition herbicide synergique WO2021240489A2 (fr)

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DE19834629A1 (de) * 1998-07-31 1998-12-03 Novartis Ag Herbizides Mittel
DE19836700A1 (de) * 1998-08-13 2000-02-17 Hoechst Schering Agrevo Gmbh Herbizide Mittel für tolerante oder resistente Getreidekulturen
WO2011159879A2 (fr) * 2010-06-16 2011-12-22 Dow Agrosciences Llc Compositions herbicides synergiques contenant du propyzamide et de l'aminopyralide
WO2018108612A1 (fr) * 2016-12-14 2018-06-21 Basf Se Compositions herbicides contenant des isoxazolo[5,4-b]pyridines

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